Organic electroluminescent elements and electronic devices
Patent Information
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- IDEMITSU KOSAN CO LTD
- Filing Date
- 2026-02-17
- Publication Date
- 2026-06-23
AI Technical Summary
【0044】 本発明の一態様によれば、性能が向上した有機エレクトロルミネッセンス素子を提供できる。また、本発明の一態様によれば、発光効率が向上した有機エレクトロルミネッセンス素子を提供できる。また、本発明の一態様によれば、当該有機エレクトロルミネッセンス素子を搭載した電子機器を提供できる。
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Figure 2026102576000001_ABST
Abstract
Claims
1. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Chemistry 1】 (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by -COOR 802 a group represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, The group is represented by the general formula (11) above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11), If there are multiple groups represented by the general formula (11), the multiple groups represented by the general formula (11) may be identical or different from each other. L 101 teeth, Single bond, or A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, Ar 101 These are substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms. mx is 0, 1, 2, 3, 4, or 5. Ar 101 This is not a substituted or unsubstituted pyrenyl group, L 101 This is not a substituted or unsubstituted pyrenylene group, R is not a group represented by the general formula (11) mentioned above. 101 ~R 110 As a substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, it is not a substituted or unsubstituted pyrenyl group, L 101 If there are two or more, then there are two or more L 101 They are either identical or different from each other. Ar 101 If there are two or more Ar 101 They are either identical or different from each other. The asterisk (*) in general formula (11) indicates the bonding position with the pyrene ring in general formula (1). 【Chemistry 2】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
2. In the organic electroluminescent element according to claim 1, mx is 1, 2, 3, 4, or 5. at least one L 101 This is at least one arylene group selected from the group consisting of substituted or unsubstituted phenylene groups, substituted or unsubstituted biphenylene groups, substituted or unsubstituted terphenylene groups, substituted or unsubstituted naphthylene groups, substituted or unsubstituted fluoroorangeyl groups, and substituted or unsubstituted phenanthrylene groups. Organic electroluminescent element.
3. In the organic electroluminescent element according to claim 1 or claim 2, Ar 101 This is an aryl group in which four or more rings are fused together. Organic electroluminescent element.
4. In an organic electroluminescent element according to any one of claims 1 to 3, The group represented by the above general formula (11) is the group represented by the following general formula (111): Organic electroluminescent element. 【Transformation 3】 (In the above general formula (111), X 1 CR 123 R 124 And, L 111 and L 112 Each of them operates independently. Single bond, or A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, ma is 0, 1, 2, 3, or 4. mb is 0, 1, 2, 3, or 4. ma + mb is 0, 1, 2, 3, or 4. Ar 101 This is Ar in the general formula (11) 101 It is synonymous with, R 121 , R 122 , R 123 , and R 124 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, or A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, mc is 3, The three R's 121 They are either identical or different from each other. md is 3, The three R's 122 They are either identical or different to one another.
5. In the organic electroluminescent element according to claim 4, ma is 0, 1, or 2. mb is 0, 1, or 2. Organic electroluminescent element.
6. In the organic electroluminescent element according to claim 4 or claim 5, ma is either 0 or 1. mb is either 0 or 1. Organic electroluminescent element.
7. In an organic electroluminescent element according to any one of claims 1 to 6, Ar 101 teeth, Substituted or unsubstituted phenyl groups, Substituted or unsubstituted naphthyl groups, Substituted or unsubstituted biphenyl groups, Substituted or unsubstituted terphenyl groups, A substituted or unsubstituted phenanthryl group, A substituted or unsubstituted fluorenyl group, Organic electroluminescent element.
8. In an organic electroluminescent element according to any one of claims 1 to 7, Ar 101 However, if the substituted ring-forming aryl group has 6 to 50 carbon atoms, Ar 101 The substituents on the aryl group are not heterocyclic groups. Organic electroluminescent element.
9. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least two groups represented by the following general formula (11), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Chemistry 4】 (In the above general formula (1), R 101 ~R 110 are each independently hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by -COOR 802 a group represented by halogen atom, Cyano group, Nitro group, or The group is represented by the general formula (11) above, However, R 101 ~R 110 Two or more of these are groups represented by the general formula (11), If there are multiple groups represented by the general formula (11), the multiple groups represented by the general formula (11) may be identical or different from each other. L 101 It is a single bond, Ar 101 These are heterocyclic groups with 5 to 50 substituted or unsubstituted ring-forming atoms. mx is 0, Ar 101 If there are two or more Ar 101 They are either identical or different from each other. The asterisk (*) in general formula (11) indicates the bonding position with the pyrene ring in general formula (1). 【Transformation 5】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
10. In the organic electroluminescent element according to claim 9, R 101 ~R 110 Two or three of these are groups represented by the general formula (11), Organic electroluminescent element.
11. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Transformation 6】 (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, Substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, or The group is represented by the general formula (11) above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11), If there are multiple groups represented by the general formula (11), the multiple groups represented by the general formula (11) may be identical or different from each other. L 101 This is a divalent heterocyclic group with 5 to 50 substituted or unsubstituted ring-forming atoms. Ar 101 These are heterocyclic groups with 5 to 50 substituted or unsubstituted ring-forming atoms. mx is 1, 2, 3, 4, or 5. R is not a group represented by the general formula (11) mentioned above. 101 ~R 110 As a substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, it is not a substituted or unsubstituted pyrenyl group, L 101 If there are two or more, then there are two or more L 101 They are either identical or different from each other. Ar 101 If there are two or more Ar 101 They are either identical or different from each other. The asterisk (*) in general formula (11) indicates the bonding position with the pyrene ring in general formula (1). 【Transformation 7】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
12. In the organic electroluminescent element according to claim 11, at least one L 101 This is a divalent heterocyclic group selected from the group consisting of a substituted or unsubstituted dibenzofranzyl group, a substituted or unsubstituted dibenzothiophenediyl group, and a substituted or unsubstituted carbazolediyl group. Organic electroluminescent element.
13. In the organic electroluminescent element according to claim 11 or claim 12, Ar 101 It is a heterocyclic group formed by the fusion of four or more rings. Organic electroluminescent element.
14. In the organic electroluminescent element according to claim 13, R 101 ~R 110 One of them is the group represented by the general formula (11), Organic electroluminescent element.
15. In the organic electroluminescent element according to claim 13 or claim 14, mx is 1. Organic electroluminescent element.
16. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Transformation 8】 (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, Substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, or The group is represented by the general formula (11) above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11), However, R 101 ~R 110 At least one of them is a heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, If there are multiple groups represented by the general formula (11), the multiple groups represented by the general formula (11) may be identical or different from each other. L 101 teeth, Single bond, or A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, Ar 101 These are substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms. mx is 0, 1, 2, 3, 4, or 5. Ar 101 This is not a substituted or unsubstituted pyrenyl group, L 101 This is not a substituted or unsubstituted pyrenylene group, R is not a group represented by the general formula (11) mentioned above. 101 ~R 110 As a substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, it is not a substituted or unsubstituted pyrenyl group, L 101 If there are two or more, then there are two or more L 101 They are either identical or different from each other. Ar 101 If there are two or more Ar 101 They are either identical or different from each other. The asterisk (*) in general formula (11) indicates the bonding position with the pyrene ring in general formula (1). 【Chemistry 9】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
17. In the organic electroluminescent element according to claim 16, mx is 1, 2, 3, 4, or 5. at least one L 101 This is at least one arylene group selected from the group consisting of substituted or unsubstituted phenylene groups, substituted or unsubstituted biphenylene groups, substituted or unsubstituted terphenylene groups, substituted or unsubstituted naphthylene groups, substituted or unsubstituted fluoroorangeyl groups, and substituted or unsubstituted phenanthrylene groups. Organic electroluminescent element.
18. In the organic electroluminescent element according to claim 16 or claim 17, Ar 101 This is an aryl group in which four or more rings are fused together. Organic electroluminescent element.
