Method for treating heavy bis(fluorosulfonyl)imide residue

By reacting the heavy residue of bis(fluorosulfonyl)imide with an acidic aqueous solution to generate a fluorinated acid solution and crude aminosulfonic acid, the problem of resource utilization of the heavy residue of bis(fluorosulfonyl)imide was solved, and cost reduction and economic benefits were achieved.

WO2025261267A1 Publication Date: 2025-12-26JIUJIANG TINCI ADVANCED MATERIALS CO LTD
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Patent Information

Application Number
PCT/CN2025/100861
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-06-17
Filing Date
2025-06-13
Publication Date
2025-12-26

AI Technical Summary

Technical Problem

In existing technologies, the bis(fluorosulfonyl)imide heavy residue has poor flowability, making it difficult to utilize as a resource, resulting in high processing costs. As market demand increases, more waste residue is generated, necessitating the development of effective treatment methods.

Method used

By reacting the heavy residue of difluorosulfonamide with an acidic aqueous solution, a fluorinated acid solution and crude aminosulfonic acid are generated. By controlling the feeding time, temperature, stirring speed and rinsing process, a commercially available aminosulfonic acid product can be obtained. The fluorinated acid solution is used as a by-product acid, thereby reducing costs.

Benefits of technology

This method enables the resource-based recycling of bis(fluorosulfonyl)imide heavy residue, reducing processing costs and improving economic efficiency. The generated aminosulfonic acid can be sold directly, and the fluorinated acid solution can be used as a by-product acid, reducing processing costs.

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Abstract

Provided in the present application is a method for treating a heavy bis(fluorosulfonyl)imide residue, comprising the following step: causing a starting material system comprising the heavy bis(fluorosulfonyl)imide residue and an acidic aqueous solution to react to obtain a fluorine-containing acid solution and a crude sulfamic acid product, wherein the fluorine-containing acid solution can be used as a by-product acid, thereby saving treatment costs; and the crude sulfamic acid product can also be directly sold as a product, thereby reducing treatment costs, bringing economic benefits, and achieving resource recycling of the heavy bis(fluorosulfonyl)imide residue.
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