Fragrance compounds

Abstract

The present invention provides novel fragrance mixtures based on fragrances that inherently have balsamic and / or leathery scent notes. The fragrance mixture comprises or consists of: (a) at least one first fragrance having balsamic and / or leathery scent notes; and (b) p-Tolylmethanol (pTM).

Description

Technical Field

[0006]

[0001] The present invention relates to the field of fragrances and relates to a fragrance mixture containing p-tolylmethanol (pTM) having an improved fragrance note.

Background Art

[0002] In the fragrance industry, there is a great demand for fragrances, especially notes, that enable the expansion of the fragrance palette. In particular, there is a high demand for fragrances that have a large impact on other fragrances in small amounts and change them in a good direction.

[0003] P-Tolylmethanol

Chemical formula

[0004] For example, Patent Document 1 describes a recording medium having excellent fixing properties without nozzle clogging by blending a colorant with p-tolylmethanol, alkylamide, and piperonyl alcohol as essential components.

[0005] Patent Document 2 claims a process for obtaining poly(arylene sulfide) and includes the following steps: (1) a polymerization step of subjecting at least one sulfur source and a dihaloaromatic compound to a polymerization reaction in an organic amide solvent; (2) a reaction step of adding a hydroxyl group-containing organic compound and reacting the formed polymer with the hydroxyl group-containing organic compound; and (3) a recovery step of recovering the polymer formed in the reaction step from the polymerization reaction system, wherein the hydroxyl group-containing organic compound is p-tolylmethanol.

[0006] Patent Document 3 claims a polymer comprising a polyacrylate homopolymer or copolymer backbone and at least one moiety derived from p-tolylmethanol.

[0007] Patent Document 4 discloses a one-pot process for preparing an imine, comprising the steps of refluxing a reaction mixture containing a catalyst, an alcohol, aniline, a base, and a solvent; and cooling the reaction mixture and then separating the catalyst under a strong magnetic field, wherein the alcohol is p-tolylmethanol. [Prior art documents] [Patent Documents]

[0008] [Patent Document 1] Japanese Patent Application Publication No. 4-222876 [Patent Document 2] U.S. Patent Publication No. 2012 / 065361 [Patent Document 3] International Publication No. 2012 / 007463 A1 [Patent Document 4] Indian Patent No. 361896 [Overview of the project] [Means for solving the problem]

[0009] Accordingly, the object of the present invention is to provide a novel fragrance mixture based on a fragrance that originally has balsamic and / or leathery notes, which shows particular improvement with respect to stronger woody, powdery, cinnamic, balsamic and leathery notes, while reducing notes such as vanilla, plastic, fat and smoky. [Modes for carrying out the invention]

[0010] The first object of the present invention is a fragrance mixture having, or consisting only of, the following: (a) at least one first fragrance having balsamic and / or leathery scent notes, (b) p-tolylmethanol.

[0011] Surprisingly, p-tolylmethanol has been observed to enhance, improve, and / or modulate the original scent of a primary fragrance that has balsamic and / or leather notes, even in very small amounts. In particular, balsamic and / or leather notes are amplified and made stronger, while other desirable notes such as woody, powdery, or cinnamon are emphasized, and less desirable notes such as vanilla, plastic, greasy, or smoky are weakened. Thus, by adding just a small amount of the ingredient, a perfumer's fragrance palette expands considerably.

[0012] <P-トリルメタノール> p-Tolylmethanol is a known compound available in the form of white crystals with a melting point of 59 to 61°C and a partition coefficient logP of 1.50. This compound is commercially available, for example, from Sigma-Aldrich.

[0013] <First Fragrance> The first group of fragrances is characterized by dominant balsamic and / or leathery scents. Typical examples include: ethyl vanillin, vanillin, propenyl guaetol, coumarin delta octalactone, benzyl cinnamate, 3-phenylpropanol, methyl lytone, furaneol, isopropylcyclohexanol, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1-penten-3-one, cade oil, styrax oil, 2,3,3-trimethylindanone, butylquinoline, isobutylquinoline, and mixtures thereof.

[0014] The mixture according to the invention may contain a first fragrance and p-tolylmethanol (pTM) in a weight ratio of from about 98:2 to about 99.9:0.5, and calculated with respect to the mixture, pTM is preferably present in an amount in the range of from about 0.6 to 1.0% by weight.

[0015] <Solvent> In a preferred embodiment, the mixture according to the invention may contain at least one solvent. Suitable solvents are selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol and triethyl citrate. Typically, said at least one solvent is present in the mixture in an amount in the range of from about 10 to about 90% by weight, preferably from about 25 to about 50% by weight.

[0016] <Perfume Compositions> Another object of the present invention relates to a perfume composition comprising the mixture defined above and at least one second fragrance different from the first fragrance and pTM. The second fragrance can be selected from the group consisting of: [Table 1-1] [Table 1-2] [Table 1-3] [Table 1-4] [Table 1-5] [Table 1-6] [Table 1-7] The fragrance composition may contain either the pTM alone or a mixture of the pTM and the first fragrance in an amount ranging from about 0.01 to about 2% by weight, preferably about 0.1 to 1% by weight, relative to the composition.

[0017] <Cosmetics and personal care products> Another object of the present invention relates to a cosmetic or personal care product comprising the fragrance mixture or the fragrance composition. The product may contain the fragrance mixture or fragrance composition in an amount ranging from about 0.01 to about 2% by weight, preferably from about 0.1 to about 1% by weight. The composition may represent, for example, a cosmetic cream, lotion, spray, emulsion, ointment, gel, or mouth.

[0018] The formulations according to the present invention include anti-dandruff agents, anti-irritation agents, irritation inhibitors, antioxidants, astringents, sweat inhibitors, preservatives, antistatic agents, binders, buffers, carriers, chelating agents, cell activators, cleansing agents, care agents, deodorants, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibers, film-forming agents, fixing agents, foam-forming agents, foam stabilizers, anti-foaming substances, foam boosters, gelling agents, gel-forming agents, hair care agents, hair styling agents, hair straightening agents, moisturizers, moisturizing substances, bleaching agents, strengthening agents, stain removers, and fluorescent whitening agents. Impregnating agents, antifouling agents, friction reducers, lubricants, moisturizing creams, ointments, opacifying agents, plasticizers, coating agents, polishing agents, glossing agents, polymers, powders, proteins, re-oiling agents, abrasives, silicones, hair growth stimulants, coolants, skin coolants, heat retainers, skin heat retainers, stabilizers, UV absorbers, UV filters, cleaning agents, thickeners, vitamins, oils and fats, waxes, lipids, phospholipids, saturated fatty acids, monounsaturated or polyunsaturated fatty acids, α-hydroxy acids, polyhydroxy fatty acids, liquefaction agents, dyes, coloring protectants, pigments, odorants, polyols, surfactants, electrolytes, organic solvents, or silicone derivatives may be included as additional aids and additives.

[0019] <Surfactants> Preferred additives and excipients are anionic and / or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants may also be present in the composition. Preferred examples are described in conjunction with the section dealing with emulsifiers.

