Residue reduction in perfluoroalkoxy alkane (PFA) dispersions

WO2025189061A8 Publication Date: 2025-10-02THE CHEMOURS CO FC LLC
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Patent Information

Application Number
PCT/US2025/018847
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-03-08
Filing Date
2025-03-07
Publication Date
2025-10-02

AI Technical Summary

Technical Problem

Existing fluoropolymer dispersions contain significant levels of nonionic surfactants and fluorinated residues, including perfluoroalkyl carboxylic acids (PFCAs), which are subject to regulatory control and environmental concerns, and current methods are inefficient in reducing these contaminants.

Method used

A process involving polymerization in an aqueous medium with a nucleant to achieve small particle sizes, followed by modification with a nonionic surfactant and treatment with an ion exchange resin to reduce linear C9-C14 perfluoroalkyl carboxylic acids to low concentrations.

Benefits of technology

The process effectively reduces linear C9-C14 perfluoroalkyl carboxylic acids to parts-per-billion levels, enhancing environmental compliance and manufacturing efficiency.

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Abstract

A process includes contacting a perfluoroalkoxy alkane (PFA) dispersion having a first cumulative concentration of linear C9-C14 perfluoroalkyl carboxylic acids to an ion exchange resin to remove at least 95% of the linear C9-C14 perfluoroalkyl carboxylic acids from the PFA dispersion. A PFA dispersion includes particles of perfluoroalkoxy alkane dispersed in an aqueous liquid. The particles have a raw dispersion particle size of less than 180 nm. The PFA dispersion has a solids content of at least 20 wt% and a total concentration of linear C9-C14 perfluoroalkyl carboxylic acids of about 500 parts-per-billion or less.
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