Method for synthesizing material for lithium ion battery consisting of nanoporous lithium iron phosphate particles

By mixing lithium, iron and phosphorus sources with carbon nanomaterials in a solvent to form a precipitation solution and calcining it, the complexity and safety issues of preparing nanoporous lithium iron phosphate particles in the existing technology are solved, and efficient and economical preparation of nanoporous lithium iron phosphate particles is achieved, thereby improving the electrochemical performance of lithium-ion batteries.

CN120752197APending Publication Date: 2025-10-03OCP SA +1
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Patent Information

Application Number
CN202380082207.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2022-09-29
Filing Date
2023-10-02
Publication Date
2025-10-03

AI Technical Summary

Technical Problem

Existing technologies make it difficult to prepare nanoporous lithium iron phosphate particles efficiently and economically on an industrial scale, and there are safety hazards and complex synthesis steps.

Method used

A single co-precipitation synthesis step is used to mix a lithium source, an iron (II) source, a phosphorus source and carbon nanomaterials in a solvent to form a precipitation solution, which is then calcined to form nanoporous lithium iron phosphate particles. This avoids the use of toxic organic solvents and reducing gases and is carried out under near-ambient conditions.

Benefits of technology

The method simplifies the synthesis steps on an industrial scale, reduces costs, and improves the electrical conductivity and lithium ion transport performance of nanoporous lithium iron phosphate particles, making them suitable for high-current charging and discharging.

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Abstract

The invention relates to a method for synthesizing a material for lithium ion batteries consisting of nanoporous lithium iron phosphate particles (1), said method comprising the following steps: (E1) forming a precipitation solution by mixing a lithium source (4), an iron (II) source (5), a phosphorus source (6), a reducing agent (8) and a carbon nanospecies (7) in a solvent, such that lithium, iron and phosphorus are co-precipitated in the form of particles around the carbon nanomaterial, referred to as LFP / C particles (9), namely lithium iron phosphate comprising carbon nanomaterial; (E2) separating LFP / C particles (9) from the precipitation solution; (E3) drying the LFP / C particles (9); (E4) calcining the LFP / C particles (9) to decompose the carbon nanomaterial (7) contained in the particles, the decomposition of the nanomaterial (7) creating nanopores (3) within the lithium iron phosphate particles.
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