Magnetic tape, magnetic tape cartridge, and magnetic tape device

Abstract

To provide a magnetic tape which may contribute to operational stability improvement of a drive during recording and / or reproduction after prolonged storage.SOLUTION: A magnetic tape is provided, comprising a non-magnetic support body and a magnetic layer containing ferromagnetic powder and having a friction coefficient of 0.35 or less as measured on a base material portion of a surface thereof and a standard deviation σ of the friction coefficient of 0.05 or less in a width direction of the surface thereof. Also provided are a magnetic tape cartridge and a magnetic tape device that comprise the magnetic tape.SELECTED DRAWING: None

Description

Technical Field

[0001] The present invention relates to a magnetic tape, a magnetic tape cartridge, and a magnetic tape device.

Background Art

[0002] Magnetic recording media include tape-shaped and disk-shaped ones. For data storage applications such as data backup and archiving, tape-shaped magnetic recording media, that is, magnetic tapes, are mainly used (see, for example, Patent Documents 1 to 3).

Prior Art Documents

Patent Documents

[0003]

Patent Document 1

Patent Document 2

Patent Document 3

Summary of the Invention

Problems to be Solved by the Invention

[0004] Recording of data on a magnetic tape is usually performed by running the magnetic tape in a magnetic tape device (commonly called a "drive") and causing a magnetic head to follow a data band of the magnetic tape to record data on the data band. As a result, data tracks are formed on the data band. Also, at the time of reproducing the recorded data, the magnetic tape is run in the magnetic tape device, and the magnetic head is caused to follow the data band of the magnetic tape to read the data recorded on the data band. And after such recording or reproduction, the magnetic tape is usually stored in a state of being wound around a reel inside a magnetic tape cartridge or the like until the next recording and / or reproduction is performed.

[0005] In order to improve the accuracy with which a magnetic head follows a data band of a magnetic tape during recording and / or playback as described above, a system that performs head tracking using a servo signal (hereinafter referred to as a "servo system") has been put into practical use. However, after the above storage, when recording and / or playback is performed, due to the tape width deformation of the magnetic tape caused by storage, a phenomenon occurs in which the magnetic head for recording and / or playing back data deviates from the target track position (generally referred to as "off-track"). Off-track can cause overwriting of recorded data, playback failures, etc., which will reduce the operating stability of the drive. In recent years, due to the increase in track density accompanying the increase in the storage capacity of magnetic tapes, off-track is likely to occur, so the need to improve the operating stability of drives is increasing. On the other hand, in recent years, in the data storage field, long-term storage of data, called archive, has been carried out. However, generally, as the storage period becomes longer, the tape width deformation of the magnetic tape tends to occur more easily and the occurrence frequency of off-track tends to increase.

[0006] In view of the above, an aspect of the present invention aims to provide a magnetic tape that can contribute to improving the operating stability of a drive during recording and / or playback after long-term storage.

Means for Solving the Problems

[0007] An aspect of the present invention is as follows. [1] A magnetic tape having a non-magnetic support and a magnetic layer containing ferromagnetic powder, where the coefficient of friction measured at the base portion of the surface of the magnetic layer is 0.35 or less, and the standard deviation σ of the coefficient of friction in the width direction of the surface of the magnetic layer is 0.05 or less. [2] The magnetic tape according to [1], where the coefficient of friction measured at the base portion is 0.20 or more and 0.35 or less. [3] The magnetic tape according to [1] or [2], where the standard deviation σ of the coefficient of friction is 0.01 or more and 0.05 or less. [4] A magnetic tape as described in any of [1] to [3], wherein the standard deviation σ of the coefficient of friction is 0.01 or more and 0.02 or less. [5] A magnetic tape according to any one of [1] to [4], further comprising a non-magnetic layer containing non-magnetic powder between the non-magnetic support and the magnetic layer. [6] The magnetic tape according to [5], wherein the thickness of the non-magnetic layer is 0.1 μm or more and 0.7 μm or less. [7] A magnetic tape according to any one of [1] to [6], further comprising a back coat layer containing non-magnetic powder on the surface side of the non-magnetic support opposite to the surface side having the magnetic layer. [8] A magnetic tape as described in any of [1] to [7], wherein the tape thickness is 5.2 μm or less. [9] A magnetic tape as described in any of [1] to [8], wherein the tape thickness is 5.0 μm or less.

[10] A magnetic tape according to any of [1] to [9], wherein the vertical aspect ratio of the magnetic tape is 0.60 or greater.

[11] A magnetic tape according to any of [1] to

[10] , wherein the vertical aspect ratio of the magnetic tape is 0.65 or greater.

[12] The coefficient of friction measured in the above-mentioned base material is 0.20 or more and 0.35 or less, The standard deviation σ of the above friction coefficient is 0.01 or more and 0.02 or less. The non-magnetic support and the magnetic layer further comprise a non-magnetic layer containing non-magnetic powder. The thickness of the above non-magnetic layer is 0.1 μm or more and 0.7 μm or less. The non-magnetic support further has a back coat layer containing non-magnetic powder on the surface side opposite to the surface side having the magnetic layer. The tape thickness is 5.0 μm or less, and The magnetic tape described in [1], wherein the vertical aspect ratio of the magnetic tape is 0.65 or greater. A magnetic tape cartridge containing the magnetic tape described in any of

[13] [1] to

[12] . A magnetic tape device containing a magnetic tape as described in any of

[14] [1] to

[12] .

[15] Further including a magnetic head, The magnetic head has a module including an element array having a plurality of magnetic head elements between a pair of servo signal reading elements, and The magnetic tape device described in

[14] , wherein the angle θ made between the axis of the element array and the width direction of the magnetic tape while the magnetic tape is running within the magnetic tape device is changed. [Effects of the Invention]

[0008] According to one aspect of the present invention, a magnetic tape can be provided that contributes to improving the operational stability of a drive during recording and / or playback after long-term storage. Furthermore, according to one aspect of the present invention, a magnetic tape cartridge and a magnetic tape device containing such a magnetic tape can be provided. [Brief explanation of the drawing]

[0009] [Figure 1] An example of a track profile is shown, with the track position plotted on the horizontal axis and the output of the playback signal on the vertical axis. [Figure 2] An example of a graph relating to the initial nonlinear components is shown. [Figure 3] An example of a graph showing the nonlinear components after storage is shown. [Figure 4] This is an example of a graph showing the absolute value of the difference between the initial nonlinear component and the nonlinear component after storage for each regenerative element (difference in the nonlinear component before and after storage). [Figure 5] This is a schematic diagram showing an example of a magnetic head module. [Figure 6] This is an explanatory diagram illustrating the relative positional relationship between the module and the magnetic tape while the magnetic tape is running in a magnetic tape drive. [Figure 7] This is an explanatory diagram regarding the change in angle θ during magnetic tape travel. [Figure 8] An example of the manufacturing process for magnetic tape (process schematic diagram) is shown. [Figure 9] An example of the arrangement of data bands and servo bands is shown. [Figure 10]This shows an example of a servo pattern arrangement for an LTO (Linear Tape-Open) Ultrium format tape. [Figure 11] This is an explanatory diagram of the method for measuring the angle θ while a magnetic tape is running. [Figure 12] This is a schematic diagram showing an example of a magnetic tape drive. [Modes for carrying out the invention]

[0010] [Magnetic tape] One aspect of the present invention relates to a magnetic tape having a non-magnetic support and a magnetic layer containing ferromagnetic powder. The coefficient of friction measured at the substrate portion of the surface of the magnetic layer (hereinafter also referred to as "substrate friction") is 0.35 or less. Furthermore, the standard deviation σ of the coefficient of friction in the width direction of the surface of the magnetic layer (hereinafter also referred to as "width direction σ of substrate friction") is 0.05 or less.

[0011] As a result of diligent research, the inventors have newly discovered that a magnetic tape having a surface friction within the above range and a surface friction width σ within the above range can contribute to improving the operational stability of a drive. The inventors' hypothesis regarding this point is described below. However, the present invention is not limited to the hypothesis described herein. As mentioned earlier, tape width deformation caused by long-term storage can lead to a decrease in the operational stability of the magnetic tape in the drive. In this regard, it has recently been proposed to use servo signals to acquire widthwise dimensional information of the magnetic tape while it is running, and to change the angle at which the axial direction of the magnetic head module is tilted relative to the widthwise direction of the magnetic tape (hereinafter also referred to as the "head tilt angle") according to the acquired dimensional information (see Patent Documents 1 and 2, for example, paragraphs 0059 to 0067 and paragraph 0084 of Patent Document 1). In addition, it is also possible to control the widthwise dimensions of the magnetic tape by acquiring widthwise dimensional information of the magnetic tape while it is running using servo signals and adjusting the tension applied in the longitudinal direction of the magnetic tape according to the acquired dimensional information (see paragraph 0171 of Patent Document 3 as an example). For example, the above-mentioned means for controlling the dynamic track position during magnetic tape running can serve as a means for suppressing off-tracking. However, in their diligent efforts to further improve the operational stability of the drive during recording and / or playback after long-term storage, the inventors noticed that there may be off-track factors that are difficult to compensate for with dynamic track position control means. This point will be explained further below. When dynamic track position control is performed by changing the head tilt angle, the pitch of the magnetic head elements (specifically, the recording elements and / or playback elements) changes uniformly according to the head tilt angle, regardless of the position in the tape width direction. When dynamic track position control is performed by adjusting the tension applied in the longitudinal direction of the magnetic tape, the tension is usually adjusted across the entire width of the tape, so the tape width changes uniformly regardless of the position in the tape width direction due to the tension adjustment. If the degree of tape width deformation is uniform across the entire magnetic tape, that is, if the tape width deformation component consists only of a linear component, it is possible to completely compensate for off-tracks by the above control means. Therefore, it is possible to perfectly align the data track and the magnetic head elements. On the other hand, if the degree of tape width deformation is uneven and varies depending on the position, that is, if the tape width deformation component includes a nonlinear component, it is difficult for the above control means to compensate for off-tracks caused by the nonlinear component. The inventors of the present invention considered that reducing this nonlinear component could contribute to suppressing the decrease in drive operation stability caused by off-track factors that are difficult to compensate for by dynamic track position control means. In this regard, the inventors believe that in magnetic tape, having the substrate friction within the above range, and having the substrate friction in the width direction σ within the above range, can contribute to suppressing the generation of nonlinear components in the tape width deformation. The inventors surmise that this will contribute to improving the operational stability of the drive during recording and / or playback after long-term storage.

[0012] <Surface friction and width direction σ of surface friction>

[0013] In the present invention and this specification, "magnetic layer surface" is synonymous with the magnetic layer side surface of the magnetic tape, and "base material portion" refers to the portion of the magnetic layer surface of the magnetic tape that is specified by the following method. An atomic force microscope (AFM) measures the surface where the volumes of the convex and concave components in the field of view are equal, and this surface is defined as the reference plane. Protrusions with a height of 15 nm or more from the reference plane are defined as protrusions. Then, the area where there are zero such protrusions, i.e., the area on the magnetic layer surface of the magnetic tape where no protrusions with a height of 15 nm or more from the reference plane are detected, is identified as the base material. Furthermore, the coefficient of friction measured on the base material (base material friction) shall be the value measured by the following method. On the substrate (measurement location: 10 μm length along the longitudinal direction of the magnetic tape), a diamond spherical indenter with a radius of 1 μm is moved back and forth once with a load of 100 μN and a speed of 1 μm / second to measure the frictional force (horizontal force) and normal force. The frictional force and normal force measured here are the arithmetic mean of the respective values ​​obtained by continuously measuring the frictional force and normal force during the above single back and forth movement. The above measurements can be performed, for example, with a Hysitron TI-950 triboindenter. The friction coefficient μ value is then calculated from the measured arithmetic mean of the frictional force and the arithmetic mean of the normal force. The friction coefficient is a value obtained from the frictional force (horizontal force) F (unit: Newton (N)) and the normal force N (unit: Newton (N)) using the following formula: F = μN. The above measurements and calculation of the friction coefficient μ value are performed at the five measurement locations described below, and the arithmetic mean of the five obtained measurements is taken as the friction coefficient (surface friction) measured at the base material on the surface of the magnetic layer of the magnetic tape being measured. Furthermore, the standard deviation σ (i.e., the positive square root of the variance) of the above five measurements is taken as the standard deviation σ (widthwise surface friction σ) of the surface friction in the width direction on the surface of the magnetic layer of the magnetic tape being measured. The five measurement locations will be the same in the longitudinal direction but different in the width direction. The longitudinal locations will be randomly selected on the magnetic layer surface, and at these longitudinal locations, the width direction will be divided into five sections relative to the magnetic tape width (therefore, if the magnetic tape width is W, the width of each section will be "W / 5"), and the substrate area will be identified and the substrate friction measured in a randomly selected area within each section.

[0014] (Surface friction) The surface friction of the magnetic tape described above is 0.35 or less, from the viewpoint of improving the operational stability of the drive during recording and / or playback after long-term storage. From the viewpoint of the above, the surface friction is preferably 0.30 or less, and more preferably 0.25 or less. The surface friction can also be, for example, 0.10 or more, 0.15 or more, or 0.20 or more. From the viewpoint of improving the operational stability of the drive during recording and / or playback after long-term storage, it is presumed that a smaller value of surface friction is more preferable.

[0015] (Horizontal direction σ of surface friction) The standard deviation σ of the friction coefficient in the width direction of the surface of the magnetic layer of the magnetic tape (width direction σ of the substrate friction) is 0.05 or less from the viewpoint of improving the operational stability of the drive during recording and / or playback after long-term storage. From the viewpoint of the above, the width direction σ of the substrate friction is preferably 0.04 or less, more preferably 0.03 or less, and even more preferably 0.02 or less. The width direction σ of the substrate friction can be, for example, 0 or more or 0.01 or more. From the viewpoint of improving the operational stability of the drive during recording and / or playback after long-term storage, it is presumed that a smaller value of the width direction σ of the substrate friction is more preferable.

[0016] The method for controlling surface friction and the method for controlling the widthwise σ of surface friction will be described later.