19. In an organic electroluminescent element according to any one of claims 16 to 18, R 101 ~R 110 A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms is a heterocyclic group selected from the group consisting of monocyclic heterocyclic groups, heterocyclic groups with two fused rings, and heterocyclic groups with three fused rings. Organic electroluminescent element.
20. In an organic electroluminescent element according to any one of claims 16 to 19, R 101 ~R 110 One or two of these are groups represented by the general formula (11), Organic electroluminescent element.
21. In an organic electroluminescent element according to any one of claims 16 to 20, Ar 101 teeth, Substituted or unsubstituted phenyl groups, Substituted or unsubstituted naphthyl groups, Substituted or unsubstituted biphenyl groups, Substituted or unsubstituted terphenyl groups, A substituted or unsubstituted phenanthryl group, A substituted or unsubstituted fluorenyl group, Organic electroluminescent element.
22. In an organic electroluminescent element according to any one of claims 16 to 21, mx is 1, 2, 3, 4, or 5. L 101 These are substituted or unsubstituted ring-forming arylene groups with 6 to 50 carbon atoms. Organic electroluminescent element.
23. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Chemistry 10】 (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, Substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, or The group is represented by the general formula (11) above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11), If there are multiple groups represented by the general formula (11), the multiple groups represented by the general formula (11) may be identical or different from each other. L 101 teeth, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 101 These are heterocyclic groups with 5 to 50 substituted or unsubstituted ring-forming atoms. mx is 1, 2, 3, 4, or 5. L 101 This is not a substituted or unsubstituted pyrenylene group, R is not a group represented by the general formula (11) mentioned above. 101 ~R 110 As a substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, it is not a substituted or unsubstituted pyrenyl group, L 101 If there are two or more, then there are two or more L 101 They are either identical or different from each other. Ar 101 If there are two or more Ar 101 They are either identical or different from each other. The asterisk (*) in general formula (11) indicates the bonding position with the pyrene ring in general formula (1). 【Chemistry 11】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
24. In the organic electroluminescent element according to claim 23, at least one L 101 This is at least one arylene group selected from the group consisting of substituted or unsubstituted phenylene groups, substituted or unsubstituted biphenylene groups, substituted or unsubstituted terphenylene groups, substituted or unsubstituted naphthylene groups, substituted or unsubstituted fluoroorangeyl groups, and substituted or unsubstituted phenanthrylene groups. Organic electroluminescent element.
25. In the organic electroluminescent element according to claim 23 or claim 24, Ar 101 It is a heterocyclic group formed by the fusion of four or more rings. Organic electroluminescent element.
26. In an organic electroluminescent element according to any one of claims 23 to 25, L 101 These are substituted or unsubstituted ring-forming arylene groups with 6 to 50 carbon atoms. Organic electroluminescent element.
27. In an organic electroluminescent element according to any one of claims 23 to 26, R 101 ~R 110 One of them is the group represented by the general formula (11), Organic electroluminescent element.
28. In an organic electroluminescent element according to any one of claims 23 to 27, mx is 1. Organic electroluminescent element.
29. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Chemistry 12】 (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, Substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, or The group is represented by the general formula (11) above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11), If there are multiple groups represented by the general formula (11), the multiple groups represented by the general formula (11) may be identical or different from each other. L 101 This is a divalent heterocyclic group with 5 to 50 substituted or unsubstituted ring-forming atoms. Ar 101 These are substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms. mx is 1, 2, 3, 4, or 5. Ar 101 This is not a substituted or unsubstituted pyrenyl group, R is not a group represented by the general formula (11) mentioned above. 101 ~R 110 As a substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, it is not a substituted or unsubstituted pyrenyl group, L 101 If there are two or more, then there are two or more L 101 They are either identical or different from each other. Ar 101 If there are two or more Ar 101 They are either identical or different from each other. The asterisk (*) in general formula (11) indicates the bonding position with the pyrene ring in general formula (1). 【Chemistry 13】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
30. In the organic electroluminescent element according to claim 29, at least one L 101 This is a divalent heterocyclic group selected from the group consisting of a substituted or unsubstituted dibenzofranzyl group, a substituted or unsubstituted dibenzothiophenediyl group, and a substituted or unsubstituted carbazolediyl group. Organic electroluminescent element.
