Application of modified perovskite loaded bimetallic catalyst in methane catalytic combustion

Through ionizing radiation modification technology, defective positions are formed on the surface of perovskite catalysts and the dispersion of bimetallic particles are improved, which solves the problem of insufficient activity of perovskite catalysts and achieves efficient methane catalytic combustion performance and stability.

CN119702005APending Publication Date: 2025-03-28NANJING TECH UNIV
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Patent Information

Application Number
CN202411947480.2
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-27
Publication Date
2025-03-28

AI Technical Summary

Technical Problem

The existing perovskite catalysts lack catalytic activity in methane catalytic combustion, and high-temperature treatment can easily lead to crystal structure damage and affect performance.

Method used

Ionizing radiation modification technology is used to interact with aqueous solution through ionizing radiation to generate strongly reduced solvated electrons and hydrogen radicals, forming uniformly distributed defect positions on the perovskite surface, improving the activity of the catalyst, and reducing the anchor alloy in situ through strong interface interaction and radiation to improve the particle dispersion of the loaded bimetals.

Benefits of technology

It significantly improves the catalytic performance and stability of the catalyst, reduces the cost of the catalyst, and is suitable for large-scale preparation and industrial applications.

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Abstract

The invention discloses an application of a modified perovskite loaded bimetallic catalyst in methane catalytic combustion. The preparation method comprises the following steps: weighing perovskite, precious metal salt and transition metal salt, dissolving in water, ultrasonically stirring to form a mixed solution, uniformly dispersing, adding a hydroxyl screening agent, uniformly dispersing, introducing an ionization source, carrying out irradiation reaction, centrifugally washing, drying to obtain a solid, roasting and activating the solid in an air atmosphere, and drying to obtain the perovskite catalyst. The ionizing radiation modified perovskite loaded bimetallic catalyst is obtained. The metal loading capacity of the catalyst is uniformly distributed, the size of metal particles is effectively controlled, the metal particles and the carrier have a relatively strong loading combination degree, and the catalyst has high catalytic activity on the combustion reaction of methane. The whole preparation process is simple to operate, the repeatability is strong, the reaction condition is mild, and the catalyst is suitable for large-scale production; the catalyst has important application value in the fields of environmental governance, gas catalytic combustion and the like.
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