Electrostatic spinning production equipment and preparation method of carbon nanowire composite electrode

Abstract

The invention relates to the field of carbon nano electrostatic spinning, in particular to electrostatic spinning production equipment of a carbon nanowire composite electrode and a preparation method, the electrostatic spinning production equipment comprises a control host, the control host is an equipment general control mechanism and is arranged on a bottom plate frame, and a mixed liquid bin is embedded in the control host; the yarn mixing bin is communicated with a spinning bin, six sets of spinning mechanisms distributed in a circular array mode are arranged in the spinning bin, and yarn guide frames fixedly installed on the inner wall of the spinning bin are arranged on the side edges of the spinning mechanisms. Six groups of guide gears are arranged, six groups of spinning discs can be driven to conduct spinning, efficient spinning is achieved, spinning mechanisms distributed corresponding to the spinning discs conduct feeding spinning, a first conductive clamp clamps a first conductive core to conduct electricity, and a second conductive clamp clamps another conductive core on a nozzle. And the six groups of second conductive clamps clamp the nozzles to form six circulating electric fields with the first conductive core, so that partitioned spinning is realized.

Description

Technical Field

[0001] The present invention relates to the field of carbon nanotube electrospinning, and specifically to an electrospinning production device and preparation method for a carbon nanotube composite electrode. Background Art

[0002] Most carbon nanotube composite electrodes are used as electrode materials for zinc-ion batteries. The scarcity and cost problems of lithium metal resources have prompted an urgent need to develop new secondary battery systems that are affordable, environmentally friendly, and have high energy density. Aqueous zinc-ion batteries have low cost, high safety, a low redox potential (-0.76 V SHE. H), and a high theoretical specific capacity of the zinc negative electrode (820 mAh g-1), and thus have become the most competitive alternative to lithium-ion batteries. Therefore, carbon nanotube composite electrodes play an extremely important role in the preparation of zinc-ion batteries.

[0003] In a document with the publication number: CN107503000A, a method for preparing nanofiber carbon filaments by electrospinning is proposed. The method states that "by adjusting the concentration of a suitable polyacrylonitrile solution, high-orientation nanofibers are prepared through a fluid-assisted electrospinning process, and then the obtained nanofibers are post-drawn, and finally high-temperature carbonization is carried out in an inert atmosphere to obtain nanofiber carbon filaments". The method involves high-temperature modification of the nanofibers. However, precise control of the temperature during high-temperature modification is crucial. If the temperature is too high, the fiber structure may be damaged, and if the temperature is too low, the expected performance improvement effect may not be achieved. At the same time, the atmosphere control during the heat treatment process also affects the surface chemical properties and microstructure of the material.

[0004] Laboratory-scale electrospinning equipment has a low output and is difficult to meet the requirements of industrial large-scale production. To achieve large-scale production, it is necessary to develop efficient spinning equipment, such as multi-nozzle spinning systems, continuous spinning devices, etc. However, the design and manufacture of these devices need to consider issues such as mutual interference between multiple nozzles, uniform supply of the solution, and continuous collection of fibers, and the technical difficulty is relatively large; When the nanofibers in electrospinning are initially formed, burrs extend from their surfaces, which will have a certain impact on subsequent annealing and the application of the electrodes. Summary of the Invention

[0005] In view of the above problems, it is necessary to provide an electrospinning production device and preparation method for a carbon nanotube composite electrode for the above technical problems.

[0006] To solve the above technical problems, the technical solution adopted by the present invention is as follows: An electrospinning production device for a carbon nanotube composite electrode, including a control host, the control host is the overall control mechanism of the device and is arranged on a bottom plate frame, a mixed liquid bin is nested and installed in the control host, and a mixed wire bin is arranged on the side of the control host; The mixed wire bin is communicated with a spinning bin, six groups of spinning mechanisms distributed in a circular array are arranged in the spinning bin, a wire guiding frame fixedly installed on the inner wall of the spinning bin is arranged on the side of the spinning mechanism, and a tension adjustment bin is connected to the other end of the spinning bin where it is located at the mixed wire bin; The wire guiding frame is distributed with a first guide roller, a second guide roller, a third guide roller and a fourth guide roller, a burr removing mechanism installed on the wire guiding frame is arranged between the second guide roller and the third guide roller, and the burr removing mechanism removes burrs from the spun nanowires; The tension adjustment bin is connected with an annealing bin, an electrolyte bin is installed at the lower end inside the annealing bin, the annealing bin is connected with a drying bin, a side support body is installed on the bottom plate frame close to the drying bin, and a collecting device is arranged on the side support body.

[0007] The control host is distributed with a control panel and control buttons, and the control host completes the electrical control of the entire device through the control panel and control buttons.

[0008] A liquid inlet is opened on the mixed liquid bin, a liquid guiding port is arranged at the lower end of the mixed liquid bin, a corresponding liquid receiving port is arranged on the control host close to the liquid guiding port, and an infusion pump is assembled on the liquid receiving port.

[0009] A first servo motor is installed in the mixed wire bin, a driving gear is installed on the output end of the first servo motor, six groups of guiding gears meshing with it are arranged on the side of the driving gear, a spinning disk is connected to the middle axis of the guiding gear through a guiding shaft, a first guide core is installed at the center of one side of the mixed wire bin, a first conductive clamp is clamped on the first guide core, and a first wire is arranged on the first conductive clamp.

[0010] An operation port is arranged on the spinning bin, extension plates are installed on both sides of it, a first bin door is arranged on the operation port, the distribution positions of the spinning mechanism and the spinning disk correspond to each other, the spinning mechanism includes an installation frame, a baffle, a nozzle, an infusion pipe, a second conductive clamp and a second wire, the installation frame is fixed to the extension plate, the baffle is integrally designed with the installation frame, a nozzle is threadedly connected to one side of the baffle, an infusion pipe is connected to the other side of the baffle, the extension port of the nozzle serves as a guide core and a second conductive clamp is clamped on it, and a second wire is connected to the second conductive clamp.

[0011] The burr removal mechanism includes an operation frame, an operation table, a pulling tooth plate, a top frame plate, a driving motor, a driving rod, a cutting mechanism, and a burr collection gear. The operation frame is fixed to the wire guiding frame, and the wire guiding frame corresponds to the distribution position of the spinning disk. The operation table is arranged on the operation frame, and a pulling tooth plate nested and slidable with it is penetrated through the operation table. A first limiting magnetic sheet is installed on the side of the pulling tooth plate, and a second limiting magnetic sheet is arranged at the bottom end of the pulling tooth plate. Both the first limiting magnetic sheet and the second limiting magnetic sheet are magnetically connected to the operation table. The top frame plate is located at the top of the operation frame, and a driving motor is installed on the side of the top frame plate. The output end of the driving motor is respectively connected with a first transmission gear and a first transmission bevel gear. A driving rod is arranged under the top frame plate, and a clamping gear is installed in the middle of the driving rod. A second transmission bevel gear is arranged on the driving rod close to the first transmission bevel gear, and the second transmission bevel gear meshes with the first transmission bevel gear. A cutting mechanism is arranged on the operation frame, and four groups of burr collection gears are distributed on the top frame plate. Intermediate gears meshing with each other are distributed among the four groups of burr collection gears, and the burr collection gears mesh with the first transmission bevel gear. A driving guide rod is penetrated through the burr collection gear, a collection fan is installed on the driving guide rod, and a collection bag communicating with it is threadedly arranged on the burr collection gear.

