Heteroaryl-triazole compounds as pesticides
By designing novel heterocyclic triazole compounds, the problems of insufficient efficacy and drug resistance of existing pesticides and veterinary drugs in controlling ectoparasites and plant pests have been solved, achieving a wider activity spectrum and lower synthesis cost, and improving efficacy and selectivity.
Patent Information
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Filing Date
- 2025-05-01
- Publication Date
- 2026-04-07
AI Technical Summary
Existing pesticides and veterinary drugs have insufficient efficacy and resistance issues in controlling ectoparasites and plant pests, and their high synthesis costs make it difficult to meet the multiple requirements of modern pesticides and veterinary drugs.
The development of novel heterocyclic triazole compounds, through specific structural design and the introduction of substituents, has expanded the activity spectrum of pesticides and veterinary drugs and improved their selectivity and efficacy against target organisms.
It offers a wider range of insecticidal and repellent effects, reduces synthesis costs, decreases toxicity risks, prolongs efficacy, and overcomes the challenge of drug resistance.
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Abstract
Description
[Technical Field]
[0001] The present invention includes novel heteroaryl-triazole compounds, and such compounds Formulations and compositions, and pests (animal pests) in plant protection (this is, Their use in the control of arthropods and insects and in the control of ectoparasites of animals Regarding their use for removal. [Background technology]
[0002] Formula (I) [R 3b Certain heteroaryl-triazole compounds represented by [=hydrogen] are, Disclosed in WO2017 / 192385 regarding its use in the control of external parasites in animals. Furthermore, pests in the field of plant protection (this includes arthropods and insects) Regarding its use in pest control, see WO2019 / 170626 and WO2019 / 21519 Disclosed in 8. Furthermore, patent applications WO2019 / 197468, WO2019 / 2 01835, WO2019 / 202077 and WO2019 / 206799 are animals. For use in the control of external parasites, and in the field of plant protection, pests (this This includes specific heteroaryl-triazeps for controlling arthropods and insects. Zole compounds are disclosed in WO2020 / 002563 and WO2020 / 0533. 64, WO2020 / 053365, WO2020 / 079198, WO2020 / 09 4363, WO2020 / 169445, WO2020 / 182649, WO2020 / 188014, WO2020 / 188027 and WO2020 / 193341 contain azo The document lists sylamide compounds, all of which are used as insecticides. This is possible.
[0003] Modern plant protection products and veterinary ectoparasitic drugs have, for example, efficacy, duration of action, and spectrum. Regarding torque and resistance breaking characteristics, etc. It must meet certain requirements, including toxicity issues, other active compounds, or formulation aids. The combinatoriality of these compounds, in addition to the cost required to synthesize the active compounds, plays a certain role. It fulfills this purpose. Furthermore, resistance may also develop. For all these reasons, novel crop protection compositions or The search for veterinary ectoparasitic drugs is not yet complete, and comparisons with known compounds are not possible. In contrast, there is a constant demand for novel compounds that have improved properties, at least in their individual aspects. It is being done. [Prior art documents] [Patent Documents]
[0004] [Patent Document 1] WO2017 / 192385 [Patent Document 2] WO2019 / 170626 [Patent Document 3] WO2019 / 215198 [Patent Document 4] WO2019 / 197468 [Patent Document 5] WO2019 / 201835 [Patent Document 6] WO2019 / 202077 [Patent Document 7] WO2019 / 206799 [Patent Document 8] WO2020 / 002563 [Patent Document 9] WO2020 / 053364 [Patent Document 10] WO2020 / 053365 [Patent Document 11] WO2020 / 079198 [Patent Document 12] WO2020 / 094363 [Patent Document 13] WO2020 / 169445 [Patent Document 14] WO2020 / 182649 [Patent Document 15] WO2020 / 188014 [Patent Document 16] WO2020 / 188027 [Patent Document 17] WO2020 / 193341 [Overview of the Initiative] [Problems that the invention aims to solve]
[0005] The objective of the present invention is to provide compounds that expand the spectrum of pesticides in various contexts. The goal was to provide something. [Means for solving the problem]
[0006] Therefore, the present invention relates to general formula (I) [ka] [In the formula (configuration 1-1): X is either O or S; Y is a CH2 that may be directly bonded or substituted; R 1 is hydrogen; C1-C6 alkyl [where the alkyl is -CN, -CONH2, Substituted with one substituent selected from -COOH, -NO2, and -Si(CH3)3 [May be]; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C4 cycloalkyl-C 1-C2 alkyl-[where the C3-C4 cycloalkyl is one or two halogens [may be substituted with an atom]; oxetane-3-yl-CH2- or benzyl [here These may be substituted with halogen atoms or C1-C3 haloalkyl groups. ; R 2 These are phenyl, pyridine, pyrimidine, pyrazine, or pyridazine, where, The phenyl, pyridine, pyrimidine, pyrazine, or pyridazine has a total of 1 to 3 substituents. It is substituted with, however, the substituent is adjacent to the carbon bonded to the C=X group. None of these carbon atoms are present, and there are at least 1 and up to 3 substituents. Hydroxyl, and in either case, C3-C6 cycloal compounds which may be substituted. Coxy, -OCO-C1-C3 alkyl, -OSO2-C1-C6 alkyl, C2-C4 Alkenyls, C2-C4 haloalkenyls, phenoxy and heterocyclyloxy; and, C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 haloalkyl, C1- C3 alkoxy, C2-C4 alkenyloxy and C2-C4 haloalkenyloxy [ Herein, the C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 haloalkoxy, C 1-C3 alkoxy, C2-C4 alkenyloxy and C2-C4 haloalkenyloxy teeth, =O (oxo), =S (thiono), hydroxy, -CN, -COOH, -CSNH 2, -NO2, -NH2, -SF5, -SiMe3; and, In either case, the C3-C6 cycloalkyl and C3-C6 cycloalkyl groups may be substituted. Rocycloalkyl, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkyl Kilthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C 6 cycloalkyl kylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cyclo alkylsulfonyl, C1-C6 haloalkylthio, C1-C6 haloalkylsulfi nyl, C1-C6 haloalkylsulfonyl, -OCONH-C1-C6 alkyl, -NH (C1-C6 alkyl), -N(C1-C6 alkyl)2, -CONR 41 R 42 、-N R 42 COR 41 、-CO2C1-C6 alkyl, -C(=NOC1-C6 alkyl)H 、-C(=NOC1-C6 alkyl)-C1-C6 alkyl; and, optionally substituted phenyl and heterocyclyl (wherein the heterocyclyl is selected from the group consisting of saturated and partially unsaturated 4- to 10-membered heterocyclyl, 5-membered heteroaryl, 6-membered hetero aryl, 9-membered heteroaryl and 10-membered heteroaryl); substituted with 1 to 3 substituents selected from the group consisting of]; independently selected from group A consisting of; and,[[ID= C may be substituted in any of the following cases: OOH, -CONH2, -NO2, or -NH2. 1-C6 alkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, C1-C6 alkyl Kilthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, -NH( C1-C6 alkyl), -N(C1-C6 alkyl)2, -NHCO-C1-C6 alkyl Lu, -N(C1-C6 alkyl)CO-C1-C6 alkyl, -CO2C1-C6 alkyl It consists of -CONH(C1-C6 alkyl) and -CON(C1-C6 alkyl)2. [May be substituted with 1 to 3 substituents independently selected from the group]; and, In either case, the C3-C6 cycloalkyl and C1-C6 halo may be substituted. Alkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl; And, benzyl [where the phenyl substituent is halogen, hydroxyl, -CN, -COO H, -CONH2, -NO2, -NH2, -SF5, and in all cases, are substituted. C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylthio, C From the group consisting of 1-C6 alkylsulfinyl and C1-C6 alkylsulfonyl They may be substituted with 1 to 5 substituents that are independently selected]; and, Heterocyclyl-C1-C6 alkyl [where the heterocyclyl substituent is 4-1 0-membered saturated and partially unsaturated heterocyclyls, 5-membered heteroaryls, and 6-membered heteroaryls Selected from a group consisting of reels, where these are halogens and =O(oxo ), hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, and i In the case of displacement, C1-C6 alkyl and C1-C6 alkoxy which may be substituted It may be substituted with 1 to 3 substituents independently selected from the group; Independently selected from the group consisting of; Or, R 3a , R 3b Along with the carbon to which they are bonded, either halogen or -CN C1-C6 alkyl, C1-C6 alkoxy and C1-C may also be substituted in some cases. Substituted with 1-2 substituents independently selected from the group consisting of 6 haloalkoxys. It may also form a C3-C6-carbon ring system or a 3- to 6-membered heterocyclic ring system; R 4 Here, the pyridine is a pyridine, pyrimidine, pyrazine, or pyridazine. Pyrimidines, pyrazines, or pyridazines are halogenated, hydroxy, or C1-C3 alkyl groups. Composed of C3-C4 cycloalkyl, C1-C3 haloalkyl, and C1-C3 alkoxy elements. It is substituted with 2-3 substituents independently selected from the group; Or, R 4 Here, the pyridine is a pyridine, pyrimidine, pyrazine, or pyridazine. Pyrimidines, pyrazines, or pyridazines are substituted with a total of 1 to 3 substituents, however And, the substituents are at least 1 and up to 3. -CN, -COOH, -NO2, -SF5, -NH2, substituted C3-C4 cells Chloalkyl; and, C1-C3 alkyl and C1-C3 alkoxy [wherein these are all -N] H2, -OH, -NO2, -CN, -SH, CO2C1-C4 alkyl, -CONH2, SF5, -SO2NH2, C3-C4 cycloalkyl, C2-C4 alkenyl, C5-C 6-cycloalkenyl, C2-C4 alkynyl, -NH(C1-C6 alkyl), -N(C 1-C6 alkyl)2, N-C1-C4 alkanoylamino, C1-C4 alkoxy, C 1-C4 haloalkoxy, C2-C4 alkenyloxy, C2-C4 alkynyloxy, C3-C4 cycloalkoxy, C5-C6 cycloalkenyloxy, C1-C4 alkoxy C2-C4 alkenyloxycarbonyl, C2-C4 alkynyloxycarbonyl Rubonyl, C6-,C 10 -,C 14 - Aryloxycarbonyl, C1-C4 alkano Il, C2-C4 alkenylcarbonyl, C2-C4 alkynylcarbonyl, C6-,C 10 -,C 14 - Arylcarbonyl, C1-C4 alkylthio, C1-C4 haloalkyl Luthio, C3-C4 cycloalkylthio, C2-C4 alkenylthio, C5-C6 cyclo Alkenylthio, C2-C4 Alkinylthio, C1-C4 Alkylsulfinyl, C1- C4-haloalkylsulfinyl, C1-C4 alkylsulfonyl, C1-C4-haloalkyl Sulfonyl, -SO2-NH(C1-C6 alkyl), -SO2-N(C1-C6 alkyl) Kill) 2, C1-C4 alkylphosphinyl, C1-C4 alkylphosphonyl, N-C1 -C4 alkylaminocarbonyl, N,N-di-C1-C4 alkylaminocarbonyl, N-C1-C4 Alkanoylaminocarbonyl, N-C1-C4 Alkanoyl-N-C1 -C4 alkylaminocarbonyl, C6-,C 10 -,C 14 -Aryl, C6-,C1 0-,C 14 -aryloxy, benzyl, benzyloxy, benzylthio, C6-,C 10 -,C14 -arylthio, C6-,C 10 -,C 14 -arylamino, benzyl Amino, heterocyclyl, heteroaryl and trialkylsilyl, and double bonds substituents bonded via the molecule, for example, C1-C4 alkylides (e.g., methylidene or Independently from the group consisting of ethylidene, oxo group, imino group and substituted imino group [Substituted with 1-3 selected substituents]; and, In either case, the substitutions may be -CO2-C1-C6 alkyl, C5-C6 Cycloalkyl, C4-C6 alkyl, C4-C6 haloalkyl, C4-C6 alkoxy , C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfini C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C 6-cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C6 halo Alkylthio, C1-C6 haloalkylsulfinyl, C1-C6 haloalkylsulfonyl C2-C4 alkenyl sulfanyl, C2-C4 alkenyl sulfinyl, C2-C 4-Alkenylsulfonyl, C2-C4 Alkynylsulfanyl, C2-C4 Alkynils Rufinyl, C2-C4 alkynylsulfonyl, phenylsulfanyl, phenylsulf Phenyl, phenylsulfonyl, S-C1-C6 alkylsulfinimidoyl, S-C3 -C6 cycloalkylsulfinimidoyl, S-C2-C6 alkenylsulfinimidoyl Doyle, S-C2-C6 alkynylsulfinimidoyl, S-phenylsulfinimidoyl Doyle, S-C1-C6 alkylsulfonimidoyl, S-C3-C6 cycloalkyls Sulfonimidoyl, S-C2-C6 alkenylsulfonimidoyl, S-C2-C6 al Quinyl sulfonimidoyl, S-phenyl sulfonimidoyl, -NH(C1-C6) Kill), -N(C1-C6 alkyl)2, -C(=NOC1-C6 alkyl)H, -C( =NOC1-C6 alkyl)-C1-C6 alkyl, phenyl and 5-6 member heterozygous Lu; and, Substructures S1-S6 below: [ka] [Here, The binding to the pyridine, pyrimidine, pyrazine, or pyridazine is marked with a #. And Z is CO or CS, and Y 1 It is selected independently of CO or SO2. ; R 41 is hydrogen, or a C1-C6 alkyl group which may be substituted in either case. C1-C6 haloalkyl, C3-C6 cycloalkyl, -C1-C6 alkyl-C3-C It is a 6-cycloalkyl and phenyl compound; R 42 is hydrogen, or a C1-C6 alkyl group which may be substituted in either case. They are C1-C6 haloalkyl and C3-C6 cycloalkyl; R 43 In either case, the C1-C6 alkyl and C1-C6 alkyl groups may be substituted. [Independently selected from C3-C6 cycloalkyl, C3-C6 cycloalkyl, and phenyl]; Independently selected from group A consisting of; And, The substituents in the remaining 1-2 cases are: Halogens and hydroxyls; and, In either case, the C1-C6 alkyl and C3-C6 cycloal groups may be substituted. Kill, C1-C6 haloalkyl and C1-C6 alkoxy; Each is independently selected from group B, which consists of; Or, R 4 is a 5-membered heteroaryl, where the heteroaryl is Halogen, hydroxyl, -CN, -COOH, -NO2, -SF5, -NH2; and , In either case, substitution may occur -CO2-C1-C6 alkyl, C1-C6 Alkyl, C3-C6 cycloalkyl, C1-C6 haloalkyl, C1-C6 alkoxy , C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfini C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C 6-cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C6 halo Alkylthio, C1-C6 haloalkylsulfinyl, C1-C6 haloalkylsulfonyl C2-C4 alkenyl sulfanyl, C2-C4 alkenyl sulfinyl, C2-C 4-Alkenylsulfonyl, C2-C4 Alkynylsulfanyl, C2-C4 Alkynils Rufinyl, C2-C4 alkynylsulfonyl, phenylsulfanyl, phenylsulf Phenyl, phenylsulfonyl, S-C1-C6 alkylsulfinimidoyl, S-C3 -C6 cycloalkylsulfinimidoyl, S-C2-C6 alkenylsulfinimidoyl Doyle, S-C2-C6 alkynylsulfinimidoyl, S-phenylsulfinimidoyl Doyle, S-C1-C6 alkylsulfonimidoyl, S-C3-C6 cycloalkyls Sulfonimidoyl, S-C2-C6 alkenylsulfonimidoyl, S-C2-C6 al Quinyl sulfonimidoyl, S-phenyl sulfonimidoyl, -NH(C1-C6) Kill), -N(C1-C6 alkyl)2, -C(=NOC1-C6 alkyl)H, -C( =NOC1-C6 alkyl)-C1-C6 alkyl, phenyl and 5-6 member heterozygous Lu; and, Substructures S1-S6 [where the bond to the 5-membered heteroaryl is marked with a #] ri, and Z are CO or CS, and Y 1 This is selected independently of CO or SO2. [to be done]; They may be substituted with 1 to 3 substituents independently selected from the group consisting of; Or, R 4 These include 4-10 member saturated or partially unsaturated heterocyclyls, 9-membered heteroaryls, and A heterocyclic ring selected from the group consisting of 10-membered heteroaryls, where these These are, Halogen, =O (oxo), =S (thiono), hydroxyl, -CN, -COOH, - SO2NH2, -CONH2, -CSNH2, -NO2, -SF5, -NH2; and, In either case, substitution may occur -CO2-C1-C6 alkyl, C1-C6 Alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl-C1-C6 alkyl , C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1- C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3 -C6 cycloalkylsulfonyl, C1-C6 haloalkylthio, C1-C6 haloalkyl Lusulfinyl, C1-C6 haloalkylsulfonyl, C2-C4 alkenylsulfanyl C2-C4 alkenyl sulfinyl, C2-C4 alkenyl sulfonyl, C2-C4 Alkynylsulfanyl, C2-C4 alkynylsulfinyl, C2-C4 alkynyls Sulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, SC 1-C6 alkylsulfinimidoyl, S-C3-C6 cycloalkylsulfinimidoyl Doyle, S-C2-C6 alkenylsulfinimidoyl, S-C2-C6 alkinyls Sulfinimidoyl, S-phenylsulfinimidoyl, S-C1-C6 alkylsulfin Honimidoyl, S-C3-C6 cycloalkyl sulfonimidoyl, S-C2-C6 Lukenyl sulfonimidoyl, S-C2-C6 alkynyl sulfonimidoyl, S-Fe Nylsulfonamidoyl, -NH(C1-C6 alkyl), -N(C1-C6 alkyl) 2, -C(=NOC1-C6alkyl)H, -C(=NOC1-C6alkyl)-C1- C6 alkyl and phenyl and 5-6 membered heteroaryl; and, Substructures S1 and S6 [where bonds to the heterocyclic ring are marked with #, And Z is CO or CS, and Y 1 It is selected independently of CO or SO2. ru]; They may be substituted with 1 to 3 substituents independently selected from the group consisting of; R 5 teeth, Hydrogen, halogens; and, In either case, the C3-C6 cycloalkyl and C1-C6 cycloalkyl groups may be substituted. Coxy, C1-C6 haloalkoxy, (C1-C6alkoxy)2CH-,-CO2C1 -C6 alkyl, -C(=NOC1-C6 alkyl)H, -C(=NOC1-C6 alkyl (Lu)-C1-C6 alkyl; and, C1-C6 alkyl and C1-C6 haloalkyl [wherein the C1-C6 alkyl and C1-C6 haloalkyls are, Halogen, =O (oxo), =S (thiono), hydroxyl, -CN, -NO2, - SF5, -SiMe3; and, In either case, the C3-C6 cycloalkyl and C1-C6 a(C6) atoms may be substituted. Lucoxy, C1-C6 haloalkoxy; They may be substituted with 1 to 3 substituents independently selected from the group consisting of [the specified group]; Selected from the group consisting of: The present invention provides a compound represented by the following:
[0007] The present invention further includes general formula (I) [wherein (components 1-2), X is either O or S; Y is a CH2 that may be directly bonded or substituted; R 1 is hydrogen; C1-C6 alkyl [where the alkyl is -CN, -CONH2, Substituted with one substituent selected from -COOH, -NO2, and -Si(CH3)3 [May be]; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C4 cycloalkyl-C 1-C2 alkyl-[where the C3-C4 cycloalkyl is one or two halogens [may be substituted with an atom]; oxetane-3-yl-CH2- or benzyl [here These may be substituted with halogen atoms or C1-C3 haloalkyl groups. ; R 2 These are phenyl, pyridine, pyrimidine, pyrazine, or pyridazine, where, The phenyl, pyridine, pyrimidine, pyrazine, or pyridazine has a total of 1 to 3 substituents. It is substituted with, however, the substituent is adjacent to the carbon bonded to the C=X group. None of these carbon atoms are present, and there are at least one and at most two substituents. C3-C6 cycloalkoxy [where the cycloalkoxy is, Halogen, =O (oxo), -CN, C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl , C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1- C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkyl kylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulf It may be substituted with 1-2 substituents selected from the group consisting of yl compounds. Or, C1-C6 alkyl [where the alkyl is, -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfite Nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C Selected from the group consisting of 6-cycloalkylsulfinyl and C3-C6 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C6 alkylcarbonyl and C3-C6 cycloalkylcarbonyl [where, C1-C6 alkylcarbonyls and C3-C6 cycloalkylcarbonyls are Halogen, -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkyl Thio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 thio chloroalkylkylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cyclo substituted with 1 to 2 substituents selected from the group consisting of or, C1-C6 alkoxy [wherein the alkoxy is =O (oxo), -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy yl, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfi nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C 6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl selected from the group consisting of substituted with 1 to 2 substituents selected; or, C1-C6 haloalkyl [wherein the haloalkyl is =O (oxo), -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy yl, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfi nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C 6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl selected from the group consisting of substituted with 1 to 2 substituents selected; or, C1-C6 haloalkoxy [wherein the haloalkoxy is =O (oxo), -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy yl, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfi[Substituted with 1-2 selected substituents]; Or, C2-C6 alkenyloxy [where the alkenyloxy is, Halogen, -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfite Nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C Selected from the group consisting of 6-cycloalkylsulfinyl and C3-C6 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C6 alkylSO2O-[where the alkylSO2O- is, Halogen, -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfite Nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C Selected from the group consisting of 6-cycloalkylsulfinyl and C3-C6 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, Phenyl-C1-C3 haloalkyl and phenyl-C1-C3 alkoxy [where, The phenyl is, Halogen, -CN, C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl , C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1- C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkyl kylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulf It may be substituted with 1 to 3 substituents independently selected from the group consisting of yl compounds. Or, Heterocyclyloxy and heterocyclyl-C1-C3 alkoxy [where the heterocyclyloxy Rocyclyl is a saturated and partially unsaturated 4-6 member heterocyclyl, 5-member heteroaryl, Selected from a group consisting of 6-membered heteroaryls, where these are, Halogen, -CN, C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl , C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1- C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkyl kylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulf It may be substituted with 1 to 3 substituents independently selected from the group consisting of yl compounds. Independently selected from the group consisting of; And, The substituents in the remaining cases are: Hydrogen, halogen, hydroxyl, -NH2, -CN, -NO2, C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkyl, C1-C3 haloalkyl, C1-C 3-alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C 3-C4 cycloalkylkylthio, C3-C4 cycloalkylsulfinyl, C3-C 4-Cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkyls Rufinyl and C1-C3 haloalkylsulfonyl; Selected from the group consisting of; R 3a , R 3b teeth, Hydrogen, halogens and -CN; and, C1-C6 alkyl [where the alkyl is halogen, hydroxy, -CN, -C OOH, -CONH2, -NO2, -NH2, C 1-C6 alkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, C1-C6 al kylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, -NH( C1-C6 alkyl), -N(C1-C6 alkyl)2, -NHCO-C1-C6 al kyl, -N(C1-C6 alkyl)CO-C1-C6 alkyl, -CO2C1-C6 al kyl, -CONH(C1-C6 alkyl) and -CON(C1-C6 alkyl)2, and is optionally substituted with 1 to 3 substituents independently selected from the group consisting of; and, and, C3-C6 cycloalkyl, C1-C6 haloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl, which are each optionally substituted; ; and, and, benzyl [where the phenyl substituent is halogen, hydroxy, -CN, -COO H, -CONH2, -NO2, -NH2, -SF5, and C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylthio, C 1-C6 alkylsulfinyl and C1-C6 alkylsulfonyl, which are each optionally substituted with 1 to 5 substituents independently selected from the group consisting of; and, ; and, heterocyclyl-C1-C6 alkyl [where the heterocyclyl substituent is selected from the group consisting of 4 to 1 0-membered saturated and partially unsaturated heterocyclyl, 5-membered heteroaryl and 6-membered heteroaryl, where these are each halogen, =O (oxo ), hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, and, respectively, and are optionally substituted with 1 to 5 substituents independently selected from the group consisting of; and, In the case of displacement, C1-C6 alkyl and C1-C6 alkoxy which may be substituted It may be substituted with 1 to 3 substituents independently selected from the group; Independently selected from the group consisting of; Or, R 3a , R 3b Along with the carbon to which they are bonded, either halogen or -CN C1-C6 alkyl, C1-C6 alkoxy and C1-C may also be substituted in some cases. Substituted with 1-2 substituents independently selected from the group consisting of 6 haloalkoxys. It may also form a C3-C6-carbon ring system or a 3- to 6-membered heterocyclic ring system; R 4 The following substructures T1~T6: [ka] One of the following is selected, where the binding to the triazole is marked with a #; Here, X 1 This is the following substructure S4-a [ka] [Here, The binding to the pyridine, pyrimidine, pyrazine, or thiazole is marked with a #; R 41 is hydrogen, or a C1-C6 alkyl group which may be substituted in either case. C1-C6 haloalkyl, C3-C6 cycloalkyl, -C1-C6 alkyl-C3-C It is a 6-cycloalkyl and phenyl compound; R 42 is hydrogen, or a C1-C6 alkyl group which may be substituted in either case. [These are C1-C6 haloalkyl and C3-C6 cycloalkyl groups.] and; X 2 is -CN or X1 and; R 5 teeth, Hydrogen, halogens; and, In either case, the C1-C6 alkyl and C1-C6 haloalkyl may be substituted. C3-C6 cycloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, ( C1-C6 Alkyl)2CH-,-CO2C1-C6 Alkyl,-C(=NOC1-C Select from the group of 6alkyl)H and -C(=NOC1-C6alkyl)-C1-C6alkyl. [to be done] The present invention provides a compound represented by the following:
[0008] The compound represented by formula (I) is further divided into all existing diastereomers or enantiomeric compounds. It includes omers and E / Z isomers, as well as salts and N-oxygen compounds of the compound represented by formula (I). This includes sids, as well as their use for pest control.
[0009] Regarding the preferred definition of radicals for the formulas specified above and below, See below.
[0010] The present invention further includes general formula (I) [wherein (components 1-3), X is either O or S; Y is a CH2 that may be directly bonded or substituted; R 1 is hydrogen; C1-C6 alkyl [where the alkyl is -CN, -CONH2, Substituted with one substituent selected from -COOH, -NO2, and -Si(CH3)3 [May be]; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C4 cycloalkyl-C 1-C2 alkyl-[where the C3-C4 cycloalkyl is one or two halogens [may be substituted with an atom]; oxetane-3-yl-CH2- or benzyl [here These may be substituted with halogen atoms or C1-C3 haloalkyl groups. ; R 2 These are phenyl, pyridine, pyrimidine, pyrazine, or pyridazine, where, The phenyl, pyridine, pyrimidine, pyrazine, or pyridazine has a total of 1 to 3 substituents. It is substituted with, however, the substituent is adjacent to the carbon bonded to the C=X group. None of these carbon atoms are present, and there are at least one and at most two substituents. C3-C6 cycloalkoxy [where the cycloalkoxy is, Halogen, =O (oxo), -CN, C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl , C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1- C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkyl kylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulf It may be substituted with 1-2 substituents selected from the group consisting of yl compounds. Or, C1-C6 alkyl [where the alkyl is, -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfite Nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C Selected from the group consisting of 6-cycloalkylsulfinyl and C3-C6 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C6 alkylcarbonyl and C3-C6 cycloalkylcarbonyl [where, C1-C6 alkylcarbonyls and C3-C6 cycloalkylcarbonyls are Halogen, -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkyl Thio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 thio chloroalkylkylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cyclo It may be substituted with one or two substituents selected from the group consisting of lucylsulfonyl; Or, C1-C6 alkoxy [where the alkoxy is, =O(oxo), -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfite Nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C Selected from the group consisting of 6-cycloalkylsulfinyl and C3-C6 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C6 haloalkyl [where the haloalkyl is, =O(oxo), -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfite Nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C Selected from the group consisting of 6-cycloalkylsulfinyl and C3-C6 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C6 haloalkoxy [where the haloalkoxy is, =O(oxo), -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfite Nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C Selected from the group consisting of 6-cycloalkylsulfinyl and C3-C6 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C2-C6 alkenyloxy [where the alkenyloxy is, Halogen, -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfite Nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C Selected from the group consisting of 6-cycloalkylsulfinyl and C3-C6 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C6 alkylSO2O-[where the alkylSO2O- is, Halogen, -CN, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfite Nyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C Selected from the group consisting of 6-cycloalkylsulfinyl and C3-C6 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, Phenyl-C1-C3 haloalkyl and phenyl-C1-C3 alkoxy [where, The phenyl is, Halogen, -CN, C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl , C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1- C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkyl kylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulf It may be substituted with 1 to 3 substituents independently selected from the group consisting of yl compounds. Or, Heterocyclyloxy and heterocyclyl-C1-C3 alkoxy [where the heterocyclyloxy Rocyclyl is a saturated and partially unsaturated 4-6 member heterocyclyl, 5-member heteroaryl, Selected from a group consisting of 6-membered heteroaryls, where these are, Halogen, -CN, C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl , C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1- C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkyl kylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulf It may be substituted with 1 to 3 substituents independently selected from the group consisting of yl compounds. Independently selected from the group consisting of; And, The substituents in the remaining cases are: Hydrogen, halogen, hydroxyl, -NH2, -CN, -NO2, C1-C3 alkyl, C3-C6-cycloalkyl, C1-C3 haloalkyl, C1-C3 alkoxy, C1- C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1 -C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C4 cyclo Lucylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkyl O, C1-C3 haloalkylsulfinyl and C1-C3 haloalkylsulfonyl; Selected from the group consisting of; R 3a , R 3b teeth, Hydrogen, halogens and -CN; and, C1-C6 alkyl [wherein the alkyl is a halogen, hydroxyl, -CN, -C C may be substituted in any of the following cases: OOH, -CONH2, -NO2, or -NH2. 1-C6 alkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, C1-C6 alkyl Kilthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, -NH( C1-C6 alkyl), -N(C1-C6 alkyl)2, -NHCO-C1-C6 alkyl Lu, -N(C1-C6 alkyl)CO-C1-C6 alkyl, -CO2C1-C6 alkyl It consists of -CONH(C1-C6 alkyl) and -CON(C1-C6 alkyl)2. [May be substituted with 1 to 3 substituents independently selected from the group]; and, In either case, the C3-C6 cycloalkyl and C1-C6 halo may be substituted. Alkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl; And, benzyl [where the phenyl substituent is halogen, hydroxyl, -CN, -COO H, -CONH2, -NO2, -NH2, -SF5, and in all cases, are substituted. C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylthio, C From the group consisting of 1-C6 alkylsulfinyl and C1-C6 alkylsulfonyl They may be substituted with 1 to 5 substituents that are independently selected]; and, Heterocyclyl-C1-C6 alkyl [where the heterocyclyl substituent is 4-1 0-membered saturated and partially unsaturated heterocyclyls, 5-membered heteroaryls, and 6-membered heteroaryls Selected from a group consisting of reels, where these are halogens and =O(oxo ), hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, and i In the case of displacement, C1-C6 alkyl and C1-C6 alkoxy which may be substituted It may be substituted with 1 to 3 substituents independently selected from the group; Independently selected from the group consisting of; Or, R 3a , R 3b Along with the carbon to which they are bonded, either halogen or -CN C1-C6 alkyl, C1-C6 alkoxy and C1-C may also be substituted in some cases. Substituted with 1-2 substituents independently selected from the group consisting of 6 haloalkoxys. It may also form a C3-C6-carbon ring system or a 3- to 6-membered heterocyclic ring system; R 4 The following substructures T1~T6: [ka] One of the following is selected, where the binding to the triazole is marked with a #; Here, X 1 This is the following substructure S4-a [ka] [Here, The binding to the pyridine, pyrimidine, pyrazine, or thiazole is marked with a #; R 41 is hydrogen, or a C1-C6 alkyl group which may be substituted in either case. C1-C6 haloalkyl, C3-C6 cycloalkyl, -C1-C6 alkyl-C3-C It is a 6-cycloalkyl and phenyl compound; R 42 is hydrogen, or a C1-C6 alkyl group which may be substituted in either case. [These are C1-C6 haloalkyl and C3-C6 cycloalkyl groups.] and; X 2 is -CN or X 1 and; R 5 teeth, Hydrogen, halogens; and, In either case, the C1-C6 alkyl and C1-C6 haloalkyl may be substituted. C3-C6 cycloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, ( C1-C6 Alkyl)2CH-,-CO2C1-C6 Alkyl,-C(=NOC1-C Select from the group of 6alkyl)H and -C(=NOC1-C6alkyl)-C1-C6alkyl. [to be done] The present invention provides a compound represented by the following:
[0011] The compound represented by formula (I) is further divided into all existing diastereomers or enantiomeric compounds. It includes omers and E / Z isomers, as well as salts and N-oxygen compounds of the compound represented by formula (I). This includes sids, as well as their use for pest control.