[0020] Typical examples of anionic and zwitterionic surfactants include the following: Almondamidopropylamine oxide, almondamidopropyl betaine, aminopropyl lauryl glutamine, C12-15 alkyl sulfate ammonium, C12-16 alkyl sulfate ammonium, caprylyl sulfate ammonium, coco monoglyceride sulfate ammonium, coco sulfate ammonium, coco isethionate ammonium, cocoyl sarcosinate ammonium, C12-15 pareth sulfate ammonium, C9-10 perfluoroalkyl sulfonate ammonium, dinonyl sulfosuccinate ammonium, dodecylbenzenesulfonate ammonium isostearate ammonium, laureth-6 carboxylate ammonium, laureth-8 carboxylate ammonium, laureth sulfate ammonium, laureth-5 sulfate ammonium, laureth-7 sulfate ammonium, laureth-9 sulfate ammonium, laureth-12 sulfate ammonium, lauroyl sarcosinate ammonium, lauryl sulfate ammonium, lauryl sulfosuccinate ammonium, myristyl sulfate ammonium, nonoxynol-4 sulfate ammonium, nonoxynol-30 sulfate ammonium, hydrolyzed coco Collagen, AMP-Rosin Hydrolyzed Collagen, AMP-Losostearoyl Hydrolyzed Collagen, AMP-Losostearoyl Hydrolyzed Keratin, AMP-Losostearoyl Hydrolyzed Soy Protein, AMP-Losostearoyl Hydrolyzed Wheat Protein, Apricot Amidopropyl Betaine, Arachidic Acid, Hexyldecyl Arginine Phosphate, Avocado Amidopropyl Betaine, Avocado Oil Glycereth-8 Ester, Babassu Acid, Babassuamidopropylamine Oxide, Babassuamidopropyl Betaine, Beeswax Acid, Behenamidopropyl Betaine Beheneth-25, Beheneth-30, Behenic Acid, Behenyl Betaine, Bis-Butyl Dimethicone Polyglyceryl-3, Butoxynol-5 Carboxylic Acid, Butoxynol-19 Carboxylic Acid, Butyldimonium Hydroxypropyl Butyl Glucoside Chloride, Butyldimonium Hydroxypropyl Lauryl Glucoside Chloride, Butyl Glucoside, Butyl Glucoside Capric Acid, Butyl Glucoside Hydroxypropyl Trimonium Chloride, Butyl Octanoic Acid, C18-36 Acid, C20-40 Acid, C30-50 Acid, C16-22 Acid Amide MEA,Calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C9-16 alkanes / cycloalkanes, C10-14 alkylbenzenesulfonic acid, C12-14 alkyldiaminoethylglycine HCl, C9-15 alkyl phosphates, Candida bombicola / glucose / rapeseed methyl ferment, canolamidopropyl betaine, capric acid, caproic acid, caproyl ethyl glucoside, capryl / capramidopropyl betaine, capryl-4 carboxylic acid, capryl-6 carboxylic acid, capryl-9 carboxylic acid, caprylic acid, capryloyl collagen Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth -34 Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Ceteareth-4 Phosphate, Ceteareth-5 Phosphate, Ceteareth-10 Phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Cetreth-22, Cetreth-24, Cetreth-25, Cetreth-30, Cetylbeta Chrysanthemum sinense flower extract, C12-14 hydroxyalkyl hydroxyethyl β-alanine C12-14 hydroxyalkyl hydroxyethyl sarcosine, cocamidoethyl betaine, cocamidopropylamine oxide, cocamidopropyl betaineamide MEA chloride, cocamidopropyl betaine, cocamidopropyl hydroxysultaine, cocamine oxide, cocaminobutyric acid, cocoaminopropionic acid, coceth-7 carboxylic acid, coceth-4 glucoside, cocoamphodipropionic acid, cocobetaineamide amphopropionic acid, cocobetaine,Cocodimonium hydroxypropyl hydrolyzed rice protein, cocodimonium hydroxypropyl hydrolyzed soy protein, cocodimonium hydroxypropyl hydrolyzed wheat protein, cocoglucoside, cocoglucoside hydroxypropyltrimonium chloride, cocohydroxysultaine, cocomorpholin oxide, coconut acid, coconut oil glycereth-8 ester, coco / oleamidopropyl betaine, cocosultaine, coco / sunflower amidopropyl betaine, cocoyl choline meth sulfate, cocoyl glutamate, cocoyl hydrolyzed Collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn acid, cottonseed acid, cottonseed oil glycereth-8 ester, C10-16 pareth-1, C10-16 pareth-2, C11-13 pareth-6, C11-13 pareth-9, C11-13 pareth-10, C11-15 pareth-30, C11-15 pareth-40, C12-13 pareth-1, C12-13 pareth-23, C12- 14 Pareth-5, C12-14 Pareth-9, C13-15 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 carboxylic acid, C9-11 Pareth-8 carboxylic acid, C11-15 Pareth-7 carboxylic acid, C12-13 Pareth-5 carboxylic acid, C12-13 Pareth-7 carboxylic acid, C12-13 Pareth-8 carboxylic acid, C12-13 Pareth-12 carboxylic acid, C12-15 Pareth-7 carboxylic acid, C1 2-15 Pareth-8 carboxylic acid, C12-15 Pareth-12 carboxylic acid, C14-15 Pareth-8 carboxylic acid, C6-10 Pareth-4 phosphate, C12-13 Pareth-2 phosphate, C12-13 Pareth-10 phosphate, C12-15 Pareth-6 phosphate, C12-15 Pareth-8 phosphate, C12-15 Pareth-10 phosphate, C12-16 Pareth-6 phosphate, C4-18 Perfluoroalkylethylthiohydroxypropyltrimonium chloride, Cupuaçu amidopropyl betaine, DEA-C12-13 alkyl sulfate, DEA-C12-15 alkyl sulfate,DEA-Ceteareth-2 Phosphate, DEA-Cetyl Sulfate, DEA-Cocoamphodipropionic Acid, DEA-C12-13 Pareth-3 Sulfate, DEA-Cyclocarboxypropyloleic Acid, DEA-Dodecylbenzenesulfonic Acid, DEA-Isostearic Acid, DEA-Laureth Sulfate, DEA-Lauryl Sulfate, DEA-Linoleic Acid, DEA-Methyl Myristate, DEA-Myristic Acid Sulfate, DEA-Myristic Acid, DEA-Myristyl Sulfate, DEA-Oleth-5 Phosphate, DEA-Oleth-20 Phosphate, DEAPG-Oleic Acid, Deceth-7 Carboxylic Acid, Deceth-7 G Glucoside, Deceth-9 Phosphate, Decylamine Oxide, Decylbetaine, Decyl Glucoside, Decyltetradeceth-30, Decyltetradecylamine Oxide, Diammonium Lauramide-MEA Sulfosuccinate, Diammonium Lauryl Sulfosuccinate, Diammonium Oleamide PEG-2 Sulfosuccinate, Dibutoxymethane, Di-Cl2-15 Pareth-2 Phosphate, Di-Cl2-15 Pareth-4 Phosphate, Di-Cl2-15 Pareth-6 Phosphate, Di-Cl2-15 Pareth-8 Phosphate, Di-Cl2-15 Pareth-10 Phosphate, Butanetetracarboxylic Acid Didodecyl, diethylamine laureth sulfate, sodium diethylhexyl sulfosuccinate, dihydroxyethyl C8-10 alkoxypropylamine oxide, dihydroxyethyl C9-11 alkoxypropylamine oxide, dihydroxyethyl C12-15 alkoxypropylamine oxide, dihydroxyethyl cocamine oxide, dihydroxyethyl lauramine oxide, dihydroxyethyl stearamine oxide, dihydroxyethyl tallowamine oxide, dimethicone PEG-7 phosphate, dimethicone PEG-10 phosphate, dimethicone P EG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone Propyl PG-Betaine, Dimyristyl Phosphate, Dioleoyl Amidoethyl Hydroxyethylmonium Methosulfate, DIPA-Hydrogenated Cocoate, DIPA-Lanolate, DIPA-Myristart, Dipotassium Capryloyl Glutamate, Dipotassium Lauryl Sulfosuccinate, Dipotassium Undecylenoyl Glutamate, Babasamide MEA-Disodium Sulfosuccinate, Disodium Capronphodiacetate,Disodium caproamphodipropionate, disodium capryloamphodiacetate, disodium capryloamphodipropionate, disodium capryloyl glutamate, disodium cetearyl sulfosuccinate, disodium cetylphenyl ether disulfonate, disodium cetyl sulfosuccinate, disodium cocamide MEA-sulfosuccinate, disodium cocamide MIPA-PEG-4 sulfosuccinate, disodium cocamide MIPA-sulfosuccinate, disodium cocamide PEG-3 sulfosuccinate, disodium coceth-3 sulfosuccinate Um, Cocoamphocarboxyethyl Hydroxypropyl Sulfonate Disodium, Cocoamphodiacetate Disodium, Cocoamphodipropionate Disodium, Cocoglucoside Sulfosuccinate Disodium, Cocosulfosuccinate Disodium, Cocoyl Butyl Glucoth-10 Sulfosuccinate Disodium, Cocoyl Glutamate Disodium, C12-14 Pareth-1 Sulfosuccinate Disodium, C12-14 Pareth-2 Sulfosuccinate Disodium, C12-15 Pareth Sulfosuccinate Disodium, C12-14Sec-Pareth-3 Sulfosuccinate Disodium sulfosuccinate, C12-14Sec-Pareth-5 sulfosuccinate, C12-14Sec-Pareth-7 sulfosuccinate, C12-14Sec-Pareth-9 sulfosuccinate, C12-14Sec-Pareth-12 sulfosuccinate, Deceth-5 sulfosuccinate, Deceth-6 sulfosuccinate, Decylphenyl ether disulfonic acid disodium, Dihydroxyethyl sulfosuccinyl undecylenate disodium, Ethylene dicocamide PEG-15 disulfinate disodium, Hydrogenated cottonseed oil glyceride disodium sulfosuccinate, hydrogenated scutellaria glutamate disodium, hydroxydecyl sorbitol citrate disodium, isodecyl sulfosuccinate disodium, isostearoamide MEA-sulfosuccinate disodium, isostearoamide MIPA-sulfosuccinate disodium, isostearoamphodiacetate disodium, isostearoamhodipropionate disodium, isostearyl sulfosuccinate disodium, lanes-5 sulfosuccinate disodium, lauramide MEA-sulfosuccinate disodium,Lauramide MIPA glycol sulfosuccinate disodium, Lauramide PEG-2 sulfosuccinate disodium, Lauramide PEG-5 sulfosuccinate disodium, Laureth-5 carboxyamphodiacetate disodium, Laureth-7 citrate disodium, Laureth sulfosuccinate disodium, Laureth-6 sulfosuccinate disodium, Laureth-9 sulfosuccinate, Disodium succinate, disodium laureth-12 sulfosuccinate, disodium lauriminobishydroxypropylsulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate, disodium lauriminodipropionate tocopheryl phosphate, disodium lauroamhodiacetate, disodium lauroamhodipropionate, disodium N-lauroyl aspartate, disodium lauroyl glutamate, disodium laurylphenyl ether disulfonate, disodium lauryl sulfosuccinate, myristamide MEA-Disodium Sulfosuccinate, Nonoxynol-10 Disodium Sulfosuccinate, Oleamide MEA-Disodium Sulfosuccinate, Oleamide MIPA-Disodium Sulfosuccinate, Oleamide PEG-2 Disodium Sulfosuccinate, Oleoamphodipropionate Disodium, Oleth-3 Disodium Sulfosuccinate, Oleyl Phosphate Disodium, Oleyl Sulfosuccinate Disodium, Palmitamide PEG-2 Disodium Sulfosuccinate, Palmitreamide PEG-2 Disodium Sulfosuccinate, PEG-4 Cocamide MIP Disodium A-sulfosuccinate, PEG-12 dimethicone disodium sulfosuccinate, PEG-8 palm glyceride disodium sulfosuccinate, PPG-2-losodeceth-7 carboxyamphodiaacetate disodium, ricinolamide MEA disodium sulfosuccinate, sitostereth-14 disodium sulfosuccinate, soybean amphodiaacetate disodium, stearamide MEA disodium sulfosuccinate, steariminodipropionate disodium, stearoamphodiaacetate disodium, stearoyl glutamate disodium Disodium stearyl sulfosuccinate, disodium stearyl sulfosuccinate, disodium 2-sulfolaurate, disodium 2-sulfopalmitate, disodium talamide MEA-sulfosuccinate, disodium taluamide MEA-sulfosuccinate, disodium taluamphodiacetate, disodium talouiminodipropionate, disodium talu sulfosuccinate, disodium tridecyl sulfosuccinate, disodium undecylenamide MEA-sulfosuccinate, disodium undecylenamide PEG-2 sulfosuccinate,Disodium undecylenoyl glutamate, disodium wheat germ amide MEA-sulfosuccinate, disodium wheat germ amide PEG-2 sulfosuccinate, disodium wheat germ amide diacetate, di-TEA-cocamide diacetate, di-TEA-oleamide PEG-2 sulfosuccinate, di-TEA-palmitoyl aspartate, sodium ditridecyl sulfosuccinate, dodecylbenzenesulfonic acid, ercamidopropyl hydroxysultaine, ethylhexeth-3 carboxylic acid, ethyl PEG-15 cocamine sulfate, glyceryl caprylate Tel, Hexyldecanoic Acid, Hydrogenated Coconut Acid, Hydrogenated Lanes-25, Hydrogenated Menhardic Acid, Hydrogenated Palm Acid, Hydrogenated Palm Kernel Amine Oxide, Hydrogenated Talus Acid, Hydrogenated Talus Amine Oxide, Hydrogenated Talus Betaine, Hydrogenated Talus S-25, Hydrogenated Talusyl Glutamate, Hydrolyzed Candida Bombicola Extract, Hydroxyceteth-60, Hydroxyethyl Acetomonium PG-Dimethicone, Hydroxyethyl Butylamine Laureth Sulfate, Hydroxyethyl Carboxymethyl Cocamidopropylamine, Hydroxyethyl Hydroxypropyl C12-15 Alkoxypropyl Pyramine oxide, hydroxyl lauryl / hydroxymyristyl betaine, hydroxystearic acid, hydroxysuccinimidyl C10-40 isoalkylate, hydroxysuccinimidyl C21-22 isoalkylate, hydroxysultaine, IPDI / PEG-15 soy oxide copolymer, IPDI / PEG-15 soethonium ethosulfate copolymer, IPDI / PEG-15 soyglycinate copolymer, isoceteth-30, isolaureth-4 phosphate, isopolyglyceryl-3 dimethicone, isopolyglyceryl-3 dimethiconol, isop Lopanolamine lanolate, isopropylamine dodecylbenzene sulfonate, isostearamidopropylamine oxide, isostearamidopropyl betaine, isostearamidopropyl morpholine oxide, isosteareth-8, isosteareth-16, isosteareth-22, isosteareth-25, isosteareth-50, isostearic acid, isostearoyl hydrolyzed collagen, jojoba oil PEG-150 ester, jojoba wax PEG-80 ester, jojoba wax PEG-120 ester, Lane 20, Lane 25, Lane 40,Lane-50, Lane-60, Lane-75, Lanolinic Acid, Lauramidopropylamine Oxide, Lauramidopropyl Betaine, Lauramidopropyl Hydroxysultaine, Lauramine Oxide, Lauraaminopropionic Acid, Laurdimonium Hydroxypropyl Decyl Glucoside Chloride, Laurdimonium Hydroxypropyl Lauryl Glucoside Chloride, 16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-38, Laureth-40, Laureth-3 Carboxylic Acid, Laureth-4 Carboxylic Acid, Laureth Laureth-5 carboxylic acid, Laureth-6 carboxylic acid, Laureth-8 carboxylic acid, Laureth-10 carboxylic acid, Laureth-11 carboxylic acid, Laureth-12 carboxylic acid, Laureth-13 carboxylic acid, Laureth-14 carboxylic acid, Laureth-17 carboxylic acid, Laureth-6 citric acid, Laureth-7 citric acid, Laureth-1 phosphate, Laureth-2 phosphate, Laureth-3 phosphate, Laureth-4 phosphate, Laureth-7 phosphate, Laureth-8 phosphate, Laureth-7 tartaric acid, Lauric acid, Lauriminobispropanediol, Lauriminodipropionic acid, Lauroyl β-alanine, La Uroyl collagen amino acids, lauroyl ethyltrimonium meth sulfate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methyl glucamide, lauroyl sarcosine, silk amino acids, lauryl betaine, lauryl dimethicone / polyglycerin-3 crosspolymer, lauryl dimonium hydroxypropyl coco-glucoside chloride, lauryl glucoside, lauryl glucoside hydroxypropyltrimonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysultaine, lauryl maramide, lau Uryl methyl glucamide, lauryl / myristyl glycol hydroxypropyl ether, lauryl / myristyl wheat bran / straw glycoside, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, laurylpyrrolidone, lauryl sultaine, linoleic acid, linolenic acid, flaxseed acid, lysine cocoate, macadamia seed oil glycereth-8 ester, magnesium coceth sulfate, magnesium coco sulfate, magnesium isododecylbenzenesulfonate, magnesium laureth-11 carboxylate, magnesium laureth sulfate, magnesium laureth-5 sulfate,Magnesium laureth-8 sulfate, magnesium laureth-16 sulfate, magnesium laureth-3 sulfosuccinate, magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium methyl cocoyl taurate, magnesium mireth sulfate, magnesium oleth sulfate, magnesium / TEA-coco sulfate, manicouagan clay, MEA-cocoate, MEA-laureth-6 carboxylate, MEA-laureth sulfate, MEA-lauryl sulfate, MEA-PPG-6 laureth-7 carboxylate, MEA-PPG-8-steareth-7 carboxylate MEA-Undecylenate, Meloxapol 108, Meloxapol 174, Meloxapol 178, Meloxapol 254, Meloxapol 255, Meloxapol 258, Meloxapol 314, MethoxyPEG-450 Amidoglutaloylsuccinimide, MethoxyPEG-450 Amidohydroxysuccinimidylsuccinimide, MethoxyPEG-450 Maleimide, Methylmorpholine Oxide, Myramidopropylamine Oxide, Myramidopropyl Betaine, Mincamidopropylamine Oxide, Mincamidopropyl Betaine, MIPA C12-15 Pareth Sulfate, MIPA-Dodecylbenzenesulfonic Acid, MIPA-Laureth Sulfate, MIPA-Lauryl Sulfate, Mixed Isopropanolamine Lanolate, Mixed Isopropanolamine Lauryl Sulfate, Mixed Isopropanolamine Myristic Acid, Morpholine Oleate, Morpholine Stearate, Myreth-3 Carboxylic Acid, Myreth-5 Carboxylic Acid, Myristalkonium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl Stamidopropyl PG-dimonium chloride phosphate, myristamine oxide, myristaminopropionic acid, myristic acid, myristoyl ethyltrimonium methosulfate, myristoyl glutamate, myristoyl hydrolyzed collagen, myristoyl sarcosine, myristyl betaine, myristyl / cetylamine oxide, myristyldimonium hydroxypropyl coco-glucoside chloride, myristyl glucoside, myristyl phosphate, nonoxynol-20, nonoxynol-23, nonoxynol-25, nonoxynol-30, nonoxynol-35,Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, n-noxynol-5 carboxylic acid, n-noxynol-8 carboxylic acid, n-noxynol-10 carboxylic acid, n-noxynol-3 phosphate, n-noxynol-4 phosphate, n-noxynol-6 phosphate, n-noxynol-9 phosphate, Nonylnoxynol-10 phosphate, Nonylnoxynol-30, Nonylnoxynol-49, Nonylnoxynol-100, Nonylnoxynol-150 Nonylnonoxynol-7 phosphate, Nonylnonoxynol-8 phosphate, Nonylnonoxynol-9 phosphate, Nonylnonoxynol-10 phosphate, Nonylnonoxynol-11 phosphate, Nonylnonoxynol-15 phosphate, Nonylnonoxynol-24 phosphate, Autoamidepropyl betaine, Octoxynol-16, Octoxynol-25, Octoxynol-30, Octoxynol-33, Octoxynol-40, Octoxynol-70, Octoxynol-20 carboxylic acid, Octyldodeceth-20, Octyldodeceth-25, O Cutyldodeceth-30, oleamidopropylamine oxide, oleamidopropyl betaine, oleamidopropyl hydroxysultaine, oleic acid, oleyl hydrolyzed collagen, oleyl sarcosine, olease-20, olease-23, olease-24, olease-25, olease-30, olease-35, olease-40, olease-44, olease-50, olease-3 carboxylic acid, olease-6 carboxylic acid, olease-10 carboxylic acid, oleyl betaine, olibamidopropylamine oxide, olibamidopropyl betaine, olivamidopropyl acid, oli Boiled hydrolyzed wheat protein, Ophiopogon extract stearate, Ozonated oleate-10, Ozonated PEG-10 oleate, Ozonated PEG-14 oleate, Ozonated polysorbate 80, Palm acid, Palmidopropyl betaine, Palmes-2 phosphate, Palmitamidopropylamine oxide, Palmitamidopropyl betaine, Palmitamine oxide, Palmitic acid, Palmitoyl collagen amino acids, Palmitoyl glycine, Palmitoyl hydrolyzed collagen, Palmitoyl hydrolyzed milk protein, Palmitoyl hydrolyzed wheat protein,Palmitoyl keratin amino acids, palmitoyl oligopeptides, palmitoyl silk amino acids, palm nucleic acid, palm kernel amidopropyl betaine, peach kernel oil glycereth-8 ester, peanut acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-5, Castor oil, PEG-54 castor oil, PEG-55 castor oil, PEG-60 castor oil, PEG-80 castor oil, PEG-100 castor oil, PEG-200 castor oil, PEG-11 cocamide, PEG-6 cocamide phosphate, PEG-4 cocamine, PEG-8 cocamine, PEG-12 cocamine, PEG-150 dibehenate, PEG-90 diisostearate, PEG-75 dilaurate, PEG-150 dilaurate, PEG-75 dioleate, PEG-150 dioleate, PEG-75 distearate, PEG-120 distearate, PEG-150 Distearate, PEG-175 distearate, PEG-190 distearate, PEG-250 distearate, PEG-30 glyceryl cocoate, PEG-40 glyceryl cocoate, PEG-78 glyceryl cocoate, PEG-80 glyceryl cocoate, PEG-30 glyceryl isostearate, PEG-40 glyceryl isostearate, PEG-50 glyceryl isostearate, PEG-60 glyceryl isostearate, PEG-90 glyceryl isostearate, PEG-23 glyceryl laurate, PEG-30 laurate Glyceryl, PEG-25 glyceryl oleate, PEG-30 glyceryl oleate, PEG-30 glyceryl soybean oil fatty acid, PEG-25 glyceryl stearate, PEG-30 glyceryl stearate, PEG-40 glyceryl stearate, PEG-120 glyceryl stearate, PEG-200 glyceryl stearate, PEG-28 glyceryl tallow, PEG-80 glyceryl tallow, PEG-82 glyceryl tallow, PEG-130 glyceryl tallow, PEG-200 glyceryl tallow, PEG-45 hydrogenated castor oil PEG-50 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin, PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate,PEG-30 isostearate, PEG-40 isostearate, PEG-26 jojobate, PEG-40 jojobate, PEG-15 jojoba alcohol, PEG-26 jojoba alcohol, PEG-40 jojoba alcohol, PEG-35 lanolin, PEG-40 lanolin, PEG-50 lanolin, PEG-55 lanolin, PEG-60 lanolin, PEG-70 lanolin, PEG-75 lanolin, PEG-85 lanolin, PEG-100 lanolin, PEG-150 lanolin, PEG-75 lanolin oil, PEG-2 lauramide, PEG-3 lauramine oxide, PE G-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glyceride, PEG-20 Mannitane Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanoic Acid, PEG-30 Oleamine, PEG-20 Oleic Acid, PEG-23 Oleic Acid, PEG-32 Oleic Acid, PEG-36 Oleic Acid, PEG-75 Oleic Acid PEG-150 oleate, PEG-20 palmitate, PEG-150 polyglyceryl-2 tristearate, PEG / PPG-28 / 21 acetate dimethicone, PEG / PPG-24 / 18 butyl ether dimethicone, PEG / PPG-3 / 17 copolymer, PEG / PPG-5 / 35 copolymer, PEG / PPG-8 / 55 copolymer, PEG / PPG-10 / 30 copolymer, PEG / PPG-10 / 65 copolymer, PEG / PPG-12 / 35 copolymer, PEG / PPG-16 / 17 copolymer, PEG / PPG-20 / 9 copolymer, PEG / PPG-20 / 20 copolymer, PEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, PEG / PPG-28 / 30 copolymer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer,PEG / PPG-300 / 55 copolymer, PEG / PPG-20 / 22 methyl ether dimethicone, PEG-26-PPG-30 phosphate ester, PEG / PPG-4 / 2 propylheptyl ether, PEG / PPG-6 / 2 propylheptyl ether, PEG-7 / PPG-2 propylheptyl ether, PEG / PPG-8 / 2 propylheptyl ether, PEG / PPG-10 / 2 propylheptyl ether, PEG / PPG-14 / 2 propylheptyl ether, PEG / PPG-40 / 2 propylheptyl ether, PEG / PPG-10 / 2 ricinoleate, PEG / PPG-32 / 3 ricinoleate, PEG-55 propylene glycol oleate, PEG-25 propylene glycol stearate, PEG-75 propylene glycol stearate, PEG-120 propylene glycol stearate, PEG-5 rapeseed sterol, PEG-10 rapeseed sterol, PEG-40 ricinolamide, PEG-75 shea butter glyceride, PEG-75 shorea butter glyceride, PEG-20 sorbitan cocoate, PEG-20 sorbitan isostearate, PEG- 40 sorbitan lanolate, PEG-75 sorbitan lanolinate, PEG-10 sorbitan laurate, PEG-40 sorbitan laurate, PEG-44 sorbitan laurate, PEG-75 sorbitan laurate, PEG-80 sorbitan laurate, PEG-20 sorbitan oleate, PEG-80 sorbitan palmitate, PEG-40 sorbitan stearate, PEG-60 sorbitan stearate, PEG-160 sorbitan triisostearate, PEG-40 soybean sterols, PEG-2 stearate amide, PEG-9 saturates Thearamid carboxylic acid, PEG-20 stearic acid, PEG-23 stearic acid, PEG-25 stearic acid, PEG-30 stearic acid, PEG-32 stearic acid, PEG-35 stearic acid, PEG-36 stearic acid, PEG-40 stearate, PEG-45 stearate, PEG-50 stearate, PEG-55 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearic acid phosphate, PEG-20 talate,PEG-50 Fat Amide, PEG-2 Fat Amide DEA, PEG-20 Fat, PEG-66 Trihydroxystearin, PEG-200 Trihydroxystearin, PEG-60 Glyceride, Pelargonic Acid, Pentadoxyl-200, Fenes-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer, er334, Poloxamer -335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl Pentacaprylate Ceryl-6, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomadris kumella Flower / Leaf Extract, Polyacococcus Extract, Abietoyl Hydrolyzed Collagen Potassium, Baba Potassium phosphate, potassium behenate, potassium C9-15 alkyl phosphate, potassium C11-15 alkyl phosphate, potassium C12-13 alkyl phosphate, potassium C12-14 alkyl phosphate, potassium caprate, potassium capryloyl glutamate, potassium capryloyl hydrolyzed rice protein, potassium castorate, potassium cocoate, potassium cocoyl glutamate, potassium cocoyl glycine, potassium cocoyl hydrolyzed casein, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin,Cocoyl hydrolyzed oat protein potassium, cocoyl hydrolyzed potato protein potassium, cocoyl hydrolyzed rice bran protein potassium, cocoyl hydrolyzed rice protein potassium, cocoyl hydrolyzed silk potassium, cocoyl hydrolyzed soy protein potassium, cocoyl hydrolyzed wheat protein potassium, cocoyl hydrolyzed yeast protein potassium, cocoyl PCA potassium, cocoyl sarcosinate potassium, cocoyl taurate potassium, cornate potassium, cyclocarboxypropyl oleate potassium, dihydroxyethyl cocamine oxide phosphate potassium, dimethicone PEG-7 phosphate potassium, dodecylbenzenesulfonate potassium, hemp seed acid potassium, hydrogenated cocoate potassium, hydrogenated palmate potassium, hydrogenated tallowate potassium, hydroxystearate potassium, isostearate potassium, lanolinate potassium, laurate potassium, laureth-3 carboxylate potassium, laureth-4 carboxylate potassium, laureth-5 carboxylate potassium, laureth-6 carboxylate potassium, laureth-10 carboxylate potassium, laureth phosphate potassium, lauroyl collagen Potassium amino acids, potassium lauroyl glutamate, potassium lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed pea protein, potassium lauroyl hydrolyzed soy protein, potassium lauroyl PCA, potassium lauroyl pea amino acids, potassium lauroyl sarcosinate, potassium lauroyl silk amino acids, potassium lauroyl wheat amino acids, potassium lauroyl phosphate, potassium lauroyl sulfate, potassium linoleate, potassium metaphosphate, potassium cocoyl taurate methyl potassium, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octoxinol-12 phosphate, potassium oleate, potassium oleoyl hydrolyzed collagen, potassium olivine, potassium oliboyl hydrolyzed oat protein, potassium oliboyl hydrolyzed wheat protein, potassium oliboyl / lauroyl wheat amino acids, potassium oliboyl PCA, potassium palmitate, potassium palmitoyl hydrolyzed corn protein, palmitoyl hydrolyzed oat protein, palmitoyl hydrolyzed rice protein,Palmitoyl hydrolyzed sweet almond protein, palmitoyl hydrolyzed wheat protein, potassium palm kernelate, potassium peanutate, potassium rapeseed, potassium ricinoleate, potassium safflowerate, potassium soybeanate, potassium stearate, potassium stearoyl hydrolyzed collagen, potassium tarate, potassium taluate, potassium taurate, potassium taurate, Potassium taurate, potassium trideceth-3 carboxylate, potassium trideceth-4 carboxylate, potassium trideceth-7 carboxylate, potassium trideceth-15 carboxylate, potassium trideceth-19 carboxylate, potassium trideceth-6 phosphate, potassium trideceth-7 phosphate, potassium tetrate, potassium undecylenate, undecylenol hydrolyzed collagen, undecylenol hydrolyzed rice protein potassium PPG-30-buteth-30, PPG-36-buteth-36, PPG-38-buteth-37, PPG-30-capryleth-4 Coco-acid, PPG-10 cetyl ether phosphate, PPG-2C9-11 pareth-8, PPG-1-deceth-5, PPG-3-deceth-2 carboxylic acid, PPG-30 ethylhexyl-4 phosphate, PPG-20-glycereth-30, PPG-2 hydroxyethyl coco / rostearamid, PPG-2-losodeceth-8, PPG-2-losodeceth-10, PPG-2-losodeceth-18, PPG-2-losodeceth-25, PPG-4-losodeceth-10, propyltrimonium hydrolyzed collagen, quaternium-24, quaternium-52, quaternium-87, nata Rice bran acid, rice bran acid, rice oil glycereth-8 ester, ricinolamidopropyl betaine, ricinoleic acid, ricinoleic acid-40, safflower acid, soapberry fruit extract, saponaria root powder, saponin, soap-K, soap-Na / K, soap syrup, soap syrup-K, sesame oil glycereth-8 ester, sesamidopropylamine oxide, sesamidopropyl betaine, shea butter amidopropyl betaine, shea butter glycereth-8 ester, sodium arachidinate, sodium arganum phoacetate, sodium astrocalium murumurate, sodium avocadoate Thorium, sodium babassuamphoacetate, sodium babasate, sodium babass sulfate, sodium behenate, sodium bisglycol ricinosulfosuccinate, sodium bishydroxyethylglycinate cocoglucoside crosspolymer, sodium bishydroxyethylglycinate lauryl glucoside crosspolymer, borage amidopropyl PG-dimonium chloride phosphate sodium, sodium butoxynol-12 sulfate, sodium butylglucoside, sodium C13-17 alkanesulfonate, sodium C14-18 alkanesulfonate,C12-15 Alkoxypropyliminodipropionate, C10-16 Alkyl Sulfate, Sodium C11-15 Alkyl Sulfate, Sodium C12-13 Alkyl Sulfate, Sodium C12-15 Alkyl Sulfate, Sodium C12-18 Alkyl Sulfate, Sodium C16-20 Alkyl Sulfate, Sodium C9-22 AlkylSec Sulfonic Acid, Sodium C14-17 AlkylSec Sulfonate, Sodium Caprate, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropyl Sulfonate, Sodium Caproamphopropionate Sodium caproyl methyl taurate, sodium caprylate, sodium capryleth-2 carboxylate, sodium capryloamphoacetate, sodium capryloamphohydroxypropyl sulfonate, sodium capryloamphopropionate, sodium capryloyl glutamate, sodium capryloyl hydrolyzed wheat protein, sodium caprylyl PG-sulfonate, sodium caprylyl sulfonate, sodium castorate, sodium ceteareth-13 carboxylate, sodium cetearyl sulfate, ceteareth- Sodium 13-carboxylate, sodium cetyl sulfate, sodium cocamidopropyl PG-dimonium chloride phosphate, sodium cocaminopropionate, sodium coceth sulfate, sodium coceth-30 sulfate, sodium cocoa butter amphoacetate, sodium cocoa butterate, sodium cocoamphoacetate, sodium cocoamphohydroxypropyl sulfonate, sodium cocoamphopropionate, sodium cocoate, sodium coco / babassu / andiroba sulfate, sodium coco / babassu sulfate, sodium cocoglucoside hydroxypropyl phosphate, cocog Sodium Glucoside Hydroxypropyl Sulfonate, Sodium Coco-Glucoside Tartrate, Sodium Coco-Glyceryl Ether Sulfonate, Sodium Coco-Hydrogenated Scutellaria Baicalensis Sulfate, Sodium Coco-Imino Diacetate, Sodium Coco-Monoglyceride Sulfate, Sodium Coco-Monoglyceride Sulfonate, Sodium Coco-PG-Dimonium Chloride Phosphate, Sodium Coco-Sulfate, Sodium Coco-Acetate, Sodium Cocoyl Alaninate, Sodium Cocoyl Amino Acids, Sodium Cocoyl Collagen Amino Acids, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutamate,Sodium cocoyl glycinate, sodium cocoyl / hydrogenated tallow glutamate, sodium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed keratin, sodium cocoyl hydrolyzed rice protein, sodium cocoyl hydrolyzed silk, sodium cocoyl hydrolyzed soy protein, sodium cocoyl hydrolyzed sweet almond protein, sodium cocoyl hydrolyzed wheat protein, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl isethionate, sodium cocoyl methylaminopropionate, sodium cocoyl oat amino acid, sodium cocoyl / palmoyl / sunflower glutamate, sodium cocoyl proline, sodium cocoyl sarcosinate, sodium cocoyl tau phosphate, sodium cocoyl threonate, sodium cocoyl wheat amino acid, sodium C12-14 olefin sulfonate, sodium C14-16 olefin sulfonate, sodium C14-18 olefin sulfonate, sodium C16-18 olefin sulfonate, sodium cornan fopropionate, sodium cottonseed amphoacetate, C13-15 Sodium reth-8 butyl phosphate, sodium C9-11 pareth-6 carboxylate, sodium C11-15 pareth-7 carboxylate, sodium C12-13 pareth-5 carboxylate, sodium C12-13 pareth-8 carboxylate, sodium C12-13 pareth-12 carboxylate, sodium C12-15 pareth-6 carboxylate, sodium C12-15 pareth-7 carboxylate, sodium C12-15 pareth-8 carboxylate, sodium C14-15 pareth-8 carboxylate, sodium C12-14 pareth-8 carboxylate, sodium C14-15 pareth -PG sodium sulfonate, C12-13 pareth-2 sodium phosphate, C13-15 pareth-8 sodium phosphate, C9-15 pareth-3 sodium sulfate, C10-15 pareth sulfate sodium, C10-16 pareth-2 sodium sulfate, C12-13 pareth sulfate sodium, C12-15 pareth sulfate sodium, C12-15 pareth-3 sodium sulfate, C13-15 pareth-3 sodium sulfate, C12-14 sec pareth-3 sodium sulfate, C12-15 pareth-3 sodium sulfonate, C12-15 pareth-7 sodium sulfonate,Sodium C12-15 Pareth-15 Sulfonate, Sodium Deceth-2 Carboxylate, Sodium Deceth Sulfate, Sodium Decylbenzenesulfonate, Sodium Decyl Glucoside Hydroxypropyl Phosphate, Sodium Decyl Glucoside Hydroxypropyl Sulfonate, Sodium Dilaureth-7 Citrate, Sodium Dilaureth-10 Phosphate, Sodium Dilinolamidopropyl PG-Dimonium Chloride Phosphate, Sodium Dilinoleate, Sodium Dioleth-8 Phosphate, Sodium Dodecylbenzenesulfonate, Sodium Ethyl 2-Sulfolaurate, Sodium Glyceryl Oleate Phosphate, Sodium Grapeseed Amphoacetate, Sodium Grapeseed Sodium, Sodium Hempseed Amphoacetate, Sodium Hexeth-4 Carboxylate, Sodium Hydrogenated Cocoyl Sodium Cocoyl Methyl Isethionate, Sodium Hydrogenated Palmitate, Sodium Hydrogenated Taluate, Sodium Hydrogenated Taluyl Glutamate, Sodium Hydroxylauryl Dimonium Ethyl Phosphate, Hydroxypropyl Palm Nucleic Acid Sodium Sodium phosphate, decyl glucoside hydroxypropyl phosphate crosspolymer sodium hydroxypropyl phosphate lauryl glucoside crosspolymer sodium hydroxypropyl sulfonic acid coco glucoside crosspolymer sodium hydroxypropyl sulfonic acid decyl glucoside crosspolymer sodium hydroxypropyl sulfonic acid lauryl glucoside crosspolymer sodium hydroxypropyl sulfonic acid lauryl glucoside crosspolymer sodium hydroxystearate sodium hydroxystearate sodium isostearate sodium isosteareth-6 carboxylate sodium isosteareth-11 carboxylate sodium isostearoyl amphoacetate sodium isostearoyl amphopropionate sodium N-isostearoyl methyl taurate sodium laneth sulfate sodium lanolinate sodium lanolinate sodium laurate sodium lauramido diacetate sodium lauaminopropionate sodium laurate sodium laureth-3 carboxylate sodium laureth-4 carboxylate sodium laureth-5 carboxylate sodium laureth-6 carboxylate sodium laureth-8 carboxylate sodium laureth-11 carboxylate sodium,Sodium laureth-12 carboxylate, sodium laureth-13 carboxylate, sodium laureth-14 carboxylate, sodium laureth-16 carboxylate, sodium laureth-17 carboxylate, sodium laureth sulfate, sodium laureth-5 sulfate, sodium laureth-7 sulfate, sodium laureth-8 sulfate, sodium laureth-12 sulfate, sodium laureth-40 sulfate, sodium laureth-7 tartrate, sodium lauriminodipropionate, sodium lauroamphoacetate, sodium lauroamphohydroxypropyl sulfonate, sodium lauroamphoPG acetate phosphate, sodium lauroamphopropionate, sodium lauroyl asparate, sodium lauroyl collagen amino acid, sodium lauroyl glycine propionate, sodium lauroyl hydrolyzed collagen, sodium lauroyl sodium silk, sodium lauroyl hydroxypropyl sulfonate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl methyl isethionate, sodium lauroyl kibi amino acid, Sodium uroyl / myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosinate, sodium lauroyl silk amino acid, sodium so-lauroyl taurate, sodium lauroyl wheat amino acid, sodium lauryl diethylenediaminoglycinate, sodium lauryl glucose carboxylate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, sodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetic acid, sodium linoleate, sodium macadamia azeate, sodium mangoamphoacetate, sodium mango seed acid, sodium laureth-2 sulfosuccinate / MEA, sodium methoxyPPG-2 acetate, sodium methyl cocoyl taurate, sodium methyl lauroyl taurate, sodium methylmyristoyl taurate, sodium methyl oleyl taurate, sodium methyl palmitoyl taurate,Sodium methylstearoyl taurate, sodium methyl 2-sulfolaurate, sodium methyl 2-sulfopalmitate, sodium methyl taurine isopalmitate, sodium methyl taurine cocoyl methyl taurate, sodium my-reth sulfate, sodium myristate, sodium myristoamphoacetate, sodium myristoyl glutamate, sodium myristoyl hydrolyzed collagen, myri, Sodium stoyl isethionate, sodium myristoyl sarcosinate, sodium myristyl sulfate, sodium nonoxynol-6 phosphate, sodium nonoxynol-9 phosphate, sodium nonoxynol-1 sulfate, sodium nonoxynol-3 sulfate, sodium nonoxynol-4 sulfate, sodium nonoxynol-6 sulfate, sodium nonoxynol-8 sulfate, sodium nonoxynol-10 sulfate, sodium nonoxynol-25 sulfate, sodium octooxynol-2 ethanesulfonate, sodium octooxynol-2 sulfate, oc Sodium toxinol-6 sulfate, sodium octoxynol-9 sulfate, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropyl sulfonate, sodium oleoamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl isethionate, sodium olease sulfate, sodium oleylmethyl isethionate, sodium oleyl sulfate, sodium olivanphoacetate, sodium olivicate, sodium olivoyl glutamate, sodium palm amphoacetate, sodium palmate, sodium palm glycerides sulfonate, sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat protein, sodium palmitoyl sarcosinate, sodium palm nucleic acid, sodium palm nucleic acid isethionate, sodium palmoyl glutamate, sodium passiflora edulis seedate, sodium peanut amphoacetate, sodium peanutate, sodium PEG-6 cocamide carboxylate, sodium PEG-8 cocamide carboxylate, sodium PEG-4 cocamide sulfate, sodium PEG-3 laura Sodium midocarboxylate, sodium PEG-4 lauramide carboxylate, sodium PEG-8 palm glyceride carboxylate, sodium pentaerythrityl hydroxypropyl iminodiacetate dendrimer, sodium propoxy PPG-2 acetate, sodium rapeseed, sodium komeblan amphoacetate, sodium ricinoleate, sodium ricinol amphoacetate, sodium rosehipsanphoacetate, sodium rosinate, sodium safflower acid, sodium safflower oil hydrolyzed soy protein, sodium sesame seed acid, sodium sesanphoacetate,Shea butter sodium amphoacetate, sodium hydroxide, soy sodium reduced collagen, sodium stearate, sodium stearoamphoacetate, sodium stearoamphohydroxypropyl sulfonate, sodium stearoamphopropionate, sodium stearoyl caseinate, sodium stearoyl glutamate, sodium stearoyl hyaluronate, sodium stearoyl hydrolyzed collagen, sodium stearoyl hydrolyzed corn protein, sodium stearoyl hydrolyzed silk, sodium stearoyl hydrolyzed soy protein, sodium stearoyl hydrolyzed wheat protein, sodium stearoyl lactalbumin, sodium stearoyl methyl isethionate, sodium stearoyl oat protein, sodium stearoyl pea protein, sodium stearoyl soy protein, sodium stearyl dimethylglycine, sodium stearyl sulfate, sodium sunflower seed amphoacetate, sodium surfactin, sodium sweet almond amphoacetate, sodium sweet almonate, sodium talanphopropionate, sodium tar acid Thorium, Sodium Taloamphoacetate, Sodium Taloate, Sodium Talosulfate, Sodium Tamanuzate, Sodium Taurate, Sodium Taurine Cocoyl Methyl Taurate, Sodium Taurine Laurate, Sodium / TEA-Lauroyl Collagen Amino Acids, Sodium / TEA-Lauroyl Hydrolyzed Collagen, Sodium / TEA-Lauroyl Hydrolyzed Keratin, Sodium / TEA-Lauroyl Keratin Amino Acids, Sodium / TEA-Undecylenoyl Collagen Amino Acids, Sodium / TEA-Undecylenoyl Hydrolyzed Collagen, Sodium / TEA-Undecylenoyl Hydrolyzed Corn Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Soy Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Wheat Protein, Sodium Theobroma Grandiflorum Seedate, Sodium Trideceth-3 Carboxylate, Sodium Trideceth-4 Carboxylate, Sodium Trideceth-6 Carboxylate, Sodium Trideceth-7 Carboxylate, Sodium Trideceth-8 Carboxylate, Sodium Trideceth-12 Carboxylate, Sodium Trideceth-15 Carboxylate,Sodium trideceth-19 carboxylate, sodium trideceth sulfate, sodium tridecylbenzenesulfonate, sodium tridecyl sulfate, sodium trimethylolpropane hydroxypropyl minodiacetate dendrimer, sodium undeceth-5 carboxylate, sodium undecylenate, sodium undecylenoamphoacetate, sodium undecylenoamphopropionate, sodium undecylenoyl glutamate, sodium wheat germ amphoacetate, sorbeth-160 tristearate, soy acid, soyamide propylamine oxide, soyamide Propyl betaine, soybean oil glycereth-8 ester, stearamidopropylamine oxide, stearamidopropyl betaine, stearamine oxide, steareth-15, steareth-16, steareth-20, steareth-21, steareth-25, steareth-27, steareth-30, steareth-40, steareth-50, steareth-80, steareth-100, steareth-2 phosphate, steareth-3 phosphate, stearic acid, stearoxypropyltrimonium chloride, stearoyl glutamic acid, stearoyl sarcosine, steareth Rubetaine, stearyldimonium hydroxypropyl butyl glucoside chloride, stearyldimonium hydroxypropyl decyl glucoside chloride, stearyldimonium hydroxypropyl lauryl glucoside chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower amide MEA, sunflower seed acid, sunflower seed amide propyl hydroxyethyldimonium chloride, sunflower seed oil glycereth-8 ester, tall oil acid, talus acid, talus amide propylamine oxide, Taroamidopropyl betaine, taroamidopropyl hydroxysultaine, taroamine oxide, taro betaine, taro dihydroxyethyl betaine, taroyl ethyl glucoside, TEA-abietoyl hydrolyzed collagen, TEA-C12-14 alkyl phosphate, TEA-C10-15 alkyl sulfate, TEA-C11-15 alkyl sulfate, TEA-C12-13 alkyl sulfate, TEA-C12-14 alkyl sulfate, TEA-C12-15 alkyl sulfate, TEA-C14-17 alkylsec sulfonate, TEA-canolate,TEA-Cocamide Diacetate, TEA-Cocoate, TEA-Cocosulfate, TEA-Cocoyl Alaninate, TEA-Cocoyl Glutamate, TEA-Cocoyl Glutaminate, TEA-Cocoyl Glycinate, TEA-Cocoyl Hydrolyzed Collagen, TEA-Cocoyl Hydrolyzed Soy Protein, TEA-Cocoyl Sarcosinate, Dimethicone PEG-7 Phosphate TEA, Dodecylbenzenesulfonate TEA, Hydrogenated Cocoate TEA, Hydrogenated Taroyl Glutamate TEA, Lostearate TEA, Lostearoyl Hydrolyzed Collagen TEA, Laurami TEA nopropionate, TEA laurate, TEA laurate / myristate, TEA laureth sulfate, TEA-lauroyl collagen amino acid salt, TEA-lauroyl glutamate, TEA-lauroyl hydrolyzed collagen, TEA-lauroyl keratin amino acid salt, TEA-lauroyl methylaminopropionate, TEA-lauroyl / myristoyl aspartate, TEA-lauroyl sarcosinate, TEA-lauryl phosphate, TEA-lauryl sulfate, TEA-myristylaminopropionate, TEA-myristate, TEA- Myristoyl hydrolyzed collagen, TEA-oleate, TEA-oleyl hydrolyzed collagen, TEA-oleyl sarcosinate, TEA-oleyl sulfate, TEA-palmitate, TEA-palm kernel sarcosinate, TEA-PEG-3 cocamide sulfate, TEA rosinate, TEA stearate, TEA tarate, TEA tridecylbenzenesulfonate, TEA undecylenate, undecylenoyl hydrolyzed collagen, tetramethyldecinediol dicarboxyethyl stearyl sulfosuccinate tetrasodium, TIPA-laureth sulfate, TI PA-Lauryl Sulfate, TIPA-Myristic Acid, TIPA-Stearate, Tocopheryl Phosphate, Trehalose Undecylenoate TM-C12-15 Pareth-2 Phosphate, TM-C12-15 Pareth-6 Phosphate, TM-C12-15 Pareth-8 Phosphate, TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Trideceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate,Tridecylbenzenesulfonic acid, trilaureth-9 citrate, trimethylolpropane hydroxypropyl bis-hydroxyethylamine dendrimer, lauroampho-PG-trisodium phosphate chloride acetate, undecanoic acid, undeceth-5 carboxylic acid, undecylenamidopropylamine oxide, undecylenamidopropyl betaine, undecylenic acid, lenoyl collagen amino acids, undecylenoyl glycine, undecylenoyl hydrolyzed collagen, undecylenoyl wheat amino acids, undecyl glucoside, wheat germic acid, wheat germamidopropylamine oxide, wheat germamidopropyl betaine, Yucca schidigera leaf / root / stem extract, Yucca schidigera stem extract, zinc coceth sulfate, zinc coco sulfate.