[0012] The cutting mechanism is set to two groups, and the two groups of cutting mechanisms are symmetrically and staggeredly distributed. The cutting mechanism includes a rotating shaft, an arc-shaped frame, spreading teeth, a linkage rod, a linkage gear, and a cutting blade. The rotating shaft is arranged on the operation frame and fixedly connected with it. The arc-shaped frame penetrates through the rotating shaft and is rotatably connected with it. Spreading teeth are arranged on the arc-shaped frame close to the pulling tooth plate, and the spreading teeth are in meshing connection with the pulling tooth plate. Linkage rods are evenly distributed on the arc-shaped frame, a linkage gear is installed on the side of the linkage rod, and a cutting blade is installed on the linkage rod.

[0013] An outer rotating wheel rotatably connected with it is arranged on the tension adjustment bin, and clamping holes are evenly opened on the outer rotating wheel. A tension control mechanism is arranged on the side of the clamping hole. The tension control mechanism includes a first fixed seat, a plug rod, a pulling handle, a second fixed seat, and a spring. The first fixed seat is fixed to the tension adjustment bin, a plug rod is penetrated through the first fixed seat, the plug rod penetrates through the second fixed seat on the side of the first fixed seat, a pulling handle is welded and fixed on the side of the plug rod, and a spring is installed in the section between the first fixed seat and the second fixed seat of the plug rod. One end of the spring close to the second fixed seat is fixed on the surface of the plug rod; A tension adjustment mechanism connected to the outer rotating wheel is arranged in the tension adjustment bin. The tension adjustment mechanism includes a first rotating ring, which is connected to the outer rotating wheel. Six groups of connecting arms rotatably connected thereto are distributed on the first rotating ring. A first pin and a second pin are respectively installed at both ends of the connecting arm. An adjustment piece is penetrated through the second pin. Multiple groups of adjustment holes with different pore diameters are distributed on the adjustment piece. The adjustment pieces are set to six groups. Each single adjustment piece is of a triangular structure and its edge is arc-shaped. A third pin is arranged on the adjustment piece and penetrates through and connects a second rotating ring.

[0014] A second bin door is arranged on the annealing bin. A first electrode position and a second electrode position are respectively connected to both sides of the electrolyte bin. A pushing member mechanism is arranged above the electrolyte bin. The pushing member mechanism includes a control motor, an electric telescopic rod, an insulating ring and a sleeve hole. The control motor is fixedly connected to the upper surface of the top end of the annealing bin. The lower end of the control motor is provided with an electric telescopic rod located in the annealing bin. An insulating ring is installed on the electric telescopic rod. Sleeve holes are distributed in the insulating ring. The insulating ring and the electrolyte bin form a telescopic structure in the vertical direction through the electric telescopic rod.

[0015] A third bin door is arranged on the drying bin. Two groups of exhaust fans are distributed on the top end of the drying bin. A first guide frame and a second guide frame are respectively arranged on both sides of the drying bin. The first guide frame is connected to the annealing bin and six groups of first guide holes are arranged on it in a circular array centered on the center of the first guide frame. Second guide holes corresponding to the first guide holes are arranged on the second guide frame. A drying cover is installed on the second guide frame. A wire guide bin is connected to the side of the second guide frame. Six groups of wire holes corresponding to the second guide holes are distributed on the wire guide bin. A wire roller is installed in the middle of the wire holes. Heating wires and heating fans are respectively installed inside the drying cover close to one end of the wire guide bin.

[0016] A second servo motor fixedly installed with the side support body is arranged on the collection device. A first steering gear is installed at the output end of the second servo motor. Six groups of second steering gears meshing with it are connected to the first steering gear. A rotating rod is connected to the second steering gear. A limiting frame fixed to the side support body is penetrated through the rotating rod. A thread is arranged on the rotating rod and a positioning clamping plate matching with it is connected to the thread.

[0017] An electrospinning production preparation method of a carbon nanotube composite electrode, a proportioning solution mixed with V 2 O 3 and nitrogen-doped carbon nanotubes is placed into the mixing liquid bin, and the mixed liquid is guided into the infusion tube through the infusion pump on the control host; The first conductive clip holds the first guide core, and the second conductive clip holds another guide core on the nozzle to form an electric field. The solution in the infusion tube is ejected through the nozzle for spinning, and V 2 O 3 is confined in the carbon nanotubes; The spinning disk rotates to collect the ejected spun fibers. The spun fibers are collected by rotating through a guide screw rod with a diameter of 0.5 cm and a length of 10 - 15 cm. They pass through the first guide roller and the second guide roller in an "S" - shaped trajectory. When passing through the burr - removing mechanism, the burrs on the edge of the nanofibers after spinning are removed, and then they pass through the third guide roller and the fourth guide roller in the same "S" - shaped trajectory for guiding; Select and adjust the corresponding adjustment holes on the adjustment piece according to the thickness diameter of the spun fiber product and pass through them. Then pass through the sleeve hole. The pusher mechanism is activated to sink the insulating ring passing through the nanofibers into the electrolyte chamber for electrochemical annealing. During the V 2 O 3 to V 2 O 5 In the process of electrochemical conversion, the carbon nanotubes can act as a "protective structure" to effectively prevent the formation of by - products, and construct a pea - pod - shaped nitrogen - doped carbon nanotube - coated amorphous V 2 O 5 microsphere independent electrode material; The nanofibers that have completed electrochemical annealing continue to pass through the first guide hole and the second guide hole. The heating wire and the heating fan in the evaporation cover cooperate to operate, forming hot air for rapid drying. The water vapor is discharged through the exhaust fan.

[0018] The dried nanofibers pass through the wire hole and are limited by fitting on the wire roller. The collected drum - type collector or the prepared collector is installed in the rotating rod, and the collector is fixed through the positioning clamping plate. As the rotating rod rotates, the nanofibers are wound up. The beneficial effects of the present invention compared with the prior art are as follows: Firstly, by setting six groups of guiding gears, six groups of spinning disks can be driven to spin, realizing efficient spinning. The spinning mechanism corresponding to the distribution of the spinning disks supplies materials for spinning. The first conductive clip holds the first guide core to conduct electricity, and the second conductive clip holds another guide core on the nozzle. Six groups of second conductive clips hold the nozzle and the first guide core to form six - cycle electric fields, realizing zonal spinning.

