Preparation method of amorphous IrOx / Ru catalyst for PEM water electrolysis to produce hydrogen

By preparing amorphous IrOx/Ru catalysts, the problems of poor stability and high cost of iridium in PEM water electrolysis hydrogen production technology were solved, efficient and low-cost catalyst application was achieved, the amount of precious metal iridium used was reduced, and the activity and stability of the catalyst were improved.

CN116356361BActive Publication Date: 2025-09-30JIAXING RES INST ZHEJIANG UNIV +1
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Patent Information

Application Number
CN202310022238.3
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-01-07
Publication Date
2025-09-30
Estimated Expiration
2043-01-07

AI Technical Summary

Technical Problem

In the existing PEM water electrolysis hydrogen production technology, the anode catalyst iridium has poor stability and high cost, resulting in a surge in catalyst manufacturing costs. It is necessary to reduce the amount of precious metal iridium and improve the activity and stability of the catalyst.

Method used

A highly active and stable catalyst was prepared by adding sodium nitrate to a mixture of iridium salt and ruthenium powder, followed by ultrasonic treatment, constant temperature heating, and calcination. The iridium content was reduced, and the synergistic effect of ruthenium was utilized to enhance the catalyst activity.

Benefits of technology

The amorphous IrOx/Ru catalyst has high OER activity under acidic conditions, low cost, and exhibits good stability and catalytic activity in the PEM water electrolysis hydrogen production system. The iridium content is only 50% of commercial IrO2, which reduces cost and improves activity.

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Abstract

The present invention relates to the technical field of electrochemical catalysts and aims to provide a method for preparing an amorphous IrOx / Ru catalyst for use in PEM water electrolysis to produce hydrogen. The method comprises the following steps: ultrasonically treating metal ruthenium powder, iridium salt, and isopropyl alcohol, stirring to form a solid suspension, adding sodium nitrate powder and mixing uniformly; heating and stirring in a water bath at a constant temperature until the liquid evaporates to dryness, obtaining a brownish-yellow powder; calcining at 350-450°C, naturally cooling, adding a perchloric acid solution, ultrasonically treating, and centrifuging to obtain a black solid; and centrifuging, washing, and drying to obtain an amorphous IrOx / Ru catalyst. x / Ru catalyst. The catalyst prepared by the present invention exhibits high OER activity and good stability under acidic conditions. The iridium content in the catalyst of the present invention is only 50% of that of commercial IrO2, resulting in a low cost. The catalyst also features a small particle size, uniform distribution of iridium and ruthenium, and low crystallinity. The iridium oxide in the catalyst has a disordered structure, resulting in high catalytic activity.
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