[0012] Regarding the preferred definition of radicals for the formulas specified above and below, See below. [Modes for carrying out the invention]
[0013] What is preferable is(Configuration 2-1), formula (I) [wherein, X is either O or S; Y is either a direct bond or CH2; R 1 is hydrogen; C1-C3 alkyl [where the alkyl is -CN, -CONH2, Substituted with one substituent selected from -COOH, -NO2, and -Si(CH3)3 [May be]; C1-C3 haloalkyl; C2-C4 alkenyl; C2-C4 haloalkenyl C2-C4 alkynyl; C2-C4 haloalkynyl; C3-C4 cycloalkyl-C 1-C2 alkyl-[where the C3-C4 cycloalkyl is one or two halogens [may be substituted with an atom]; oxetane-3-yl-CH2-; or benzyl [this In this case, the benzyl may be substituted with a halogen atom or a C1-C3 haloalkyl group. ] and; R 2 These are phenyl, pyridine, pyrimidine, pyrazine, or pyridazine, where, The phenyl, pyridine, pyrimidine, pyrazine, or pyridazine has a total of 1 to 3 substituents. It is substituted with, however, the substituent is adjacent to the carbon bonded to the C=X group. None of these carbon atoms are present, and there are at least one and at most two substituents. Hydroxy, and C3-C6 cycloalkoxy, -OCO-C1-C3 alkyl, -OSO2-C1-C4 alkyl, C2-C4 alkenyl, C2-C4 haloalkenyl; And, Phenoxy and heterocyclyloxy [wherein the heterocyclyl is saturated and partially] It consists of heterounsaturated 4-6 member heterocyclyls, 5-member heteroaryls, and 6-member heteroaryls. Selected from the group, and the phenoxy or heterocyclyloxy is a halogen, -CN, A molecule is independently selected from the group consisting of C1-C3 alkyl and C1-C3 haloalkyl. It may be substituted with 1-2 substituents; and, C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 haloalkyl, C1- C3 alkoxy, C2-C4 alkenyloxy and C2-C4 haloalkenyloxy [ Herein, the C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 haloalkoxy, C 1-C3 alkoxy, C2-C4 alkenyloxy and C2-C4 haloalkenyloxy teeth, Halogen, =O (oxo), =S (thiono), hydroxyl, -CN, -COOH, -CSNH2, -NO2, -NH2, -SF5, -SiMe3, and C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C4 alcohol C1-C4 haloalkoxy, C1-C4 alkylthio, C1-C4 alkylsulfite Nyl, C1-C4 alkylsulfonyl, C3-C6 cycloalkylkylthio, C3-C 6-cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C4 halo Alkylthio, C1-C4 haloalkylsulfinyl, C1-C4 haloalkylsulfonyl -OCONH-C1-C4alkyl, -NH(C1-C4alkyl), -N(C1- C4 alkyl)2,-CONR 41 R 42 , -NR 42 COR 41 -CO2C1-C4 Alkyl, -C(=NOC1-C4alkyl)H, -C(=NOC1-C4alkyl)- [Substituted with 1 to 3 substituents selected from the group consisting of C1-C4 alkyl groups]; and , Phenyl-C1-C3 alkyl, phenyl-C1-C3 haloalkyl, phenyl-C 1-C3 haloalkoxy, phenyl-C1-C3 alkoxy, heterocyclyl-C1-C 3-alkyl, heterocyclyl-C1-C3 haloalkyl, heterocyclyl-C1-C3 ha Roalkoxy, heterocyclyl-C1-C3 alkoxy [where the heterocyclyl is, Saturated and partially unsaturated 5- to 6-membered heterocyclyls, 5-membered heteroaryls, and 6-membered heteroaryls. Selected from the group consisting of phenyl or heterocyclyl, where the phenyl or heterocyclyl is a halogen n, =O (oxo), -CN, C1-C4 alkyl, C3-C4 cycloalkyl, C1- From the group consisting of C4 haloalkyl, C1-C4 alkoxy, and C1-C4 haloalkoxy, [May be substituted with 1 to 3 substituents selected for their respective properties]; Independently selected from group A consisting of; And, The substituents in the remaining 1-2 cases are: Halogen, -CN, SF5-NO2, C1-C3 alkyl, C1-C3 haloalkyl , C1-C3 alkoxy, C1-C3 haloalkoxy and C1-C3 haloalkylthio; Each is independently selected from group B, which consists of; R 3a , R 3b teeth, Hydrogen, halogens and -CN; and, C1-C4 alkyl [wherein the alkyl is hydroxy, -CN, -COOH, - CONH2, -NO2, -NH2, C1-C4 alkyl, C3-C6 cycloalkyl, C 1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 Alkylthio, C1-C4 alkylsulfinyl, C1-C4 alkylsulfonyl, C1 -C4 haloalkylthio, C1-C4 haloalkylsulfinyl, C1-C4 haloalkyl It may be substituted with 1 to 3 substituents independently selected from the group consisting of sulfonyls. ]; and, C3-C6 cycloalkyl [wherein the cycloalkyl is a halogen, -CN, -C OOH, -CONH2, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cyk Selected from the group consisting of hydroxyalkyl, C1-C4 alkoxy, and C1-C4 haloalkoxy. [may be substituted with 1-2 substituents]; and, C1-C4 haloalkyl [wherein the haloalkyl is hydroxy, -CN, C3- From the group consisting of C6 cycloalkyl, C1-C4 alkoxy, and C1-C4 haloalkoxy [May be substituted with 1-2 selected substituents]; Independently selected from the group consisting of; R 4 Here, the pyridine is a pyridine, pyrimidine, pyrazine, or pyridazine. Pyrimidines, pyrazines, or pyridazines are Halogen, hydroxyl, C1-C3 alkyl, C3-C4 cycloalkyl, C1-C Two to three substitutions independently selected from the group consisting of 3-haloalkyl and C1-C3 alkoxy compounds. It is substituted with the base; Or, R 4 Here, the pyridine is a pyridine, pyrimidine, pyrazine, or pyridazine. Pyrimidines, pyrazines, or pyridazines are substituted with a total of 1 to 3 substituents, however And substituents of at least 1 and up to 2 are, -CN, -COOH, -NO2, -SF5, -NH2, substituted C3-C4 cells Chloalkyl; and, C1-C3 alkyl and C1-C3 alkoxy [wherein these are all C1-C3 alkyl and C1-C3 alkoxy] N,-CO2C1-C4 alkyl,-CONH2,SF5,-SO2NH2,C3-C4 Cycloalkyl, -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2, N- C1-C4 alkanoylamino, C1-C4 alkyl, C1-C4 haloalkyl, C 1-C4 alkoxycarbonyl, C6-,C 10 -,C 14 -Aryloxycarbonyl , C1-C4 alkanoyl, C1-C4 alkylthio, C1-C4 haloalkylthio, C 3-C4 cycloalkylthio, C1-C4 alkylsulfinyl, C1-C4 haloalkyl Lusulfinyl, C1-C4 alkylsulfonyl, C1-C4 haloalkylsulfonyl, -SO2-NH(C1-C4 alkyl), -SO2-N(C1-C4 alkyl)2, N- C1-C4 alkylaminocarbonyl, N,N-di-C1-C4 alkylaminocarbonyl Lu, N-C1-C4 Alkanoylaminocarbonyl, N-C1-C4 Alkanoyl-N- C1-C4 alkylaminocarbonyl, heterocyclyl, heteroaryl, and bilayer Substituents that are bonded via a bond, for example, C1-C4 alkylides (e.g., methylides) From the group consisting of (a) or ethylidene, an oxo group, an imino group, and a substituted imino group, [Substituted with 1-2 substituents selected for their respective properties] ; and, -CO2-C1-C4 alkyl, C4-C6 haloalkyl, C1-C4 haloalcohydrate C1-C4 alkylthio, C1-C4 alkylsulfinyl, C1-C4 alkyls Sulfonyl, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfi Nyl, C3-C6 cycloalkylsulfonyl, C1-C4 haloalkylthio, C1-C4 Haloalkylsulfinyl, C1-C4 haloalkylsulfonyl, -NH(C1-C4 Lukil), -N(C1-C4 alkyl)2, -C(=NOC1-C4 alkyl)H, -C (=NOC1-C4alkyl)-C1-C4alkyl; and, Phenyl and 5-6 member heteroaryl [wherein the phenyl or 5-6 member heteroaryl] The ions are halogen, -CN, and C1-C4, which may be substituted in either case. Alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C3 alkoxy , C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfini C1-C3 alkylsulfonyl, C3-C6 cycloalkylthio, C3-C6 cyclo Alkyl sulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkyl From thio, C1-C3 haloalkylsulfinyl and C1-C3 haloalkylsulfonyl It may be substituted with 1 to 3 substituents independently selected from the group; and, Substructures S1-S6 below: [ka] [Here, The binding to the pyridine, pyrimidine, pyrazine, or pyridazine is marked with a #. And Z is CO or CS, and Y 1 It is selected independently of CO or SO2. ; R 41 is hydrogen, or a C1-C4 alkyl which may be substituted in either case. C1-C4 haloalkyl, C3-C6 cycloalkyl, C1-C4 alkyl-C3-C6 They are cycloalkyl and phenyl; R 42 This includes hydrogen and, in either case, a C1-C4 alkyl group which may be substituted. , C1-C4 haloalkyl and C3-C6 cycloalkyl; R43 In either case, the C1-C4 alkyl and C1-C4 alkyl groups may be substituted. [Independently selected from C3-C6 cycloalkyl, C3-C6 cycloalkyl, and phenyl]; Independently selected from group A consisting of; And, The substituents in the remaining 1-2 cases are: Halogens and hydroxyls; and, C1-C4 alkyl, C3-C6 cycloalkyl, C1-C4 haloalkyl and C1 -C4 alkoxy; Each is independently selected from group B, which consists of; Or, R 4 is a 5-membered heteroaryl, where the heteroaryl is Halogen, hydroxyl, -CN, -COOH, -NO2, -SF5, -NH2; and , -CO2-C1-C4 alkyl, C1-C4 alkyl, C3-C6 cycloalkyl, C1-C4 haloalkyl, C1-C4 alkyl, C1-C4 haloalkyl, C1-C 4-alkylthio, C1-C4 alkylsulfinyl, C1-C4 alkylsulfonyl, C 3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3- C6 cycloalkylsulfonyl, C1-C4 haloalkylthio, C1-C4 haloalkyl Sulfinyl, C1-C4 haloalkylsulfonyl, -NH(C1-C4 alkyl), - N(C1-C4alkyl)2, -C(=NOC1-C4alkyl)H, -C(=NOC1 -C4alkyl)-C1-C4alkyl; and, Phenyl and 5-6 member heteroaryl [wherein the phenyl or 5-6 member heteroaryl] The ions are halogen, -CN, and C1-C4, which may be substituted in either case. Alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C3 alkoxy , C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfini C1-C3 alkylsulfonyl, C3-C6 cycloalkylthio, C3-C6 cyclo Alkyl sulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkyl Thio, C1-C3 haloalkylsulfinyl and C1-C3 haloalkylsulfonyl; and Beauty, Substructures S1-S6 [where the bond to the 5-membered heteroaryl is marked with a #] ri, and Z are CO or CS, and Y 1 This is selected independently of CO or SO2. [to be done]; They may be substituted with 1 to 3 substituents independently selected from the group consisting of; R 5 teeth, Hydrogen, halogens; and, C3-C6 cycloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, ( C1-C4 Alkyl)2CH-,-CO2C1-C4 Alkyl,-C(=NOC1-C 4alkyl)H, -C(=NOC1-C4alkyl)-C1-C4alkyl; and, C1-C4 alkyl and C1-C4 haloalkyl [wherein the C1-C4 alkyl and C1-C4 haloalkyls are, Halogen, =O (oxo), =S (thiono), hydroxyl, -CN, -NO2, - SF5, -SiMe3; and, In either case, the C3-C6 cycloalkyl and C1-C6 a(C6) atoms may be substituted. Lucoxy, C1-C6 haloalkoxy; [May be substituted with 1 to 3 substituents selected from the group consisting of ] Selected from the group consisting of: It is a compound represented by [formula].
[0014] What is preferable is (Construction 2-2), and furthermore, equation (I) [in the equation, X is either O or S; Y is either a direct bond or CH2; R 1 is hydrogen; C1-C3 alkyl [where the alkyl is -CN, -CONH2, Substituted with one substituent selected from -COOH, -NO2, and -Si(CH3)3 [May be]; C1-C3 haloalkyl; C2-C4 alkenyl; C2-C4 haloalkenyl C2-C4 alkynyl; C2-C4 haloalkynyl; C3-C4 cycloalkyl-C 1-C2 alkyl-[where the C3-C4 cycloalkyl is one or two halogens [may be substituted with an atom]; oxetane-3-yl-CH2-; or benzyl [this In this case, the benzyl may be substituted with a halogen atom or a C1-C3 haloalkyl group. ] and; R 2 These are phenyl, pyridine, pyrimidine, pyrazine, or pyridazine, where, The phenyl, pyridine, pyrimidine, pyrazine, or pyridazine has a total of 1 to 3 substituents. It is substituted with, however, the substituent is adjacent to the carbon bonded to the C=X group. None of these carbon atoms are present, and there are at least one and at most two substituents. C3-C6 cycloalkoxy [where the cycloalkoxy is, Halogen, =O (oxo), -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C3-C4 halocycloalkyl , C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1- C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkyl kylthio, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl It may be substituted with 1-2 substituents selected from the group consisting of yl compounds. Or, C1-C3 alkyl [where the alkyl is, -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 haloalkyl Coxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkyl Sulfonyl, C3-C4 cycloalkylkylthio, C3-C4 cycloalkylsulf 1-2 substituents selected from the group consisting of ynyls and C3-C4 cycloalkylsulfonyls [It is replaced by...] Or, C1-C3 alkylcarbonyl and C3-C6 cycloalkylcarbonyl [where, The C1-C3 alkylcarbonyl and C3-C6 cycloalkylcarbonyl are Halogen, -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkyl Thio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 thio Chloalkylkylthio, C3-C4 cycloalkylsulfinyl, C3-C4 cyclo It may be substituted with one or two substituents selected from the group consisting of lucylsulfonyl; Or, C1-C3 alkoxy [where the alkoxy is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 haloalkyl [where the haloalkyl is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 haloalkoxy [where the haloalkoxy is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C2-C4 alkenyloxy [where the alkenyloxy is, Halogen, -CN, and C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 alkylSO2O-[where the alkylSO2O- is, Halogen, -CN, and C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, Phenyl-C1-C3 haloalkyl and phenyl-C1-C3 alkoxy [where, The phenyl is, Halogen, -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C3-C4 halocycloalkyl , C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1- C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkyl kylthio, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl It may be substituted with 1 to 3 substituents independently selected from the group consisting of yl compounds. Or, Heterocyclyloxy and heterocyclyl-C1-C3 alkoxy [where the heterocyclyloxy Rocyclyl is a saturated and partially unsaturated 4-6 member heterocyclyl, 5-member heteroaryl, Selected from a group consisting of 6-membered heteroaryls, where these are, Halogen, -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C3-C4 halocycloalkyl , C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1- C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkyl kylthio, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl It may be substituted with 1 to 3 substituents independently selected from the group consisting of yl compounds. Independently selected from the group consisting of; And, The substituents in the remaining cases are: Hydrogen, halogen, hydroxyl, -NH2, -CN, -NO2, C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkyl, C1-C3 haloalkyl, C1-C 3-alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C 3-C4 cycloalkylkylthio, C3-C4 cycloalkylsulfinyl, C3-C 4-Cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkyls Rufinyl and C1-C3 haloalkylsulfonyl; Selected from the group consisting of; R 3a , R 3b teeth, Hydrogen, halogens and -CN; and, C1-C4 alkyl [wherein the alkyl is hydroxy, halogen-CN,-CO] OH, -CONH2, -NO2, -NH2, C1-C4 alkyl, C3-C6 cycloal Kill, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C 1-C4 alkylthio, C1-C4 alkylsulfinyl, C1-C4 alkylsulfony C1-C4 haloalkylthio, C1-C4 haloalkylsulfinyl, C1-C4 Substituted with 1 to 3 substituents independently selected from the group consisting of roalkylsulfonyls [May be]; and, C3-C6 cycloalkyl [wherein the cycloalkyl is a halogen, -CN, -C OOH, -CONH2, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cyk Selected from the group consisting of hydroxyalkyl, C1-C4 alkoxy, and C1-C4 haloalkoxy. [may be substituted with 1-2 substituents]; and, C1-C4 haloalkyl [wherein the haloalkyl is hydroxy, -CN, C3- From the group consisting of C6 cycloalkyl, C1-C4 alkoxy, and C1-C4 haloalkoxy [May be substituted with 1-2 selected substituents]; Independently selected from the group consisting of; R 4 The following substructures T1~T6: [ka] One of the following is selected, where the binding to the triazole is marked with a #; Here, X 1 This is the following substructure S4-a [ka] [Here, The binding to the pyridine, pyrimidine, pyrazine, or thiazole is marked with a #; R 41 is hydrogen, or a C1-C4 alkyl which may be substituted in either case. C1-C4 haloalkyl, C3-C6 cycloalkyl, C1-C4 alkyl-C3-C6 They are cycloalkyl and phenyl; R 42 This includes hydrogen and, in either case, a C1-C4 alkyl group which may be substituted. , C1-C4 haloalkyl and C3-C6 cycloalkyl and; X 2 is -CN or X 1 and; R 5 is hydrogen, halogen; and C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C1- C4 alkoxy, C1-C4 haloalkoxy, (C1-C4 alkoxy)2CH-, -C O2C1-C4 alkyl, -C(=NOC1-C4 alkyl)H, -C(=NOC1-C 4 alkyl)-C1-C4 alkyl selected from the group is a compound represented by
[0015] What is preferable is (Configuration 2-3), and also, formula (I) [wherein X is O or S; Y is a direct bond or CH2; R 1 is hydrogen; C1-C3 alkyl [wherein the alkyl is substituted with one substituent selected from -CN, -CONH2, -COOH, -NO2 and -Si(CH3)3 and may be]; C1-C3 haloalkyl; C2-C4 alkenyl; C2-C4 haloalkenyl ; C2-C4 alkynyl; C2-C4 haloalkynyl; C3-C4 cycloalkyl-C 1-C2 alkyl - [wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-; or benzyl [where the benzyl may be substituted with a halogen atom or C1-C3 haloalkyl ; R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, wherein The phenyl, pyridine, pyrimidine, pyrazine, or pyridazine has a total of 1 to 3 substituents. It is substituted with, however, the substituent is adjacent to the carbon bonded to the C=X group. None of these carbon atoms are present, and there are at least one and at most two substituents. C3-C6 cycloalkoxy [where the cycloalkoxy is, Halogen, =O (oxo), -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C3-C4 halocycloalkyl , C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1- C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkyl kylthio, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl It may be substituted with 1-2 substituents selected from the group consisting of yl compounds. Or, C1-C3 alkyl [where the alkyl is, -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 haloalkyl Coxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkyl Sulfonyl, C3-C4 cycloalkylkylthio, C3-C4 cycloalkylsulf 1-2 substituents selected from the group consisting of ynyls and C3-C4 cycloalkylsulfonyls [It is replaced by...] Or, C1-C3 alkylcarbonyl and C3-C6 cycloalkylcarbonyl [where, The C1-C3 alkylcarbonyl and C3-C6 cycloalkylcarbonyl are Halogen, -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkyl Thio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 thio Chloalkylkylthio, C3-C4 cycloalkylsulfinyl, C3-C4 cyclo It may be substituted with one or two substituents selected from the group consisting of lucylsulfonyl; Or, C1-C3 alkoxy [where the alkoxy is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 haloalkyl [where the haloalkyl is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 haloalkoxy [where the haloalkoxy is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C2-C4 alkenyloxy [where the alkenyloxy is, Halogen, -CN, and C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 alkylSO2O-[where the alkylSO2O- is, Halogen, -CN, and C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, Phenyl-C1-C3 haloalkyl and phenyl-C1-C3 alkoxy [where, The phenyl is, Halogen, -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C3-C4 halocycloalkyl , C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1- C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkyl kylthio, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl It may be substituted with 1 to 3 substituents independently selected from the group consisting of yl compounds. Or, Heterocyclyloxy and heterocyclyl-C1-C3 alkoxy [where the heterocyclyloxy Rocyclyl is a saturated and partially unsaturated 4-6 member heterocyclyl, 5-member heteroaryl, Selected from a group consisting of 6-membered heteroaryls, where these are, Halogen, -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C3-C4 halocycloalkyl , C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1- C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkyl kylthio, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl It may be substituted with 1 to 3 substituents independently selected from the group consisting of yl compounds. Independently selected from the group consisting of; And, The substituents in the remaining cases are: Hydrogen, halogen, hydroxyl, -NH2, -CN, -NO2, C1-C3 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C3 alkyl, C1-C 3-haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1- C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C4 cycloal Cylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio , C1-C3 haloalkylsulfinyl and C1-C3 haloalkylsulfonyl; Selected from the group consisting of; R 3a , R 3b teeth, Hydrogen, halogens and -CN; and, C1-C4 alkyl [wherein the alkyl is hydroxy, halogen-CN,-CO] OH, -CONH2, -NO2, -NH2, C1-C4 alkyl, C3-C6 cycloal Kill, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C 1-C4 alkylthio, C1-C4 alkylsulfinyl, C1-C4 alkylsulfony C1-C4 haloalkylthio, C1-C4 haloalkylsulfinyl, C1-C4 Substituted with 1 to 3 substituents independently selected from the group consisting of roalkylsulfonyls [May be]; and, C3-C6 cycloalkyl [wherein the cycloalkyl is a halogen, -CN, -C OOH, -CONH2, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cyk Selected from the group consisting of hydroxyalkyl, C1-C4 alkoxy, and C1-C4 haloalkoxy. [may be substituted with 1-2 substituents]; and, C1-C4 haloalkyl [wherein the haloalkyl is hydroxy, -CN, C3- From the group consisting of C6 cycloalkyl, C1-C4 alkoxy, and C1-C4 haloalkoxy [May be substituted with 1-2 selected substituents]; Independently selected from the group consisting of; R 4 The following substructures T1~T6: [ka] One of the following is selected, where the binding to the triazole is marked with a #; Here, X 1 This is the following substructure S4-a [Chemical formula] [Here, the bond to the pyridine, pyrimidine, pyrazine or thiazole is marked with #; R 41 is hydrogen, or C1-C4 alkyl which may be substituted in any case, C1-C4 haloalkyl, C3-C6 cycloalkyl, C1-C4 alkyl-C3-C6 cycloalkyl and phenyl; R 42 is hydrogen, as well as C1-C4 alkyl which may be substituted in any case , C1-C4 haloalkyl and C3-C6 cycloalkyl) is; X 2 is -CN or X 1 is; R 5 is hydrogen, halogen; and C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C1- C4 alkoxy, C1-C4 haloalkoxy, (C1-C4 alkoxy)2CH-, -C O2C1-C4 alkyl, -C(=NOC1-C4 alkyl)H, -C(=NOC1-C 4 alkyl)-C1-C4 alkyl selected from the group] is a compound represented by.
[0016] What is even more preferable is (Configuration 3-1), formula (I) [wherein, X is O or S; Y is a direct bond; R 1 is hydrogen; C1-C3 alkyl [where the alkyl may be substituted with 1 substituent selected from -CN, -NO2 and - Si(CH3)3]; C3-C4 cyclo cycloalkyl-C1-C2 alkyl-[where the C3-C4 cycloalkyl group is one or [May be substituted with two halogen atoms]; or benzyl [where the benzyl is [may be substituted with a halogen atom or a C1-C3 haloalkyl group]; R 2 is phenyl or pyridine, where the phenyl or pyridine is 1-2 The molecule may be substituted with a substituent, provided that the substituent is adjacent to the carbon atom bonded to the C=X group. None of the carbon atoms present, and at least one and up to two substituents are present. Hydroxy, and C3-C6 cycloalkoxy, -OCO-C1-C3 alkyl, -OSO2-C1-C3 alkyl, C2-C4 alkenyl, C2-C4 haloalkenyl; And, Phenoxy [wherein the phenoxy is a halogen, -CN, C1-C3 alkyl and Each molecule is independently substituted with 1-2 substituents selected from the group consisting of C1-C3 haloalkyl groups. [May be replaced]; and, Heterocyclyloxy [where the heterocyclyl contains one oxygen atom] [Selected from the group consisting of saturated 4-6 member heterocyclines]; and, C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 haloalkyl, C1- C3 alkoxy, C2-C4 alkenyloxy and C2-C4 haloalkenyloxy [ Herein, the C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 haloalkoxy, C 1-C3 alkoxy, C2-C4 alkenyloxy and C2-C4 haloalkenyloxy teeth, Halogen, =O (oxo), -CN; and, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; and, Phenyl-C1-C3 haloalkyl, phenyl-C1-C3 alkoxy and heteroalkyl Kryl-C1-C3 alkyl [wherein the heterocyclyl is pyrazolyl, triazolyl] Selected from the group consisting of and tetrazolyl, and said phenyl or heterocyclyl, Halogen, =O (oxo), -CN, C1-C3 alkyl, C3-C4 cycloalkyl, A group consisting of C1-C3 haloalkyl, C1-C3 alkoxy, and C1-C3 haloalkoxy. [may be substituted with 1 to 3 substituents independently selected from; and, Heterocyclyl-C1-C3 alkoxy [where the heterocyclyl is one oxygen atom] [Selected from the group consisting of saturated 4-6 member heterocyclines containing atoms]; Independently selected from group A consisting of; And, The substituents in the remaining cases are: Halogen, hydroxy, -NH2, -CN, SF5, -COOH, -CONH2, - NO2, C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkyl, C1- C3 haloalkoxy and C1-C3 haloalkylthio; Selected from group B consisting of; R 3a , R 3b is hydrogen; C1-C3 alkyl [where the alkyl is a halogen, - Independently selected from the group consisting of CN, C3-C4 cycloalkyl, and C1-C3 alkoxy. [May be substituted with 1-3 substituents]; C3-C4 cycloalkyl; C1-C Independently selected from the group consisting of 3-haloalkyl groups; R 4 Here, the pyridine is a pyridine, pyrimidine, pyrazine, or thiazole. Pyrimidines, pyrazines, or thiazoles are substituted with a total of 1 to 2 substituents, however And the substituents of 1 are -CN, -NO2, -NH2, substituted C3-C4 cycloalkyl, C1-C 4-haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1- C3 alkylsulfonyl, C3-C4 cycloalkylsulfanyl, C3-C4 cyclo Lucylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkyl O, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, -CO 2C1-C3 alkyl, -C(=NOC1-C3 alkyl)H, -C(=NOC1-C3 Alkyl)-C1-C3 alkyl; and, The following substructures S1, S2, S4 and S5: [ka] [Here, The # symbol indicates the attachment to pyridine, pyrimidine, pyrazine, pyridazine, or thiazole. It is stated that Z is CO or CS: Selected from group A consisting of; And, The substituents in the remaining cases are: Halogen, -CN; and, C1-C3 alkyl, C3-C4 cycloalkyl, C1-C3 haloalkyl, C1- C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkoxy C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1 -C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, C3-C4 cyclo C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfinyl Lucyl sulfonyl; Selected from group B consisting of; R 41 These are hydrogen, C1-C3 alkyl, C1-C3 haloalkyl and C3-C4 cyclo It is a chloroalkyl; R 42 These are hydrogen, C1-C3 alkyl, and C1-C3 haloalkyl; R 43 These are C1-C3 alkyl, C1-C3 haloalkyl and C3-C4 cycloalkyl It's a kill; R 5 These are hydrogen, halogen, C1-C3 alkyl, C1-C3 haloalkyl, and C3-C4 [It is a cycloalkyl or C1-C3 alkoxy.] It is a compound represented by [formula].
[0017] Similarly, even more preferable is (Configuration 3-2), formula (I) [wherein, X is either O or S; Y is a direct bond; R 1 is hydrogen; C1-C3 alkyl [where the alkyl is -CN, -NO2 and - [May be substituted with one substituent selected from Si(CH3)3]; C3-C4 cyclamate cycloalkyl-C1-C2 alkyl-[where the C3-C4 cycloalkyl group is one or [May be substituted with two halogen atoms]; or benzyl [where the benzyl is [may be substituted with a halogen atom or a C1-C3 haloalkyl group]; R 2 is phenyl or pyridine, where the phenyl or pyridine is 1-2 It is substituted with a substituent, however, the substituent is adjacent to the carbon bonded to the C=X group. None of the carbon atoms are present, and there are at least one and at most two substituents. C3-C6 cycloalkoxy [where the cycloalkoxy is, One or two substituents selected from the group consisting of halogens, -CN, and C1-C3 alkyl groups. [May be replaced with]; Or, C1-C3 alkyl [where the alkyl is, -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 alkylcarbonyl and C3-C4 cycloalkylcarbonyl [where, The alkylcarbonyl and cycloalkylcarbonyl are Halogen, -CN, Selected from the group consisting of C3-C4 cycloalkyl and C3-C4 halocycloalkyl. [May be substituted with 1-2 substituents]; Or, C1-C3 alkoxy [where the alkoxy is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 haloalkyl [where the haloalkyl is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 haloalkoxy [where the haloalkoxy is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C2-C4 alkenyloxy [where the alkenyloxy is, Halogen, -CN, and C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 alkylSO2O-[where the alkylSO2O- is, Halogen, -CN, and C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, Phenyl-C1-C3 haloalkyl and phenyl-C1-C3 alkoxy [where, The phenyl is, Halogen, -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C1-C3 haloalkyl, C1 1-3 independently selected from the group consisting of -C3 alkoxy and C1-C3 haloalkoxy. [May be substituted with substituents]; Or, Heterocyclyloxy and heterocyclyl-C1-C3 alkoxy [where the heterocyclyloxy Rocyclyl is a group consisting of saturated 4-6 member heterocyclyls containing one oxygen atom. Selected, and said heterocyclylphenyl, Halogen, -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C1-C3 haloalkyl, C1 1-3 independently selected from the group consisting of -C3 alkoxy and C1-C3 haloalkoxy. [May be substituted with substituents]; Independently selected from the group consisting of; And, The substituents in the remaining cases are: Hydrogen, halogen, hydroxyl, -NH2, -CN, -NO2, C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkyl, C1-C3 haloalkyl, C1-C 3-alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C 3-C4 cycloalkylkylthio, C3-C4 cycloalkylsulfinyl, C3-C 4-Cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkyls Rufinyl and C1-C3 haloalkylsulfonyl; Selected from the group consisting of; R 3a , R 3b is hydrogen; C1-C3 alkyl [where the alkyl is a halogen, - From CN, C3-C4 cycloalkyl, C1-C3 alkoxy, and C1-C3 haloalkyl From the group consisting of: [may be substituted with 1 to 3 substituents independently selected from the group] Independently selected; R 4 The following substructures T1~T6: [ka] One of the following is selected, where the binding to the triazole is marked with a #; Here, X 1 This is the following substructure S4-a [ka] [Here, The binding to the pyridine, pyrimidine, pyrazine, or thiazole is marked with a #; R 41 This is hydrogen, C1-C3 alkyl, C1-C3 cyanoalkyl, C1-C3 halo It is a lucyl and C3-C4 cycloalkyl; R42 These are hydrogen, C1-C3 alkyl, and C1-C3 haloalkyl. and; X 2 is -CN or X 1 and; R 5 These are hydrogen, halogen, C1-C3 alkyl, C1-C3 haloalkyl, and C3-C4 [It is a cycloalkyl or C1-C3 alkoxy.] It is a compound represented by [formula].
[0018] Similarly, even more preferable is (Configuration 3-3), formula (I) [wherein, X is either O or S; Y is a direct bond; R 1 is hydrogen; C1-C3 alkyl [where the alkyl is -CN, -NO2 and - [May be substituted with one substituent selected from Si(CH3)3]; C3-C4 cyclamate cycloalkyl-C1-C2 alkyl-[where the C3-C4 cycloalkyl group is one or [May be substituted with two halogen atoms]; or benzyl [where the benzyl is [may be substituted with a halogen atom or a C1-C3 haloalkyl group]; R 2 is phenyl or pyridine, where the phenyl or pyridine is 1-2 It is substituted with a substituent, however, the substituent is adjacent to the carbon bonded to the C=X group. None of the carbon atoms are present, and there are at least one and at most two substituents. C3-C6 cycloalkoxy [where the cycloalkoxy is, One or two substituents selected from the group consisting of halogens, -CN, and C1-C3 alkyl groups. [May be replaced with]; Or, C1-C3 alkyl [where the alkyl is, -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 alkylcarbonyl and C3-C4 cycloalkylcarbonyl [where, The alkylcarbonyl and cycloalkylcarbonyl are Halogen, -CN, Selected from the group consisting of C3-C4 cycloalkyl and C3-C4 halocycloalkyl. [May be substituted with 1-2 substituents]; Or, C1-C3 alkoxy [where the alkoxy is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 haloalkyl [where the haloalkyl is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 haloalkoxy [where the haloalkoxy is, =O(oxo), -CN, C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C2-C4 alkenyloxy [where the alkenyloxy is, Halogen, -CN, and C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, C1-C3 alkylSO2O-[where the alkylSO2O- is, Halogen, -CN, and C3-C4 cycloalkyl, C3-C4 halocycloalkyl, C1-C3 alkoxy C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfite Nyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C Selected from the group consisting of 4-cycloalkylsulfinyl and C3-C4 cycloalkylsulfonyl [Substituted with 1-2 selected substituents]; Or, Phenyl-C1-C3 haloalkyl and phenyl-C1-C3 alkoxy [where, The phenyl is, Halogen, -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C1-C3 haloalkyl, C1 1-3 independently selected from the group consisting of -C3 alkoxy and C1-C3 haloalkoxy. [May be substituted with substituents]; Or, Heterocyclyloxy and heterocyclyl-C1-C3 alkoxy [where the heterocyclyloxy Rocyclyl is a group consisting of saturated 4-6 member heterocyclyls containing one oxygen atom. Selected, and said heterocyclylphenyl, Halogen, -CN, C1-C3 alkyl, C3-C4 cycloalkyl, C1-C3 haloalkyl, C1 1-3 independently selected from the group consisting of -C3 alkoxy and C1-C3 haloalkoxy. [May be substituted with substituents]; Independently selected from the group consisting of; And, The substituents in the remaining cases are: Hydrogen, halogen, hydroxyl, -NH2, -CN, -NO2, C1-C3 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C3 alkyl, C1-C 3-haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1- C3 alkylsulfonyl, C3-C4 cycloalkylkylthio, C3-C4 cycloal Cylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio , C1-C3 haloalkylsulfinyl and C1-C3 haloalkylsulfonyl; Selected from the group consisting of; R 3a , R 3b is hydrogen; C1-C3 alkyl [where the alkyl is a halogen, - From CN, C3-C4 cycloalkyl, C1-C3 alkoxy, and C1-C3 haloalkyl From the group consisting of: [may be substituted with 1 to 3 substituents independently selected from the group] Independently selected; R 4 The following substructures T1~T6: [ka] One of the following is selected, where the binding to the triazole is marked with a #; Here, X 1 This is the following substructure S4-a [ka] [Here, The binding to the pyridine, pyrimidine, pyrazine, or thiazole is marked with a #; R 41 This is hydrogen, C1-C3 alkyl, C1-C3 cyanoalkyl, C1-C3 halo It is a lucyl and C3-C4 cycloalkyl; R 42 These are hydrogen, C1-C3 alkyl, and C1-C3 haloalkyl. and; X 2 is -CN or X 1 and; R 5 These are hydrogen, halogen, C1-C3 alkyl, C1-C3 haloalkyl, and C3-C4 [It is a cycloalkyl or C1-C3 alkoxy.] It is a compound represented by [formula].
[0019] What is particularly preferable is(Construction 4-1) is Equation (I) [wherein, X is O; Y is a direct bond; R 1 is hydrogen; R 2 The following is a substructure Q1: [ka] [Here, the bond to the C=X- group is marked with a '#'.] Selected from; R 21 teeth, Hydroxy, cyanomethyl, 1-cyanoethyl, 2-cyanopropan-2-yl, cyanopropyl Clopropyl(difluoromethyl), (methylsulfanyl)methyl, (methylsulf (Nyl)methyl, (methylsulfonyl)methyl, 2-ethoxy-1,1-difluoro-2- Oxoethyl, (methylsulfanyl)methoxy, (methylsulfinyl)methoxy, (Methylsulfonyl)methoxy, 1-cyano-1-methylethoxy, oxetane-3- Iloxy, tetrahydro-2H-pyran-4-yloxy, tetrahydro-2H-pyran 4-ylmethoxy, (3,3-dichloropropane-2-en-1-yl)oxy, (2 ,3,3-trichloropropane-2-en-1-yl)oxy, (2,2-difluorocycline (2,2-dichlorocyclopropyl)methoxy, (1,2,2- Trichlorocyclopropyl(methoxy), cyclopropyloxy, cyclobutyloxy, cy Clopentyloxy, cyclopropylmethoxy, 2,2-dichlorovinyl, (3,4-di Methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl) Methyl, acetoxy, cyclopropylcarbonyl, methanesulfonyloxy; or, Benzyloxy, 1-phenylethoxy, phenoxy, pyrazole-1-ylmethyl or difluoro(phenyl)methyl [wherein the benzyloxy, 1-phenylethoxy] Phenoxy, pyrazole-1-ylmethyl, or difluoro(phenyl)methyl are halos. Selected from the group consisting of gen, CN, C1-C3 alkyl, and C1-C3 haloalkyl. It may be substituted with one substituent; R 22 These are hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, isopropyl L, difluoromethyl, trifluoromethyl, difluoromethoxy or trifluoromethyl It is Kishi; R 3a is hydrogen; R 3b is selected from the group consisting of hydrogen and methyl; R 4 The following are substructures S50, S51 and S52: [ka] [Here, the binding to the triazole is marked with a '#'.] Selected from one of the following; X 41 -CN and -CONR 41 R 42 Selected from; X 42 -CN and -CONR 41 R 42 Selected from; X 43 -CN, -NO2 and -CONR 41 R 42 Selected from; R 41 These are hydrogen, methyl, ethyl, or cyclopropyl; R 42 is hydrogen, methyl, or ethyl; R 5 [These are hydrogen, methyl, ethyl, cyclopropyl, methoxy, or ethoxy.] It is a compound represented by [formula].
[0020] Similarly, particularly preferred is (Configuration 4-2), formula (I) [wherein, X is O; Y is a direct bond; R 1 is hydrogen; R 2 The following are substructures Q1 and Q2: [ka] [Here, the bond to the C=X- group is marked with a '#'.] Selected from; Here, R 21 These are cyclopropyl oxy, (2,2-dichlorocyclopropyl)oxy, and cy Anomethyl, 2-cyanopropan-2-yl, cyclopropyl(difluoromethyl), 2 -Cyanopropane-2-yloxy, cyclopropylmethoxy, (2,2-difluorocy) (Clopropyl)methoxy, (2,2-dichlorocyclopropyl)methoxy, (3,3-di (Chloropropane-2-en-1-yl)oxy, (2,3,3-trichloropropane-2-yl) It is 1-yl(I)oxy; R 22 These are hydrogen, fluorine, chlorine, bromine, iodine, difluoromethyl, and trifluoromethyl. Tyl, difluoromethoxy, trifluoromethoxy, methylsulfonyl, difluorometh It is either sulfonyl or trifluoromethylsulfonyl; R 3a is hydrogen; R 3b is hydrogen or methyl; R 4 The following substructures T1~T6: [ka] [Here, the binding to the triazole is marked with a '#'.] Selected from one of the following; Here, X 1 The following is a substructure S4-a: [ka] [Here, The binding to the pyridine, pyrimidine, pyrazine, or thiazole is marked with a #; R 41 These are hydrogen, methyl, ethyl, or cyclopropyl; R 42 [These are hydrogen, methyl, or ethyl.] and; X 2 is -CN or X 1 and; R 5 [These are hydrogen, methyl, ethyl, or cyclopropyl.] It is a compound represented by [formula].
[0021] Similarly, particularly preferred is (Configuration 4-3), formula (I) [wherein, X is O; Y is a direct bond; R 1 is hydrogen; R 2 The following are substructures Q1 and Q2: [ka] [Here, the bond to the C=X- group is marked with a '#'.] Selected from; Here, R 21 These are cyclopropyl oxy, (2,2-dichlorocyclopropyl)oxy, and cy Anomethyl, 2-cyanopropan-2-yl, cyclopropyl (difluoromethyl), cyanopropyl Clopropylcarbonyl, 2-cyanopropane-2-yloxy, cyclopropylmethoxy C, (2,2-difluorocyclopropyl)methoxy, (2,2-dichlorocyclopropyl (Lu)methoxy, (3,3-dichloropropane-2-en-1-yl)oxy, (2,3,3 -Trichloropropane-2-en-1-yl)oxy, difluoro-(4-fluorophenyl) It is methyl; R 22 These are hydrogen, fluorine, chlorine, bromine, iodine, cyclopropyl, and difluoromethyl Trifluoromethyl, difluoromethoxy, trifluoromethoxy, methylsulfonyl , difluoromethylsulfonyl or trifluoromethylsulfonyl; R 3a is hydrogen; R 3b is hydrogen or methyl; R 4 The following substructures T1~T6: [ka] [Here, the binding to the triazole is marked with a '#'.] Selected from one of the following; Here, X 1 The following is a substructure S4-a: [ka] [Here, The binding to the pyridine, pyrimidine, pyrazine, or thiazole is marked with a #; R 41 These are hydrogen, methyl, ethyl, or cyclopropyl; R 42 [These are hydrogen, methyl, or ethyl.] and; X 2 is -CN or X 1 and; R 5 [These are hydrogen, methyl, ethyl, or cyclopropyl.] It is a compound represented by [formula].