[0019] Secondly, the first transmission gear and the first transmission bevel gear on the driving motor rotate synchronously, driving the driving rod and the burr - collecting gear to rotate. When the clamping gear on the driving rod contacts the linkage gear, linkage is realized, driving multiple groups of linkage gears to make the upper cutting blades operate, collecting the debris while removing the burrs.

[0020] Thirdly, the rotation of the outer rotating wheel drives the connecting arm on the first rotating ring to move. The connecting arm disengages from the second rotating ring, driving the six groups of adjusting pieces to expand synchronously. At this time, the nanowires arranged in the adjusting holes can adjust their own tension, and the nanowires can flexibly form a tight or loose state. Through the fixation of the insertion rod and the corresponding card holes, the rotation angle of the first rotating ring on the outer rotating wheel is fixed.

[0021] Fourthly, through the up and down settlement of the nanowires in the sleeve holes of the insulating ring, the nanowires can be immersed in the electrolyte storage tank during production, and electrochemical annealing is completed in cooperation with the electrolyte and the voltages released by the first electrode position and the second electrode position.

[0022] Fifthly, through the operation of the heating wire and the heating fan in the evaporation cover, the heat can be fully and evenly transferred to every direction in the drying chamber. The nanowires located at the periphery of the evaporation cover are dried during the movement through the evaporation of the heat flow, avoiding the moisture of the modified nanoelectrodes from affecting the storage. BRIEF DESCRIPTION OF THE DRAWINGS

[0023] Figure 1 is a schematic diagram of the overall structure of the present invention; Figure 2 is a schematic diagram of the first perspective of the overall internal structure of the present invention; Figure 3 is a schematic diagram of the second perspective of the overall internal structure of the present invention; Figure 4 is a schematic diagram of the installation structure of the mixed liquid storage tank of the present invention; Figure 5 is a schematic diagram of the spinning chamber structure of the present invention; Figure 6 is a schematic diagram of the mixed wire chamber structure of the present invention; Figure 7 is a schematic diagram of the wire guiding frame structure of the present invention; Figure 8 is a schematic diagram of the spinning mechanism structure of the present invention; Figure 9 is a schematic diagram of the tension adjusting mechanism structure of the present invention; Figure 10 is a schematic diagram of the annealing chamber structure of the present invention; Figure 11 is a schematic diagram of the installation structure of the outer rotating wheel of the present invention; Figure 12 of the present invention Figure 11 is a partial enlarged structure schematic diagram of point A; Figure 13 is a schematic diagram of the pusher mechanism structure of the present invention; Figure 14 is a schematic diagram of the drying chamber structure of the present invention; Figure 15 is a schematic diagram of the wire guiding chamber structure of the present invention; Figure 16 Schematic structural diagram of the collection device of the present invention; Figure 17 Schematic structural diagram of the winding component of the present invention; Figure 18 Schematic structural diagram of the burr removal mechanism of the present invention; Figure 19 Schematic structural diagram of the burr collection gear of the present invention; Figure 20 Schematic unfolded structural diagram of the cutting mechanism of the present invention; Figure 21 Schematic folded structural diagram of the cutting mechanism of the present invention.

[0024] The reference numerals in the figure are: 1, control host; 101, control panel; 102, control button; 103, infusion pump; 104, liquid collection port; 2, mixed liquid bin; 201, liquid inlet; 202, liquid guiding port; 3, mixed filament bin; 31, first servo motor; 32, driving gear; 33, guiding gear; 34, spinning disc; 35, first guide core; 36, first conductive clip; 37, first wire; 4, spinning bin; 41, spinning mechanism; 411, mounting frame; 412, baffle; 413, nozzle; 414, infusion tube; 415, second conductive clip; 416, second wire; 42, wire guiding frame; 421, first guide roller; 422, second guide roller; 423, third guide roller; 424, fourth guide roller; 425, burr removal mechanism; 4251, operating frame; 4252, operating table; 4253, pulling toothed plate; 4253a, first limiting magnetic sheet; 4253b, second limiting magnetic sheet; 4254, top frame plate; 4255, driving motor; 4255a, first transmission gear; 4255b, first transmission bevel gear; 4256, driving rod; 4256a, second transmission bevel gear; 4256b, clamping gear; 4257, cutting mechanism; 4257a, rotating shaft; 4257b, arc-shaped frame; 4257c, unfolding teeth; 4257d, connecting rod; 4257e, linkage gear; 4257f, cutting blade; 4258, burr collection gear; 4258a, driving guide rod; 4258b, collection fan; 4258c, collection bag; 4259, transfer gear; 43, first bin door; 44, extension plate; 5. Tension adjustment bin; 51. Outer runner; 52. Card hole; 53. Tension control mechanism; 531. First fixed seat; 532. Insert rod; 533. Pull handle; 534. Second fixed seat; 535. Spring; 54. Tension adjustment mechanism; 541. First rotating ring; 542. Connecting arm; 543. First pin; 544. Second pin; 545. Adjusting piece; 546. Adjusting hole; 547. Second rotating ring; 548. Third pin; 6. Annealing bin; 61. Second bin door; 62. Pushing mechanism; 621. Control motor; 622. Electric telescopic rod; 623. Insulating ring; 624. Sleeve hole; 63. Electrolyte bin; 64. First electrode position; 65. Second electrode position; 7. Drying bin; 71. Third bin door; 72. Exhaust fan; 73. First guide frame; 731. First guide hole; 74. Second guide frame; 741. Second guide hole; 75. Evaporation cover; 76. Wire bin; 761. Wire hole; 762. Wire roller; 77. Heating wire; 78. Heating fan; 8. Side support body; 9. Collection device; 91. Second servo motor; 92. First steering gear; 93. Limit frame; 94. Rotating rod; 95. Positioning clamping plate; 96. Second steering gear. Detailed implementation manner

[0025] To further understand the features, technical means, specific purposes and functions achieved by the present invention, the present invention will be further described in detail below in conjunction with the drawings and specific implementation manners.

[0026] Refer to Figures 1 to 21 , the present invention provides a technical solution: an electrostatic spinning production device for a carbon nanotube composite electrode, including a control host 1. The control host 1 is the overall control mechanism of the device and is arranged on the bottom plate frame. A control panel 101 and control buttons 102 are distributed on the control host 1. The control host 1 completes the electrical control of the entire device through the control panel 101 and control buttons 102. A mixing liquid bin 2 is nested and installed in the control host 1 (as Figure 3 shown). A liquid inlet 201 is opened on the mixing liquid bin 2. A liquid guide port 202 is arranged at the lower end of the mixing liquid bin 2. A corresponding liquid collection port 104 is arranged on the control host 1 close to the liquid guide port 202. An infusion pump 103 is assembled on the liquid collection port 104 (as Figure 4 shown). The infusion pump 103 increases the power for the corresponding liquid collection port 104. If the raw liquid in the mixing liquid bin 2 is sufficient, spinning production can be carried out for a long time.