[0017] <Nonlinear component of tape width deformation> The inventors believe that the nonlinear component of tape width deformation described above can be indicated by the "nonlinear component in the tape width direction resulting from 10 days of storage in an environment of 60°C and 20% relative humidity," which can be determined by the following method. The storage condition of "10 days of storage in an environment of 60°C and 20% relative humidity" is adopted as an example of storage conditions under accelerated conditions, which correspond to long-term data storage known as archiving, and the magnetic tape described above is not limited to those stored under such conditions. The following operations and measurements are performed in an environment with a temperature of 20-25°C and a relative humidity of 40-60%, unless otherwise specified. The magnetic tape to be measured will be a magnetic tape with a length of 200m or more. The magnetic tape to be measured is wound onto a magnetic tape reel with a hub diameter (outer diameter, the same applies hereafter) of 44 mm, using a device with a winding mechanism that applies tension to the magnetic tape in the longitudinal direction. The magnetic tape wound on the reel in this manner is then stored for at least 24 hours in an environment with a temperature of 20-25°C and a relative humidity of 40-60% before the following measurements. For magnetic tape, the end on the side where winding onto the reel begins is called the inner circumference end, and the other end is called the outer circumference end. The following measurements will be performed in the central wrap of each data band in the area within 100m from the outer circumference end (hereinafter referred to as the "outer circumference area") and the area within 100m from the inner circumference end (hereinafter referred to as the "inner circumference area"). The following measurements are performed using a magnetic head equipped with a playback module containing an array of elements, each having 10 or more playback elements with an element width (specifically, playback element width) of 0.2 μm to 1.0 μm between a pair of servo signal reading elements, and a recording module containing an array of elements, each having 10 or more recording elements with an element width (specifically, recording element width) of 1.2 μm to 2.9 μm between a pair of servo signal reading elements. "Element width" refers to the physical dimension of the element width and can be measured using an optical microscope, scanning electron microscope, etc. In the recording module, the distance between two adjacent recording elements in the head width direction is 83.25 μm. In the playback module, the distance between two adjacent playback elements in the head width direction is 83.25 μm. The above distances are the distance between the centers of two adjacent recording elements in the recording module and the distance between the centers of two adjacent playback elements in the playback module, and can be measured using an optical microscope, etc. In the measurements for the embodiments and comparative examples described later, a magnetic head was used that included a recording module with an element array having 32 channels (channels 0 to 31) of recording elements between a pair of servo signal reading elements, and a playback module with an element array having 32 channels (channels 0 to 31) of playback elements between a pair of servo signal reading elements. The reel on which the magnetic tape to be measured is wound, along with the magnetic head, is attached to the tape transport system of a magnetic tape device to record and play back data. The tape transport system is attached to a recording / playback amplifier capable of driving the magnetic head elements (specifically, the recording and playback elements) of the magnetic head. The recording / playback amplifier can be controlled from a computer (PC: Personal Computer) via a controller. The magnetic head is mounted on an actuator (piezo motor or VCM (voice coil motor)) that operates in the tape width direction, and can servo-follow so that the magnetic head remains at a constant track position during tape travel based on the servo signal of the magnetic tape. Furthermore, to compensate for the linear component of tape width deformation, the head tilt angle of the magnetic head can be changed to dynamically control the track position so that the difference in the width direction reading position PES (Position Error Signal) signals (PES1, PES2) based on the servo signals obtained by two upper and lower servo signal reading elements remains constant. The above-mentioned servo-following and dynamic track position control are performed during the following recording and playback. Next, while running the magnetic tape at a constant speed of 3.0 m / s, a DC (Direct Current) pattern is recorded on the first wrap, a single-frequency signal of 255 kfci is recorded on the second wrap, and a DC pattern is recorded on the third wrap, all in the same direction. The unit "kfci" is the unit of linear recording density (cannot be converted to the SI system). Single recording is performed on three or more tracks such that the difference between (PES1 + PES2) / 2 is 1200 nm. Single recording is also called tile recording. Next, for the center wrap of three consecutive wraps, data playback is performed over a length of 90m in both the area within 100m from the outer edge of the tape (outer edge area) and the area within 100m from the inner edge of the tape (inner edge area). The playback signal waveform and servo signal waveform are acquired and saved using an oscilloscope. After each measurement, the track position of the playback element is moved in the tape width direction at intervals of 1 / 30 or less of the track pitch. The "output of the playback signal" is calculated for each playback element from the playback signal waveform acquired and saved using the oscilloscope, and the track position is calculated from the servo signal waveform. From these results, a track profile is created with the track position plotted on the horizontal axis and the output of the playback signal plotted on the vertical axis. Figure 1 shows an example of the track profile created in this way. The median value between two track positions that are more than 1 dB below the maximum output of the playback signal is determined, and the median value is plotted on the vertical axis for each playback element. A linear approximation line is obtained by linear fitting using the least squares method. For both the outer and inner regions of the tape, the difference between the above linear approximation line and the measured value is calculated for each playback element, and this is defined as the "initial nonlinear component". Figure 2 shows an example of a graph relating to the initial nonlinear component. In the example shown in Figure 2 and the example shown in Figure 3 described later, the number of playback elements (number of channels) is 32 channels (playback element number (No.): channel 0 to channel 31). After measuring the initial nonlinear components as described above, the magnetic tape to be measured is wound onto a magnetic tape reel with a hub diameter of 44 mm, using a device with a winding mechanism that applies tension to the magnetic tape in the longitudinal direction, with a tension of 0.6 N in the longitudinal direction of the magnetic tape. During this winding, the end that was the inner circumference end of the tape when it was wound onto the reel before the initial measurement of the nonlinear components becomes the inner circumference end of the tape again. The magnetic tape wound onto the reel in this manner is stored for 10 days in an environment with a temperature of 60°C and a relative humidity of 20%. After the above storage, the magnetic tape to be measured is stored on the reel in an environment with a temperature of 20-25°C and a relative humidity of 40-60% for 24 hours or more (but up to a maximum of 120 hours). Then, using the magnetic tape device used for measuring the initial nonlinear components, the entire length of the magnetic tape to be measured is run back and forth once (forward and reverse). Using the same recording element, playback element, magnetic tape device, and playback conditions as when measuring the initial nonlinear components, data playback is performed over a length of 90m in both the area within 100m from the outer edge of the tape (outer edge region) and the area within 100m from the inner edge of the tape (inner edge region). The output of the playback signal and the servo signal waveform are acquired and saved using the same oscilloscope as when measuring the initial nonlinear components. The track position of the playback element is moved relative to the tape width direction for each measurement at the same intervals as when measuring the initial nonlinear components. The "output of the playback signal" is calculated for each playback element from the playback signal waveform acquired and saved using the above oscilloscope, and the track position is calculated from the servo signal waveform. From these results, a track profile is created with the track position plotted on the horizontal axis and the output of the playback signal plotted on the vertical axis. Figure 1 is an example of a track profile created in this way. The median value between two track positions that are more than 1 dB below the maximum output of the playback signal is determined, and the median value is plotted on the vertical axis for each playback element. A linear approximation line is obtained by linear fitting using the least squares method. For both the outer and inner regions of the tape, the difference between the above linear approximation line and the measured value is calculated for each playback element, and this is defined as the "nonlinear component after storage." Figure 3 shows an example of a graph relating to the nonlinear component after storage. The absolute value of the difference between the "initial nonlinear component" and the "nonlinear component after storage" (the difference in the nonlinear component before and after storage) for each of the above-mentioned regeneration elements is calculated. Figure 4 is an example of a graph showing the absolute value of the above difference obtained for each regeneration element. The maximum value of the above absolute value in the outer circumference region and the inner circumference region of the tape is taken as the "nonlinear component of tape width deformation" of the magnetic tape being measured. The initial nonlinear component can be considered to be a nonlinear component caused by factors other than the magnetic tape. Therefore, the inventors believe that by calculating the difference in the nonlinear component before and after storage as described above, it is possible to accurately evaluate the nonlinear component caused by the magnetic tape.

[0018] The nonlinear component of tape width deformation obtained by the method described above for the magnetic tape is preferably 100 nm or less, more preferably 95 nm or less, and even more preferably 90 nm or less, 85 nm or less, 80 nm or less, 75 nm or less, 70 nm or less, 65 nm or less, 60 nm or less, 55 nm or less, and 50 nm or less, in that order. Having the substrate friction and the width direction σ of the substrate friction within the above range can contribute to controlling the value of the nonlinear component within the above range. Furthermore, the nonlinear component of tape width deformation can be, for example, 0 nm or more, greater than 0 nm, 1 nm or more, 5 nm or more, 10 nm or more, 15 nm or more, 20 nm or more, 25 nm or more, 30 nm or more, 35 nm or more, or 40 nm or more. From the viewpoint of improving the operational stability of the drive, a smaller nonlinear component of tape width deformation is preferable.

[0019] <Explanation of head tilt angle> As mentioned earlier, one example of a means for controlling the dynamic track position during magnetic tape travel is to change the head tilt angle. In this regard, the configuration of the magnetic head, the head tilt angle, etc. will be explained below. Furthermore, the reason why it is possible to control the dynamic track position during magnetic tape travel by tilting the axial direction of the magnetic head module with respect to the width direction of the magnetic tape will also be explained below.

[0020] The magnetic head may have one or more modules, two or more, or three or more, which include an element array having multiple magnetic head elements between a pair of servo signal reading elements. The total number of such modules may be, for example, five or fewer, four or fewer, or three or fewer, or the magnetic head may contain more modules than the total number exemplified herein. Examples of arrangements of multiple modules include "recording module - playback module" (total number of modules: 2), "recording module - playback module - recording module" (total number of modules: 3), etc. However, the arrangement is not limited to the examples shown herein.

[0021] Each module may include an element array, i.e., an array of elements, having multiple magnetic head elements between a pair of servo signal reading elements. A module having recording elements as magnetic head elements is a recording module for recording data onto magnetic tape. A module having playback elements as magnetic head elements is a playback module for playing back data recorded on magnetic tape. In a magnetic head, multiple modules are arranged, for example, in a recording / playback head unit, with the axes of the element arrays of each module oriented parallel to each other. Such "parallel" does not necessarily mean parallel in the strict sense, but includes a range of error that is normally acceptable in the art to which this invention belongs. The range of error can mean, for example, a range of less than ±10° of strict parallelism.

[0022] In each element array, a pair of servo signal reading elements and a plurality of magnetic head elements (i.e., recording elements or playback elements) are typically arranged in a straight line and spaced apart. Here, "arranged in a straight line" means that each magnetic head element is arranged on a straight line connecting the center of one servo signal reading element and the center of the other servo signal reading element. Furthermore, in this invention and specification, "axis of the element array" means the straight line connecting the center of one servo signal reading element and the center of the other servo signal reading element.

[0023] Next, the module configuration and other details will be further explained with reference to the drawings. However, the configurations shown in the drawings are illustrative and do not limit the present invention.

[0024] Figure 5 is a schematic diagram showing an example of a magnetic head module. The module shown in Figure 5 has multiple magnetic head elements between a pair of servo signal reading elements (servo signal reading elements 1 and 2). Magnetic head elements are also called "channels." "Ch" in the figure is an abbreviation for Channel. The module shown in Figure 5 has a total of 32 magnetic head elements, from Ch0 to Ch31.

[0025] In Figure 5, "L" represents the distance between a pair of servo signal reading elements, that is, the distance between one servo signal reading element and the other. In the module shown in Figure 5, "L" is the distance between servo signal reading element 1 and servo signal reading element 2. More specifically, it is the distance between the center of servo signal reading element 1 and the center of servo signal reading element 2. This distance can be measured, for example, by an optical microscope.

[0026] Figure 6 is an explanatory diagram of the relative positional relationship between the module and the magnetic tape during magnetic tape movement in a magnetic tape device. In Figure 6, dotted line A indicates the width direction of the magnetic tape. Dotted line B indicates the axis of the element array. Angle θ can be said to be the head tilt angle during magnetic tape movement, and is the angle between dotted line A and dotted line B. When angle θ is 0° during magnetic tape movement, the distance in the magnetic tape width direction between one servo signal reading element and the other servo signal reading element of the element array (hereinafter also referred to as the "effective distance between servo signal reading elements") is "L". In contrast, when angle θ is greater than 0°, the effective distance between servo signal reading elements is "Lcosθ", and Lcosθ is smaller than L. That is, "Lcosθ <L」である。

[0027] As mentioned earlier, during recording or playback, if the magnetic head used to record or play back data is misaligned from the intended track position due to deformation of the magnetic tape's width, phenomena such as overwriting of recorded data or playback failures may occur. For example, if the width of the magnetic tape shrinks or expands, the magnetic head element that should record or play back at the intended track position may end up recording or playing back at a different track position. Also, if the width of the magnetic tape expands, the effective distance between servo signal reading elements may become shorter than the distance between two adjacent servo bands separated by a data band (also referred to as "servo band spacing" or "servo band interval"; more specifically, the distance between the two servo bands in the width direction of the magnetic tape), which may result in data not being recorded or played back in areas close to the edge of the magnetic tape. In contrast, when the element array is tilted at an angle θ greater than 0°, as explained earlier, the effective distance between servo signal reading elements becomes "Lcosθ". The larger the value of θ, the smaller the value of Lcosθ, and the smaller the value of θ, the larger the value of Lcosθ. Therefore, by changing the value of θ according to the degree of dimensional change (i.e., contraction or expansion) in the width direction of the magnetic tape, it becomes possible to bring the effective distance between servo signal reading elements closer to or matching the spacing of the servo bands. This prevents or reduces the frequency of phenomena such as overwriting of recorded data or playback failures that occur when the magnetic head used to record or play back data is misaligned from the target track position due to width deformation of the magnetic tape during recording or playback.

[0028] Figure 7 is an explanatory diagram regarding the change in angle θ during magnetic tape travel. The angle θ at the start of the journey is θ initial This can be set to, for example, 0° or greater than or equal to 0°. In Figure 7, the central diagram shows the state of the module at the start of operation. In Figure 7, the right-hand figure shows the angle θ as θ initial An angle θ is a larger angle. cshows the state of the module when [condition]. The effective distance Lcosθ between servo signal reading elements c is a value smaller than Lcosθ at the start of magnetic tape running. When the width of the magnetic tape contracts during magnetic tape running, it is preferable to perform such angle adjustment. initial When the width of the magnetic tape contracts during magnetic tape running, it is preferable to perform such angle adjustment. On the other hand, in Fig. 7, the left figure shows the state of the module when the angle θ is an angle θ initial smaller than [angle]. e shows the state of the module when [condition]. The effective distance Lcosθ between servo signal reading elements e is a value larger than Lcosθ at the start of magnetic tape running. When the width of the magnetic tape expands during magnetic tape running, it is preferable to perform such angle adjustment. initial When the width of the magnetic tape expands during magnetic tape running, it is preferable to perform such angle adjustment.

[0029] As described above, changing the head tilt angle during magnetic tape running can contribute to preventing phenomena such as overwriting of recorded data and playback failure that may occur when the magnetic head for recording or playing data deviates from the target track position due to width deformation of the magnetic tape during recording or playback, or can contribute to reducing the occurrence frequency thereof. However, for example, in the dynamic track position control means as described above, although the off-track caused by the linear component of the tape width deformation can usually be compensated, it is difficult to suppress the off-track caused by the non-linear component. In contrast, in the above magnetic tape, it is presumed that the base friction and the width direction σ of the base friction being within the above range contribute to reducing the non-linear component of the tape width deformation. It is considered that this can improve the operation stability of the drive. Such a magnetic tape is preferable for increasing the track density to a higher density.

[0030] Hereinafter, the above magnetic tape will be described in more detail.

[0031] <Magnetic layer> (Ferromagnetic powder) As the ferromagnetic powder contained in the magnetic layer, one or more ferromagnetic powders known for use in the magnetic layers of various magnetic recording media can be used. In this invention and specification, "powder" means an aggregate of multiple particles. For example, ferromagnetic powder means an aggregate of multiple ferromagnetic particles. Furthermore, the aggregate of multiple particles is not limited to a form in which the particles constituting the aggregate are in direct contact, but also includes a form in which binders, additives, etc., described later, are interposed between the particles. The word "particle" is sometimes used to refer to powder. Using ferromagnetic powder with a small particle size is preferable from the viewpoint of improving recording density. Furthermore, the inventors' research has revealed that using ferromagnetic powder with a small particle size is preferable in reducing the value of the substrate friction in the width direction σ. The activation volume can be cited as an indicator of particle size. From the viewpoint of controlling the substrate friction in the width direction σ to the above range, the ferromagnetic powder contained in the magnetic layer has an activation volume of 2500 nm. 3 It is preferable to use the following ferromagnetic powders. The activation volume of the ferromagnetic powder is 2000 nm. 3 The following is more preferable: 1500nm 3 It is even more preferable that the following conditions are met. Furthermore, the activation volume of the ferromagnetic powder is, for example, 900 nm. 3 Above, 1000nm 3 or above or 1200nm 3 It can be any of the above.