[0021] Preferably, the compound is one or more compounds selected from the group consisting of sodium laureth sulfate, cocamidopropyl betaine, sodium cocoamphoacetate, cocoglucoside, and ammonium lauryl sulfosuccinate.

[0022] The surfactant content in the formulation may be 0.1 to 10% by weight, preferably 0.5 to 5% by weight, based on the formulation.

[0023] <Oil Body> Suitable oil bodies for forming the components of the O / W emulsion, for example, gelbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10 carbon atoms, esters of linear C6-C22-fatty acids and linear or branched C6-C22-fatty alcohols, or esters of branched C6-C13-carboxylic acids and linear or branched C6-C22-fatty alcohols, for example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate These are lyl, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl myristate, oleyl palmitate, oleyl palmitate, oleyl palmitate, oleyl palmitate, oleyl palmitate, oleyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl palmitate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate, and erucate.Also preferred are esters of linear C6-C22-fatty acids with branched alcohols, particularly 2-ethylhexanol; esters of C18-C38-alkylhydroxycarboxylic acids with linear or branched C6-C22-fatty alcohols, particularly dioctyl malate; linear and / or branched fatty acids with polyhydric alcohols (e.g., propylene glycol, dimergol, or trimeltriol) and / or gelbet alcohols; triglycerides based on C6-C10-fatty acids; liquid mono / di / triglyceride mixtures based on C6-C18-fatty acids; esters of C6-C22-fatty alcohols and / or gelbet alcohols with aromatic carboxylic acids, particularly benzoic acid; esters of C2-C12-dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms, or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups. Vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C6-C22 fatty alcohol carbonates, e.g., dicaprylyl carbonate (Cetiol® CC), guerbet carbonates based on aliphatic alcohols having 6 to 18, preferably 8 to 10 carbon atoms, esters of benzoic acid with linear and / or branched C6-C22 alcohols (e.g., C6-C22) (Finsolv® TN), linear or branched symmetric or asymmetric dialkyl ethers having 6 to 22 carbon atoms per alkyl group, e.g., dicaprylyl ether (Cetiol® OE), epoxidized fatty acid esters and polyols, silicone oils (cyclomethicone, silicone methicone grade, etc.) and / or aliphatic or naphthenic hydrocarbons, e.g., squalane, squalene or dialkylcyclohexane, and ring-opening products.

[0024] <Emulsifier> Other nonionic or cationic surfactants can also be added to the preparation as emulsifiers, including, for example: - Addition products of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear C8-22 fatty alcohols, C12-22 fatty acids, and alkylphenols containing 8 to 15 carbon atoms in the alkyl group; - C12 / 18 fatty acid monoesters and diesters of addition products of 1 to 30 moles of ethylene oxide to glycerol; - Glycerol mono and diesters, sorbitan mono and diesters of saturated and unsaturated fatty acids having 6 to 22 carbon atoms and their ethylene oxide addition products; - Addition product of 15 to 60 moles of ethylene oxide to castor oil and / or hydrogenated castor oil; - Polyol esters, especially polyglycerol esters such as polyglycerol polyricinolate, polyglycerol poly-12-hydroxystearate, or polyglycerol dimerate isostearate; mixtures of compounds of these classes are also suitable; - Addition product of 2 to 15 moles of ethylene oxide to castor oil and / or hydrogenated castor oil; - Linear, branched, unsaturated or saturated C6 / 22 fatty acids, ricinoleic acid and 12-hydroxystearic acid, as well as partial esters based on glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (e.g., sorbitol), alkyl glucosides (e.g., methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g., cellulose); - Mono-, di-, and trialkyl phosphates, mono-, di-, and / or tri-PEG-alkyl phosphates and their salts; - Wool wax alcohol; - Polysiloxane / polyalkyl polyether copolymers and their corresponding derivatives; - Mixed esters of pentaerythritol, fatty acids, citric acid, and fatty alcohols and / or mixed esters of C6-22 fatty acids, methyl glucose, and polyols, preferably glycerol or polyglycerol; - Polyalkylene glycol; and - Glycerin carbonate.

[0025] Addition products of ethylene oxide and / or propylene oxide to fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters, sorbitan mono- and diester fatty acids, or castor oil are known commercially. These are homologous mixtures, and their average degree of alkoxylation corresponds to the ratio of the amount of substrate undergoing the addition reaction with ethylene oxide and / or propylene oxide. C12 / 18 fatty acid monoesters and diesters of ethylene oxide addition products to glycerol are known as lipid layer enhancers in cosmetic formulations. Preferred emulsifiers are described in detail below:

[0026] Partial glycerides. Typical examples of suitable partial glycerides include hydroxystearate monoglyceride, hydroxystearate diglyceride, isostearate monoglyceride, isostearate diglyceride, oleate monoglyceride, oleate diglyceride, ricinoleate monoglyceride, ricinoleate diglyceride, linoleate monoglyceride, linoleate diglyceride, linolenic acid monoglyceride, linolenic acid diglyceride, erucate monoglyceride, erucate diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citrate monoglyceride, citrate diglyceride, malic acid monoglyceride, malic acid diglyceride, and industrial mixtures thereof that may contain small amounts of triglycerides derived from the manufacturing process. Addition products obtained by adding 1 to 30 moles, preferably 5 to 10 moles, of ethylene oxide to a partial glyceride are also suitable.

[0027] Sorbitan ester. Suitable sorbitan esters include sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoelucate, sorbitan sesquielucate, sorbitan dielucate, sorbitan trioleate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diricinoleate, and sorbitan triricinoleate. These include ethyl esters, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquienoate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate, and technical mixtures thereof. Addition products obtained by adding 1 to 30, preferably 5 to 10 moles, of ethylene oxide to a sorbitan ester are also suitable.

[0028] Polyglycerol ester. Typical examples of suitable polyglycerol esters include polyglyceryl-2 dipolyhydroxystearate (Dehymuls® PGPH), polyglycerin-3-diisostearate (Lameform® TGI), polyglyceryl-4 isostearate (Isolan® GI34), polyglyceryl-3 oleate, polyglyceryl-3 diisostearoyl diisostearate (Isolan® PDI), and polyglyceryl-3 methylglucose distearate (TegoCare®). Examples of polyol esters include (Registered Trademark) 450), polyglyceryl-3 beeswax (CeraBellina®), polyglyceryl-4 caprate (Polyglycerin Caprate T2010 / 90), polyglyceryl-3 cetyl ether (Chimexane® NL), polyglyceryl-3 distearate (Cremophor® GS32), and polyglyceryl polyricinoleate (Admul® WOL1403), polyglyceryl dimerate isostearate, and mixtures thereof. Other suitable examples of polyol esters include mono, di, and triesters of trimethylolpropane or pentaerythritol with lauric acid, coco fatty acid, beef tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid, etc., which may optionally be reacted with 1 to 30 moles of ethylene oxide.

[0029] Tetraalkylammonium salt. Cationic surfactants consist of hydrophobic polymeric groups necessary for the surface activity of cations by dissociation in aqueous solution. An important representative group of cationic surfactants is the tetraalkylammonium salt with the general formula: (R1R2R3R4N+)X-, where R1 represents a C1-C8 alkyl(alkenyl) group, and R2, R3, and R4 independently represent alkyl(alkenyl) radicals having 1 to 22 carbon atoms. X is a counterion, preferably selected from the group of halides, alkyl sulfates, and alkyl carbonates. Cationic surfactants in which the nitrogen group is substituted with two long acyl groups and two short alkyl(alkenyl) groups are particularly preferred.

[0030] Estherquat. A further class of cationic surfactants particularly useful as co-surfactants for the present invention is represented by so-called ester quats. Ester quats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of preparative organic chemistry. In this regard, WO91 / 01295A1 is referenced, which states that triethanolamine is partially esterified with a fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate or ethylene oxide. Furthermore, German patent DE4308794C1 describes a method for producing solid ester quats in which the quaternization of the triethanolamine ester is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0031] Typical examples of ester quats suitable for use according to the present invention are products derived from monocarboxylic acids corresponding to the formula RCOOH, where RCO is an acyl group containing 6 to 10 carbon atoms, and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid, and technical mixtures thereof such as so-called head-fractionated fatty acids. Ester quats derived from monocarboxylic acids containing 8 to 10 carbon atoms in the acyl component are preferably used. Other ester quats are derived from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. Overall, ester quats derived from a mixture of monocarboxylic acids containing 6 to 22 carbon atoms and adipic acid are preferably used. The molar ratio of monocarboxylic acid to dicarboxylic acid in the final ester quat may range from 1:99 to 99:1, preferably from 50:50 to 90:10, and more specifically from 70:30 to 80:20. Besides quaternized fatty acid triethanolamine ester salts, other suitable ester quats are quaternized ester salts of mono- / dicarboxylic acid mixtures with diethanolalkylamine or 1,2-dihydroxypropyldialkylamine. Ester quats can be obtained from fatty acids as well as from corresponding triglycerides mixed with the corresponding dicarboxylic acids. A representative example of such a method is proposed in EP0750606B1, representing relevant prior art. To produce quaternized esters, mixtures of mono- and dicarboxylic acids and triethanolamine (based on available carboxyl functional groups) can be used in molar ratios from 1.1:1 to 3:1. Considering the performance characteristics of ester quats, ratios of 1.2:1 to 2.2:1, preferably 1.5:1 to 1.9:1, have proven particularly advantageous. Preferred ester quats are technical mixtures of mono-, di-, and triesters with an average degree of esterification of 1.5 to 1.9.

[0032] <Superfat agents and consistency factors> Superfatting agents can be selected from substances such as lanolin and lecithin, as well as polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides, and fatty acid alkanolamides, with fatty acid alkanolamides also functioning as foam stabilizers.

[0033] The coherence factors primarily used are fatty alcohols or hydroxyfatty alcohols containing 12 to 22, preferably 16 to 18, carbon atoms, as well as partial glycerides, fatty acids, or hydroxyfatty acids. These substances are preferably used in combination with alkyl oligoglucosides and / or fatty acid N-methylglucamides and / or polyglycerol poly-12-hydroxystearates of the same chain length.

[0034] <Thickeners and rheological additives> Suitable thickeners include high molecular weight thickeners, such as Aerosil® type (hydrophilic silica), polysaccharides, more specifically xanthan gum, guar-guar, agar, alginates and tyroses, carboxymethylcellulose and hydroxyethylcellulose, as well as relatively high molecular weight polyethylene glycol monoesters and diesters of fatty acids, polyacrylates (e.g., Carbopols® [Goodrich] or Synthalens® [Sigma]), polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone, surfactants such as ethoxylated fatty acid glycerides, esters of fatty acids and polyols such as pentaerythritol and trimethylolpropane, narrow range fatty alcohol ethoxylates, and electrolytes such as sodium chloride and ammonium chloride.

[0035] <polymer> Suitable cationic polymers include, for example, cationic cellulose derivatives such as quaternized hydroxyethylcellulose available from Amerchol under the name Polymer JR400®, cationic starch, copolymers of diallylammonium salts and acrylamide, such as quaternized vinylpyrrolidone / vinylimidazole polymers such as Luviquat® (BASF), condensation products of polyglycols and amines, such as quaternized collagen polypeptides such as lauryldimonium hydroxypropyl hydrolyzed collagen, quaternized collagen polypeptides such as lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat® L, Grunau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers such as amodimethicone, copolymers of adipic acid and dimethylaminohydroxypropyl diethylenetriamine (Cartaretine® Sandoz), copolymers of acrylic acid and dimethyldiallylammonium chloride (Merquat®) These include polyaminopolyamides and their crosslinked water-soluble polymers, cationic chitin derivatives such as quaternary chitosan, optionally in microcrystalline form, dihaloalkyls such as dibromobutan and bis-dialkylamines such as bis-dimethylamino-1,3-propane condensation products, cationic guar gums such as Celanese's Jaguar® CBS, Jaguar® C-17, Jaguar® C-16, quaternary ammonium salt polymers such as Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol, and various polyquaternium types (e.g., 6, 7, 32, or 37) commercially available under trade names such as Rheocare® CC or Ultragel® 300.

[0036] Suitable anionic, zwitterionic, amphoteric, and nonionic polymers include, for example, vinyl acetate / crotonic acid copolymer, vinylpyrrolidone / vinyl acrylate copolymer, vinyl acetate / butyl maleate / isobornyl acrylate copolymer, methyl vinyl ether / maleic anhydride copolymer and its esters, uncrosslinked and polyol-crosslinked polyacrylic acids, acrylamide-propyltrimethylammonium chloride / acrylate copolymer, octylacrylamide / methyl methacrylate / tert.butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymer, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, vinylpyrrolidone / dimethylaminoethyl methacrylate / vinyl caprolactam terpolymer, and optionally derivatized cellulose ethers and silicones.

[0037] <Pearlescent wax> Suitable pearlescent waxes include, for example, alkylene glycol esters, particularly ethylene glycol distearate; fatty acid alkanolamides, particularly coco-fatty acid diethanolamide; partially glycerides, particularly monoglyceride stearate; esters of polybasic, optionally hydroxysubstituted carboxylic acids with fatty alcohols containing 6 to 22 carbon atoms, particularly long-chain esters of tartaric acid; fatty compounds, such as fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, particularly laurone and distearyl ethers, containing at least 24 carbon atoms in total; fatty acids, such as stearic acid, hydroxystearic acid or behenic acid; ring-opening products of olefin epoxides containing 12 to 22 carbon atoms with fatty alcohols containing 12 to 22 carbon atoms and / or polyols containing 2 to 15 carbon atoms and 2 to 10 hydroxyl groups, and mixtures thereof.