[0022] What is extremely preferable is (Configuration 5-1), formula (I) [wherein, X is O; Y is a direct bond; R 1 is hydrogen; R 2 These are 3-(1-cyanoethyl)phenyl and 3-(2,3,3-trichloroallyl) Xy)-5-(trifluoromethyl)phenyl,3-(2-cyanopropan-2-yl) -5-(trifluoromethoxy)phenyl,3-(2-cyanopropan-2-yl)-5 -(trifluoromethyl)phenyl,3-(2-cyanopropan-2-yl)-5-iso Propylphenyl, 3-(3,3-dichloroallyloxy)-5-(trifluoromethyl ) Phenyl, 3-(cyanomethyl)-5-fluorophenyl, 3-(cyanomethyl) phenyl Nyl, 3-(cyclopropylmethoxy)-5-methylphenyl, 3-(methylsulfini (Ilmethoxy)-5-(trifluoromethyl)phenyl, 3-(oxan-4-ylmethoxy (C)-5-(trifluoromethyl)phenyl,3-(oxan-4-yloxy)-5- (trifluoromethyl)phenyl, 3-[(2,2-dichlorocyclopropyl)methoxy] ]-5-(trifluoromethyl)phenyl,3-[(2-chlorophenyl)methoxy]- 5-(trifluoromethyl)phenyl, 3-[(3-chlorophenyl)methoxy]-5- (Trifluoromethyl)phenyl, 3-[(4-chlorophenyl)methoxy]-5-( (Lifluoromethyl)phenyl, 3-[1-(2-chlorophenyl)ethoxy]-5-( (Lifluoromethyl)phenyl, 3-[1-(3-chlorophenyl)ethoxy]-5-( (Lifluoromethyl)phenyl, 3-[1-(4-chlorophenyl)ethoxy]-5-( (Lifluoromethyl)phenyl, 3-acetyloxy-5-chlorophenyl, 3-benzyl Oxy-5-(trifluoromethyl)phenyl, 3-bromo-5-(2,2-dichlorophenyl Ten-1-yl)phenyl, 3-bromo-5-(2,3,3-trichloroallyloxy) Phenyl, 3-bromo-5-[difluoro-(4-fluorophenyl)methyl]phenyl , 3-bromo-5-cyclopropyloxyphenyl, 3-chloro-5-(2-cyanopropyl Pan-2-yl)phenyl, 3-chloro-5-(4-chlorophenoxy)phenyl, 3- Chloro-5-(4-fluorophenoxy)phenyl, 3-chloro-5-(cyanomethyl) Phenyl, 3-chloro-5-(cyclopropylcarbonyl)phenyl, 3-chloro-5- (methylsulfonylmethyl)phenyl, 3-chloro-5-[(3,4-dimethyl-5-o Xo-4,5-dihydro-1H-1,2,4-triazol-1-yl)methyl]phen 3-chloro-5-[[4-(trifluoromethyl)-1H-pyrazole-1-yl] Methylphenyl, 3-chloro-5-methylsulfonyloxyphenyl, 3-chloro-5 -Phenoxyphenyl, 3-cyclobutyloxy-5-methylphenyl, 3-cyclopene Tyloxy-5-methylphenyl, 3-hydroxy-5-(trifluoromethyl)phenyl It is either 3-methyl-5-(oxetane-3-yloxy)phenyl or 3-methyl-5-(oxetane-3-yloxy)phenyl; R 3a is hydrogen; R 3b It is methyl; R 4 These are 5-cyanopyridine-2-yl and 5-cyano-1,3-thiazole-2-yl , 5-(dimethylaminocarbonyl)-1,3-thiazole-2-yl or 5-nitro- It is 1,3-thiazole-2-yl; R 5 [These are hydrogen, methyl, cyclopropyl, or methoxy.] It is a compound represented by [formula].
[0023] Similarly, what is extremely preferable is (Configuration 5-2), formula (I) [wherein, X is O; Y is a direct bond; R 1 is hydrogen; R 2 teeth, 3-Bromo-5-(cyclopropoxy)phenyl, 3-cyclopropyloxy-5- (trifluoromethoxy)phenyl, 3-bromo-5-(2,2-dichlorocyclopropyl) (Lu) oxyphenyl, 3-Chloro-5-(cyanomethyl)phenyl, 3-(cyanomethyl)-5-(trif (Luoromethoxy)phenyl, 3-chloro-5-(2-cyanopropan-2-yl)phenyl Lu, 3-(2-cyanopropan-2-yl)-5-(trifluoromethyl)phenyl, 3 -(2-cyanopropan-2-yl)-5-(trifluoromethoxy)phenyl, 3-( 2-Cyanopropan-2-yl)-5-methylsulfonylphenyl, 3-Chloro-5-(2-cyanopropan-2-yloxy)phenyl, 3-bromo- 5-(2-cyanopropan-2-yloxy)phenyl, 3-Bromo-5-[cyclopropyl(difluoro)methyl]phenyl, 3-Bromo-5-[(2,2-difluorocyclopropyl)methoxy]phenyl, 3 -bromo-5-[(2,2-dichlorocyclopropyl)methoxy]phenyl, 3-[(2 ,2-dichlorocyclopropyl)methoxy]-5-(trifluoromethyl)phenyl, 3-[(2,3,3-trichloropropane-2-en-1-yl)oxy]-5-(to (Lifluoromethyl)phenyl, 3-bromo-5-[(2,3,3-trichloropropane-2) -en-1-yl)oxy]phenyl, or, It is 2-chloro-6-(2-cyanopropan-2-yl)pyridine-4-yl; R 3a is hydrogen; R 3b It is methyl; R 4 This is 5-[[ethyl(methyl)amino]carbonyl]pyridine-2-yl, 5-cy Anopyrazine-2-yl, 6-cyanopyrimidine-4-yl, 6-(aminocarbonyl) Pyrimidine-4-yl, 5-cyano-1,3-thiazole-2-yl, 5-(methylcal Bamoyl)-1,3-thiazole-2-yl or 5-(dimethylaminocarbonyl)-1 It is 3-thiazole-2-yl; R 5 [These are hydrogen, methyl, or cyclopropyl.] It is a compound represented by [formula].
[0024] Similarly, what is extremely preferable is (Configuration 5-3), formula (I) [wherein, X is O; Y is a direct bond; R 1 is hydrogen; R 2 teeth, 3-Bromo-5-(cyclopropoxy)phenyl, 3-cyclopropyloxy-5- (trifluoromethoxy)phenyl, 3-bromo-5-(2,2-dichlorocyclopropyl) (Lu) oxyphenyl, 3-Chloro-5-(cyanomethyl)phenyl, 3-(cyanomethyl)-5-(trif (Luoromethoxy)phenyl, 3-chloro-5-(2-cyanopropan-2-yl)phenyl Lu, 3-(2-cyanopropan-2-yl)-5-(trifluoromethyl)phenyl, 3 -(2-cyanopropan-2-yl)-5-(trifluoromethoxy)phenyl, 3-( 2-Cyanopropan-2-yl)-5-methylsulfonylphenyl, 3-Chloro-5-(cyclopropylcarbonyl)phenyl, 3-Chloro-5-(2-cyanopropan-2-yloxy)phenyl, 3-bromo- 5-(2-cyanopropan-2-yloxy)phenyl, 3-Bromo-5-[cyclopropyl(difluoro)methyl]phenyl, 3-(2-Cyclopropyl(difluoro)methyl]phenyl Anopropan-2-yloxy)-5-cyclopropylphenyl, 3-Bromo-5-[(2,2-difluorocyclopropyl)methoxy]phenyl, 3 -bromo-5-[(2,2-dichlorocyclopropyl)methoxy]phenyl, 3-[(2 ,2-dichlorocyclopropyl)methoxy]-5-(trifluoromethyl)phenyl, 3-[(2,3,3-trichloropropane-2-en-1-yl)oxy]-5-(to (Lifluoromethyl)phenyl, 3-bromo-5-[(2,3,3-trichloropropane-2) -en-1-yl)oxy]phenyl, 3-bromo-5-[difluoro-(4-fluorophenyl)methyl]phenyl, or , It is 2-chloro-6-(2-cyanopropan-2-yl)pyridine-4-yl; R 3a is hydrogen; R 3b It is methyl; R 4 This is 5-[[ethyl(methyl)amino]carbonyl]pyridine-2-yl, 5-cy Anopyrazine-2-yl, 6-cyanopyrimidine-4-yl, 6-(aminocarbonyl) Pyrimidine-4-yl, 6-(methylaminocarbonyl)pyrimidine-4-yl, 5-cy Ano-1,3-thiazole-2-yl, 5-(methylcarbamoyl)-1,3-thiazo Lu-2-yl or 5-(dimethylaminocarbonyl)-1,3-thiazole-2-yl can be; R 5 [These are hydrogen, methyl, or cyclopropyl.] It is a compound represented by [formula].
[0025] In a preferred further embodiment, the present invention relates to formula (I') [ka] [In the formula, the structural element R 1 , R 2 , R 3a , R 3b , R 4 , R 5 And Y is in configuration (1-1) The meaning or structure given in (2-1) The meaning or structure given in (3 -1) The meaning or structure given in (4-1) [Having the meaning given in the composition (5-1)] This relates to compounds represented by [the specified formula / method].
[0026] In a preferred further embodiment, the present invention relates to formula (I') [ka] [In the formula, the structural element R 1 , R 2 , R 3a , R 3b , R 4 , R 5 And Y is in configuration (1-2) The meaning or structure given in (2-2) The meaning or structure given in (3 -2) The meaning or structure given in (4-2) [Having the meaning given in the composition (5-2)] This relates to compounds represented by [the specified formula / method].
[0027] In a preferred further embodiment, the present invention relates to formula (I'') [ka] [During the ceremony, R 3b is a C1-C3 alkyl group, particularly preferably Me, and R 3a teeth , H is; and, Structural element R 1 , R 2 , R 4 , R 5 And Y is given in the configuration (1-1) The meaning or composition given in taste or composition (2-1) In the meaning or structure (4-1) given in the meaning or structure (5-1) [Having the given meaning] This relates to compounds represented by [the specified formula / method].
[0028] In a preferred further embodiment, the present invention relates to formula (I'') [ka] [During the ceremony, R 3b is a C1-C3 alkyl group, particularly preferably Me, and R 3a teeth , H is; and, Structural element R 1 , R 2 , R 4 , R 5 And Y is given in the configuration (1-2) The meaning or composition given in taste or composition (2-2) In the meaning or structure (4-2) given in the meaning or structure (5-2) [Having the given meaning] This relates to compounds represented by [the specified formula / method].
[0029] In a preferred further embodiment, the present invention relates to formula (I'') [ka] [During the ceremony, R 3b is a C1-C3 alkyl group, particularly preferably Me, and R 3a teeth , H is; and, Structural element R 1 , R 2 , R 4 , R 5 And Y is given in the configuration (1-3) The meaning or composition given in taste or composition (2-3) In the meaning or structure (4-3) given in the meaning or structure (5-3) [Having the given meaning] This relates to compounds represented by [the specified formula / method].
[0030] In a preferred further embodiment, the present invention relates to formula (I''') [ka] [During the ceremony, R 3b is a C1-C3 alkyl group, particularly preferably Me, and R 3a teeth , H is; and, Structural element R 1 , R 2 , R 4 , R 5 And Y is given in the configuration (1-1) The meaning or composition given in taste or composition (2-1) In the meaning or structure (4-1) given in the meaning or structure (5-1) [Having the given meaning] This relates to compounds represented by [the specified formula / method].
[0031] In a preferred further embodiment, the present invention relates to formula (I''') [ka] [During the ceremony, R 3b is a C1-C3 alkyl group, particularly preferably Me, and R 3a teeth , H is; and, Structural element R 1 , R 2 , R 4 , R 5 And Y is given in the configuration (1-2) The meaning or composition given in taste or composition (2-2) In the meaning or structure (4-2) given in the meaning or structure (5-2) [Having the given meaning] This relates to compounds represented by [the specified formula / method].
[0032] In a preferred further embodiment, the present invention relates to formula (I''') [ka] [During the ceremony, R 3b is a C1-C3 alkyl group, particularly preferably Me, and R 3a teeth , H is; and, Structural element R 1 , R 2 , R 4 , R 5 And Y is given in the configuration (1-3) The meaning or composition given in taste or composition (2-3) In the meaning or structure (4-3) given in the meaning or structure (5-3) [Having the given meaning] This relates to compounds represented by [the specified formula / method].
[0033] Furthermore, the present invention encompasses the following intermediate compounds and their salts (see Table 2). ): Intermediate 5A: 3-Chloro-5-(2-cyanopropan-2-yl)benzoic acid; Intermediate 9A: 3-chloro-5-(cyclopropylcarbonyl)benzoic acid; Intermediate 10A: 3-[(methylsulfinyl)methoxy]-5-(trifluoromethyl Benzoic acid; Intermediate 25A: 3-(cyanomethyl)-5-(trifluoromethoxy)benzoic acid; Intermediate 26A: 3-(2-cyanopropan-2-yl)-5-(trifluoromethyl) Sodium benzoate / 3-(2-cyanopropan-2-yl)-5-(trifluoro Methoxybenzoic acid; Intermediate 28A: 3-bromo-5-(2,2-dichlorovinyl)benzoic acid; Intermediate 35A: 3-bromo-5-[difluoro(4-fluorophenyl)methyl] zoic acid; Intermediate 48A: 3-chloro-5-[(methylsulfonyl)methyl]benzoic acid; Intermediate 50A: 3-(cyclopropoxy)-5-(trifluoromethoxy)benzoic acid ; Intermediate 51A: 3-bromo-5-(1-cyano-1-methylethoxy)benzoic acid; Intermediate 52A: 3-chloro-5-(1-cyano-1-methyl-ethoxy)benzoic acid; Intermediate 54A: 5-[5-[(1S)-1-aminoethyl]-1,2,4-triazo [Il-1-yl]pyrazine-2-carbonilicate hydrochloride; Intermediate 58A: 6-[5-[(1S)-1-aminoethyl]-3-cyclopropyl- 1,2,4-Triazole-1-yl]pyrimidine-4-carbonitrile hydrochloride; Intermediate 59A: 6-[5-[(1S)-1-aminoethyl]-3-cyclopropyl- 1,2,4-Triazole-1-yl]pyrimidine-4-carboxamide hydrochloride; Intermediate 60A: 3-Chloro-6-(1-cyano-1-methyl-ethyl)pyridine-4 -carboxylic acid; Intermediate 61A: 6-{5-[(1S)-1-aminoethyl]-3-methyl-1H-1 ,2,4-triazol-1-yl}-N-ethyl-N-methylnicotinamide hydrochloride; Intermediate 69A: 3-(cyanomethyl)-5-(methylsulfonyl)benzoic acid; Intermediate 70A: 3-(2-cyanopropan-2-yl)-5-(methylsulfonyl) benzoic acid; Intermediate 72A: 3-(1-cyano-1-methyl-ethoxy)-5-cyclopropyl- Benzoic acid.
[0034] The compound represented by formula (I) can also exist as a stereoisomer depending on the type of substituent it has. The geometric isomers and / or optical isomers or isomer mixtures in various compositions. Compound forms can also exist, even if generally only for compounds represented by formula (I). Even if discussed herein, the present invention relates to pure stereoisomers and these isomers It provides both of any desired mixtures.
[0035] However, according to the present invention, preferably the optical activity of the compound represented by formula (I) Stereoisomers and their salts are used.
[0036] Therefore, the present invention prevents pests (which include arthropods, and in particular insects) This relates to both pure enantiomers and diastereomers and mixtures thereof for removal. do.
[0037] In appropriate cases, the compound represented by formula (I) may exist in various polymorphic forms, or It can exist as a mixture of various polymorphic forms. Both pure polymorphs and polymorphic mixtures Provided by the present invention and usable in accordance with the present invention.
[0038] definition A person skilled in the art will know that when the expression "a" or "an" is used in this application, even if it is clearly Even if not explicitly indicated, depending on the situation, it may be "1", "1 or more", or "at least 1 I know that it can mean "...".
[0039] With respect to all structures described herein, such as ring systems and groups, adjacent atoms are -O It must not be -O- or -OS-.
[0040] The purpose is to specify more concretely structures that have a variable number of carbon atoms (C atoms). In this application, C 炭素原子の下限 -C 炭素原子の上限 Structure (C LL -C UL It can be described as a structure. For example, an alkyl group can be composed of 3 to 10 carbon atoms. In that case, C3-C 10 - Corresponds to alkyl. Composed of carbon atoms and heteroatoms. The resulting ring structure can be described as an "LL~UL member" structure. One example of a 6-membered ring structure is the Tolué. It is a 6-membered ring structure substituted with a methyl group.
[0041] Collective terms relating to substituents, for example, C LL -C UL -alkyl is a complex substituent, for example, C LL -C UL -Cycloalkyl-CLL -C UL -If it is at the end of an alkyl group, then The first component of the compound substituent, for example, C LL -C UL -Cycloalkyls are similar In a manner that is either different from or different from the latter substituent, for example, C LL -C UL - Al It can be monosubstituted or polysubstituted by Kil. With respect to chemical groups, ring systems and cyclic groups used in this application All the collective words are "C LL -C UL By adding "" or "LL~UL member", It can be specified more specifically.
[0042] In the definition of the symbols given in the above formula, the set generally represents the following substituents. The word was used.
[0043] The halogen is an element from Group 7, preferably fluorine, chlorine, bromine, and iodine, more preferably More preferably, the invention relates to fluorine, chlorine, and bromine, and more preferably to fluorine and chlorine.
[0044] Examples of heteroatoms are N, O, S, P, B, and Si. Preferably, the term "heteroatom" is used. This relates to N, S, and O.
[0045] According to the present invention, "alkyl" is preferably 1, either alone or as part of a chemical group. Linear or branched hydrocarbons having ~6 carbon atoms, such as methyl, ethyl, n- Propyl, isopropyl, n-butyl, isobutyl, s-butyl, t-butyl, pentyl 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,2-dimethylpropyl , 1,1-dimethylpropyl, 2,2-dimethylpropyl, 1-ethylpropyl, hex L, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl Lu, 1,2-dimethylpropyl, 1,3-dimethylbutyl, 1,4-dimethylbutyl, 2 ,3-dimethylbutyl, 1,1-dimethylbutyl, 2,2-dimethylbutyl, 3,3-dimethylbutyl Methylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1 - Represents ethylbutyl and 2-ethylbutyl. Alkyl compounds having 1 to 4 carbon atoms, e.g. For example, methyl, ethyl, ethyl, n-propyl, isopropyl, n-butyl, Isobutyl, s-butyl, or t-butyl are also preferred. The alkyl according to the present invention is 1 or It can be substituted with the same or different radicals listed above.
[0046] According to the present invention, the "alkenyl" is used either alone or as part of a chemical group, preferably A linear or branched hydrocarbon having 2 to 6 carbon atoms and at least one double bond. For example, vinyl, 2-propenyl, 2-butenyl, 3-butenyl, 1-methyl-2-p Lopenyl, 2-methyl-2-propenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl Nyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl , 1,1-dimethyl-2-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl -2-propenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl , 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl Nyl, 4-methyl-2-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl Pentenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4 -Pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1 -dimethyl-3-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3- Butenyl, 1,3-dimethyl-2-butenyl, 2,2-dimethyl-3-butenyl, 2,3 -Dimethyl-2-butenyl, 2,3-Dimethyl-3-butenyl, 1-ethyl-2-butenyl 1-ethyl-3-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl , 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl And represents 1-ethyl-2-methyl-2-propenyl. Al having 2 to 4 carbon atoms Kenyl, for example, in particular 2-propenyl, 2-butenyl or 1-methyl-2-propenyl Alkenyls are also preferred. The alkenyls according to the present invention are one or more identical or different alkenyls. It can be substituted with radicals.
[0047] According to the present invention, "alkynyl" is used either alone or as part of a chemical group, preferably A linear or branched hydrocarbon having 2 to 6 carbon atoms and at least one triple bond. For example, 2-propynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl , 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-3-butynyl, 2- Methyl-3-butynyl, 1-methyl-2-butynyl, 1,1-dimethyl-2-propynyl , 1-ethyl-2-propynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5 -Hexynyl, 1-methyl-2-pentynyl, 1-methyl-3-pentynyl, 1-methyl -4-pentynyl, 2-methyl-3-pentynyl, 2-methyl-4-pentynyl, 3-methyl Tyl-4-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-3-butynyl , 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 1-ethyl-3 -Butynyl, 2-ethyl-3-butynyl, 1-ethyl-1-methyl-2-propynyl and Represents 2,5-hexadinyl. An alkynyl having 2 to 4 carbon atoms, for example, birdwax Ethynyl, 2-propynyl, or 2-butynyl-2-propenyl are also preferred. The alkynyl by Akira can be substituted with one or more identical or different radicals. .
[0048] According to the present invention, "cycloalkyl" is preferred to be used alone or as part of a chemical group. 'k' refers to monocyclic, bicyclic, or tricyclic hydrocarbons having 3 to 10 carbon atoms, for example, cyclo Propyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclo Cutyl, bicyclo[2.2.1]heptyl, bicyclo[2.2.2]octyl or Adama Represents ethyl. A cycloalkyl group having 3, 4, 5, 6, or 7 carbon atoms, e.g. For example, cyclopropyl or cyclobutyl are particularly preferred. Alkyl can be substituted with one or more identical or different radicals.
[0049] According to the present invention, the "alkylcycloalkyl" is preferably 4 to 10 or 4 to 7 A monocyclic, bicyclic, or tricyclic alkylcycloalkyl having carbon atoms, for example, Isopropylcyclopropyl, ethylcyclopropyl, isopropylcyclobutyl, 3-methyl ethyl Represents clopentyl and 4-methylcyclohexyl. Has 4, 5, or 7 carbon atoms. Alkylcycloalkyl groups, for example, ethylcyclopropyl or 4-methyl, in particular. Cyclohexyl is also preferred. The alkylcycloalkyl according to the present invention is one or more identical It may be substituted with a radical that is or is different from it.
[0050] According to the present invention, the "cycloalkylalkyl" is preferably 4 to 10 or 4 to 7 A monocyclic, bicyclic, or tricyclic cycloalkylalkyl having carbon atoms, for example, Clopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl Represents cycloammonium compounds and cyclopentyl ethyl compounds. Cycloammonium compounds having 4, 5, or 7 carbon atoms. chloroalkyls, for example, cyclopropylmethyl or cyclobutylmethyl, among others. Preferred. The cycloalkylalkyls according to the present invention are one or more identical or different It can be substituted with a radical.
[0051] According to the present invention, the "hydroxyalkyl" preferably has 1 to 6 carbon atoms. , straight-chain or branched-chain alcohols, for example methanol, ethanol, n-propanol, Isopropanol, n-butanol, isobutanol, s-butanol, and t-butanol This represents a hydroxyalkyl group having 1 to 4 carbon atoms. The hydroxyalkyl group may be substituted with one or more identical or different radicals. ru.
[0052] According to the present invention, the "alkoxy" preferably has 1 to 6 carbon atoms and is linear or These are branched O-alkyl groups, such as methoxy, ethoxy, n-propoxy, and isopropoxy. Represents 1-4 carbon atoms, n-butoxy, isobutoxy, s-butoxy, and t-butoxy. Alkoxy groups having elementary atoms are also preferred. The alkoxy group according to the present invention is one or more identical It can be substituted with a radical that is present or different.
[0053] According to the present invention, "alkylthio" or "alkylsulfanil" is preferably 1 to A linear or branched S-alkyl group having 6 carbon atoms, such as methylthio or ethyl. Thio, n-propylthio, isopropylthio, n-butylthio, isobutylthio, s-propylthio Represents tilthio and t-butylthio. Alkylthio groups having 1 to 4 carbon atoms are also preferred. The alkylthio group according to the present invention is one or more identical or different radicals. It can be replaced with.
[0054] According to the present invention, the "alkyl sulfinyl" preferably has 1 to 6 carbon atoms. linear or branched alkylsulfinyl compounds, such as methylsulfinyl and ethylsulfinyl compounds. Finyl, n-propylsulfinyl, isopropylsulfinyl, n-butylsulf Nyl, isobutylsulfinyl, s-butylsulfinyl and t-butylsulfinyl This represents an alkylsulfinyl group having 1 to 4 carbon atoms. The lucyl sulfinyl group is substituted with one or more identical or different radicals. It is possible to include both enantiomers.
[0055] According to the present invention, the "alkylsulfonyl" preferably has 1 to 6 carbon atoms. , linear or branched alkylsulfonyl compounds, for example, methylsulfonyl, ethylsulfonyl, n-propylsulfonyl, isopropylsulfonyl, n-butylsulfonyl, isobutyl Represents sulfonyl, s-butylsulfonyl, and t-butylsulfonyl. 1 to 4 carbon atoms Alkyl sulfonyl groups having a derivative are also preferred. The alkyl sulfonyl group according to the present invention is 1 These radicals may be substituted with identical or different radicals.
[0056] According to the present invention, "cycloalkylthio" or "cycloalkylsulfanil" is preferred. The compound is an -S-cycloalkyl compound having 3 to 6 carbon atoms, such as cyclopropyl Represents thio, cyclobutylthio, cyclopentylthio, and cyclohexylthio. 3 to 5 Cycloalkylthio groups having carbon atoms are also preferred. Cycloalkylthio group according to the present invention It can be substituted with one or more identical or different radicals.
[0057] According to the present invention, "cycloalkylsulfinyl" preferably has 3 to 6 carbon atoms. -S(O)-cycloalkyl, for example, cyclopropylsulfinyl, cyclo Represents butylsulfinyl, cyclopentylsulfinyl, and cyclohexylsulfinyl. A cycloalkylsulfinyl group having 3 to 5 carbon atoms is also preferred. The cycloalkylsulfinyl group is composed of one or more identical or different radicals. They can be interchanged and contain both enantiomers.
[0058] According to the present invention, "cycloalkylsulfonyl" preferably has 3 to 6 carbon atoms It contains -SO2-cycloalkyl compounds, such as cyclopropylsulfonyl and cyclobutyl. Represents sulfonyl, cyclopentylsulfonyl, and cyclohexylsulfonyl. 3 to 5 Cycloalkylsulfonyl groups having carbon atoms are also preferred. The sulfonyl group may be substituted with one or more identical or different radicals.
[0059] According to the present invention, "phenylthio" or "phenylsulfanil" is -S-phenyl For example, it represents phenylthio. The phenylthio group according to the present invention is one or more identical or Alternatively, it may be substituted with a different radical.
[0060] According to the present invention, "phenylsulfinyl" is -S(O)-phenyl, for example, phenyl It represents nilsulfinyl. The phenylsulfinyl group according to the present invention is one or more identical groups. It can be substituted with a different radical, and both enantiomers To include.
[0061] According to the present invention, "phenylsulfonyl" is -SO2-phenyl, for example, phenyl It represents sulfonyl. The phenylsulfonyl group according to the present invention is one or more identical or different It can be substituted with the radical that is currently in place.
[0062] According to the present invention, "alkylcarbonyl" is methylcarbonyl, ethylcarbonyl, n-propylcarbonyl, isopropylcarbonyl, s-butylcarbonyl and t-butyl Linear or branched alkyl groups, such as 2-7 carbon atoms, are preferably having 2 to 7 carbon atoms. This represents C (=O). Alkyl carbonyls having 1 to 4 carbon atoms are also preferred. The alkylcarbonyl according to the invention is composed of one or more identical or different radicals. It can be exchanged.
[0063] According to the present invention, "alkoxycarbonyl" as a single entity or as a component of a chemical group is A The lucoxy portion preferably has 1 to 6 carbon atoms or 1 to 4 carbon atoms. Linear or branched alkoxycarbonyls, for example, methoxycarbonyl, ethoxycarbonyl Rubonyl, n-propoxycarbonyl, isopropoxycarbonyl, s-butoxycarbonyl Represents nyl and t-butoxycarbonyl. The alkoxycarbonyl group according to the present invention is 1 or It can be substituted with the same or different radicals listed above.
[0064] According to the present invention, the alkylaminocarbonyl preferably has 1 to 6 alkyl portions. A linear or branched alkylaminocarb having 1 to 4 carbon atoms. Nyl, for example, methylaminocarbonyl, ethylaminocarbonyl, n-propylamino Carbonyl, isopropylaminocarbonyl, s-butylaminocarbonyl and t-butyl This represents an alkylaminocarbonyl group. The alkylaminocarbonyl group according to the present invention is one or more identical groups. It may be substituted with a radical that is or is different from it.
[0065] According to the present invention, "N,N-dialkylaminocarbonyl" is preferred in the alkyl portion. ≤ a linear or branched N,N-diagonal molecule having 1 to 6 carbon atoms or 1 to 4 carbon atoms. Alkylaminocarbonyl, for example, N,N-dimethylaminocarbonyl, N,N-die Tylaminocarbonyl, N,N-di(n-propylamino)carbonyl, N,N-di( Represents sopropylamino)carbonyl and N,N-di-(s-butylamino)carbonyl The N,N-dialkylaminocarbonyl groups according to the present invention are one or more identical or different. It can be substituted with the radical that is currently in place.
[0066] According to the present invention, "aryl" preferably has 6 to 14 ring carbon atoms, particularly 6 to 10 ring carbon atoms. Monocyclic, bicyclic, or polycyclic aromatic systems having offsprings, such as phenyl, naphthyl, and ammonium compounds. It represents tolyl, phenantrenyl, and preferably phenyl. Furthermore, aryl is A condensed polycyclic system in which the bonding site is located on an aromatic system, for example, tetrahydronaphthyl, indenyl This also represents indanyl, fluorenyl, biphenyl, etc. The aryl group according to the present invention is 1 or It can be substituted with the same or different radicals listed above.
[0067] An example of a substituted aryl is an arylalkyl, which is a C1-C4 alkyl group. Part and / or C6-C 14 - In the aryl portion, one or more identical or different They can similarly be substituted with radicals. An example of such an arylalkyl is ben Examples include zyl and phenyl-1-ethyl.
[0068] According to the present invention, the term "polycyclic" refers to fused, crosslinked, and spirocyclic carbon rings. This refers to rings and heterocycles, as well as ring systems linked by single or double bonds.
[0069] According to the present invention, "heterocycle," "heterocyclic ring," or "heterocyclic ring system" is less than Each of them has one carbon atom that is a heteroatom (preferably made of N, O, S, P, B, Si, Se) It is replaced by a heteroatom selected from the group and is saturated, unsaturated or heteroaromatic. At least one ring in the family (where the ring is either not substituted or is not substituted) It may also represent a carbocyclic ring system having a bond site on a ring atom. Unless otherwise specified, the heterocyclic ring preferably contains 3 to 9 rings. Atoms (especially 3 to 6 ring atoms) and one or more (preferably 1 to 4, especially 1 or 2) Or 3 heteroatoms (preferably heteroatoms selected from the group consisting of N, O, and S) It contains (a) but the two oxygen atoms must not be directly adjacent. Heterocyclic rings are usually , containing 4 or fewer nitrogen atoms and / or 2 or fewer oxygen atoms and / or 2 or fewer sulfur atoms In the case of heterocyclyls which may be substituted, the present invention relates to polycyclic ring systems, for example. , 8-azabicyclo[3.2.1]octanyl, 1-azabicyclo[2.2.1]hepti Lu, 1-oxa-5-azaspiro[2,3]hexyl or 2,3-dihydro-1H-in This also includes dolls and similar items.
[0070] The heterocyclyl group according to the present invention is, for example, piperidinyl, piperazinyl, morpholinyl Lu, thiomorpholinil, dihydropyranil, tetrahydropyranil, dioxanil, pyro Linyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazo Lidinyl, Dioxolanil, Dioxolyl, Pyrazolidinil, Tetrahydrofuranil, Di Hydrofuranil, oxetanil, oxyranil, azetidinil, aziridinil, oxaze Tidinyl, oxaziridinyl, oxazepanil, oxazinanil, azepanil, oxop Loridinil, dioxopyrrolidinil, oxomorpholinil, oxopiperazinil and ox Examples include sepanil.
[0071] Of particular importance are heteroaryls, i.e., heteroaromatic systems. According to the present invention, The term "heteroaryl" is encompassed within the above definition of heteroaromatic compounds, i.e., heterocyclic compounds. It represents a completely unsaturated aromatic heterocyclic compound. Preferably, one selected from the above group. It has ~3 (preferably 1 or 2) identical or different heteroatoms. It is a ring with 5 to 7 members. Examples of heteroaryls according to the present invention are furyl, thienyl, and py Lazolyl, imidazolyl, 1,2,3-triazolyl and 1,2,4-triazolyl, i Soxazolyl, thiazolyl, isothiazolyl, 1,2,3-oxadiazolyl, 1,3 ,4-Oxadiazolyl, 1,2,4-Oxadiazolyl and 1,2,5-Oxadiazo Ril, azepinyl, pyrrolyl, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, 1 ,3,5-triazinyl, 1,2,4-triazinyl and 1,2,3-triazinyl, 1 ,2,4-oxazinyl, 1,3,2-oxazinyl, 1,3,6-oxazinyl and 1 ,2,6-Oxazinyl, Oxepinyl, Thiepinyl, 1,2,4-Triazolonyl, Furthermore, it is 1,2,4-diazepinyl. The heteroaryl group according to the present invention is one or more of the same It may also be substituted with one or a different radical.
[0072] According to the present invention, the substituent = O (oxo) is the two hydrogen atoms of the methylene (CH2) group or This refers to the lone pairs of electrons on sulfur atoms, nitrogen atoms, and phosphorus atoms that have substituents other than hydrogen. It can change. For example, a radical C2-alkyl can be changed by, for example, =O (oxo) Through substitution, it becomes -COCH3, and the heterocyclic thiethane-3-yl- is, for example, one =By substitution with an O (oxo) group, it becomes 1-oxothietan-3-yl or two = Substitution with an O (oxo) group results in 1,1-dioxothietan-3-yl.
[0073] According to the present invention, the substituent S (thiono) is attached to the two hydrogen atoms of the methylene (CH2) group. It can be replaced. For example, a radical C2-alkyl can be replaced by, for example, =S(thiono The substitution by ) results in -CSCH3.
[0074] The expression "may be replaced" as used herein means that even if it is replaced The good group is either substituted with a further substituent or not substituted with a further substituent. It means...
[0075] The term "may be substituted in either case" refers to a group / substituent, e.g., alkyl, Alkenyl, Alkinyl, Alkoxy, Alkylthio, Alkylsulfinyl, Alkyl Sulfonyl, cycloalkyl, aryl, phenyl, benzyl, heterocyclyl and heterocyclyl This means that loaryl radicals, etc., are substituted, for example, This refers to a substituted radical derived from a non-existent base structure, where the substituent (e.g., One substituent, or multiple substituents, preferably 1, 2, 3, 4, 5, 6, or 7 substituents. ) are, for example, amino, hydroxyl, halogen, nitro, cyano, isocyan, mercapto Puto, isothiocyanate, C1-C4-carboxyl, carvonamide, SF5, amino Sulfonyl, C1-C4-alkyl, C1-C4-haloalkyl, C3-C4-cyclo Lukyl, C2-C4-alkenyl, C5-C6-cycloalkenyl, C2-C4-alkyl Nyl, N-mono-C1-C4-alkylamino, N,N-di-C1-C4-alkylamino No, N-C1-C4-alkanoylamino, C1-C4-alkoxy, C1-C4-halo Alkoxy, C2-C4-alkenyloxy, C2-C4-alkynyloxy, C3-C 4-Cycloalkoxy, C5-C6-Cycloalkenyloxy, C1-C4-alkoxy Carbonyl, C2-C4-alkenyloxycarbonyl, C2-C4-alkynyloxy Carbonyl, C6-aryloxycarbonyl, C 10 -Aryloxycarbonyl, C 14 -Aryloxycarbonyl, C1-C4-alkanoyl, C2-C4-alkenyl Carbonyl, C2-C4-alkynylcarbonyl, C6-arylcarbonyl, C 10 - Arylcarbonyl, C 14 -arylcarbonyl, C1-C4-alkylthio, C1- C4-haloalkylthio, C3-C4-cycloalkylthio, C2-C4-alkenylthio O, C5-C6-cycloalkenylthio, C2-C4-alkynylthio, C1-C4-A Lukylsulfinyl (where both C1-C4-alkylsulfinyl groups are enantio) (where C1-C4-haloalkylsulfinyl is included), C1-C4-haloalkylsulfinyl (where C1-C4-haloalkylsulfinyl is included), (Both enantiomers of the chloroalkylsulfinyl group are included), C1-C4-alkyl Sulfonyl, C1-C4-haloalkylsulfonyl, N-mono-C1-C4-alkyl Aminosulfonyl, N,N-di-C1-C4-alkylaminosulfonyl, C1-C4- Alkylphosphenyl, C1-C4-alkylphosphonyl (where C1-C4-alkyl It includes both the phosphophenyl and C1-C4 alkylphosphonyl enantiomers. ), N-C1-C4-alkylaminocarbonyl, N,N-di-C1-C4-alkyl Aminocarbonyl, N-C1-C4-Alkanoylaminocarbonyl, N-C1-C4- Alkanoyl-N-C1-C4-alkylaminocarbonyl, C6-aryl, C 10 - Ariel, C 14 -aryl, C6-aryloxy, C10 -aryloxy, C 14 -aryloxy, benzyl, benzyloxy, benzylthio, C6-arylthio, C 10 -Aylthio, C 14 -arylthio, C6-arylamino, C 10 -Aryl Amino, C 14 -Arylamino, benzylamino, heterocyclyl and trialkyl Lylle, substituents bonded via a double bond (for example, C1-C4 alkylidene (for example) (If, then, methylidene or ethylidene), oxo group, imino group and substituted imino group) Selected from the following group. If two or more radicals form one or more rings, these , carbocyclic, heterocyclic, saturated, partially saturated, unsaturated (e.g., including aromatic rings) It may be, and may be further substituted. For example, the above example Substituting groups ("first substituent level") are those that contain hydrocarbon components. Further substituents ("second substituent level"), such as halogens, hydroxyls, Amino, nitro, cyano, isocyano, azide, acylamino, oxo, and imino groups Each of these molecules may have one or more substituents that are independently selected. The group that is (or may be) encapsulates only one or two substituent levels, preferably Includes.