[0027] On the side of the control host 1, there is a wire mixing bin 3. Inside the wire mixing bin 3, a first servo motor 31 is installed. On the output end of the first servo motor 31, a driving gear 32 is installed. On the side of the driving gear 32, six groups of connecting gears 33 meshing with it are arranged. At the central axis of the connecting gears 33, a spinning disk 34 is connected through a guide shaft. The six groups of connecting gears 33 drive the six groups of spinning disks 34 to spin. When the spinning disk 34 rotates, nanofibers can be collected. The silk thread is rotated and collected through a guide screw rod with a diameter of 0.5 cm and a length of 10 - 15 cm, achieving efficient spinning. At the center of one side of the wire mixing bin 3, a first guide core 35 is installed. A first conductive clip 36 is clamped on the first guide core 35. A first wire 37 is arranged on the first conductive clip 36. The first conductive clip 36 clamps on the first wire 37 to provide current for it (such as Figure 5 and Figure 6 shown).

[0028] The wire mixing bin 3 is connected to a spinning bin 4. Inside the spinning bin 4, six groups of spinning mechanisms 41 distributed in a circular array are arranged. On the spinning bin 4, there is an operation port, and extension plates 44 are installed on both sides of it. A first bin door 43 is arranged on the operation port (such as Figure 3 shown). The distribution positions of the spinning mechanisms 41 correspond to those of the spinning disks 34. The spinning mechanism 41 includes a mounting frame 411, a baffle 412, a nozzle 413, an infusion tube 414, a second conductive clip 415, and a second wire 416. The mounting frame 411 is fixed to the extension plate 44. The baffle 412 is integrally designed with the mounting frame 411. On one side of the baffle 412, a nozzle 413 threadedly connected to it is arranged. On the other side of the baffle 412, an infusion tube 414 is connected. The mixed liquid in the liquid collection port 104 will directly flow into the infusion tube 414. The extension port of the nozzle 413 serves as a guide core, and a second conductive clip 415 is clamped on it. A second wire 416 is connected to the second conductive clip 415 (such as Figure 8 shown). The first conductive clip 36 clamps on the first guide core 35. At the same time, the second conductive clip 415 clamps on the nozzle 413, forming an interactive electric field. The six groups of second conductive clips 415 clamp the nozzle 413 and the first guide core 35 to form six circulating electric fields, achieving zoned spinning.

[0029] A wire guide frame 42 fixedly installed on the inner wall of the spinning bin 4 is provided at the side of the spinning mechanism 41. The wire guide frame 42 is distributed with a first guide roller 421, a second guide roller 422, a third guide roller 423 and a fourth guide roller 424. A burr removing mechanism 425 installed on the wire guide frame 42 is arranged between the second guide roller 422 and the third guide roller 423. The burr removing mechanism 425 removes burrs from the nanofibers after spinning. The burr removing mechanism 425 includes an operation frame 4251, an operation table 4252, a pulling tooth plate 4253, a top frame plate 4254, a driving motor 4255, a driving rod 4256, a cutting mechanism 4257 and a burr collecting gear 4258. The operation frame 4251 is fixed to the wire guide frame 42, and the distribution position of the wire guide frame 42 corresponds to that of the spinning disk 34. The operation table 4252 is arranged on the operation frame 4251. A pulling tooth plate 4253 nested and slidably penetrated through the operation table 4252 is arranged on the operation table 4252. A first limiting magnetic sheet 4253a is installed at the side of the pulling tooth plate 4253, and a second limiting magnetic sheet 4253b is arranged at the bottom end of the pulling tooth plate 4253. Both the first limiting magnetic sheet 4253a and the second limiting magnetic sheet 4253b are magnetically connected to the operation table 4252. The top frame plate 4254 is located at the top of the operation frame 4251. Four groups of burr collecting gears 4258 are distributed on the top frame plate 4254. A transfer gear 4259 meshing with them is distributed between the four groups of burr collecting gears 4258. A driving guide rod 4258a is penetrated through the burr collecting gear 4258. A collecting fan 4258b is installed on the driving guide rod 4258a. A driving motor 4255 is installed at the side of the top frame plate 4254. The output ends of the driving motor 4255 are respectively connected with a first transmission gear 4255a and a first transmission bevel gear 4255b. A driving rod 4256 is arranged under the top frame plate 4254. A clamping gear 4256b is installed at the middle part of the driving rod 4256. A second transmission bevel gear 4256a is arranged at the position where the driving rod 4256 is close to the first transmission bevel gear 4255b. The second transmission bevel gear 4256a meshes with the first transmission bevel gear 4255b. The first transmission gear 4255a and the first transmission bevel gear 4255b on the driving motor 4255 rotate synchronously. The driving rod 4256 and the burr collecting gear 4258 operate, and the cutting mechanism 4257 moves synchronously. Cooperating with the collecting fan 4258b installed on the driving guide rod 4258a, the debris is collected while the burrs are removed.

[0030] The operating frame 4251 is provided with a cutting mechanism 4257. The cutting mechanism 4257 is set into two groups, and the two groups of cutting mechanisms 4257 are symmetrically and staggeredly distributed. The cutting mechanism 4257 includes a rotating shaft 4257a, an arc-shaped frame 4257b, an unfolding tooth 4257c, a linkage rod 4257d, a linkage gear 4257e and a cutting blade 4257f. The rotating shaft 4257a is arranged on the operating frame 4251 and fixedly connected thereto. The arc-shaped frame 4257b penetrates through the rotating shaft 4257a and is rotatably connected thereto. An unfolding tooth 4257c is arranged on the arc-shaped frame 4257b close to the pulling tooth plate 4253, and the unfolding tooth 4257c is in meshing connection with the pulling tooth plate 4253. Linkage rods 4257d are evenly distributed on the arc-shaped frame 4257b. A linkage gear 4257e is installed on the side of the linkage rod 4257d, and a cutting blade 4257f is installed on the linkage rod 4257d. Pulling down the pulling tooth plate 4253 meshes with the unfolding tooth 4257c to drive the arc-shaped frame 4257b to unfold and close. When the arc-shaped frame 4257b is closed, the engaging gear 4256b on the driving rod 4256 contacts the linkage gear 4257e to drive the linkage gear 4257e. The linkage gear 4257e drives the cutting blades 4257f to rotate one by one to cut the burrs on the nanowires.