[0038] <Silicone> Suitable silicones can be selected from the following group: Acrylate / Behenyl, Acrylate / Dimethicone Methacrylate Copolymer, Acrylate / Behenyl Methacrylate / Dimethicone Methacrylate Copolymer, Acrylate / Bis-Hydroxypropyl Dimethicone Crosspolymer, Acrylates / Dimethicone Copolymer, Acrylates / Dimethicone Methacrylate / Ethylhexyl Acrylate Copolymer, Acrylates / Dimethiconol Acrylate Copolymer, Acrylates / Ethylhexyl Acrylate / Dimethicone Methacrylate Copolymer, Acrylates / Octylacrylamide / Diphenyl amodimethicone copolymer, acrylates / polytrimethylsiloxymethacrylate copolymer, acrylates / propyltrimethicone methacrylate copolymer, acrylates / stearyl acrylate / dimethicone methacrylate copolymer, acrylates / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate copolymer, acrylates / trifluoropropyl methacrylate / polytrimethylsiloxymethacrylate copolymer, aminobispropyl dimethicone, aminoethylaminopropyl Ropyl Dimethicone, Aminopropyl Dimethicone, Aminopropyl Phenylen Trimethicone, Aminopropyl Triethoxysilane, Dimethicone PEG-7 Ammonium Sulfate, Amodimethicone, Amodimethicone Hydroxystearate, Amodimethicone / Silsesquioxane Copolymer, Ascorbyl Carboxydecyl Trisiloxane, Ascorbyl Methylsilanol Pectin, Behenoxy Dimethicone, Behentrimonium Dimethicone Phthalate PEG-8, Behenyl Dimethicone, Bis-AminoPEG / PPG-41 / 3 Aminoethyl PG-Propyl Dimethicone Bis-aminopropyl / ethoxyaminopropyl dimethicone, bis(butylbenzoate)diaminotriazineaminopropyltrisiloxane, bis-butyldimethicone polyglyceryl-3, bis-butyloxyamodimethicone / PEG-60 copolymer, bis(C13-15 alkoxy)hydroxybutamide amodimethicone, bis(C13-15 alkoxy)PG-amodimethicone, bis-(C1-8 alkyllauroyllysinedecylcarboxamide)dimethicone, bis-cetylcetyldimethicone, bis-cetyl / PEG-8 cetylPEG-8 dimethicone,Bis-diphenylethyldisiloxane, bis-ethylethylmethicone, bis-gluconamideethylaminopropyldimethicone, bis-hydrogendimethicone, bis-hydroxyethoxypropyldimethicone, bis-hydroxylauryl, dimethicone / IPDI copolymer, bis-hydroxy / methoxyamodimethicone, bis-hydroxypropyldimethicone behenic acid, bis-hydroxypropyldimethicone / SMDI copolymer, bis-isobutyl PEG-14 / amodimethicone copolymer, bis-isobutyl PEG-15 / amodimethicone copolymer, bis-isobutyl PEG / PPG-20 / 35 / amodimethicone copolymer, bis-isobutyl PEG / PPG-10 / 7 / dimethicone copolymer, bis-isobutyl PEG-24 / PPG-7 / dimethicone copolymer, bis-PEG-1 dimethicone, bis-PEG-4 dimethicone, bis-PEG-8 dimethicone, bis-PEG-12 dimethicone, bis-PEG-20 dimethicone, bis-PEG-12 dimethicone beeswax, bis-PEG-12 dimethicone candyllylate, bis-PEG-15 dimethicone / IPDI copolymer, bis-PEG-15 methyl ether dimethicone, bis- PEG-18 Methyl Ether Dimethyl Silane, Bis-PEG / PPG-14 / 14 Dimethicone, Bis-PEG / PPG-15 / 5 Dimethicone, Bis-PEG / PPG-18 / 6 Dimethicone, Bis-PEG / PPG-20 / 20 Dimethicone, Bis-PEG / PPG-16 / 16 Dimethicone, Bis-PEG / PPG-20 / 5 Dimethicone, Bis-Phenylenhexamethicone, Bis-Phenylenpropyl Dimethicone, Bis-Polyethylene Dimethicone, Bis-(Polyglyceryl-3 Oxyphenylpropyl) Dimethicone Dimethicone, Bis-(Polyglyceryl-7 Oxyphenylpropyl) Dimethicone, Bis-PPG-15 Dimethicone / IPDI Copolymer, Bis-(PPG-7 Undeceneth-21) Dimethicone, Bis-Stearyl Dimethicone, Bis-Trimethoxysilylethyl Tetramethyl Disiloxyethyl Dimethicone, Bis-Vinyl Dimethicone, Bis-Vinyl Dimethicone / Dimethicone Copolymer, Borage Seed Oil PEG-7 Dimethicone Ester, Butyl Acrylate / C6-14 Perfluoroalkyl Ethyl Acrylate / Mercaptopropyl Dimethicone Copolymer,Butyl acrylate / hydroxypropyl dimethicone acrylate copolymer, butyl dimethicone acrylate / cyclohexyl methacrylate / ethylhexyl acrylate copolymer, butyl dimethicone methacrylate / methyl methacrylate crosspolymer, t-butyldimethylciacin vine seed extract, butyl polydimethylsiloxyethylene / propylene / vinyl norbornene copolymer, C6-8 alkyl C3-6 alkyl glucoside dimethicone, C20-24 alkyl dimethicone, C24-28 alkyl dimethicone, C26-28 alkyl Dimethicone, C30-45 alkyl dimethicone, C30-60 alkyl dimethicone, C32 alkyl dimethicone, C30-45 alkyl dimethicone / polycyclohexene oxide crosspolymer, C26-28 alkyldimethylsilyl polypropylsilsesquioxane, C30-45 alkyldimethylsilyl polypropylsilsesquioxane, C20-24 alkyl methicone, C24-28 alkyl methicone, C26-28 alkyl methicone, C30-45 alkyl methicone, C20-28 alkyl perfluorodecyl ethoxydimethicone, C26-54 Alkyltetradecyldimethicone, Capryldimethicone, Capryldimethicone ethoxyglucoside, Caprylylmethicone, Caprylyltrimethicone, Carboxydecyltrisiloxane, Castor oil bishydroxypropyl dimethicone ester cerotyldimethicone, Cetearyldimethicone crosspolymer, Cetearyldimethicone / vinyldimethicone crosspolymer, Cetearylmethicone, Cetrimonium carboxydecyl PEG-8 dimethicone, Cetrimonium dimethicone PEG-7 phthalate, Cetylbehenyldimethicone, Cetyldimethicone, Cetyldimethicone Cetyl / bis-vinyl dimethicone crosspolymer, cetyl hexacosyl dimethicone, cetyl oxy dimethicone, cetyl PEG-8 dimethicone, cetyl PEG / PPG-15 / 15 butyl ether dimethicone, cetyl PEG / PPG-7 / 3 dimethicone, cetyl PEG / PPG-10 / 1 dimethicone, cetyltriethylmonium dimethicone PEG-8 phthalate, cetyltriethylmonium dimethicone PEG-8 succinate, copper acetyltyrosine methylsilanol, copper PCA methylsilanol, C4-14 perfluoroalkyl ethoxydimethicone,Cycloethoxymethicone, cycloheptasiloxane, cyclohexasiloxane, cyclomethicone, cyclopentasiloxane, cyclophenylmethicone, cyclotetrasiloxane, m-cyclovinylmethicone, cystine bis-PG-propylsilanetriol, DEAPG-propylPEG / PPG-18 / 21 dimethicone, diisostearoyl trimethylolpropanesiloxysilicate, dilauroyl trimethylolpropanesiloxysilicate, dilinolamidopropyl dimethylamine, dimethicone PEG-7 phosphate, dimethicone, dimethicone crosspolymer -, Dimethicone Crosspolymer-3, Dimethicone / Divinyldimethicone / Silsesquioxane Crosspolymer, Dimethicone Ethoxyglucoside, Dimethicone Hydroxypropyltrimonium Chloride, Dimethicone / Mercaptopropyl Methicone Copolymer, Dimethicone PEG-15 Acetate, Dimethicone PEG-8 Adipate, Dimethicone PEG-7 Avocadoate, Dimethicone PEG-8 Avocadoate, Dimethicone PEG-8 Beeswax, Dimethicone PEG-8 Benzoate, Dimethicone PEG-8 Boragiate, Dimethicone PEG-7 Cocoate, Dimethicone / PEG-10 Crosspolymer, Dimethicone / PEG-10 / 15 Crosspolymer, Dimethicone / PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG-8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG-8 Lanolate, Dimethicone PEG-8 Laurate, Dimethicone PEG-8 Meadowfoamate, Dimethicone PEG-7 Octyldodecyl Ethanol, Dimethicone PEG-7 Oliveate, Dimethicone PEG-8 Oliveate, Dimethicone PEG-7 Phosphate, Dimethicone PEG-7 G-8 phosphate, dimethicone PEG-10 phosphate, dimethicone PEG-7 phthalate, dimethicone PEG-8 phthalate, dimethicone PEG-8 polyacrylate, dimethicone PEG / PPG-20 / 23 benzoate, dimethicone PEG / PPG-7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone PEG-7 succinate, dimethicone PEG-8 succinate, dimethicone PEG-7 sulfate, dimethicone PEG-7 non-decylenate, dimethicone PG-diethylmonium chloride, dimethicone / phenylvinyl dimethicone crosspolymer,Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone / PPG-20 Crosspolymer, Dimethicone Propyl Ethylenediamine Behenate, Dimethicone Propyl PG Betaine, Dimethicone / Silsesquioxane Copolymer, Dimethicone Silylate, Dimethicone / Vinyl Dimethicone Crosspolymer, Dimethicone / Vinyl Trimethylsiloxysilicate Crosspolymer, Dimethiconol, Dimethiconol Arginine, Dimethiconol Beeswax, Dimethiconol Behenate, Dimethylconol Boragiate, Dimethiconol Candelillalate, Dimethiconol Cal Nabatate, Dimethiconol Cysteine, Dimethiconol Dupa Butterate, Dimethiconol Fluoroalcohol Dilinoleate, Dimethiconol Hydroxystearate, Dimethiconol Lip Butterate, Dimethiconol / IPDI Copolymer, Dimethiconol Isostearate, Dimethiconol Cocum Butterate, Dimethiconol Lactate, Dimethiconol Meadowfoamate, Dimethiconol Methionine, Dimethiconol / Methylsilanol / Silicate Crosspolymer, Dimethiconol Moiré Butterate, Dimethiconol Panthenol, Dimethiconol Dimethiconol / silica crosspolymer, dimethiconol / silsesquioxane copolymer, dimethiconol stearate, dimethiconol / stearyl, methicone / phenyl trimethicone copolymer, dimethoxysilylethylenediaminopropyl dimethicone, dimethylaminopropylamide PCA dimethicone, dimethyloxobenzodioxasilane, dimethylsilanol hyaluronic acid, dioleyl tocopheryl methylsilanol, diphenylamodimethicone, diphenyldimethicone, diphenyldimethicone crosspolymer, di Phenyldimethicone / Inyldiphenyldimethicone / Silsesquioxane Crosspolymer, Diphenylethylbenzyloxydisiloxane, Diphenylisopropyldimethicone, Diphenylsiloxyphenyl / Propyltrimethicone, DiphenylsiloxyphenyltrimethiconeDisiloxane, Amodimethicone Disodium Disodium Disuccinate, PEG-12 Dimethicone Sulfosuccinate Disodium, PEG-8 Lauryldimethicone Sulfosuccinate Disodium, Divinyldimethicone / Dimethicone Copolymer, Divinyldimethicone / Dimethicone Crosspolymer,Drometrizole trisiloxane, ethylhexyl acrylate / VP / dimethicone methacrylate copolymer, ethyl methicone, ethyl trisiloxane, fluoro C2-8 alkyl dimethicone, gluconamidopropyl aminopropyl dimethicone, 4-(2-β-glucopyranosiloxy)propoxy-2-hydroxybenzophenone, , Lyceryl undecyl dimethicone, glycidoxy dimethicone, hexadecyl methicone, hexyl dimethicone, hexyl methicone, hexyl trimethoxysilane hydrogen dimethicone, hydrogen dimethicone / octyl silsesquioxane copolymer, hydrolyzed collagen PG-propyl dimethiconol, hydrolyzed collagen PG-propylmethylsilanediol, hydrolyzed collagen PG-propylsilanetriol, hydrolyzed keratin PG-propylmethylsilanediol, hydrolyzed sesame protein PG-propylmethylsilanediol, hydrolyzed silk PG-propyl Ropropylmethylsilanediol, hydrolyzed silk PG-propylmethylsilanediol crosspolymer, hydrolyzed soy protein / dimethicone PEG-7 acetate, hydrolyzed soy protein PG-propylmethylsilanediol, hydrolyzed vegetable protein PG-propylsilanetriol, hydrolyzed wheat protein / cystine bis-PG-propylsilanetriol copolymer, hydrolyzed wheat protein / dimethicone PEG-7 acetate, hydrolyzed wheat protein / dimethicone PEG-7 phosphate copolymer, hydrolyzed wheat protein PG-propylmethylsilanediol, hydrolyzed wheat protein PG-propylsilanetriol, hydroxyethylacetone PG-dimethicone, hydroxypropyl dimethicone, hydroxypropyl dimethicone behenate, hydroxypropyl dimethicone isostearate, hydroxypropyl dimethicone stearate, isobutyl methacrylate / bis-hydroxypropyl dimethicone acrylate copolymer, isobutyl methacrylate / trifluoroethyl methacrylate / bis-hydroxypropyl dimethicone acrylate copolymer, trimethoxy Isopentyl trisiloxane cinnamate, isopolyglyceryl-3 dimethicone, isopolyglyceryl-3 dimethiconol, isopropyl titanium (triisostearate / triethoxysilylethyl), polydimethylsiloxyethyl dimethicone crosspolymer, isostearyl carboxydecyl PEG-8 dimethicone, lactolyl methylsilanol elastic acid, lauryl dimethicone, lauryl dimethicone PEG-15 crosspolymer, lauryl dimethicone PEG-10 phosphate, lauryl dimethicone / polyglycerin-3 crosspolymer, lauryl methicone,Lauryl PEG-8 Dimethicone, Lauryl PEG-10 Methyl Ether Dimethicone, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Lauryl PEG / PPG-18 / 18 Methicone, Lauryl Phenylenisopropyl Methicone, Lauryl Phenylenpropyl Methicone, Lauryl Polydimethylsiloxyethyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Trimethicone, Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone, Methacryloyl Propylene Glycol Pyltrimethoxysilane, methicone, methoxyamodimethicone / silsesquioxane copolymer, methoxycinnamidopropyl polysilsesquioxane, methoxycinnamoylpropyl silsesquioxane, methoxyPEG-13 ethyl polysilsesquioxane, methoxyPEG / PPG-7 / 3 aminopropyl dimethicone, methoxyPEG / PPG-25 / 4 dimethicone, methoxyPEG-10 propyltrimethoxysilane, methylurenyl PEG-8 dimethicone, methylpolysiloxane emulsion, methylsilanol acetylmethionate, methyl sil Lanol ​​acetyltyrosine, methylsilanol ascorbate, methylsilanol carboxymethyl theophylline, methylsilanol carboxymethyl theophylline alginate, methylsilanol elastinate, methylsilanol glycyrrhizinate, methylsilanol hydroxyproline, methylsilanol hydroxyproline aspartate, methylsilanol mannuronate, methylsilanol PCA, methylsilanol PEG-7 glyceryl cocoate, methylsilanol / silicate crosspolymer, methylsilanol spiral phosphate, Tri-PEG-8 Glyceryl Cocoate, Methyl Trimethicone, Methyl Trimethoxysilane, PEG-7 Myristylamidopropyl Dimethicone Phosphate, Myristyl Methicone, Myristyl Trisiloxane, Nylon-611 / Dimethicone Copolymer, PCA Dimethicone, PEG-7 Amodimethicone, PEG-8 Amodimethicone, PEG-8 Cetyl Dimethicone, PEG-3 Dimethicone, PEG-6 Dimethicone, PEG-7 Dimethicone, PEG-8 Dimethicone, PEG-9 Dimethicone, PEG-10 Dimethicone, PEG-12 Dimethicone, PEG-14 Dimethicone,PEG-17 Dimethicone, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoleate, PEG-8 Dimethicone / Dimer Dilinoleate Copolymer, PEG-10 Dimethicone / Vinyl Dimethicone Crosspolymer, PEG-8 Disteaammonium Chloride PG-Dimethicone, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, PEG-8 Methicone, PEG-6 Methicone Acetate, PEG-6 Methyl Ether Dimethicone, PEG-7 Methyl Ether Dimethicone, PEG-8 Methyl Ether Dimethicone, PEG-9 Methyl Ether Dimethicone, PEG-10 Methyl Ether Dimethicone, PEG-11 Methyl Ether Dimethicone, PEG-32 Methyl Ether Dimethicone, PEG-8 Methyl Ether Triethoxysilane, PEG-10 Nonafluorohexyl Dimethicone Copolymer, PEG-4 PEG-12 Dimethicone, PEG-8 PG-Coco-Glucoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone Dimethicone, PEG / PPG-20 / 22 Butyl Ether Dimethicone, PEG / PPG-22 / 22 Butyl Ether Dimethicone, PEG / PPG-23 / 23 Butyl Ether Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-27 / 9 Butyl Ether Dimethicone, PEG / PPG-3 / 10 Dimethicone, PEG / PPG-4 / 12 Dimethicone, PEG / PPG-6 / 4 Dimethicone, PEG / PPG-6 / 11 Dimethicone, PEG / PPG-8 / 14 Dimethicone, PEG / PPG-8 / 26 Dimethicone, PEG / PPG-1 0 / 2 Dimethicone, PEG / PPG-12 / 16 Dimethicone, PEG / PPG-12 / 18 Dimethicone, PEG / PPG-14 / 4 Dimethicone, PEG / PPG-15 / 5 Dimethicone, PEG / PPG-15 / 15 Dimethicone, PEG / PPG-16 / 2 Dimethicone, PEG / PPG-16 / 8 Dimethicone, PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 6 Dimethicone, PEG / PPG-18 / 12 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG / PPG-20 / 6 Dimethicone,PEG / PPG-20 / 15 Dimethicone, PEG / PPG-20 / 20 Dimethicone, PEG / PPG-20 / 23 Dimethicone, PEG / PPG-20 / 29 Dimethicone, PEG / PPG-22 / 23 Dimethicone, PEG / PPG-22 / 24 Dimethicone, PEG / PPG-23 / 6 Dimethicone, PEG / PPG-25 / 25 Dimethicone, PEG / PPG-27 / 27 Dimethicone, PEG / PPG-30 / 10 Dimethicone, PEG / PPG-25 / 25 Dimethicone / Acrylate Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG / PPG-24 / 24 Methyl Ether Glycidoxy Dimethicone, PEG / PPG-10 / 3 Oleyl Ether Dimethicone, PEG / PPG-5 / 3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorocaprylyliethoxysilyl Methicone, Perfluorononyl Dimethicone, Perfluorononyl Dimethicone / Methicone / Amodimethicone Crosspolymer, Perfluorononyl Ethyl carboxydecylbehenyl dimethicone, perfluorononylethyl carboxydecylhexacosyl dimethicone, perfluorononylethyl carboxydecyl lauryl / behenyl dimethicone, perfluorononylethyl carboxydecyl lauryl dimethicone, perfluorononylethyl carboxydecyl PEG-8 dimethicone, perfluorononylethyl carboxydecyl PEG-10 dimethicone, perfluorononylethyl dimethicone / methicone copolymer, perfluorononylethyl PEG-8 dimethicone, perfluorononylethyl stearyl Dimethicone, perfluorooctyl ethyl / diphenyl dimethicone copolymer, perfluorooctyl ethyl triethoxysilane, perfluorooctyl ethyl trimethoxysilane, perfluorooctyl trisiloxane, perfluorooctyl triethoxysilane, PG-amodimethicone, phenethyl dimethicone, phenethyl disiloxane, phenyl dimethicone, phenylisopropyl dimethicone, phenyl methicone, phenyl methiconol, phenylpropyl dimethylsiloxysilicate, phenylpropyl ethyl methicone, phenylpropyl trimethicone,Phenylpropyl Trimethicone / Diphenyl Methicone, Phenyl Trimethicone, Platinum Divinyl Disiloxane, Polyacrylate-6, Polydiethylsiloxane, Polydimethylsiloxyethyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Polydimethylsiloxyethyl Dimethicone / Methicone Copolymer, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-3 Disiloxane Dimethicone, Polyglyceryl-3 / Lauryl Polydimethylsiloxyethyl dimethicone crosspolymer, poly-glyceryl-3 polydimethylsiloxyethyl dimethicone, poly(glycol adipate) / bis-hydroxyethoxypropyl dimethicone copolymer, polymethylsilsesquioxane, polymethylsilsesquioxane / trimethylsiloxysilicate, polyphenylsilsesquioxane, polypropylsilsesquioxane, polysilicone-1, polysilicone-2, polysilicone-3, polysilicone-4, polysilicone-5, polysilicone-6, polysilicone-7, polysilicone Polysilicone-8, Polysilicone-9, Polysilicone-10, Polysilicone-11, Polysilicone-12, Polysilicone-13, Polysilicone-14, Polysilicone-15, Polysilicone-16, Polysilicone-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysilicone-21, Polysilicone-18 Cetyl Phosphate, Polysilicone-1 Crosspolymer, Polysilicone-18 Stearate, Polyurethane-10, Dimethicone PEG-7 Potassium Panthenyl Phosphate, Dimethicone PEG-7 Potassium Phosphate, PPG-12 Butyl Ether Dimethicone, PPG-2 Dimethicone, PPG-12 Dimethicone, PPG-27 Dimethicone, PPG-4 Olase-10 Dimethicone, Propoxytetramethylpiperidinyl Dimethicone, Propyl Trimethicone, Quaternium-80, Retinoxytrimethylsilane, Silanediol Salicylate, Silanetriol, Silanetriol Arginate, Silanetriol Glutamate, Silanetriol Lysinate, Silanetriol Melaninate, Silanetriol Trehalose Ether, Silica, Silica Dimethicone Silylate,Silica dimethyl silylate, silica silylate, silicon carbide, silicone quaternium-1, silicone quaternium-2, silicone quaternium-2 panthenol succinate, silicone quaternium-3, silicone quaternium-4, silicone quaternium-5, silicone quaternium-6, silicone quaternium- 7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, Silicone Quaternium-16, Silicone Quaternium-16 / Glycidoxydimethicone Crosspolymer, Silicone Quaternium-17, Silicone Quaternium-18, Silicone Quaternium-19, Silicone Quaternium-20, Silicone Quaternium-21, Silicone Quaternium-22, Silicone Quaternium-24 Silicone quaternium-25, siloxanetriol alginate, siloxanetriol phytate, simethicone, carboxydecyl PEG-8 sodium dimethicone, dimethicone PEG-7 sodium acetylmethyl taurate, sodium dimethylsilanol hyaluronate, sodium methylsilanol lacate, sodium methylsilanol mannuronate, sodium methylsilanol PCA, PG-propyl dimethicone sodium thiosulfate copolymer, sodium PG-propyl thiosulfate dimethicone, sodium propoxy Hydroxypropyl thiosulfate silica, sorbitylsilanediol, soybean triethoxysilylpropyldimonium chloride, stearalkonium dimethicone PEG-8 phthalate, S-tetrabutoxypropyl trisiloxane, tetramethylhexaphenyltetrasiloxane, tetramethyltetraphenyltrisiloxane, tocopheryloxypropyl trisiloxane, trideceth-9PG-amodimethicone, triethoxycaprylylsilane, triethoxysilylethyl dimethicone / methicone copolymer, triethoxysilylethyl poly Dimethylsiloxyethyl dimethicone, triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone, triethoxysilylpropyl carbamoylethoxypropyl butyl dimethicone, trifluoromethyl C1-4 alkyl dimethicone, trifluoropropyl cyclopentasiloxane, trifluoropropyl cyclotetrasiloxane, trifluoropropyl dimethicone, trifluoropropyl dimethicone / PEG-10 crosspolymer, trifluoropropyl dimethicone / trifluoropropyl divinyl dimethicone crosspolymer,Trifluoropropyl dimethicone / vinyl trifluoropropyl, dimethicone / silsesquioxane crosspolymer, trifluoropropyl dimethiconol, trifluoropropyl dimethyl / trimethylsiloxysilicate, trifluoropropyl methicone, trimethoxycaprylylsilane, trimethoxysilyl dimethicone, trimethylpentaphenyltrisiloxane, trimethylsiloxyamodimethicone, trimethylsiloxyphenyl dimethicone, trimethylsiloxysilicate, trimethylsiloxysilicate / dimethicone crosspolymer, trimethylsiloxysilicate / dimethicone crosspolymer, trimethylsiloxysilicate / dimethiconol crosspolymer, trimethylsiloxysilyl carbamoyl pullulan, trimethylsilyl hydrolyzed conchiolin protein PG-propylmethylsilanediol crosspolymer, trimethylsilyl hydrolyzed silk PG-propylmethylsilanediol crosspolymer Polymers, trimethylsilyl hydrolyzed wheat protein PG-propylmethylsilanediol crosspolymer, trimethylsilyl pullulan, trimethylsilyl trimethylsiloxyglycolate, trimethylsilyl trimethylsiloxy lactate, trimethylsilyl trimethylsiloxysalicylate, triphenyl trimethicone, trisiloxane, tris-tributoxysiloxymethylsilane, undecyl chrylamide methicone, vinyl dimethicone, vinyl dimethicone / lauryl dimethicone crosspolymer, vinyl dimethicone / methicone silsesquioxane crosspolymer, vinyl dimethyl / stearyl trimethylsiloxysilicate dimethicone crosspolymer, VP / dimethiconyl acrylate / polycarbamyl / polyglycol ester, zinc carboxydecyltrisiloxane, dimethicone PEG-8 zinc succinate, and mixtures thereof.

[0039] More preferably, the silicones to be included in the mixture according to the present invention are dimethicone, cyclomethicone, phenyltrimethicone, cyclohexasiloxane, and cyclopentasiloxane. A detailed overview of suitable volatile silicones can be found in Todd et al., Cosm. Toil. 91, 27 (1976).

[0040] <Waxes and stabilizers> In addition to the natural oils used, waxes may also be present in the preparation. Natural waxes, in particular, include, for example, candelilla wax, carnauba wax, japonica wax, espartograss wax, cork wax, guarma wax, rice oil wax, sugarcane wax, uricury wax, montan wax, beeswax, shellac wax, spermacethi, lanolin (wool wax), uropygan fat, ceresin, ozocerite (earth wax), petrolatum, paraffin wax, and microwax; chemically modified waxes (hard waxes) include, for example, montan ester wax, sazole wax, hydrogenated jojoba wax, and synthetic waxes such as polyalkylene wax and polyethylene glycol wax.

[0041] As stabilizers, metal salts of fatty acids such as magnesium, aluminum, and / or zinc stearate or ricinoleate can be used.

[0042] <Primary sun protection filter> The primary sun protection filter referred to in this invention is, for example, an organic substance (light filter) that is liquid or crystalline at room temperature, absorbs ultraviolet light, and releases the absorbed energy in the form of long-wave radiation, such as heat.

[0043] The product according to the present invention advantageously contains at least one UV-A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic pigment. The product according to the present invention preferably contains at least one UV-B filter or a broadband filter, and more preferably contains at least one UV-A filter and at least one UV-B filter.

[0044] The UV filters cited below, which can be used in the context of the present invention, are preferred but not limited. Preferred UV filters are selected from the group consisting of 1, 2, 3, 4, 5 or more types: [Table 2]

[0045] In a preferred embodiment, the sunscreen filter forming component (II) represents a blend of UV-A and UV-B filters selected from the group consisting of homosalate, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, butyl methoxydibenzoylmethane, ethylhexyl salicylate, and mixtures thereof. Particularly preferred is a blend of all these filters commercially available in NeoHeliopan® Flat (SYMRISE) of WO2020 / 088778A1.

[0046] Suitable pigments include oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g., MnO), aluminum (Al2O3), cerium (e.g., Ce2O3), and / or mixtures thereof.

[0047] In a further preferred embodiment, the product according to the present invention contains a total amount of sunscreen, i.e., particularly UV filters and / or inorganic pigments (UV filter pigments), such that the product according to the present invention has a photoprotection coefficient of 5 to 50. Such a product according to the present invention is particularly suitable for the protection of skin and hair.

[0048] <Secondary sun protection filter> In addition to the primary sun protection factors mentioned above, antioxidant-type secondary sun protection factors can also be used. Antioxidant-type secondary sun protection factors interrupt the photochemical reaction chain that is initiated when ultraviolet rays penetrate the skin. Typical examples include amino acids (e.g., glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g., urocanic acid) and their derivatives, peptides (e.g., D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g., anserine)), carotenoids, carotenes (e.g., α-carotene, β-carotene, lycopene, β-carotene) and their derivatives, chlorogenic acid and its derivatives, liponic acid and its derivatives (e.g., dihydroliponic acid), aurothioglucose, propylthiouracil, and other thiols (thioredoxin, glutathione, cysteine, cystine, cystamine, glycosyl, N-acetyl) Methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, α-linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides and their salts), sulfoximine compounds (e.g., butionine sulfoximine, homocysteine ​​sulfoximine, butionine sulfone, penta-, hexa-, hepta-thionine sulfoximine), (metal) chelating agents (e.g., α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g., citric acid, lactic acid, malic acid), humic acid, bile acids, bile extracts, bilirubin, biliverdin, EDTA, EGTA and its derivatives, unsaturated fatty acids and their derivatives (linoleic acid, oleic acid, etc.), folic acid and its derivatives, ubiquinone, ubiquinol and its derivatives, Vitamin C and its derivatives (ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate, etc.), tocopherol and its derivatives (vitamin E acetate, etc.), vitamin A and its derivatives (vitamin A palmitate), coniferyl benzoate from benzoic resin, rutic acid and its derivatives, glycosylrutin, ferulic acid, furfrillidendene glucitolCarnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiaric acid, nordihydroguaiaretinic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (e.g., dispersion in ethanol), zinc and its derivatives (e.g., ZnO, ZnSO4), selenium and its derivatives (e.g., selenium methionine), stilbene and its derivatives (e.g., stilbene oxide, trans-stilbene oxide), and derivatives of these active substances (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides, and lipids) suitable for the purposes of the present invention.

[0049] Advantageous inorganic secondary photoprotective pigments are finely dispersed metal oxides and metal salts, as described in WO 2005 / 123101A1. The total amount of inorganic pigments, particularly hydrophobic inorganic micropigments, in the finished cosmetic formulation according to the present invention is advantageously 0.1 to 30% by weight, preferably 0.5 to 10.0% by weight, in any case, based on the total weight of the formulation.

[0050] Preferably, particulate UV filters or optionally hydrophobized inorganic pigments can be used, such as oxides and / or mixtures thereof of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g., MnO), aluminum (Al2O3), cerium (e.g., Ce2O3).

[0051] <Biogenic substances and antioxidants> The physiologically active substances include, for example, tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy)ribonucleic acid and its fragment products, β-glucan, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acid, amino acids, ceramide, pseudoceramide, essential oils, plant extracts such as Prunus, bisabolol, allantoin, phytantriol, panthenol, AHA acid, amino acids, ceramide, pseudoceramide, essential oils, plant extracts such as Prunus extract and Bambaranus extract, and vitamin complexes.

[0052] Antioxidants disrupt the photochemical reaction chains triggered when UV radiation penetrates the skin. Typical examples include amino acids (e.g., glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g., urocanic acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g., anserine), carotenoids, carotenes (e.g., 1-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g., dihydrophosphate), aurothioglucose, propylthiouracil and other thiols (e.g., thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl derivatives, N-acetyl, methyl, ethyl, propyl, amyl, Butyl and lauryl, palmitoyl, oleyl, linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, ditearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts), and sulfoximine compounds (e.g., onin sulfoximine, homocysteine ​​sulfoximine, butionine sulfone, penta-, hexa-, heptathionine sulfoximine) in very low tolerance volumes (e.g., from pmol to mol / kg), as well as (metal) chelating agents (e.g., hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), tocopherols and their derivatives (e.g., Vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate), and benzoic acid aryl benzoates of benzoin resin, rutin and its derivatives, glycosylrutin, ferulic acid, furfridenglucitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiacitic acid, nordihydroguaiaretinic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (E.Examples include ZNO, ZnSO4), selenium and its derivatives (e.g., selenium-methionine), stilbene and its derivatives (e.g., styrene oxide, trans-stilbene oxide), and derivatives of these named active substances suitable for the present invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides, and lipids).

[0053] <Active ingredients that regulate hair pigmentation> Preferred active ingredients for lightening hair are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinol and 4-(1-phenylethyl)1,3-dihydroxybenzene (phenylethylresorcinol), cyclohexylcarbamate (preferably one or more cyclohexylcarbamates disclosed in WO2010 / 122178 and WO2010 / 097480), sulfur-containing molecules, preferably glutathione or cysteine, α-hydroxy acids (preferably citric acid, lactic acid, malic acid), their salts and esters, N-acetyltyrosine and derivatives, undecenoylphenylalanine, gluco Niacin acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, tsyaprulinin and its derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably senkyu nolide, vinylguacol, ethylguacol, diionic acid, preferably octodecendionic acid and / or azelaic acid, inhibitors of nitrogen oxide synthesis, preferably L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiocitrulline, metal chelating agents (preferably α-hydroxy fatty acids, phytic acid, humic acid, bile acids, bile extracts, EDTA, EGTA and its derivatives), retinoids, soy milk and extracts, serine protease inhibitors or lipoic acid, or other synthetic or natural active ingredients for lightening skin and hair.The latter is preferably used in the form of plant extracts, preferably bamboo grass extract, rice extract, papaya extract, turmeric extract, mulberry extract, sedum extract, feverfew extract, licorice root extract or components concentrated or isolated therefrom, preferably glabridin or licochalcone A, Altocarpus extract, dock and ramulus extract, pine (pinus) extract, grape extract or stilbene derivatives isolated or concentrated therefrom, saxifrage extract, scutellaria extract, grape extract and / or microalgae extract, especially Tetracermis suesica extract.