31. In the organic electroluminescent element according to claim 29 or claim 30, Ar 101 This is an aryl group in which four or more rings are fused together. Organic electroluminescent element.
32. In an organic electroluminescent element according to any one of claims 29 to 31, R 101 ~R 110 One of them is the group represented by the general formula (11), Organic electroluminescent element.
33. In an organic electroluminescent element according to any one of claims 29 to 32, mx is 1. Organic electroluminescent element.
34. In an organic electroluminescent element according to any one of claims 29 to 33, Ar 101 teeth, Substituted or unsubstituted phenyl groups, Substituted or unsubstituted naphthyl groups, Substituted or unsubstituted biphenyl groups, Substituted or unsubstituted terphenyl groups, A substituted or unsubstituted phenanthryl group, A substituted or unsubstituted fluorenyl group, Organic electroluminescent element.
35. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11A), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Chemistry 14】 (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, Substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, or The group is represented by the general formula (11A) mentioned above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11A), If there are multiple groups represented by the general formula (11A), the multiple groups represented by the general formula (11A) may be the same as or different from each other. X A is an oxygen atom or a sulfur atom, R 131 , R 133 and R 134 Of the sets of two or more adjacent items, one or more sets are They combine with each other to form a monoring, either substituted or unsubstituted, They bond to each other to form substituted or unsubstituted fused rings, or They do not bind to each other, R 135 ~R 138 , and R that does not form the substituted or unsubstituted monoring and does not form the substituted or unsubstituted condensed ring 131 , R 133 and R 134 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, In the above general formula (11A), the asterisk (*) indicates the bonding position with the pyrene ring in the above general formula (1). 【Chemistry 15】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
36. In the organic electroluminescent element according to claim 35, The first compound has one group represented by the general formula (11A). Organic electroluminescent element.
37. In the organic electroluminescent element according to claim 35 or claim 36, R 101 , R 103 , R 106 or R 108 However, the group is represented by the general formula (11A) above, Organic electroluminescent element.
38. In an organic electroluminescent element according to any one of claims 35 to 37, R 135 ~R 138 teeth, hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, or It is a nitro group, Organic electroluminescent element.
39. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11B), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Chemistry 16】 (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, Substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, or The group is represented by the general formula (11B) mentioned above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11B), If there are multiple groups represented by the general formula (11B), the multiple groups represented by the general formula (11B) may be identical or different from each other. X A is an oxygen atom or a sulfur atom, R 131 , R 133 ~R 135 , R 138 And R 141 ~R 144 Of the sets of two or more adjacent items, one or more sets are They combine with each other to form a monoring, either substituted or unsubstituted, They bond to each other to form substituted or unsubstituted fused rings, or They do not bind to each other, R that does not form the aforementioned substituted or unsubstituted monoring and does not form the aforementioned substituted or unsubstituted condensed ring 131 , R 133 ~R 135 , R 138 And R 141 ~R 144 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, However, R 135 , R 138 And R 141 ~R 144 Of these, at least one is A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, The asterisk (*) in the above general formula (11B) indicates the bonding position with the pyrene ring in the above general formula (1). 【Chemistry 17】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
40. In the organic electroluminescent element according to claim 39, The first compound has one group represented by the general formula (11B). Organic electroluminescent element.
41. In the organic electroluminescent element according to claim 39 or claim 40, R 101 , R 103 , R 106 or R 108 However, the group is represented by the general formula (11B) above. Organic electroluminescent element.
42. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11C), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. [Chemistry 18] (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, Substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, or The group is represented by the general formula (11C) mentioned above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11C), If there are multiple groups represented by the general formula (11C), the multiple groups represented by the general formula (11C) may be the same as or different from each other. X A is an oxygen atom or a sulfur atom, R 131 , R 133 , R 134 , R 137 , R 138 And R 141 ~R 144 Of the sets of two or more adjacent items, one or more sets are They combine with each other to form a monoring, either substituted or unsubstituted, They bond to each other to form substituted or unsubstituted fused rings, or They do not bind to each other, R that does not form the aforementioned substituted or unsubstituted monoring and does not form the aforementioned substituted or unsubstituted condensed ring 131 , R 133 , R 134 , R 137 , R 138 And R 141 ~R 144 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, In the above general formula (11C), the asterisk (*) indicates the bonding position with the pyrene ring in the above general formula (1). 【Chemistry 19】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
43. In the organic electroluminescent element according to claim 42, The first compound has one group represented by the general formula (11C). Organic electroluminescent element.
44. In the organic electroluminescent element according to claim 42 or claim 43, R 101 , R 103 , R 106 or R 108 However, the group is represented by the general formula (11C) above, Organic electroluminescent element.
45. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11D), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Chemistry 20】 (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, Substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, or The group is represented by the general formula (11D) above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11D), If there are multiple groups represented by the general formula (11D), the multiple groups represented by the general formula (11D) may be identical or different from each other. X A is an oxygen atom or a sulfur atom, R 131 , R 133 , R 134 , R 135 , R 136 And R 141 ~R 144 Of the sets of two or more adjacent items, one or more sets are They combine with each other to form a monoring, either substituted or unsubstituted, They bond to each other to form substituted or unsubstituted fused rings, or They do not bind to each other, R that does not form the aforementioned substituted or unsubstituted monoring and does not form the aforementioned substituted or unsubstituted condensed ring 131 , R 133 , R 134 , R 135 , R 136 And R 141 ~R 144 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, The asterisk (*) in the above general formula (11D) indicates the bonding position with the pyrene ring in the above general formula (1). 【Chemistry 21】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
46. In the organic electroluminescent element according to claim 45, The first compound has one group represented by the general formula (11D), Organic electroluminescent element.
47. In the organic electroluminescent element according to claim 45 or claim 46, R 101 , R 103 , R 106 or R 108 However, the group is represented by the general formula (11D) above, Organic electroluminescent element.
48. Anode and, Cathode and, A first light-emitting layer disposed between the anode and the cathode, It comprises a second light-emitting layer disposed between the first light-emitting layer and the cathode, The first light-emitting layer has at least one group represented by the following general formula (11E), and contains a first compound represented by the following general formula (1) as a first host material. The second light-emitting layer contains a second compound represented by the following general formula (2) as a second host material, The first light-emitting layer and the second light-emitting layer are in direct contact. Organic electroluminescent element. 【Chemistry 22】 (In the above general formula (1), R 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, Substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, or The group is represented by the general formula (11E) mentioned above, However, R 101 ~R 110 At least one of them is a group represented by the general formula (11E), If there are multiple groups represented by the general formula (11E), the multiple groups represented by the general formula (11E) may be the same as or different from each other. X A is an oxygen atom or a sulfur atom, R 131 , R 133 ~R 135 , R 138 And R 141 ~R 144 Of the sets of two or more adjacent items, one or more sets are They combine with each other to form a monoring, either substituted or unsubstituted, They bond to each other to form substituted or unsubstituted fused rings, or They do not bind to each other, R that does not form the aforementioned substituted or unsubstituted monoring and does not form the aforementioned substituted or unsubstituted condensed ring 131 , R 133 ~R 135 , R 138 And R 141 ~R 144 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 101 teeth, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, mx is 1, 2, 3, 4, or 5. L 101 If there are two or more, then there are two or more L 101 They are either identical or different from each other. In the general formula (11E), the asterisk (*) indicates the bonding position with the pyrene ring in the general formula (1). 【Chemistry 23】 (In the above general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, It is a heterocyclic group with 5 to 50 ring-forming atoms, either substituted or unsubstituted. (Among the first compound represented by the general formula (1) and the second compound represented by the general formula (2), R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 and R 802 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, R 901 If multiple R 901 They are either identical or different from one another. R 902 If multiple R 902 They are either identical or different from one another. R 903 If multiple R 903 They are either identical or different from one another. R 904 If multiple R 904 They are either identical or different from one another. R 905 If multiple R 905 They are either identical or different from one another. R 906 If multiple R 906 They are either identical or different from one another. R 907 If multiple R 907 They are either identical or different from one another. R 801 If multiple R 801 They are either identical or different from one another. R 802 If multiple R 802 (They are either identical or different to each other.)
