Allomelanin-inspired nanoadditives for the radiation protection of polyurethane

Synthetic melanin-inspired nanoparticles enhance the radiation resistance and mechanical properties of polymeric materials by forming nanocomposites with covalently-linked allomelanin and eumelanin precursors, addressing the limitations of existing additives like polydopamine nanomaterials.

WO2025171328A1 Publication Date: 2025-08-14NORTHWESTERN UNIV
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Patent Information

Application Number
PCT/US2025/015109
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-02-09
Filing Date
2025-02-07
Publication Date
2025-08-14

AI Technical Summary

Technical Problem

Existing radiation protectant additives for polymeric materials, such as polydopamine nanomaterials, are limited by moderate radical scavenging ability and require organic solvents for dispersion, necessitating a need for more effective radiation-resistant additives.

Method used

Development of synthetic melanin-inspired nanoparticles comprising covalently-linked artificial allomelanin and eumelanin precursors, which are incorporated into polymer nanocomposites to enhance radiation resistance and mechanical properties.

Benefits of technology

The synthetic melanin-inspired nanoparticles improve the radiation resistance and mechanical properties of polymeric materials, effectively scavenging free radicals and maintaining structural integrity under ionizing radiation exposure.

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Abstract

Aspects of the invention include a nanoadditive comprising a synthetic melanin-inspired nanoparticle, wherein: the synthetic melanin-inspired nanoparticle comprises a plurality of covalently-linked artificial melanin precursors, and each artificial melanin precursor independently comprises an artificial allomelanin precursor, an artificial eumelanin precursor, or a structural isomer thereof. Aspects of the invention include methods of generating polymer nanocomposites and methods of enhancing a mechanical property of a polymeric material.
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