[0031] The spinning bin 4 is connected to a tension adjustment bin 5 at the other end of the mixing bin 3. An outer runner 51 rotatably connected thereto is arranged on the tension adjustment bin 5. Card holes 52 are evenly opened on the outer runner 51. A tension control mechanism 53 is arranged on the side of the card hole 52. The tension control mechanism 53 includes a first fixing seat 531, a plug rod 532, a pulling handle 533, a second fixing seat 534 and a spring 535. The first fixing seat 531 is fixed to the tension adjustment bin 5. The first fixing seat 531 is internally penetrated with a plug rod 532. The plug rod 532 penetrates through the second fixing seat 534 at the side of the first fixing seat 531. A pulling handle 533 is welded and fixed to the side of the plug rod 532. A spring 535 is installed in the section between the first fixing seat 531 and the second fixing seat 534 of the plug rod 532. One end of the spring 535 close to the second fixing seat 534 is fixed to the surface of the plug rod 532. The plug rod 532 is fixed to the corresponding card hole 52 to realize the fixation of the rotation angle of the outer runner 51.

[0032] Inside the tension adjustment bin 5, there is a tension adjustment mechanism 54 connected to the outer rotating wheel 51. The tension adjustment mechanism 54 includes a first rotating ring 541, which is connected to the outer rotating wheel 51. Six groups of connecting arms 542 rotatably connected thereto are distributed on the first rotating ring 541. A first pin 543 and a second pin 544 are respectively installed at both ends of the connecting arm 542. An adjustment piece 545 is penetrated through the second pin 544. Multiple groups of adjustment holes 546 with different hole diameters are distributed on the adjustment piece 545. The adjustment holes 546 with different diameters are respectively marked as a, b, c, d, e, f on the upper adjustment piece 545. There are six groups of adjustment pieces 545. Each adjustment piece 545 is of a triangular structure and its edge is arc-shaped. A third pin 548 is provided on the adjustment piece 545 and penetrates through and is connected to a second rotating ring 547. The rotation of the outer rotating wheel 51 drives the connecting arm 542 on the first rotating ring 541 to move. When the connecting arm 542 disengages from the second rotating ring 547, it drives the six groups of adjustment pieces 545 to expand synchronously. At this time, the nanowires arranged in the adjustment holes 546 can adjust their own tensions, and the nanowires can flexibly form a taut or loose state.

[0033] The tension adjustment bin 5 is connected to an annealing bin 6. A second bin door 61 is provided on the annealing bin 6. Opening the second bin door 61 enables the threading of the carbon nanowire thread inside the annealing bin 6. At the lower end inside the annealing bin 6, an electrolyte bin 63 is installed. On both sides of the electrolyte bin 63, a first electrode position 64 and a second electrode position 65 are respectively connected. The voltage released by the first electrode position 64 and the second electrode position 65 with the electrolyte as the medium performs electrochemical annealing on the carbon nanowire composite electrode of the spun fiber. In the 2 O 3 direction of V 2 O 5 During the process of electrochemical conversion, the carbon nanowires can act as a "protective structure", effectively preventing the formation of by-products, and constructing a pea pod-shaped nitrogen-doped carbon nanowire-coated amorphous V 2 O 5 microsphere independent electrode material.

[0034] Above the electrolyte bin 63, there is a pushing member mechanism 62. The pushing member mechanism 62 includes a control motor 621, an electric telescopic rod 622, an insulating ring 623 and a sleeve hole 624. The control motor 621 is fixedly connected to the upper surface of the top of the annealing bin 6. At the lower end of the control motor 621, there is an electric telescopic rod 622 located inside the annealing bin 6. An insulating ring 623 is installed on the electric telescopic rod 622. Sleeve holes 624 are distributed inside the insulating ring 623. The insulating ring 623 forms a telescopic structure in the vertical direction with the electrolyte bin 63 through the electric telescopic rod 622. The up and down settlement of the nanowires in the sleeve holes 624 on the insulating ring 623 can immerse the nanowires into the electrolyte bin 63 during production.

[0035] An annealing chamber 6 is connected to a drying chamber 7. A third chamber door 71 is provided on the drying chamber 7. Two groups of exhaust fans 72 are distributed at the top of the drying chamber 7. A filtering mechanism can be set according to the composition of the electrolyte to determine whether it is harmful. This direction is not the improvement point of this solution, and the existing technology is mature, so it has not been expanded too much. First guide frames 73 and second guide frames 74 are respectively provided on both sides of the drying chamber 7. The first guide frame 73 is connected to the annealing chamber 6 and is provided with six first guide holes 731 distributed in a circular array with the center of the first guide frame 73 as the center. Second guide holes 741 corresponding to the first guide holes 731 are provided on the second guide frame 74. A drying cover 75 is installed on the second guide frame 74. A wire guide chamber 76 is connected to the side of the second guide frame 74. Six wire holes 761 corresponding to the second guide holes 741 are distributed on the wire guide chamber 76. A wire roller 762 is installed in the middle of the wire hole 761. Heating wires 77 and heating fans 78 are respectively installed inside the drying cover 75 close to one end of the wire guide chamber 76. The operation of the heating wires 77 and heating fans 78 in the drying cover 75 can fully and evenly conduct heat flow in every direction inside the drying chamber 7. When the nanowires located outside the drying cover 75 pass by, the heat flow transpires on the moving nanowires to complete drying.

[0036] A side support body 8 is installed close to the drying chamber 7 on the bottom plate frame. A collection device 9 is provided on the side support body 8. A second servo motor 91 fixedly installed with the side support body 8 is provided on the collection device 9. A first steering gear 92 is installed at the output end of the second servo motor 91. Six second steering gears 96 meshing with the first steering gear 92 are connected to the first steering gear 92. A rotating rod 94 is connected to the second steering gear 96. A limiting frame 93 fixed to the side support body 8 is penetrated through the rotating rod 94. A threaded portion is provided on the rotating rod 94 and a positioning clamping plate 95 matching with it is connected to the threaded portion. The collected drum collector or the prepared collector is installed inside the rotating rod 94. The installation of the positioning clamping plate 95 on the rotating rod 94 fixes and clamps the collector. As the rotating rod 94 rotates, the nanowires are wound up.