[0032] "Activation volume" is a unit of magnetization reversal and an indicator of the magnetic size of a particle. The activation volume and the anisotropy constant Ku described herein and below are measured using a vibrating sample type magnetometer at magnetic field sweep speeds of 3 minutes and 30 minutes for the coercivity Hc measurement section (measurement temperature: 23℃±1℃), and are values ​​obtained from the following relationship between Hc and activation volume V. Note that the unit of the anisotropy constant Ku is 1erg / cc = 1.0 × 10⁻⁶. -1 J / m 3 That is the case. Hc=2Ku / Ms{1-[(kT / KuV)ln(At / 0.693)] 1 / 2} [In the above formula, Ku: anisotropy constant (unit: J / m 3 ), Ms: Saturation magnetization (unit: kA / m), k: Boltzmann constant, T: Absolute temperature (unit: K), V: Activation volume (unit: cm) 3 ), A: Spin precession frequency (unit: s) -1 ), t: magnetic field reversal time (unit: s)]

[0033] In one embodiment, the ferromagnetic powder contained in the magnetic layer may be plate-shaped ferromagnetic powder. In the present invention and this specification, "plate-shaped ferromagnetic powder" refers to an aggregate of plate-shaped ferromagnetic particles. With respect to the particle shape, "plate-shaped" refers to a shape having two opposing plate surfaces. The particle shape can be confirmed by particle photographs obtained without the orientation treatment described below and / or by particle photographs obtained with the orientation treatment described below. "Plate-shaped ferromagnetic powder" is a ferromagnetic powder in which the majority of the shapes of 500 particles randomly selected from the particles constituting the ferromagnetic powder are plate-shaped. For example, the proportion of plate-shaped particles based on the number of particles can be 50% or more, 60% or more, 70% or more, 80% or more, or 90% or more, or even 100%. The particle shape and size (e.g., plate diameter and plate thickness described below) are measured by transmission electron microscopy. Specifically, the shape and size of 500 particles are determined from particle images taken using the direct method with a transmission electron microscope (e.g., Hitachi H-9000 transmission electron microscope) with an acceleration voltage of 100kV. More specifically, particle images are taken at a magnification of 100,000x and printed on photographic paper or displayed on a screen to achieve a total magnification of 500,000x. Target particles are selected from the particle images, and their contours (independent particles without aggregation, i.e., primary particles) are traced using a digitizer. The shape and size of the particles can then be observed and measured using image analysis software (e.g., Carl Zeiss KS-400 image analysis software). By using particle images obtained by photographing the target powder without orientation treatment, the particle size on the plate surface (i.e., plate diameter) can be measured. By using particle images obtained by photographing the target powder after orientation treatment in the horizontal direction (parallel to the horizontal plane), the plate thickness can be measured. The magnetic force and size of the magnets used for this orientation treatment are not limited. An example of the orientation treatment will be described later in the Examples section. The ferromagnetic powder can be extracted from the magnetic layer by, for example, the method described in paragraph 0032 of Japanese Patent Application Publication No. 2015-91747.

[0034] Regarding the control of the widthwise σ of the substrate friction, the inventors' research has revealed that using plate-shaped ferromagnetic powder with an average plate ratio of 2.5 to 4.0 is preferable for reducing the value of the widthwise σ of the substrate friction. From this viewpoint, plate-shaped ferromagnetic powder with an average plate ratio of 2.5 or higher is preferred for the ferromagnetic powder contained in the magnetic layer, and an average plate ratio of 3.0 or higher is more preferable. Furthermore, from this viewpoint, the average plate ratio of the plate-shaped ferromagnetic powder is preferably 4.0 or lower, and more preferably 3.5 or lower.

[0035] In the present invention and this specification, "average plate ratio" refers to the value calculated as "average plate diameter / average plate thickness" by determining the arithmetic mean of the plate diameter (average plate diameter) and the arithmetic mean of the plate thickness (average plate thickness) measured for each plate-like particle among the 500 randomly selected particles. "Plate surface" refers to the plane observed in a particle photograph obtained by taking a photograph without applying the orientation treatment described above, and the plane opposite to that plane, on the surface of the plate-like particle. The diameter that allows for the longest length of the particle on the plane observed in the particle photograph obtained by taking a photograph without applying the orientation treatment described above is determined as the major axis, and the length of this major axis is defined as the "plate diameter". "Plate thickness" refers to the longest distance between two opposing plate surfaces observed in a particle photograph obtained by taking a photograph after applying the orientation treatment described above. Furthermore, the average values ​​of particle size or shape, such as the average particle size, for the various powders in this invention and specification are the arithmetic mean of the values ​​obtained for 500 randomly selected particles using the particle photographs taken as described above. The average particle sizes described in the Examples section below were obtained using a Hitachi H-9000 transmission electron microscope and Carl Zeiss KS-400 image analysis software.

[0036] As the ferromagnetic powder contained in the magnetic layer, a ferromagnetic powder having an activation volume within the above range and / or an average plate ratio within the above range is preferred.

[0037] Hexagonal ferrite powder A preferred specific example of ferromagnetic powder is hexagonal ferrite powder. For details on hexagonal ferrite powder, see, for example, paragraphs 0012 to 0030 of Japanese Patent Publication No. 2011-225417, paragraphs 0134 to 0136 of Japanese Patent Publication No. 2011-216149, paragraphs 0013 to 0030 of Japanese Patent Publication No. 2012-204726, and paragraphs 0029 to 0084 of Japanese Patent Publication No. 2015-127985. As the hexagonal ferrite powder contained in the magnetic layer, hexagonal ferrite powder having an activation volume and / or an average plate ratio within the above range is preferred.

[0038] In the present invention and this specification, "hexagonal ferrite powder" refers to a ferromagnetic powder in which a hexagonal ferrite crystal structure is detected as the main phase by X-ray diffraction analysis. The main phase refers to the structure to which the highest intensity diffraction peak in the X-ray diffraction spectrum obtained by X-ray diffraction analysis belongs. For example, if the highest intensity diffraction peak in the X-ray diffraction spectrum obtained by X-ray diffraction analysis is attributed to the hexagonal ferrite crystal structure, it shall be determined that the hexagonal ferrite crystal structure has been detected as the main phase. If only a single structure is detected by X-ray diffraction analysis, this detected structure shall be considered the main phase. The hexagonal ferrite crystal structure contains at least iron atoms, divalent metal atoms, and oxygen atoms as constituent atoms. Divalent metal atoms are metal atoms that can become divalent cations as ions, and examples include strontium atoms, barium atoms, alkaline earth metal atoms such as calcium atoms, and lead atoms. In the present invention and this specification, hexagonal strontium ferrite powder refers to powder in which the main divalent metal atom contained is strontium, and hexagonal barium ferrite powder refers to powder in which the main divalent metal atom contained is barium. The main divalent metal atom refers to the divalent metal atom that accounts for the largest proportion on an atomic percentage basis among the divalent metal atoms contained in the powder. However, rare earth atoms are not included in the above divalent metal atoms. In the present invention and this specification, "rare earth atoms" are selected from the group consisting of scandium atoms (Sc), yttrium atoms (Y), and lanthanide atoms. Lanthanide atoms are selected from the group consisting of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).

[0039] Below, we will describe hexagonal strontium ferrite powder, a form of hexagonal ferrite powder, in more detail.

[0040] As an indicator of reducing thermal fluctuations, or in other words, improving thermal stability, the anisotropy constant Ku can be cited. The hexagonal strontium ferrite powder is preferably 1.8 × 10⁻⁶ 5 J / m 3 It can have a Ku of the above, and more preferably 2.0 × 10 5 J / m 3 It can have a Ku content of the above. Also, the Ku content of hexagonal strontium ferrite powder is, for example, 2.5 × 10⁻⁶. 5 J / m 3 The following values ​​are possible. However, since a higher Ku value is preferable as it indicates higher thermal stability, the values ​​are not limited to those exemplified above.

[0041] Hexagonal strontium ferrite powder may or may not contain rare earth atoms. When hexagonal strontium ferrite powder contains rare earth atoms, it is preferable that the rare earth atoms are present at a concentration of 0.5 to 5.0 atomic percent (bulk concentration) per 100 atomic percent of iron atoms. In one embodiment, hexagonal strontium ferrite powder containing rare earth atoms may exhibit a segregation of rare earth atoms in the surface layer. In the present invention and this specification, "rare earth atom surface layer segregation" means that the rare earth atom content relative to 100% of iron atoms in a solution obtained by partially dissolving hexagonal strontium ferrite powder with acid (hereinafter referred to as "rare earth atom surface layer content" or simply "surface layer content" with respect to rare earth atoms) is different from the rare earth atom content relative to 100% of iron atoms in a solution obtained by completely dissolving hexagonal strontium ferrite powder with acid (hereinafter referred to as "rare earth atom bulk content" or simply "bulk content" with respect to rare earth atoms), Rare earth atom surface content / Rare earth atom bulk content > 1.0 This means that the ratio is satisfied. The rare earth atom content of hexagonal strontium ferrite powder described later is synonymous with the rare earth atom bulk content. In contrast, partial dissolution using acid dissolves the surface layer of the particles constituting the hexagonal strontium ferrite powder, so the rare earth atom content in the solution obtained by partial dissolution is the rare earth atom content in the surface layer of the particles constituting the hexagonal strontium ferrite powder. When the rare earth atom surface layer content satisfies the ratio "rare earth atom surface layer content / rare earth atom bulk content > 1.0", it means that in the particles constituting the hexagonal strontium ferrite powder, rare earth atoms are concentrated in the surface layer (i.e., there are more of them in the surface layer than in the interior). In this invention and specification, the surface layer means a part of the region extending from the surface to the interior of the particles constituting the hexagonal strontium ferrite powder.

[0042] When hexagonal strontium ferrite powder contains rare earth atoms, the rare earth atom content (bulk content) is preferably in the range of 0.5 to 5.0 atomic percent relative to 100 atomic percent of iron atoms. It is believed that containing rare earth atoms at the bulk content within the above range, and having the rare earth atoms unevenly distributed on the surface of the particles constituting the hexagonal strontium ferrite powder, contributes to suppressing the decrease in regeneration output during repeated regeneration. This is presumed to be because the anisotropy constant Ku can be increased by containing rare earth atoms at the bulk content within the above range, and having the rare earth atoms unevenly distributed on the surface of the particles constituting the hexagonal strontium ferrite powder. The higher the value of the anisotropy constant Ku, the more it is possible to suppress the occurrence of a phenomenon called thermal fluctuation (in other words, to improve thermal stability). By suppressing the occurrence of thermal fluctuation, the decrease in regeneration output during repeated regeneration can be suppressed. It is speculated that the uneven distribution of rare earth atoms on the surface of hexagonal strontium ferrite powder particles contributes to stabilizing the spin of iron (Fe) sites within the crystal lattice of the surface layer, thereby increasing the anisotropy constant Ku. Furthermore, it is presumed that using hexagonal strontium ferrite powder with a rare-earth atom uneven distribution on the surface as the ferromagnetic powder for the magnetic layer contributes to suppressing wear on the magnetic layer surface due to sliding with the magnetic head. In other words, it is presumed that hexagonal strontium ferrite powder with a rare-earth atom uneven distribution on the surface may also contribute to improving the running durability of the magnetic tape. This is presumed to be because the uneven distribution of rare-earth atoms on the surface of the particles constituting the hexagonal strontium ferrite powder contributes to improved interaction between the particle surface and organic substances (e.g., binders and / or additives) contained in the magnetic layer, resulting in improved strength of the magnetic layer. From the viewpoint of further suppressing the decrease in regeneration output during repeated regeneration and / or further improving running durability, the rare earth atom content (bulk content) is more preferably in the range of 0.5 to 4.5 atomic percent, even more preferably in the range of 1.0 to 4.5 atomic percent, and even more preferably in the range of 1.5 to 4.5 atomic percent.

[0043] The bulk content mentioned above is the content obtained by completely dissolving the hexagonal strontium ferrite powder. In this invention and specification, unless otherwise specified, the content of atoms refers to the bulk content obtained by completely dissolving the hexagonal strontium ferrite powder. The hexagonal strontium ferrite powder containing rare earth atoms may contain only one type of rare earth atom, or it may contain two or more types of rare earth atoms. When two or more types of rare earth atoms are included, the bulk content mentioned above is determined for the sum of the two or more types of rare earth atoms. This also applies to other components in this invention and specification. That is, unless otherwise specified, a certain component may be used alone, or two or more types may be used. When two or more types are used, the content or content refers to the sum of the two or more types.

[0044] When hexagonal strontium ferrite powder contains rare earth atoms, the rare earth atoms included may be one or more of the rare earth atoms. From the viewpoint of further suppressing the decrease in regeneration output during repeated regeneration, preferred rare earth atoms include neodymium atoms, samarium atoms, yttrium atoms, and dysprosium atoms, with neodymium atoms, samarium atoms, and yttrium atoms being more preferred, and neodymium atoms being even more preferred.

[0045] In hexagonal strontium ferrite powder having a rare-earth atom surface segregation, the rare-earth atoms only need to be segregated in the surface layer of the particles constituting the hexagonal strontium ferrite powder, and the degree of segregation is not limited. For example, in hexagonal strontium ferrite powder having a rare-earth atom surface segregation, the ratio of the rare-earth atom surface content obtained by partial dissolution under the dissolution conditions described later to the rare-earth atom bulk content obtained by total dissolution under the dissolution conditions described later, "surface content / bulk content," is greater than 1.0 and can be 1.5 or greater. A "surface content / bulk content" greater than 1.0 means that in the particles constituting the hexagonal strontium ferrite powder, rare-earth atoms are segregated in the surface layer (i.e., there are more of them in the surface layer than in the interior). Furthermore, the ratio of the surface content of rare earth atoms obtained by partial dissolution under the dissolution conditions described later to the bulk content of rare earth atoms obtained by total dissolution under the dissolution conditions described later, "surface content / bulk content," can be, for example, 10.0 or less, 9.0 or less, 8.0 or less, 7.0 or less, 6.0 or less, 5.0 or less, or 4.0 or less. However, in hexagonal strontium ferrite powder having a rare earth atom surface distribution bias, the rare earth atoms only need to be biased towards the surface of the particles constituting the hexagonal strontium ferrite powder, and the above "surface content / bulk content" is not limited to the upper or lower limits exemplified.

[0046] The partial and total dissolution of hexagonal strontium ferrite powder is described below. For hexagonal strontium ferrite powder existing as a powder, the sample powders to be partially and completely dissolved are taken from the same lot of powder. On the other hand, for hexagonal strontium ferrite powder contained in the magnetic layer of a magnetic tape, a portion of the hexagonal strontium ferrite powder extracted from the magnetic layer is subjected to partial dissolution, and another portion is subjected to total dissolution. The extraction of hexagonal strontium ferrite powder from the magnetic layer can be carried out, for example, by the method described in paragraph 0032 of Japanese Patent Application Publication No. 2015-91747. Partial dissolution, as described above, refers to a state where the hexagonal strontium ferrite powder is dissolved to the extent that residual particles can be visually confirmed in the liquid at the end of the dissolution process. For example, partial dissolution can dissolve 10 to 20% by mass of the particles constituting the hexagonal strontium ferrite powder, with the total particles being 100% by mass. On the other hand, total dissolution, as described above, refers to a state where the hexagonal strontium ferrite powder is dissolved to the extent that no residual particles can be visually confirmed in the liquid at the end of the dissolution process. The above-mentioned partial dissolution and surface layer content measurement are performed, for example, by the following method. However, the dissolution conditions such as the amount of sample powder described below are examples only, and any dissolution conditions that enable partial and total dissolution can be arbitrarily adopted. A container (e.g., a beaker) containing 12 mg of sample powder and 10 mL of 1 mol / L hydrochloric acid is held on a hot plate at a set temperature of 70°C for 1 hour. The resulting solution is filtered through a 0.1 μm membrane filter. Elemental analysis of the resulting filtrate is performed using an inductively coupled plasma (ICP) analyzer. In this way, the surface content of rare earth atoms relative to 100% iron atoms can be determined. If multiple types of rare earth atoms are detected by elemental analysis, the total content of all rare earth atoms is taken as the surface content. This is also the case when measuring bulk content. On the other hand, the measurement of total dissolution and bulk content is performed, for example, by the following method. A container (e.g., a beaker) containing 12 mg of sample powder and 10 mL of 4 mol / L hydrochloric acid is held on a hot plate at a set temperature of 80°C for 3 hours. Afterward, the bulk content relative to 100 atomic percent of iron can be determined by performing the same procedure as described above for partial dissolution and surface layer content measurement.

