Copper Hydrogen Nanoclusters Cu 20 H8 and its preparation method and catalytic application
By adopting the copper hydrogen nanoclusters of [Cu20H8Y10]·X2 and combining with specific synthesis methods, the problems of existing copper hydrogen nanoclusters in terms of stability and catalytic activity are solved, and the effect of efficient catalyzing of cinnamaldehyde is achieved.
Patent Information
- Application Number
- CN202310298016.4
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2023-03-24
- Publication Date
- 2025-03-28
- Estimated Expiration
- 2043-03-24
AI Technical Summary
The existing copper hydrogen nanoclusters have problems in synthesis difficulties, poor stability and H-difficulty in precise positioning, resulting in poor performance in catalytic applications.
[Cu20H8Y10]·X2 copper hydrogen nanoclusters, Y is the nitrogen ligand after dehydrogenation, and X is an anion. Through a specific synthesis method, Cu(CH3CN)4X and nitrogen ligand, and the addition of alkaline solvent and tert-butylamine boronane in methanol solution was obtained to obtain copper hydrogen nanoclusters with high stability and catalytic activity.
The high selectivity and high conversion rate of copper hydrogen nanoclusters are achieved, with significant catalytic effect on cinnamaldehyde, with a selectivity of up to 100%, a conversion rate of up to 95%, and a simple synthesis method and a high yield.