[0037] Referring to Figures 1 to 21 , the present invention provides a technical solution: an electrostatic spinning production preparation method for a carbon nanowire composite electrode. A ratio solution mixed with V 2 O 3 and nitrogen-doped carbon nanowires is placed into the mixing liquid chamber 2. The mixed liquid is guided into the infusion tube 414 through the infusion pump 103 on the control host 1; The first conductive clip 36 clamps the first guide core 35, and the second conductive clip clamps another guide core on the nozzle to form an electric field. The solution in the infusion tube 414 is sprayed out through the nozzle for spinning, and V 2 O 3 is confined in the carbon nanowires; The spinning disk 34 rotates to collect the ejected spinning, and the spinning wire is collected by a spinning rod with a diameter of 0.5 cm and a length of 10-15 cm, and passes through the first guide roller 421 and the second guide roller 422 in an "S"-shaped trajectory, and the burrs on the edges of the nanowires after spinning are removed by a burr removal mechanism 425; According to the thickness and diameter of the spun product, the corresponding adjustment hole 546 on the adjustment plate 545 is selected and passed through, and then through the sleeve hole 624, the pusher mechanism 62 is opened, and the insulating ring 623 passing through the nanowire is sunk into the electrolyte tank 63 for electrochemical annealing. 2 O 3 To V 2 O 5 During the electrochemical conversion process, carbon nanowires can act as a "protective structure" to effectively prevent the formation of by-products, constructing a pea-pod-shaped nitrogen-doped carbon nanowire-coated amorphous V 2 O 5 Microsphere free-standing electrode materials; The nanowires that have completed electrochemical annealing continue to pass through the first guide hole 731 and the second guide hole 741 . The heating wire 77 and the heating fan 78 in the evaporation cover 75 cooperate to form hot air for rapid drying, and the water vapor is discharged through the exhaust fan 72 .

[0038] The dried nanowires pass through the wire hole 761 and fit onto the upper limit of the wire roller 762. The collected drum collector or the prepared collector is installed in the rotating rod 94 and fixed by the positioning clamp 95. As the rotating rod 94 rotates, the nanowires are wound up.

[0039] Working principle: Before the equipment starts spinning production, the first chamber door 43, the second chamber door 61 and the third chamber door 71 will be opened one by one, and the electrolyte will be injected into the electrolyte chamber 63, that is, the basic preparation for the operation of the equipment before spinning is completed; Mix with V 2 O 3 The original solution of nitrogen-doped carbon nanoparticles is placed in the mixed liquid tank 2, the liquid guide port 202 is connected to the liquid receiving port 104, and the infusion pump 103 pumps the liquid into the infusion tube 414. The capacity of the mixed liquid tank 2 is large and can accommodate more spinning stock solution. The liquid inlet 201 on it can also be directly opened to directly inject and replenish liquid, so as to avoid the injection and replenishment affecting the operation of the equipment; The first servo motor 31 drives the driving gear 32 to rotate, which meshes with and drives the six groups of guiding gears 33 around it to continuously rotate the spinning disks 34 installed on them. When the spinning disks 34 rotate, the air flow generated forms a vortex. The nozzle 413 receives the spinning solution input from the infusion tube 414. The first conductive clip 36 clamps the first guide core 35, and the second conductive clip 415 clamps another guide core on the nozzle 413 to form an electric field. The six groups of spinning mechanisms 41 control the formation of six groups of circulating and relatively independent electric fields. The solution in the infusion tube 414 is ejected through the nozzle 413 for spinning, and the nanofibers spun are concentrated towards the spinning disks 34. A guide wire rod with a diameter of 0.5 cm and a length of 10 - 15 cm is used to collect the rotating filaments near the spinning disks 34. After being pulled, a single filament is formed and gradually tightened as the spinning disks 34 rotate. The formed nanowire passes through the first guide roller 421 and the second guide roller 422 in an "S" - shaped trajectory; Similarly, it then passes through between the second guide roller 422 and the third guide roller 423 in an "S" - shaped trajectory, pushing the pulling tooth plate 4253. The teeth on it contact the unfolding teeth 4257c. When the pulling tooth plate 4253 is pushed to the vertex, the arc - shaped frame 4257b is fully unfolded, and the second limit magnetic sheet 4253b is adsorbed and fixed on the operating table 4252 for upper limit. When the pulling tooth plate 4253 is pulled down to the vertex, the arc - shaped frame 4257b is fully closed, and the first limit magnetic sheet 4253a is magnetically attracted to the operating table 4252 for fixed limit. When the arc - shaped frame 4257b is closed, the linkage gear 4257e at the top is stuck on the clamping gear 4256b installed in the middle of the driving rod 4256. Through the clamping gear 4256b, all the linkage gears 4257e are driven, driving the cutting blades 4257f on the linkage rod 4257d to rotate. The rotation directions of two adjacent cutting blades 4257f are opposite, and the contact between two adjacent cutting blades 4257f directly cuts off the excess burrs; When the arc - shaped frame 4257b is unfolded, it is convenient for threading the carbon nanotubes. When it is closed, the burr - removing mechanism 425 operates. The driving motor 4255 drives the first transmission gear 4255a and the first transmission bevel gear 4255b to rotate. The first transmission gear 4255a drives the burr - collecting gear 4258 to rotate. The driving guide rod 4258a installed inside the burr - collecting gear 4258 drives the collecting fan 4258b to rotate, collecting the removed burr tissues and entering the collecting bag 4258c for collection.

[0040] According to the thickness diameter of the finished nanowire spinning product, select and pass through the corresponding adjustment holes 546 on the adjustment piece 545. When adjusting the tension of the nanowire, rotate the outer runner 51. When fixing the rotation angle of the outer runner 51, pull the pull handle 533, and the insert rod 532 will leave the original clamping hole 52. After the rotation angle of the outer runner 51 is completed, through the resilience of the spring 535, the insert rod 532 can be limited in the existing clamping hole 52. The rotation of the outer runner 51 drives the connecting arm 542 on the first rotating ring 541 to move. The connecting arm 542 disengages from the second rotating ring 547 to complete the rotation, driving the six groups of adjustment pieces 545 to expand synchronously. The nanowire arranged in the adjustment hole 546 can adjust its own tension according to the position of the adjustment piece 545, and can flexibly form a tight or loose state. The nanowire also passes through the sleeve hole 624 and enters the first guide hole 731 synchronously; Precisely control the telescopic dimension of the electric telescopic rod 622 through the control panel 101 and the control button 102 on the control host 1. Immerse the insulating ring 623 on the electric telescopic rod 622 into the electrolyte tank 63. There is electrolyte in the electrolyte tank 63. The voltage released by the first electrode position 64 and the second electrode position 65 with the electrolyte as the medium performs electrochemical annealing on the spun carbon nanowire composite electrode. At V 2 O 3 towards V 2 O 5 During the process of electrochemical conversion, the carbon nanowire acts as a "protective structure", effectively preventing the formation of by-products, and constructing a pea pod-shaped nitrogen-doped carbon nanowire-coated amorphous V 2 O 5 microsphere independent electrode material; The nanowire that has completed electrochemical annealing continues to pass through the first guide hole 731 and the second guide hole 741 and enters the drying chamber 7. The heating wire 77 and the heating fan 78 in the evaporation cover 75 are synchronously turned on and operate in cooperation with each other to form hot air spreading around the evaporation cover 75 to quickly dry the carbon nanowire immersed in the electrolyte. The water vapor is discharged through the exhaust fan 72; The dried nanowire passes through the wire hole 761 and is limited by fitting on the wire roller 762. Take out the collector, insert the collector into the rotating rod 94, and through the threaded connection between the positioning clamp 95 and the rotating rod 94, clamp and fix the collector on the collecting device 9. Install the six groups of collectors one by one together. As the multiple groups of rotating rods 94 rotate, the nanowire is efficiently prepared and electrochemically annealed, and the processed carbon nanowire composite electrode is wound up.