[0047] From the perspective of increasing the playback output when reproducing data recorded on magnetic tape, it is desirable for the mass magnetization σs of the ferromagnetic powder contained in the magnetic tape to be high. In this regard, hexagonal strontium ferrite powder containing rare earth atoms but lacking surface segregation of rare earth atoms tended to have a significantly lower σs compared to hexagonal strontium ferrite powder that does not contain rare earth atoms. In contrast, hexagonal strontium ferrite powder with surface segregation of rare earth atoms is considered preferable in order to suppress such a large decrease in σs. In one embodiment, the σs of hexagonal strontium ferrite powder is 45 A·m 2 It can be 47 A·m or more / kg. 2 It can also be more than / kg. On the other hand, σs is 80 A·m from the viewpoint of noise reduction. 2 Preferably less than / kg, at 60 A·m 2 It is more preferable that it be less than or equal to / kg. σs can be measured using a known measuring device capable of measuring magnetic properties, such as a vibrating sample magnetometer. In this invention and specification, unless otherwise specified, the mass magnetization σs is the value measured at a magnetic field strength of 15 kOe. 1 [kOe] = 10 6 It is / 4π[A / m].

[0048] Regarding the constituent atom content (bulk content) of hexagonal strontium ferrite powder, the strontium atom content can be in the range of, for example, 2.0 to 15.0 atomic percent per 100 atomic percent of iron atoms. In one form, hexagonal strontium ferrite powder may contain only strontium atoms as the divalent metal atom. In another form, hexagonal strontium ferrite powder may contain one or more other divalent metal atoms in addition to strontium atoms. For example, it may contain barium atoms and / or calcium atoms. When other divalent metal atoms besides strontium atoms are included, the barium atom content and calcium atom content in the hexagonal strontium ferrite powder can be in the range of, for example, 0.05 to 5.0 atomic percent per 100 atomic percent of iron atoms.

[0049] The known crystal structures of hexagonal ferrites include magnetoplumbite (also called "M-type"), W-type, Y-type, and Z-type. Hexagonal strontium ferrite powder may have any of these crystal structures. The crystal structure can be confirmed by X-ray diffraction analysis. Hexagonal strontium ferrite powder may show a single crystal structure or two or more crystal structures by X-ray diffraction analysis. For example, in one form, hexagonal strontium ferrite powder may show only the M-type crystal structure by X-ray diffraction analysis. For example, M-type hexagonal ferrite is AFe 12 O 19It is represented by the following compositional formula: Here, A represents a divalent metal atom, and if the hexagonal strontium ferrite powder is of type M, A is either only a strontium atom (Sr), or if A contains multiple divalent metal atoms, then as described above, strontium atoms (Sr) make up the largest proportion on an atomic percentage basis. The divalent metal atom content of hexagonal strontium ferrite powder is usually determined by the type of crystal structure of the hexagonal ferrite and is not particularly limited. The same applies to the iron atom content and oxygen atom content. Hexagonal strontium ferrite powder contains at least iron atoms, strontium atoms and oxygen atoms, and may also contain rare earth atoms. Furthermore, hexagonal strontium ferrite powder may or may not contain atoms other than these atoms. As an example, hexagonal strontium ferrite powder may contain aluminum atoms (Al). The aluminum atom content can be, for example, 0.5 to 10.0 atomic percent relative to 100 atomic percent of iron atoms. From the viewpoint of further suppressing the decrease in regeneration output during repeated regeneration, the hexagonal strontium ferrite powder preferably contains iron atoms, strontium atoms, oxygen atoms, and rare earth atoms, and the content of atoms other than these atoms is preferably 10.0 atomic percent or less, more preferably in the range of 0 to 5.0 atomic percent, and may even be 0 atomic percent, relative to 100 atomic percent of iron atoms. That is, in one embodiment, the hexagonal strontium ferrite powder does not need to contain atoms other than iron atoms, strontium atoms, oxygen atoms, and rare earth atoms. The above content expressed in atomic percent is obtained by converting the content of each atom (unit: mass%) obtained by completely dissolving the hexagonal strontium ferrite powder into an atomic percent value using the atomic weight of each atom. Furthermore, in the present invention and this specification, "does not contain" for a certain atom means that the content measured by an ICP analyzer after complete dissolution is 0 mass%. The detection limit of an ICP analyzer is typically 0.01 ppm (parts per million) or less by mass. The term "does not contain" above is used to include the presence of substances in amounts below the detection limit of the ICP analyzer.Hexagonal strontium ferrite powder can, in one form, be bismuth-free (Bi).

[0050] Regarding the measurement method for substrate friction, the reason why protrusions with a height of 15 nm or more from the reference surface were defined as protrusions is that the protrusions that are usually recognized as protrusions on the surface of the magnetic layer are mainly those with a height of 15 nm or more from the reference surface. Such protrusions are formed on the surface of the magnetic layer by non-magnetic powders added as abrasives, protrusion-forming agents, etc. In contrast, it is thought that there are microscopic irregularities on the surface of the magnetic layer that are finer than the irregularities formed by such protrusions. It is presumed that the substrate friction can be adjusted by controlling the shape of these microscopic irregularities. One means to achieve this is to use two or more ferromagnetic powders with different activation volumes. More specifically, it is thought that the ferromagnetic powder with a larger activation volume can form the above-mentioned microscopic irregularities on the substrate by becoming a convex part, and the presence rate of convex parts on the substrate can be increased by increasing the mixing ratio of the ferromagnetic powder with a larger activation volume (or conversely, the presence rate of convex parts on the substrate can be decreased by decreasing the mixing ratio). Details of this means will be described further later. However, the above-mentioned adjustment means are illustrative, and a surface friction of 0.35 or less can be achieved by any means that allows for adjustment of the surface friction, and such configurations are also included in the present invention.

[0051] As described above, one means of adjusting substrate friction is to form a magnetic layer using two or more ferromagnetic powders with different activation volumes. In this case, it is preferable to use the ferromagnetic powder with the smallest activation volume as the one used in the largest proportion among the two or more ferromagnetic powders, from the viewpoint of controlling the substrate friction and / or the width direction σ of the substrate friction within the above range. From this point of view, when using two or more ferromagnetic powders with different activation volumes as ferromagnetic powders for a magnetic layer, it is preferable to use the ferromagnetic powder with an activation volume within the range described above as the ferromagnetic powder used in the largest proportion. On the other hand, it is preferable that the other ferromagnetic powders used together with the ferromagnetic powder used in the largest proportion have a larger activation volume than the ferromagnetic powder used in the largest proportion. This is because it is thought that the value of substrate friction can be reduced by the convexity formed on the substrate by the ferromagnetic powder with a large activation volume. From this perspective, the activation volume of the ferromagnetic powder used in the largest proportion and the activation volume of the ferromagnetic powder used together with it can be calculated as "(activation volume of the latter) - (activation volume of the former)", and the difference is between 2500 and 4500 nm. 3 It is preferable that the range is within this range. It is also possible to use two or more ferromagnetic powders with different activation volumes as ferromagnetic powders used together with the ferromagnetic powder used in the largest proportion. In this case, it is preferable that the activation volume of at least one of the two or more ferromagnetic powders satisfies the above difference with respect to the activation volume of the ferromagnetic powder used in the largest proportion, it is more preferable that the activation volumes of more types of ferromagnetic powders satisfy the above difference, and it is even more preferable that the average particle size of all ferromagnetic powders satisfies the above difference. Furthermore, it is preferable that some or all of the multiple types of ferromagnetic powders are plate-shaped ferromagnetic powders having an average plate ratio within the range described above.

[0052] For two or more ferromagnetic powders with different activation volumes, from the viewpoint of controlling substrate friction, the mixing ratio of the ferromagnetic powder used in the largest proportion to the other ferromagnetic powders (the sum of those if two or more other ferromagnetic powders with different activation volumes are used) is preferably in the range of 90.0:10.0 to 99.9:0.1 by mass, and more preferably in the range of 95.0:5.0 to 99.5:0.5. Here, ferromagnetic powders with different activation volumes refer to the entire lot or a part of the lot of ferromagnetic powders with different activation volumes.

[0053] The content (filling rate) of ferromagnetic powder in the magnetic layer is preferably in the range of 50 to 90% by mass, and more preferably in the range of 60 to 90% by mass, relative to the total mass of the magnetic layer. A high filling rate of ferromagnetic powder in the magnetic layer is preferable from the viewpoint of improving recording density.

[0054] (Binder) The above magnetic tape can be a coated magnetic tape, and the magnetic layer may contain a binder. The binder is one or more resins. Various resins commonly used as binders for coated magnetic recording media can be used as the binder. For example, as the binder, a resin selected from polyurethane resin, polyester resin, polyamide resin, vinyl chloride resin, acrylic resin copolymerized with styrene, acrylonitrile, methyl methacrylate, etc., cellulose resin such as nitrocellulose, epoxy resin, phenoxy resin, polyvinyl acetal, polyvinyl alkylal resin such as polyvinyl butyral can be used alone or in mixture of multiple resins. Among these, polyurethane resin, acrylic resin, cellulose resin, and vinyl chloride resin are preferred. These resins may be homopolymers or copolymers. These resins can also be used as binders in the non-magnetic layer and / or back coat layer described later. For more information on the binders, refer to paragraphs 0028 to 0031 of Japanese Patent Application Publication No. 2010-24113. The binder may also be a radiation-curable resin such as an electron beam-curable resin. For radiation-curable resins, refer to paragraphs 0044 to 0045 of Japanese Patent Publication No. 2011-048878. The average molecular weight of the resin used as a binder can be, for example, 10,000 to 200,000 as a weight-average molecular weight. In this invention and specification, the weight-average molecular weight is the value obtained by converting the value measured under the following measurement conditions by gel permeation chromatography (GPC) to polystyrene equivalent. The weight-average molecular weight of the binders shown in the examples described later is the value obtained by converting the value measured under the following measurement conditions to polystyrene equivalent. The binder can be used in an amount of, for example, 1.0 to 30.0 parts by mass per 100.0 parts by mass of ferromagnetic powder. GPC device: HLC-8120 (manufactured by Tosoh Corporation) Column: TSK gel Multipore HXL-M (manufactured by Tosoh Corporation, 7.8mm ID (Inner Diameter) × 30.0cm) Eluent: Tetrahydrofuran (THF)

[0055] (Hardening agent) A curing agent can also be used together with a resin that can be used as a binder. In one form, the curing agent can be a thermosetting compound, which is a compound that undergoes a curing reaction (crosslinking reaction) by heating, and in another form, it can be a photocurable compound, which undergoes a curing reaction (crosslinking reaction) by light irradiation. As the curing reaction progresses during the magnetic layer formation process, at least a portion of the curing agent may be included in the magnetic layer in a state where it has reacted (crosslinked) with other components such as the binder. This also applies to layers formed using a composition that contains a curing agent when the composition used to form other layers contains a curing agent. Preferred curing agents are thermosetting compounds, and polyisocyanates are preferred. For details on polyisocyanates, refer to paragraphs 0124 to 0125 of Japanese Patent Application Publication No. 2011-216149. The curing agent can be used in the magnetic layer forming composition in an amount of, for example, 0 to 80.0 parts by mass, preferably 50.0 to 80.0 parts by mass, per 100.0 parts by mass of the binder.

[0056] (Additives) The magnetic layer may contain one or more additives as needed. Commercially available additives can be appropriately selected and used according to the desired properties. Alternatively, compounds synthesized by known methods can be used as additives. Additives can be used in any amount. An example of an additive is the curing agent mentioned above. Additives that can be included in the magnetic layer include non-magnetic powders (e.g., inorganic powders, carbon black, etc.), lubricants, dispersants, dispersion aids, antifungal agents, antistatic agents, antioxidants, etc. For example, for lubricants, refer to paragraphs 0030-0033, 0035, and 0036 of Japanese Patent Application Publication No. 2016-126817. A lubricant may also be included in the non-magnetic layer described later. For lubricants that can be included in the non-magnetic layer, refer to paragraphs 0030-0031, 0034, 0035, and 0036 of Japanese Patent Application Publication No. 2016-126817. For dispersants, see paragraphs 0061 and 0071 of Japanese Patent Publication No. 2012-133837. Dispersants may be added to the composition for forming a non-magnetic layer. For dispersants that can be added to the composition for forming a non-magnetic layer, see paragraph 0061 of Japanese Patent Publication No. 2012-133837. Non-magnetic powders that can be included in the magnetic layer include non-magnetic powders that can function as abrasives, and non-magnetic powders that can function as protrusion-forming agents that form appropriately protruding protrusions on the surface of the magnetic layer (e.g., non-magnetic colloidal particles). For example, for abrasives, see paragraphs 0030 to 0032 of Japanese Patent Publication No. 2004-273070. As protrusion-forming agents, colloidal particles are preferred, inorganic colloidal particles are preferred from the viewpoint of availability, inorganic oxide colloidal particles are more preferred, and silica colloidal particles (colloidal silica) are even more preferred. The average particle size of the abrasive and the protrusion-forming agent is preferably in the range of 30 to 200 nm, and more preferably in the range of 50 to 100 nm.

[0057] The magnetic layer described above can be provided directly on the surface of a non-magnetic support, or indirectly via a non-magnetic layer.

[0058] <Nonmagnetic layer> Next, the non-magnetic layer will be described. The magnetic tape described above may have a magnetic layer directly on the surface of a non-magnetic support, or it may have a magnetic layer on the surface of a non-magnetic support via a non-magnetic layer containing non-magnetic powder. The non-magnetic powder used in the non-magnetic layer may be an inorganic powder or an organic powder. Carbon black can also be used. Examples of inorganic powders include metals, metal oxides, metal carbonates, metal sulfates, metal nitrides, metal carbides, and metal sulfides. These non-magnetic powders are commercially available and can also be manufactured by known methods. For details, see paragraphs 0146 to 0150 of Japanese Patent Application Publication No. 2011-216149. For carbon black that can be used in the non-magnetic layer, see paragraphs 0040 and 0041 of Japanese Patent Application Publication No. 2010-24113. The content (filling rate) of non-magnetic powder in the non-magnetic layer is preferably in the range of 50 to 90% by mass, and more preferably in the range of 60 to 90% by mass, relative to the total mass of the non-magnetic layer.

[0059] The non-magnetic layer may contain a binder and may also contain additives. For further details regarding the binder, additives, etc., of the non-magnetic layer, known technology relating to non-magnetic layers can be applied. Furthermore, for example, regarding the type and content of the binder, the type and content of the additives, etc., known technology relating to magnetic layers can also be applied.

[0060] In the present invention and this specification, the non-magnetic layer includes a substantially non-magnetic layer containing a small amount of ferromagnetic powder, for example as an impurity or intentionally, along with the non-magnetic powder. A substantially non-magnetic layer is defined as a layer having a remanent magnetic flux density of 10 mT or less, a coercivity of 7.96 kA / m(100 Oe) or less, or a layer having a remanent magnetic flux density of 10 mT or less and a coercivity of 7.96 kA / m(100 Oe) or less. It is preferable that the non-magnetic layer has no remanent magnetic flux density and coercivity.

[0061] <Nonmagnetic support> Next, non-magnetic supports will be described. Examples of non-magnetic supports (hereinafter also simply referred to as "supports") include known materials such as biaxially oriented polyethylene terephthalate, polyethylene naphthalate, polyamide, polyamide-imide, and aromatic polyamide. Among these, polyethylene terephthalate, polyethylene naphthalate, and polyamide are preferred. These supports may be subjected to pre-treatment such as corona discharge, plasma treatment, easy-adhesion treatment, or heat treatment.

[0062] <Backcoat layer> The above tape may or may not have a back coat layer containing non-magnetic powder on the surface side opposite to the surface side having the magnetic layer of the non-magnetic support. Preferably, the back coat layer contains either or both carbon black and inorganic powder. The back coat layer may contain a binder and may also contain additives. For details regarding the non-magnetic powder, binder, additives, etc. of the back coat layer, known technology relating to back coat layers may be applied, as may known technology relating to magnetic layers and / or non-magnetic layers. For example, paragraphs 0018 to 0020 of Japanese Patent Application Publication No. 2006-331625 and lines 65 to 38 of column 5 of U.S. Patent No. 7,029,774 can be referenced regarding the back coat layer.