49. In the organic electroluminescent element according to claim 48, The first compound has one group represented by the general formula (11E). Organic electroluminescent element.
50. In the organic electroluminescent element according to claim 48 or claim 49, R 101 , R 103 , R 106 or R 108 However, the group is represented by the general formula (11E), Organic electroluminescent element.
51. In an organic electroluminescent element according to any one of claims 48 to 50, The group represented by the general formula (11) is the group represented by the following general formula (111E): Organic electroluminescent element. 【Chemistry 24】 (In the above general formula (111E), X 1 CR 123 R 124 , oxygen atom, sulfur atom, or NR 125 And, L 111 and L 112 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, ma is 1, 2, 3, or 4. MB is 1, 2, 3, or 4. ma + mb is 2, 3, or 4. X A , R 131 , R 133 ~R 135 , R 138 And R 141 ~R 144 These are, respectively, X in the general formula (11E) above. A , R 131 , R 133 ~R 135 , R 138 And R 141 ~R 144 It is synonymous with, R 121 , R 122 , R 123 , R 124 and R 125 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, Nitro group, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, A heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, mc is 3, The three R's 121 They are either identical or different from each other. md is 3, The three R's 122 They are either identical or different to one another.
52. In the organic electroluminescent element according to claim 51, ma is either 1 or 2. mb is either 1 or 2. Organic electroluminescent element.
53. In the organic electroluminescent element according to claim 51 or claim 52, ma is 1, mb is 1. Organic electroluminescent element.
54. In an organic electroluminescent element according to any one of claims 35 to 53, R is not a group represented by the general formula (11A), general formula (11B), general formula (11C), general formula (11D), or general formula (11E). 101 ~R 110 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, These are heterocyclic groups with 5 to 50 substituted or unsubstituted ring-forming atoms. Organic electroluminescent element.
55. In an organic electroluminescent element according to any one of claims 1 to 54, The aforementioned organic electroluminescent element emits light with a main peak wavelength of 430 nm to 480 nm when the element is driven. Organic electroluminescent element.
56. In an organic electroluminescent element according to any one of claims 1 to 55, The second light-emitting layer further contains a fluorescent fourth compound, The fourth compound is a compound that exhibits emission with a main peak wavelength of 430 nm or more and 480 nm or less. Organic electroluminescent element.
57. In an organic electroluminescent element according to any one of claims 1 to 56, The first light-emitting layer further contains a third fluorescent compound, The third compound is a compound that exhibits emission with a main peak wavelength of 430 nm or more and 480 nm or less. Organic electroluminescent element.
58. In an organic electroluminescent element according to any one of claims 1 to 57, R is not a group represented by the general formula (11), the general formula (11A), the general formula (11B), the general formula (11C), the general formula (11D), or the general formula (11E). 101 ~R 110 Each of them operates independently. hydrogen atom, A substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, A substituted or unsubstituted cycloalkyl group having 3 to 50 carbon atoms, Organic electroluminescent element.
59. In an organic electroluminescent element according to any one of claims 1 to 58, R is not a group represented by the general formula (11), the general formula (11A), the general formula (11B), the general formula (11C), the general formula (11D), or the general formula (11E). 101 ~R 110 is a hydrogen atom, Organic electroluminescent element.
60. In an organic electroluminescent element according to any one of claims 1 to 59, R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, Substituted or unsubstituted haloalkyl groups with 1 to 50 carbon atoms, Substituted or unsubstituted alkenyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted alkynyl groups having 2 to 50 carbon atoms, Substituted or unsubstituted ring-forming cycloalkyl groups with 3 to 50 carbon atoms, -Si(R 901 ) (Caution 902 ) (Caution 903 ) a base represented by -O-(R 904 ) a base represented by -S-(R 905 ) a base represented by -N(R) 906 ) (Caution 907 ) a base represented by Substituted or unsubstituted aralkyl groups with 7 to 50 carbon atoms, -C(=O)R 801 A base represented by - COOR 802 A base represented by halogen atom, Cyano group, or It is a nitro group, L 201 and L 202 Each of them operates independently. single bond, A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, or A divalent heterocyclic group having 5 to 50 substituted or unsubstituted ring-forming atoms, Ar 201 and Ar 202 Each of them operates independently. A substituted or unsubstituted ring-forming aryl group having 6 to 50 carbon atoms, These are heterocyclic groups with 5 to 50 substituted or unsubstituted ring-forming atoms. Organic electroluminescent element.
61. In an organic electroluminescent element according to any one of claims 1 to 60, L 201 and L 202 Each of them operates independently. Single bond, or A substituted or unsubstituted ring-forming arylene group having 6 to 50 carbon atoms, Ar 201 and Ar 202 These are, independently, substituted or unsubstituted ring-forming aryl groups with 6 to 50 carbon atoms. Organic electroluminescent element.
62. In an organic electroluminescent element according to any one of claims 1 to 60, Ar 201 and Ar 202 Each of them operates independently. Phenyl group, Naphthyl group, Phenanthryl group, biphenyl group, Terphenyl group, diphenylfluorenyl group, Dimethylfluorenyl group, Benzodiphenylfluorenyl group, Benzodimethylfluorenyl group, Dibenzofuranyl group, dibenzothienyl group, Naphthobenzofuranyl group, or It is a naphthobenzothienyl group, Organic electroluminescent element.
63. In an organic electroluminescent element according to any one of claims 1 to 62, The second compound represented by the general formula (2) is a compound represented by the following general formulas (201), (202), (203), (204), (205), (206), (207), (208), or (209). Organic electroluminescent element. 【Chemistry 25】 【Chemistry 26】 【Chemistry 27】 【Chemistry 28】 【Chemistry 29】 【Transformation 30】 【Chemistry 31】 【Chemistry 32】 【Transformation 33】 (In the above general formulas (201) to (209), L 201 and Ar 201 L in the general formula (2) is 201 and Ar 201 It is synonymous with, R 201 ~R 208 Each of these independently corresponds to R in the general formula (2) above. 201 ~R 208 (This is synonymous with...)
64. In an organic electroluminescent element according to any one of claims 1 to 63, In the second compound represented by the general formula (2), R 201 ~R 208 Each of them operates independently. hydrogen atom, Substituted or unsubstituted alkyl groups having 1 to 50 carbon atoms, A substituted or unsubstituted ring-forming cycloalkyl group having 3 to 50 carbon atoms, or -Si(R 901 ) (Caution 902 ) (Caution 903 The base represented by ) Organic electroluminescent element.
65. In an organic electroluminescent element according to any one of claims 1 to 64, In the second compound represented by the general formula (2), R 201 ~R 208 is a hydrogen atom, Organic electroluminescent element.
66. In an organic electroluminescent element according to any one of claims 1 to 65, In the first compound and the second compound, the groups described as "substituted or unsubstituted" are all "unsubstituted" groups. Organic electroluminescent element.
67. In an organic electroluminescent element according to any one of claims 1 to 66, A hole transport layer is provided between the anode and the first light-emitting layer. Organic electroluminescent element.
68. In an organic electroluminescent element according to any one of claims 1 to 67, An electron transport layer is provided between the cathode and the second light-emitting layer. Organic electroluminescent element.
69. An electronic device equipped with an organic electroluminescent element according to any one of claims 1 to 68.