Preparation method and application of iridium-based catalyst with asymmetric structure

By preparing asymmetric iridium-based catalysts, the problem of structural symmetry limitations of existing iridium-based catalysts was solved, efficient and low-cost hydrogen production by water electrolysis was achieved, and the application of clean energy was promoted.

CN120683533APending Publication Date: 2025-09-23HAINAN UNIV
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Patent Information

Application Number
CN202511137463.7
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-08-14
Publication Date
2025-09-23

AI Technical Summary

Technical Problem

The symmetrical structure of existing iridium-based catalysts makes it difficult to fully expose active sites, making it difficult to improve catalytic performance. In addition, their high cost and poor stability limit their application in hydrogen production by water electrolysis.

Method used

An asymmetric iridium-based catalyst was prepared using a one-pot method and air calcination technology. By introducing lanthanide metal salts and glucose urea, the electronic structure and coordination environment of the Ir active site were regulated, the symmetry of IrO2 was broken, an asymmetric structure was formed, and the activity and stability of the catalyst were enhanced.

Benefits of technology

It significantly improves the catalytic activity and chemical stability of the catalyst, reduces the preparation cost, extends the service life, improves the efficiency of hydrogen production by water electrolysis, and promotes the development and utilization of clean energy.

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Abstract

The invention discloses a preparation method and application of an iridium-based catalyst with an asymmetric structure, and belongs to the technical field of preparation of electrochemical catalysts. The iridium-based catalyst with the asymmetric structure is prepared by adopting a one-pot method and an air calcination strategy, the Ir-O-Ir symmetric structure can be broken, and the local coordination environment of IrO2 can be changed, so that the catalytic activity of the catalyst is greatly improved, the OER reaction rate is increased, and the development of a water electrolysis hydrogen production technology is promoted.
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