Complexing agent for chrome-free tanning of leather and preparation method of complexing agent

By preparing a complexing agent, the problems of low precipitation points and environmental pollution of zirconium tanning and titanium tanning agents in leather tanning are solved, and high-performance chrome-free tanning is achieved, which improves leather performance and reduces environmental impact.

CN120350182APending Publication Date: 2025-07-22WENZHOU UNIV
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Patent Information

Application Number
CN202310581995.4
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-05-19
Publication Date
2025-07-22

AI Technical Summary

Technical Problem

The existing zirconium tanning and titanium tanning agents have problems such as low precipitation points, strong hydrolysis, strict tanning environment requirements, and uneven tanning effects in leather tanning, resulting in a gap between leather performance and chrome tanning agents, and the tanning process is polluted to the environment.

Method used

A complexing agent is prepared by reactions such as glycol polyols, unsaturated conjugated anhydrides, catalysts and anhydrous sodium sulfite through a specific temperature and time to improve the precipitation point and alkali resistance of zirconium tanning and titanium tanning agents and improve leather performance.

Benefits of technology

The prepared complexing agent can significantly improve the precipitation point of zirconium tanning and titanium tanning agent, improve the performance of the leather, make the leather shrinkage temperature reach above 85℃, reduce environmental pollution, and be easy to obtain.

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Abstract

The invention discloses a complexing agent for chrome-free tanning of leather. The complexing agent is prepared by reacting the following components in parts by mass: 50 to 100 parts of glycol polyol, 50 to 200 parts of unsaturated conjugated anhydride, 0.1 to 0.5 part of catalyst, 50 to 300 parts of anhydrous sodium sulfite and 150 to 600 parts of water. Aiming at the characteristics of zirconium tanning and titanium tanning, the invention provides the complexing agent for chrome-free tanning of leather, which has the advantages of easily available raw materials, simple production process operation and small environmental pollution.
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