Catalyst for preparing dialkyl carbonate, preparation method and application thereof

The invention adopts a homogeneous catalytic reaction to prepare dialkyl carbonate by combining an ionic liquid main catalyst and a co-catalyst, thereby solving the problems of active component loss and low selectivity in the prior art and realizing efficient and low-cost production of dialkyl carbonate.

CN117339629BActive Publication Date: 2025-09-26CHINA PETROLEUM & CHEMICAL CORP +1
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Patent Information

Application Number
CN202210754149.3
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2022-06-28
Publication Date
2025-09-26
Estimated Expiration
2042-06-28

AI Technical Summary

Technical Problem

Existing dimethyl carbonate synthesis methods have problems such as loss of active components, low selectivity, high cost and unstable raw materials, making it difficult to efficiently prepare dialkyl carbonate.

Method used

The invention adopts a combination of ionic liquid main catalyst and co-catalyst to prepare dialkyl carbonate through homogeneous catalytic reaction. Dialkyl oxalate is used as raw material, and a decarbonylation reaction is carried out under specific conditions to generate dialkyl carbonate. The product is separated by a distillation tower.

Benefits of technology

The selectivity of dialkyl carbonate and the service life of the catalyst are improved, side reactions are reduced, the problem of loss of active components of traditional catalysts is solved, and production costs are reduced.

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Abstract

The present invention provides a catalyst for preparing dialkyl carbonate, a preparation method, and applications thereof. The catalyst comprises an ionic liquid main catalyst and a co-catalyst. Based on 100 parts by weight of the total weight of the ionic liquid main catalyst and the co-catalyst, the ionic liquid main catalyst comprises 85 to 95 parts by weight, and the co-catalyst comprises 5 to 15 parts by weight. The catalyst of the present invention is used to prepare dialkyl carbonate, resulting in high selectivity for the target product, a long catalyst life, and effective reduction in side reactions.
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