Electrochemical detection of monochloramine and / or ammonia

By combining electrochemical sensors and Berthelot chemical reactions with electrochemical voltammetry, the problems of convenience and accuracy in the detection of monochloramine and ammonia in liquid samples have been solved, achieving highly sensitive concentration determination and making it suitable for rapid analysis in various environments.

CN121844201APending Publication Date: 2026-04-10PALINTEST
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Patent Information

Application Number
CN202480058948.4
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2023-09-14
Filing Date
2024-09-12
Publication Date
2026-04-10

AI Technical Summary

Technical Problem

Existing methods are difficult to efficiently and conveniently detect and quantify the concentrations of monochloramine and ammonia in liquid samples, especially under different environments, and are easily affected by free chlorine, dichloramine or trichloramine.

Method used

A device and method based on electrochemical sensors were adopted, utilizing the Berthelot chemical reaction, and a coupling agent containing phenol derivatives and transition metal-based complexes was coated on the working electrode. This was combined with electrochemical voltammetry, especially differential pulse voltammetry, to achieve highly sensitive determination of monochloramine and ammonia.

Benefits of technology

A high-precision, portable electrochemical analysis system is provided, which can accurately determine the concentration of monochloramine and ammonia over a wide range, avoiding interference from other chloramines, and is suitable for rapid detection in various environments.

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Abstract

An apparatus and method for determining the presence or amount of monochloramine and / or ammonia. The devices and methods utilize an electrochemical sensor that includes a working electrode, a reference electrode, and a counter electrode. The working electrode is coated with a formulation specifically for the analysis of monochloramine and / or ammonia comprising reagents associated with the Berthelot reaction to produce an indophenol product for electrochemical detection by voltammetry, in particular differential pulse voltammetry.
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