[0054] In this regard, effective ingredients for treating sunburn on skin and hair include tyrosinase substrates or substrate analogs, such as L-tyrosine, N-acetyltyrosine, L-DOPA, or L-dihydroxyphenylalanine; xanthine alkaloids, such as caffeine, theobromine, and theophylline and their derivatives; proopiomelanocortin peptides, such as ACTH, α-MSH and its peptide analogs, and other substances that bind to melanocortin receptors; peptides such as VAL-GLY-VAL-ALA-PRO-GLY, LYS-LLE-GLY-ARG-LYS, or LEU-LLE-GLY-LYS; purines; pyrimidines; folic acid; copper salts, such as copper gluconate, copper chloride, or copper pyrrolidone; 1,3,4-oxadiazole-2-thiol, such as 5-pyrazine-2-yl-1,3,4-oxadiazole-2-thiol; curcumin; and zinc diglycinate (Zn (Gly)2), for example, manganese(II) bicarbonate complexes ("pseudocatalases") described in EP0584178, for example, tetrasubstituted cyclohexene derivatives described in WO2005 / 032501, isoprenoids described in WO2005 / 102252 and WO2006 / 010661, melanin derivatives such as MELASYN-100 and MELANZE, diacylglycerols, aliphatic or cyclic diols, psoralens, prostaglandins and their analogues, adenylate cyclase activators, and compounds that activate the transfer of melanosomes to keratinocytes, such as serine, PAR-2 ​​receptor proteases or agonists, extracts of plants and plant parts of the genera Chrysanthemum and Sanguisorba, walnut extracts, Urukum extracts, rhubarb extracts, microalgae extracts, especially Isochrysis galbana, trehalose, erythrulose and dihydroxyacetone. Flavonoids that cause skin and hair discoloration or browning (e.g., quercetin, rhamnetin, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosmin and diosmetine, morin, quercitrin, naringenin, hesperidin, phlorizin and phloretin) may also be used.

[0055] Next, the amount of additional active ingredients (one or more compounds) for regulating skin and hair pigmentation in the products according to the present invention, as in the above examples, is preferably 0.00001 to 30% by weight, preferably 0.0001 to 20% by weight, and particularly preferably 0.001 to 5% by weight, based on the total weight of the preparation.

[0056] <Hair growth activators or inhibitors> The products and by-products of the invention may also contain one or more hair growth activators, i.e., agents that stimulate hair growth. The hair growth activators are preferably selected from the group consisting of pyrimidine derivatives such as 2,4-diaminopyrimidine-3-oxide (Aminexil), 2,4-diamino-6-piperidinopyrimidine-3-oxide (Minoxidil) and derivatives thereof, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and its derivatives, xanthine alkaloids such as caffeine, theobromine, and theophylline and their derivatives, quercetin and its derivatives, Dihydroquercetin (taxifolin) and its derivatives, potassium channel openers, antiandrogens, synthetic or natural 5-reductase inhibitors, nicotinic acid esters such as tocopherol nicotinate, benzyl nicotinate, and C1-C6 alkyl nicotinates, proteins such as tripeptide Lys-Pro-Val, diphencyprene, hormones, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, diuretics such as cyproterone acetate and spironolactone, calcineurin inhibitors such as FK506 (tacrolimus, fujimacin) and its derivatives, cyclosporine A and its derivatives, zinc and zinc salts, polyphenols, procyanidins, proanthocyanidins Extracts from plants and plant parts such as β-sitosterol, biotin, eugenol, (±)-β-citronellol, panthenol, glycogen derived from mussels, microorganisms, algae, plants, and plants such as dandelions (Taraxacum leontodon or dandelion), orthosiphon, Vitex, coffee plant, Paulinia, Theobroma, Asiasalum, pumpkin or Stifnorobium, saw palmetto, Sophora flavecens, Pydium africanum, millet, Simisifuga racemosa, soybean, Eugenia caryophyllata, Cotinus cogulia, hibiscus, tea, yew, Isochrysis galbana, licorice, grape, apple, barley or hops, or / or hydrolysates from rice or wheat.

[0057] Alternatively, the product and supplies may contain one or more hair growth inhibitors (as described above), i.e., agents that reduce or prevent hair growth. The hair growth inhibitors are preferably activin, activin derivatives or activin agonists, ornithine decarboxylase inhibitors, such as α-difluoromethylornithine or pentacyclic triterpenes, such as ursolic acid, betulin, betulinic acid, oleanolic acid and its derivatives, 5α-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, gamma-glutamyl transpeptidase inhibitors, transglutaminase inhibitors, soy-derived serine protease inhibitors, such as those belonging to the genera Chondrus, Gloiopeltis, Ceramium, Durvillea, Glycine max, Sanguisorba officinalis, Calendula officinalis, Hamamelis virginiana, Arnica montana, Salix alba, Hypericum perforatum or Gymnema, from the legume, nightshade, grass, milkweed, or cucurbitaceae families. It is an extract from microorganisms of the genus Sylvestre, algae, various microalgae, or plants and plant parts.

[0058] <Physiological coolants and warmers> Physiological coolants are preferably selected from the group formed by the species (including their optical isomers and racemates) described in the table below: [Table 3]

[0059] Physiological warming agents can be selected from the group consisting of capsaicin, dihydrocapsaicin, nordihydrocapsaicin, homocapsaicin, homodihydrocapsaicin nonibamide, and chili pepper extract.

[0060] <Anti-inflammatory drugs> Suitable anti-inflammatory agents can be selected from the group formed by the following: (i) Corticosteroid-type steroidal anti-inflammatory substances, especially hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone, (ii) Nonsteroidal anti-inflammatory substances, especially oxicams such as piroxicam and tenoxicam, salicylates such as aspirin, disalside, sorprine, and fendosal, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin, and clindanac, fenamate salts such as mefenum, meclofenum, flufenum, and niflumin, propionic acid derivatives such as ibufenum, flufenum, and niflumin, acetic acid derivatives such as tolmetin and clindanac, fenamic acid derivatives such as mefenum, meclofenum, flufenum, and niflumin, propionic acid derivatives such as ibuprofen, naproxen, and benoxaprofen, pyrazoles such as phenylbutazone, oxyphenylbutazone, febrazone, and azapropazone, (iii) Natural or naturally occurring anti-inflammatory substances, or substances that relieve redness and / or itching, especially extracts or fractions from chamomile, aloe vera, Commiphora species, Rubia species, willow, willow herb, oat, calendula, arnica, St. John's wort, honeysuckle, rosemary, Passiflora incarnata, witch hazel, ginger or echinacea, or single active compounds thereof. (iv) Histamine receptor antagonists, serine protease inhibitors (e.g., soy extract), TRPV1 antagonists (e.g., 4-t-butylcyclohexanol), NK1 antagonists (e.g., aprepitant, hydroxyphenylpropamide benzoate), cannabinoid receptor agonists (e.g., palmitoylethanolamine), and TRPV3 antagonists.

[0061] <Antimicrobial agents> Suitable antimicrobial agents are, in principle, all substances effective against Gram-positive bacteria, such as 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether (triclosan), 4-chloro-3,5-dimethylphenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy)-1,2-propanediol, 3-iodo-2-propynylbutylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antimicrobial fragrances, thymol, thyme oil, eugenol, clove oil, menthol, mint oil, farnesol, These include phenoxyethanol, glycerol monocaprate, glycerol monocaprylate, glycerol monolaurate (GML), diglycerol monocaprate (DMC), and salicylic acid N-alkylamide, such as n-octylsalicylamide or n-decylsalicylamide.

[0062] <Enzyme inhibitors> Suitable enzyme inhibitors are, for example, esterase inhibitors. These are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate, and especially triethyl citrate (Hydagen CAT). These substances inhibit enzyme activity and suppress odor generation. Other suitable esterase inhibitors include sulfates or phosphates of sterols, such as lanosterol, cholesterol, campesterol, stigmasterol, and sitosterol sulfates or phosphates; dicarboxylic acids and their esters, such as glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid, diethyl malonate, and other dicarboxylic acids and their esters; hydroxycarboxylic acids and their esters, such as citric acid, malic acid, tartaric acid, and diethyl tartrate; and zinc glycinate.

[0063] <Odor Absorbent and Antiperspirant Activator> Suitable odor absorbers are substances that can absorb and retain most odor-forming compounds. These reduce the partial pressure of individual components and decrease their diffusion rate. It is important that the fragrance is not damaged in this process. Odor absorbers are ineffective against bacteria. These consist, for example, as the main component, a complex zinc salt of ricinoleic acid, or a specific, mostly odorless fragrance known to those skilled in the art as a "fixative," such as an extract of labdanum or styrax, or a specific abietic acid derivative. Odor masking agents are fragrances or perfume oils that, in addition to their function as odor maskers, impart their respective fragrance notes to the deodorant. Perfume oils are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracted from flowers, stems, leaves, fruits, peels, roots, trees, herbs, grasses, needles, branches, resins, and balsams. Animal products such as civet and castoreum are also suitable. Typical synthetic fragrance compounds include esters, ethers, aldehydes, ketones, alcohols, and hydrocarbone-type products. Examples of ester-type fragrance compounds include benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styryl propionate, and benzyl salicylate. Examples of ethers include benzyl ethyl ether, and examples of aldehydes include linear alcanals with 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, lilial, and brugsonal. Examples of ketones include ionones and methyl cedyl ketone; examples of alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linaol, phenylethyl alcohol, and terpineol; and examples of hydrocarbons include mainly terpenes and balsams. However, it is preferable to use a mixture of different fragrances that produces a pleasant fragrance note.Essential oils with relatively low volatility are mainly used as aromatherapy components, but are also suitable as perfumed oils. Examples include sage oil, chamomile oil, clove oil, melissa oil, mint oil, cinnamon leaf oil, linden flower oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil, and lavandin oil. It is preferable to use bergamot oil, dihydromyrcenol, lilial, liral, citronellol, phenylethyl alcohol, α-hexyl cinnamaldehyde, geraniol, benzylacetone, cyclamenaldehyde, linalool, boissan blenforte, ambroxan, indole, hedione, sandelice, lemon oil, mandarin oil, orange oil, allylamyl glycolic acid, cyclobeltal, lavandin oil, clary sage oil, β-damascone, bourbon geranium oil, cyclohexyl salicylic acid, Beltfix cool, Iso-E-super, Fixolid NP, Evernyl, iraldine gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, ilotyl, and floramato individually or in combination.

[0064] Suitable astringent antiperspirant active ingredients are primarily salts of aluminum, zirconium, or zinc. Such suitable antiperspirant active ingredients include, for example, aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesquichlorohydrate, and complex compounds thereof with, for example, 1,2-propylene glycol, aluminum hydroxyallantoinate, aluminum tartrate chloride, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate, and complex compounds thereof with, for example, amino acids such as glycine.

[0065] <Film-forming agent and dandruff inhibitor> Standard film-forming agents include, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, acrylic acid series polymers, quaternized cellulose derivatives, collagen, hyaluronic acid and their salts, and similar compounds.

[0066] Suitable anti-dandruff agents include piroctone olamine (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), Baypival (trademark) (Crinbazole), Ketoconazol (trademark) (4-acetyl-1-{4-[2-(2,4-dichlorophenyl)R-2-(1H-imidazole-1-ylmethyl)-1,3-dioxirane-C-4-ylmethoxyphenyl}-piperazine, ketoconazole, erbiol, selenium disulfide, colloidal sulfur, The ingredients are sulfur polyethylene glycol sorbitan monooleate, sulfur ricinol polyethoxylate, sulfur tar distillate, salicylic acid (or in combination with hexachlorophene), undecylenic acid, monoethanolamide sulfosuccinate sodium salt, Lamepon® UD (protein / undecylenic acid condensate), zinc pyrithione, aluminum pyrithione, and pyrithione / dipyrithione magnesium sulfate.

[0067] <Carriers and Hydrotropes> Preferred cosmetic carrier materials are solid or liquid (including highly viscous substances) at 25°C and 10¹³ mbar, such as glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water, and mixtures of two or more of the above liquid carrier materials with water. Optionally, these preparations according to the present invention may be prepared using preservatives or solubilizers. Other preferred liquid carrier substances that may be components of the preparations according to the present invention are selected from the group consisting of oils such as vegetable oils, neutral oils, and mineral oils.

[0068] Preferred solid carrier materials that can be components of the formulation according to the present invention include starch, hydrolyzed starch, chemically or physically modified starch, dextrin, (powdered) maltodextrin (preferably with a dextrose equivalent value of 5 to 25, preferably 10 to 20), lactose, silicon dioxide, glucose, modified cellulose, acacia gum, ghati gum, tragacanth, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, carob flour, alginate, agar, pectin and inulin, and mixtures of two or more of these solids, particularly hydrophilic colloids such as maltodextrin (preferably with a dextrose equivalent value of 15 to 20), lactose, silicon dioxide and / or glucose.

[0069] Furthermore, hydrotropes, such as ethanol, isopropyl alcohol, or polyols, can be used to improve the flow behavior. Preferred polyols preferably contain 2 to 15 carbon atoms and at least 2 hydroxyl groups. The polyol may also contain other functional groups, particularly amino groups, or may be modified with nitrogen. Typical examples are as follows: - Glycerol; - Alkylene glycols with an average molecular weight of 100 to 1000 daltons, such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol, and polyethylene glycol; - In particular, methylol compounds such as trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol, and dipentaerythritol; - Lower alkyl glucosides, particularly those containing 1 to 8 carbon atoms in the alkyl group, such as methyl glucoside and butyl glucoside; - Sugar alcohols containing 5 to 12 carbon atoms, such as sorbitol and mannitol; - Sugars containing 5 to 12 carbon atoms, such as glucose and sucrose; - Amino sugars, such as glucamine; - Dialcoholamines, such as diethanolamine or 2-aminopropane-1,3-diol.

[0070] <Preservatives and / or product protectants> Appropriate preservatives are listed in Parts A and B of Annex 6 of the Kosmetikver-ordnung ("Cosmetics Directive").

[0071] Suitable species may be selected from the group consisting of preservatives selected from the group consisting of the following: Benzoic acid and parahydroxybenzoic acid, their esters and salts, benzyl benzoate, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienic acid (sorbic acid) and its salts, levulinic acid and its salts, anisic acid and its salts, perillic acid and its salts, cinnamic acid and its salts, formaldehyde and paraformaldehyde, 4-hydroxybenzaldehyde, ortho-, meta- and para-anisaldehyde, cinnamaldehyde, cinnamon alcohol, 2-hydroxybiphenyl ether and its salts, 2-zinc sulfidopyridine-N-oxide, inorganic sulfites and bisulfites, sodium iodate, Chlorobutanorm, 4-ethylmercury-(II)5-amino-1,3-bis(2-hydroxybenzoic acid), its salts and esters, dehydrated acetic acid, formic acid, 1,6-bis(4-amidino-2-bromophenoxy)-N-hexane and its salts, sodium salt of ethylmercury-(II)-thiosalicylic acid, phenylmercury and its salts, 10-undecylenic acid and its salts, 5-amino-1,3-bis(2-ethylhexyl)-5-methyl-hexahydropyrimidine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3-propanediol, 2,4-Dichlorobenzyl alcohol, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)-urea, 4-chloro-M-cresol, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether, 4-chloro-3,5-dimethylphenol, 1,1'-methylene-bis(3-(1-hydroxymethyl-2,4-dioxyimidazolidine-5-yl)urea), poly-(hexamethylenediguanide) hydrochloride, (benzyloxymethoxy)-methanolhexamethylenetetramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azonia-adamantan chloride, 1-(4-chlorophenoxy)-1-(1H-imidazole-1-yl)-3,3-dimethyl-2-butanone, 1,3-bis-(hydroxymethyl)-5,5-dimethyl-2, 4-Imidazolidinedione, 1,2-dibromo-2,4-dicyanovutane, 2,A mixture of 2'-methylene-bis(6-bromo-4-chlorophenol), bromochlorophene, and 5-chloro-2-methyl-3(2H)-isothiazolinone, a mixture of 2-methyl-3(2H)-isothiazolinone with magnesium chloride and magnesium nitrate, 2-octyl-2H-isothiazol-3-one, 1,2-benzisothiazol-3(2H)-one, 2-benzyl-4-chlorophenol, 3-(4-chlorphenoxy)-1,2-propanediol (chlorphenesin), 2-chloroacetamide, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, N-alkyl(C12-C22)trimethylammonium bromide and chloride, 4,4-dimethyl-1,3-oxazolidine, N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5-dioxoimidazolidine-4-yl)-N'-hydroxymethylurea, 1,6-bis(4-amidino-phenoxy)-N-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, 3-(4-chlorophenoxy)-1,2-propanediol, hyamine, alkyl-(C8-C18)-dimethylbenzylammonium chloride, alkyl- (C8-C18)-dimethylbenzylammonium bromide, alkyl-(C8-C18)-dimethylbenzylammonium saccharinate, benzylhemiformal, 3-iodo-2-propynylbutylcarbamate, sodium hydroxymethylaminoacetate or sodium hydroxymethylaminoacetate, imidazolidinyl urea, diazolidinyl urea, sodium hydroxymethylglycinate, DMDM ​​hydantoin, tropolone, (ethylenedioxy)dimethanol, 2-Brome-2-(bromomethyl)pentanedinitrile, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, α,α',α"-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol, pyridine-2-thiol-1-oxide, sodium salt, tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo[4,5-D]imidazole-2,5(1H,3H)-dione, 1,3-bis(hydroxymethyl)-1-(1,3,4-Tris(hydroxymethyl)-2,5-dioxoimidazolidine-4-yl)urea(diazolidinylurea), 1,3-bis(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione, 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, cetylpyridinium chloride, caprylhydroxamic acid, sorbohydroxamic acid, and mixtures thereof; 1,3-propanediol, methylpropanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, 1,5-pentanediol, 1,6-hexanediol, 1,8-octanediol, 1,2-decanediol, ethylhexylglycerin, hexoxy-propane-1,2-diol, heptoxy-propane-1,2-diol, octoxy-propane-1,2-diol, 3-phenoxy-propane-1,2-diol, 3-benzyloxy-propane-1,2-diol, 3-phenylethyloxy-propane-1,2-diol, 3-phenylpropyloxy-propane-1,2-diol, 3-methylbenzyloxy-propane-1,2-diol, sorbitan caprylate, triclosan, crimbazole, Octopirox (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)-pyridone, 2-aminoethanol), chitosan, farnesol, 2-butyloctanoic acid, 2-benzylheptan-1-ol, glycerol monolaurate, bis(2-pyridylthio)zinc 1,1'-dioxide, N,N'-(decane-1,10-diyldipyridine-1-yl-4-ylidene)-dioctan-1-amine dihydrochloride (octenidine dihydrochloride), thymol, eugenol, benzyl alcohol, 2-phenylethyl alcohol, 3-phenylpropanol, 2-phenoxyethanol, 1-phenoxy-propane-2-ol, 3-phenoxypropanol, benzyloxymethanol, 4-hydroxyacetophenone, and mixtures thereof.

[0072] <Perfume oil> A suitable perfume oil is a mixture of natural and synthetic fragrances. Natural fragrances include flowers (lily, lavender, rose, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway, juniper), peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calamus), woods (pine wood, sandalwood, guaiac wood, cedarwood, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), needles and branches (spruce, fir, pine, dwarf pine), and resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax). Animal-derived ingredients such as civet and beaver may also be used.

[0073] Suitable fragrances with a woody scent are selected from the following group: [Table 4]

[0074] <Amber-scented fragrance> Suitable fragrances with an amber scent are selected from the following group: [Table 5]

[0075] <Fruity fragrance> Suitable fragrances with a fruity scent are selected from the following group: [Table 6]

[0076] <Fragrance with a musk scent> Suitable fragrances with a musk scent are selected from the following group: [Table 7] The fragrances summarized above also represent preferred embodiments of the secondary fragrances that form the main components of the fragrance composition described in the claims.

[0077] <dye> Suitable dyes are any of the substances approved and suitable for cosmetic purposes, such as those listed in the publication "Kosmetische Farbemittel" of the Farbstoff-kommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pp. 81 to 106. Examples include cochineal red A (CI 16255), patent blue V (CI 42051), indigotine (CI 73015), chlorophyllin (CI 75810), quinoline yellow (CI 47005), titanium dioxide (CI 77891), indanthrene blue RS (CI 69800), and madder lake (CI 58000). Luminol can also exist as a luminescent pigment. Favorable coloring pigments include, for example, titanium dioxide, mica, iron oxides (e.g., Fe2O3, Fe3O4, FeO(OH)) and / or tin oxide. Advantageous dyes include, for example, carmine, berlin blue, chromium oxide green, ultramarine blue, and / or manganese violet.

[0078] <Pharmacy> Preferred compositions according to the present invention are selected from the group of products as products for treating, protecting, caring for and cleansing skin and / or hair, or as makeup products, preferably as leave-on products (meaning that one or more compounds remain on the skin and / or hair for a longer period of time compared to rinse-off products).

[0079] Products according to the present invention are preferably emulsions, such as W / O (water in oil), O / W (oil in water), W / O / W (oil in water), O / W / O (water in oil) emulsions, PIT emulsions, Pickering emulsions, low oil content emulsions, microemulsions or nanoemulsions, solutions, such as in oil (fatty oil or fatty acid esters, particularly C6-C32 fatty acid C2-C30 esters) or silicone oil, dispersions, suspensions, creams, lotions or emulsions. Impregnation solutions for foams or cosmetic wipes (depending on the manufacturing method and ingredients), gels (including hydrogels, hydro-dispersion gels, and oleogels), sprays (e.g., pump sprays or propeller sprays), cleansing agents (e.g., soaps, synthetic detergents, liquid cleansing agents), shower and bath additives, bath products (capsules, oils, tablets, salts, bath additives, soaps, etc.), foaming agents, skincare products (e.g., lotions (as described above), ointments, pastes, gels (as described above), oils, balsams, serums, powders (e.g., Face powder, body powder, eau de parfum, eau de toilette, aftershave, mask, pencil, stick, roll-on, pump, aerosol (foaming, non-foaming or post-foaming), deodorant and / or antiperspirant, mouthwash and mouth rinse, foot care products (including exfoliants and deodorants), insect repellents, sunscreens, aftersun products, shaving products, aftershave balm, pre- and aftershave lotions, depilatory agents, shampoo (2-in-1 shampoo, dandruff control) These products include hair care products such as non-stick shampoos, baby shampoos, shampoos for dry scalps, and concentrated shampoos, conditioners, hair tonics, hair waters, hair rinses, styling creams, pomades, perm / set lotions, and hair sprays; styling aids (gels, waxes, etc.); hair smoothing agents (detangling agents, relaxers); hair dyes (temporary direct dyes, semi-permanent dyes, permanent dyes, etc.); hair conditioners; hair mousses; eye care products; makeup; makeup removers; and baby products.

[0080] Auxiliary substances and additives may be included in amounts of 5 to 99% by weight, preferably 10 to 80% by weight, based on the total weight of the product. The amount of cosmetic or dermatological auxiliary agents and additives and fragrances to be used in each case can be easily determined by a person skilled in the art through simple trial and error, depending on the properties of the particular product.

[0081] The compound may also contain water in any of the following amounts, based on the total weight of the compound: up to 99% by weight, preferably about 5 to about 80% by weight, more preferably about 10 to about 50% by weight or about 60 to about 80% by weight.

[0082] <Detergent Products> Another object of the present invention relates to detergent products comprising the fragrance mixture or the fragrance composition. The product may contain the fragrance mixture or fragrance composition in an amount ranging from about 0.01 to about 2% by weight, preferably about 0.1 to 1% by weight, calculated from the detergent product. Suitable examples of detergents include heavy-duty powder detergents, heavy-duty liquid detergents, light-duty powder detergents, light-duty liquid detergents, detergent tablets, fabric softeners, manual dishwashing detergents, all-purpose cleaners, and the like.

[0083] The detergent composition according to the present invention may contain any of the components conventionally found in such compositions, such as anionic, nonionic, cationic, amphoteric, or zwitterionic (co)surfactants, organic solvents, builders, enzymes, and additional auxiliary agents such as soil water repellents, thickeners, colorants, and fragrances.