[0076] A halogen-substituted chemical group or halogenated group (e.g., alkyl) according to the present invention (or alkoxy) is monosubstituted with a halogen, or has up to the maximum possible number of substituents. It is polysubstituted with halogens. Such groups are also called halo groups (e.g., haloalkyl groups). When polysubstituted with halogens, the halogen atoms may be the same or different. They may be, and all may be bonded to one carbon atom or multiple carbon atoms It may be bonded to the parent. The halogen is preferably fluorine, chlorine, bromine, or iodine. The element is fluorine, chlorine, or bromine, and more preferably fluorine. More specifically, The halogen-substituted group is a monohalocycloalkyl group, for example, 1-fluoroalkyl Fluoropropyl, 2-fluorocyclopropyl or 1-fluorocyclobutyl, monohalopropyl Kill, for example, 2-chloroethyl, 2-fluoroethyl, 1-chloroethyl, 1-fluorinated chloromethyl, fluoromethyl, or perhaloalkyl, for example, trichloromethyl Tyl or trifluoromethyl or CF2CF3, polyhaloalkyl, for example, difluoro Methyl, 2-fluoro-2-chloroethyl, dichloromethyl, 1,1,2,2-tetraf These are haloethyl or 2,2,2-trifluoroethyl. Further examples of haloalkyls are Trichloromethyl, chlorodifluoromethyl, dichlorofluoromethyl, chloromethyl Bromomethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl , 2,2,2-trifluoroethyl, 2,2,2-trichloroethyl, 2-chloro-2, 2-difluoroethyl, pentafluoroethyl, 3,3,3-trifluoropropyl and It is pentafluoro-t-butyl. Preferably, it has 1 to 4 carbon atoms and fluorine and chlorine. and 1 to 9 (preferably 1 to 5) identical or different elements selected from bromine. It is a haloalkyl having a halogen atom. Particularly preferred is one or two carbon atoms. Atom and 1 to 5 identical or different halogens selected from fluorine and chlorine Haloalkyls having atoms (for example, difluoromethyl, trifluoromethyl, etc.) (or 2,2-difluoroethyl). Further examples of halogen-substituted compounds These are haloalkoxys, for example, OCF3, OCHF2, OCH2F, OCF2CF3, O CH2CF3, OCH2CHF2 and OCH2CH2Cl, haloalkylsulfanyl, For example, difluoromethylthio, trifluoromethylthio, trichloromethylthio, chloro Logifluoromethylthio, 1-fluoroethylthio, 2-fluoroethylthio, 2,2- Difluoroethylthio, 1,1,2,2-tetrafluoroethylthio, 2,2,2-tri Fluoroethylthio or 2-chloro-1,1,2-trifluoroethylthio, haloalkyl Sulfinyl, for example, difluoromethylsulfinyl, trifluoromethylsulfinyl Nyl, trichloromethylsulfinyl, chlorodifluoromethylsulfinyl, 1-flu Oroethylsulfinyl, 2-fluoroethylsulfinyl, 2,2-difluoroethyl Sulfinyl, 1,1,2,2-tetrafluoroethylsulfinyl, 2,2,2-tri Fluoroethylsulfinyl and 2-chloro-1,1,2-trifluoroethylsulfinyl Nyl, haloalkylsulfinyl, e.g., difluoromethylsulfinyl, trifluoro methylsulfinyl, trichloromethylsulfinyl, chlorodifluoromethylsulf Fluoroethylsulfinyl, 1-fluoroethylsulfinyl, 2-fluoroethylsulfinyl, 2,2- Difluoroethylsulfinyl, 1,1,2,2-tetrafluoroethylsulfinyl, 2,2,2-trifluoroethylsulfinyl and 2-chloro-1,1,2-trifluoro Roethylsulfinyl, haloalkylsulfonyl group, for example, difluoromethylsulfonyl L, trifluoromethylsulfonyl, trichloromethylsulfonyl, chlorodifluoromethyl Tylsulfonyl, 1-fluoroethylsulfonyl, 2-fluoroethylsulfonyl, 2, 2-difluoroethylsulfonyl, 1,1,2,2-tetrafluoroethylsulfonyl, 2,2,2-trifluoroethylsulfonyl and 2-chloro-1,1,2-trifluoro It is ethylsulfonyl.
[0077] In the case of a radical having carbon atoms, it is preferable to have 1 to 4 carbon atoms (especially 1 or It has two carbon atoms. Generally, halogens (e.g., fluorine and chlorine) (C1-C4) alkyl (preferably methyl or ethyl), (C1-C4) haloal Kill (preferably trifluoromethyl), (C1-C4) alkoxy (preferably me) Selected from the group consisting of toxic or ethoxy, (C1-C4) haloalkoxy, nitro, and cyano. A substituent is preferred. Particularly preferred substituents are methyl, methoxy, and fluorine. And chlorine.
[0078] Substituting amino acids (e.g., monosubstituted amino acids or disubstituted amino acids) are, for example, alkyl 1 or 2 selected from the group consisting of aryl, hydroxy, amino, alkoxy, acyl, and aryl. N-substituted substituted amino radicals by identical or different radicals. This means a radical selected from the group; preferably, N-monoalkylamino and N,N -Dialkylamino (e.g., methylamino, ethylamino, N,N-dimethylamino, N,N-diethylamino, N,N-di-n-propylamino, N,N-diisopropylamino Mino (or N,N-dibutylamino), N-monoalkoxyalkylamino or N,N-di Alkoxyalkylamino groups (e.g., N-methoxymethylamino, N-methoxyethyl) Amino, N,N-di(methoxymethyl)amino, or N,N-di(methoxyethyl)amino ), N-monoarylaminos and N,N-diarylaminos, for example, even if substituted Good aniline, acylamino, N,N-diacylamino, N-alkyl-N-aryl Mino, N-alkyl-N-acylamino, and furthermore, saturated N-heterocyclic; here Therefore, preferred is an alkyl radical having 1 to 4 carbon atoms; here, The compound is preferably phenyl or a substituted phenyl compound; as for the acyl, The definitions further given below apply, preferably (C1-C4)-alkano It is yl. The same applies to substituted hydroxylamino or hydrazino. It will be done.
[0079] The substituted amino is a quaternary amino having four organic substituents on the nitrogen atom. This also includes monoium compounds (salts).
[0080] The phenyl that may be substituted is preferably an unsubstituted phenyl. Alternatively, halogen, (C1-C4)-alkyl, (C1-C4)-alkoxy, (C1-C 4)-alkoxy-(C1-C4)-alkoxy, (C1-C4)-alkoxy-(C1 (C4)-alkyl, (C1-C4)-haloalkyl, (C1-C4)-haloalkoxy (C1-C4)-alkylthio, (C1-C4)-haloalkylthio, (C1-C4) -Alkyl sulfinyl, (C1-C4)-haloalkylsulfinyl, (C1-C4) -Alkyl sulfonyl, (C1-C4)-haloalkylsulfonyl, cyano, isocyano and nitro are identical or different radicals selected from the group. Phenyls that are substituted or polysubstituted (preferably up to 3-substituted), for example, o-triphenyls. L, m-tolyl and p-tolyl, dimethylphenyl, 2-chlorophenyl, 3-chlorophenyl phenyl and 4-chlorophenyl, 2-fluorophenyl, 3-fluorophenyl and 4- Fluorophenyl, 2-trifluoromethylphenyl, 3-trifluoromethylphenyl and 4-trifluoromethylphenyl, and 4-trichloromethylphenyl, 2,4- Dichlorophenyl, 3,5-dichlorophenyl, 2,5-dichlorophenyl and 2,3- Dichlorophenyl, o-methoxyphenyl, m-methoxyphenyl, and p-methoxyphenyl It is 4-heptafluorophenyl.
[0081] The cycloalkyl which may be substituted is preferably an unsubstituted cycloalkyl It is either a halogen, cyanoacrylate, (C1-C4)-alkyl, or (C1-C4)-alkyl. Lucoxy, (C1-C4)-alkoxy-(C1-C4)-alkoxy, (C1-C4) -alkoxy-(C1-C4)-alkyl, (C1-C4)-haloalkyl and (C1- C4) A selection of identical or different haloalkoxys Cycloalkyls that are monosubstituted or polysubstituted (preferably up to 3-substituted) in a dikal manner. In particular, cycloalkyls substituted with 1 or 2 (C1-C4)-alkyl radicals That is the case.
[0082] The compounds of the present invention may exist in preferred embodiments. Individuals described herein The embodiments can be combined with each other. Contrary to the laws of nature, and therefore, a person skilled in the art can combine them themselves. Combinations that would be excluded based on expertise are not included. For example, three or more adjacent combinations. Ring structures containing oxygen atoms are excluded.
[0083] isomer The compound represented by formula (I) can also exist in geometric isomer form, depending on the type of substituent, and or / or in the form of optically active isomers, or mixtures of the corresponding isomers in various compositions. These can also exist in other forms. These stereoisomers are, for example, enantiomers and diasteres. These are omers, atropisomers, or geometric isomers. Therefore, the present invention relates to pure stereoisomers and It includes both any mixtures of those isomers.
[0084] Method and Use The present invention also relates to a method for controlling pests, wherein the method is represented by formula (I) The compound is applied to the pests and / or their habitat. The control of the pests is preferably In agriculture and forestry, and in the protection of materials, It is performed. Preferably, a surgical or therapeutic method of the human or animal body and human or Diagnostic methods performed on the animal's body are excluded from the above methods.
[0085] The present invention further relates to a pesticide, particularly a crop protectant, represented by formula (I). This also concerns the use of the compounds involved.
[0086] In relation to this application, the term "pesticide" is used in all cases. However, it always includes the term "crop protection agent."
[0087] The plants exhibit good tolerance, the toxicity to warm-blooded animals is desirable, and good Compounds represented by formula (I) that demonstrate environmental compatibility are those that are resistant to both biological and abiotic stressors. It is suitable for protecting plants and plant organs from stress factors and increasing yields. It is suitable for improving the quality of harvested crops, and is also suitable for agriculture and horticulture. In livestock farming, aquatic cultivation, forests, gardens and leisure facilities, and storage products In the protection of materials and substances, and in the field of hygiene, pests encountered, especially insects, It is suitable for controlling arachnids, helminths, especially nematodes and mollusks.
[0088] In relation to this patent application, the term "hygiene" refers to disease (especially infectious diseases). Any means, methods and practices aimed at preventing the disease of humans and animals Helps protect health and / or protect the environment and / or maintain cleanliness. This is understood to mean any means, methods, and practices. According to the present invention, this includes In particular, means for cleaning, means for disinfecting and means for sterilization, for example if, fibrous or hard surface (especially glass, wood, concrete, porcelain, ceramic) Hands for cleaning plastic surfaces, or even metal surfaces. Steps, means for disinfection and means for sterilization, and for controlling sanitary pests and / or This includes means to ensure that the state of excrement is maintained in a non-existent condition. In connection therewith, preferably, surgical or therapeutic treatments that can be performed on the body of a human or animal. The method of placement and the diagnostic method performed on the body of a human or animal are within the scope of protection according to the present invention. Excluded from the enclosure.
[0089] The term "field of hygiene" therefore implies that such hygienic means, methods, and practices are important. This includes all areas, technical and industrial applications, such as kitchens, bakeries, airports, bathrooms, Regarding hygiene in swimming pools, department stores, hotels, hospitals, livestock sheds, and livestock farming. This encompasses all areas, technological fields, and industrial applications.
[0090] Therefore, the term "sanitary pest" refers to a pest whose presence is problematic in the field of hygiene, particularly in health. Regarding the reason for the above, it is understood to mean one or more types of pests. The main objective is to avoid or minimize the presence of sanitary pests in the field of hygiene. Controlling and / or avoiding or minimizing contact with sanitary pests. This is especially important for preventing outbreaks and addressing existing outbreaks. This can be achieved by applying an insecticide that can be used for both purposes. Yes. It is also possible to use preparations that avoid or reduce contact with pests. Examples of living pests include the organisms listed below.
[0091] Thus, the term "hygienic protection" includes such hygienic means, methods, and practices. This includes all actions that maintain and / or improve the system.
[0092] Compounds represented by formula (I) can preferably be used as pesticides. They are effective against both normally susceptible and resistant species, and at all developmental stages. Alternatively, it may be active against certain developmental stages. Examples of the above-mentioned pests include the following: can: Arthropoda pests, especially those of the Arachnida class, such as species of the genus Acarus. Acarus spp.), for example, Acarus siro, Ake Aceria Kuko, Aceria She Aculops spp., Aculus (Aculus) (us spp.), for example, Aculus fockeui Aculus schlechtendali, Anne Amblyomma spp., Amphytetranicus bienensis Amphitetranychus viennensis, Argus genus species (Ar (gas spp.), Boophilus spp., brevipal Brevipalpus spp., for example, Brevipalpus hoenis. (Brevipalpus phoenicis), Briovia gramineum (Bryo Bia graminum, Bryobia praethiosa Centruroides spp., Corylopsis iosa Chorioptes spp., Dermanisus galinae Derma yssus gallinae), Derma phagoides pteronicus (Derma tophagoides pteronyssinus), Dermatophagoides pha Dermatophagoides farinae, a species of the genus Dermatophagoides ( Dermacentor spp.), Eotetranych species (us spp.), for example, Eotetranychus hikoriae Epitrimerus pyri (Epitrimerus hicoriae) , species of the genus Eutetranychus, for example, Eutet Eutetranychus banksi, genus Eriophies Species (Eriophyes spp.), for example, Eriophy Piri (Eriophy Glycyphagus dome Halotydeus destru ctor), Hemitarsonemus spp., for example Hemitarsonemus latus (= Poly Polyphagotarsonemus latus ), Hyalomma spp., Ixodes genus Latrodectus spp., Loxoscere Loxosceles spp., Neutrombicula autumnalis (Ne Utrombicula autumnalis, Nupersa species (spp.), Oligonychus spp., for example, Oligonychus coffeae, Oligonychus co Oligonychus coniferarum, Oligonychus i Oligonychus ilicis, Oligonychus indicus (Oli gonychus indicus, Oligonycus mangifers (Chus mangiferus), Oligonyx pratensis (Oligonych us pratensis), Oligonychus pu Oligonychus yothersi ), species of the genus Ornithodorus (Ornithodorus spp.), species of the genus Ornithonisus (Ornithonyssus spp.), Panonychus species (spp.), for example, Panonychus citri (=Me Metatetranychus citri, Panonic Su-urumi (Panonychus ulmi) (= Metatetranicus urumi (Met atetranychus ulmi)), phyllocoptorta oleivora (Phyll Ocoptruta oleivora, Platitetranicus multifida (Pl atytetranychus multidigituli, polyphagotalsonem Polyphagotarsonemus latus, genus Psoroptes species (Psoroptes spp.), Rhipicephalus spp. (s spp.), Rhizoglyphus spp., Sarcoptes Sarcoptes spp., Scorpio maurus maurus), species of the genus Steneotarsonemus sp. p.), Steneotarsonemus spi nki), species of the genus Tarsonemus (Tarsonemus spp.), for example, Tarsonemus Tarsonemus confusus, Tarsonemus parizus (Tarsonemus pallidus), Tetranych species (us spp.), for example, Tetranychus c. Tetranychus ci anadensis (nnabarinus), Tetranychus turkestani Tetranychus urticae ae), Trombicula alfredduge si), Vaejovis spp., Basates lycopersis ( Vasface lycopersici); For example, species of the genus Geophilus in the class Chilopoda. Scutigera spp. (species); Collembola, or the class Collembola, for example, Onyxurus al Matsus (Onychiurus armatus); Sminturus viridis (Smi nthurus viridis); For example, Braniurus gutturatus (Blani) of the class Diplopoda. ulus guttulatus); Insecta, for example, Blattodea, for example , Blatta orientalis, Blatta a Blatella asahinai, Blatella germanica (Ttella germanica), Leucophaea maderae a maderae), Loboptera decipiens ens), Neostylopyga rhombifolia folia), Panchlora spp., Parcobratta species (Parcoblatta spp.), species of the genus Periplaneta (spp.), for example, Periplaneta americana cana), Periplaneta australasiae alasiae), Pycnoscelus surinamensis namensis), Supella longipalpa ; For example, Acarinotum vitatum, a member of the order Coleoptera. Ymma vittatum), Acanthoscelides obtexus (Acanthosc elides obtectus), Adoretus spp. Aethina tumida, Agelastika Arni Agrilus spp. (Agrilus alni), for example, Agrilus planipennis, Agrilus... Coxalis (Agrilus coxalis), Agrillus virineatus (Agri Agrilus anx Agriotes spp., for example, Agriotes... Agriotes linneatus, Agriotes manx (A Agriotes o Alphitobius diaperinus perinus), Amphimallon sorstichialis lstitialis), Anobium punctat Anomala dubia, Anoprohora species Anoplophora spp.), for example, Anoplophora grabripennis (Anopl Ophora glabripennis), Anthonomus species (spp.), for example, Anthonomus grand is), species of the genus Anthrenus (Anthrenus spp.), species of the genus Apion (Apion) n spp.), Apogonia spp., Athos haemol Hoidales (Athous haemorrhoidales), species of the genus Atmaria (At omaria spp.), for example, Atomaria lin Atagenus spp., Barris caerules Baris caerulescens, Burcisius obtexus (Bru chidius obtectus), Bruchus spp., e.g. For example, Bruchus pisorum, Bruchus rufimanu Bruchus rufimanus, Cassida spp. ), Cerotoma trifurcata, ceutrin Species of the genus Ceutorrhynchus (e.g., Ceutorrhynchus spp.), for example, Ceutorrhynchus ass Myris (Ceutorrhynchus assimilis), Ceutorrhynchus qua Ceutorrhynchus quadridens • Ceutorrhynchus rapae, a species of the genus Chaetokunema tocnema spp.), for example, Chaetocnema confinis (Chaetocn Chaetocnema confinis, Chaetocnema denciculata Chaetocnema ect ypa), Cleonus mendicus, Conoderus Genus species (Conoderus spp.), Cosmopolites genus species (Cosmopolite s spp.), for example, Cosmopolites s Costelytra zealan (Costelytra ordidus) Ctenicera spp., Curculio genus (Cu rculio spp.), for example, Curculio car yae), Curculio caryatrypes Curculio obtusus, Curculio saii (Curculio sayi), Cryptol Cryptol Cryptorhynchus estes pusillus, Cryptorhynchus lapati Cryptorhynchus hus lapathi, Cryptorhynchus mangiferae Chus mangiferae), Cylindrocopturus species Cylindro pturus spp., Cylindrocopturus adpersus Copturus adspersus, Cylindrocopturus furnis (Cyli Dendrocopturus furnissi), a species of the genus Dendrocopturus (Dendro ctonus spp.), for example, Dendroctonus ponderosae (Dendroc tonus ponderosae), Dermestes spp. .), species of the genus Diabrotica (Diabrotica spp.), for example, Diabrotica... Diabrotica balteata, Diabrotica barberi (D iabrotica barberi, diabrotica undesimpunkutata howal Diabrotica undecimpunctata howardi, Diabrotica Diabrotica undesimpunkata undesimpunkata Diablotica decimpunctata (undecimpunctata), Diablotica vir Giffera Birgifera (Diabrotica virgifera virgife) ra), Diabrotica virgifera zeae Dichocrocis spp. (Dichocrocis zeae), Dichocrocis species Dicladispa armigera, a species of the genus Dicladispa (D iloboderus spp.), Epicaerus genus species (Epicaerus spp.) ), species of the genus Epilachna (Epilachna spp.), for example, Epilachna boreali Epilachna borealis, Epilachna baribestis (Epila (Chna varivestis), Epitrix genus species (Epitrix spp.), For example, Epitrix cucumeris, Epitri Epitrix fuscula, Epitrix hirtipennis Epitrix hirtipennis, Epitrix subculinita (Epitr Epitrix tuber (Epitrix subcrinita), Epitrix tuber is), Faustinus spp., Gibium psiloide Gibbium psylloides, Gnathocels cornutus ocerus cornutus, Hellula undal is), Heteronychus arator, hetero Heteronyx spp., Hoplia argentea argentea), Hylamorpha elega ns), Hylotrupes bajulus, Hypera • Postica (Hypera postica), Hypomeses squamosus (Hypom eces squamosus), Hypothenemus sp. p.), for example, Hypothenemus hampei Hypothenemus obscurus, Hypo Hypothenemus pubescens, Lachnoste Luna consanguinea (Lachnosterna consanguinea), La Lasioderma serricorne, Latheticus • Oryzae (Latheticus oryzae), species of the genus Lathri *Lema dius spp.*, *Lema spp.*, *Leptinotharsa desemline* Ata (Leptinotarsa decemlineata), a species of the genus Leucoptera (L eucoptera spp.), for example, Leucoptera cophela (Leucopt era coffeella, Limonius ecty Lissorhoptrus oryzophilus (pus), Lissorhoptrus oryzophilus Listronotus spp. (=Hypernistella ophilus), Listronotus species (=Hypernistella ophilus) species of the genera Hyperodes and Lixus. , Luperodes spp., Luperomorpha xanthodera ( Luperomorpha xanthodera), Lyctus spp. pp.), Megacyllene genus species (Megacyllene spp.), for example, Megacyllene • Megacyllene robiniae, species of the genus Megacelis (Meg (Ascelis spp.), Melanotus genus species (Melanotus spp.), for example Melanotus longulus oregonensis oregonensis), Meligethes aeneus Melolontha spp. (eus), for example, Melolontha... Melolontha melolontha, a species of the genus Migdolus (Mig dolus spp.), Monocamus genus species, Naupa Naupactus xanthographus, Necro Necrobia spp. and Neogalerella genus species Niptus hololeucus (cella spp.) s), Oryctes rhinoceros, Oryzaev Oryzaephilus surinamensis, Oryzaphagus oryzae, genus Othiorhynx Species (Otiorhynchus spp.), e.g., Otiorhynchus cribricolis (Otiorhynchus cribricollis), Otiorhynchus cribricollis Otiorhynchus ligustici, Otiorhynchus ovatus (O Otiorhynchus ovatus, Otiorhynchus rugosostriatus (Ot iorhynchus rugosostriarus, Othiolynchus surcatus (Otiorhynchus sulcatus), Oulema sp. p.), for example, Oulema melanopus, Oulema Oulema oryzae, Oxysetonia jukunda Etonia jucunda, Phaedon cochleariae Phyllophaga spp. (Phyllophaga chleariae), Phyllophaga species Phyllophaga helleri, a species of the genus Phyllophaga (P (Phyllotreta spp.), for example, Phyllotreta almorasiae (Phyl Lotreta armoraciae, Phyllotreta psilla ta pusilla), Phyllotreta ramosa a) Phyllotreta striolata, Popillia japonica, a species of the genus Premnotripes. (Premnotrypes spp.), Prostephanus Truncatus (Pros tephanus truncatus), Psylliodes sp. (spp.), for example, Psylliodes affinis s ), Psylliodes chrysocephalus a) Psylliodes punctulata, Ptinus spp., Rhizobius ventralis Us ventralis), Rhizopertha Dominica Rhynchophorus inica), Rhynchophorus spp., Rhynchophorus Rhynchophorus ferrugineus, Rhynchophorus Cophorus palmarum, Scolitus Genus and species (Scolytus spp.), for example, Scolytus multistriatus (Sc Olytus multistriatus), Sinoxylon perhorans (Sino (xylon perforans), Sitophilus spp. .), for example, Sitophilus granarius s), Sitophilus linearis, Sitophil Sitophilus oryzae, Sitophilus zeamais (Sitophilus zeamais), a species of the genus Sphenopho (rus spp.), Stegobium paniceu m), species of the genus Sternechus (Sternechus spp.), for example, Sternechus... Sternechus paludatus, a species of the genus Symphilethes. mphyletes spp.), Tanymecus genus species, For example, Tanymecus dilaticollis Tanymecus indicus, Tanymecus paris Attus (Tanymecus palliatus), Tenebrio molitor (Tene brio molitor), Tenebrioides mauretanicus (Tenebrioi Tribolium spp. (Tribolium des mauretanicus) .), for example, Tribolium audax, Tribo Tribolium castaneum, Tribolium co Tribolium confusum, Trogoderma species (Erma spp.), Tychius spp., Xylotrex genus Species (Xylotrechus spp.), Zabrus genus species (Zabrus spp.), For example, Zabrus tenebrioides; For example, Anisorabis marichime of the order Dermaptera. Solabis maritime), Holficula auricularia (Forficula la auricularia, Labidura riparia ia); For example, species of the genus Aedes in the order Diptera, Aedes aegypti, Aedes arbopictus (Aedes albopictus), Aedes sti Aedes vexans, Agromiza species (Agromyza spp.), for example, Agromyza frontera (Agromyza (frontella), Agromyza parvicornis (Agromyza parvicornis) Anastrepha spp. (cornis), Anastrepha genus species, Anofele Anopheles spp., for example, Anopheles quadrimaculatus (Anopheles quadrimaculatus), Anopheles gambiae (Anopheles gambiae), Asphondylia genus species a spp.), Bactrocera spp., for example, Bactrocera Bactrocera cucurbitae, Bactrocera Bactrocera dorsalis, Bactrocera oleae (Bactrocera oleae), Bibio horzlanus ulanus), Calliphora erythro Cephala, Calliphora vicina, Selachi Ceratitis capitata, a species of the genus Chilonomus (Chir Chrysomya spp. (Chrysomya spp.), Chrysomya Chrysops spp., Chrysozona pulvialis (Chrysozona pulvialis) Cochliomya spp. (Ona pluvialis) , species of the genus Contarinia (Contarinia spp.), for example, Contarinia jo Contarinia johnsoni, Contarinia nasturtii (C Ontarinia nasturtii), Contarinia pyribora (Contari Contarinia sch Contarinia sorghicola (ulzi), Contarinia sorghicola ), Contarinia tritici, Cordylovia • Anthropophaga (Cordylobia anthropophaga), Clichoto Cricotopus sylvestris, a species of the genus Cricotopus. (Culex spp.), for example, Culex pipiens. s), Culex quinquefasciat (us), species of the genus Culicoides (Culcoides spp.), species of the genus Chryseta (Cul Iseta spp.), Cuterebra spp., Dacus Dacus oleae, Dasineura spp. ), for example, Dasineura brassicae, De Delia species (Delia spp.), for example, Delia antqua iqua), Delia coarctata, Delia flora Delia Florilega, Delia Platura ura), Delia radicum, Dermatovia Hominis (Dermatobia hominis), Drosophila species (spp.), for example, Drosphila melanogaster Drosophila suzukii ), Echinocnemus spp., Eurea herac Euleia heraclei, Fannia spp. Gasterophilus spp., Gasterophilus genus species ( Glossina spp., Haematopota spp. ), Hydrellia spp., Hydrellia griceola (Hy Hylemya spp. (Drellia griseola), Hylemya species Species of the genus Hippobosca (Hippobosca spp.), species of the genus Hypoderma (Hypoderma) Liriomyza spp., for example, Lirio Liriomyza brassicae, Liriomyza fuidobu Liriomyza huidobrensis, Liriomyza huidobrensis ( Liriomyza sativae, Lucilia spp. For example, Lucilia cuprina, a species of the genus Lutzomia ( Lutzomyia spp., Mansonia genus species, Mu Species of the genus Musca, for example, Musca domestica. Musca domestica vi cina), Oestrus spp., Osinella frito (Os Cinella frit), Paratanytarsus species (spp.), Paralauterbornela subscinkuta (Paralauterborni) Pegomya or Pegomya species (Pegomya or Pegomya subcincta) Pegomyia spp.), for example, Pegomyia betae (Pegomya bet ae), Pegomya hyoscyami, Pegomya ru Vibora (Pegomya rubivora), Phlebottoms genus species Phorbia spp. (us spp.), Phorbia species, Phormia species (rmia spp.), Piophila casei, Platy Platyparea poeciloptera, Proji Prodiplosis spp., Psila rosae Rhagoletis spp., for example, Rhagoletis • Rhagoletis cingulata, Rhagoletis completa (Rhagoletis completa), Rhagoletis Fausta (Rhagol etis fausta), Rhagoletis indifferens (ndifferens), Rhagoletis menda x) Rhagoletis pomonella, Salkov Sarcophaga spp. and Simulium spp. pp.), for example, Simulium meridiona le), Stomoxys spp., Tabanus species (s spp.), Tetanops spp., Tipla species pula spp.), for example, Tipula paludosa. Tipula simplex, Toxotrypana curvica Uda (Toxotrypana curvicauda); For example, in the order Hemiptera, Astizia acaciae baileyanae (Acizzia acaciaebaileyanae), Acizzia dodonae ( Acizzia dodonaeae, Acizzia uncatoides Acrida turrita, also known as uncatoides or acyl. species of the genus Acyrthosipon, e.g., Acyrthosipon pis Acrogonia species (Acyrthosiphon pisum) a spp.), Aeneolamia spp., Aneolamia Aganoscena spp., Aleurocanthus genus species Thus spp.), Aleyrodes proletera Aleurolobus barodensis (Aleurolobus barodensis) Aleurothrixus floccosus sus), Allocaridara malayensis Amrasca spp., e.g., Amrasca biguts Amrasca bigutulla, Amrasca debastans (Amrasc a devastans), Anuraphis cardu i) Species of the genus Aonidiella, for example, Aonidiella... Aonidiella aurantii, Aonidiella citrina Aonidiella citrina, Aonidiella inornata (Aonidie Aphanostigma p. (Aphanostigma inornata) Aphis spp., for example, Aphis citricola (A Aphis citricola, Aphis cracciv ora), Aphis fabae, Aphis holbesi (Ap his forbesi), Aphis glycines, Aphis gossypii, Aphis hederae Aphis illinoise nsis), Aphis middletoni, Aphis Aphis nasturtii, Aphis n erii), Aphis pomi, Aphis spiracola (Ap his spiraecola), Aphis viburniphylla Arboridia apicalis (Arboridia niphila) ), species of the genus Arytainilla, species of the genus Aspicella Pidiella spp., Aspidiotus spp. ), for example, Aspidiotus nerii, Atanus Genus and species (Atanus spp.), Aulacorthum solani solani), Bemisia tabaci, Blastopsila • Blastopsylla occidentalis, borei Boreioglycaspis melaleuca e) Brachycaudus helichrysi ), Brachycolus spp., Brevicoline brassica Brevicoryne brassicae, Cacopsy lla spp.), for example, Cacopsylla pyri cola, Calligypona marginata , Capulinia spp., Carneocephala fulgida (C Arneocephala fulgida, Ceratobacna lanigera Vaccuna lanigera, Cercopidae, Ceropragma Ceroplastes spp., Caetosiphon fragaehorii (C haetosiphon fragaefolii), Kyonaspis tegarensis (C hionaspis tegalensis, Chlorita onukii onukii), Chondracris rosea, Chromaphis juglandicola Chrysomphalus aonidum, Chrysomphalus ficus, *Chrysomphalus ficus* Mbira (Cicadulina mbila), Coccom Mytilus halii Coccus spp. (Coccus halli), for example, Coccus Coccus hesperidum, Coccus longus Coccus longulus, Coccus pseudomagnoliarum (Pseudomagnoliarum), Coccus viridis idis), Cryptomyzus ribis, Cryptomyzus Cryptoneossa spp. and Ctena genus Dalbulus spp., Dalbulus species Dialeurodes chittendeni, Dialeurodes Dialeurodes citri, Diaphorina citri aphorina citri), Diaspis spp., Jiu Diuraphis spp. and Doralis sp. p.), Drosicha spp., Dysaphis genus species is spp.), for example, Dysaphis apiif Dysaphis plantaginea (olia) ), Dysaphis tulipae, Dysaphis genus species (Dysmicoccus spp.), species of the genus Empoasca (Empoasca spp.) .), for example, Empoasca abrupta, Em Empoasca fabae, Empoasca Maligna Empoasca maligna, Empoasca sola na), Empoasca Stevensi, Helioso Species of the genus Eriosoma (Eriosoma spp.), for example, Eriosoma americanum (Erio Eriosoma la Eriosoma pyricola, Eriosoma nigerum Erythroneura spp. and Eucalyptrum species (E (Euphyllura spp.), Euphyllura species (pp.), Euscelis bilobatus, Feri Species of the genus Ferrisia (spp.), species of Fiorinia (sp.) p.), Furcaspis oceanica, Geoco Geococcus coffeae, a species of the genus Gl (ycaspis spp.), Heteropsylla cu bana), Heteropsylla spinulosa a) Homalodisca coagulata, Hyalopterus arundinis, Hyalo Pterus pruni, a species of the genus Icerya a spp.), for example, Icerya purchasi, I Species of the genus Idiocerus (Idiocerus spp.), species of the genus Idioscops (Idioscops) opus spp., Laodelphax striaterus Lecanium triatellus), Lecanium spp., for example, Lecanium corni (= Parthenole Lecanium corni) Parthenolecanium corni), Lepidosafes species Lepidosafes spp.), for example, Lepidosafes urumi (Lepidosaph Lipaphis erysimi, Roho Leucasspis japonica, Lyco Lycorma delicatula, a species of the genus *Lycorma macrosifleum*. crosiphum spp.), for example, Macrosiphum euforbiae (Macro Macrosiphum euphorbiae, Macrosiphum lily m lilii), Macrosiphum rosae, Ma Macrosteles facifrons, Maha Mahanarva spp., Melanaphys sacchari Metcalfiella sacchari, Metcalfiella species pp.), Metcalfa pruinosa, Metopo Metopolophium dirhodum, Moneria Monellia costalis, Monelliopsis pecanis (Mo Nelliopsis pecanis), Myzus genus species, for example Myzus ascalonicus, Myzus cerasi (Myzus cerasi), Myzus ligustri Myzus ornatus, Myzus persicae Myzus nicotianae Nasonovia ribisnigri, Neomas Species of the genus Neomaskellia, species of Nephotechchis (tettix spp.), for example, Nephotettix cinticocephalus (Nephote Nephotichkis negropictus (Nephotichkis cincticeps) ttix nigropictus, Nettigoni cla spectra), Nilaparvata lugens Oncometopia genus (gens), Oncometopia spp., Ortezia Orthezia praelonga, Oxya chinensis Pachypsylla spp. (ya chinensis), Parabemisia myricae, genus Paratriosa Species (Paratrioza spp.), for example, Paratriosa choquerelli (Para (Parlatoria trioza cockerelli), Parlatoria species pp.), Pemphigus spp., for example, Pemphigus • Bursarius (Pemphigus bursarius), Pemphigus potpourri Pemphigus populivenae, Peregrinus meigis (Pe Perkinsiella species (regrinus maidis) Phenacoccus spp., for example, Na Phenacoccus madeirensis, Pro Phloeomyzus passerinii, Holodo Phorodon humuli, a species of the genus Phylloxera. ra spp.), for example, Phylloxera debastratrix. devastatrix, Phylloxera notabilis tabilis, Pinnaspis aspid (istrae), Planococcus genus species (Planococcus spp.), for example, Planococcus citri, Prosopidopsis Flava (Prosopidopsylla flava), Protoplubinaria pirifolia Lumis (Protopulvinaria pyriformis), Pseudauracas Pseudaula caspis pentagona, Pseudo Species of the genus Pseudococcus, for example, Pseudococcus ka Pseudococcus calceolariae, Pseudococcus Pseudococcus comstocki, Pseudococcus Pseudococcus longispinus, Pseudococcus Udococcus maritimus, Pseudococcus Pseudococcus viburni, genus Pseudococcus Species (Psyllopsis spp.), Psylla genus species (Psylla spp.), for example Psylla buxi, Psylla mal i) Psylla pyri, Pteromal species (us spp.), Pulvinaria spp., Pirilla genus (Pyrilla spp.), species of the genus Quadraspidio tus spp.), for example, Quadraspigiotus jugransregiae (Quad raspidiotus juglansregiae, quadraspiridiotus male Quadraspidiotus ostreaeformis Quadraspidiotus perniciosus ciosus, Quesada gigas, Lastorococcus Genus species (Rastrococcus spp.), Rhopalosi genus species (Rhopalosi phum spp.), for example, Rhopalosiphum majestis. maidis, Rhopalosiphum oxyacanthae xyacanthae), Rhopalosiphum padi ), Rhopalosiphum rufiabdominare (Rhopalosiphum rufiabd ominale), Saissetia genus species (Saissetia spp.), for example, Saissetia Saissetia coffeae, Saissetia miranda (S aissetia miranda, Saissetia neglecta neglecta, Saissetia oleae, suka Scaphoideus titanus, Scaphoideus schizaphis Schizaphis graminum, Serenaspidus archiculatus Selenaspidus articulatus, Siph Flava a flava), Sitobion avenae, sogata Genus and species (Sogata spp.), Sogatella furcifera rcifera), Sogatodes spp., Stichthocephalus La Festina (Stictocephala festina), Siphoninus Phili Rheae (Siphoninus phillyreae), Tenaraphala maraiensi (Tenalaphara malayensis), Tetragonocephalus species (Te tragonocephela spp., Tinocallis cariaehoriae callis caryaefoliae), Tomaspis sp. p.), species of the genus Toxoptera (Toxoptera spp.), for example, Toxoptera... Toxoptera aurantii, Toxoptera citrichidus (Toxoptera citricidus), Trialeurodes bapolariorum ( Trialeurodes vaporariorum, Trioza genus (spp.), for example, Trioza diospyri, Typhlocyba spp., Unaspis (spp.), Viteus vitifolii, species of the genus Zigina (Zygina spp.); For example, species of the genus Aelia in the suborder Heteroptera. (pp.), Anasa tristis, genus Anthesiopsis species (Antestiopsis spp.), Boisea spp. , species of the genus Blissus (spp.), species of the genus Calocoris ( (spp.), Campylomma livida, Cabelleri Species of the genus Cavelerius, species of Cimex For example, Cimex adjunctus, Cimex • Hemipterus (Cimex hemipterus), Symex reticularius (C Cimex pilos Collaria spp., Cleonthiades gill Tus (Creontiades dilutus), Dasynus piperis (Dasynu (s piperis), Dichelops furcatus s), Diconocoris hewetti, disde Species of the genus Dysdercus, species of Euschistus us spp.), for example, Euschistus hero s), Euschistus servus, Euschis Euschistus tristigmus, Euschist Euschistus variolarius, genus Eurydema Species (Eurydema spp.), species of the genus Eurygaster (Eurygaster sp.) p.), Halyomorpha halys, heliopal Heliopeltis spp., Horcius nobilelus Leptocorisa spp. (as nobilellus), Leptocorisa species. ), Leptocorisa varicornis, Leptoglossus occidentalis is), Leptoglossus phyllopus ), species of the genus Lygocoris, for example, Lygocoris pabrine Lygocoris pabulinus, Lygus spp. For example, Lygus elisus, Lygus hesperus (Ly Lygus hesperus, Lygus lineolari s), Macropes excavatus, Megaco Megacopta cribraria, Miridae dae), Monalonion atratum, Netherland Species of the genus Nezara (Nezara vir) idula), species of the genus Nysius (spp.), species of the genus Oebal ( us spp.), Pentomidae, Piesma quadrata (P Piezodorus spp. (iesma quadrata), Piezodorus species. For example, Piezodorus guildinii ), Psallus spp., Pseudacista percea (Pseu Dacysta persea), Rhodnius spp., Sa Sahlbergella singularis, S Scaptocoris castanea, Scotinophore Species of the genus Scotinophora, Stephanitis pear. *Triatoma* (genus *Triatoma*), *Triatoma* (genus *Triatoma*). Species (Triatoma spp.); For example, species of the genus Acromyrmex in the order Hymenoptera. (rmex spp.), Athalia genus species, for example, Athalia • Athalia rosae, Atta spp., Campo Species of the genus Camponotus (Camponotus spp.), species of the genus Dolichobespra (Dolichobespra) Vespula spp.), Diprion genus species, for example, Diprion similis, a species of the genus Hoplocampa. (Hoplocampa spp.), for example, Hoplocampa kookei (cookei), Hoplocampa testud inea), Lasius spp., Linepitema (Iridiomyrmex) S)·Fumire (Linepithema (Iridiomyrmex) humile) Monomorium pharaonis, Palato Species of the genus Paratrechina (Paratrechina spp.), species of the genus Paravespra (Parave Plagiolepis spula spp., Plagiolepis genus species Species of the genus Sirex (Sirex spp.), for example, Sirex noctilio (Sirex Solenopsis invicta (Solenopsis noctilio) a) Tapinoma spp., technomyrmex albipes ( Technomyrmex albipes), Urocerus species (Urocerus s Vespa spp., e.g., Vespa crubro a crabro), Wasmannia auropunctata punctata), Xeris spp.; For example, Armaziridium vulgare (Arma) of the order Isopoda. dillidium vulgare, Oniscus asellus ellus), Porcellio scaber; For example, species of the genus Coptotermes in the order Isoptera. mes spp.), for example, Coptotermes Hormosanas formosanus), Cornitermes c umulans), Cryptotermes spp., Species of the genus Incisitermes (Incisitermes spp.), species of the genus Kalotermes (Ka lotermes spp.), Microtermes obesi besi), Nasutitermes spp., Odontothe Odontotermes spp., Porotetermes genus Reticulitermes spp. .), for example, Reticulitermes fla vipes), Reticulitermes hes Perus; Lepidoptera, for example, Acroa glycera ia grisella), Acronicta major ), species of the genus Adoxophyes, for example, Adoxophyes Adoxophyes orana, Aedia leucomelas (Aedia) Agrotis spp. (Agrotis leucomelas), for example Agrotis segetum, Agrotis epsilon (Agrotis ipsilon), Alabama spp., e.g. For example, Alabama argillacea, Amieloi Amyelois transitella, a species of the genus Analcia (A Narsia spp.), Anticarsia genus species, For example, Anticarsia gemmatalis ), Argyroploce spp., Autographa genus ( Autographa spp.), Barathra bra ssicae), Blastodacna atra, Bor Borbo cinnara, Buukratrikis tulbergera (Ccculatrix thurberiella), Bupa pinialius Busseola spp. (Lus piniarius), a species of the Busseola genus, Caco Cacoecia spp., Caloptilia tebora (lia theivora), Capua reticulana ), Carpocapsa pomonella, Carposi Carposina niponensis, Caymatbia blu Cheimatobia brumata, Chilo spp. For example, Chilo plejadellus, Chilo spur Chilo suppressalis, Coleutis pariana reutis pariana), Choristoneura sp. (spp.), Chrysodeixis chalcites es), Clysia ambiguella, Kunafaro Cnaphalocerus spp., Cnaphalocerus mejina Cnaphalocrocis medinalis, a species of the genus Cnephasia. Phasia spp., Conopomorpha spp. ), species of the genus Conotrachelus, species of the genus Copitarsia (Copitarsia spp.), Cydia genus species, for example, Cydia nigricana, Cydia pomonera a pomonella, Dalaca noctuides ), species of the genus Diaphania (Diaphania spp.), species of the genus Dipa Diatraea saccarias (Diatraea saccarias) *haralis*, *Dioryctria spp.