[0041] The above embodiments merely represent one or several implementation manners of the present invention. The description thereof is relatively specific and detailed, but it should not be construed as a limitation on the scope of the patent for the present invention. It should be noted that for those of ordinary skill in the art, without departing from the concept of the present invention, several modifications and improvements can still be made, and these all fall within the protection scope of the present invention. Therefore, the protection scope of the patent for the present invention shall be subject to the appended claims.

Claims

1. An electrospinning production device for carbon nanowire composite electrodes, characterized in that: The device comprises a control host (1), the control host (1) being a master control mechanism of the device and arranged on a bottom frame, a mixed liquid bin (2) being nested and installed inside the control host (1), and a mixed fiber bin (3) being arranged on the side of the control host (1); The mixing chamber (3) is connected to a spinning chamber (4), and six groups of spinning mechanisms (41) arranged in a circular array are arranged in the spinning chamber (4). A wire guide frame (42) fixedly mounted to the inner wall of the spinning chamber (4) is arranged on the side of the spinning mechanism (41), and the other end of the spinning chamber (4) located at the mixing chamber (3) is connected to a tension adjustment chamber (5); A first guide roller (421), a second guide roller (422), a third guide roller (423) and a fourth guide roller (424) are distributed on the guide wire frame (42); a burr removal mechanism (425) mounted on the guide wire frame (42) is provided between the second guide roller (422) and the third guide roller (423); the burr removal mechanism (425) removes burrs from the nanowires after spinning; The tension adjustment chamber (5) is connected to an annealing chamber (6), an electrolyte chamber (63) is installed at the lower end of the annealing chamber (6), the annealing chamber (6) is connected to a drying chamber (7), a side support body (8) is installed on the bottom frame close to the drying chamber (7), and a collecting device (9) is provided on the side support body (8).

2. The electrospinning production equipment for carbon nanowire composite electrodes according to claim 1, characterized in that: The control host (1) is provided with a control panel (101) and control buttons (102). The control host (1) completes electrical control of the entire device through the control panel (101) and the control buttons (102). The mixed liquid tank (2) is provided with a liquid inlet (201). The lower end of the mixed liquid tank (2) is provided with a liquid guide port (202). The control host (1) is provided with a corresponding liquid receiving port (104) close to the liquid guide port (202). The liquid receiving port (104) is equipped with an infusion pump (103).

3. The electrospinning production equipment for carbon nanowire composite electrodes according to claim 1, characterized in that: A first servo motor (31) is installed in the mixing chamber (3); a driving gear (32) is installed on the output end of the first servo motor (31); six groups of guide gears (33) meshing with the driving gear (32) are arranged on the side of the driving gear (32); a spinning disk (34) is connected to the central axis of the guide gear (33) via a guide shaft; a first guide core (35) is installed at the center of one side of the mixing chamber (3); a first conductive clip (36) is clamped on the first guide core (35); and a first conductive wire (37) is arranged on the first conductive clip (36).

4. The electrospinning production equipment for carbon nanowire composite electrodes according to claim 1, characterized in that: The spinning chamber (4) is provided with an operation port, and extension plates (44) are installed on both sides of the operation port. A first chamber door (43) is provided on the operation port. The spinning mechanism (41) corresponds to the distribution position of the spinning disk (34). The spinning mechanism (41) comprises a mounting frame (411), a baffle (412), a nozzle (413), an infusion tube (414), a second conductive clip (415) and a second conductive wire (416). The mounting frame (411) is fixed to the extension plate (44). The baffle (412) and the mounting frame (411) are designed as an integral whole. A nozzle (413) threadedly connected to the baffle (412) is provided on one side of the baffle (412), and an infusion tube (414) is connected to the other side of the baffle (412). The extension port of the nozzle (413) serves as a guide core, on which a second conductive clip (415) is clamped, and the second conductive clip (415) is connected to the second conductive clip (416).

5. The electrospinning production equipment for carbon nanowire composite electrodes according to claim 4, characterized in that: The burr removal mechanism (425) comprises an operating frame (4251), an operating table (4252), a pulling tooth plate (4253), a top frame plate (4254), a driving motor (4255), a driving rod (4256), a cutting mechanism (4257) and a burr collecting gear (4258); the operating frame (4251) is fixed to a wire guide frame (42); the wire guide frame (42) and the spinning disk (34) are arranged at corresponding positions; the operating table (4252) is arranged on the operating frame (4251); and the operating table (4252) is penetrated by A pulling tooth plate (4253) is provided which is nested and slidable therewith, a first limiting magnetic plate (4253a) is installed at the side of the pulling tooth plate (4253), a second limiting magnetic plate (4253b) is installed at the bottom end of the pulling tooth plate (4253), the first limiting magnetic plate (4253a) and the second limiting magnetic plate (4253b) are both magnetically connected to the operating table (4252), the top frame plate (4254) is located at the top of the operating frame (4251), and a driving motor (4255) is installed on the side of the top frame plate (4254). ), the output end of the driving motor (4255) is respectively connected to the first transmission gear (4255a) and the first transmission bevel gear (4255b), the lower side of the top frame plate (4254) is provided with a driving rod (4256), the middle part of the driving rod (4256) is provided with a clamping gear (4256b), the driving rod (4256) is provided with a second transmission bevel gear (4256a) close to the first transmission bevel gear (4255b), and the second transmission bevel gear (4256a) is meshed with the first transmission bevel gear (4255b) The operating frame (4251) is provided with a cutting mechanism (4257), the top frame plate (4254) is provided with four groups of burr collecting gears (4258), and transfer gears (4259) meshing with the four groups of burr collecting gears (4258) are distributed between the four groups of burr collecting gears (4258), a driving guide rod (4258a) is provided through the burr collecting gear (4258), a collecting fan (4258b) is installed on the driving guide rod (4258a), and the burr collecting gear (4258) is meshed with the first transmission gear (4255a).

6. The electrospinning production equipment for carbon nanowire composite electrodes according to claim 5, characterized in that: The cutting mechanism (4257) is provided in two groups, and the two groups of the cutting mechanism (4257) are symmetrically staggered. The cutting mechanism (4257) comprises a rotating shaft (4257a), an arc frame (4257b), an expansion tooth (4257c), a connecting rod ( 4257d), a linkage gear (4257e) and a cutting blade (4257f), the rotating shaft (4257a) is arranged on the operating frame (4251) and is fixedly connected thereto, the arc frame (4257b) passes through the rotating shaft (4257a) and is rotatably connected thereto, the arc frame (4257b) is provided with an expansion tooth (4257c) close to the pulling tooth plate (4253), the expansion tooth (4257c) is meshingly connected with the pulling tooth plate (4253), the linkage rods (4257d) are evenly distributed on the arc frame (4257b), the side of the linkage rod (4257d) is installed with a linkage gear (4257e), and the cutting blade (4257f) is installed on the linkage rod (4257d).