[0084] <Anionic and zwitterionic surfactants> Typical examples of anionic and zwitterionic surfactants include the following: Almondamidopropylamine oxide, almondamidopropyl betaine, aminopropyl lauryl glutamine, C12-15 alkyl ammonium sulfate, C12-16 alkyl ammonium sulfate, caprylyl sulfate ammonium, coco monoglyceride ammonium sulfate, Ammonium cocosulfate, ammonium cocoyl isethionate, ammonium cocoyl sarcosinate, ammonium C12-15 pareth sulfate, ammonium C9-10 perfluoroalkyl sulfonate, ammonium dinonyl sulfosuccinate, ammonium dodecylbenzenesulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 sulfate, ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myristyl sulfate, ammonium nonoxynol-4 sulfate, ammonium nonoxynol-30 sulfate, ammonium oleate, ammonium palm kernel sulfate, ammonium stearate, ammonium talarate, AMPD-isostearate Hydrolyzed rhizome collagen, AMPD-rosin hydrolyzed collagen, AMP-isostearoyl hydrolyzed collagen, AMP-isostearoyl hydrolyzed keratin, AMP-isostearoyl hydrolyzed soy protein, AMP-isostearoyl hydrolyzed wheat protein, apricotamidopropyl betaine, arachidic acid, arginine hexyldecyl phosphate, avocadoamidopropyl betaine, avocado oil glycereth-8 ester, babassu acid, babassuamidopropylamine Oxide, babassuamidopropyl betaine, beeswax acid, behenamidopropyl betaine, behenamine oxide, beheneth-25, beheneth-30, behenic acid, behenyl betaine, bisbutyldimethicone polyglyceryl-3, butoxynol-5 carboxylic acid, butoxynol-19 carboxylic acid, butyldimonium hydroxypropyl butylglucoside chloride, butyldimonium hydroxypropyl lauryl glucoside chloride, butylglucoside, butylglucoside caprate,Butyl glucoside hydroxypropyltrimonium chloride, butyl octanoic acid, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C9-16 alkane / cycloalkane, C10-14 alkylbenzenesulfonic acid, C12-14 alkyldiaminoethylglycine HCl, C9-15 alkyl phosphate, Candida bombicola / glucose / methyl rapeseed oil ferment, canolamidopropyl betaine, capric acid, caproic acid, caproyl ethyl glycan Glucoside, Capryl / Capramidopropyl Betaine, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Caprylic Acid, Capryloyl Collagen Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids, Caprylyl / Capryl Glucoside, Caprylyl / Capryl Wheat Bran / Wheat Straw Glycoside, Caprylyl Glucoside, Caprylyl Glyceryl Ether, Caprylylpyrrolidone, Carnitine, Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 carboxylic acid, Ceteareth-2 phosphate, Ceteareth-4 phosphate, Ceteareth-5 phosphate, Ceteareth-10 phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-1 50, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Ceteth-22, Ceteth-24, Ceteth-25, Ceteth-30, Cetyl Betaine, Chrysanthemum Flower Extract, C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidoethyl Betaine, Cocamidopropylamine Oxide, Cocamidopropyl Betaine Amide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid,Coceth-7 carboxylic acid, coceth-4 glucoside, cocoamphodipropionic acid, cocobetaine amide amphopropionate, cocobetaine, cocodimonium hydroxypropyl hydrolyzed rice protein, cocodimonium hydroxypropyl hydrolyzed soy protein, cocodimonium hydroxypropyl hydrolyzed wheat protein, cocoglucoside, cocoglucoside hydroxypropyltrimonium chloride, cocohydroxysultaine, cocomorpholine oxide, coconut acid, coconut oil glycereth-8 ester, coco / oleamide Propyl betaine, cocosultaine, coco / sunflower amidopropyl betaine, cocoyl choline methosulfate, cocoyl glutamic acid, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn acid, cottonseed acid, cottonseed oil glycereth-8 ester, C10-16 pareth-1, C10-16 pareth-2, C11-13 pareth-6, C1 1-13 Pareth-9, C11-13 Pareth-10, C11-15 Pareth-30, C11-15 Pareth-40, C12-13 Pareth-1, C12-13 Pareth-23, C12-14 Pareth-5, C12-14 Pareth-9, C13-15 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 carboxylic acid, C9-11 Pareth-8 carboxylic acid, C11-15 Pareth-7 carboxylic acid, C12 -13 Pareth-5 carboxylic acid, C12-13 Pareth-7 carboxylic acid, C12-13 Pareth-8 carboxylic acid, C12-13 Pareth-12 carboxylic acid, C12-15 Pareth-7 carboxylic acid, C12-15 Pareth-8 carboxylic acid, C12-15 Pareth-12 carboxylic acid, C14-15 Pareth-8 carboxylic acid, C6-10 Pareth-4 phosphate, C12-13 Pareth-2 phosphate, C12-13 Pareth-10 phosphate, C12-15 Pareth-6 phosphate, C12-15 Pareth-8 phosphate, C12-15 Pareth-10 phosphate, C12-16 Pareth-6 phosphate,C4-18 perfluoroalkylethylthiohydroxypropyltrimonium chloride, cupusamidopropyl betaine, DEA-C12-13 alkyl sulfate, DEA-C12-15 alkyl sulfate, DEA-ceteareth-2 phosphate, DEA-cetyl sulfate, DEA-cocoamphodipropionate, DEA-C12-13 pareth-3 sulfate, DEA-cyclocarboxypropyl oleate, DEA-dodecylbenzenesulfonic acid, DEA-isostearate, DEA-laureth sulfate, DEA-lauryl sulfate, DEA-linoleic acid, DEA-methylmyristate sulfonic acid, DEA-myristic acid, DEA-myristyl sulfate, DEA-oleth-5 phosphate, DEA-oleth-20 phosphate, DEA PG-oleic acid, deceth-7 carboxylic acid, deceth-7 glucoside, deceth-9 phosphate, decylamine oxide, decyl betaine, decyl glucoside, decyltetradeceth-30, decyltetradecylamine oxide, diammonium lauramide-MEA sulfosuccinate, diammonium lauryl sulfosuccinate, diammonium oleamide PEG-2 sulfosuccinate, dibutoxymethane, di-C12-15 pareth-2 phosphate, di-C12-15 pareth-4 phosphate, di-C12-15 pareth-6 phosphate, di-C12-15 pareth-8 phosphate, di-C12-15 pareth-10 phosphate, didodecyl butanetetracarboxylic acid, diethylamine laureth sulfate, sodium diethylhexyl sulfosuccinate, dihydroxyethyl C8-10 alkoxypropyl Amine oxide, dihydroxyethyl C9-11 alkoxypropylamine oxide, dihydroxyethyl C12-15 alkoxypropylamine oxide, dihydroxyethyl cocamine oxide, dihydroxyethyl loramine oxide, dihydroxyethyl stearamine oxide, dihydroxyethyl tallowamine oxide, dimethicone PEG-7 phosphate, dimethicone PEG-10 phosphate, dimethicone PEG / PPG-7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone / polyglycerin-3 crosspolymer, dimethicone propyl PG-betaine, dimyristyl phosphate, dioleoylamide ethyl hydroxyethylmonium methosulfate, DIPA-hydrogenated cocoate, DIPA-lanolate, DIPA-myristate,Dipotassium capryloyl glutamate, dipotassium lauryl sulfosuccinate, dipotassium undecylenoyl glutamate, babasamide MEA-disodium sulfosuccinate, disodium capronphodiacetate, disodium caproamphodipropionate, disodium capryloamphodiacetate, disodium capryloamphodipropionate, disodium capryloyl glutamate, disodium cetearyl sulfosuccinate, disodium cetylphenyl ether disulfonate, disodium cetyl sulfosuccinate, cocamide MEA-disodium sulfosuccinate, cocamide MIPA Disodium PEG-4 sulfosuccinate, disodium cocamide MIPA sulfosuccinate, disodium cocamide PEG-3 sulfosuccinate, disodium coceth-3 sulfosuccinate, disodium cocoampho-carboxyethyl hydroxypropyl sulfonate, disodium cocoamphodiacetate, disodium cocoamphodipropionate, coco-glucoside sulfosuccinate, disodium coco-sulfosuccinate, disodium cocoyl butylgluceth-10 sulfosuccinate, disodium cocoyl glutamate, disodium C12-14 pareth-1 sulfosuccinate, disodium C12-14 pareth-2 sulfosuccinate, disodium C12-15 pareth-sulfosuccinate, disodium C12-14 sec-pareth-3 sulfosuccinate, disodium C12-14 sec-pareth-5 sulfosuccinate Disodium citrate, disodium C12-14Sec-Pareth-7 sulfosuccinate, disodium C12-14Sec-Pareth-9 sulfosuccinate, disodium C12-14Sec-Pareth-12 sulfosuccinate, disodium deceth-5 sulfosuccinate, disodium deceth-6 sulfosuccinate, disodium decylphenyl ether disulfonic acid, disodium dihydroxyethyl sulfosuccinyl undecylenate, disodium ethylene dicocamide PEG-15 disulfinate, disodium hydrogenated cottonseed oil glyceride sulfosuccinate, disodium hydrogenated scutellaria glutamate, disodium hydroxydecyl sorbitol citrate, disodium isodecyl sulfosuccinate, disodium isostearamide MEA sulfosuccinate, disodium isostearamide MIPA sulfosuccinate,Disodium isostearoamhodiacetate, disodium isostearoamhodipropionate, disodium isostearyl sulfosuccinate, disodium laureth-5 sulfosuccinate, disodium lauramide MEA sulfosuccinate, disodium lauramide MIPA glycol sulfosuccinate, disodium lauramide PEG-2 sulfosuccinate, disodium lauramide PEG-5 sulfosuccinate, disodium laureth-5 carboxyamphodiacetate, , disodium laureth-7 citrate, disodium laureth sulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium lauriminobishydroxypropyl sulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate, disodium lauriminodipropionate tocopheryl phosphate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium N-lauroyl aspartate, lauroyl glyceride Disodium glutamate, disodium laurylphenyl ether disulfonate, disodium lauryl sulfosuccinate, disodium myristamide MEA-sulfosuccinate, disodium nonoxynol-10 sulfosuccinate, disodium oleamide MEA-sulfosuccinate, disodium oleamide MIPA-sulfosuccinate, disodium oleamide PEG-2 sulfosuccinate, disodium oleoamphodipropionate, disodium olease-3 sulfosuccinate, disodium oleyl phosphate, disodium oleyl sulfosuccinate, palmita Mido PEG-2 sulfosuccinate disodium, palmitreamide PEG-2 sulfosuccinate disodium, PEG-4 cocamide MIPA sulfosuccinate disodium, PEG-12 dimethicone sulfosuccinate disodium, PEG-8 palm glyceride sulfosuccinate disodium, PPG-2-losodeceth-7 carboxyamphodiaacetate disodium, ricinolamide MEA sulfosuccinate disodium, sitostereth-14 sulfosuccinate disodium, soybean amphodiaacetate disodium, stearamide MEA sulfosuccinate disodium Um, steariminodipropionate disodium, stearoamhodiacetate disodium, stearoylglutamate disodium, stearylsulfosuccinate disodium, stearylsulfosuccinate disodium, 2-sulfolaurate disodium, 2-sulfopalmitate disodium, taloamide MEA-sulfosuccinate disodium, taloamide MEA-sulfosuccinate disodium, taloamphodiacetate disodium, taloiminodipropionate disodium, talosulfosuccinate disodium, tridecylsulfosuccinate disodium,Disodium undecylenamide MEA-sulfosuccinate, disodium undecylenamide PEG-2 sulfosuccinate, disodium undecylenoyl glutamate, disodium wheat germamide MEA-sulfosuccinate, disodium wheat germamide PEG-2 sulfosuccinate, disodium wheat germamide phodiacetate, di-TEA-cocamide diacetate, di-TEA-oleamide PEG-2 sulfosuccinate, di-TEA-palmitoyl aspartate, ditridecyl sodium sulfosuccinate, dodecylbenzenesulfonic acid , ercamidopropyl hydroxysultaine, ethylhexeth-3 carboxylic acid, ethyl PEG-15 cocamine sulfate, glyceryl capryl ether, hexyldecanoic acid, hydrogenated coconut acid, hydrogenated laness-25, hydrogenated menhardic acid, hydrogenated palm acid, hydrogenated palm kernel amine oxide, hydrogenated beef tallow acid, hydrogenated beef tallow amine oxide, hydrogenated beef tallow betaine, hydrogenated tallow S-25, hydrogenated beef tallow oil glutamic acid, hydrolyzed Candida bombicola extract, hydroxyceteth-60, hydroxyethylacetomonium PG-dimethicone, hydroxyethylbutylamine laureth sulfide Salt, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylauryl / hydroxymyristyl betaine, hydroxystearic acid, hydroxysuccinimidyl C10-40 isoalkyl acidate, hydroxysuccinimidyl C21-22 isoalkyl acidate, hydroxysultaine, IPDI / PEG-15 soyamine oxide copolymer, IPDI / PEG-15 soyethonium ethosulfate copolymer, IPDI / PEG-15 so Iglycinate copolymer, Isoceteth-30, Isolaureth-4 phosphate, Isopolyglyceryl-3 dimethicone, Isopolyglyceryl-3 dimethiconol, Isopropanolamine lanolate, Isopropylamine dodecylbenzenesulfonate, Isostearamidopropylamine oxide, Isostearamidopropyl betaine, Isostearamidopropyl morpholine oxide, Isosteareth-8, Isosteareth-16, Isosteareth-22, Isosteareth-25, Isosteareth-50, Isostearic acid, Isostearoyl hydrolyzed collagen,Jojoba oil PEG-150 ester, jojoba wax PEG-80 ester, jojoba wax PEG-120 ester, Laneth-20, Laneth-25, Laneth-40, Laneth-50, Laneth-60, Laneth-75, lanolinic acid, lauramidopropylamine oxide, lauramidopropyl betaine, lauramidopropyl hydroxysultaine, lauramine oxide, lauaminopropionic acid, laurdimonium hydroxypropyl decyl glucoside chloride Lauryl glucoside chloride, laureth-16, laureth-20, laureth-21, laureth-23, laureth-25, laureth-30, laureth-38, laureth-40, laureth-3 carboxylic acid, laureth-4 carboxylic acid, laureth-5 carboxylic acid, laureth-6 carboxylic acid, laureth-8 carboxylic acid, laureth-10 carboxylic acid, laureth-11 carboxylic acid, laureth-12 carboxylic acid, laureth-13 carboxylic acid, laureth-14 carboxylic acid, laureth-17 carboxylic acid, laureth-6 citrate, laureth-7 citrate, laureth-1 phosphate, laureth-2 phosphate, laureth-3 phosphate, laureth-4 phosphate, laureth-7 phosphate, laureth-8 phosphate, laureth-7 tartrate, lauric acid, lauriminobispropanediol, lauriminodipropionic acid, lauroamphodipropionic acid, lauroyl β-alanine, lauroyl collagen Mino acid, lauroyl ethyltrimonium methosulfate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methylglucamide, lauroyl sarcosine, lauroyl silk amino acids, lauryl betaine, lauryl dimethicone / polyglycerin-3 crosspolymer, lauryldimonium hydroxypropyl coco-glucoside chloride, lauryl glucoside, lauryl glucoside hydroxypropyltrimonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysultaine, lauryl maramide, lauryl methylglucamide, lauryl / myristyl glycol hydroxypropyl ether, lauryl / myristyl wheat bran / straw glycoside, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, laurylpyrrolidone, lauryl sultaine, linoleic acid, linolenic acid, flaxseed acid, lysine cocoate,Macadamia seed oil glycereth-8 ester, magnesium coceth sulfate, magnesium coco sulfate, magnesium isododecylbenzenesulfonate, magnesium laureth-11 carboxylate, magnesium laureth sulfate, magnesium laureth-5 sulfate, magnesium laureth-8 sulfate, magnesium laureth-16 sulfate, magnesium laureth-3 sulfosuccinate, magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium methyl cocoyl taurate, magnesium myreth sulfate, magnesium olease sulfate, magnesium / TEA-coco sulfate, manicuagan clay, MEA-cocoate, MEA-laureth-6 carboxylate, MEA-laureth sulfate, MEA-lauryl sulfate, MEA PPG-6 Laureth-7 Carboxylate, MEA-PPG-8 Steareth-7 Carboxylate, MEA-Undecylenate, Meloxapole 108, Meloxapole 174, Meloxapole 178, Meloxapole 254, Meloxapole 255, Meloxapole 258, Meloxapole 314, MethoxyPEG-450 Amidoglutaloylsuccinimide, MethoxyPEG-450 Amidohydroxysuccinimidylsuccinamate, MethoxyPEG-450 Maleimide, Methylmorpholine Oxide, Milcamidopropylamine Oxide, Milcamidopropyl Betaine, Mincamidopropylamine Oxide, Mincamidopropyl Betaine, MIPA C12-15 Pareth Sulfate, MIPA-Dodecylbenzenesulfonate, MIPA-Laureth Sulfate, MIPA-Lauryl Sulfate, Mixed Isopropanolamine Lanolate, Mixed Isopropanolamine Lauryl Sulfate, Mixed Isopropanolamine Myristate, Morpholine Oleate, Morpholine Stearate, Myreth-3 Carboxylic Acid, Myreth-5 Carboxylic Acid, Myristalkonium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myristamine Oxide, Myristaminopropionic Acid, Myristic Acid, Myristoyl Ethyltrimonium Metasulfate, Myristoyl Glutamic Acid, Myristoyl Hydrolyzed Collagen, Myristoyl Sarcosine, Myristyl Betaine,Myristyl / Cetylamine Oxide, Myristyldimonium Hydroxypropyl Coco-Glucoside Chloride, Myristyl Glucoside, Myristyl Phosphate, Nonoxynol-20, Nonoxynol-23, Nonoxynol-25, Nonoxynol-30, Nonoxynol-35, Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 Carboxylic Acid, Nonoxynol-8 Carboxylic Acid, Nonoxynol-10 Carboxylic Acid, Nonoxynol-3 Phosphate, Nonoxynol-4 Phosphate Acid, Nonoxynol-6 phosphate, Nonoxynol-9 phosphate, Nonoxynol-10 phosphate, Nonylnonoxynol-30, Nonylnonoxynol-49, Nonylnonoxynol-100, Nonylnonoxynol-150, Nonylnonoxynol-7 phosphate, Nonylnonoxynol-8 phosphate, Nonylnonoxynol-9 phosphate, Nonylnonoxynol-10 phosphate, Nonylnonoxynol-11 phosphate, Nonylnonoxynol-15 phosphate, Nonylnonoxynol-24 phosphate, Autoamidepropyl betaine, Octoxynol-16, Octoxynol Lu-25, Octoxynol-30, Octoxynol-33, Octoxynol-40, Octoxynol-70, Octoxynol-20 carboxylic acid, Octyldodeceth-20, Octyldodeceth-25, Octyldodeceth-30, Oleamidopropylamine oxide, Oleamidopropyl betaine, Oleamidopropyl hydroxysultaine, Oleamine oxide, Oleic acid, Oleoyl hydrolyzed collagen, Oleoyl sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleth Su-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Olive Amidopropylamine Oxide, Olive Amidopropyl Betaine, Olive Acid, Hydrolyzed Wheat Protein, Ophiopogon Extract Stearate, Ozonated Oleth-10, Ozonated PEG-10 Oleic Acid, Ozonated PEG-14 Oleic Acid, Ozonated Polysorbate 80, Palm Acid, Palmimidopropyl Betaine, Palmes-2 Phosphate, Palmitamidopropylamine Oxide, Palmitamidopropyl Betaine,Palmitamine oxide, palmitic acid, palmitoyl collagen amino acids, palmitoyl glycine, palmitoyl hydrolyzed collagen, palmitoyl hydrolyzed milk protein, palmitoyl hydrolyzed wheat protein, palmitoyl keratin amino acids, palmitoyl oligopeptide, palmitoyl silk, Cocamine, palm nucleic acid, palm kernel amidopropyl betaine, peach kernel oil glycereth-8 ester, peanut acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-50 castor oil, PEG-54 castor oil, PEG-55 castor oil, PEG-60 castor oil, PEG-80 castor oil, PEG-100 castor oil, PEG-200 castor oil, PEG-11 cocamide, PEG-6 cocamide phosphate, PEG-4 cocamine, PEG-8 cocamine, PEG-12 cocamine, PEG-150 dibehenate, PEG-90 diisostearate, P EG-75 dilaurate, PEG-150 dilaurate, PEG-75 dioleate, PEG-150 dioleate, PEG-75 distearate, PEG-120 distearate, PEG-150 distearate, PEG-175 distearate, PEG-190 distearate, PEG-250 distearate, PEG-30 glyceryl cocoate, PEG-40 glyceryl cocoate, PEG-78 glyceryl cocoate, PEG-80 glyceryl cocoate, PEG-30 glyceryl isostearate, PEG-40 glyceryl isostearate PEG-50 glyceryl isostearate, PEG-60 glyceryl isostearate, PEG-90 glyceryl isostearate, PEG-23 glyceryl laurate, PEG-30 glyceryl laurate, PEG-25 glyceryl oleate, PEG-30 glyceryl oleate, PEG-30 glyceryl soybean oil fatty acid, PEG-25 glyceryl stearate, PEG-30 glyceryl stearate, PEG-40 glyceryl stearate, PEG-120 glyceryl stearate, PEG-200 glyceryl stearate, PEG- 28 Glyceryl, PEG-80 Glyceryl Talotate, PEG-82 Glyceryl Talotate, PEG-130 Glyceryl Talotate, PEG-200 Glyceryl Talotate, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil, PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin, PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate,PEG-4 isostearate, PEG-6 isostearate, PEG-8 isostearate, PEG-10 isostearate, PEG-12 isostearate, PEG-20 isostearate, PEG-30 isostearate, PEG-40 isostearate, PEG-26 jojoba acid, PEG-40 jojoba acid, PEG-15 jojoba alcohol, PEG-26 jojoba alcohol, PEG-40 jojoba alcohol, PEG-35 lanolin, PEG-40 lanolin, PEG-50 lanolin, PEG-55 lanolin, PEG-60 lanolin, PEG-70 lanolin Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glyceride, PEG-20 Mannitane Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Trioleic Acid Methyl glucose, PEG-4 montana, PEG-30 oleic acid, PEG-20 oleic acid, PEG-23 oleic acid, PEG-32 oleic acid, PEG-36 oleic acid, PEG-75 oleic acid, PEG-150 oleic acid, PEG-20 palmitic acid, PEG-150 polyglyceryl-2 tristearate, PEG / PPG-28 / 21 acetate dimethicone, PEG / PPG-24 / 18 butyl ether dimethicone, PEG / PPG-3 / 17 copolymer, PEG / PPG-5 / 35 copolymer, PEG / PPG-8 / 55 copolymer - PEG / PPG-10 / 30 copolymer, PEG / PPG-10 / 65 copolymer, PEG / PPG-12 / 35 copolymer, PEG / PPG-16 / 17 copolymer, PEG / PPG-20 / 9 copolymer, PEG / PPG-20 / 20 copolymer, PEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, PEG / PPG-28 / 30 copolymer, PEG / PPG-30 / 35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer,PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer, PEG / PPG-300 / 55 copolymer, PEG / PPG-20 / 22 methyl ether dimethicone, PEG-26-PPG-30 phosphate ester, PEG / PPG-4 / 2 propylheptyl ether, PEG / PPG-6 / 2 propylheptyl ether, PEG-7 / PPG-2 propylheptyl ether, PEG / PPG-8 / 2-Propylheptyl Ether, PEG / PPG-10 / 2-Propylheptyl Ether, PEG / PPG-14 / 2-Propylheptyl Ether, PEG / PPG-40 / 2-Propylheptyl Ether, PEG / PPG-10 / 2-Ricinoleate, PEG / PPG-32 / 3-Ricinoleate, PEG-55-Propylene Glycol Oleate, PEG-25-Propylene Glycol Stearate, PEG-75-Propylene Glycol Stearate, PEG-120-Propylene Glycol Stearate, PEG-5-Rapeseed Sterol, PEG-10-Rapeseed Sterol Seed sterols, PEG-40 ricinolamide, PEG-75 shea butter glyceride, PEG-75 shorea butter glyceride, PEG-20 sorbitan cocoate, PEG-20 sorbitan isostearate, PEG-40 sorbitan lanolinate, PEG-75 sorbitan lanolinate, PEG-10 sorbitan laurate, PEG-40 sorbitan laurate, PEG-44 sorbitan laurate, PEG-75 sorbitan laurate, PEG-80 sorbitan laurate, PEG-20 sorbitan oleate, PEG-80 sorbitan palmitate, s PEG-40 sorbitan thearate, PEG-60 sorbitan stearate, PEG-160 sorbitan triisostearate, PEG-40 soybean sterols, PEG-2 stearamide carboxylic acid, PEG-9 stearamide carboxylic acid, PEG-20 stearate, PEG-23 stearate, PEG-25 stearate, PEG-30 stearate, PEG-32 stearate, PEG-35 stearate, PEG-36 stearate, PEG-40 stearate, PEG-45 stearate, PEG-50 stearate, PEG-55 stearate,PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 talolate, PEG-50 taloamide, PEG-2 taloamide DEA, PEG-20 talolate, PEG-66 trihydroxystearin, PEG-200 trihydroxystearin, PEG-60 twillate glycerides, pelargonic acid, pentadoxynol-200, fenes-6 phosphate, poloxamer 105, poloxamer 108, poloxa M182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288, Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl Dilaurate -10, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomadelis cumellatus flower / leaf extract, Polyacococcus extract, Abietoyl hydrolyzed collagen potassium, Babastic acid potassium, Behenate potassium, C9-15 alkyl phosphate potassium, C11-15 alkyl phosphate potassium, C12-13 alkyl phosphate potassium, C12-14 alkyl phosphate potassium, Capryloyl caprate potassium, Capryloyl hydrolyzed rice protein,Potassium castorate, potassium cocoate, potassium cocoyl glutamate, potassium cocoyl glycinate, potassium cocoyl hydrolyzed caseinate, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin protein, potassium cocoyl hydrolyzed oat protein, potassium cocoyl hydrolyzed potato protein, potassium cocoyl hydrolyzed rice bran protein, potassium cocoyl hydrolyzed rice protein, potassium cocoyl hydrolyzed silk protein, potassium cocoyl hydrolyzed soy protein, potassium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed yeast protein, potassium cocoyl PCA, potassium cocoyl sarcosinate, potassium cocoyl taurate, potassium cornate, potassium cyclocarboxypropylrolate, potassium dihydroxyethyl cocamine oxide phosphate, potassium dimethicone PEG-7 phosphate, potassium dodecylbenzenesulfonate, potassium hemp seed acid, potassium hydrogenated cocoate, potassium hydrogenated palmitate, potassium hydrogenated tallowate, potassium hydroxystearate, potassium isostearate, potassium lanolate, potassium laurate, laurate, Potassium ureth-3 carboxylate, potassium laureth-4 carboxylate, potassium laureth-5 carboxylate, potassium laureth-6 carboxylate, potassium laureth-10 carboxylate, potassium laureth phosphate, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed pea protein, potassium lauroyl hydrolyzed soy protein, potassium lauroyl PCA, potassium lauroyl pea amino acid, potassium lauroyl sarcosinate, potassium lauroyl silk amino acid, potassium lauroyl wheat amino acid, potassium lauryl phosphate, potassium lauryl sulfate, potassium linoleate, potassium metaphosphate, potassium methyl cocoyl taurate, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octoxinol-12 phosphate, potassium oleate, potassium oleoyl hydrolyzed collagen, potassium olivoyl hydrolyzed oat protein, potassium olivoyl hydrolyzed wheat protein, potassium olivoyl / lauroyl wheat amino acidPotassium oliboyl PCA, potassium palmitate, potassium palmitate, palmitoyl hydrolyzed corn protein, palmitoyl hydrolyzed oat protein, palmitoyl hydrolyzed rice protein, palmitoyl hydrolyzed sweet almond protein potassium, palmitoyl hydrolyzed wheat protein potassium, palm kernelate potassium, peanut acid, Potassium, rapeseed potassium, potassium ricinoleate, safflower potassium, soybean potassium, potassium stearate, stearoyl hydrolyzed collagen potassium, potassium tarate, potassium taurate, potassium taurine laurate, potassium trideceth-3 carboxylate, potassium trideceth-4 carboxylate, potassium trideceth-7 carboxylate, potassium trideceth-15 carboxylate, potassium trideceth-19 carboxylate, potassium trideceth-6 phosphate, potassium trideceth-7 phosphate, potassium tsubate, potassium undecylenate, potassium undecylenol hydrolyzed collagen, potassium undecylenol hydrolyzed rice protein, PPG-30-buteth-30, PPG-36-buteth-36, PPG-38-buteth-37, PPG-30-capryleth-4 phosphate, PPG-10 cetyl ether phosphate, PPG-2 C9-11 Pareth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylic Acid, PPG-30 Ethylhexeth-4 Phosphate, PPG-20-Glycereth-30, PPG-2 Hydroxyethyl Coco-Isostearamide, PPG-2-Isodeceth-8, PPG-2-Isodeceth-10, PPG-2-Isodeceth-18, PPG-2-Isodeceth-25, PPG-4-Isodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Acid, Rice Bran Acid, Rice Oil Glycereth-8 Ester, Ricinolamidopropyl Betaine, Lysine Oleic Acid, Ricinol Ace-40, Safflower Acid, Sapindus Oenanthate Fruit extract, Saponaria officinalis root powder, Saponin soap-K, Soap-Sodium / K, Soap Soap, Soap Soap-K, Sesame oil glycereth-8 ester, Sesamidopropylamine oxide, Cesamidopropyl betaine, Shea butter amidopropyl betaine, Shea butter glycereth-8 ester, Sodium arachidate, Sodium arganamphoacetate, Sodium astrocaryum murumurate, Sodium avocadoate, Sodium babassuamphoacetate, Sodium babassuate, Sodium babassu sulfate, Sodium behenate, Sodium bisglycol ricinosulfosuccinate, Sodium bis-hydroxyethylglycinate coco-glucoside crosspolymer,Sodium bis-hydroxyethylglycinate lauryl-glucoside crosspolymer, sodium boradiamidopropyl PG-dimonium chloride phosphate, sodium butoxynol-12 sulfate, sodium butylglucoside hydroxypropyl phosphate, sodium C13-17 alkanesulfonate, sodium C14-18 alkanesulfonate, sodium C12-15 alkoxypropyl iminodipropionate, sodium C10-16 alkyl sulfate, sodium C11-15 alkyl sulfate, sodium C12-13 alkyl sulfate, C12-15 Sodium alkyl sulfate, C12-18 sodium alkyl sulfate, C16-20 sodium alkyl sulfate, C9-22 sodium alkylsec sulfonate, C14-17 sodium alkylsec sulfonate, sodium caprate, sodium caproamphoacetate, sodium caproamphohydroxypropyl sulfonate, sodium caproamphopropionate, sodium caproyl methyltaurate, sodium caprylate, sodium capryleth-2 carboxylate, sodium capryleth-9 carboxylate, sodium capryloamphoacetate, capry Sodium loamphohydroxypropyl sulfonate, sodium capryloamphopropionate, sodium capryloyl glutamate, sodium capryloyl hydrolyzed wheat protein, sodium caprylyl PG-sulfonate, sodium caprylyl sulfonate, sodium castorate, sodium ceteareth-13 carboxylate, sodium cetearyl sulfate, sodium ceteth-13 carboxylate, sodium cetyl sulfate, sodium cocamidopropyl PG-dimonium chloride phosphate, sodium cocaminopropionate, sodium coceth sulfate, Sodium ceth-30 sulfate, sodium cocoa butter amphoacetate, sodium cocoa butterate, sodium cocoamphoacetate, sodium cocoamphohydroxypropyl sulfonate, sodium cocoamphopropionate, sodium cocoate, sodium coco / babassu / andiroba sulfate, sodium coco / babassu sulfate, sodium coco glucoside hydroxypropyl phosphate, sodium coco glucoside hydroxypropyl sulfonate, sodium coco glucoside tartrate, sodium coco glyceryl ether sulfonate, sodium coco / scutellaria baicalensis sulfate,Sodium cocoiminodiacetate, sodium cocomonoglyceride sulfate, sodium cocomonoglyceride sulfonate, sodium coco-PGdimonium chloride phosphate, sodium coco sulfate, sodium coco sulfoacetate, sodium cocoyl alaninate, sodium cocoyl amino acids, sodium cocoyl collagen amino acids, sodium cocoyl glutamate, sodium cocoyl glutamate, sodium cocoyl glycinate, sodium cocoyl / hydrogenated beef tallow glutamate, sodium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed keratin, sodium cocoyl hydrolyzed rice protein, sodium cocoyl hydrolyzed silk, sodium cocoyl hydrolyzed soy protein, sodium cocoyl hydrolyzed sweet almond protein, sodium cocoyl hydrolyzed wheat protein, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl isethionate, sodium cocoyl methylaminopropionate, sodium cocoyl oat amino acids, sodium cocoyl / palmoyl / sunflower oil glutamate, sodium cocoyl proline, sodium cocoyl sarcosinate Sodium cocoyl taurate, sodium cocoyl threonate, sodium cocoyl wheat amino acid, sodium C12-14 olefin sulfonate, sodium C14-16 olefin sulfonate, sodium C14-18 olefin sulfonate, sodium C16-18 olefin sulfonate, sodium cornan phopropionate, sodium cottonseed amphoacetate, sodium C13-15 pareth-8 butyl phosphate, sodium C9-11 pareth-6 carboxylate, sodium C11-15 pareth-7 carboxylate, sodium C12-13 pareth-5 carboxylate Sodium phosphate, sodium C12-13 pareth-8 carboxylate, sodium C12-13 pareth-12 carboxylate, sodium C12-15 pareth-6 carboxylate, sodium C12-15 pareth-7 carboxylate, sodium C12-15 pareth-8 carboxylate, sodium C14-15 pareth-8 carboxylate, sodium C12-14 Sec-pareth-8 carboxylate, sodium C14-15 pareth-PG sulfonate, sodium C12-13 pareth-2 phosphate, sodium C13-15 pareth-8 phosphate, sodium C9-15 pareth-3 sulfate,C10-15 Pareth Sulfate Sodium, C10-16 Pareth-2 Sulfate Sodium, C12-13 Pareth Sulfate Sodium, C12-15 Pareth Sulfate Sodium, C12-15 Pareth-3 Sulfate Sodium, C13-15 Pareth-3 Sulfate Sodium, C12-14 Sec-Pareth-3 Sulfate Sodium, C12-15 Pareth-3 Sulfonate Sodium, C12-15 Pareth-7 Sulfonate Sodium, C12-15 Pareth-15 Sulfonate Sodium, Deceth-2 Carboxylate Sodium, Deceth Sulfate Sodium, Decylbenzene Sulfonate Sodium, Decyl Glu Sodium coside hydroxypropyl phosphate, sodium decyl glucoside hydroxypropyl sulfonate, sodium dilaureth-7 citrate, sodium dilaureth-10 phosphate, sodium dilinolamidopropyl PG-dimonium chloride phosphate, sodium dilinoleate, sodium dioleth-8 phosphate, sodium dodecylbenzenesulfonate, sodium ethyl 2-sulfolaurate, sodium glyceryl oleate phosphate, sodium grapeseed amphoacetate, sodium grapeseed amphoacetate Thorium, Sodium Grape Seedate, Sodium Hemp Seed Amphoacetate, Sodium Hexeth-4 Carboxylate, Sodium Hydrogenated Cocoate, Sodium Hydrogenated Cocoyl Methyl Isethionate, Sodium Hydrogenated Palmitate, Sodium Hydrogenated Taloyl Glutamate, Sodium Hydroxylauryl Dimonium Ethyl Phosphate, Sodium Hydroxypropyl Palm Nucleic Acid Sulfonate, Decyl Glucoside Crosspolymer Hydroxypropyl Phosphate, Sodium Lauryl Glucoside Crosspolymer Hydroxypropyl Phosphate, Sodium Hydroxypropyl Sulfonate Coco Glucoside Crosspolymer, Sodium Hydroxypropyl Sulfonate Decyl Glucoside Crosspolymer, Sodium Hydroxypropyl Sulfonate Lauryl Glucoside Crosspolymer, Sodium Hydroxystearate, Sodium Isostearate, Sodium Isosteareth-6 Carboxylate, Sodium Isosteareth-11 Carboxylate, Sodium Isostearoamphoacetate, Sodium Isostearoamphopropionate, Sodium N-Isostearoyl Methyl Taurate, Sodium Lanes Sulfate,Sodium lanolinate, sodium laurate, sodium lauramide diacetate, sodium lauraminopropionate, sodium laurate, sodium laureth-3 carboxylate, sodium laureth-4 carboxylate, sodium laureth-5 carboxylate, sodium laureth-6 carboxylate, sodium laureth-8 carboxylate, sodium laureth-11 carboxylate, sodium laureth-12 carboxylate, sodium laureth-13 carboxylate, sodium laureth-14 carboxylate, sodium laureth-16 carboxylate, sodium laureth-17 carboxylate, sodium laureth sulfate, sodium laureth-5 sulfate, sodium laureth-7 sulfate, sodium laureth-8 sulfate, sodium laureth-12 sulfate, sodium laureth-40 sulfate, sodium laureth-7 tartrate, sodium laurominodipropionate, sodium lauroamphoacetate, sodium lauroamphohydroxypropylsulfonate, sodium lauroampho-PG-acetate phosphate, sodium lauroamphopropionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, lauroyl glycyrrhein Sodium umpropionate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropyl sulfonate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl methyl isethionate, sodium lauroyl millet amino acid, sodium lauroyl / myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosinate, sodium lauroyl silk amino acid, sodium lauroyl tau phosphate, sodium lauroyl wheat amino acid, sodium lauryl diethylenediaminoglycinate, sodium lauryl glucose carboxylate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, sodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, sodium macadamia acetate, sodium mango amphoacetate, sodium mangostine,MEA Laureth-2 Sulfosuccinate Sodium, MethoxyPPG-2 Sodium Acetate, Methyl Cocoyl Taurate Sodium, Methyl Lauroyl Taurate Sodium, Methyl Myristoyl Taurate Sodium, Methyl Oleyl Taurate Sodium, Methyl Palmitoyl Taurate Sodium, Methyl Stearoyl Taurate Sodium, Methyl 2-Sulfo Laurate Sodium Sodium methyl 2-sulfopalmitate, sodium methyl taurine isopalmitate, sodium methyl taurine cocoyl methyl taurine, sodium myristate, sodium myristoamphoacetate, sodium myristoyl glutamate, sodium myristoyl hydrolyzed collagen, sodium myristoyl isethionate, sodium myristoyl sarcosinate, sodium myristyl sulfate, sodium nonoxynol-6 phosphate, sodium nonoxynol-9 phosphate, sodium nonoxynol-1 sulfate, sodium nonoxynol-3 sulfate Nonoxynol-4 Sodium Sulfate, Nonoxynol-6 Sodium Sulfate, Nonoxynol-8 Sodium Sulfate, Nonoxynol-10 Sodium Sulfate, Nonoxynol-25 Sodium Sulfate, Octoxynol-2 Sodium Ethanesulfonate, Octoxynol-2 Sodium Sulfate, Octoxynol-6 Sodium Sulfate, Octoxynol-9 Sodium Sulfate, Sodium Oleate, Sodium Oleoamphoacetate, Sodium Oleoamphohydroxypropyl Sulfonate, Sodium Oleopropyl Hydrolyzed Collagen Sodium oleyl isethionate, sodium oleyl sulfate, sodium oleylmethyl isethionate, sodium oleyl sulfate, sodium olivanphoacetate, sodium olivine, sodium olivoyl glutamate, sodium palmanphoacetate, sodium palmitate, sodium palmglyceride sulfonate, sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat protein, sodium palmitoyl sarcosinate, sodium palm nucleotide, sodium palm nucleotide isethionate Sodium palmoyl glutamate, sodium passiflora edulis seed acid, sodium peanut amphoate, sodium peanut acid, sodium PEG-6 cocamide carboxylate, sodium PEG-8 cocamide carboxylate, sodium PEG-4 cocamide sulfate, sodium PEG-3 lauramide carboxylate, sodium PEG-4 lauramide carboxylate, sodium PEG-8 palm glyceride carboxylate, sodium pentaerythrityl hydroxypropyl minodiacetate dendrimer, sodium propoxy PPG-2 acetate,Sodium rapeseed, sodium ricinoleate, sodium ricinoleate, sodium ricinol amphoacetate, sodium rosehip amphoacetate, sodium rosinate, sodium safflower acid, sodium safflower acid, safflower hydrolyzed soy protein, sodium sesaminate, sodium sesamin phosphate, sodium shea butter amphoacetate, sodium soy acid, sodium hydrolyzed soy collagen, sodium stearate, sodium stearoamphoacetate, sodium stearoamphohydroxypropyl sulfonate, sodium stearoampho Sodium propionate, sodium stearoyl caseinate, sodium stearoyl glutamate, sodium stearoyl hyaluronate, sodium stearoyl hydrolyzed collagen, sodium stearoyl hydrolyzed corn protein, sodium stearoyl hydrolyzed silk, sodium stearoyl hydrolyzed soy protein, sodium stearoyl hydrolyzed wheat protein, sodium stearoyl lactate, sodium stearoyl methyl isethionate, sodium stearoyl oat protein, sodium stearoyl pea protein Sodium stearoyl soy protein, sodium stearyldimethylglycine, sodium stearyl sulfate, sodium sunflower seed amphoacetate, sodium surfactin, sodium sweet almond amphoacetate, sodium sweet almondate, sodium talamphopropionate, sodium talphosphate, sodium taloamphoacetate, sodium taloate, sodium talo sulfate, sodium tamanucide, sodium taurate, sodium cocoyl methyl taurine, sodium taurate, sodium laurate, sodium lauroyl collagen amino acid sodium / TEA, sodium lauroyl hydrolyzed collagen / TEA, sodium lauroyl hydrolyzed keratin / TEA, sodium lauroyl keratin amino acid sodium / TEA, sodium undecylenoyl collagen amino acid sodium / TEA, sodium undecylenoyl hydrolyzed collagen / TEA, sodium undecylenoyl hydrolyzed corn protein sodium / TEA, sodium undecylenoyl hydrolyzed soy protein sodium / TEA, sodium undecylenoyl hydrolyzed wheat protein / TEA, sodium theobroma grandiflorum seed oil,Sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium trideceth sulfate, sodium tridecylbenzenesulfonate, sodium tridecyl sulfate, sodium trimethylolpropanehydroxypropylminodiacetate dendrimer, sodium undeceth-5 carboxylate Sodium undecylenate, sodium undecylenoamphoacetate, sodium undecylenoamphopropionate, sodium undecylenoyl glutamate, sodium wheat germ amphoacetate, sorbeth-160 tristearate, soybean acid, soyamidopropylamine oxide, soyamidopropyl betaine, soybean oil glycereth-8 ester, stearamidopropylamine oxide, stearamidopropyl betaine, stearamine oxide, steareth-15, steareth-16, steareth-20, steareth-21, steareth-25, steareth Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyltrimonium Chloride, Stearoyl Glutamic Acid, Stearoyl Sarcosine, Stearyl Betaine, Stearyldimonium Hydroxypropyl Butyl Glucoside Chloride, Stearyldimonium Hydroxypropyl Decyl Glucoside Chloride, Stearyldimonium Hydroxypropyl Lauryl Glucoside Chloride, Castor Oil Sulfate, Coconut Sulfate Sunflower oil, glyceryl oleate sulfate, olive oil sulfate, peanut oil sulfate, sunflower amide MEA, sunflower seed acid, sunflower seed amide hydroxyethyldimonium chloride, sunflower seed oil glycereth-8 ester, tall oil acid, beef tallow acid, beef tallow amide propylamine oxide, beef tallow amide propyl betaine, beef tallow amide propyl hydroxysultaine, beef tallow amine oxide, beef tallow betaine, beef tallow dihydroxyethyl betaine, beef tallow ethyl glucoside, TEA-abietoyl hydrolyzed collagen, TEA-C12-14 alkyl phosphate,TEA-C10-15 alkyl sulfate, TEA-C11-15 alkyl sulfate, TEA-C12-13 alkyl sulfate, TEA-C12-14 alkyl sulfate, TEA-C12-15 alkyl sulfate, TEA-C14-17 alkyl disulfonic acid, TEA-canolate, TEA-cocamido diacetate, TEA-cocoate, TEA-cocosulfate, TEA-cocoyl alaninate, TEA-cocoyl glutamate, TEA-cocoyl glutamate, TEA-cocoyl glycinate, TEA-cocoyl hydrolyzed collagen, TEA-cocoyl hydrolyzed soy protein, TEA-cocoyl sarcosinate, dimethicone PEG-7 phosphate TEA, dodecylbenzenesulfonate TEA, hydrogenated cocoate TEA, water TEA-Taroyl Glutamate, TEA-Lostearate, TEA-Lostearoyl Hydrolyzed Collagen, TEA-Lauraminopropionate, TEA-Laurate, TEA-Laurate / Myristic Acid, TEA-Laureth Sulfate, TEA-Lauroyl Collagen Amino Acid Salt, TEA-Lauroyl Glutamate, TEA-Lauroyl Hydrolyzed Collagen, TEA-Lauroyl Keratin Amino Acid Salt, TEA-Lauroyl Methylaminopropionate, TEA-Lauroyl / Myristoyl Aspartate, TEA-Lauro Il sarcosinate, TEA-lauryl phosphate, TEA-lauryl sulfate, TEA-myristylaminopropionate, TEA-myristate, TEA-myristoyl hydrolyzed collagen, TEA-oleate, TEA-oleyl hydrolyzed collagen, TEA-oleyl sarcosinate, TEA-oleyl sulfate, TEA-palmitate, TEA-palm kernel sarcosinate, TEA-PEG-3 cocamide sulfate, EA-rosinate, TEA-stearate, TEA-talate, TEA-trid Sylbenzenesulfonate, TEA-undecylenate, TEA-undecylenoyl hydrolyzed collagen, tetramethyldecinediol, dicarboxyethyl stearyl sulfosuccinate tetrasodium, TIPA-laureth sulfate, TIPA-lauryl sulfate, TIPA-myristicate, TIPA-stearate, tocopheryl phosphate, trehalose undecylenoate, TM-C12-15 pareth-2 phosphate, TM-C12-15 pareth-6 phosphate, TM-C12-15 pareth-8 phosphate,TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Trideceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate, Tridecylbenzenesulfonic Acid, Trilaureth-9 Citrate, Trimethylolpropane Hydroxypropyl Bishydroxyethylamine Dendrimer, Lauroampho PG-Acetate Chloride Phosphate (Tri-Sodium) Undecanoic acid, undeceth-5 carboxylic acid, undecylamidopropylamine oxide, undecylamidopropyl betaine, undecylenic acid, undecylenol collagen amino acid, undecylenol glycine, undecylenol hydrolyzed collagen, undecylenol wheat amino acid, undecyl glucoside, wheat germ acid, wheat germ amidopropylamine oxide, wheat germ amidopropyl betaine, Yucca schidigera leaf / root / stem extract, Yucca schidigera stem extract, zinc coceth sulfate, and zinc coco-sulfate.