[0063] <Various thicknesses> Regarding the thickness (total thickness) of magnetic tape, with the enormous increase in the amount of information in recent years, there is a demand for increased recording capacity (higher capacity) in magnetic recording media. For tape-shaped magnetic recording media (i.e., magnetic tape), means of increasing capacity include reducing the thickness of the magnetic tape and increasing the length of magnetic tape that can be stored in one reel of magnetic tape cartridge. From this point of view, the thickness (total thickness) of the magnetic tape is preferably 5.6 μm or less, more preferably 5.5 μm or less, even more preferably 5.4 μm or less, even more preferably 5.3 μm or less, even more preferably 5.2 μm or less, even more preferably 5.0 μm or less, and even more preferably 4.8 μm or less. Furthermore, from the viewpoint of ease of handling, the thickness of the magnetic tape is preferably 3.0 μm or more, more preferably 3.5 μm or more, and even more preferably 4.0 μm or more.

[0064] The thickness (total thickness) of a magnetic tape can be measured by the following method. Ten samples (e.g., 5-10 cm in length) are cut from any section of the magnetic tape, and the thickness of these samples is measured by stacking them. The measured thickness is divided by ten to obtain the value obtained (thickness per sample), which is taken as the total thickness. The above thickness measurement can be performed using a known measuring instrument capable of measuring thickness to the order of 0.1 μm.

[0065] The thickness of the non-magnetic support is preferably 3.0 to 5.0 μm. The thickness of the magnetic layer can be optimized according to the saturation magnetization of the magnetic head used, the head gap length, the bandwidth of the recording signal, etc., and is generally 0.01 μm to 0.15 μm, preferably 0.02 μm to 0.12 μm, and more preferably 0.03 μm to 0.1 μm from the viewpoint of high-density recording. At least one magnetic layer is sufficient, and the magnetic layer may be separated into two or more layers having different magnetic properties, and known configurations for multilayer magnetic layers can be applied. When separated into two or more layers, the thickness of the magnetic layer is the total thickness of these layers. The thickness of the non-magnetic layer is, for example, 0.1 to 1.5 μm, preferably 0.1 to 1.0 μm, and more preferably 0.1 to 0.7 μm. The thickness of the backcoat layer is preferably 0.9 μm or less, and more preferably 0.1 to 0.7 μm. Various thicknesses, such as the thickness of the magnetic layer, can be determined by the following method. After exposing the cross-section of the magnetic tape in the thickness direction using an ion beam, the exposed cross-section is observed using a scanning electron microscope or a transmission electron microscope. Various thicknesses can be determined as the arithmetic mean of the thicknesses obtained at any two locations during the cross-sectional observation. Alternatively, various thicknesses can be determined as design thicknesses calculated from manufacturing conditions, etc.

[0066] <Manufacturing process> (Preparation of compositions for each layer) A composition for forming a magnetic layer, a non-magnetic layer, or a backcoat layer typically contains a solvent along with the various components described above. As the solvent, one or more of the solvents commonly used in the manufacture of coated magnetic recording media can be used. The solvent content of each layer-forming composition is not particularly limited. For solvents, refer to paragraph 0153 of Japanese Patent Application Publication No. 2011-216149. The solid content concentration and solvent composition of each layer-forming composition may be appropriately adjusted in accordance with the handling suitability of the composition, the coating conditions, and the thickness of each layer to be formed. The process of preparing a composition for forming a magnetic layer, a non-magnetic layer, or a backcoat layer typically includes at least a kneading step, a dispersion step, and mixing steps provided before or after these steps as needed. Each individual step may be divided into two or more stages. The various components used in the preparation of each layer-forming composition may be added at the beginning or in the middle of any of the steps. Alternatively, individual components may be added in two or more separate steps. For example, a binder may be added in separate steps: a kneading step, a dispersion step, and a mixing step for viscosity adjustment after dispersion. In the manufacturing process of the magnetic tape described above, conventional known manufacturing techniques can be used as some of the steps. In the kneading step, kneaders with strong kneading force, such as open kneaders, continuous kneaders, pressure kneaders, and extruders, can be used. Details of the kneading step are described in Japanese Patent Publication No. 1-106338 and Japanese Patent Publication No. 1-79274. As the disperser, various known dispersers that utilize shear force, such as bead mills, ball mills, sand mills, or homomixers, can be used. Dispersion beads can preferably be used for dispersion. Examples of dispersion beads include ceramic beads and glass beads, with zirconia beads being preferred. Two or more types of beads may be used in combination. The bead diameter (particle size) and bead packing rate of the dispersion beads are not particularly limited and should be set according to the powder to be dispersed. Each layer-forming composition may be filtered by a known method before being subjected to the coating step. Filtration can be performed, for example, by filter filtration. As the filter used for filtration, for example, a filter with a pore size of 0.01 to 3 μm (e.g., a glass fiber filter, a polypropylene filter, etc.) can be used.

[0067] (Coating process, cooling process, heat drying process) The magnetic layer can be formed by directly applying the magnetic layer-forming composition onto a non-magnetic support, or by sequentially or simultaneously applying it in layers with the non-magnetic layer-forming composition. For details on the application for each layer formation, refer to paragraph 0066 of Japanese Patent Application Publication No. 2010-231843.

[0068] As described above, in one embodiment, the magnetic tape may have a non-magnetic layer between a non-magnetic support and a magnetic layer. Such a magnetic tape can preferably be manufactured by sequential layer coating. The manufacturing process for sequential layer coating can preferably be carried out as follows: The non-magnetic layer is formed by a coating step of forming a coated layer by applying a non-magnetic layer-forming composition onto a non-magnetic support, and a heat drying step of drying the formed coated layer by heat treatment. Then, the magnetic layer is formed by a coating step of forming a coated layer by applying a magnetic layer-forming composition onto the formed non-magnetic layer, and a heat drying step of drying the formed coated layer by heat treatment.

[0069] In the non-magnetic layer formation step of such a manufacturing method that involves sequential layer coating, the inventors believe that it is preferable to perform a coating step using a non-magnetic layer forming composition to form a coated layer, and to perform a cooling step to cool the coated layer between the coating step and the heating and drying step, in order to reduce the value of the substrate friction in the width direction σ.

[0070] The following describes an example of the manufacturing process for the magnetic tape described above, based on Figure 8. However, the present invention is not limited to the example below.

[0071] Figure 8 is a schematic diagram showing an example of a process for manufacturing a magnetic tape having a non-magnetic layer and a magnetic layer in that order on one side of a non-magnetic support, and a back coat layer on the other side. In the example shown in Figure 8, the non-magnetic support (long film) is continuously wound from a feed-out section to a feed-back section, and various processes such as coating, drying, and orientation are performed in each section or zone shown in Figure 8. This allows for the sequential layering of the non-magnetic and magnetic layers on one side of the moving non-magnetic support, and the formation of a back coat layer on the other side. The example shown in Figure 8 can be carried out in the same way as the manufacturing process normally performed for the manufacture of coated magnetic recording media, except that it includes a cooling zone.

[0072] On the non-magnetic support fed from the dispensing unit, a non-magnetic layer-forming composition is applied in the first coating unit (coating step of non-magnetic layer-forming composition).

[0073] After the above coating step, the coated layer of the non-magnetic layer-forming composition formed in the coating step is cooled in a cooling zone (cooling step). For example, the cooling step can be performed by passing the non-magnetic support on which the above-mentioned coated layer is formed through a cooling atmosphere. The ambient temperature of the cooling atmosphere can preferably be in the range of -10°C to 0°C, and more preferably in the range of -5°C to 0°C. The time for performing the cooling step (for example, the time from when any part of the coated layer is brought into the cooling zone until it is brought out (hereinafter also referred to as "residence time")) is not particularly limited. The longer the residence time, the smaller the value of the substrate friction in the width direction σ tends to be. In the cooling step, cooled gas may be blown onto the surface of the coated layer.

[0074] After the cooling zone, in the first heat treatment zone, the coated layer is dried by heating it after the cooling process (heat drying process). The heat drying process can be carried out by passing the nonmagnetic support having the coated layer after the cooling process through a heated atmosphere. The ambient temperature of the heated atmosphere here, as well as the ambient temperature of the heated atmosphere in the heat drying process in the second heat treatment zone and the heat drying process in the third heat treatment zone described later, are also called the "drying temperature". Increasing the drying temperature in each heat treatment zone can contribute to reducing the value of the widthwise σ of the substrate friction. From this point of view, the drying temperature in each heat treatment zone is preferably 95°C or higher, and more preferably 100°C or higher. In addition, the drying temperature in each heat treatment zone can be, for example, 140°C or lower or 130°C or lower, and can be higher than the temperatures listed here. Furthermore, heated gas may be optionally blown onto the surface of the coated layer.

[0075] Next, in the second coating section, a magnetic layer-forming composition is applied to the non-magnetic layer formed by the heat drying process in the first heat treatment zone (application process of magnetic layer-forming composition).

[0076] Subsequently, in the configuration in which orientation processing is performed, the orientation processing of the ferromagnetic powder in the coated layer of the magnetic layer-forming composition is carried out in the orientation zone while the coated layer is still wet. Various known techniques, including those described in paragraph 0067 of Japanese Patent Application Publication No. 2010-231843, can be applied to the orientation processing. For example, vertical orientation processing can be performed by known methods such as using opposite-polarity opposing magnets. In the orientation zone, the drying rate of the coated layer can be controlled by the temperature and airflow of the drying air and / or the transport speed of the magnetic tape in the orientation zone. Alternatively, the coated layer may be pre-dried before being transported to the orientation zone.

[0077] The coated layer, after orientation treatment, is subjected to a heat drying process in a second heat treatment zone.

[0078] Next, in the third coating section, the back coat layer forming composition is applied to the surface of the non-magnetic support opposite to the surface on which the non-magnetic and magnetic layers are formed, thereby forming a coating layer (coating step of back coat layer forming composition). After that, the coating layer is heat-treated and dried in the third heat treatment zone.

[0079] Through the above process, a magnetic tape can be obtained having a non-magnetic layer and a magnetic layer in that order on one side of a non-magnetic support, and a back coat layer on the other side.

[0080] (Other processes) In the manufacturing process of magnetic tape, calendering is usually performed to improve the surface smoothness of the magnetic tape. Strengthening the calendering conditions can contribute to reducing the value of the widthwise friction σ of the substrate. Specific examples of strengthening the calendering conditions include increasing the calendering pressure, increasing the calendering temperature, and decreasing the calendering speed. Regarding the calendering conditions, the calendering pressure (linear pressure) is preferably 300 to 500 kN / m, more preferably 310 to 350 kN / m, the calendering temperature (surface temperature of the calendering roll) is preferably 95 to 120°C, more preferably 100 to 120°C, and the calendering speed is preferably 50 to 75 m / min. For other processes for manufacturing magnetic tape, refer to paragraphs 0067 to 0070 of Japanese Patent Publication No. 2010-231843. Through various processes, a long roll of magnetic tape raw material can be obtained. The obtained magnetic tape raw material is then cut (slit) using a known cutting machine to the width of a magnetic tape to be housed in a magnetic tape cartridge, for example. The above width can be determined according to standards and is usually 1 / 2 inch. 1 inch = 2.54 cm. A servo pattern is typically formed on the magnetic tape obtained by slitting.

[0081] Varnish treatment For example, a burnish treatment can be applied to the surface of the magnetic layer after calendering. Burnish treatment is a process of rubbing the surface of the object to be treated with a material (e.g., abrasive tape, or a grinding tool such as a grinding blade or grinding wheel). Burnish treatment can preferably be carried out by rubbing (polishing) the surface of the coated layer of the object to be treated with abrasive tape, or by rubbing (grinding) the surface of the coated layer of the object to be treated with a grinding tool, or both. As the abrasive tape, a commercially available product may be used, or an abrasive tape manufactured by a known method may be used. As the grinding tool, a known grinding blade such as a fixed blade, a diamond wheel, or a rotary blade, or a grinding wheel may be used. In addition, a wiping treatment may be performed in which the surface of the coated layer rubbed with the abrasive tape and / or grinding tool is wiped with a wiping material. For details on preferred polishing tapes, grinding tools, burnishing treatment, and wiping treatment, refer to paragraphs 0034 to 0048, Figure 1, and the embodiments of Japanese Patent Publication No. 6-52544. Examples of burnishing treatment conditions include the tension applied in the longitudinal direction of the magnetic tape during burnishing (hereinafter referred to as "burnishing tension"). The larger the burnishing tension, the smaller the widthwise σ of the substrate friction tends to be. From the viewpoint of controlling the widthwise σ of the substrate friction within the above range, it is preferable that the burnishing tension in the burnishing treatment of the magnetic layer surface be between 200 gf and 400 gf. Regarding units, "gf" indicates gram-force, and 1 N (Newton) is approximately 102 gf.

[0082] (Formation of servo patterns) "Forming a servo pattern" can also be described as "recording a servo signal." The formation of a servo pattern is explained below.

[0083] Servo patterns are typically formed along the longitudinal direction of the magnetic tape. Examples of control methods that utilize servo signals (servo control) include timing-based servo (TBS), amplitude servo, and frequency servo.

[0084] As indicated in ECMA (European Computer Manufacturers Association) - 319 (June 2001), magnetic tapes conforming to the LTO (Linear Tape-Open) standard (commonly referred to as "LTO tapes") employ a timing-based servo system. In this timing-based servo system, the servo pattern is composed of multiple pairs of non-parallel magnetic stripes (also called "servo stripes") arranged continuously along the longitudinal direction of the magnetic tape. In this invention and specification, "timing-based servo pattern" refers to a servo pattern that enables head tracking in a timing-based servo system. The reason the servo pattern is composed of pairs of non-parallel magnetic stripes, as described above, is to inform the servo signal reading element of its position as it passes over the servo pattern. Specifically, the pair of magnetic stripes described above are formed such that their spacing changes continuously along the width direction of the magnetic tape, and the servo signal reading element can determine the relative position between the servo pattern and the servo signal reading element by reading this spacing. This relative position information enables tracking of the data track. Therefore, multiple servo tracks are typically set up on the servo pattern, aligned with the width of the magnetic tape.

[0085] A servo band consists of a servo pattern that runs continuously along the longitudinal direction of the magnetic tape. Typically, multiple servo bands are provided on a magnetic tape. For example, in an LTO tape, there are five. The area between two adjacent servo bands is the data band. A data band consists of multiple data tracks, each corresponding to a servo track.

[0086] In one embodiment, as shown in Japanese Patent Publication No. 2004-318983, each servo band has embedded information indicating the servo band number (also called "servo band ID (identification)" or "UDIM (Unique DataBand Identification Method) information"). This servo band ID is recorded by shifting a specific pair of servo stripes within a servo band so that its position is displaced relative to the longitudinal direction of the magnetic tape. Specifically, the method of shifting a specific pair of servo stripes is changed for each servo band. As a result, the recorded servo band ID is unique for each servo band, so that a servo band can be uniquely identified by reading it with a servo signal reading element.

[0087] Furthermore, one method for uniquely identifying a servo band is the staggered method, as described in ECMA-319 (June 2001). In this staggered method, a group of non-parallel magnetic stripes (servo stripes) arranged continuously along the longitudinal direction of the magnetic tape are recorded in a way that they are shifted along the longitudinal direction of the magnetic tape for each servo band. Since the combination of this shift between adjacent servo bands is unique across the entire magnetic tape, it is possible to uniquely identify a servo band when reading the servo pattern with two servo signal reading elements.

[0088] Furthermore, each servo band typically contains embedded information indicating its position along the longitudinal direction of the magnetic tape (also known as "LPOS (Longitudinal Position) information"), as described in ECMA-319 (June 2001). This LPOS information, like the UDIM information, is recorded by shifting the positions of a pair of servo stripes along the longitudinal direction of the magnetic tape. However, unlike the UDIM information, the same signal is recorded for each servo band in this LPOS information.