*, for example, Dioryctria zimmermani, Aeri Earias spp., Ecdytropha aurantium Elasmopalpus lignocellus (Elasmopalpus aurantium), Elasmopalpus lignocellus (Elasmopalpus aurantium) Alpus lignosellus, Eldana saccharina Ephestia spp., for example, Ephe Ephestia elutella, Ephestia Quenie Ephestia kuehniella, a species of the genus Epinotia. (spp.), Epiphyas postvittan a) Erannis spp., Erscobiella musculana (E rschoviella musculana), Etiella sp. p.), Eudocima spp., Eulia genus species (spp.), Eupoecilia ambiguel la), species of the genus Euproctis, for example, Euproctis Euproctis chrysorrhoea, a species of the Euproctis genus. (Euxoa spp.), Feltia genus species, Galleria me Lonella (Galleria mellonella), Gracilaria species (Laria spp.), Grapholitha genus species, for example Grapholita molesta, Grapholita Pu Grapholita prunivora, Hedyl spp. Helicoverpa spp., for example Helicoverpa armigera, Helicoverpa Helicoverpa zea, a species of the genus Heliothi (s spp.), for example, Heliothis virecens Hepialus spp., for example, Hepialus humm Hepialus humuli, Hoffmannophila pseudospletera (Ho fmannophila pseudospretella), Homo eosoma species (Ho Moeosoma spp., Homona genus species, Hyponomeuta • Padella (Hyponomeuta padella), Cacaria flavofasiata (Kakivoria flavofasciata), Lampid spp. Laphygma spp., Laphygma species, Laspeylesia Laspeyresia molesta, Leusinodes orbonalis Leucinodes orbonalis, species of the genus Leucoptera a spp.), for example, Leucoptera coff Lithocolletis spp., for example, Lithocolletis blancardella a) Lithophane antennata, Robe Species of the genus Lobesia, for example, Lobesia botorana. (botrana), Loxagrotis albicosta Lymantria spp., for example, Lymantria Lymantria dispar, Lyonetia species ia spp.), for example, Lyonetia clerchera lla), Malacosoma neustria, Ma Luca testulalis, Mamestra Brascae (Mamestra brassicae), Melanitis leda Mocis spp., Monopis obviera is obviella, Mythimna separata ), Nemapogon cloacellus, Nymph Species of the genus Nymphula (spp.), species of the genus Oiketicus (sp.) p.), Omphisa spp., Operofthera genus Phtera spp.), Oria spp., Ortaga spp. haga spp.), Ostrinia genus species, for example, O Ostrinia nubilalis, Panoris Fran Panolis flammea, Parnalla genus species (Parnara spp.) Pectinophora spp., for example, Pectinophora... Pectinophora gossypiella, Perileucopter Species of the genus Perileucoptera (spp.), species of Phthor imaea spp.), for example, Phthorimaea opelclera. a operculella), Phyllocnistes citrela is citrella), Phyllonorycter species pp.), for example, Phyllonorycter blanccaldera blancardella), phyllonoricter culataegera (Phyllonor (Pieris crataegella), Pieris genus species (Pieris spp.), example For example, Pieris rapae, Platinota struthana (Pl atynota stultana, Plodia interpunctera Prussia interpunctella, Prussia genus species (Plusia spp.), Prussia • Plutella xylostella (= Plutella macrippen) Plutella maculipennis, Podesia species a spp.), for example, *Podesia syringae* Prays spp., Prodenia spp. .), Protoparce spp., Pseudaletia genus (P (Seudaletia spp.), for example, Pseudaletia unipuncta (Pseu daletia unipuncta), Pseudoprussia inclus (Pseu doplusia includens, Pyrausta nubilalis nubilalis), Rachiplusia nu, Skoye Species of the genus Schoenobius (e.g., Schoenobius bipun) Schoenobius bipunctifer, a species of the genus Silpophaga. Scirpophaga spp.), for example, Scirpophaga innotata (Scirp Scotia segetum (Scotia ophaga innotata) m), species of the genus Sesamia (e.g., Sesamia inferens) (Sesamia inferens), Sparganotis species Spodoptera spp.), for example, Spodoptera species Spodoptera eradiana, Spodoptera e Spodoptera exigua, Sp. Spodoptera frugiperda, Spodoptera praeffica ptera praefica), Stathmopoda spp. .), Stenoma spp., Stomopteryx subusesibewera ( Stomopteryx subsecivella, Sinantedon species Thedon (spp.), Tecia solanivora Thaumetopoea spp., Termesia genmata Squirrel (Thermesia gemmatalis), Tinea croacera cloacella, Tinea pellionella , Tineola bisselliella, Tortricis Genus and species (Tortrix spp.), Trichophaga tapetozera (a tapetzella), Trichoplusia spp. .), for example, Trichoplusia ni, Tripoliza Insertulas (Tryporyza incertulas), Ivy absoluta (T Viracola spp. (Virachola uta absoluta); Grasshoppers of the order Orthoptera or Saltatoria, for example, Aketa • Acheta domesticus, Diclopurus species Roplus spp.), Gryllotalpa genus species, For example, Grilotalpa gryllotalpa a) Species of the genus Hieroglyphus (Hieroglyphus spp.), species of the genus Roxsta (L (ocusta spp.), for example, Locusta mig Melanoplus spp., for example, Melanoplus devastator, Paratra Paratlanticus ussuriensis Schistocerca gregaria; For example, species of the genus Damalinia in the order Phthiraptera. Haematopinus spp., Rhinoceros species of the genus Linognathus (Linognathus spp.), species of the genus Pedicul (us spp.), Phylloxera vasta Trix, Phthirus pubis, Trichodectes genus species (Trichodectes spp.); For example, species of the genus Lepinotus in the order Psocoptera. Liposcelis spp. (Liposcelis tus spp.); For example, species of the genus Ceratophyllum in the order Siphonaptera. Ctenocephalide species (Phyllus spp.) s spp.), for example, Ctenocephalide canis Ctenocephalides canis, Ctenocephalides felis felis), Pulex irritans, Tunga pene Tunga penetrans, Xenopsis cheopis Ylla Cheopis); For example, Anaphotripsy obscura, a member of the order Thysanoptera. Anaphothrips obscurus, Baryotrips biformis (B aliothrips biformis, caetanahotrips reeuweni (Ch aetanaphothrips leeuweni), drepanotrips leuteri Drepanothrips reuteri), Enneotrips flavens (En Neothrips flavens, Frankliniera genus (lla spp.), for example, Frankliniella Fusca Frankliniella ossidentalis (Frankliniella fusca) (occidentalis), Frankliniera Skultzei lla schultzei), Frankliniel Triticisi la tritici), Frankliniella Basciny vaccinii), Frankliniella Williams williamsi), Haplothrips spp., Heliothrips spp., Hersinotrips femora Squirrel (Hercinothrips femoralis), species of the genus Cacotrips (Kak Rhipiphora othrips spp., Lipiothrips cruentatus othrips cruentatus), species of the genus Scirtothri (ps spp.), Taeniothrips cardamomi damomi), genus species of Thrips (Thrips spp.), for example, Thrips palmi (Thrips palmi), Thrips tabaci; For example, cytenolepisma (Zygentoma (=Thysanura)) Genus and species (Ctenolepisma spp.), Lepisma saccharina Lepismodes i (nquilinus), Thermobia domesti ca); For example, species of the genus Scutigerella in the class Symphyla. lla spp.), for example, Scutigerella immaculata immaculata; Pests of the phylum Mollusca, for example, the class Bivalvia For example, species of the genus Dreissena (Dreissena spp.); and further, For example, species of the genus Arion (Arion spp.) in the class Gastropoda. .), for example, Arion ater rufus, Bio Biomphalaria spp. and Bulinus species (us spp.), species of the genus Deroceras, for example, Deroceras Deroceras laeve, Galba spp. ), species of the genus Lymnaea (Lymnaea spp.), species of the genus Oncomelania (Oncome lania spp., Pomacea spp., succinea genus (Succinea spp.); Plant pests of the phylum Nematoda (i.e., plant parasitic nematodes), especially Aggre Aglenchus spp., for example, Aglenchus agricola (A glenchus agricola), Anguina spp. For example, Anguina tritici, Afelenkoy Aphelenchoides spp., for example, Aphelenchoides... Aphelenchoides arachidis Aphelenchoides fragariae, Veronolai Species of the genus Belonolaimus (e.g., Belonolaimus gracilis) Belonolaimus gracilis, Belonolaimus longicaudatsu Belonolaimus longicaudatus, Belonolaimus 'Nor' Belonolaimus nortoni, a species of the genus Bursaferencus. Saphelenchus spp.), for example, Bursaphelenchus cocofilus ( Bursaphelenchus cocophilus) Bursaphelenchus eremus, Bursaphelenchus xylosa Bursaphelenchus xylophilus, Cacopaulus genus Species (Cacopaurus spp.), for example, Cacopaurus pestis (Cacop aurus pestis), Criconemella spp. ), for example, Criconemella curvata, Criconemella onoensis, Crico Criconemella ornata, Criconemella lucidum Criconemella rusium, Criconemella xenoprakis (Cr iconemella xenoplax (=Mesocliconema xenoplax) Socriconema xenoplax, a species of the genus Criconemoides. emoides spp.), for example, Criconnemoides ferniae (Cricon Cricone moides ferniae, Cricone moides onoense Criconemoides onoense, Criconemoides ornatum des ornatum), Ditylenchus spp. For example, Ditylenchus dipsaci, Doriko Dolichodorus spp., Globodera ra spp.), for example, Globodera pallida ), Globodera rostochiensis ), species of the genus Helicotylenchus (Helicotylenchus spp.), for example, Helicotylenchus dihystera Hemicriconemoides spp., Hemi Species of the genus Hemicycliophora, species of Heterodera (H eterodera spp.), for example, Heterodera avenae a avenae), Heterodera glycine s), Heterodera schachtii, hills Species of the genus Hirschmaniella (Hirschmaniella spp.), species of the genus Hoplolymes (H oplolaimus spp., Longidorus genus species (Longidorus spp.) .), for example, Longidorus africanu s), species of the genus Meloidogyne, for example, Meloidogyne • Meloidogyne chitwoodi, Meloidogyne fa Meloidogyne fallax, Meloidogyne hapla Meloidogyne incognita Meloinema spp. (incognita), Nacobbs Genus species (Nacobbus spp.), Neotylenchus genus species Paralongidorus spp., Paralongidorus species Paraphelenchus spp., Paratrichodolus genus Species (Paratrichodorus spp.), e.g., Paratrichodorus minor (Paratrichodorus minor), Paraty *Pratylenchus spp.*, species of the genus *Pratylenchus*. .), for example, Platylenchus penet Pseudohalenchus spp. (rans), Psilenchus spp. and Punctodera species Odera spp., Quinisulcius spp. ), species of the genus Radopholus (Radopholus spp.), for example, Radopholus citro Phyllus (Radopholus citrophilus), Radopholus similis ( Radopholus similis), Rotylenchu spp. lus spp.), Rotylenchus genus species, Scutellaria Species of the genus Scutellonema, species of Subang *Trichodorus spp.*, *Trichodorus spp.*, for example However, Trichodorus obtusus, Trichodo Trichodorus primitivus, thylenecholine Species of the genus Tylenchorhynchus (e.g., Tylenchorhynchus thylenegoma) • Tylenchorhynchus annulatus, Chilenk Species of the genus Tylenchulus, for example, Tylenchulus semipenetra Tylenchulus semipenetrans, a species of the genus X Xiphinema spp.), for example, Xiphinema index (Xiphinema aindex).
[0093] The compound represented by formula (I) may, depending on the circumstances, be removed at a specific concentration or dose. It can also be used as a herbicide, a phytotoxicity reducer, a growth regulator, or a plant action agent to improve plant characteristics. or, a microbicide or a gametocid e) For example, fungicides, antifungal agents c) Bactericidal or virucidal agents (this includes agents that act on viroids) It can also be used as MLO (Mycoplasma-like organism) and RLO (Rickettsia) They can also be used as agents for various organisms. When appropriate, they can be used with other activating compounds. It can also be used as an intermediate or precursor for the synthesis of other substances.
[0094] Formulation / Form of Use The present invention further relates to formulations, in particular formulations for controlling undesirable animal pests. The formulation can be applied to animal pests and / or their habitats.
[0095] The formulation of the present invention is intended to be used in a "ready-for-use" form. It can be provided to the end user, that is, the formulation can be applied to plants or seeds using a spraying device or It can be applied directly by a suitable device such as a powder dispensing device. Alternatively, the formulation can be used. Provide to the end user in a concentrated form that requires dilution, preferably with water, before use. It is possible. Therefore, unless otherwise indicated, the expression "formulation" means such a concentrated It refers to an object, while the expression "form of use" refers to a "ready-to-use" solution, that is, normally This refers to the end user of such a diluted formulation.
[0096] The formulations of the present invention are, in a conventional manner, for example, by disclosing the compounds of the present invention herein. It can be prepared by mixing it with one or more appropriate auxiliary agents, such as the auxiliary agents used. can.
[0097] The formulation comprises at least one compound of the present invention and at least one type of agricultural auxiliary agent. (For example, containing carriers (one or more) and / or surfactants (one or more)) .
[0098] The carrier is generally an inert, solid or liquid natural or synthetic organic or inorganic substance. Yes, such carriers are generally used for the application of the compound, for example, to plants, plant parts, or seeds. To improve application to [the target area]. Suitable solid carriers include, but are not limited to, [the following]. Ammonium salts, in particular ammonium sulfate, ammonium phosphate, and ammonium nitrate, natural Rock powders, such as kaolin, clay, talc, chalk, quartz, attapulgite, montwood. Lilonite and diatomaceous earth, silica gel, and synthetic rock powder, such as finely powdered silica, aluminum Examples include mina and silicate. These are typical solid carriers that are useful for preparing granules. This does not limit the types of natural rocks that have been crushed and separated, such as calcite, marble, and light Synthetic granules consisting of rock, meerschmites and dolomite, inorganic and organic powders, and organic materials, for example Granules made from paper, sawdust, coconut shells, corn cobs, and tobacco leaf stalks. These include, but are not limited to, water, organic solvents, and Some combinations of these exist. Examples of suitable solvents include polar and nonpolar organic compounds. Chemical liquids, for example, can be selected from the following types: aromatic and non-aromatic carbon Hydrogen compounds (e.g., cyclohexane, paraffins, alkylbenzenes, xylene, etc.) Luene, tetrahydronaphtherene, alkylnaphthalenes, chlorinated aromatic compounds or chlorine Aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes, or methylene chlorides. Alcohols and polyols (these may be substituted in some cases, and ether) It may be esterified and / or esterified, for example, ethanol , propanol, butanol, benzyl alcohol, cyclohexanol or glycol ), ketones (e.g., acetone, methyl ethyl ketone, methyl isobutyl ketone, acetone) Tophenone or cyclohexanone), esters (this includes fats and oils) and (poly)ethers, unsubstituted and substituted amines, amides (e.g.) For example, dimethylformamide or fatty acid amides) and their esters, lactams ( For example, N-alkylpyrrolidones, especially N-methylpyrrolidone, and lactones, Rufons and sulfoxides (e.g., dimethyl sulfoxide), of plant or animal origin. Oils, nitriles (alkyl nitriles, e.g., acetonitrile, propionotril, Butyronitrile, or aromatic nitriles (e.g., benzonitrile), carbonate esters (Cyclic carbonate esters, for example, ethylene carbonate, propylene carbonate, butylene carbonate, or Dialkyl carbonates, for example, dimethyl carbonate, diethyl carbonate, dipropyl carbonate, carbonic acid Dibutyl (dioctyl carbonate). The carrier is a liquefied gas extender, i.e., under standard temperature and standard pressure. So what about liquids that are gases, such as aerosol propellants, such as halohydrocarbons, butane, and p These can also be propylthiouracil, nitrogen, and carbon dioxide.
[0099] Preferred solid supports are selected from clay, talc, and silica.
[0100] Preferred liquid carriers include water, fatty acid amides and their esters, and aromatic and non-aromatic carbons. Hydrogen compounds, lactams, lactones, carbonate esters, ketones, (poly)ethers They are selected.
[0101] The amount of the carrier is typically in the range of 1 to 99.99% by weight of the formulation, preferably 5% A range of 99.9% by weight, more preferably a range of 10 to 99.5% by weight, and most preferably The percentage is in the range of 20-99% by weight.
[0102] The liquid carrier is typically in the range of 20-90% by weight of the formulation, for example, 30-80% by weight. It exists within the percentage range.
[0103] The solid carrier is typically in the range of 0 to 50% by weight of the formulation, preferably 5 to 45% by weight. It exists within a percentage range, for example, between 10 and 30% by weight.
[0104] If the formulation contains two or more carriers, the approximate range refers to the total amount of carriers. do.
[0105] The surfactant may be ionic (cationic or anionic), amphoteric, or nonionic. ionic or nonionic surfactants, such as emulsifiers, foaming agents, dispersants, and wetting agents. These can be penetration enhancers and any mixture thereof. Examples of suitable surfactants include While not limiting, examples include: polyacrylic acid Salts of, ethoxylated poly(α-substituted)acrylate derivatives, salts of lignosulfonic acid (for example) , sodium lignosulfonate, phenolsulfonic acid, or naphthalenesulfonic acid Ethyl salts, alcohols, fatty acids, or fatty amines, or those that do not contain them. Polyhydrate oxide and / or polycondensate of propylene oxide (polyoxyethylene fatty acid ester For example, castor oil ethoxylate, polyoxyethylene fatty alcohol ether, For example, alkylaryl polyglycol ethers, substituted phenols (preferably) Alternatively, alkylphenols or arylphenols), salts of sulfosuccinate esters, Taurine derivatives (preferably alkyl taurates), polyethoxylated alcohols or These are phosphate esters of polyethoxylated phenols and fatty esters of polyols (for example, glycerides). Fatty acid esters of lycerol, sorbitol, or sucrose, sulfates (for example) , alkyl sulfates and alkyl ether sulfates), sulfonates (for example, Alkyl benzenesulfonates, aryl sulfonates, and alkylbenzene sulfonates), Phthalene / formaldehyde sulfonated polymer, phosphate ester, protein hydrolysate Dioxides, lignosulfite wastewater, and methylcellulose. The reference to salts in this paragraph is, Preferably, the respective alkali salts, alkaline earth metal salts, and ammonium salts are represented. ru.
[0106] Preferred surfactants include ethoxylated poly(α-substituted)acrylate derivatives and alcohols. Polycondensates of ethylene oxide and / or propylene oxide containing polyoxyen Chilean fatty acid ester, alkylbenzene sulfonate, naphthalene / formaldehyde Sulfonated polymers, polyoxyethylene fatty acid esters, for example, castor oil ethoxy Select from ethyl phosphate, sodium lignosulfonate, and arylphenol ethoxylate. It will be done.
[0107] The amount of surfactant is typically in the range of 5 to 40% by weight of the formulation, for example, 10 to 20% It is within the range of weight percent.
[0108] Further examples of suitable auxiliary agents include: water repellents, desiccants, and binders. (Adhesives, tackifiers, fixatives, such as carboxymethylcellulose, and powders) Or natural and synthetic polymers in the form of granules or latex, for example, Arabic Rubber, polyvinyl alcohol and polyvinyl acetate, natural phospholipids, such as cephalin (and lecithin, and synthetic phospholipids, polyvinylpyrrolidone and tyrose), thickeners and Second thickener (e.g., cellulose ether, acrylic acid derivative, xanthan gum, modified) Clay (for example, products available under the name Bentone, and finely powdered silica), stable Agents (e.g., low-temperature stabilizers, preservatives (e.g., dichlorophene, benzyl alcohol hemiphosphate) Lumar, 1,2-benzoisothiazolin-3-one, 2-methyl-4-isothiazolin -3-on), antioxidants, light stabilizers, especially ultraviolet stabilizers, or chemical and / or (another agent that improves physical stability), dyes or pigments (e.g., inorganic pigments, e.g., Iron oxide, titanium dioxide, and Prussian blue; organic dyes, For example, alizarin dyes, azo dyes and metal phthalocyanine dyes), defoaming agents (for example, cyanoacrylate dyes) (Licone defoaming agent and magnesium stearate), antifreeze, adhesives, gibberellins, and Processing aids, mineral oils and vegetable oils, aromatic substances, waxes, nutrients (this includes iron salts, manganese salts, boron) (Including trace nutrients such as natural salts, copper salts, cobalt salts, molybdenum salts, and zinc salts), protection Colloids, thixotropes, penetrants, metal ion chelating agents, and complex-forming substances (comple x (orth).
[0109] The selection of the auxiliary agent depends on the intended application method of the compound of the present invention and / or the physical properties of the compound. It depends on the characteristics. Furthermore, the auxiliary agent is used in the formulation or in a form of use prepared from the formulation. Selected to impart special characteristics (technical characteristics, physical characteristics, and / or biological characteristics) It is also possible to customize the formulation to meet specific needs by selecting an adjuvant. It can be customized.
[0110] The formulation contains one or more of the compounds of the present invention in an effective amount for insecticidal / acaricidal / nematicidal effects. The term "effective amount" refers to the amount used to control harmful insects / mites / nematodes on cultivated plants or on materials. This represents an amount that is sufficient for protection and does not cause substantial damage to the treated plant. Such quantities can vary widely, and are influenced by various factors, for example, The species of insect / mites / nematodes to be controlled, the treated cultivated plants or materials, the climatic conditions and the usage The present invention depends on specific compounds, etc. Typically, the formulations according to the present invention are 0.01 to 99 times Amount %, preferably 0.05 to 98% by weight, more preferably 0.1 to 95% by weight, More preferably, the layer is 0.5 to 90% by weight, most preferably 1 to 80% by weight. It contains a compound. The formulation may contain two or more of the compounds of the present invention. The approximate range indicates the total amount of the compound of the present invention.
[0111] The formulations of the present invention include solutions (e.g., aqueous solutions), emulsions, and aqueous and oily suspensions. Liquid formulations, powder formulations (e.g., wettable powders, soluble powders), powders, paste formulations, granular formulations (e.g., Soluble granules, granules for distribution, suspend emulsion formulations, impregnated with the compound of the present invention Natural or synthetic products, fertilizers, and furthermore, microencapsulated in polymer materials. The compounds of the present invention can be any conventional formulation type, such as the one described above. It can exist in the form of a suspension, an emulsified form, or a dissolved form. Examples of formulation types include solution formulations, water-soluble concentrates (e.g., SL, LS), and dispersible concentrates (DC). , suspensions and suspension formulations (e.g., SC, OD, OF, FS), emulsions (e.g., EC), Emulsions (e.g., EW, EO, ES, ME, SE), capsules (e.g., CS) ZC), pastes, pastels, wettable powders or powders (e.g., WP, SP, WS, DP) , DS), compression molding agents (e.g., BR, TB, DT), granular agents (e.g., For example, WG, SG, GR, FG, GG, MG), insecticide products (e.g., LN), and This is a gel formulation (e.g., GW, GF) for processing plant propagation material (e.g., seeds). These formulation types and further formulation types are by the Food and Agriculture Organization of the United Nations (FAO). It is defined. The summary is, “Catalogue of pesticide for mulation types and international coding System”, Technical Monograph No. 2, 6th As shown in "Croplife International, Ed. May 2008" It is being done.
[0112] Preferably, the formulation of the present invention is in one of the following forms: EC, SC, FS, SE, OD, WG, WP, CS, and more preferably, EC, SC, OD, WG, C S.
[0113] Examples of formulation types and further details on their preparation are provided below. If two or more compounds of the invention are present, the approximate amount of the compounds of the present invention is the total amount of the compounds of the present invention. This indicates the total amount of the substance. This means that there are two or more of any further components of the preparation in question. If typical components (e.g., wetting agents, binders) exist, then those components should also be treated accordingly. It is used.
[0114] (i) Water-soluble concentrate (SL, LS) 10-60% by weight of at least one compound of the present invention and 5-15% by weight of a surfactant ( For example, polycondensation of ethylene oxide and / or propylene oxide containing alcohol. (compound) is mixed with water and / or a water-soluble solvent (e.g., pro) in an amount such that the total amount is 100% by weight. Alcohols such as pyrene glycol, or carbonates such as propylene carbonate) Dissolve. Dilute the concentrated substance with water before application.
[0115] (ii) Dispersible concentrate (DC) 5 to 25% by weight of at least one compound of the present invention and 1 to 10% by weight of a surfactant and and / or a binder (e.g., polyvinylpyrrolidone) in such a total amount as 100% by weight Dissolve in a certain amount of organic solvent (e.g., cyclohexanone). Dilute with water to create a dispersion. You can obtain this.
[0116] (iii) Emulsion (EC) 15-70% by weight of at least one compound of the present invention and 5-10% by weight of a surfactant ( For example, a mixture of calcium dodecylbenzenesulfonate and castor oil ethoxylate. , an amount of water-insoluble organic solvent (for example, aromatic hydrocarbons or) that is 100% by weight in total Dissolve in fatty acid amide and, if necessary, in an additional water-soluble solvent. Diluting with water will An emulsion is obtained.
[0117] (iv) Emulsions (EW, EO, ES) 5-40% by weight of at least one compound of the present invention and 1-10% by weight of a surfactant (e.g.) For example, a mixture of calcium dodecylbenzenesulfonate and castor oil ethoxylate, , ethylene oxide and / or propyl alcohol, with or without alcohol (Polycondensate of ylene oxide) in 20-40% by weight of a water-insoluble organic solvent (e.g., aromatic carbon Dissolve in hydrogen. Use an emulsifier to emulsify the mixture until the total volume is 100% by weight. Add to a certain amount of water. The resulting formulation is a homogeneous emulsion. Before application, the emulsion The solution can be further diluted with water.
[0118] (v) Suspensions and Suspension Formulations (v-1) Water-based (SC, FS) In a suitable grinding device (e.g., a stirring ball mill), 20-60% by weight of the present invention At least one compound is mixed with 2-10% by weight of a surfactant (e.g., sodium lignosulfonate). (and polyoxyethylene fatty alcohol ether), 0.1-2% by weight of a thickening agent (for example) Then, xanthan gum and water are added and finely ground to obtain a suspension of fine active substances. Add in an amount that makes the total amount 100% by weight. Diluting with water stabilizes the active substance. A suspension is obtained. In FS-type formulations, up to 40% by weight of a binder (e.g., polyvinyl chloride) is used. Add (yl alcohol).
[0119] (v-2) Oil-based (OD, OF) In a suitable grinding device (e.g., a stirring ball mill), 20-60% by weight of the present invention At least one compound is mixed with 2-10% by weight of a surfactant (e.g., sodium lignosulfonate). (and polyoxyethylene fatty alcohol ether), 0.1-2% by weight of a thickening agent (for example) Then, a modified clay (especially bentone or silica) and an organic carrier are added and finely ground. This yields a fine active substance oil suspension. The organic support is such that the total amount is 100% by weight. Add by volume. Diluting with water will yield a stable dispersion of the active substance.
[0120] (vi) Granular wettable powders and water-soluble granules (WG, SG) 1-90% by weight (preferably 20-80% by weight, most preferably 50-80% by weight) At least one compound of the present invention is a surfactant (e.g., sodium lignosulfonate) (Sodium alkylnaphthylsulfonate and sodium alkylnaphthylsulfonate) and, if applicable, a carrier material are added and finely ground. Furthermore, using typical technical equipment (e.g., extrusion granulation, spray drying granulation, fluidized bed granulation) The surfactant and carrier substance are converted into a wettable granular preparation or a water-soluble granular preparation. It is used in an amount that is 0% by weight. Diluting with water provides a stable dispersion of the active substance. A solution is obtained.
[0121] (vii) Wettable powders and water-soluble powders W (WP, SP, WS) 50-80% by weight of at least one compound of the present invention in a rotor stator mill , 1-20% by weight of surfactant (e.g., sodium lignosulfonate, alkyl naphthium Sodium sulfonate) and a solid carrier in an amount such that the total amount is 100% by weight (for example, Add silica gel and grind. Dilute with water to obtain a stable dispersion or solution of the active substance. You can obtain this.
[0122] (viii) Gel formulations (GW, GF) In a stirring ball mill, 5 to 25% by weight of at least one compound of the present invention is added in 3 to 10 wt% surfactant (e.g., sodium lignosulfonate), 1-5 wt% binder ( For example, add carboxymethylcellulose and an amount of water such that the total amount is 100% by weight. Then, it is finely ground. This yields a fine suspension of the active substance. Diluting with water... This yields a stable suspension of the active substance.
[0123] (ix) Microemulsion agents (ME) 5-20% by weight of at least one compound of the present invention in a 5-30% by weight organic solvent blend (e.g., fatty acid dimethylamide and cyclohexanone), 10-25% by weight of surfactant Agent blend (e.g., polyoxyethylene fatty alcohol ether and arylphenol) Add the ethoxylate and water in an amount that makes up 100% by weight of the total. Stirring for 1 hour allows a thermodynamically stable microemulsion to spontaneously form.
[0124] (x) Microcapsules (CS) 5-50% by weight of at least one compound of the present invention, and 0-40% by weight of a water-insoluble organic solvent. (e.g., aromatic hydrocarbons), 2-15% by weight of acrylic monomers (e.g., methyl The oil phase containing acrylate, methacrylic acid, and di- or triacrylate is protected. Disperse in an aqueous solution of Lloyd's (e.g., polyvinyl alcohol). Radical initiation. By radical polymerization initiated by the agent, poly(meth)acrylate microcapsules A layer is formed. Alternatively, 5 to 50% by weight of at least one compound of the present invention, 0 to 40 wt% water-insoluble organic solvents (e.g., aromatic hydrocarbons) and isocyanate monomers (e.g.) For example, an oil phase containing diphenylmethene-4,4'-diisocyanate is protected by a protective agent. Disperse it in an aqueous solution of an iodine (for example, polyvinyl alcohol), thereby, Urea microcapsules are formed. In some cases, polyamines (e.g., hexamethylene) are used. Even when a diamine is added, polyurea microcapsules are formed. The monomer is C This accounts for 1-10% of the total weight of the S preparation.
[0125] (xi) dustable powders (DP, DS) At least one compound of the present invention is finely ground in an amount of 1 to 10% by weight, and the total amount becomes 100% by weight. It is then closely mixed with a suitable amount of solid carrier (e.g., pulverized kaolin).
[0126] (xii) Granules (GR, FG) 0.5 to 30% by weight of at least one compound of the present invention is finely ground, and the total amount is 100% by weight. It is bound to a solid support (e.g., silicate) in such an amount.
[0127] (xiii) Ultra-low volume liquids for spraying in small quantities )(UL) 1 to 50% by weight of at least one compound of the present invention, so that the total amount is 100% by weight Dissolve in a suitable amount of organic solvent (e.g., aromatic hydrocarbon).
[0128] Formulation types (i) to (xiii) may, in some cases, contain additional adjuvants, e.g., 0.1 to 1% by weight of preservative, 0.1 to 1% by weight of defoamer, 0.1 to 1% by weight of dye and / or pigment It may also contain 5-10% by weight of an antifreeze agent, etc.
[0129] mixture Compounds represented by formula (I) are, for example, used to expand the spectrum of action and sustain the action. To prolong the duration and increase the rate of action, repulsion To prevent or prevent the development of resistance, one or more appropriate fungicides, Bacterial agents, acaricides, mollusk repellents, nematicides, insecticides, microbial agents (microbiol (Phytotonic), beneficial species, herbicides, fertilizers, bird repellents, plant tonics (phytotonic) c) Used as a mixture with sterilizers, drug-induced harm reduction agents, information chemicals and / or plant growth regulators. It can also be used. Furthermore, such combinations of active compounds can improve plant growth. It is possible to do so, and / or to have resistance to abiotic factors (e.g., high or low temperatures). To improve tolerance to drought or to tolerance to increased water content or soil salinity. This is possible. Furthermore, it is also possible to improve flowering performance and fruiting performance, and germination ability It is also possible to optimize the development of strength and roots, and to make harvesting easier. It is possible to improve yield, and it is also possible to influence maturation, and harvested It is also possible to improve the quality and / or nutritional value of the harvested produce. It is also possible to extend the shelf life and / or improve the processability of harvested produce. It is also possible to do so.
[0130] Furthermore, the compound represented by formula (I) may be another active compound or an informative chemical (e.g., an inducer). Attractants, and / or bird repellents, and / or plant activators, and / or growth regulators, It can also be present in a mixture with (or fertilizer). Similarly, it can be represented by formula (I) These compounds are used to improve plant characteristics (e.g., growth, yield, and quality of harvested produce). It is also possible to use it.
[0131] In a particular embodiment of the present invention, the compound represented by formula (I) is present in the formulation, or Among the forms of use prepared from such formulations, further compounds (preferably described below) It exists in a mixed state with the listed compounds.
[0132] If one of the compounds listed below may exist in various tautomer forms: And in each case, those forms are also included, even if not explicitly mentioned. Furthermore, all the listed mixing partners are possible due to their functional groups. If possible, it can also form a salt with an appropriate base or acid, depending on the circumstances.