[0085] <Nonionic surfactants> Alcohol alkoxide. The added nonionic surfactant is preferably an alkoxylated and / or propoxylated primary alcohol having 8 to 18 carbon atoms and containing an average of 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per mole of alcohol. C8-C16 alcohol alkoxylates, advantageously ethoxylated and / or propoxylated C10-C15 alcohol alkoxylates, particularly C12-C14 alcohol alkoxylates, are especially preferred, with an ethoxylation degree of 2 to 10, preferably 3 to 8, and / or a propoxylation degree of 1 to 6, preferably 1.5 to 5. The cited ethoxylation and propoxylation degrees constitute statistically average values ​​and may be integers or fractions for a particular product. Preferred alcohol ethoxylates and propoxylates have a narrow homology distribution (narrow-range ethoxylate / propoxylate, NRE / NRP). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples of these include (fatty) fatty alcohols with 14EO, 16EO, 20EO, 25EO, 30EO, or 40EO.

[0086] Alkyl glycoside (APG® trademark). Furthermore, as an additional nonionic surfactant, an alkyl glycoside satisfying the general formula RO(G)x can be added, for example, as a compound with an anionic surfactant, where R means a primary linear or methyl-branched, particularly 2-methyl-branched, aliphatic group containing 8 to 22, preferably 12 to 18 carbon atoms, and G represents a glycose unit containing 5 or 6 carbon atoms, preferably glucose. The degree of oligomerization x, which defines the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10, preferably between 1.1 and 1.4.

[0087] Fatty acid ester alkoxylate. Another class of preferred nonionic surfactants, used alone or in combination with other nonionic surfactants, particularly with alkoxylated fatty alcohols and / or alkyl glycosides, is alkoxylated, preferably ethoxylated or ethoxylated and propoxylated, fatty acid alkyl esters containing preferably 1 to 4 carbon atoms in the alkyl chain, more specifically, fatty acid methyl esters produced by processes described, for example, Japanese Patent Application Publication No. S58-217598 or preferably international patent application WO 90 / 13533A. Methyl esters of C12 to C18 fatty acids containing an average of 3 to 15 EOs, particularly 5 to 12 EOs, are especially preferred.

[0088] Amine oxides. Amine oxide type nonionic surfactants, such as N-cocoalkyl-N,N-dimethylamine oxide, N-talualkyl-N,N-dihydroxyethylamine oxide, and fatty acid alkanolamides, can also be suitably used. The amount of these nonionic surfactants used is preferably less than or equal to the amount of ethoxylated fatty alcohol used, and particularly less than half of that amount.

[0089] Gemini surfactant. So-called gemini surfactants can be considered as a further category of surfactants. Generally, such compounds are understood to mean compounds having two hydrophilic groups and two hydrophobic groups per molecule. In principle, these groups are separated from each other by "spacers." The spacers are usually hydrocarbon chains, intended to be long enough so that the hydrophilic groups are far enough apart to act independently of each other. This type of surfactant is generally characterized by its unusually low critical micelle concentration and its ability to significantly reduce the surface tension of water. However, exceptionally, not only dimeric but also trimer surfactants are referred to as gemini surfactants. Suitable gemini surfactants are, for example, the sulfated hydroxy mixed ethers by DE4321022A1, or the dimeric alcohol bis- and trimer alcohol tris sulfates and ether sulfates by WO96 / 23768 A1. The block-terminated dimeric and trimer mixed ethers by DE19513391A1 are particularly characterized by their bifunctional and polyfunctional properties. Gemini polyhydroxy fatty acid amides or polyhydroxy fatty acid amides, as described in WO95 / 19953A1, WO95 / 19954A1, and WO95 / 19955A1, may also be used.

[0090] <Cationic surfactant> Tetraalkylammonium salt. Cationic surfactants consist of hydrophobic polymeric groups necessary for the surface activity of cations by dissociation in aqueous solution. An important group of representative cationic surfactants is the tetraalkylammonium salt with the general formula: (R1R2R3R4N+)X-, where R1 represents a C1 to C8 alkyl (alkenyl) group, and R2, R3, and R4 independently represent alkyl (alkenyl) radicals having 1 to 22 carbon atoms. X is a counterion, preferably selected from the group of halides, alkyl sulfates, and alkyl carbonates. Cationic surfactants in which the nitrogen group is substituted with two long acyl groups and two short alkyl (alkenyl) groups are particularly preferred.

[0091] Estherquat. A further class of cationic surfactants particularly useful as co-surfactants for the present invention is represented by so-called ester quats. Ester quats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of preparative organic chemistry. In this regard, WO91 / 01295A1 is referenced, which describes how triethanolamine is partially esterified with a fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate or ethylene oxide. Furthermore, DE4308794C1 describes a method for producing solid ester quats in which the quaternization of the triethanolamine ester is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0092] Typical examples of ester quats suitable for use according to the present invention are products in which the acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, where RCO is an acyl group containing 6 to 10 carbon atoms, and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid, and technical mixtures thereof such as so-called head-fractionated fatty acids. Ester quats derived from monocarboxylic acids in which the acyl component contains 8 to 10 carbon atoms are preferably used. Other ester quats are those in which the acyl component is derived from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. Overall, ester quats derived from a mixture of monocarboxylic acids containing 6 to 22 carbon atoms and adipic acid are preferably used. The molar ratio of monocarboxylic acid to dicarboxylic acid in the final ester quat may range from 1:99 to 99:1, preferably from 50:50 to 90:10, and more specifically from 70:30 to 80:20. Besides quaternized fatty acid triethanolamine ester salts, other suitable ester quats are quaternized ester salts of mono- / dicarboxylic acid mixtures with diethanolalkylamine or 1,2-dihydroxypropyldialkylamine. Ester quats can be obtained from fatty acids or from corresponding triglycerides mixed with the corresponding dicarboxylic acid. A representative example of relevant prior art is proposed in European Patent EP 0750606B1, which describes such a method. To produce quaternized esters, mixtures of mono- and dicarboxylic acids and triethanolamine (based on available carboxyl functional groups) can be used in molar ratios from 1.1:1 to 3:1. Considering the performance characteristics of ester quats, ratios of 1.2:1 to 2.2:1, preferably 1.5:1 to 1.9:1, have proven particularly advantageous. Preferred ester quats are technical mixtures of mono-, di-, and triesters with an average degree of esterification of 1.5 to 1.9.