[0089] It is also possible to embed information other than the UDIM and LPOS information mentioned above into the servo bands. In this case, the embedded information may be different for each servo band, like the UDIM information, or it may be common to all servo bands, like the LPOS information. Furthermore, methods other than those described above can be used to embed information in the servo bands. For example, a predetermined code may be recorded by thinning out a predetermined pair from a group of servo stripes.

[0090] A servo pattern forming head is called a servo light head. A servo light head typically has a pair of gaps corresponding to the pair of magnetic stripes mentioned above, for each servo band. Typically, a core and a coil are connected to each pair of gaps, and by supplying current pulses to the coils, the magnetic field generated in the core can create a leakage magnetic field in the pair of gaps. When forming a servo pattern, by inputting current pulses while running a magnetic tape over the servo light head, the magnetic patterns corresponding to the pair of gaps are transferred to the magnetic tape, thereby forming the servo pattern. The width of each gap can be appropriately set according to the density of the servo pattern to be formed. For example, the width of each gap can be set to 1 μm or less, 1 to 10 μm, 10 μm or more, etc.

[0091] Before forming a servo pattern on a magnetic tape, it is usually demagnetized (erased). This erasing process can be performed by applying a uniform magnetic field to the magnetic tape using a DC or AC magnet. There are two types of erasing: DC (Direct Current) erasing and AC (Alternating Current) erasing. AC erasing is performed by gradually reducing the strength of the magnetic field while reversing the direction of the magnetic field applied to the magnetic tape. On the other hand, DC erasing is performed by applying a unidirectional magnetic field to the magnetic tape. There are two further methods of DC erasing. The first method is horizontal DC erasing, which applies a unidirectional magnetic field along the longitudinal direction of the magnetic tape. The second method is vertical DC erasing, which applies a unidirectional magnetic field along the thickness direction of the magnetic tape. The erasing process may be performed on the entire magnetic tape or on each servo band of the magnetic tape.

[0092] The direction of the magnetic field of the formed servo pattern is determined according to the direction of the erase. For example, when a magnetic tape is horizontally DC erased, the servo pattern is formed such that the direction of the magnetic field is opposite to the direction of the erase. This makes it possible to increase the output of the servo signal obtained by reading the servo pattern. As shown in Japanese Patent Application Publication No. 2012-53940, when a magnetic pattern using the above gap is transferred to a vertically DC erased magnetic tape, the servo signal obtained by reading the formed servo pattern is in the shape of a single-pole pulse. On the other hand, when a magnetic pattern using the above gap is transferred to a horizontally DC erased magnetic tape, the servo signal obtained by reading the formed servo pattern is in the shape of a double-pole pulse.

[0093] <Vertical squareness ratio> In one embodiment, the vertical aspect ratio of the magnetic tape can be, for example, 0.55 or more, preferably 0.60 or more, and more preferably 0.65 or more, from the viewpoint of improving electromagnetic conversion characteristics. The upper limit of the aspect ratio is, in principle, 1.00 or less. The vertical aspect ratio of the magnetic tape can be 1.00 or less, and can be 0.95 or less, 0.90 or less, 0.85 or less, or 0.80 or less. A large value for the vertical aspect ratio of the magnetic tape is preferable from the viewpoint of improving electromagnetic conversion characteristics. The vertical aspect ratio of the magnetic tape can be controlled by known methods such as performing a vertical orientation process.

[0094] In the present invention and this specification, "vertical angle ratio" refers to the angle ratio measured in the vertical direction of the magnetic tape. In relation to the angle ratio, "vertical direction" refers to the direction perpendicular to the surface of the magnetic layer, and can also be referred to as the thickness direction. In the present invention and this specification, the vertical angle ratio is determined by the following method. A sample piece of a size suitable for introduction into a vibrating magnetometer is cut from the magnetic tape to be measured. Using a vibrating magnetometer, a magnetic field is applied to this sample piece perpendicular to the sample piece (in the direction perpendicular to the magnetic layer surface) at a maximum applied magnetic field of 3979 kA / m, a measurement temperature of 296 K, and a magnetic field sweep speed of 8.3 kA / m / sec, and the magnetization intensity of the sample piece against the applied magnetic field is measured. The measured magnetization intensity is obtained as a value after demagnetization correction and after subtracting the magnetization of the sample probe of the vibrating magnetometer as background noise. When the magnetization intensity at the maximum applied magnetic field is Ms and the magnetization intensity at zero applied magnetic field is Mr, the squareness ratio SQ is calculated as SQ = Mr / Ms. The measurement temperature refers to the temperature of the sample piece, and the temperature of the sample piece can be set to the measurement temperature by setting the ambient temperature around the sample piece to the measurement temperature, thereby achieving thermal equilibrium.

[0095] [Magnetic tape cartridge] One aspect of the present invention relates to a magnetic tape cartridge including the magnetic tape described above.

[0096] Details of the magnetic tape included in the above magnetic tape cartridge are as previously described. The above magnetic tape cartridge can be mounted in a magnetic tape device equipped with a magnetic head and used for recording and / or playing back data.

[0097] In a magnetic tape cartridge, the magnetic tape is generally housed inside the cartridge body, wound onto a reel. The reel is rotatably mounted inside the cartridge body. Two types of magnetic tape cartridges are widely used: single-reel cartridges, which have one reel inside the cartridge body, and double-reel cartridges, which have two reels inside the cartridge body. When a single-reel magnetic tape cartridge is mounted in a magnetic tape device for recording and / or playing back data onto magnetic tape, the magnetic tape is pulled out of the cartridge and wound onto the reel on the magnetic tape device. A magnetic head is positioned in the magnetic tape transport path from the magnetic tape cartridge to the take-up reel. The magnetic tape is fed and wound between the reel on the magnetic tape cartridge side (supply reel) and the reel on the magnetic tape device side (take-up reel). For example, during this process, the magnetic head and the magnetic layer surface of the magnetic tape come into contact and slide against each other, enabling data recording and / or playback. In contrast, a dual-reel magnetic tape cartridge has both a supply reel and a take-up reel located inside the magnetic tape cartridge.

[0098] The above-described magnetic tape cartridge may, in one embodiment, include a cartridge memory. The cartridge memory may be, for example, a non-volatile memory, and in one embodiment, head tilt angle adjustment information may already be recorded or will be recorded. The head tilt angle adjustment information is information for adjusting the head tilt angle while the magnetic tape is running within the magnetic tape device. For example, the head tilt angle adjustment information may include the values ​​of the servoband interval at each position in the longitudinal direction of the magnetic tape during data recording. For example, when playing back data recorded on the magnetic tape, the value of the servoband interval is measured during playback, and the control device of the magnetic tape device can change the head tilt angle so that the absolute value of the difference between this value and the servoband interval recorded in the cartridge memory at the same longitudinal position during recording approaches 0. The head tilt angle may be, for example, the angle θ described above.

[0099] The magnetic tape and magnetic tape cartridge described above can be suitably used in a magnetic tape device (in other words, a magnetic recording and playback system) that records and / or plays back data at different head tilt angles. In one embodiment, such a magnetic tape device can record and / or play back data by changing the head tilt angle while the magnetic tape is running. For example, the head tilt angle can be changed according to the widthwise dimensional information of the magnetic tape acquired while the magnetic tape is running. Alternatively, for example, the head tilt angle for one recording and / or playback cycle may be changed from the head tilt angle for subsequent recordings and / or playback cycles, and the head tilt angle may be fixed without changing it during the magnetic tape running for each recording and / or playback cycle.

[0100] [Magnetic tape drive] One aspect of the present invention relates to a magnetic tape device including the magnetic tape described above. In the magnetic tape device, recording data onto the magnetic tape and / or reproducing data recorded on the magnetic tape can be performed, for example, by bringing the magnetic layer surface of the magnetic tape into contact with and sliding a magnetic head.

[0101] In one configuration, the magnetic tape is treated as a removable medium (a so-called interchangeable medium), and a magnetic tape cartridge containing the magnetic tape is inserted into and removed from a magnetic tape device. In another configuration, the magnetic tape is not treated as an interchangeable medium, and the magnetic tape is wound onto a reel of a magnetic tape device equipped with a magnetic head, and the magnetic tape is housed within the magnetic tape device.

[0102] In the present invention and in this specification, “magnetic tape device” means a device capable of recording data onto a magnetic tape and playing back data recorded on a magnetic tape. Such a device is generally called a drive.

[0103] <Magnetic head> The above magnetic tape device may include a magnetic head. The configuration of the magnetic head and the angle θ, which is the head tilt angle, are as previously explained with reference to Figures 5 to 7. If the magnetic head includes a playback element, a magnetoresistive (MR) element that can read information recorded on the magnetic tape with high sensitivity is preferred as the playback element. Various known MR elements (e.g., GMR (Giant Magnetoresistive) elements, TMR (Tunnel Magnetoresistive) elements, etc.) can be used as the MR element. Hereinafter, the magnetic head that records data and / or plays back recorded data will also be referred to as the "recording / playback head". The elements for recording data (recording elements) and the elements for playing back data (playback elements) will be collectively referred to as "magnetic head elements".

[0104] When recording data and / or playing back recorded data, tracking using servo signals can be performed first. That is, by making the servo signal reading element follow a predetermined servo track, the magnetic head element can be controlled to pass over the target data track. The movement of the data track is achieved by changing the servo track read by the servo signal reading element in the tape width direction. Furthermore, the recording / playback head can also record and / or play back data on other data bands. In this case, the servo signal reading element can be moved to a predetermined servo band using the UDIM information described earlier, and tracking for that servo band can be started.

[0105] Figure 9 shows an example of the arrangement of data bands and servo bands. In Figure 9, multiple servo bands 1 are arranged on the magnetic layer of the magnetic tape MT, sandwiched between guide bands 3. Multiple regions 2 sandwiched between two servo bands are the data bands. A servo pattern is a magnetized region, formed by magnetizing a specific region of the magnetic layer with a servo light head. The region magnetized by the servo light head (the position where the servo pattern is formed) is defined by the standard. For example, in the industry standard LTO Ultrium format tape, multiple servo patterns inclined with respect to the tape width direction are formed on the servo bands during magnetic tape manufacturing, as shown in Figure 10. More specifically, in Figure 10, the servo frame SF on the servo band 1 consists of a servo subframe 1 (SSF1) and a servo subframe 2 (SSF2). The servo subframe 1 consists of an A-burst (indicated as A in Figure 10) and a B-burst (indicated as B in Figure 10). The A-burst consists of servo patterns A1 to A5, and the B-burst consists of servo patterns B1 to B5. On the other hand, servo subframe 2 consists of C-bursts (indicated as C in Figure 10) and D-bursts (indicated as D in Figure 10). C-bursts consist of servo patterns C1 to C4, and D-bursts consist of servo patterns D1 to D4. These 18 servo patterns are arranged in sets of 5 and 4 on subframes in a 5, 5, 4, 4 sequence, and are used to identify the servo frames. Figure 10 shows one servo frame for illustrative purposes. However, in reality, in the magnetic layer of a magnetic tape where timing-based servo head tracking is performed, multiple servo frames are arranged in the direction of travel for each servo band. In Figure 10, the arrows indicate the direction of travel of the magnetic tape. For example, LTO Ultrium format tape typically has more than 5000 servo frames per meter of tape length in each servo band of the magnetic layer.

[0106] In one embodiment, the head tilt angle can be changed while the magnetic tape is running within the magnetic tape device. The head tilt angle is, for example, the angle θ that the axis of the element array makes with respect to the width direction of the magnetic tape. The angle θ is as previously described. For example, by providing an angle adjustment unit in the recording / playback head unit of the magnetic head to adjust the angle of the magnetic head module, the angle θ can be variably adjusted while the magnetic tape is running. Such an angle adjustment unit may include, for example, a rotation mechanism for rotating the module. Known technologies can be applied to the angle adjustment unit.

[0107] Regarding the head tilt angle during magnetic tape travel, if the magnetic head contains multiple modules, the angle θ can be defined for a randomly selected module, as explained with reference to Figures 5 to 7. The angle θ at the start of magnetic tape travel is θ. initial It can be set to 0° or greater than or equal to 0°. initial The larger the angle θ, the greater the change in the effective distance between servo signal reading elements in response to the change in angle θ. This is preferable from the standpoint of adjustment capability to adjust the effective distance between servo signal reading elements in response to changes in the width direction of the magnetic tape. initial The angle is preferably 1° or more, more preferably 5° or more, and even more preferably 10° or more. On the other hand, regarding the angle formed between the magnetic layer surface and the contact surface of the magnetic head when the magnetic tape is running and contacts the magnetic head (generally called the "lap angle"), keeping the deviation in the tape width direction small is effective in improving the uniformity of friction in the tape width direction caused by contact between the magnetic head and the magnetic tape during magnetic tape running. Furthermore, improving the uniformity of the friction in the tape width direction is desirable from the viewpoint of the magnetic head's position tracking ability and running stability. From the viewpoint of reducing the deviation of the lap angle in the tape width direction, θ initial The angle is preferably 45° or less, more preferably 40° or less, and even more preferably 35° or less.

[0108] Regarding the change in angle θ during magnetic tape movement, for recording data onto magnetic tape and / or for playing back data recorded on magnetic tape, the angle θ of the magnetic head remains constant from the initial angle θ while the magnetic tape is moving in the magnetic tape drive. initial When it changes from, the maximum change in angle θ during magnetic tape travel, Δθ, is calculated by the following formula: max and Δθ min Among these, it is the larger value. The maximum value of the angle θ during magnetic tape travel is θ max The minimum value is θ. min That is the case. Note that "max" is an abbreviation for maximum, and "min" is an abbreviation for minimum. Δθ max =θ max -θ initial Δθ min =θ initial -θ min

[0109] In one embodiment, Δθ can be greater than 0.000°, and from the viewpoint of adjustment capability to adjust the effective distance between servo signal reading elements in response to changes in the width direction of the magnetic tape, it is preferably 0.001° or more, and more preferably 0.010° ​​or more. Furthermore, from the viewpoint of ease of ensuring synchronization of recorded data and / or playback data between multiple magnetic head elements during data recording and / or playback, Δθ is preferably 1.000° or less, more preferably 0.900° or less, even more preferably 0.800° or less, even more preferably 0.700° or less, and even more preferably 0.600° or less.

[0110] In the examples shown in Figures 6 and 7, the axis of the element array is tilted toward the direction of magnetic tape travel. However, the present invention is not limited to such examples. Embodiments in which the axis of the element array is tilted toward the direction opposite to the direction of magnetic tape travel are also included in the present invention.

[0111] θ is the head tilt angle at the start of magnetic tape playback. initialThis can be set by the control device of the magnetic tape drive, etc. Regarding the head tilt angle during magnetic tape travel, Figure 11 is an explanatory diagram of the method for measuring the angle θ during magnetic tape travel. The angle θ during magnetic tape travel can be determined, for example, by the following method. When determining the angle θ during magnetic tape travel by the following method, the angle θ is to be varied within the range of 0 to 90° during magnetic tape travel. That is, if the axis of the element array is tilted toward the direction of magnetic tape travel at the start of magnetic tape travel, the element array will not be tilted during magnetic tape travel so that the axis of the element array is tilted toward the direction of magnetic tape travel at the start of magnetic tape travel, and if the axis of the element array is tilted toward the direction of magnetic tape travel at the start of magnetic tape travel, the element array will not be tilted during magnetic tape travel so that the axis of the element array is tilted toward the direction of magnetic tape travel at the start of magnetic tape travel. The phase difference (i.e., time difference) ΔT of the regenerated signals from a pair of servo signal reading elements 1 and 2 is measured. ΔT can be measured by a measurement unit provided in the magnetic tape device. The configuration of such a measurement unit is well known. The distance L between the center of servo signal reading element 1 and the center of servo signal reading element 2 can be measured using an optical microscope or the like. When the magnetic tape travels at speed v, the distance between the centers of the two servo signal reading elements in the direction of magnetic tape travel is Lsinθ, and the relationship Lsinθ = v × ΔT holds. Therefore, the angle θ during magnetic tape travel can be calculated using the formula "θ = arcsin(vΔT / L)". Note that Figure 11 (right) shows an example where the axis of the element array is tilted toward the direction of magnetic tape travel. In this example, the phase difference (i.e., time difference) ΔT between the phase of the regenerated signal from servo signal reading element 1 and the phase of the regenerated signal from servo signal reading element 2 is measured. If the axis of the element array is tilted in the direction opposite to the direction in which the magnetic tape travels, θ can be determined by the above method, except that ΔT is measured as the phase difference (i.e., time difference) between the phase of the regenerated signal of servo signal reading element 1 and the phase of the regenerated signal of servo signal reading element 2. Furthermore, the measurement pitch for the angle θ, that is, the measurement interval for the angle θ in the longitudinal direction of the tape, can be selected according to the frequency of tape width deformation in the longitudinal direction of the tape. For example, the measurement pitch can be set to, for example, 250 μm.

[0112] <Configuration of a magnetic tape drive> The magnetic tape device 10 shown in Figure 12 controls the recording and playback head unit 12 by command from the control device 11 to record and play back data on the magnetic tape MT. The magnetic tape device 10 has a configuration that allows for the detection and adjustment of tension applied in the longitudinal direction of the magnetic tape from spindle motors 17A, 17B and their drive units 18A, 18B that control the rotation of the magnetic tape cartridge reel and the take-up reel. The magnetic tape device 10 has a configuration that allows for the loading of a magnetic tape cartridge 13. The magnetic tape device 10 has a cartridge memory read / write device 14 that can read from and write to the cartridge memory 131 in the magnetic tape cartridge 13. From the magnetic tape cartridge 13 mounted in the magnetic tape device 10, the end of the magnetic tape MT or the leader pin is pulled out by an automatic loading mechanism or manually, and the magnetic layer surface of the magnetic tape MT passes over the recording / playback head of the recording / playback head unit 12 through guide rollers 15A and 15B with the magnetic layer surface of the magnetic tape MT in contact with the surface of the recording / playback head, and the magnetic tape MT is wound onto the take-up reel 16. The rotation and torque of spindle motors 17A and 17B are controlled by signals from the control device 11, so that the magnetic tape MT runs at a desired speed and tension. A servo pattern pre-formed on the magnetic tape can be used to control the tape speed and head tilt angle. A tension detection mechanism may be provided between the magnetic tape cartridge 13 and the take-up reel 16 for tension detection. In addition to control by spindle motors 17A and 17B, tension may also be controlled using guide rollers 15A and 15B. The cartridge memory read / write device 14 is configured to read and write information to the cartridge memory 131 in response to commands from the control device 11. For example, the ISO (International Organization for Standardization) 14443 standard can be used as the communication method between the cartridge memory read / write device 14 and the cartridge memory 131.

[0113] The control device 11 includes, for example, a control unit, a storage unit, a communication unit, and the like.

[0114] The recording / playback head unit 12 consists of, for example, a recording / playback head, a servo tracking actuator for adjusting the position of the recording / playback head in the track width direction, a recording / playback amplifier 19, and a connector cable for connecting to the control device 11. The recording / playback head consists of, for example, a recording element for recording data on magnetic tape, a playback element for reproducing data on magnetic tape, and a servo signal reading element for reading servo signals recorded on magnetic tape. Within a single magnetic head, for example, one or more recording elements, playback elements, and servo signal reading elements are mounted. Alternatively, each element may be separately contained in multiple magnetic heads corresponding to the direction in which the magnetic tape travels.

[0115] The recording / playback head unit 12 is configured to record data onto the magnetic tape MT in response to commands from the control device 11. It is also configured to play back data recorded on the magnetic tape MT in response to commands from the control device 11.

[0116] The control device 11 has a mechanism to determine the running position of the magnetic tape MT from the servo signals read from the servo bands when the magnetic tape MT is running, and to control the servo tracking actuator so that the recording element and / or playback element are positioned at the target running position (track position). This track position control is performed, for example, by feedback control. The control device 11 has a mechanism to determine the servo band spacing from the servo signals read from two adjacent servo bands when the magnetic tape MT is running. The control device 11 can store the determined servo band spacing information in its internal storage unit, cartridge memory 131, or external connected equipment. Furthermore, the control device 11 can change the head tilt angle according to the dimensional information in the width direction of the running magnetic tape. This makes it possible to bring the effective distance between servo signal reading elements close to or match the servo band spacing. The above dimensional information can be obtained using a servo pattern pre-formed on the magnetic tape. For example, while the magnetic tape is running within the magnetic tape device, the angle θ that the axis of the element array makes with respect to the width direction of the magnetic tape can be changed according to the width direction dimensional information of the magnetic tape acquired during the running process. The head tilt angle can be adjusted, for example, by feedback control. Alternatively, the head tilt angle can also be adjusted, for example, by the method described in Japanese Patent Application Publication No. 2016-524774 (Patent Document 1) or US2019 / 0164573A1 (Patent Document 2). [Examples]

[0117] The present invention will be described below based on examples. However, the present invention is not limited to the embodiments shown in the examples. In the following, "parts" and "%" refer to "parts by mass" and "mass%", respectively. Furthermore, unless otherwise specified, the processes and evaluations described below were carried out in an environment of 23°C ± 1°C. In the following, "eq" refers to equivalent and is a unit that cannot be converted to SI units.

[0118] [Ferromagnetic powder] In Table 1, "BaFe" refers to hexagonal barium ferrite powder (activation volume: see Table 1).

[0119] In Table 1, "SrFe1" is hexagonal strontium ferrite powder prepared by the following method. 1707g of SrCO3, 687g of H3BO3, 1120g of Fe2O3, 45g of Al(OH)3, 24g of BaCO3, 13g of CaCO3, and 235g of Nd2O3 were weighed out and mixed in a mixer to obtain a raw material mixture. The obtained raw material mixture was melted in a platinum crucible at a melting temperature of 1390°C. While stirring the molten material, the outlet at the bottom of the platinum crucible was heated, and the molten material was dispensed in a rod shape at approximately 6 g / second. The dispensed material was rolled and rapidly cooled using water-cooled twin rollers to produce an amorphous body. 280g of the prepared amorphous material was placed in an electric furnace and heated to 635°C (crystallization temperature) at a heating rate of 3.5°C / min. The temperature was maintained at this temperature for 5 hours to precipitate (crystallize) hexagonal strontium ferrite particles. Next, the crystalline material obtained above, containing hexagonal strontium ferrite particles, was coarsely ground in a mortar and pestle. This was then mixed with 1000g of 1mm particle size zirconia beads and 800ml of 1% aqueous acetic acid solution in a glass bottle and dispersed in a paint shaker for 3 hours. After that, the resulting dispersion was separated from the beads and placed in a stainless steel beaker. The dispersion was allowed to stand at a liquid temperature of 100°C for 3 hours to dissolve the glass components, then precipitated using a centrifuge and washed by repeated decantation. Finally, it was dried in a heating furnace at a furnace temperature of 110°C for 6 hours to obtain hexagonal strontium ferrite powder. The activation volume of the hexagonal strontium ferrite powder obtained above is shown in Table 1, and the anisotropy constant Ku is 2.2 × 10⁻⁶. 5 J / m 3 , mass magnetization σs is 49A m 2 It was / kg. A sample powder of 12 mg was taken from the hexagonal strontium ferrite powder obtained above, and the elemental analysis of the filtrate obtained by partially dissolving this sample powder under the dissolution conditions exemplified earlier was performed using an ICP analyzer to determine the surface layer content of neodymium atoms. Separately, 12 mg of sample powder was taken from the hexagonal strontium ferrite powder obtained above, and the elemental analysis of the filtrate obtained by completely dissolving this sample powder under the dissolution conditions exemplified earlier was performed using an ICP analyzer to determine the bulk content of neodymium atoms. The neodymium atom content (bulk content) relative to 100 atomic percent of iron atoms in the hexagonal strontium ferrite powder obtained above was 2.9 atomic percent. Furthermore, the neodymium atom content in the surface layer was 8.0 atomic percent. The ratio of surface layer content to bulk content, "surface layer content / bulk content," was 2.8, confirming that neodymium atoms were concentrated in the surface layer of the particles. The hexagonal ferrite crystal structure of the powder obtained above was confirmed by scanning with CuKα rays at a voltage of 45kV and intensity of 40mA, and measuring the X-ray diffraction pattern under the following conditions (X-ray diffraction analysis). The powder obtained above showed a magnetoplanbite-type (M-type) hexagonal ferrite crystal structure. Furthermore, the crystalline phase detected by X-ray diffraction analysis was a single phase of the magnetoplanbite type. PANalytical X'Pert Pro diffractometer, PIXcel detector Soller slit for incident and diffracted beams: 0.017 radians Fixed angle of dispersion slit: 1 / 4 degree Mask: 10mm Scatter prevention slit: 1 / 4 degree Measurement mode: Continuous Measurement time per step: 3 seconds Measurement speed: 0.017 degrees per second Measurement step: 0.05 degrees

[0120] In Table 1, "SrFe2" is hexagonal strontium ferrite powder prepared by the following method. 1725g of SrCO3, 666g of H3BO3, 1332g of Fe2O3, 52g of Al(OH)3, 34g of CaCO3, and 141g of BaCO3 were weighed out and mixed in a mixer to obtain a raw material mixture. The obtained raw material mixture was melted in a platinum crucible at a melting temperature of 1380°C. While stirring the molten material, the outlet at the bottom of the platinum crucible was heated, and the molten material was dispensed in a rod shape at a rate of approximately 6 g / second. The dispensed material was rolled and rapidly cooled using water-cooled twin rollers to produce an amorphous body. 280g of the obtained amorphous material was placed in an electric furnace, heated to 645°C (crystallization temperature), and held at the same temperature for 5 hours to precipitate (crystallize) hexagonal strontium ferrite particles. Next, the crystalline material obtained above, containing hexagonal strontium ferrite particles, was coarsely ground in a mortar and pestle. This was then mixed with 1000g of 1mm particle size zirconia beads and 800ml of 1% aqueous acetic acid solution in a glass bottle and dispersed in a paint shaker for 3 hours. After that, the resulting dispersion was separated from the beads and placed in a stainless steel beaker. The dispersion was allowed to stand at a liquid temperature of 100°C for 3 hours to dissolve the glass components, then precipitated using a centrifuge and washed by repeated decantation. Finally, it was dried in a heating furnace at a furnace temperature of 110°C for 6 hours to obtain hexagonal strontium ferrite powder. The activation volume of the obtained hexagonal strontium ferrite powder is shown in Table 1, and the anisotropy constant Ku is 2.0 × 10⁻⁶. 5 J / m 3 , mass magnetization σs is 50A m 2 It was / kg.

[0121] The activation volume and anisotropy constant Ku mentioned above were determined for each ferromagnetic powder using a vibrating sample magnetometer (manufactured by Toei Kogyo Co., Ltd.) and the method described above. Furthermore, the mass magnetization σs was measured using a vibrating sample type magnetometer (manufactured by Toei Kogyo Co., Ltd.) at a magnetic field strength of 15 kOe.

[0122] [Shape observation and measurement of average plate ratio of hexagonal ferrite powder] In the following, a Hitachi H-9000 transmission electron microscope was used, and Carl Zeiss KS-400 image analysis software was used to observe the shape of the particles and measure the diameter and thickness of the plates. One mg of each hexagonal ferrite powder (target powder) shown in Table 1 was added to 5 ml of pure water and dispersed using ultrasonic technology (28 kHz, 10 minutes) to prepare a dispersion. 5 μL of the prepared dispersion was dropped onto a grid mesh (mesh-shaped sample dish) and allowed to air dry to sample the target powder onto the grid mesh (no orientation treatment). The target powder, along with the grid mesh, was introduced into a transmission electron microscope, and particle images (hereinafter referred to as "particle image 1") were obtained by imaging with the transmission electron microscope. The shape of 500 randomly selected particles was then observed. One mg of each hexagonal ferrite powder (target powder) shown in Table 1 was added to 5 ml of pure water and dispersed using ultrasonic technology (28 kHz, 10 minutes) to prepare a dispersion. 5 μL of the prepared dispersion was dropped onto a grid mesh (mesh-shaped sample dish) with magnets (each magnet having a magnetic force of 1.5 T) placed on both sides (left and right), and air-dried to orient the target powder horizontally on the grid mesh. The target powder, along with the grid mesh, was introduced into a transmission electron microscope, and particle images (hereinafter referred to as "particle image 2") were obtained by imaging with the transmission electron microscope. The shape of 500 randomly selected particles was then observed. Based on the shape observations described above, it was confirmed that 90-100% (based on particle count) of the 500 randomly selected particles were plate-shaped. Using particle photograph 1 above, the plate diameter of each plate-like particle was determined, and the average plate diameter was calculated as the arithmetic mean of the determined plate diameters. Using particle photograph 2 above, the plate thickness of each plate-like particle was determined, and the average plate thickness was calculated as the arithmetic mean of the determined plate thicknesses. Using the calculated average plate diameter and average plate thickness, the average plate ratio was calculated for each hexagonal ferrite powder shown in Table 1 as "average plate diameter / average plate thickness".

[0123] [Example 1] (1) Formulation of a composition for forming a magnetic layer (Magnetic liquid) Ferromagnetic powder (see Table 1): 100.0 parts Use the ferromagnetic powders (1) and (2) listed in Table 1 at the formulation rates (by mass) listed in Table 1. SO3Na group-containing polyurethane resin: 14.0 parts Weight average molecular weight: 70,000, SO3Na group: 0.4meq / g Cyclohexanone: 150 copies Methyl ethyl ketone: 150 parts (Abrasive solution A) Alumina abrasive (average particle size: 100 nm): 3.0 parts Sulfonic acid group-containing polyurethane resin: 0.3 parts Weight average molecular weight: 70,000, SO3Na group: 0.3meq / g Cyclohexanone: 26.7 parts (Abrasive solution B) Diamond abrasive (average particle size: 100nm): 1.0 part Sulfonic acid group-containing polyurethane resin: 0.1 part Weight average molecular weight: 70,000, SO3Na group: 0.3meq / g Cyclohexanone: 26.7 parts (Silica sol) Colloidal silica (average particle size: 100 nm): 0.2 parts Methyl ethyl ketone: 1.4 parts (Other ingredients) Stearic acid: 2.0 parts Butyl stearate: 10.0 parts Polyisocyanate (Coronate, manufactured by Nippon Polyurethane Co., Ltd.): 2.5 parts Cyclohexanone: 200.0 parts Methyl ethyl ketone: 200.0 parts

[0124] (2) Formulation of composition for forming a non-magnetic layer Non-magnetic inorganic powder (α-iron oxide): 100.0 parts Average particle size (average major axis length): 10nm Average acicular ratio: 1.9 BET (Brunauer-Emmett-Teller) specific surface area: 75m 2 / g Carbon Black: 25.0 parts Average particle size: 20nm SO3Na group-containing polyurethane resin: 18.0 parts Weight average molecular weight: 70,000, SO3Na group: 0.2meq / g Stearic acid: 1.0 part Cyclohexanone: 300.0 parts Methyl ethyl ketone: 300.0 parts

[0125] (3) Formulation of composition for forming backcoat layer Carbon Black: 100.0 parts Cabot BP-800, average particle size: 17nm SO3Na group-containing polyurethane resin (SO3Na group: 70 eq / ton): 20.0 parts OSO3K group-containing polyvinyl chloride resin (OSO3K group: 70 eq / ton): 30.0 parts Cyclohexanone: 140.0 parts Methyl ethyl ketone: 170.0 parts Butyl stearate: 2.0 parts Stearic acid amide: 0.1 part

[0126] (4) Preparation of each layer-forming composition For the magnetic layer forming composition, the above components of the magnetic liquid were dispersed for 24 hours using a batch-type vertical sand mill to prepare the magnetic liquid. Zirconia beads with a diameter of 0.5 mm were used as the dispersion beads. For the abrasive solutions, the above components of abrasive solution A and abrasive solution B were dispersed for 24 hours using a batch-type ultrasonic device (20kHz, 300W) to obtain abrasive solution A and abrasive solution B. The magnetic liquid, abrasive solution A, and abrasive solution B were mixed with silica sol and other components, and then dispersed using a batch-type ultrasonic device (20 kHz, 300 W) for 30 minutes. The mixture was then filtered using a filter with a pore size of 0.5 μm to prepare a composition for forming a magnetic layer. For the composition for forming a non-magnetic layer, the above components were dispersed for 24 hours using a batch-type vertical sand mill. Zirconia beads with a diameter of 0.1 mm were used as the dispersion beads. The obtained dispersion was filtered using a filter with a pore size of 0.5 μm to prepare the composition for forming a non-magnetic layer. For the backcoat layer forming composition, the above components were kneaded in a continuous kneader and then dispersed using a sand mill. 40.0 parts of polyisocyanate (Coronate L, manufactured by Nippon Polyurethane Industry Co., Ltd.) and 1000.0 parts of methyl ethyl ketone were added to the resulting dispersion, and the mixture was filtered using a filter with a pore size of 1 μm to prepare the backcoat layer forming composition.

[0127] (5) Manufacturing of magnetic tape and magnetic tape cartridges Magnetic tape was manufactured according to the manufacturing process shown in Figure 8. Details are as follows: A polyethylene naphthalate support with a thickness of 3.7 μm was fed from a feeding section, and a non-magnetic layer-forming composition was applied to one surface in the first coating section so that the thickness after drying was 0.7 μm to form a coating layer. While the formed coating layer was still wet, it was passed through a cooling zone adjusted to an ambient temperature of 0°C for the residence time shown in Table 1 to perform a cooling process, and then passed through a first heat treatment zone at the drying temperature (ambient temperature, the same applies hereafter) shown in Table 1 to perform a heat drying process and form a non-magnetic layer. Subsequently, in the second coating area, the magnetic layer-forming composition prepared above was applied onto the non-magnetic layer to form a coating layer, such that the thickness after drying was 0.1 μm. While this coating layer was still wet, a magnetic field of strength 0.5 T was applied perpendicularly to the surface of the coating layer of the magnetic layer-forming composition in the orientation zone to perform a vertical orientation treatment, and then it was dried in the second heat treatment zone at the drying temperature shown in Table 1. Subsequently, in the third coating section, the backcoat layer-forming composition prepared above was applied to the surface of the polyethylene naphthalate support opposite to the surface on which the non-magnetic and magnetic layers were formed, so that the thickness after drying would be 0.3 μm, thereby forming a coating layer. The formed coating layer was then dried in the third heat treatment zone at the drying temperature shown in Table 1. Subsequently, calendering (surface smoothing treatment) was performed using a calendering roll consisting solely of metal rolls, under the calendering conditions shown in Table 1. Subsequently, the material was heat-treated for 36 hours in an environment with an ambient temperature of 70°C. After heat treatment, the material was slit into 1 / 2-inch width strips to produce magnetic tape. The magnetic layer surface of the 1 / 2-inch wide magnetic tape obtained in this way was subjected to a burnishing and wiping treatment. The burnishing and wiping treatments were performed in a processing apparatus with the configuration shown in Figure 1 of Japanese Patent Application Publication No. 6-52544, using a commercially available polishing tape (product name MA22000, manufactured by Fujifilm Corporation, abrasive: diamond / Cr2O3 / α-iron oxide) as the polishing tape, a commercially available sapphire blade (manufactured by Kyocera Corporation, width 5 mm, length 35 mm, tip angle 60 degrees) as the grinding blade, and a commercially available wiping material (product name WRP736, manufactured by Kuraray Co., Ltd.) as the wiping material. The treatment conditions were the same as those in Example 12 of Japanese Patent Application Publication No. 6-52544, except that the burnishing tension during the burnishing treatment was set to the value shown in Table 1. Subsequently, with the magnetic layer of the magnetic tape obtained above demagnetized, servo signals were recorded on the magnetic layer using a commercially available servo writer. This resulted in a magnetic tape having data bands, servo bands, and guide bands arranged according to the LTO (Linear Tape-Open) Ultrium format, and having a servo pattern (timing-based servo pattern) on the servo bands arranged and shaped according to the LTO Ultrium format. The servo pattern thus formed conforms to the servo patterns described in JIS (Japanese Industrial Standards) X6175:2006 and Standard ECMA-319 (June 2001). The total number of servo bands is 5, and the total number of data bands is 4. A magnetic tape (length 960m) with the servo signals recorded in this way was then produced.

[0128] [Examples 2-11, Comparative Examples 1-8] A magnetic tape was obtained using the method described for Example 1, except that the items shown in Table 1 were changed as shown in Table 1. In the comparative example where "none" is written in the column for cooling zone residence time in Table 1, the magnetic tape was manufactured using a manufacturing process that did not include a cooling zone in the non-magnetic layer formation step.

[0129] For each example and comparative example, four magnetic tapes with a length of 960m were prepared and used for the evaluations described in (1) to (4) below.

[0130] [Evaluation Method] (1) Surface friction, width direction of surface friction σ For each magnetic tape in the examples and comparative examples, the substrate friction and the width direction σ of the substrate friction were determined by the method described above. The width direction of the magnetic tape to be measured was divided into five sections relative to the magnetic tape width (therefore, if the magnetic tape width is W, the width of each section is "W / 5"), and the substrate portion was identified in a randomly selected area within each section as follows. First, the surface of the magnetic layer to be measured was marked with a laser marker, and atomic force microscope (AFM) images were taken from a certain distance (approximately 100 μm) away from the marked area. The measurement was performed with a field of view of 7 μm × 7 μm. At this time, as will be described later, the cantilever was changed to a hard material (single-crystal silicon) to facilitate the acquisition of scanning electron microscope (SEM) images of the same area, and the markings were made on the AFM. From the AFM images thus measured, all protrusions at a height of 15 nm or more from the reference plane were extracted. The areas where no protrusions were determined to be present were identified as the substrate, and the substrate friction was measured using a Hysitron TI-950 triboindenter in the method described above. Furthermore, by measuring SEM images of the same locations as those measured in the AFM images and obtaining a component map, it was confirmed that protrusions with a height of 15 nm or more from the extracted reference plane were formed by alumina, diamond, or colloidal silica. In addition, in each example and comparative example, alumina, diamond, and colloidal silica were not detected in the substrate portion in the component map obtained using the above SEM.

[0131] (2) Nonlinear component of tape width deformation For each magnetic tape in the examples and comparative examples, the nonlinear component of tape width deformation resulting from 10 days of storage at a temperature of 60°C and a relative humidity of 20% was measured using the method described above.

[0132] (3) Total thickness of magnetic tape (tape thickness) Ten tape samples (5 cm in length) were cut from any part of each magnetic tape in the examples and comparative examples, and the thickness of these tape samples was measured by stacking them. The thickness was measured using a digital thickness meter consisting of a MARH Millimar 1240 compact amplifier and a Millimar 1301 inductive probe. The measured thickness was divided by 10 to obtain the value obtained (thickness per tape sample), which was defined as the tape thickness. For all magnetic tapes, the tape thickness was 4.8 μm. The thicknesses of the magnetic layer, non-magnetic layer, and backcoat layer of each magnetic tape in the examples and comparative examples were confirmed to be as previously described by cross-sectional observation.

[0133] (4) Recording and playback performance The recording and playback performance of each magnetic tape in the examples and comparative examples was evaluated using the following method. The magnetic head used included a playback module comprising an element array having 10 or more playback elements with a playback element width of 0.2 μm or less between a pair of servo signal reading elements, and a recording module comprising an element array having 10 or more recording elements with a recording element width of 1.5 times or more the playback element width between a pair of servo signal reading elements. In the above element array, the distance between two adjacent elements (i.e., two adjacent playback elements and two adjacent recording elements) in the head width direction is 40 μm or more. The environment for recording and playing back data was set to a temperature of 20-25°C and a relative humidity of 40-60%. A magnetic tape drive, with the magnetic tape and magnetic head mounted on a tape transport system (reel tester), was left in this environment for at least 24 hours before data recording and playback were performed. The recording and playback amplifier attached to the tape transport system of the magnetic tape drive was the same amplifier described earlier for measuring the nonlinear component of tape width deformation. During data recording and playback, the servo-following and dynamic track position control (change in head tilt angle) described earlier were implemented. Data recording and playback were performed in detail as follows. The signal was recorded using a recording element while the magnetic tape was run at a constant speed of 5 m / s. The bit sequence to be recorded was a 255-bit pseudo-random bit sequence (PRBS) generated according to the generator polynomial x^8 + x^6 + x^5 + x^4 + 1. The symbol "^" represents exponentiation. The linear recording density was set to 600 kbpi. The unit "kbpi" is the unit of linear recording density (cannot be converted to the SI unit system). Three or more tracks were recorded in single (shingled) format so that the difference between adjacent tracks (PES1 + PES2) / 2 was 1.5 times the playback track width. The magnetization pattern recorded on the magnetic tape is reproduced by the next regeneration element (i.e., the regeneration element with the same channel number) and the signal is amplified by the regeneration amplifier. The reproduced signal is processed by PLL (Phase Lock Loop) and AGC (Auto Gain Control), and then decoded into a bit sequence based on DD-NPML (Data Dependent Noise Predictive Maximum Likelihood) signal processing. The recorded bit sequence and the reproduced and decoded bit sequences are compared bit by bit, and if the two are different bits, it is counted as a 1-bit error. The data was compared over 10 Mbits, and the value obtained by dividing the accumulated error bit count by 10 Mbit was defined as the bit error rate. For the reproduced signal immediately after recording, it was confirmed that the bit error rate was 1 / 1000 or less for all channels. Next, the magnetic tape, still wound on the reel of the reel tester mentioned above, was stored for 10 days in an environment with a temperature of 60°C and a relative humidity of 20%. After the above storage, the magnetic tape was removed from the storage environment and mounted in the same magnetic tape drive used before storage. It was then placed in an environment with a temperature of 20-25°C and a relative humidity of 40-60% for at least 24 hours. Under these conditions, the data tracks recorded before storage were played back (no recording was performed). In this process, playback was performed only on data tracks that had data tracks recorded on both sides. The bit error rate was calculated for all channels, and channels with a bit error rate of 1 / 100 or more were considered defective channels. The recording and playback performance was then evaluated according to the following evaluation criteria. (Evaluation Criteria) A: The ratio of defective channels to the total number of channels is less than 5%. B: The ratio of defective channels to the total number of channels is 5% or more and less than 10%. C: The ratio of defective channels to the total number of channels is 10% or more.

[0134] The results are shown in Table 1 (Tables 1-1 to 1-3).

[0135] [Table 1-1]

[0136] [Table 1-2]

[0137] [Table 1-3]

[0138] As shown in Table 1, the magnetic tape of the example showed superior recording and playback performance compared to the magnetic tape of the comparative example after being stored in an accelerated environment equivalent to long-term storage. From these results, it can be confirmed that the magnetic tape of the example contributed to improving the operational stability of the drive (magnetic tape device).

[0139] The magnetic tape was manufactured using the method described in Example 1, except that vertical orientation processing was not performed during the manufacturing process. A sample piece was cut from the magnetic tape mentioned above. Using a Tamagawa Seisakusho TM-TRVSM5050-SMSL vibrating sample magnetometer, the vertical angular ratio of this sample piece was determined using the method described earlier and was found to be 0.55. The vertical aspect ratio was similarly determined for a sample piece cut from the magnetic tape of Example 1, and it was found to be 0.65.

[0140] The two magnetic tapes described above were each mounted on a 1 / 2-inch reel tester, and their electromagnetic conversion characteristics (SNR: Signal-to-Noise Ratio) were evaluated using the following method. As a result, the magnetic tape of Example 1 obtained an SNR value 4 dB higher than the magnetic tape manufactured without vertical orientation treatment. Recording and playback were performed in 10 passes under a tension of 0.7 N (Newtons) in the longitudinal direction of the magnetic tape in an environment of 23°C and 50% relative humidity. The relative speed between the magnetic tape and the magnetic head was set to 6 m / s. For recording, a MIG (Metal-in-gap) head (gap length 0.15 μm, track width 1.0 μm) was used as the recording head, and the recording current was set to the optimal recording current for each magnetic tape. For playback, a GMR (Giant-magnetoresistive) head (element thickness 15 nm, shielding gap 0.1 μm, playback element width 0.8 μm) was used as the playback head. The head tilt angle was set to 0°. A signal with a linear recording density of 300 kfci was recorded, and the playback signal was measured using a spectrum analyzer manufactured by Shibasoku. The unit kfci is the unit of linear recording density (cannot be converted to the SI system). As the signal, the portion where the signal was sufficiently stable after the start of magnetic tape movement was used. [Industrial applicability]

[0141] One aspect of the present invention is useful in the technical field of various data storage technologies.

Claims

1. A magnetic tape comprising a non-magnetic support and a magnetic layer containing ferromagnetic powder, The coefficient of friction measured on the substrate portion of the surface of the magnetic layer is 0.35 or less, and A magnetic tape in which the standard deviation σ of the coefficient of friction in the width direction of the surface of the magnetic layer is 0.05 or less.

2. The magnetic tape according to claim 1, wherein the coefficient of friction measured in the base material portion is 0.20 or more and 0.35 or less.

3. The magnetic tape according to claim 1, wherein the standard deviation σ of the coefficient of friction is 0.01 or more and 0.05 or less.

4. The magnetic tape according to claim 1, wherein the standard deviation σ of the coefficient of friction is 0.01 or more and 0.02 or less.

5. The magnetic tape according to claim 1, further comprising a non-magnetic layer containing non-magnetic powder between the non-magnetic support and the magnetic layer.

6. The magnetic tape according to claim 5, wherein the thickness of the non-magnetic layer is 0.1 μm or more and 0.7 μm or less.

7. The magnetic tape according to claim 1, further comprising a back coat layer containing non-magnetic powder on the surface side of the non-magnetic support opposite to the surface side having the magnetic layer.

8. The magnetic tape according to claim 1, wherein the tape thickness is 5.2 μm or less.

9. The magnetic tape according to claim 1, wherein the tape thickness is 5.0 μm or less.

10. The magnetic tape according to claim 1, wherein the vertical aspect ratio of the magnetic tape is 0.60 or greater.

11. The magnetic tape according to claim 1, wherein the vertical aspect ratio of the magnetic tape is 0.65 or more.

12. The coefficient of friction measured in the aforementioned base material is 0.20 or more and 0.35 or less. The standard deviation σ of the friction coefficient is 0.01 or more and 0.02 or less. The non-magnetic support and the magnetic layer further comprise a non-magnetic layer containing non-magnetic powder. The thickness of the non-magnetic layer is 0.1 μm or more and 0.7 μm or less. The non-magnetic support further has a back coat layer containing non-magnetic powder on the surface side opposite to the surface side having the magnetic layer, The tape thickness is 5.0 μm or less, and The magnetic tape according to claim 1, wherein the vertical aspect ratio of the magnetic tape is 0.65 or more.

13. A magnetic tape cartridge comprising the magnetic tape according to any one of claims 1 to 12.

14. A magnetic tape device including a magnetic tape according to any one of claims 1 to 12.

15. Further including a magnetic head, The magnetic head has a module including an element array having a plurality of magnetic head elements between a pair of servo signal reading elements, and The magnetic tape device according to claim 14, wherein the magnetic tape device changes the angle θ that the axis of the element array makes with respect to the width direction of the magnetic tape while the magnetic tape is running within the magnetic tape device.

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