7. The electrospinning production equipment for carbon nanowire composite electrodes according to claim 1, characterized in that: The tension adjustment bin (5) is provided with an outer rotating wheel (51) rotatably connected thereto, the outer rotating wheel (51) is evenly provided with clamping holes (52), the side of the clamping holes (52) is provided with a tension adjustment mechanism (53), the tension adjustment mechanism (53) comprises a first fixed seat (531), an insertion rod (532), a pull handle (533), a second fixed seat (534) and a spring (535), the first fixed seat (531) is fixed to the tension adjustment bin (5), the first fixed seat (531) is fixed to the tension adjustment bin (5), and the first fixed seat (534) is fixed to the tension adjustment bin (5). The seat (531) is provided with an insertion rod (532) penetrating therein, the insertion rod (532) is provided with a second fixing seat (534) penetrating therein at the side of the first fixing seat (531), a pull handle (533) is welded and fixed to the side of the insertion rod (532), a spring (535) is installed on the insertion rod (532) between the first fixing seat (531) and the second fixing seat (534), and one end of the spring (535) close to the second fixing seat (534) is fixed to the surface of the insertion rod (532); A tension adjustment mechanism (54) connected to the outer rotating wheel (51) is arranged in the tension adjustment chamber (5), and the tension adjustment mechanism (54) comprises a first rotating ring (541), the first rotating ring (541) being connected to the outer rotating wheel (51), six groups of connecting arms (542) rotatably connected to the first rotating ring (541) are arranged on the first rotating ring (541), a first latch (543) and a second latch (544) are respectively mounted at two ends of the connecting arm (542), an adjustment sheet (545) is penetrated and connected to the second latch (544), a plurality of adjustment holes (546) with different aperture diameters are arranged on the adjustment sheet (545), six groups of the adjustment sheets (545) are arranged, a single adjustment sheet (545) is a triangular structure and its edge is an arc, and a third latch (548) is arranged on the adjustment sheet (545) and penetrated and connected to the second rotating ring (547).

8. The electrospinning production equipment for carbon nanowire composite electrodes according to claim 1, characterized in that: The annealing chamber (6) is provided with a second chamber door (61); the first electrode position (64) and the second electrode position (65) are respectively connected to the two sides of the electrolyte chamber (63); a pusher mechanism (62) is provided above the electrolyte chamber (63); the pusher mechanism (62) comprises a control motor (621), an electric telescopic rod (622), an insulating ring (623) and a sleeve hole (624); the control motor (621) is fixedly connected to the top upper surface of the annealing chamber (6); the lower end of the control motor (621) is provided with an electric telescopic rod (622) located in the annealing chamber (6); the electric telescopic rod (622) is mounted with an insulating ring (623); the insulating ring (623) is provided with sleeve holes (624); the insulating ring (623) forms a vertical telescopic structure with the electrolyte chamber (63) through the electric telescopic rod (622); The drying chamber (7) is provided with a third chamber door (71), two groups of exhaust fans (72) are distributed at the top of the drying chamber (7), a first guide frame (73) and a second guide frame (74) are respectively provided on both sides of the drying chamber (7), the first guide frame (73) is connected to the annealing chamber (6) and is provided with six groups of first guide holes (731) distributed in a circular array with the first guide frame (73) as the center, and the second guide frame (74) is provided with six groups of first guide holes (731) corresponding to the first guide holes (731). A second guide hole (741) is formed on the second guide frame (74), a steam drying cover (75) is installed on the second guide frame (74), a wire bin (76) is connected to the side of the second guide frame (74), six groups of wire holes (761) corresponding to the second guide holes (741) are distributed on the wire bin (76), a wire roller (762) is installed at the middle of the wire holes (761), and a heating wire (77) and a heating fan (78) are respectively installed inside one end of the steam drying cover (75) close to the wire bin (76).

9. The electrospinning production equipment for carbon nanowire composite electrodes according to claim 1, characterized in that: The collecting device (9) is provided with a second servo motor (91) fixedly mounted on the side bracket body (8); a first steering gear (92) is mounted at the output end of the second servo motor (91); the first steering gear (92) is connected to six groups of second steering gears (96) meshing therewith; the second steering gear (96) is connected to a rotating rod (94); a limiting frame (93) fixed to the side bracket body (8) is penetrated through the rotating rod (94); the rotating rod (94) is provided with a thread on which a positioning clamp (95) matching with the thread is connected.

10. A method for preparing a carbon nanowire composite electrode by electrospinning, comprising an electrospinning production device for a carbon nanowire composite electrode as claimed in any one of claims 1 to 9, characterized in that: A mixed solution of V2O3 and nitrogen-doped carbon nanoparticles is placed in a mixed liquid tank (2), and the mixed liquid is guided into an infusion tube (414) via an infusion pump (103) on a control host (1); The first conductive clamp (36) clamps the first conductive core (35), and the second conductive clamp (415) clamps another conductive core on the nozzle (413) to form an electric field, and the solution in the infusion tube (414) is sprayed out through the nozzle for spinning, thereby confining V2O3 in the carbon nanowires; The spinning disk (34) rotates to collect the ejected spinning fibers, and the fibers are collected by rotating through a wire guide rod having a diameter of 0.5 cm and a length of 10-15 cm, and pass through a first guide roller (421) and a second guide roller (422) in an "S"-shaped trajectory, and burrs on the edges of the nanowires after spinning are removed through a burr removal mechanism (425); According to the thickness and diameter of the finished spinning product, the corresponding adjustment hole (546) on the adjustment sheet (545) is selected and passed through, and then passed through the sleeve hole (624), the pusher mechanism (62) is opened, and the insulating ring (623) passing through the nanowire is sunk into the electrolyte tank (63) for electrochemical annealing. In the process of electrochemical conversion of V2O3 to V2O5, the carbon nanowire acts as a "protective structure" to effectively prevent the formation of by-products, thereby constructing a pea pod-shaped nitrogen-doped carbon nanowire-coated amorphous V2O5 microsphere independent electrode material; The nanowires that have completed the electrochemical annealing continue to pass through the first guide hole (731) and the second guide hole (741), and the heating wire (77) and the heating fan (78) in the steam drying cover (75) cooperate to form hot air for rapid drying, and the water vapor is discharged through the exhaust fan (72); The dried nanowires pass through the wire hole (761) and fit onto the upper limit of the wire roller (762). The collected drum collector or the prepared collector is installed in the rotating rod (94). The collector is fixed by the positioning clamp (95). As the rotating rod (94) rotates, the nanowires are rolled up.

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