[0133] Insecticides / Acaricides / Nematicides In this specification, the active compounds identified by the "generic name" are known, and For example, the pesticide handbook ("The Pesticide Manual” 16th Ed., British Cro (p Protection Council 2012) or, It can be found on the internet (for example, "http: / / www.alanw (ood.net / pesticides). The classification is as of the filing date of this patent application. The latest "IRAC Mode of Action Classification" It is based on "Scheme".
[0134] (1) Acetylcholinesterase (AChE) inhibitors, preferably, Carbamate drugs include alanicarb, aldicarb, benziocarb, and benflaca. Lubu, Butocarboxime, Butoxycarboxime, Carbaryl, Carbofuran, Carbos Rufan, Ethiofencarb, Phenobucarb, Formetanate, Frathiocarb, I Soprocarb, Methiocarb, Methomyl, Metholcarb, Oxamyl, Pyrimikab, P Lopoxul, Thiodilb, Thiofanox, Triazamate, Trimethacarb, XM Selected from C and xylcarb; or Organic phosphate esters include acephate, azamethiphos, and azinephos-ethyl. Adinphos-methyl, Kazsaphos, Chlorethoxyphos, Chlorfenbinphos, Chlor Mephos, Chlorpyrifos-methyl, Coumaphos, Cyanophos, Dimeton-S-methyl, Di Azinon, dichlorvos / DDVP, diclotophos, dimethoate, dimethylvinphos, Disulfone, EPN, Ethion, Ethoprophos, Famfur, Fenamiphos, Fe Nitrothion, fenthion, fothiazate, heptenofos, imisiafos, isofe Nphos, O-(methoxyaminothiophosphoryl) salicylate isopropyl, isoxathio Malathion, Mecarbam, Methamidophos, Methidathion, Mevinphos, Monoclothol S, Nared, Omethoate, Oxydimethone-methyl, Parathion-methyl, Fenthoethone Fosmet, phosphamide, phosphamide, phoxim, pirimiphosphamide Profenofos, Propetamfos, Prothiofos, Pyraclofos, Pyridafenthio n, quinalphos, sulfotep, tebupyrimphos, temephos, terbuphos, tetrachlor Selected from vinphos, thiometone, triazophos, trichlorfon, and bamidothion. .
[0135] (2) GABA-controlled chloride channel blockers, preferably, Cyclodiene-organochlorine systems, selected from chlordan and endosulfan. ; or, Phenylpyrazole derivatives (fiprole derivatives) are ethiprole and fipronil. They are selected.
[0136] (3) Sodium channel modulator, preferably, Pyrethroids include acrinatrin, allethrin, and d-cis-trans-allethrin. n, d-transarethrin, bifenthrin, bioarethrin, bioarethrin s- Cyclopentenyl isomer, violethmetrin, cycloprothrin, cyfluthrin, beta -Cyfluthrin, Cyhalothrin, Lambda-Cyhalothrin, Gamma-Cyhalothrin, Cyper Metrine, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin n, zeta-cypermethrin, cyphenothrin [(1R)-trans-isomer], delta Metrine, empenthrin [(EZ)-(1R)-isomer], esfenvalerate, e Tofenprox, fenpropathrin, fenvalerate, flucitrinate, flu Metrine, tau-fluvalinate, halfenprox, imiprothrine, cadetrine monfluorothrin, permethrin, phenothrin [(1R)-trans-isomer], Prallethrin, pyrethrins (pyrethrum), resmethrin, siraphne Luofen, tefluthrin, tetramethrin, tetramethrin [(1R)-isomer], to Selected from laromethrine and transfluthrine; or DDT; or methoxychloride.
[0137] (4) Nicotinic acetylcholine receptor (nAChR) competitive modulators, preferred For more information, Neonicotinoids include acetamiprid, clothianidin, dinotefuran, and imi Selected from dacloprid, nitenpyram, thiacloprid, and thiamethoxam; or , Nicotine; or, Sulfoximine series, selected from sulfoxaflor; or, Butenolide derivatives, which are selected from flupyradiflon; or, Mesoionic drugs are selected from triflumezopyrim.
[0138] (5) Nicotinic acetylcholine receptor (nAChR) allosteric modulators - (Part I), preferably, Spinosine derivatives are selected from spinetrum and spinosad.
[0139] (6) Glutamate-regulated chloride channel (GluCl) allosteric modulo Ta, preferably, Avermectin / milbemycin derivatives: These are abamectin and emamectin benzoic acid. Selected from salt, lepimectin, and milbemectin.
[0140] (7) A juvenile hormone mimetic, preferably, Juvenile hormone analogs, which are selected from hydroprene, quinoprene, and methoprene. To be; or, Phenoxycarb; or pyriproxyfen.
[0141] (8) Various unspecified (multi-site) inhibitors, preferably, Alkyl halides, which are selected from methyl bromide and other alkyl halides. ru; or, Chloropicrin; or sulfuryl fluoride; or borax; or tartaric acid; or Methyl isocyanate-producing substances, these are dazomet and metham. They are selected.
[0142] (9) A string organ TRPV channel modulator, preferably, Pyridineazomethane derivatives, selected from pyrimetrozine and pyrifluquinazone; Or, Pilopene-type drugs are selected from afidopilopene.
[0143] (10) Mite growth inhibitors that act on CHS1, such as clofentezine, hexit Selected from azox, diflovidazine, and etoxazole.
[0144] (11) Microbial disruptors of the insect intestinal membrane, such as Bacillus turingiensis. Subspecies: Bacillus thuringiensis subsp. islaerensis ecies israelensis, Bacillus sphaericus sphaericus), Bacillus turingiensis subspecies Aizawai (Baci Illus thuringiensis subspecies aizawai), Bacillus thuringiensis subspecies (Bacillus thuringiensis) Bacillus turingiensis (nsis subspecies kurstaki), Bacillus turingiensis Subspecies: Bacillus thuringiensis subspecies cies tenebrionis) and Bt plant protein (this is Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCr Selected from y3A, Cry3Ab, Cry3Bb, and Cry34Ab1 / 35Ab1. ) will be selected from.
[0145] (12) Mitochondrial ATP synthase inhibitors, preferably, ATP disruptors, which are selected from diafenthiurone; or, Organotin compounds, which are derived from azocyclotin, cyhexatin, and fenbutatin oxide. Selected; or, Propargit; or tetradiphon.
[0146] (13) Uncoupling agents for oxidative phosphorylation by disrupting the proton gradient, which is, The choice is made from lorfenapir, DNOC, and sulfuramide.
[0147] (14) Nicotinic acetylcholine receptor channel blockers, such as bensultate P, cartap hydrochloride, thiocylam, and thiosultap-sodium Selected from Rium.
[0148] (15) Chitin biosynthesis inhibitors that act on CHS1, preferably, Benzoylurea derivatives include bistriflurone, chlorfluazurone, and diflubenzlor N, Flucycloxron, Flufenoxron, Hexaflumuron, Lufenuron, Nova The following are selected: rulon, nobiflumulone, teflubenzuron, and triflumulone.
[0149] (16) Chitin biosynthesis inhibitors (type 1), which are selected from buprofezin. ru.
[0150] (17) Molting disruptors (especially against Diptera, i.e., bi For dipterans, this is selected from cyromazine.
[0151] (18) Ecdysone receptor agonists, preferably, Diacylhydrazine derivatives include chromafenozide, halofenozide, and methoxyphenozide. Selected from zide and tebufenozide.
[0152] (19) Octopamine receptor agonist, which is selected from amitraz.
[0153] (20) Mitochondrial complex III electron transport inhibitors, such as hydramethylnon. Selected from asequinosyl, fluacrypilim, and bifenazate.
[0154] (21) Mitochondrial complex I electron transport inhibitors, preferably, METI acaricide and insecticide, this is phenazaquin, fenpyroximate, pirimi Selected from diphen, pyridaben, tebufenpyrad and tolfenpyrad; or, Derris (Rotenon).
[0155] (22) Voltage-gated sodium channel blockers, preferably, Oxadiazine derivatives, selected from indoxacarb; or, Semicarbazone-based drugs are selected from metaflumizone.
[0156] (23) An acetyl-CoA carboxylase inhibitor, preferably, Tetronic acid derivatives and tetramic acid derivatives, which include spirodiclofen and spiromethic acid Selected from fen, spiropidione, and spirotetramat.
[0157] (24) Mitochondrial complex IV electron transport inhibitors, preferably, Phosphide compounds include aluminum phosphide, calcium phosphide, phosphine, and phosphorus. Selected from zinc oxide; or, Cyanides include calcium cyanide, potassium cyanide, and sodium cyanide. Selected from.
[0158] (25) Mitochondrial complex II electron transport inhibitors, preferably, β-ketonitrile derivatives, selected from cyenopyrafen and cyflumetofen. To be; or, Carboxyanilide derivatives are selected from piflubumides.
[0159] (28) A ryanodine receptor modulator, preferably, Diamides include chlorantraniliprole, cyantranilprole, and cyclani. Selected from liprole, flubendiamide, and tetraliniprole.
[0160] (29) Chord organ modulator (target site not defined), this is Floni Selected from Kamid.
[0161] (30) GABA-controlled chloride channel allosteric modulator, preferably , Metadiamides, which are selected from broflanilides; or, Isoxazole-based drugs are selected from fluxamethamide.
[0162] (31) Baculovirus, preferably, Granulopathy viruses (GVs) are caused by codlinga (Cydia pomonella). GV and Codlinga look-alike (Thaumatotibia leucotreta) (G Selected from V); or Nuclear polyhedron disease viruses (NPVs) are found in the velvet bean caterpillar (Anticarsi). a gemmatalis)MNPV and Helicoverpa ar Selected from migera)NPV.
[0163] (32) Nicotinic acetylcholine receptor allosteric modulator (site II) This is selected from the GS-Omega / Kappa HXTX-Hv1a peptide.
[0164] (33) Further active compounds selected from the following: acinonapyr, afoxo Rayner, azadirachtin, benkrothiaz, benzoximate, benzpyrimoxane, Bromopropylate, quinomethionate, chloroprallethrin ethrin), cryolite, cyclobutriflurum (cyclobutriflurum) trifluram or cyclobutrifen (CAS 1460292-16-3), cycloxapride, cyetpyrphen (Cyetpyr afen), cyhalodiamide, dichloromesothiaz, di Cohol, dimpropyridaz, ε-Metofluthrin, ε- Momfluthrin (epsilon-momfluthrin), Frometkin, Fluaza Indolinidine, fluensulfone, fluphenelim, fluphenoxystrobin, fluf Diprole, fluhexaphon, fluopyram, flupyrim, flularaner, fluphenodyl Fupentiofenox (CAS 1472050) -04-6) Guadipyr, heptafluthrin, imidaclotiz, iprodione, isosyl Cloceram, κ-bifenthrin, κ-tefluthrin, lotiraner, meperfluthrin, Oxazosulfyl, paichongding, pyridaryl Pyrifluquinazon, pyriminostrobin, spirobudic lofen), tetramethylfluthrin, tetrachlorantraniliprole, tygolaner (tigolaner), thioxazafen, thiofluoximate (thiofluo ximate, iodomethane, triflupentoxide e) (CAS 1472050-04-6); Furthermore, Bacillus Films (Bac Preparation based on illus firmus (I-1582, BioNeem, Vo tivo), and furthermore, the following compounds: 1-{2-fluoro-4-methyl-5-[ (2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl (Chill)-1H-1,2,4-triazole-5-amine (WO2006 / 043635) (Known) (CAS 885026-50-6), {1'-[(2E)-3-(4-chloro Phenyl)propa-2-en-1-yl]-5-fluorospiro[indole-3,4' -Piperidine]-1(2H)-yl}(2-chloropyridine-4-yl)methanone (WO (Known since 2003 / 106457) (CAS 637360-23-7), 2-chloro- N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl] ]piperidine-4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (Known from WO2006 / 003494) (CAS 872999-66-1), 3-( 4-Chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-di Azaspiro[4.5]deca-3-en-2-on (known from WO2010052161) (CAS 1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl )-8-methoxy-2-oxo-1,8-diazaspiro[4.5]deca-3-en-4- Il ethyl carbonate (known from EP2647626) (CAS 1440516- 42-6), 4-(buta-2-in-1-yloxy)-6-(3,5-dimethylpiper (Zin-1-yl)-5-fluoropyrimidine (known from WO2004 / 099160) CAS 792914-58-0), PF1364 (already from JP2010 / 018586) (CAS 1204776-60-2), (3E)-3-[1-[(6-chloro-3 [-pyridyl)methyl]-2-pyridylidene]-1,1,1-trifluoropropane-2 - ON (Known from WO2013 / 144213) (CAS 1461743-15-6) , N-[3-(benzylcarbamoyl)-4-chlorophenyl]-1-methyl-3-(pe (Trifluoromethyl)-4-(trifluoromethyl)-1H-pyrazole-5-carbbox Samide (known from WO2010 / 051926) (CAS 1226889-14-0) , 5-bromo-4-chloro-N-[4-chloro-2-methyl-6-(methylcarbamoyl )phenyl]-2-(3-chloro-2-pyridyl)pyrazole-3-carboxamide (C (Known from N103232431) (CAS 1449220-44-3), 4-[5-( 3,5-Dichlorophenyl)-4,5-Dihydro-5-(trifluoromethyl)-3-I Soxazolyl]-2-methyl-N-(cis-1-oxide-3-thietanyl)benzal Mido, 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoro Romethyl)-3-isoxazolyl]-2-methyl-N-(trans-1-oxide-3 -Thietanyl)benzamide and 4-[(5S)-5-(3,5-dichlorophenyl)- 4,5-Dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl -N-(cis-1-oxide-3-thietanyl)benzamide (WO2013 / 0503) (Known from 17A1) (CAS 1332628-83-7), N-[3-chloro-1-( [3-pyridinyl)-1H-pyrazole-4-yl]-N-ethyl-3-[(3,3,3- [Trifluoropropyl)sulfinyl]propanamide, (+)-N-[3-chloro-1 -(3-pyridinyl)-1H-pyrazole-4-yl]-N-ethyl-3-[(3,3, 3-Trifluoropropyl)sulfinyl]propanamide and (-)-N-[3-chloro Ro-1-(3-pyridinyl)-1H-pyrazole-4-yl]-N-ethyl-3-[(3 ,3,3-trifluoropropyl)sulfinyl]propanamide (WO2013 / 16 2715A2, WO2013 / 162716A2, US2014 / 0213448A1 or (Known) (CAS 1477923-37-7), 5-[[(2E)-3-chloro-2- [propen-1-yl]amino]-1-[2,6-dichloro-4-(trifluoromethyl) Phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-ca Rubonitrile (known from CN101337937A) (CAS 1105672-77- 2) 3-bromo-N-[4-chloro-2-methyl-6-[(methylamino)thioxide [Tyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-cal Boxamide, (Liudaibenjiaxuanan, CN103109816A) (Known) (CAS 1232543-85-9); N-[4-chloro-2-[[(1,1- Dimethylethyl)amino]carbonyl]-6-methylphenyl]-1-(3-chloro-2 -pyridinyl)-3-(fluoromethoxy)-1H-pyrazole-5-carboxamide ( (Known from WO2012 / 034403A1) (CAS 1268277-22-0), N -[2-(5-amino-1,3,4-thiadiazole-2-yl)-4-chloro-6-methyl Tylphenyl]-3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole -5-Carboxamide (known from WO2011 / 085575A1) (CAS 1233) 882-22-8), 4-[3-[2,6-dichloro-4-[(3,3-dichloro-2- [Propen-1-yl]oxy]phenoxy]propoxy]-2-methoxy-6-(trif Luoromethyl pyrimidine (known from CN101337940A) (CAS 11081) 84-52-6);(2E)- and 2(Z)-2-[2-(4-cyanophenyl)-1- [3-(trifluoromethyl)phenyl]ethylidene]-N-[4-(difluoromethyl] (C) Phenylhydrazine carboxamide (known from CN101715774A) (CA S 1232543-85-9); 3-(2,2-dichloroethenyl)-2,2-dimethicone Lu-4-(1H-benzoimidazole-2-yl)phenylcyclopropanecarboxylic acid Ester (known from CN103524422A) (CAS 1542271-46-4) ;(4aS)-7-chloro-2,5-dihydro-2-[[(methoxycarbonyl)[4- [(trifluoromethyl)thio]phenyl]amino]carbonyl]indeno[1,2-e [1,3,4]Oxadiazine-4a(3H)-methyl carboxylate (CN10 (Known from 2391261A) (CAS 1370358-69-2); 6-deoxy-3 -O-ethyl-2,4-di-O-methyl-,1-[N-[4-[1-[4-(1,1,2 ,2,2-pentafluoroethoxy)phenyl]-1H-1,2,4-triazole-3 -ylphenylcarbamate-α-L-mannopyranose (US2014 / 027 (Known from 5503A1) (CAS 1181213-14-8); 8-(2-cyclopro Pyrmethoxy-4-trifluoromethyl-phenoxy)-3-(6-trifluoromethyl -Pyridazine-3-yl)-3-aza-bicyclo[3.2.1]octane (CAS 12 53850-56-4), (8-anti)-8-(2-cyclopropylmethoxy-4-to (6-trifluoromethyl-pyridazine-3-i)-3-(6-trifluoromethyl-pyridazine-3-i) Lu)-3-azabicyclo[3.2.1]octane (CAS 933798-27-7) (8-Syn)-8-(2-Cyclopropylmethoxy-4-trifluoromethylpheno Xy)-3-(6-trifluoromethylpyridazine-3-yl)-3-azabicyclo [3.2.1] Octane (WO2007040280A1, WO2007040282A (1 known) (CAS 934001-66-8), N-[3-chloro-1-(3-pyriol) [(Dinyl)-1H-pyrazole-4-yl]-N-ethyl-3-[(3,3,3-triflu) Oropropyl)thio]-propanamide (WO2015 / 058021A1, WO201 (Known from 5 / 058028A1) (CAS 1477919-27-9), and N-[ 4-(aminothioxomethyl)-2-methyl-6-[(methylamino)carbonyl]phen [Nyl]-3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-ca Ruboxamide (known from CN103265527A) (CAS 1452877-50- 7) 5-(1,3-dioxan-2-yl)-4-[[4-(trifluoromethyl) [enyl]methoxy]-pyrimidine (known from WO2013 / 115391A1) (CAS 1449021-97-9), 3-(4-chloro-2,6-dimethylphenyl)-8- Methoxy-1-methyl-1,8-diazaspiro[4.5]decane-2,4-dione(WO (Known from 2014 / 187846A1) (CAS 1638765-58-8), 3-( 4-Chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-2-oxo-1 ,8-diazaspiro[4.5]deca-3-en-4-yl-ethyl carbonate (WO2 (Known from 010 / 066780A1 and WO2011151146A1) (CAS 122) 9023-00-0), 4-[(5S)-5-(3,5-dichloro-4-fluorophenicol [Lu)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-N- [(4R)-2-ethyl-3-oxo-4-isoxazolidinyl]-2-methyl-ben Zuamido (known from WO2011 / 067272 and WO2013 / 050302) (CA) S 1309959-62-3).
[0165] disinfectant In this specification, the active ingredients identified by the "generic name" are known and For example, "The Pesticide Manual (16th Ed. Bri) Is it listed in the "Tissue Crop Protection Council"? Alternatively, you can search for it on the internet (for example, www.alanwood.n et / pesticides ).
[0166] All bactericidal mixing agents listed under the names of Class (1) to (15) are those If possible, the functional groups may also form salts with suitable bases or acids. All mixing agents listed in classes (1) to (15) may be used as appropriate. This may include tautomer forms.
[0167] (1) Inhibitors of ergosterol biosynthesis, e.g., (1.001) cyproconazole , (1.002) difenoconazole, (1.003) epoxyconazole, (1.00 4) Fenhexamide, (1.005) Fenpropidine, (1.006) Fenprop Morph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1. 009) Flutriol, (1.010) Imazalil, (1.011) Imazalil sulfate (1.012) Ipconazole, (1.013) Metconazole, (1.014) Mik Lobutanil, (1.015) Paclobutrazol, (1.016) Prochloraz, (1. 017) Propiconazole, (1.018) Prothioconazole, (1.019) Pyriso Xazol, (1.020) Spiroxamine, (1.021) Tebuconazole, (1.0 22) Tetraconazole, (1.023) Triadimenol, (1.024) Tridemol F, (1.025) Triticonazole, (1.026) (1R, 2S, 5S) - 5 - (4 -Chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-) (Riazole-1-ylmethyl)cyclopentanol, (1.027)(1S,2R,5R) )-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1 ,2,4-triazole-1-ylmethyl)cyclopentanol, (1.028)(2R )-2-(1-chlorocyclopropyl)-4-[(1R)-2,2-dichlorocyclopropyl Pill-1-(1H-1,2,4-triazole-1-yl)butan-2-ol, (1 .029)(2R)-2-(1-chlorocyclopropyl)-4-[(1S)-2,2-di Chlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butane- 2-All, (1.030)(2R)-2-[4-(4-chlorophenoxy)-2-(To [Difluoromethyl)phenyl]-1-(1H-1,2,4-triazole-1-yl) Ropan-2-ol, (1.031)(2S)-2-(1-chlorocyclopropyl)-4 -[(1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazo (1-yl)butan-2-ol, (1.032)(2S)-2-(1-chlorocycline (L-propyl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1, 2,4-Triazole-1-yl)butan-2-ol, (1.033)(2S)-2- [4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H -1,2,4-triazol-1-yl)propan-2-ol, (1.034)(R) -[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl) -1,2-oxazol-4-yl](pyridine-3-yl)methanol, (1.035 )(S)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl [(Pyridine-3-yl)(1 .036)[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl) [(Pyridine-3-yl)(1 .037)1-({(2R,4S)-2-[2-chloro-4-(4-chlorophenoxy) Phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2, 4-Triazole, (1.038)1-({(2S,4S)-2-[2-chloro-4-( 4-Chlorophenoxy)phenyl]-4-methyl-1,3-dioxolann-2-yl}methyl (Tyl)-1H-1,2,4-triazole, (1.039)1-{[3-(2-chloroph [phenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H -1,2,4-triazole-5-ylthiocyanate, (1.040)1-{[rel (2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)o Xylan-2-yl]methyl}-1H-1,2,4-triazole-5-ylthiocyane (1.041)1-{[rel(2R,3S)-3-(2-chlorophenyl)-2 -(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4 -Triazole-5-ylthiocyanate, (1.042)2-[(2R,4R,5R) -1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhepta [n-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, ( 1.043)2-[(2R,4R,5S)-1-(2,4-dichlorophenyl)-5-H [Droxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1 ,2,4-triazole-3-thione, (1.044)2-[(2R,4S,5R)-1 -(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptane- 4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1. 045)2-[(2R,4S,5S)-1-(2,4-dichlorophenyl)-5-hydro [Xy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2 ,4-triazole-3-thione, (1.046)2-[(2S,4R,5R)-1-( 2,4-Dichlorophenyl)-5-Hydroxy-2,6,6-Trimethylheptane-4- Il-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.04 7) 2-[(2S,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy -2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4 -Triazole-3-thione, (1.048)2-[(2S,4S,5R)-1-(2, 4-Dichlorophenyl)-5-Hydroxy-2,6,6-Trimethylheptan-4-yl ]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.049) 2-[(2S,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2 ,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-to Reazol-3-thione, (1.050)2-[1-(2,4-dichlorophenyl)-5 -Hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H -1,2,4-triazole-3-thione, (1.051)2-[2-chloro-4-(2 ,4-Dichlorophenoxy)phenyl]-1-(1H-1,2,4-Triazole-1- Il)propan-2-ol, (1.052)2-[2-chloro-4-(4-chlorophenate [Noxy)phenyl]-1-(1H-1,2,4-triazole-1-yl)butane-2- All, (1.053)2-[4-(4-chlorophenoxy)-2-(trifluoromethicone) [(1H-1,2,4-triazole-1-yl)butan-2-O (1.054)2-[4-(4-chlorophenoxy)-2-(trifluoromethyl) Phenyl]-1-(1H-1,2,4-triazol-1-yl)pentan-2-ol (1.055) Mefentrifluconazole, (1.056) 2-{[3-(2-clo (Lopenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}- 2,4-Dihydro-3H-1,2,4-Triazole-3-thione, (1.057)2- {[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorof [(enyl)oxyran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-tri Azole-3-thione, (1.058)2-{[rel(2R,3S)-3-(2-chloro) (Lopenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}- 2,4-Dihydro-3H-1,2,4-Triazole-3-thione, (1.059)5- (4-Chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4 -Triazole-1-ylmethyl)cyclopentanol, (1.060)5-(alylus Ruphanyl)-1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl (Lu)Oxyran-2-yl]methyl}-1H-1,2,4-triazole, (1.061 )5-(allylsulfanil)-1-{[rel(2R,3R)-3-(2-chlorophenate) [Nyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H- 1,2,4-Triazole, (1.062)5-(allylsulfanil)-1-{[re l(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl) Oxyran-2-yl]methyl}-1H-1,2,4-triazole, (1.063)N '-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)f [phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide, (1 .064)N'-(2,5-dimethyl-4-{[3-(2,2,2-trifluoroethoxy [Phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide (1.065)N'-(2,5-dimethyl-4-{[3-(2,2,3,3-tetraph [Oropropoxy]phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimi Doformamide, (1.066)N'-(2,5-dimethyl-4-{[3-(Pentafull Oroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidophenyl Lumamide, (1.067)N'-(2,5-dimethyl-4-{3-[(1,1,2,2 -tetrafluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methyl Chiliimidoformamide, (1.068)N'-(2,5-dimethyl-4-{3-[(2 ,2,2-trifluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl- N-methylimidoformamide, (1.069)N'-(2,5-dimethyl-4-{3- [(2,2,3,3-tetrafluoropropyl)sulfanyl]phenoxy}phenyl) -N-ethyl-N-methylimidoformamide, (1.070)N'-(2,5-dimeth Lu-4-{3-[(pentafluoroethyl)sulfanyl]phenoxy}phenyl)-N -Ethyl-N-methylimidoformamide, (1.071)N'-(2,5-dimethyl- 4-Phenoxyphenyl)-N-ethyl-N-methylimidoformamide, (1.072 )N'-(4-{[3-(difluoromethoxy)phenyl]sulfanyl}-2,5-di Methylphenyl)-N-ethyl-N-methylimidoformamide, (1.073)N'- (4-{3-[(difluoromethyl)sulfanyl]phenoxy}-2,5-dimethylphenyl (enyl)-N-ethyl-N-methylimidoformamide, (1.074)N'-[5- Romo-6-(2,3-dihydro-1H-inden-2-yloxy)-2-methylpyridyl [N-3-yl]-N-ethyl-N-methylimidoformamide, (1.075)N'-{ 4-[(4,5-dichloro-1,3-thiazole-2-yl)oxy]-2,5-dimeth {Fruphenyl}-N-ethyl-N-methylimidoformamide, (1.076)N'-{5 -Bromo-6-[(1R)-1-(3,5-difluorophenyl)ethoxy]-2-meth Lupyridine-3-yl-N-ethyl-N-methylimidoformamide, (1.077) N'-{5-bromo-6-[(1S)-1-(3,5-difluorophenyl)ethoxy] -2-methylpyridine-3-yl}-N-ethyl-N-methylimidoformamide, (1 .078)N'-{5-bromo-6-[(cis-4-isopropylcyclohexyl)oxy [C]-2-methylpyridine-3-yl}-N-ethyl-N-methylimidoformamide, (1.079)N'-{5-bromo-6-[(trans-4-isopropylcyclohexyl [L)oxy]-2-methylpyridine-3-yl}-N-ethyl-N-methylimidoform Amide, (1.080)N'-{5-bromo-6-[1-(3,5-difluorophenyl Ethoxy-2-methylpyridine-3-yl}-N-ethyl-N-methylimidoform a Mid, (1.081) Ipfentrifluconazole zole), (1.082)2-[4-(4-chlorophenoxy)-2-(trifluoro Methyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propane-2 -ol, (1.083)2-[6-(4-bromophenoxy)-2-(trifluoromethyl [Cyl)-3-pyridyl]-1-(1,2,4-triazole-1-yl)propane-2- All, (1.084)2-[6-(4-chlorophenoxy)-2-(trifluoromethicone) [Lu)-3-pyridyl]-1-(1,2,4-triazole-1-yl)propane-2-ol (1.085)3-[2-(1-chlorocyclopropyl)-3-(3-chloro-2 [-Fluorophenyl)-2-hydroxypropyl]imidazole-4-carbonitri Lu, and (1.086)4-[[6-[rac-(2R)-2-(2,4-difluoro Phenyl)-1,1-difluoro-2-hydroxy-3-(5-thioxo-4H-1,2 ,4-triazole-1-yl)propyl]-3-pyridyl]oxy]benzonitrile.
[0168] (2) Inhibitors of the respiratory chain in complex I or complex II, for example, (2.001) Nzovindiflupil, (2.002) Bixafen, (2.003) Boscalid, (2. 004) Carboxine, (2.005) Fluopyram, (2.006) Fluthranil, ( 2.007) Fluxapiroxad, (2.008) Flamethopil, (2.009) Isoph Etamide, (2.010) isopyrazam (anti-epimeric enantiomer 1R,4 S,9S), (2.011) Isopyrazam (anti-epimerized enantiomer 1S, 4R,9R), (2.012) Isopyrazam (anti-epimerated racemic compound 1RS) ,4SR,9SR), (2.013) Isopyrazam (Syn-epimerated racemic compound (1 RS, 4SR, 9RS) and anti-epimerated racemic compounds (1RS, 4SR, 9SR) (a mixture of), (2.014) isopyrazam (syn-epimerized enantiomer 1R,4 S,9R), (2.015) Isopyrazam (syn-epimerized enantiomer 1S,4 R,9S), (2.016) Isopyrazam (syn-epimerated racemic compound 1RS,4 SR, 9RS), (2.017) Penflufen, (2.018) Penthiopyrad, (2 .019) Pidiflumetofen, (2.020) Pyraziflumid, (2.021) Sedaki San, (2.022)1,3-dimethyl-N-(1,1,3-trimethyl-2,3-dimethyl) Dro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.0 23) 1,3-dimethyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro -1H-Inden-4-yl]-1H-pyrazole-4-carboxamide, (2.024 )1,3-dimethyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1 H-Inden-4-yl]-1H-pyrazole-4-carboxamide, (2.025)1 -methyl-3-(trifluoromethyl)-N-[2'-(trifluoromethyl)biphenyl Ru-2-yl]-1H-pyrazole-4-carboxamide, (2.026)2-fluoro -6-(trifluoromethyl)-N-(1,1,3-trimethyl-2,3-dihydro-1 H-Inden-4-yl)benzamide, (2.027)3-(difluoromethyl)-1 -methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-indene-4-i) (Lu)-1H-pyrazole-4-carboxamide, (2.028)impilfluxam, ( 2.029)3-(difluoromethyl)-1-methyl-N-[(3S)-1,1,3- [Lymethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-ca Ruboxamide, (2.030)fluindapir, (2.031)3-(difluoromethyl )-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H -Inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2. 032)3-(difluoromethyl)-N-[(3S)-7-fluoro-1,1,3-tri [methyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole Lu-4-carboxamide, (2.033)5,8-difluoro-N-[2-(2-fluorine Ro-4-{[4-(trifluoromethyl)pyridine-2-yl]oxyphenyl)eth [Lu]Quinazoline-4-amine, (2.034)N-(2-cyclopentyl-5-fluoro Benzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl Lu-1H-pyrazole-4-carboxamide, (2.035)N-(2-tert-buty (L-5-methylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-flu Oro-1-methyl-1H-pyrazole-4-carboxamide, (2.036)N-(2- tert-butylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-f Luoro-1-methyl-1H-pyrazole-4-carboxamide, (2.037)N-(5 -Chloro-2-ethylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5 -Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038)N- (5-Chloro-2-isopropylbenzyl)-N-cyclopropyl-3-(difluoromethyl (Tyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.0 39) N-[(1R,4S)-9-(dichloromethylene)-1,2,3,4-tetrahydr Ro-1,4-methanonaphthalene-5-yl]-3-(difluoromethyl)-1-methyl- 1H-pyrazole-4-carboxamide, (2.040)N-[(1S,4R)-9-( Dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalene-5- Il-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxami (2.041)N-[1-(2,4-dichlorophenyl)-1-methoxypropane- 2-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboc Thamide, (2.042)N-[2-chloro-6-(trifluoromethyl)benzyl]-N -Cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyra Zol-4-carboxamide, (2.043)N-[3-chloro-2-fluoro-6-( [Trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5 -Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.044)N- [5-Chloro-2-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(di Fluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (2.045)N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1- Methyl-N-[5-methyl-2-(trifluoromethyl)benzyl]-1H-pyrazole -4-Carboxamide, (2.046)N-Cyclopropyl-3-(Difluoromethyl) -5-Fluoro-N-(2-Fluoro-6-Isopropylbenzyl)-1-methyl-1H -Pyrazole-4-carboxamide, (2.047)N-cyclopropyl-3-(diflu Oromethyl)-5-fluoro-N-(2-isopropyl-5-methylbenzyl)-1-methyl Chil-1H-pyrazole-4-carboxamide, (2.048)N-cyclopropyl-3 -(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl Lu-1H-pyrazole-4-carbothioamide, (2.049)N-cyclopropyl-3 -(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl Lu-1H-pyrazole-4-carboxamide, (2.050)N-cyclopropyl-3- (Difluoromethyl)-5-fluoro-N-(5-fluoro-2-isopropylbenzyl) )-1-methyl-1H-pyrazole-4-carboxamide, (2.051)N-cyclop Ropyru-3-(difluoromethyl)-N-(2-ethyl-4,5-dimethylbenzyl)- 5-Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052)N -Cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobendi (Lu)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.05 3) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-methyl (2. 054) N-Cyclopropyl-N-(2-Cyclopropyl-5-Fluorobenzyl)-3 -(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboc Thamide, (2.055)N-cyclopropyl-N-(2-cyclopropyl-5-methylbe (Nzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole- 4-Carboxamide, (2.056)N-Cyclopropyl-N-(2-Cyclopropyl (Nzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole- 4-Carboxamide, (2.057)pyrapropoine.
[0169] (3) Inhibitors of the respiratory chain in complex III, e.g., (3.001) ametoctra Gin, (3.002) Amisulbrom, (3.003) Azoxystrobin, (3.00 4) Coumethoxystrobin, (3.005) Moxistrobin, (3.006) cyazofamide, (3.007) dimoxistrobin (3.008) Enoxastrobin, (3.009) Famoxadone, (3.010) Fenamidon, (3.011) Flufenoxystrobin (obin), (3.012) fluoxastrobin, (3.013) kresoxim-methionine Lu, (3.014) Metminostrobin, (3.015) Orysastrobin, (3.01 6) Picoxystrobin, (3.017) Pyraclostrobin, (3.018) Pyrameth Strobin, (3.019) pyroxystrobin, (3.020) trifloxystrobin Bin, (3.021)(2E)-2-{2-[({[(1E)-1-(3-{[(E)- 1-Fluoro-2-phenylvinyl]oxy}phenyl)ethylidene]amino}oxy) Methylphenyl}-2-(methoxyimino)-N-methylacetamide, (3.022 )(2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazole-3-yl ]oxy}-2-(methoxyimino)-N,3-dimethylpenta-3-enamide, (3 .023)(2R)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl} -2-Methoxy-N-methylacetamide, (3.024)(2S)-2-{2-[(2 ,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamine D, (3.025) fenpicoxamide, (3.026) mandestrobin, (3.02 7) N-(3-ethyl-3,5,5-trimethylcyclohexyl)-3-formamide- 2-Hydroxybenzamide, (3.028)(2E,3Z)-5-{[1-(4-chloro (L-2-fluorophenyl)-1H-pyrazole-3-yl]oxy}-2-(methoxy) (imino)-N,3-dimethylpenta-3-enamide, (3.029){5-[3-(2 ,4-dimethylphenyl)-1H-pyrazole-1-yl]-2-methylbenzyl}cal Methyl bamate, (3.030) methyltetraprole, (3.031) floryl picocyl Samido.
[0170] (4) Inhibitors of mitosis and cell division, e.g., (4.001) carbendazim, ( 4.002) Dietofencarb, (4.003) Etaboxam, (4.004) Fluoro Picolid, (4.005) Pencyclon, (4.006) Thiabendazole, (4.00 7) Thiophanate-methyl, (4.008) Zoxamide, (4.009) 3-chloro- 4-(2,6-difluorophenyl)-6-methyl-5-phenylpyridazine, (4.0 10) 3-chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl) -6-methylpyridazine, (4.011)3-chloro-5-(6-chloropyridine-3- (Iyl)-6-methyl-4-(2,4,6-trifluorophenyl)pyridazine, (4.0 12)4-(2-bromo-4-fluorophenyl)-N-(2,6-difluorophenyl) )-1,3-dimethyl-1H-pyrazole-5-amine, (4.013)4-(2-bro (mo-4-fluorophenyl)-N-(2-bromo-6-fluorophenyl)-1,3-di Methyl-1H-pyrazole-5-amine, (4.014)4-(2-bromo-4-fluorine (Lofenyl)-N-(2-bromophenyl)-1,3-dimethyl-1H-pyrazole-5 -amine, (4.015)4-(2-bromo-4-fluorophenyl)-N-(2-chloro (4-6-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4 .016)4-(2-bromo-4-fluorophenyl)-N-(2-chlorophenyl)- 1,3-dimethyl-1H-pyrazole-5-amine, (4.017)4-(2-bromo- 4-Fluorophenyl)-N-(2-Fluorophenyl)-1,3-dimethyl-1H-P Razole-5-amine, (4.018)4-(2-chloro-4-fluorophenyl)-N -(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine , (4.019)4-(2-chloro-4-fluorophenyl)-N-(2-chloro-6- Fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4.020 )4-(2-chloro-4-fluorophenyl)-N-(2-chlorophenyl)-1,3- Dimethyl-1H-pyrazole-5-amine, (4.021)4-(2-chloro-4-flu Olophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazole -5-amine, (4.022)4-(4-chlorophenyl)-5-(2,6-difluoro Phenyl)-3,6-dimethylpyridazine, (4.023)N-(2-bromo-6-flu) Olophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H -Pyrazole-5-amine, (4.024)N-(2-bromophenyl)-4-(2- (Lolo-4-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, ( 4.025)N-(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4 -Fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine.
[0171] (5) Compounds that can act on multiple sites, for example, (5.001) Bordeaux mixture, (5. 002) Captahole, (5.003) Captan, (5.004) Chlorothalonil, ( 5.005) Copper hydroxide, (5.006) Copper naphthenate, (5.007) Copper oxide, (5.0 08) Basic copper chloride, (5.009) Copper(2+) sulfate, (5.010) Dithianone, (5 .011) Dozin, (5.012) Holpet, (5.013) Mancozeb, (5.014 Maneb, (5.015) Methylam, (5.016) Methylam Zinc (zinc), (5.017) copper oxine, (5.018) propineb, (5.019) sulfur Yellow and sulfur agents, e.g., calcium polysulfide, (5.020) thiuram, (5.021) di Neb, (5.022)diram, (5.023)6-ethyl-5,7-dioxo-6,7- Dihydro-5H-pyrrolo[3',4':5,6][1,4]dithiino[2,3-c][1 ,2] Thiazole-3-carbonitride.
[0172] (6) Compounds that can induce host defense, e.g., (6.001) Acibenzoral-S -Methyl, (6.002)Isothianil, (6.003)Probenazole, (6.004 ) Thiazinyl.
[0173] (7) Inhibitors of amino acid and / or protein biosynthesis, e.g., (7.001) C Prodinil, (7.002) Kasugamycin, (7.003) Kasugamycin hydrochloride hydrate Substance, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.00 6)3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinoli (n-1-il) Quinoline.
[0174] (8) Inhibitors of ATP production, e.g., (8.001) silthiofam.
[0175] (9) Inhibitors of cell wall synthesis, e.g., (9.001) benthevalicarb, (9.0 02) Dimethomorph, (9.003) Fullmorph, (9.004) Iprovaricarb, ( 9.005) Mandipropamide, (9.006) Pyrimorph, ( 9.007) Valifenarate, (9.008)(2E)-3-(4-tert-butyl Phenyl)-3-(2-chloropyridine-4-yl)-1-(morpholine-4-yl) Ropa-2-en-1-one, (9.009)(2Z)-3-(4-tert-butylfe Nyl)-3-(2-chloropyridine-4-yl)-1-(morpholine-4-yl)propane -2-en-1-on.
[0176] (10) Inhibitors of lipid and membrane synthesis, e.g., (10.001) propamocarb, ( 10.002) Propamocarb hydrochloride, (10.003) Torcrofos-methyl.
[0177] (11) Inhibitors of melanin biosynthesis, e.g., (11.001) trichillazole, ( 11.002) 2,2,2-trifluoroethyl{3-methyl-1-[(4-methylbenn Zoyl aminobutan-2-yl carbamate.
[0178] (12) Nucleic acid synthesis inhibitors, e.g., (12.001) Benalaxil, (12.00 2) Benalaxyl-M (Kiralaxyl), (12.003) Metalaxyl, (12.00 4) Metalaxyl-M (mephenoxam).
[0179] (13) Signaling inhibitors, e.g., (13.001) fludioxonil, (1 3.002) Iprodione, (13.003) Procymidone, (13.004) Proquina Zid, (13.005) quinoxyfen, (13.006) vinclozoline.
[0180] (14) Compounds that can act as uncoupling agents, e.g., (14.001) fluazinum (14.002) Meptilzino Cup.
[0181] (15) Further fungicides selected from the group consisting of the following: (15.001) A Bucidic acid, (15.002) Benciazole, (15.003) Bethoxazine, (15 .004) Capsimycin, (15.005) Carvone, (1 5.006) Quinomethionate, (15.007) Cufraneb, (15.008) Sifr Fenamide, (15.009) cymoxanil, (15.010) cyprosulfamide, ( 15.011) Fluthianil, (15.012) Fosetyl-aluminum, (15.01 3) Fosetyl-calcium, (15.014) Fosetyl-sodium, (15.015) Methyl isothiocyanate, (15.016) Metraphenone, (15.017) Mildi Omycin, (15.018) Natamycin, (15.019) Dimethyldithiocarbami Nickel nitrate, (15.020)nitrotal-isopropyl, (15.021)oxamethyl Oxamocarb, (15.022)oxathiapiproline, (15.02 3) Oxyfenthiin, (15.024) Pentachloroph Phosphates and salts, (15.025) Phosphites and salts thereof, (15.026) Propamocal Bu-fosetylate (propamocarb-fosetylate), (15.027 )periophenone (chlazafenone), (15.028) Tebufloxin, (15.029) Tecrophthalam, (15.030) Tornifanide, ( 15.031)1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4 ,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazole-2-yl} Piperidine-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyra Zole-1-yl]etanone, (15.032)1-(4-{4-[(5S)-5-(2 ,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]- 1,3-thiazole-2-yl}piperidine-1-yl)-2-[5-methyl-3-( (15.033)2-( 6-Benzylpyridine-2-yl)quinazoline, (15.034)dipimethitone, (1 5.035)2-[3,5-bis(difluoromethyl)-1H-pyrazole-1-yl] -1-[4-(4-{5-[2-(propa-2-in-1-yloxy)phenyl]-4 ,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazole-2-yl) Piperidine-1-yl]ethanone, (15.036)2-[3,5-bis(difluoromethyl) [Tyl)-1H-pyrazole-1-yl]-1-[4-(4-{5-[2-chloro-6-( [propa-2-in-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazo [Il-3-yl]-1,3-thiazole-2-yl)piperidine-1-yl]ethanone, (15.037)2-[3,5-bis(difluoromethyl)-1H-pyrazole-1-i Lu]-1-[4-(4-{5-[2-fluoro-6-(propane-2-in-1-yloxine [Phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thia Zole-2-yl)piperidine-1-yl]etanone, (15.038)2-[6-(3 -Fluoro-4-methoxyphenyl)-5-methylpyridine-2-yl]quinazoline, ( 15.039)2-{(5R)-3-[2-(1-{[3,5-bis(difluoromethyl )-1H-pyrazole-1-yl]acetyl}piperidine-4-yl)-1,3-thiazo [4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chloro Phenyl methanesulfonate, (15.040)2-{(5S)-3-[2-(1-{ [3,5-Bis(difluoromethyl)-1H-pyrazole-1-yl]acetyl}piper [Din-4-yl)-1,3-thiazole-4-yl]-4,5-dihydro-1,2-oxy Sazole-5-yl-3-chlorophenyl methanesulfonate, (15.041) Puflufenoquine, (15.042)2-{2-fluoro-6-[(8-fluoro-2- Methylquinoline-3-yl)oxy]phenyl}propan-2-ol, (15.043 ) Fluoxapiproline, (15.044) 2-{3-[2-(1-{[3,5-bis( Difluoromethyl)-1H-pyrazole-1-yl]acetyl}piperidine-4-yl) -1,3-thiazole-4-yl]-4,5-dihydro-1,2-oxazole-5-yl 2-phenylmethanesulfonate, (15.045)2-phenylphenol and salts, (15.046)3-(4,4,5-trifluoro-3,3-dimethyl-3,4-dihydr (15.047)Quinoline (quinofu) melin), (15.048) 4-amino-5-fluoropyrimidine-2-ol (alternative) Mutagenic form: 4-amino-5-fluoropyrimidine-2(1H)-one), (15.04 9) 4-Oxo-4-[(2-phenylethyl)amino]butanoic acid, (15.050)5 -amino-1,3,4-thiadiazole-2-thiol, (15.051)5-chloro- N'-phenyl-N'-(propa-2-in-1-yl)thiophene 2-sulfonohydr Radid, (15.052)5-fluoro-2-[(4-fluorobenzyl)oxy]pyri Midine-4-amine, (15.053)5-fluoro-2-[(4-methylbenzyl)o [Xy]pyrimidine-4-amine, (15.054)9-fluoro-2,2-dimethyl-5 -(quinoline-3-yl)-2,3-dihydro-1,4-benzoxazepine, (15. 055) Buta-3-in-1-yl{6-[({[(Z)-(1-methyl-1H-tetra Zol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridine-2-yl Carbamate, (15.056)(2Z)-3-amino-2-cyano-3-phenyl Ethyl acrylate, (15.057)phenazine-1-carboxylic acid, (15.058)3 ,4,5-Propyl trihydroxybenzoate, (15.059)quinoline-8-ol, (15.060) Quinoline-8-all sulfate (2:1), (15.061) {6 -[({[(1-methyl-1H-tetrazole-5-yl)(phenyl)methylene]ami (15.0) methyl pyridine-2-yl tert-butyl carbamate 62) 5-Fluoro-4-imino-3-methyl-1-[(4-methylphenyl)sulfonyl [Lu]-3,4-dihydropyrimidine-2(1H)-one, (15.063)aminopyrimidine En, (15.064)(N'-[2-chloro-4-(2-fluorophenoxy)-5- Methylphenyl (N-ethyl-N-methylimidoformamide), (15.065) N'-(2-chloro-5-methyl-4-phenoxyphenyl)-N-ethyl-N-methyl Imodoformamide), (15.066)(2-{2-[(7,8-difluoro-2-methylamide) Tylquinoline-3-yl)oxy]-6-fluorophenyl}propan-2-ol), (15.067)(5-bromo-1-(5,6-dimethylpyridine-3-yl)-3,3 -Dimethyl-3,4-dihydroisoquinoline), (15.068)(3-(4,4-diph Luoro-5,5-dimethyl-4,5-dihydrothieno[2,3-c]pyridine-7-yl (Quinoline), (15.069)(1-(4,5-dimethyl-1H-benzimidazole) -1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline ), (15.070)8-fluoro-3-(5-fluoro-3,3-dimethyl-3,4- Dihydroisoquinoline-1-yl)quinolone, (15.071)8-fluoro-3-(5 -Fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinoline-1-yl )Quinolone, (15.072)3-(4,4-difluoro-3,3-dimethyl-3,4- Dihydroisoquinoline-1-yl)-8-fluoroquinoline, (15.073)(N-Me Tyl-N-phenyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazo (Lu-3-yl]benzamide), (15.074)(methyl{4-[5-(trifluoro Methyl)-1,2,4-oxadiazole-3-yl]phenyl}carbamate), (1 5.075)(N-{4-[5-(trifluoromethyl)-1,2,4-oxadiazo [3-yl]benzyl cyclopropanecarboxamide), (15.076)N-methicone Lu-4-(5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]be Nzamide, (15.077)N-[(E)-methoxyiminomethyl]-4-[5-( (15) .078)N-[(Z)-methoxyiminomethyl]-4-[5-(trifluoromethyl) -1,2,4-Oxadiazole-3-yl]benzamide, (15.079)N-[4 -[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]phenyl Cyclopropanecarboxamide, (15.080)N-(2-fluorophenyl)-4 -[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]benzalkonium Mido, (15.081)2,2-difluoro-N-methyl-2-[4-[5-(triflu Oromethyl)-1,2,4-oxadiazole-3-yl]phenyl]acetamide, ( 15.082)N-allyl-N-[[4-[5-(trifluoromethyl)-1,2,4- Oxadiazole-3-yl)phenyl]methyl]acetamide, (15.083)N- [(E)-N-methoxy-C-methylcarbonimidoyl]-4-(5-(trifluoro (Methyl)-1,2,4-Oxadiazole-3-yl]-Benzamide, (15.08 4) N-[(Z)-N-methoxy-C-methyl-carbonimidoyl]-4-[5-( (15) .085)N-allyl-N-[[4-[5-(trifluoromethyl)-1,2,4-Oxy Sadiazole-3-yl]phenyl]-methyl]propanamide, (15.086)4, 4-dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazo [3-yl]phenyl]methyl]pyrrolidine-2-one, (15.087)N-methyl Lu-4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]be Nzencarbothioamide, (15.088)5-methyl-1-[[4-[5-(triflu Oromethyl)-1,2,4-oxadiazole-3-yl]phenyl]methyl]pyrrolidine N-2-one, (15.089)N-((2,3-difluoro-4-[5-(trifluoro Romethyl)-1,2,4-oxadiazole-3-yl]phenyl]methyl]-3,3, 3-Trifluoro-propanamide, (15.090)1-Methoxy-1-methyl-3- [[4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]f [Ethyl]methyl]urea, (15.091)1,1-diethyl-3-[[4-[5-(tri Fluoromethyl-1,2,4-oxadiazole-3-yl]phenylmethyl]urea (15.092)N-[[4-[5-(trifluoromethyl)-1,2,4-oxadi Azole-3-yl]phenyl]methyl]propanamide, (15.093)N-methoxy C-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3- Ilphenylmethylcyclopropanecarboxamide, (15.094)1-methoxy C-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadia Zole-3-yl]phenyl]methyl]urea, (15.095)N-methoxy-N-[[ 4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]phen [L]methyl)cyclopropanecarboxamide, (15.096)N,2-dimethoxy-N -[[4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl] centre [enyl]methyl]propanamide, (15.097)N-ethyl-2-methyl-N-[[ 4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl)phen [L]methyl]propanamide, (15.098)1-methoxy-3-methyl-1-[[4 -[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]phenyl ]methyl]urea, (15.099)1,3-dimethoxy-1-[[4-[5-(triflu Oromethyl)-1,2,4-oxadiazole-3-yl]phenyl]methyl]urea, ( 15.100)3-ethyl-1-methoxy-1-[[4-[5-(trifluoromethyl) -1,2,4-Oxadiazole-3-yl]phenyl]methyl]urea, (15.101 )1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-I [phenyl]methyl]piperidine-2-one, (15.102)4,4-dimethyl-2 -[[4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl] Phenylmethyl isoxazolidine-3-one, (15,103)5,5-dimethyl -2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-i [Phenyl]methyl]isoxazolidine-3-one, (15.104)3,3-dimethyl Chil-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3 -ylphenylmethylpiperidine-2-one, (15.105)1-[[3-full Oro-4-(5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl) -phenyl]methyl]azepan-2-one, (15.106)4,4-dimethyl-2-[ [4-(5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]-f [enyl]methyl]isoxazolidine-3-one, (15,107)5,5-dimethyl- 2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl ]phenyl]methyl]isoxazolidine-3-one, (15.108)(1-{4-[ 5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]benzyl}- 1H-pyrazole-4-yl)ethyl acetate, (15,109)N,N-dimethyl-1-{ 4-[5-(trifluoromethyl)-1,2,4-oxadiazole-3-yl]benzyl {1H-1,2,4-triazole-3-amine and (15.110)N-{2 ,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazole -3-yl]benzyl butanamide.
[0182] Biological pesticides as mixed components The compound represented by formula (I) can be combined with biological pesticides.
[0183] Biological pesticides include, in particular, bacteria, fungi, yeasts, plant extracts, and microorganisms. This includes the products formed by this process (e.g., proteins and secondary metabolites).
[0184] Biological pesticides include bacteria, such as spore-forming bacteria, which form colonies on roots. These include bacteria that act as biological insecticides, fungicides, or nematodes.
[0185] The above-mentioned bacteria that are used or can be used as biological pests Examples are as follows: Bacillus amyloliquefac Bacillus cereus (Bac) strain FZB42 (DSM 231179), or Bacillus cereus (Bac) Illus cereus), especially the Bacillus cereus strain CN CM I-1562, or Bacillus firmus Stock I-1582 (Accession number CNCM I-1582), or Bacillus pumilus (B Acillus pumilus), in particular, strain GB34 (accession number ATCC 7008) 14) and stock QST2808 (accession number NRRL B-30087), or Bacillus • Bacillus subtilis, in particular strain GB03 (accession number) ATCC SD-1397), or Bacillus subtilis tilis) stock QST713 (accession number NRRL B-21661), or Bacillus • Bacillus subtilis strain OST 30002 (Accession number) NRRL B-50421), Bacillus th uringiensis), especially the subspecies Bacillus turingiensis israelensis S (B. thuringiensis subspecies israelensi) s)(antigen type H-14) strain AM65-52 (accession number ATCC 1276), or, Bacillus thuringiensis subspecies (B. thuringiensis) subsp. aizawai), in particular, strain ABTS-1857 (SD-1372), and This is the subspecies Bacillus thuringiensis, *B. thuringiensis*. Bacillus turingiensis (s subsp. kurstaki) strain HD-1, or Bacillus turingiensis Subspecies tenebrioris (B. thuringiensis subsp. tene brionis) strain NB 176 (SD-5428), Pasteuria penetrans (P Pasteuria penetrans, Pasteuria species pp.) (Rotylenchulus renifo rmis) Nematode)-PR3 (Accession number ATCC SD-5834), Streptomyces • Microflavus strain (Streptomyces microflavus) AQ612 1 (= QRD 31.013, NRRL B-50550), Streptomyces gal Streptomyces galbus (AQ 6047, accession number NRR) L 30232).
[0186] Fungi and yeasts that are used or can be used as biological pesticides Examples of this type are as follows: Beauveria bassiana, especially strain ATCC 74040, Coniothyrium mini wardrobe ns), in particular, stock CON / M / 91-8 (accession number DSM-9660), Lekanishiriu Lecanicillium spp., especially strain HRO LEC 12, Lecanicillium lecanii (formerly known as Be Known as Verticillium lecanii (In particular, strain KV01, Metarhizium anisopriae) Anisopliae), in particular, strain F52 (DSM3884 / ATCC 90448) Metschnikowia fructico la), especially strain NRRL Y-30752, Paesilomyces humosoroseus (Pae Cilomyces fumosoroseus) (present: Isaria fumosorosea (I Saria fumosorosea), in particular, stock IFPC 200613 or stock Ap opka 97 (accession number ATCC 20874), Paesilomyces lyracinus (P aecilomyces lilacinus), especially Paesilomyces lilacinus ( P. lilacinus) strain 251 (AGAL 89 / 030550), Talaromyces • Talaromyces flavus, especially strain V117b, Trichodelia Trichoderma atroviride, especially strain SC 1 (Accession number CBS 122089), Trichoderma harzianum (Trichod Trichoderma harzianum), especially Trichoderma harzianum rify (T. harzianum rifai)T39 (accession number CNCM I-952).
[0187] Viruses that are used or can be used as biological pests Examples are as follows: Apple tortrix moth (Adoxophyes orana) granuloma virus (GV) Codlinga (Cydia pomonella) granulosis virus (GV), tobacco Helicoverpa armigera, nuclear polyhedra disease virus (NPV), white Spodoptera exigua mNPV, also known as the common fall armyworm. (Spodoptera frugiperda)mNPV, Egyptian armyworm (Afri) can cotton leafworm)(Spodoptera littoral is) NPV.
[0188] It is added as an "inoculant" to a plant, a part of a plant, or an organ of a plant, and its characteristics Bacteria and fungi that promote plant growth and health through specific characteristics are also included. Examples that can be given are as follows: Agrobacterium species (Agrobacterium spp.), Azorhizobium Caurinodance (Azorhizobium caulinodans), azospirill Species of the genus Azospirillum (Azospirillum spp.), species of the genus Azotobacter (Azotoba (cter spp.), Bradyrhizobium genus species (Bradyrhizobium spp.) .), Burkholderia spp., especially Burkholderia Rudellia cepacia (Burkholderia cepacia) (formerly known as Pseudo (formerly known as Pseudomonas cepacia), Gigaspora spp. or Gigaspora monosporum (Gi Glomus genus (Glomus spp.), Laccaria spp., Lactobacillus bucneri Obacillus buchneri), Paraglomus species (spp.), Pisolithus tinctorus Pseudomonas spp., Rhizobium species Rhizobium spp.), especially Rhizobium trifolia. ifolii), Rhizopogon genus species (Rhizopogon spp.), Scleroderma Genus species (Scleroderma spp.), Suillus genus species (Suillus spp.) ), species of the genus Streptomyces.
[0189] Plant extracts that are used or can be used as biological pesticides. and products formed by microorganisms (which include proteins and secondary metabolites). Examples of ) are as follows: Garlic (Allium sativum), Wormwood (Artemisia abs) inthium), azadirachtin, Biokeeper WP, Cassia nigricans, Cerastrus • Celastrus angulatus, American ant plant (C Henopodium anthelminticum), chitin, Armour-Ze n, European fern (Dryopteris filix-mas), horsetail (Equi setum arvense), Fortune Aza, Fungastop, Hea ds Up (Quinopodium quinoa saponin extract), insect repellent Chrysanthemum (Pyrethrum / Pyrethrins), Suriname quince (Quassia) Quercus, Quillaja, Rega lia, ("Requiem TM Insecticide), Rotenon, Liania / Rianodine, Symphytum officinale, Artemisia (Tanacetum vulgare), thymol, Triact 70, TriCo n, Nasturtium (Tropaeulum majus), Urticaria (Stinging nettle) a dioica), Veratrin, European Mistletoe (Viscum album) ), Brassicaceae extract, especially rapeseed powder or mustard powder The end of the plant, and bio-insecticidal / acaricidal active substances obtained from olive oil, in particular, for example, Products bearing the trademark name FLiPPER (registered trademark) contain charcoal as an active ingredient. Chain length C 16 -C 20 Unsaturated fatty acids / carboxylic acids.
[0190] Drug-damaging agents as mixed components The compound represented by formula (I) is a drug-induced harm reduction agent, for example, benoxacol, cloquintoset. To(-mexyl), siometrinil, cyprosulfamide, dichlormid, fenchlor Zole(-ethyl), fenchlorim, flurazole, fluxofenim, flirazole , isoxadiphen(-ethyl), mefenpyr(-diethyl), naphthalic anhydride, o Xavethrinyl, 2-methoxy-N-({4-[(methylcarbamoyl)amino]phen (Dichloro)(Sulfonyl)benzamide (CAS 129531-12-0), 4-(Dichloro) Cetyl)-1-oxa-4-azaspiro[4.5]decane (CAS 71526-07- 3) 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine( It can be combined with CAS 52836-31-4, etc.
[0191] Plants and parts of plants According to the present invention, all plants and parts of plants can be processed. Here, the plant is , desirable and undesirable wild plants or crop plants (including naturally occurring crop plants) All plants and parts of plants, such as grains (wheat, rice, rye, Barley, rye, oats, corn, soybeans, potatoes, sugar beets, taro Water oats, tomatoes, peppers, cucumbers, melons, carrots, watermelons, onions, lettuce, Spinach, leeks, green beans, and plants of the Brassica genus in the Brassicaceae family. (For example, cabbage) and other vegetable varieties, cotton, tobacco, rapeseed, and other vegetables. Furthermore, fruit plants (those that bear fruit, such as apples, pears, citrus fruits, and grapevines) It is understood to mean things like this. Crop plants are obtained through conventional breeding and optimization methods. It may be a plant that can be obtained by biotechnology and genetic engineering methods. It may be a plant that can be obtained by a combination of the above methods, or a plant that can be obtained by a combination of the above methods. It can be an object. Such crop plants also include transgenic plants. Furthermore, it includes plant varieties that can be protected by variety ownership rights and those that cannot. Plants grow from all stages of development, such as seeds, seedlings, and young plants (immature plants). It should be understood to mean the entire plant, including the mature parts. The parts of the plant are the shoots, leaves, and flowers. It is understood to mean all parts and organs of the above-ground and underground parts of a plant, including roots. Examples of parts that should be included are leaves, needle-like leaves, stems, trunks, flowers, fruiting bodies, fruits and seeds, and Furthermore, these include tubers, roots, and rhizomes. Harvested plants or parts of harvested plants. Furthermore, vegetative propagation organs al) and reproductive organs (genetic propagation mater) (al), for example, seedlings, tubers, rhizomes, cuttings and seeds are also plants. It is included in the part.
[0192] The treatment of plants and parts of plants according to the present invention using the compound represented by formula (I) is conventional Depending on the processing method, for example, immersion, spraying, vaporization, fogging, scattering, This can be done directly by application, injection, etc., or by applying the compound around the plant and parts of the plant. This is done by acting on the habitat or storage space. Furthermore, in the case of reproductive organs (propagation material), especially seeds... This can also be done by applying one or more coatings.
[0193] As already stated above, in accordance with the present invention, all plants and their parts can be processed. This can be done. In a preferred embodiment, wild plant species and plant varieties, or hybrids or p Plant species and varieties obtained by conventional biological breeding methods such as rotoplast fusion, Furthermore, those parts are processed. In yet another preferred embodiment, appropriate location In combination, transgenic genes obtained by genetic engineering methods combined with conventional methods are used. Processing plants and plant varieties (genetically modified organisms) and their parts. Term "part (pa) rts) or "parts of plants" or "parts of plants ( The term "plant parts)" has already been explained above. The present invention is particularly preferred Each of these processes the plants of the commercially available conventional varieties or the conventional varieties used. It is used for the purpose of plant varieties being developed through conventional breeding, mutagenesis, or recombinant DNA technology. It is understood to mean a plant that possesses new characteristics ("traits") obtained through a technique. These can be varieties, cultivars, biotypes, or genotypes.
[0194] Transgenic plants, seed treatment, and integrated events According to the present invention, the compound represented by formula (I) is advantageous for transgenic plants. Receiving genetic material that confers advantageous and / or useful characteristics (traits) to plant varieties or plant parts. It can be used to process the plants, plant varieties, or plant parts that have been picked. Yes. Therefore, the present invention relates to one or more recombinant traits or transgenic events or so It is intended that these can be combined and used in combination. Regarding the purpose of this application Transgenic events occur at specific locations (locuses) within the chromosomes of the plant genome. It is created by inserting a specific recombinant DNA molecule. This insertion results in "Ibe A novel DNA sequence called "the sequence" is formed, and the inserted recombinant DNA molecule and, The inserted DNA is adjacent to both ends. It is characterized by a certain amount of genomic DNA. While not limited to transgenic events, pest resistance and water use are also important factors. Efficiency, yield performance, drought tolerance, seed quality, improved nutritional quality, hybrid seed production and They have traits such as resistance to herbicides, and here, the trait is such a trait or transgenic trait. Measured in comparison to plants lacking bent. Such advantageous and / or useful characteristics Specific examples of (traits) include improved plant growth, vitality, stress tolerance, and uprightness. This includes lodging resistance, nutrient uptake, plant nutrition and / or yield, and in particular, improvement. Improved growth, increased tolerance to high or low temperatures, drought, or water or soil salinity levels. Improved resistance to pests, enhanced flowering performance, improved ease of harvesting, and accelerated maturation. , increased yield, improved quality and / or improved nutritional value of harvested produce, harvested The improved shelf life and / or processability of the products, as well as the protection against harmful animals and harmful microorganisms. Things (for example, insects, arachnids, nematodes, mites, slugs and snails) This refers to improved resistance or tolerance to it.
[0195] The characteristics of resistance or tolerance to such harmful animals and harmful microorganisms (especially insects) Among the DNA sequences that encode the protein to be donated, in particular, those that are widely described in the literature and are relevant to our work. Bacillus turingiensis (Ba), which encodes the Bt protein, is well known to the human brain. Genetic material derived from *Cillus thuringiensis* is one example. Also, proteins extracted from bacteria such as Photorhabdus Quality can also be mentioned (WO97 / 17432 and WO98 / 08932). In particular, the following: Examples include: Bt Cry protein or VIP protein (this is CrylA, C ryIAb, CryIAc, CryIIA, CryIIIA, CryIIIB2, Cry 9c (including Cry2Ab, Cry3Bb, and CryIF proteins) or exhibiting toxicity These fragments, as well as their hybrids or combinations, in particular , CrylF protein or hybrids derived from CrylF protein (e.g., hybrids Lid (Cryl A-Cryl F protein or its toxic fragments), Cryl Type A protein or a toxic fragment thereof, preferably a CrylAc protein. or hybrids derived from CrylAc protein (e.g., hybrid CrylAb- CrylAc protein, or CrylAb or Bt2 protein, or exhibiting toxicity The tail fragment, Cry2Ae, Cry2Af or Cry2Ag protein or The toxic fragment, the Cryl A.105 protein, or the toxic flag Menthol, VIP3Aa19 protein, VIP3Aa20 protein, COT202 or The VIP3A protein produced in the COT203 cotton ventricle, "Estruch et al. (1996), Proc Natl Acad Sci US A. The VIP3Aa protein described in "28;93(11):5389-94" or The toxic fragment, Cry protein, is described in WO2001 / 47952. The insecticidal protein (WO9) derived from the insecticide Xenorhabdus. (As described in 8 / 50427), insecticidal tadpoles derived from Serratia Protein (especially derived from Serratia entomophila) Insecticidal proteins, or derived from various species of the genus Photorhabdus. Insecticidal proteins, for example, photolabus described in WO98 / 08932 Tc-protein derived from (Photorhabdus). Furthermore, as mentioned above The sequences (especially the sequences of those fragments that exhibit toxicity) and several amino acids ( Any variant of those proteins in which 1-10, preferably 1-5) is different or Mutation, or signal peptide (e.g., plastid signal peptide) or other Any variant or mutation of the protein or peptide fused to that protein Mutants are also included here.
[0196] Another particularly important example of such properties is one or more herbicides (e.g., imidazolinone). Resistance to (sulfonylurea systems, glyphosate, or phosphinotricin) is conferred. The goal is to give transformed plant cells and plants resistance to specific herbicides. Among the DNA sequences that encode the donating protein, the following are particularly noteworthy: WO2009 / 152359 describes the confation of resistance to lufosinate herbicides. The bar gene or PAT gene or Streptomyces coericolor (Strep tomyces coelicolor) gene, herbicides targeting EPSPS (especially Appropriate EPSPS ( which confers resistance to herbicides such as glyphosate and its salts) 5 -Enolpyrubilushikimic acid-3-phosphate-synthase The gene that codes for glyphosate The gene encoding sate-n-acetyltransferase, or glyphosate acid Genes that encode reductase enzymes. Further suitable herbicide resistance traits include the following: These include: at least one type of ALS (acetolactate synthase) inhibitor (e.g., WO2) 007 / 024782), mutant Arabidopsis (ALS) / AHAS gene (e.g., U.S. Patent No. 6,855,533), 2,4-D(2,4-di A 2,4-D-monooxygenase that confers resistance to chlorophenoxyacetic acid is used. The gene that causes doping, and the relationship between dicamba (3,6-dichloro-2-methoxybenzoic acid) and A gene that encodes dicamba monooxygenase, which confers resistance.
[0197] Another particularly important example of such characteristics is, for example, systemic acquired resistance (SAR). Systemin, phytoalexins, inducing factors, and further resistance genes and the proteins and toxins expressed thereby, plant pathogenic fungi, bacteria and / or This refers to improved resistance to viruses.