[0093] <Amphoteric surfactants> Betaine compounds. Amphoteric surfactants, or amphoteric electrolytic surfactants, have multiple functional groups that can be ionized in aqueous solution, thereby conferring anionic or cationic properties to the compound depending on the conditions of the medium (see DIN 53900, July 1972). Near the isoelectric point (around pH 4), amphoteric surfactants form internal salts and become sparingly soluble or insoluble in water. Amphoteric surfactants are divided into amphoteric ions and betaine, the latter existing as zwitterions in solution. Amphoteric electrolytes are compounds that possess both acidic and basic hydrophilic groups and behave as acids or bases depending on the conditions. Betaine, in particular, is a well-known surfactant, mainly produced by carboxyalkylation, preferably carboxymethylation, of amine compounds. The starting material is preferably condensed with a halocarboxylic acid or a salt thereof, particularly sodium chloroacetate, to form a salt of 1 mole per mole of betaine. The addition of unsaturated carboxylic acids, such as acrylic acid, is also possible. Suitable examples of betaines are carboxyalkylation products of secondary amines, particularly tertiary amines, corresponding to the formula R1R2R3N-(CH2)qCOOX, where R1 is an alkyl radical having 6 to 22 carbon atoms, R2 is an alkyl group containing hydrogen or 1 to 4 carbon atoms, R3 is an alkyl group containing 1 to 4 carbon atoms, q is a number from 1 to 6, and X is an alkali metal and / or alkaline earth metal or ammonium. Typical examples include carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, C12 / 14-cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylmethylamine, oleyldimethylamine, C16 / 18-taloalkyldimethylamine and technical mixtures thereof, particularly dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine and technical mixtures thereof.

[0094] Alkylamide betaine. Other suitable betaines are carboxyalkylation products of amidoamines corresponding to the formula R1CO(R3)(R4)-NH-(CH2)PN-(CH2)QCOOX, where R1CO is an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, R2 is an alkyl radical having hydrogen or 1 to 4 carbon atoms, R3 is an alkyl radical having 1 to 4 carbon atoms, P is a number from 1 to 6, Q is a number from 1 to 3, and X is an alkali metal and / or alkaline earth metal or ammonium. Typical examples include reaction products of fatty acids having 6 to 22 carbon atoms, such as caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroseric acid, linoleic acid, elaeostearic acid, arachidonic acid, gadolic acid, behenic acid, erucic acid, and industrial mixtures thereof, with N,N-dimethylaminoethylamine, N,N-dimethylaminopropylamine, N,N-diethylaminoethylamine, and N,N-diethylaminopropylamine, which are condensed with sodium chloroacetate. Commercial products include Dehyton® K and Dehyton® PK (Cognis Deutschland GmbH & Co.KG), and Tego® Betaine (Goldschmidt).

[0095] Imidazolins. Other suitable starting materials for the betaines used in the purposes of the present invention are imidazolines. These substances are also known and can be obtained, for example, by cyclization condensation of 1 mole or 2 moles of a C6-C22 fatty acid with a polyfunctional amine such as aminoethylethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are condensation products of the above fatty acids with AEEA, preferably lauric acid-based imidazolines, which are then betained with sodium chloroacetate. A commercially available example is DEHYTON® G (Cognis Deutschland GmbH & Co.).

[0096] The amount of (co)surfactant in the composition of the present invention is advantageously 0.1% to 90% by weight, particularly 10% to 80% by weight, and especially preferably 20% to 70% by weight.

[0097] <Organic solvents> The liquid light or heavy detergent may contain an organic solvent, preferably one that is miscible with water. Polydiols, ethers, alcohols, ketones, amides and / or esters are used as organic solvents for this purpose, preferably in amounts of 0.1 to 90% by weight, preferably 0.1 to 70% by weight, and especially 0.1 to 60% by weight. Low molecular weight polar substances such as methanol, ethanol, propylene carbonate, acetone, acetonylacetone, diacetone alcohol, ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, glycerin, diethylene glycol, dipropylene glycol monomethyl ether and dimethylformamide or mixtures thereof are preferred.

[0098] <Enzyme> Cellulase enzyme. The cellulase enzyme optionally used in the detergent compositions of the present invention is incorporated at a level sufficient to provide up to about 5 mg by weight, more preferably about 0.01 mg to about 3 mg, of active enzyme per gram of composition, if present. Unless otherwise specified, the compositions herein preferably contain about 0.001% to about 5% by weight, more preferably 0.01% to 1% by weight, of a commercially available enzyme preparation.

[0099] Suitable cellulases for the present invention include bacterial cellulases or fungal cellulases. Preferably, their optimal pH is between 5 and 9.5. Suitable cellulases are fungal cellulases produced from Humicola Insolens and Humicola strain DSM1800, or cellulase 212-producing fungi belonging to the genus Aeromonas, and cellulases extracted from the hepatopancreas of marine mollusks (Dolabella Auricula Solander), suitable cellulases are also disclosed in GB2,075,028 A. Furthermore, cellulases particularly suitable for use in the present invention are disclosed in WO1992 / 013057A1. Most preferably, the cellulases used in the detergent compositions of the present invention are commercially purchased from NOVO Industries A / S under the product names CAREZYMEO and CELLUZYMEO.

[0100] Other enzymes Additional enzymes may be included in the detergent compositions herein for a wide variety of fabric washing purposes, including, for example, the removal of protein-based, carbohydrate-based, or triglyceride-based stains, the prevention of refugee dye migration, and the repair of fabrics. Examples of additional enzymes to be incorporated include proteases, amylases, lipases, peroxidases, and mixtures thereof. Other types of enzymes may also be included. These enzymes may be of any origin, such as plant, animal, bacterial, fungal, or yeast. However, their selection is governed by several factors, including optimal pH activity and / or stability, heat resistance, stability against active detergents, builder properties, and the potential to cause unpleasant odors during use. In this regard, bacterial or fungal enzymes, such as bacterial amylases and proteases, are preferred.

[0101] The enzyme is typically incorporated at a level sufficient to provide up to about 5 mg by weight per gram of composition, more typically from about 0.01 mg to about 3 mg of active enzyme. In other words, the compositions herein typically contain about 0.001% to about 5% by weight, preferably 0.01% to 1% by weight, of a commercially available enzyme preparation. The protease enzyme is usually present in such commercially available preparations at a level sufficient to provide 0.005 to 0.1 anson units (AU) of activity per gram of composition.

[0102] Suitable examples of proteases include subtilisin, obtained from specific strains of B. subtilis and B. licheniforms. Another suitable protease is obtained from a Bacillus strain with maximum activity in the pH range of 8 to 12 and is developed and marketed by Novo Industries A / S under the registered trademark ESPERASE®. Preparations of this enzyme and similar enzymes are described in Novo's GB1,243,784. Commercially available proteases suitable for removing protein-based stains include those marketed by Novo Industries A / S under the trade names ALCALASE® and SAVINASE®, and by International Bio-Synthetics, INC. under the trade name MAXATASE®. Other proteases include protease A; protease B, and proteases manufactured by Genencor International, Inc. according to US5,204,015 and US5,244,791.

[0103] Examples of amylases include α-amylases such as RAPIDASE® (manufactured by International Bio-Synthetics, Inc.) and TERMAMYL® (manufactured by Novo Industries).

[0104] Suitable lipase enzymes for detergent applications include those produced by Pseudomonas microorganisms, such as Pseudomonas Stutzeri ATCC 19154. This lipase is available from Amano Pharmaceutical Co., Ltd. under the trade name Lipase P "AMANO". Other commercially available lipases include Amano-CES, lipases derived from Chromobacter Viscosum, such as Chromobacter Viscosum Var. Lipolyticum NRRLB 3673, commercially available from Toyo Jozo Co., Ltd., CHROMOBACTER VISCOSUM lipase from US Biochemical Corp. and Disoynth Co., and lipases derived from Pseudomonas glazioli. The LIPOLASE® enzyme from HUMICOLA LANUGINOSA (commercially available from Novo Industries A / S) is a preferred lipase for use in this invention.

[0105] Peroxidase enzymes are used in combination with oxygen sources, such as percarbonates, perborates, persulfates, hydrogen peroxide, etc. Peroxidase enzymes are used to prevent dyes or pigments removed from a substrate during a "solution bleaching" or washing operation from migrating to other substrates in the washing solution. Peroxidase enzymes are known in the art and include, for example, horseradish peroxidase, ligninase, chloroperoxidase, and haloperoxidases such as bromoperoxidase. Peroxidase-containing detergent compositions are disclosed, for example, in WO1989 / 099813A1.

[0106] Enzyme stabilizer. The enzymes used herein are stabilized by the presence of a water-soluble source of calcium and / or magnesium ions in the finished detergent composition, supplying such ions to the enzyme. (Calcium ions are generally somewhat more effective than magnesium ions and are preferred herein when using only one type of cation). Further stability may be provided by the presence of various other technically disclosed stabilizers, particularly borates (see US 4,537,706, which is incorporated herein in whole). Typical detergent compositions, especially liquids, contain about 1 to about 30 mmol, preferably about 2 to about 20 mmol, more preferably about 5 to about 15 mmol, and most preferably about 8 to about 12 mmol of calcium ions per liter of the finished composition. In solid detergent compositions, the product may contain a water-soluble calcium ion source in an amount sufficient to supply such an amount to the laundry liquid. Alternatively, the hardness of natural water may suffice.

[0107] It is understood that the aforementioned levels of calcium and / or magnesium ions are sufficient to provide enzyme stability. Further addition of calcium and / or magnesium ions to the composition can further enhance the grease removal performance. Therefore, as a general suggestion, the compositions herein typically contain about 0.05% to about 2% by weight of a water-soluble source of calcium or magnesium ions, or both. Of course, the amount may vary depending on the amount and type of enzyme used in the composition.

[0108] The compositions herein may optionally, but preferably, include a variety of additional stabilizers, particularly borate stabilizers. Typically, such stabilizers are used in the composition in amounts of about 0.25% to about 10%, preferably about 0.5% to about 5%, and more preferably about 0.75% to about 3%, by weight of boric acid or other borate compounds capable of forming boric acid in the composition (calculated relative to boric acid). While boric acid is preferred, other compounds such as boron oxide, borax, and other alkali metal borates (e.g., orthoboric acid, metaboric acid, sodium pyroborate, and sodium pentaborate) are also suitable. Substituted boric acids (e.g., phenylboronic acid, butaneboronic acid, and p-bromophenylboronic acid) may also be used instead of boric acid.

[0109] <Builder> Zeolite. Synthetic zeolites containing bound water in microcrystalline form can be used as builders, for example, zeolites A and / or P are preferred. Zeolite MAP.RTM. (commercially available from Crosfield) is particularly preferred as zeolite P. However, zeolites X and mixtures of A, X, Y, and / or P are also suitable. Sodium / potassium aluminum silicate cocrystallized from zeolite A and zeolite X (available as Vegobond® RX. (commercially available from Condea Augusta SpA)) is also of particular interest. The zeolites can preferably be used as spray-dried powders. When the zeolites are added as a suspension, a small amount of nonionic surfactant, for example, 1 to 3% by weight, can be included as a stabilizer. Based on the zeolite, the suspension contains 10 to 20% by weight of ethoxylated C12-C18 fatty alcohols having 2 to 5 ethylene oxide groups, C12-C14 fatty alcohols having 4 to 5 ethylene oxide groups, or ethoxylated isotridecanol. A suitable zeolite has an average particle size of less than 10 μm (test method: volume distribution Coulter counter) and preferably contains 18 to 22% by weight, particularly 20 to 22% by weight, bound water. Separately, phosphates can also be used as builders.

[0110] Layered silicate. A suitable or partial substitute for phosphates and zeolites is crystalline layered sodium silicate. These types of crystalline layered silicates are described, for example, in EP0164514A1. Preferred crystalline layered silicates are obtained, for example, by the method described in WO91 / 08171A1.

[0111] Amorphous silicate. Preferred builders also include amorphous sodium silicate with a modulus (Na2O:SiO2 ratio) of 1:2 to 1:3.3, preferably 1:2 to 1:2.8, and more preferably 1:2 to 1:2.6, which exhibit slow dissolution and multiple wash cycle characteristics. Slow dissolution compared to conventional amorphous sodium silicate can be achieved by various methods such as surface treatment, compounding, compression / compression, or over-drying. In the context of this invention, the term “amorphous” also means “X-ray amorphous.” In other words, silicates do not produce the sharp X-ray reflections typical of crystalline materials in X-ray diffraction experiments, but at best produce one or more maxima of scattered X-rays with a diffraction angle width of several degrees. However, particularly excellent builder properties can be achieved even if the silicate particles produce indistinct or sharp diffraction maxima in electron diffraction experiments. This is interpreted as meaning that the product has microcrystalline regions ranging in size from 10 nm to several hundred nm, with values ​​up to 50 nm, and particularly up to 20 nm being preferred. This type of X-ray amorphous silicate dissolves similarly slowly compared to ordinary water glass, as described, for example, in DE4400024A1. Compressed / densified amorphous silicates, composite amorphous silicates, and excess dried X-ray amorphous silicates are particularly preferred.

[0112] Phosphate. In addition, commonly known phosphates can be added as builders unless their use should be avoided for ecological reasons. Sodium salts of orthophosphates, pyrophosphates, and especially tripolyphosphates are particularly suitable. Their content is generally 25% by weight or less, preferably 20% by weight or less, based on the finished composition. In some cases, tripolyphosphates in particular have been shown to provide a synergistic improvement in secondary cleaning power when combined with other builders, even at low amounts of up to 10% by weight, based on the finished composition. The preferred amount of phosphate is 10% by weight or less, especially 0% by weight.

[0113] <Cobuilder> Polycarboxylic acid. Useful organic cobuilders are polycarboxylic acids, for example, polycarboxylic acids usable in the form of sodium salts thereof, where polycarboxylic acid is understood to be a carboxylic acid carrying two or more acidic functions. These include, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA) and its derivatives and mixtures thereof. Preferred salts are salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.

[0114] organic acid. Acids themselves can also be used. In addition to their building effects, acids typically also possess the properties of acidifying components and therefore play a role in establishing a relatively low and mild pH in detergent or cleansing compositions. Citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid, and mixtures thereof are particularly noteworthy in this regard. More suitable acidifying agents are known pH adjusters such as sodium bicarbonate and sodium bisulfate.

[0115] polymer. Particularly suitable polymer cobuilders are polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. Due to their excellent solubility, a preferred representative of this group is also short-chain polyacrylates, which have a molecular weight of 2,000 to 10,000 g / mol, and more particularly 3,000 to 5,000 g / mol. Suitable polymers also include substances consisting of vinyl alcohol units or derivatives thereof, partially or entirely.

[0116] Further preferred copolymerizable polycarboxylates are copolymers of acrylic acid and methacrylic acid, and copolymers of acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid and maleic acid, consisting of 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid, have proven particularly suitable. The relative molecular weight based on free acid is generally in the range of 2,000 to 70,000 g / mol, preferably 20,000 to 50,000 g / mol, and particularly 30,000 to 40,000 g / mol. (Co)polymerizable polycarboxylates can be added as aqueous solutions or, preferably, as powders. To improve water solubility, the polymer may also contain allyl sulfonic acid, such as allyloxybenzenesulfonic acid and methallyl sulfonic acid, as monomers, e.g., EP0727448B1.

[0117] Biodegradable polymers consisting of two or more different monomer units are particularly preferred, examples of which include those consisting of acrylic acid and maleic acid salts, and vinyl alcohol or vinyl alcohol derivatives as monomers, as in DE4300772A1, or those consisting of acrylic acid and 2-alkylallyl sulfonic acid salts, and sugar derivatives as monomers. More preferred copolymers are those described in DE4303320A1 and DE4417734A1, which preferably contain acrolein and acrylic acid / acrylate, or acrolein and vinyl acetate as monomers.

[0118] Similarly, other preferred builders are high molecular weight aminodicarboxylic acids, their salts, or precursors. Polyaspartic acid or its salts and derivatives, disclosed in DE19540086A1, are particularly preferred as they possess bleach-stabilizing properties in addition to their co-building properties.

[0119] A more preferred builder is a polyacetal, which can be obtained by treating a dialdehyde with a polyol carboxylic acid having 5 to 7 carbon atoms and at least 3 hydroxyl groups, as described in EP0280223A1. Preferred polyacetals can be obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof, as well as from polycarboxylic acids such as gluconic acid and / or glucoheptonic acid.

[0120] carbohydrates. Further preferred organic cobuilders are dextrins, for example, oligomers or polymers of carbohydrates that can be obtained by partial hydrolysis of starch. Hydrolysis can be carried out using typical processes, such as acidic or enzyme-catalyzed processes. The hydrolysis product preferably has an average molecular weight in the range of 400 to 500,000 g / mol. Polysaccharides with a dextrose equivalent (DE) of 0.5 to 40, particularly 2 to 30, are preferred, where DE is an acceptable measure of the reducing effect of the polysaccharide compared to dextrose having a DE of 100. Maltodextrins with a DE of 3 to 20 and dry glucose syrup with a DE of 20 to 37, as well as relatively high molecular weight so-called yellow dextrins and white dextrins of 2,000 to 30,000 g / mol, can also be used. Preferred dextrins are described in UK Patent Application 94 19 091.

[0121] Such oxidized derivatives of dextrins relate to reaction products with oxidizing compositions that can oxidize at least one alcohol functional group of the saccharide ring to a carboxylic acid functional group. Such oxidized dextrins and methods for producing them are known, for example, from EP0232202A1. Products oxidized at C6 of the sugar ring are particularly advantageous.

[0122] Other derivatives of oxydisuccinate and disuccinate, preferably ethylenediamine disuccinate, are also more suitable cobuilders. Here, ethylenediamine-N,N'-disuccinate (EDDS), whose synthesis is described, for example, in US3,158,615, is preferably used in the form of its sodium or magnesium salt. In this context, glycerin disuccinate and glycerin trisuccinate are also particularly preferred, including, for example, those described in US4,524,009. Appropriate amounts added to zeolite-containing products and / or silicate-containing formulations range from 3 to 15% by weight.

[0123] Lactone. Other useful organic cobuilders include, for example, acetylated hydroxycarboxylic acids and their salts, which may optionally exist in the form of lactones, and which contain at least four carbon atoms, at least one hydroxyl group, and at most two acid groups. Such cobuilders are described, for example, in WO1995 / 020029A1.

[0124] <Bleaching compounds, bleaching agents, and bleaching activators> The detergent compositions herein may optionally contain a bleaching agent, or a bleaching composition comprising a bleaching agent and one or more bleaching activators. If present, the bleaching agent is typically present in an amount of about 1% to about 30%, more typically about 5% to about 20%, of the detergent composition, and is particularly intended for washing fabrics. If present, the amount of bleaching activators is typically present in an amount of about 0.1% to about 60%, more typically about 0.5% to about 40%, of the bleaching composition consisting of bleaching agent plus bleaching activators.

[0125] The bleaching agents used herein may be any bleaching agents currently known or becoming known that are useful in detergent compositions for textile cleaning, hard surface cleaning, or other cleaning purposes. These include oxygen-based bleaching agents and other bleaching agents. Perborate bleaching agents, such as sodium perborate (e.g., monohydrate or tetrahydrate), may be used herein.

[0126] Another classification of bleaches that can be used without restriction includes percarboxylic acid bleaches and their salts. Preferred examples of agents in this class include magnesium monoperoxyphthalate hexahydrate, magnesium salts of meta-chloroperbenzoic acid, 4-nonylamino-4-oxoperoxybutyric acid, and diperoxide decanedioic acid.

[0127] Peroxide bleaches can also be used. Suitable peroxide bleaches include sodium carbonate peroxyhydrate and equivalent "percarbonate" bleaches, sodium pyrophosphate peroxyhydrate, urea peroxyhydrate, and sodium peroxide. Persulfate bleaches (e.g., OXONEO®, marketed by DuPont) can also be used.

[0128] A preferred percarbonate bleach consists of dry particles having an average particle size in the range of about 500 μm to about 1,000 μm, wherein about 10% by weight or less of the particles are smaller than about 200 μm, and about 10% by weight or less of the particles are larger than about 1,250 μm. Optionally, the percarbonate can be coated with a silicate, borate, or water-soluble surfactant. Percarbonates are available from a variety of commercial sources.

[0129] A mixture of bleaching agents can also be used.

[0130] Peroxygen bleaches, perborates, and percarbonates are preferably combined with bleaching activators, thereby generating peroxy acids corresponding to the bleaching activator in aqueous solution (i.e., during the washing process) in situ. Nonanoyloxybenzenesulfonates (NOBS) and tetraacetylethylenediamine (TAED) activators are typical examples, and mixtures thereof can also be used.

[0131] Preferred amide-derived bleaching agents include (6-octaneamide caproyl)oxybenzenesulfonate, (6-nonanamide caproyl)oxybenzenesulfonate, (6-decanamide caproyl)oxybenzenesulfonate, and mixtures thereof.

[0132] Another class of bleaching activators consists of benzoxazine-type activators disclosed in US4,966,723, which is incorporated herein by reference.

[0133] Highly preferred lactam activators include benzoyl caprolactam, octanoyl caprolactam, 3,5,5-trimethylhexanoyl caprolactam, nonanoyl caprolactam, decanoyl caprolactam, undecenoyl caprolactam, benzoyl valerolactam, octanoyl valerolactam, decanoyl valerolactam, undecenoyl valerolactam, nonanoyl valerolactam, 3,5,5-trimethylhexanoyl valerolactam, and mixtures thereof, which are optionally adsorbed to a solid carrier, such as acyl caprolactam, preferably benzoyl caprolactam, and adsorbed to sodium perborate.

[0134] Other bleaching agents besides oxygen bleaching agents are also known in the art and can be used herein. Among the non-oxygen bleaching agents of particular interest are photoactivating bleaching agents such as zinc sulfonate and / or aluminum phthalocyanine. When used, the detergent composition typically contains about 0.025% to about 1.25% by weight of such bleaching agent, particularly zinc sulfonate phthalocyanine.

[0135] If necessary, the bleaching compound can be catalyzed with a manganese compound. Such manganese catalysts are well known in the art and include MnIV2(uO)3(1,4,7-trimethyl-1,4,7-triazacyclononane)2(PF6)2, MnIII2(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)2, MnIV4(uO)6(1,4,7-triazacyclononane)4(ClO4)4MnIIIMnIV4(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)3, MnIV(1,4,7-trimethyl-1,4,7-triazacyclononane)-(OCH3)3(PF6), and mixtures thereof.

[0136] For practical purposes, but not limited to, the compositions and processes described herein can be adjusted to supply at least 1 part in 10,000,000 of the active bleaching catalyst species to the aqueous laundry solution, preferably from about 0.1 ppm to about 700 ppm, more preferably from about 1 ppm to about 500 ppm, of the catalyst species to the laundry solution.

[0137] <Polymer-based stain remover> Any polymeric stain remover known to those skilled in the art may be optionally used in the detergent composition and method of the present invention. The polymeric stain remover is characterized by having both a hydrophilic segment that hydrophilizes the surface of hydrophobic fibers such as polyester and nylon, and a hydrophobic segment that is deposited on the hydrophobic fibers and remains attached there until the completion of the washing and rinsing cycle, and functions as an anchor for the hydrophilic segment. This makes it easier to wash away dirt generated after treatment with the stain remover in subsequent washing steps.

[0138] Polymeric stain removers useful in the present invention include, in particular, the following: (a) One or more nonionic hydrophilic components consisting essentially of the following: (i) Polyoxyethylene segments having a degree of polymerization of at least 2, or (ii) The hydrophilic segment is an oxypropylene or polyoxypropylene segment with a degree of polymerization of 2 to 10, which does not contain any oxypropylene units unless bonded to adjacent sites at each end by ether bonds, or (iii) A mixture of oxyalkylene units comprising oxyethylene and 1 to about 30 oxypropylene units, wherein the mixture comprises one or more nonionic hydrophilic components, preferably at least about 25% oxyethylene units, and more preferably, particularly in the case of such components comprising about 20 to 30 oxypropylene units, at least about 50% oxyethylene units; or (b) One or more hydrophobic components, (i) If the C3 oxyalkylene terephthalate segment is included and the hydrophobic component also includes oxyethylene terephthalate, the ratio of oxyethylene terephthalate to C3 oxyalkylene terephthalate units is approximately 2:2, and the ratio of C3 oxyalkylene terephthalate units is approximately 2:1 or less. (ii) C4-C6 alkylene or oxy C4-C6 alkylene segments, or mixtures thereof, (iii) A poly(vinyl ester) segment having at least 2 degrees of polymerization, preferably polyvinyl acetate), or (iv) comprising a C1-C4 alkyl ether or C4 hydroxyalkyl ether substituent, or a mixture thereof, wherein the substituent exists in the form of a C1-C4 alkyl ether or C4 hydroxyalkyl ether cellulose derivative, or a mixture thereof, and such cellulose derivative is amphiphilic, thereby having sufficient levels of C1-C4 alkyl ether and / or C4 hydroxyalkyl ether units to deposit on conventional polyester synthetic fibers, and once attached to such conventional synthetic fiber surface, retaining sufficient levels of hydroxyl groups to enhance the hydrophilicity of the fiber surface, or A combination of (a) and (b).

[0139] Typically, the polyoxyethylene segment of (a)(i) may have a degree of polymerization of about 200, preferably 3 to about 150, and more preferably 6 to about 100, although higher levels may be used. Suitable oxy C4-C6 alkylene hydrophobic segments include, but are not limited to, end caps for polymeric stain removers.

[0140] Polymeric stain removers useful in the present invention also include cellulose derivatives such as hydroxyether cellulose polymers, ethylene terephthalate or copolymer blocks of propylene terephthalate and polyethylene oxide or polypropylene oxide terephthalate. Such agents are commercially available and include cellulose hydroxyethers such as METHOCEL® (DOW). Cellulosic stain removers used in the present invention also include those selected from the group consisting of C1-C4 alkylcellulose and C4 hydroxyalkylcellulose.

[0141] Polymeric stain removers characterized by poly(vinyl ester) hydrophobic segments include graft copolymers of poly(vinyl ester), such as C1-C6 vinyl esters, preferably poly(vinyl acetate), grafted onto a polyalkylene oxide skeleton, such as a polyethylene oxide skeleton. See EP0 219048 incorporated herein.

[0142] A preferred polymeric soil remover is a copolymer having random blocks of ethylene terephthalate and polyethylene oxide (PEO) terephthalate. The molecular weight of this polymeric soil release agent is preferably in the range of about 25,000 to about 55,000.

[0143] Another preferred polymeric stain remover is a polyester having repeating units of ethylene terephthalate units, comprising 10 to 15% by weight of ethylene terephthalate units along with 90 to 80% by weight of polyoxyethylene terephthalate units, derived from polyoxyethylene glycol with an average molecular weight of 300 to 5,000. