Crystal form regulation and production process of high-temperature-resistant aramid pulp

By using a binary proton-competitive solvent system and high-speed shear forming technology, the problem of micropore defects caused by solvent layer retention was solved, and aramid pulp with high temperature resistance was prepared, achieving an improvement in high-order crystal structure and thermal stability.

CN122215097APending Publication Date: 2026-06-16烟台泰和兴材料科技股份有限公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
烟台泰和兴材料科技股份有限公司
Filing Date
2026-05-19
Publication Date
2026-06-16

AI Technical Summary

Technical Problem

In the existing pure sulfuric acid spinning process for preparing high-temperature resistant aramid pulp, the solvent layer remains during the solidification stage, leading to micropores and amorphous defects, which affect the structural stability of the material at high temperatures.

Method used

A binary proton-competitive solvent system was used to prepare aramid pulp with a Form-II crystal structure by mixing concentrated sulfuric acid and polyphosphate to form a metastable solvent and combining it with high-speed shear forming.

Benefits of technology

It achieves a highly ordered crystal structure, avoids solvent retention, improves the thermal stability and specific surface area of ​​the material at high temperatures, simplifies the process flow, and ensures consistent product quality.

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Abstract

The application relates to the technical field of high-molecular fiber manufacturing, and discloses a crystal form regulation and manufacturing process of high-temperature-resistant aramid pulp, which comprises the following steps: dispersing 2.5% to 5.5% polyphosphoric acid in concentrated sulfuric acid to prepare a mixed solvent at 60 DEG C to 80 DEG C; dissolving poly-p-phenyleneterephthalamide to construct a metastable anisotropic liquid crystal spinning stock solution; and pouring the stock solution into a low-temperature coagulation bath to perform shearing coagulation. The metastable state characteristics of the binary solvent system under a specific ratio are utilized, the stock solution is rapidly desolvated and crystallized at the moment of coagulation, a high-order Form-II crystal structure is formed, the problem of crystal lattice defects caused by solvent residues is solved, and the high-temperature resistance of the pulp is improved.
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