[0198] Transgenic plants or plant varieties that can be preferably treated according to the present invention Particularly useful transgenic events in this context include the following: KIRU: Event 531 / PV-GHBK04 (Cotton, insect control, WO2002 / 0406) (as described in 77), Event 1143-14A (Cotton, insect control, not deposited) (As stated in WO2006 / 128569); Event 1143-51B (Wata) , insect control, not deposited, described in WO2006 / 128570); Ibe 1445 (Cotton, herbicide resistant, not deposited, US-A2002-120964) Or as described in WO2002 / 034946); Event 17053 (rice, weed control) Drug resistance, deposited as PTA-9843, described in WO2010 / 117737. (is being held); Event 17314 (rice, herbicide resistant, deposited as PTA-9844) (As stated in WO2010 / 117735); Event 281-24-23 6 (Cotton, insect control - herbicide resistant, deposited as PTA-6233, WO200) (As described in 5 / 103266 or US-A2005-216969); Event 3 006-210-23 (Cotton, insect control - herbicide resistant, deposited as PTA-6233) As described in US-A2007-143876 or WO2005 / 103266 (is present); Event 3272 (Corn, Quality trait, as PTA-9972) The depositary is listed as WO2006 / 098952 or US-A2006-230473. Listed as; Event 33391 (Wheat, herbicide resistant, PTA-2347) Entrusted, as described in WO2002 / 027004, event 40416 ( Corn, insect control-herbicide resistant, deposited as ATCC PTA-11508 It is listed in WO11 / 075593); Event 43A47 (Corn) Insect control - herbicide resistant, deposited as ATCC PTA-11509, WO2 (As described in 011 / 075595); Event 5307 (Corn, Insect Control) It is deposited as ATCC PTA-9561, and is recorded in WO2010 / 077816. Listed); Event ASR-368 (Bentgrass, Herbicide Resistant, ATCC PT) Deposited as A-4816, US-A2006-162007 or WO2004 (as described in / 053062); Event B16 (Corn, herbicide resistant, deposit) Not listed in US-A2003-126634); Event BPS- CV127-9 (Soybean, herbicide resistant, deposited as NCIMB No. 41603) It is listed in WO2010 / 080829); event BLRl (rapeseed, Restoration of male sterility, deposited as NCIMB 41193, WO2005 / 074 (as described in 671), Event CE43-67B (Cotton, Insect Control, DSM AC) Deposited as C2724, US-A2009-217423 or WO2006 / (As described in 128573); Event CE44-69D (Cotton, insect control, deposit) Not listed in US-A2010-0024077); Event CE44 -69D (Cotton, insect control, not deposited, listed in WO2006 / 128571) (is); Event CE46-02A (cotton, insect control, not deposited, WO200) (As stated in 6 / 128572); Event COT102 (Cotton, insect control, deposit) Not listed in US-A2006-130175 or WO2004 / 039986 (is being held); Event COT202 (cotton, insect control, not deposited, US-A20) (As stated in 07-067868 or WO2005 / 054479); Event CO T203 (Cotton, insect control, not deposited, listed in WO2005 / 054480) Event DAS21606-3 / 1606 (Soybeans, Herbicide Resistant, PTA) (Deposited as -11028, as listed in WO2012 / 033794), Event DAS40278 (Corn, Herbicide Resistant, ATCC PTA-10244) It is deposited as, as described in WO2011 / 022469; Event DA S-44406-6 / pDAB8264.44.06.l (Soybean, herbicide resistant, PTA) (Deposited as -11336, as listed in WO2012 / 075426), Event DAS-14536-7 / pDAB8291.45.36.2 (Soybeans, herbicides) Resistance, deposited as PTA-11335, described in WO2012 / 075429 (is being used), event DAS-59122-7 (corn, insect control - herbicide resistant, Deposited as ATCC PTA 11384, US-A2006-070139 (As described in) Event DAS-59132 (Corn, Insect Control - Herbicide Resistant) Sex, not deposited, listed in WO2009 / 100188); Event DA S68416 (Soybean, herbicide resistant, deposited as ATCC PTA-10442) (as described in WO2011 / 066384 or WO2011 / 066360); Event DP-098140-6 (Corn, Herbicide Resistant, ATCC PTA-82) Deposited as 96, US-A2009-137395 or WO08 / 11201 As described in 9); Event DP-305423-1 (Soybeans, traits related to quality, Not deposited, US-A2008-312082 or WO2008 / 054747 (As described); Event DP-32138-1 (Corn, Hybridize) Deposited as ATCC PTA-9158, US-A2009-021 (As described in 0970 or WO2009 / 103049); Event DP-3560 43-5 (Soybean, herbicide resistant, deposited as ATCC PTA-8287, U As described in S-A2010-0184079 or WO2008 / 002872); Event EE-I (eggplant, insect control, not deposited, listed in WO07 / 091277) (is being done); Event Fil 17 (Corn, herbicide resistant, ATCC 2090) Deposited as item 31, US-A2006-059581 or WO98 / 04414 0 is listed); Event FG72 (Soybean, Herbicide Resistant, PTA-11041 and It is deposited as described in WO2011 / 063413, event GA2 1 (Corn, herbicide resistant, deposited as ATCC 209033, US- (As described in A2005-086719 or WO98 / 044140); Event G G25 (corn, herbicide resistant, deposited as ATCC 209032, U As described in S-A2005-188434 or WO98 / 044140); event GHB119 (cotton, insect control - herbicide resistant, deposited as ATCC PTA-8398) (as described in WO2008 / 151780); Event GHB614( Cotton, herbicide resistant, deposited as ATCC PTA-6878, US-A201 (As described in 0-050282 or W02007 / 017186); Event GJ1 1 (Corn, herbicide resistant, deposited as ATCC 209030, US- (As described in A2005-188434 or WO98 / 044140); Event G M RZ13 (sugar beet, virus resistant, deposited as NCIMB-41601) (as described in WO2010 / 076212); Event H7-l (Tensai, Except Herbicide resistant, deposited as NCIMB 41158 or NCIMB 41159. As described in US-A2004-172669 or WO2004 / 074492); Event JOPLIN (wheat, disease resistant, not deposited, US-A2008-0) (As described in 64032); Event LL27 (Soybean, Herbicide Resistant, NCIMB4) Deposited as 1658, WO2006 / 108674 or US-A2008-3 (As described in 20616); Event LL55 (Soybean, Herbicide Resistant, NCIMB) Deposited as 41660, WO2006 / 108675 or US-A2008- Listed in 196127); Event LLcotton25 (cotton, herbicide resistant, Deposited as ATCC PTA-3343, WO2003 / 013224 or U (As described in S A2003-097687); Event LLRICE06 (Rice, Herbicide resistant, deposited as ATCC 203353, US 6,468,747 Or as described in WO2000 / 026345); Event LLRice62 (Rice Herbicide resistant, deposited as ATCC 203352, WO2000 / 0263 (As described in 45), Event LLRICE601 (rice, herbicide resistant, ATCC) Deposited as PTA-2600, US-A2008-2289060 or WO2 Listed in 000 / 026356); Event LY038 (Corn, Quality The trait in question is deposited as ATCC PTA-5623, US-A2007-0 (As described in 28322 or WO2005 / 061720); Event MIR162 (Deposited as corn, insect control, PTA-8166, US-A2009) -300784 or WO2007 / 142840; Event MIR6 04 (Corn, insect control, not deposited, US-A2008-167456 or This is described in WO2005 / 103301); Event MON15985 (Wata, Insect control, deposited as ATCC PTA-2516, US-A2004-25 (As described in 0317 or WO2002 / 100163); Event MON810( Corn, insect control, not deposited, listed in US-A2002-102582 Event MON863 (corn, insect control, ATCC PTA-26) Deposited as 05, WO2004 / 011601 or US-A2006-095 (As described in 986); Event MON87427 (Corn, pollination control, AT) Deposited as CC PTA-7899, listed in WO2011 / 062904 (is); Event MON87460 (Corn, Stress Tolerance, ATCC PTA) Deposited as -8910, WO2009 / 111263 or US-A2011- Listed in 0138504); Event MON87701 (Soybeans, Insect Control, A Deposited as TCC PTA-8194, US-A2009-130071 or (As described in WO2009 / 064652); Event MON87705 (Soybeans, Quality trait - herbicide resistance, deposited as ATCC PTA-9241, U As described in S-A2010-0080887 or WO2010 / 037016); Event MON87708 (Soybeans, herbicide resistant, as ATCC PTA-9670) Entrusted, as described in WO2011 / 034704); Event MON877 12 (Soybeans, yield, deposited as PTA-10296, WO2012 / 051) (as described in 199), Event MON87754 (Soybeans, Quality traits, A Deposited as TCC PTA-9385, as described in WO2010 / 024976 (is being); Event MON87769 (Soybeans, traits related to quality, ATCC PTA) Deposited as -8911, US-A2011-0067141 or WO2009 (as described in / 102873); Event MON88017 (Corn, Insect Repellent) Herbicide resistant, deposited as ATCC PTA-5582, US-A2008 -028482 or WO2005 / 059103; Event MON8 8 913 (Cotton, herbicide resistant, deposited as ATCC PTA-4854, WO2) (As described in 004 / 072235 or US-A2006-059590); event MON88302 (Brassica napus, herbicide resistant, deposited as PTA-10955) (as described in WO2011 / 153186), event MON88701 (Wata, Herbicide resistant, deposited as PTA-11754, in WO2012 / 134808 (as listed), Event MON89034 (Corn, Insect Control, ATCC P Deposited as TA-7455, WO07 / 140256 or US-A2008- (As described in 260932); Event MON89788 (Soybean, Herbicide Resistant, A) Deposited as TCC PTA-6708, US-A2006-282915 or (As described in WO2006 / 130436); Event MSl 1 (Brassica napus, pollination) Controlled herbicide resistance, deposited as ATCC PTA-850 or PTA-2485. (as described in WO2001 / 031042); Event MS8 (Brassica napus, pollination) Controlled herbicide-resistant, deposited as ATCC PTA-730, WO2001 / 0 (As described in 41558 or US-A2003-188347); Event NK60 3 (Corn, herbicide resistant, deposited as ATCC PTA-2478, U (As described in S-A2007-292854); Event PE-7 (rice, insect control) Not deposited, as described in WO2008 / 114282); Event RF3 (Brassica napus, pollination controlled - herbicide resistant, deposited as ATCC PTA-730) As described in WO2001 / 041558 or US-A2003-188347); Event RT73 (Brassica napus, herbicide resistant, not deposited, WO2002 / 0368) 31 or as described in US-A2008-070260); Event SYHT0H2 / SYN-000H2-5 (Soybean, herbicide resistant, deposited as PTA-11226) (It is listed in WO2012 / 082548), Event T227-1 (Tensa I. Herbicide resistant, not deposited, WO2002 / 44407 or US-A2009- Listed in 265817); Event T25 (Corn, herbicide resistant, deposited) Not listed in US-A2001-029014 or WO2001 / 051654 (is being held); Event T304-40 (Cotton, insect control - herbicide resistant, ATCC PTA) Deposited as -8171, US-A2010-077501 or WO2008 / Listed in 122406); Event T342-142 (Cotton, insect control, deposit) Not listed in WO2006 / 128568); Event TC1507( Corn, insect control-herbicide resistant, not deposited, US-A2005-0392 26 or as described in WO2004 / 099447); Event VIP1034 (T Corn, insect control-herbicide resistant, deposited as ATCC PTA-3925. (as described in WO2003 / 052073), Event 32316 (Corn) Insect control - herbicide resistant, deposited as PTA-11507, WO2011 / 0 (As described in 84632), Event 4114 (Corn, Insect Control - Herbicide Resistant) Sex, deposited as PTA-11506, listed in W02011 / 084621 (is present), event EE-GM3 / FG72 (soybean, herbicide resistant, ATCC accession number P TA-11041) [This may be Event EE-GM1 / LL27 or Event depending on the circumstances.] [Stacked with EE-GM2 / LL55] (WO2011 / 063413A2) Event DAS-68416-4 (Soybeans, Herbicide Resistant, ATCC Accession Number PTA-1) 0442, WO2011 / 066360Al), Event DAS-68416-4 (Dai Z, herbicide resistant, ATCC accession number PTA-10442, WO2011 / 066384A l) Event DP-040416-8 (corn, insect control, ATCC commission number P) TA-11508, WO2011 / 075593Al), Event DP-043A47- 3 (Corn, insect control, ATCC contract number PTA-11509, WO2011 / 0) 75595Al), Event DP-004114-3 (Corn, Insect Control, ATC) C (Accession Number PTA-11506, WO2011 / 084621Al), Event DP-0 32316-8 (Corn, insect control, ATCC contract number PTA-11507, WO 2011 / 084632Al), Event MON-88302-9 (Brassica napus, herbicide resistant) Sex, ATCC accession number PTA-10955, WO2011 / 153186Al), event DAS-21606-3 (Soybean, herbicide resistant, ATCC accession number PTA-11028) (WO2012 / 033794A2), Event MON-87712-4 (Soybeans, Quality) Traits relating to [the subject], ATCC accession number PTA-10296, WO2012 / 051199A2 ), Event DAS-44406-6 (Soybeans, Stacked Herbicide Resistant, ATCC Accepted) Commission number PTA-11336, WO2012 / 075426Al), Event DAS-14 536-7 (Soybean, stacked herbicide resistant, ATCC accession number PTA-11335) (WO2012 / 075429Al), Event SYN-000H2-5 (Soybeans, Weed Control) Drug resistance, ATCC accession number PTA-11226, WO2012 / 082548A2), i Bent DP-061061-7 (Brassica napus, herbicide resistant, deposit number not available, WO2012) 071039Al), Event DP-073496-4 (Brassica napus, herbicide resistant, deposit number) Issue not yet obtained, US2012131692), Event 8264.44.06.1 (Soybeans, Stacked herbicide-resistant, accession number PTA-11336, WO2012075426A 2) Event 8291.45.36.2 (Soybeans, Stacked Herbicide Resistant, Consignee) Number PTA-11335, WO2012075429A2), Event SYHT0H2 (Da Iz, ATCC accession number PTA-11226, WO2012 / 082548A2), Ibe MON88701 (Wata, ATCC Commission Number PTA-11754, WO2012 / 1 34808Al), Event KK179-2 (Alfalfa, ATCC Commission Number PTA) -11833, WO2013 / 003558Al), Event pDAB8264.42. 32.1 (Soybeans, stacked herbicide resistant, ATCC accession number PTA-11993) WO2013 / 010094Al), Event MZDT09Y (Corn, ATCC) Accession number PTA-13025, WO2013 / 012775Al).
[0199] Furthermore, a list of such transgenic events is available from the United States Department of Agriculture (USDA). Provided by the Animal and Plant Health Inspection Service (APHIS), and on the World Wide Web Those websites aphis.usda.gov It can be found in "". Regarding the application, the status of the relevant list that existed / existed on the filing date of this application is relevant. ru.
[0200] The gene / event that confers the desired trait is mutually exclusive within the transgenic plant. It is also possible to combine and create them. Transgenic can be listed. Examples of plants include important crop plants, such as cereals (wheat, rice, rye, barley, etc.). (Wheat, oats), corn, soybeans, potatoes, sugar beets, sugarcane, tomatoes Tomatoes, peas and other types of vegetables, cotton, tobacco, rapeseed, and also fruit plants. Examples include things that bear fruit, such as apples, pears, citrus fruits, and grapes. Corn, soybeans, wheat, rice, potatoes, cotton, sugarcane, tobacco and na Seeds are especially important. Particularly important traits are found in insects, arachnids, nematodes, and slugs. Improved resistance of plants to damselfish and snails, and resistance to one or more herbicides. This represents improved resistance in plants.
[0201] Preferably, such plants, plant parts, or plant seeds can be processed according to the present invention. Examples of commercially available products include those sold or marketed under the following brand names. Examples include (plant seeds): GENUITY®, DROUGHTGA RD (registered trademark), SMARTSTAX (registered trademark), RIB COMPLETE (registered trademark) Trademark), ROUNDUP READY (Registered Trademark), VT DOUBLE PRO (Registered Trademark) Trademark), VT TRIPLE PRO (registered trademark), BOLLGARD II (registered trademark) ), ROUNDUP READY 2 YIELD(registered trademark), YIELDGARD( (Registered Trademark), ROUNDUP READY 2 (Registered Trademark) XTEN DTM INTA CTA RR2 PRO (registered trademark), VISTIVE GOLD (registered trademark), and / Alternatively, XTENDFLEX TM .
[0202] Crop protection - Types of treatments Treatment of plants and plant parts using the compound represented by formula (I) is a conventional treatment method. It can be used for, for example, immersion, spraying, misting, irrigation, vaporization, dusting, fogging, scattering, foaming, and coating. , spreading-on, injection, drenching, spot This can be done directly by drip irrigation, or by applying the compound around the plant and parts of the plant. , carried out by acting on the habitat or storage space, and also on the reproductive organs (pro In the case of packaging material, especially seeds, furthermore, dry seed processing As a powder for chemical treatment, a solution for liquid seed treatment, and a water-soluble powder for slurry treatment, by coating Furthermore, it is also treated by coating with one or more films. The compound is applied using the ultra-low volume method. It is also possible to use the application method or the compound represented by formula (I) itself in the soil. It can also be injected into it.
[0203] The preferred direct treatment of plants is foliar application (i.e., applying the compound represented by formula (I) to the foliage). (to be applied to) and in that case, the frequency and amount of treatment will be the level of the occurrence of the pest. It should be adapted according to the rules.
[0204] In the case of osmotically active compounds, the compound represented by formula (I) can also be transmitted through the root system. It can reach plants. In that case, the plant is represented by formula (I) in relation to its habitat. The treatment is carried out by applying a compound. This is, for example, drenching (drenchin g) by or by mixing into soil or nutrient solution [i.e., the growing place of the plant ( For example, impregnating soil or a hydroponic system with the liquid form of the compound represented by formula (I). ] by or by soil application [i.e., the compound represented by formula (I) according to the present invention in solid form] By introducing it (for example, in granular form) into the plant's growing area, or by drip application. Often referred to as "chemical solution irrigation" (i.e., plant A compound represented by formula (I) according to the present invention is placed in a predetermined position in the vicinity of the compound with a variable amount of water. Together, apply liquid from the ground surface or underground drip lines over a specific period of time. This can be implemented by [ ]. In the case of rice crops, this is in the form of solid application. The compound represented by formula (I) (for example, as granules) is weighed and supplied to a flooded paddy field. It can also be implemented by a smaller group.
[0205] Digital technology The compounds of the present invention can be used in combination with models, for example, in site-specific crop management, satellites. Agriculture, precision farming or precision farming Models incorporated into computer programs for agriculture It can be used in combination with the following. Such models are profitable, sustainable and For the purpose of optimizing environmental protection, soil, weather, crops (e.g., type, growth stage, plant health) Condition, weeds (e.g., species, growth stage), diseases, pests, nutrients, water, moisture, biomass Using data from various sources such as satellite data and harvest yields, the location-specific characteristics of agricultural sites are revealed. It supports heterogeneous management. In particular, such models optimize agricultural decisions. It is useful for controlling the accuracy of pesticide application and for recording the work that has been carried out.
[0206] As an example, a model simulates the occurrence of pests and applies the compound of the present invention to crop plants. If the threshold for recommended use has been reached, the appropriate administration plan will be followed. The compounds described above can be applied to crop plants.
[0207] Examples of commercially available systems that include agricultural models include The Climate FieldScripts by Corporation TM BASF Xarvio TM AGLogic by John Deere TM These are some examples.
[0208] The compounds of the present invention are used in farm vehicles (e.g., tractors, robots, helicopters, airplanes). , attached to or housed in an unmanned aerial vehicle (UAV), such as a drone. Combined with computerized spraying equipment such as spot sprayers or precision sprayers. It is also possible to use them together. Such devices typically have input sensors (for example, Cameras, etc.) and processing devices (which are configured to analyze input data, and Based on the analysis of the input data, the present invention is specifically applied to crop plants (each a weed). It includes (which is designed to provide a decision on how to administer it in a specific and precise manner). The use of computerized spraying equipment is typically for positioning recorded data. A positioning system (e.g., GPS receiver) for guiding or controlling farm vehicles, and information A geographic information system (GIS) for representing data on an easy-to-understand map, as well as necessary functions such as scattering. Appropriate farm vehicles are also needed to carry out essential farming tasks.
[0209] For example, pests can be detected from images acquired by a camera. The pests can be identified and / or classified based on the above images. Image processing algorithms can be used for and / or classification. The algorithm is a machine learning algorithm, for example, a trained neural network. It is possible to use trained neutral networks, decision trees, etc. , and artificial intelligence algorithms can be utilized. In this way, within this specification The compounds described may be applied only where necessary.
[0210] Seed treatment Pest control by treating plant seeds has long been known and has been continuously improved. It has been added. However, seed treatment does not always provide a satisfactory solution. This is accompanied by a series of problems that make it impossible. Thus, during plant storage, after sowing or To eliminate or at least significantly reduce the need for additional application of pesticides after germination. It is desirable to develop methods to protect seeds and germinating plants in such a way. Furthermore, The active compounds used do not cause damage to the plants themselves, and protect them from pest attacks. The amount of active compound used is optimized to ensure optimal protection of seeds and germinating plants. It is also desirable to treat seeds using the smallest possible amount of pesticide. In particular, in seed treatment methods, the smallest possible amount of pesticide should be used on the seeds. To achieve optimal protection of the plant, and furthermore, to achieve optimal protection of the plant during germination, Intrinsic insecticidal properties of insect-resistant transgenic plants or pest-tolerant transgenic plants Sexual or nematode-killing properties should also be taken into consideration.
[0211] Therefore, the present invention relates in particular to a method for protecting seeds and germinating plants from attacks by pests. In this regard, the method involves treating the seeds with one of the compounds represented by formula (I). This invention provides a method for protecting seeds and germinating plants from pest attacks. The method further involves using a compound represented by formula (I) and a mixed component to process the seeds in a single operation. This also includes methods that process the seeds simultaneously or sequentially. This also includes methods in which the compounds and mixed components represented in I) are processed at different time points. .
[0212] The present invention further provides a method for protecting seeds and plants grown from those seeds from pests. This also relates to the use of the compound represented by formula (I) for processing the child.
[0213] Furthermore, the present invention is provided to protect against pests by formula (I) according to the present invention. The present invention also relates to seeds treated with the compound. The present invention further relates to the compound represented by formula (I) and mixed The present invention also relates to seeds treated simultaneously with synthetic compounds. The present invention is further represented by formula (I) This also applies to seeds treated at different time points with the compound and mixed components. It is represented by formula (I). In the case of seeds treated with different compounds and mixed components at different time points, the individual substances will affect the seeds. It can exist in different layers on the surface of the child. In this case, it can be mixed with the compound represented by formula (I). The layer containing the component can, in some cases, be separated by an intermediate layer. Furthermore, the compound represented by formula (I) and the mixed components may be used as components of the coating or added to the coating. This also applies to seeds that have been applied as one or more additional layers.
[0214] Furthermore, the present invention reduces seed abrasion by dust after treatment with a compound represented by formula (I). This also concerns the seeds subjected to the film coating process in order to prevent this.
[0215] One advantage of the ostomate-acting compound represented by formula (I) is that it can treat seeds. By doing so, not only is the seed itself protected from pests, but the seed The fact is that the plants that emerge from this are also protected after germination. In this way, at the time of sowing or This eliminates the need to directly process the crops shortly after sowing.
[0216] By treating seeds with the compound represented by formula (I), the germination of the treated seeds and The fact that germination can be enhanced should also be considered an additional advantage.
[0217] The compound represented by formula (I) is used, in particular, for transgenic seeds. The fact that this is possible is also considered an advantage.
[0218] Furthermore, the compound represented by formula (I) can be combined with a composition or compound of a signal transduction technology. It can also be used in this way, thereby enabling the use of symbiotic organisms (e.g., rhizobia, mycorrhizal fungi and / Or colony formation by endoparasitic bacteria or fungi becomes better, and / or nitrogen The prime fixed values are optimized.
[0219] The compound represented by formula (I) is used in agriculture, greenhouses, forests, or horticulture. It is suitable for protecting the seeds of all plant varieties. In particular, it is suitable for cereals (for example, Wheat, barley, rye, millet and oats), corn, cotton, soybeans, rice Potatoes, sunflowers, coffee, tobacco, canola, rapeseed, beets (for example, tensa (and feed beets), peanuts, vegetables (e.g., tomatoes, cucumbers, green beans) Seeds of beans, cruciferous vegetables (onions and lettuce), fruit plants, turfgrass and ornamental plants. It is a child. Cereals (e.g., wheat, barley, rye and oats), maize, Processing soybean, cotton, canola, rapeseed, vegetable and rice seeds is especially important. ru.
[0220] As already mentioned above, transgenic seeds produced by the compound represented by formula (I) The treatment of these is also particularly important. This is especially true for polys that have insecticidal and / or nematode-killing properties. Plant seeds generally contain at least one heterologous gene that controls peptide expression. These heterogeneous genes within transgenic seeds are found in Basilus. s) species, Rhizobium species, Pseudomonas s) species, Serratia species, Trichoderma species Clavibacter species, Glomus species or Gli This invention may originate from microorganisms such as the Gliocladium species. It contains at least one heterologous gene derived from a species of the genus Bacillus (Bacillus sp.). It is particularly suitable for processing transgenic seeds. It is especially preferable Derived from Bacillus turingiensis. These are heterogeneous genes.
[0221] In connection with the present invention, the compound represented by formula (I) is applied to the seeds. Preferably The seeds are processed in a state that is stable enough to avoid damage during processing. Generally, the seeds It can be processed at any point between harvesting and sowing. The seeds commonly used are planted It has been separated from the object, with the rachis, hull, petiole, outer layer, hairs, or pulp removed. For example, Seeds that have been harvested, had impurities removed, and dried to a moisture content suitable for storage. The child can be used. Alternatively, it can be treated with water after drying, for example, and then dried again. You can also use primed seeds (for example, primed seeds). In the case of rice seeds, rice embryo Use the soaked seeds, for example, in water, until they reach a specific stage (the pigeon chest stage). This is also possible, as it stimulates germination and results in more uniform sprouting.
[0222] When processing seeds, ensure that seed germination is not negatively affected, or that the resulting plants are not damaged. To prevent this from happening, the amount of the compound represented by formula (I) applied to the seeds and / or any further additions Generally, care must be taken when selecting the amount of additive. For example, in the case of active compounds that can exhibit pharmacotoxic effects at specific dosages, it must be carried out reliably. I don't know.
[0223] Generally, the compound represented by formula (I) is applied to the seeds in an appropriate formulation. Appropriate formulations and methods for processing are known to those skilled in the art.
[0224] The compound represented by formula (I) is a conventional seed coating formulation, such as a solution or emulsion. It can be transformed into a formulation, suspension, powder, foaming agent, slurry, or other coating composition for seeds. It is possible to convert it, and furthermore, it is also possible to convert it into a ULV formulation.
[0225] These formulations use known methods to add the compound represented by formula (I) to conventional additives, for example, , conventional bulking agents, and further, solvents or diluents, colorants, wetting agents, dispersants, emulsifiers, It is mixed with an antifoaming agent, a preservative, a second thickening agent, a tack, gibberellins, and further, It is prepared by mixing it with water.
[0226] Colorants that can be present in seed powder-coated formulations that can be used according to the present invention. The agent is all the conventional colorants for such purposes. Face colorants that do not dissolve well in water. You can use a dye that dissolves in water or a liquid. For example, "Rhodami n B", "CIPigment Red 112", and "CISolvent Examples include colorants known as "Red 1."
[0227] Useful substances that can be present in seed powder-coated formulations that can be used according to the present invention Wetting agents are all types of wetting agents that are conventionally used in the formulation of pesticide active compounds to promote wetting. It is a substance. Preferably, alkylnaphthalene sulfonates, for example, diisopropyl Use naphthalene sulfonate or diisobutylnaphthalene sulfonate, etc.
[0228] Useful substances that can be present in seed powder-coated formulations that can be used according to the present invention Dispersants and / or emulsifiers are nonionic, which are conventionally used in the formulation of pesticide active ingredients. These are all types of dispersants: nonionic, anionic, and cationic. Preferably, nonionic or Use an anionic dispersant or a mixture of nonionic or anionic dispersants. Among the nonionic dispersants used, ethylene oxide / propylene oxide blotch is particularly noteworthy. Acrylic polymers, alkylphenol polyglycol ethers and tristyryl phenol Tristryrylphenol polyglycol ethers, and those Examples include phosphorylated or sulfated derivatives of the same. Suitable anionic dispersants are, in particular, Lignosulfonates, polyacrylates, and aryl sulfonates / formaldehyde It is a do-condensate.
[0229] Antifoaming agents that can be present in seed powder-coated formulations that can be used according to the present invention. The agent is all foam inhibitors conventionally used in formulations of pesticide active ingredients. Alternatively, a silicone defoaming agent and magnesium stearate may be used.
[0230] Preservatives that can be present in seed powder formulations that can be used according to the present invention. The agent is all substances that can be used for the purpose in the pesticide composition. For example, Examples include dichlorophene and benzyl alcohol hemiformal.
[0231] A second seed powder coating formulation that can be used in accordance with the present invention can be present in the seed powder coating formulation. The thickening agents are all substances that can be used for that purpose in a pesticide composition. Cellulose derivatives, acrylic acid derivatives, xanthan gum, modified clay, and finely powdered silica are preferred. It's nice.
[0232] Adhesive that can be present in seed powder coating formulations that can be used according to the present invention. The agent is all conventional binders that can be used in seed coating products. Polyvinylpyrrolidone Polyvinyl acetate, polyvinyl alcohol, and tyrose are listed as preferred materials. It is possible.
[0233] Gibberellin can be present in seed powder formulations that can be used according to the present invention. The gibberellins are preferably gibberellin A1, gibberellin A3 (=gibberellic acid), gibberellin Phosphorus A4 and gibberellin A7; gibberellic acid is particularly preferred. Phosphorus compounds are known (cf. R. Wegler “Chemie der Pfl anzenschutz- and Schadlingsbekampfungsmi ttel”, vol.2, Springer Verlag, 1970, pp. 401-412).
[0234] The seed powder coating formulations that can be used according to the present invention are for a wide range of different types of seeds. To process the child, it can be used directly, or after being diluted with water beforehand. It can be used, for example, as a concentrated preparation or diluted with water. The preparations that can be obtained from the concentrated preparation are cereals, such as wheat and barley. It can be used to powder the seeds of rye, oats, and other grains. Furthermore, corn, rice, rapeseed, peas, green beans, cotton It can also be used to coat sunflower, soybean, and beet seeds, or It can be used to coat a wide variety of vegetable seeds with powder. Seed powder preparations that can be used in this manner, or their diluted forms of use, are trans- It can also be used to powder the seeds of ecology plants.
[0235] A seed powder coating preparation that can be used in accordance with the present invention, or a seed powder coating preparation from which water can be added. When processing seeds using a form of use prepared by doing so, habitually for seed coating All conventionally available mixing devices are useful. Specifically, the procedure in seed coating is: Place the seeds into a mixer (which operates in batch or continuously), if desired. A specific amount of the seed powder preparation is added either as is or after being diluted with water beforehand. This involves mixing all of the ingredients until the preparation is evenly distributed across the surface of the seeds. If appropriate, a drying process is then carried out.
[0236] The application rate of the seed powder coating formulation that can be used according to the present invention can be varied within a relatively wide range. This can be obtained by determining the specific content of the compound represented by formula (I) in the preparation and This depends on the seed. The application rate of the compound represented by formula (I) is generally per 1 kg of seed. The amount is 0.001 to 50 g, preferably 0.01 to 15 g per kg of seeds.
[0237] animal health In the field of animal health, specifically in the field of veterinary medicine, the compound represented by formula (I) is used in animals. It exhibits activity against parasites, particularly against ectoparasites or endoparasites. "Endoparasites" specifically include helminths and protozoa (e.g., coccidia). Parasitic organisms are typically, and preferably, arthropods, particularly insects or mites. ru.
[0238] In the field of veterinary medicine, the degree of toxicity to warm-blooded animals is expressed by formula (I). These compounds are used in animal breeding and livestock farming for livestock animals, breeding animals, zoo animals, and research. Occurs in animals kept indoors, laboratory animals, and domestic animals. They are suitable for controlling parasites. They are effective at all developmental stages or specific stages of the parasite. It shows activity in the developmental stages of [the organism].
[0239] Examples of livestock used for agriculture include the following: mammals, for example, Sheep, goats, horses, donkeys, camels, buffalo, rabbits, reindeer, fallow deer, and , in particular cattle and pigs; or poultry, such as turkeys, ducks, geese, and and especially chickens; or fish or crustaceans, for example, fish in aquaculture. Or crustaceans; or, depending on the case, insects, such as bees.
[0240] Examples of domestic animals include the following: mammals, for example, Hamsters, guinea pigs, rats, mice, chinchillas, ferrets, and especially, Nu, cat; caged bird; reptile; amphibian, or aquarium fish.
[0241] In certain embodiments, the compound represented by formula (I) is administered to mammals.
[0242] In a specific alternative embodiment, the compound represented by formula (I) is used against birds, i.e., caged birds. It is administered, or in particular, to poultry.
[0243] By using the compound represented by formula (I) to control animal parasites, To reduce or prevent disease and death in animals, and to improve productivity (performance) e) To reduce or prevent the decline of (meat, milk, wool, leather, eggs, honey, etc.) This is intended to enable, as a result, more economical and easier animal husbandry, and better Such a state of animal health can be achieved.
[0244] The terms "control" or "controlling" are When used in this specification in connection with the field of animal health, the compound represented by formula (I) to reduce the occurrence of individual parasites in animals infected with parasites to a harmless level. This means that it is effective in reducing it. More specifically, it means "to control". When used in the present invention, the compound represented by formula (I) kills individual parasites. This means that it is effective in inhibiting its growth or inhibiting its proliferation. do.
[0245] Representative arthropods, though not limited to them, include the following: ru: For example, species of the genus Haematopinus in the order Anoplurida. atopinus spp.), Linognathus genus species (Linognathus spp.) ), species of the genus Pediculus (Pediculus spp.), species of the genus Phtirus (Phtirus (spp.), Solenopotes genus species (Solenopotes spp.); The order Mallophagida and the suborder Ambly cerina) and the Ischnocerina suborder, for example, bobi species of the genus Bovicola, species of Damalina. ), species of the genus Felicola (Felicola spp.); species of the genus Lepikentron (Lepik Menopon spp., Menopon species, Trichodectes Species of the genus Trichodectes (Trichodectes spp.), species of the genus Trimenopon (Trimenopon) (on spp.), Trinoton genus species, Wernechiella genus Species (Werneckiella spp.); Diptera and Nematocerina For example, species of the genus Aedes in the Brachycerina suborder. (spp.), Anopheles spp., Atylothus genus ( Atylotus spp., Braula spp., Calliphora genus Calliphora spp., Chrysomyia spp. pp.), Chrysops spp., Culex genus (spp.), Culicoides genus species, Eusimurium Genus species (Eusimulium spp.), Fannia genus species (Fannia spp.) Gasterophilus spp., Glossina genus (G Lossina spp.), Haematobia genus species, Haematopota spp., Hippobosca genus (bosca spp.), Hybomitra genus species, Hydrota Species of the genus Hydrotaea (Hydrotaea spp.), species of Hypoderma (Hypoderma spp.) pp.), Lipoptena spp., Lucilia genus Lutzomyia spp., merophagus Species of the genus Melophagus (spp.), species of Morellia (spp.) .), Musca spp., Odagmia spp. .), Oestrus spp., Phillipomia genus species ipomyia spp., Phlebotoms genus species , species of the genus Rhinoestrus (Rhinoestrus spp.), species of the genus Sarcophaga (Sa (rcophaga spp.), Simulium genus species, St. Species of the genus Stomoxys, species of Tabanus. ), Tipula spp., Wilhelmia genus (spp.), Wohlfahrtia genus species (Wohlfahrtia spp.); For example, species of the genus Cerathophilus in the order Siphonapterida. tophyllus spp.), species of the genus Ctenocephalides (Ctenocephali species of the genus *Pulex* (des spp.), *Pulex* (Pulex spp.), and *Tunga* (Tunga) Xenopsylla spp. (spp.), Xenopsylla species; For example, species of the genus *Cimex* in the order Heteropterida. ex spp.), Panstrongylus genus species (Panstrongylus spp.) Rhodnius spp., Triatoma species (spp.); and harmful and sanitary pests of the order Blattodea (cockroaches).
[0246] Furthermore, among arthropods, although not limited to them, the following mites can also be given as examples. It is possible to: The subclass Acari (Acarina) and the order Metastigma mata) For example, of the family Argasidae, for example, species of the genus Argas ( Argas spp., Ornithodorus genus species Examples of species in the genus Otobius (Otobius spp.), family Ixodidae, For example, species of the genus Amblyomma (Amblyomma spp.) and species of the genus Dermacentr (D Haemaphysalis species (Haemaphysalis spp.) (I) Rhipicephalus (Rhipicephalus spp.), species of the genus Rhipicephalus (Borphilus) lus (Boophilus) spp.), Rhipicephalus species alus spp. (the original genus of multi-host mites); Mesostigma For example, species of the genus Dermanyssus (Dermanyssus spp.), ornitho Species of the genus Ornithonyssus (Ornithonyssus spp.), species of the genus Pneumonisus (Pneumonisus) (Monyssus spp.), Raylietia genus species (Raillietia spp.) species of the genus Sternostoma, species of the genus Tropiraerapus ( Tropilaelaps spp.), Varroa genus species (Varroa spp.); A For example, the order Actinedida (Prostigmata), *Acala* species of the genus Acarapis, species of Cheyletiell a spp.), Demodex species (Demodex spp.), Listrohorus species ( Listrophorus spp., Myobia spp., Ne Neotrombicula spp., Ornithocheirethia genus Ornithocheyletia spp., Psore rgates spp.), Trombicula spp.; For example, Acaridida (Astigmata), Genus species (Acarus spp.), Caloglyphus genus species (Caloglyphus spp.) .), species of the genus Chorioptes (Chorioptes spp.), species of the genus Cytodites (Cyt Hypodectes spp., Species of the genus Knemidocoptes, species of Laminosioptes (Laminosioptes spp.), Notoedleres genus species (spp.), Otodectes spp., Psoroptes species ( Psoroptes spp., Pterolichus spp. .), Sarcoptes spp., Trixacarus genus (Tr (Ixacarus spp.), Tyrophagus genus species (Tyrophagus spp.) .
[0247] Representative parasitic protozoa include, but are not limited to, the following: It is possible: Subphylum Mastigophora (Flagellata), example Eba: Metamonada: Diplomonadi For example, species of the genus Giardia (Giardia spp.) and the genus Spironucleus. Species (Spironucleus spp.); Parabasala: Trichomonadales (order Trichomonadales) For example, Histomonas spp., pentatonica Genus Pentathrichomonas (species), Tetratrichomonas genus Species (Tetratrichomonas spp.), Trichomonas genus species (Tricho Tritrichomonas sp. (monas spp.), species of the genus Tritrichomonas p); Euglenozoa: Order Trypanosoma For example, species of the genus Leishmania (Leishmania spp.), Trypanosoma spp. (genus) Subphylum Sarcomastigophora (Rhizopods) da)), for example, Entamoebidae, for example, Entamo Entamoeba genus (Entamoeba spp.), Centramo Amoeba family (Centramo Amoeba family) ebidae), for example, species of the genus Acanthamoeba (Acanthamoeba sp.), Euamoebidae, for example, species of the genus Hartmanella nella Sp.); Alveolata, for example, the phylum Apicomplexa (Sporozoa), for example, species of the genus Cryptosporidium (Cryptosporidium spp.); Eimeriida For example, species of the genus Besnoitia, cystoisospora Genus species (Cystoisospora spp.), Eimeria genus species (Eimeria spp.) pp.), Hammondia spp., Isospora species Neospora spp., Neospora species, sarcosis Species of the genus Sarcocystis, species of Toxoplasma sma spp.); of the order Adeleida, for example, the genus Hepatozoon. species (Hepatozoon spp.), Klossiella sp. p.); Haemosporida, for example, Leucositozo Leucocytozoon spp. and Plasmodium species (Plasmo dium spp.); of the order Piroplasmida, for example, Babesia spp., Ciliophora (spp.), Echinozoon spp., Teyleria genus ( Theileria spp.; Vesibuliferid a) For example, Balantidium species, Buxist Buxtonella species (spp.) Microspora, for example, species of the genus Encephalitozoon (Enc ephalitozoon spp.), Enterocyt (Ozoon spp.), Globidium genus species, Nosema Genus and species (Nosema spp.), and further, for example, species of the genus Myxozoa (Myxoz (oa spp.)
[0248] Examples of helminths that are pathogenic to humans or animals include those belonging to the phylum Acanthodes (Acanthocephala). Hocephala, Nematodes, Pentastoma, and Platyhelminthes (platyhelmintha) [e.g., monogenea, cestodes ( Examples include cestodes and trematodes.
[0249] Representative helminths, though not limited to them, include the following: : Monogenea: For example: Dactylogyrus species Gyrodactylus spp., Gyrodactylus species Species of the genus Microbothrium, species of the genus Polystomus (Po (lystoma spp.), Troglocephalus species spp.); Cestodes: Pseudophyllids For example: Bothridium spp., diphyllo genus Diphyllobothrium spp., genus Diphyllobothrium Species (Diplogonoporus spp.), Ichthyobotrium genus species (Ichth (Yobothrium spp.), Ligula spp., Cystoc Species of the genus Schistocephalus (Spp.), species of the genus Sp. irometra spp.); For example, species of the genus Anjila in the order Cyclophyllida. (Andyra spp.), Anoplocephala species pp.), Avitellina spp., Be Cittotaenia spp. (Cittotaenia spp.) , species of the genus Davainea (spp.), species of the genus Diorchis ( Diplopylidium spp., Dip Dipylidium spp. and Echinococcus species coccus spp., Echinocotyle genus species Echinolepis spp., Hyda (Tigera spp.), Hymenolepis spp. species of the genus Joyeuxiella, species of the genus Mesocestoides (Mesocestoides spp.), Moniezia sp. p.), Paranoplocephala spp., Species of the genus *Raillietina*, species of the genus *Stiles* Taenia spp., Th Thysanosoma spp. (*ysaniezia* spp.), *Thysanosoma* spp. ); Trematodes: A subclass of Digenea, for example: Austrobilharzia spp., Brachyraima Genus species (Brachylaima spp.), Calicophoron genus species (Calicophoron (on spp.), Catatropis spp., Chronorki Species of the genus Clonorchis (spp.), species of the genus Collyriculum (Collyriculum) (m spp.), Cotylophoron genus species, Cyclocoporon Elm species (Cyclocoelum spp.), Dicrocoelium species Coelium spp.), Diplostomum spp. ), Echinochasmus spp., Echinoparifiu Echinoparyphium spp. and Echinostoma species Ostoma spp.), Eurytrema spp., Fa Species of the genus Fasciola (Fasciola spp.), species of the genus Fascioli (Fascioli (des spp.), Fasciolopsis genus species, Fischoederius spp., Gastrotiracus Genus species (Gastrothylacus spp.), Gigantville genus species (Gig Antobilharzia spp., Gigantocot Hypophyses spp., Heterophyes genus species, Hypophyses Species of the gen...
Claims
1. Compounds 3-chloro-5-(2-cyanopropan-2-yl)benzoic acid, 3-(cyanomethyl)-5-(trifluoromethoxy)benzoic acid, 3-(2-cyanopropan-2-yl)-5-(trifluoromethoxy)benzoic acid, 3-chloro-5-[(methylsulfonyl)methyl]benzoic acid, 2-chloro-6-(1-cyano-1-methyl-ethyl)pyridine-4-carboxylic acid, 3-(cyanomethyl)-5-(methylsulfonyl)benzoic acid, 3-(2-cyanopropan-2-yl)-5-(methylsulfonyl)benzoic acid, or their salts, or 5-[5-[(1S)-1- [aminoethyl]-1,2,4-triazole-1-yl]pyrazine-2-carbonitrile hydrochloride, 6-[5-[(1S)-1-aminoethyl]-3-cyclopropyl-1,2,4-triazole-1-yl]pyrimidine-4-carbonitrile hydrochloride, 6-[5-[(1S)-1-aminoethyl]-3-cyclopropyl-1,2,4-triazole-1-yl]pyrimidine-4-carboxamide hydrochloride, or 6-{5-[(1S)-1-aminoethyl]-3-methyl-1H-1,2,4-triazole-1-yl}-N-ethyl-N-methylnicotinamide hydrochloride.
2. Compound 3-(2-cyanopropan-2-yl)-5-(trifluoromethoxy)sodium benzoate.
Citation Information
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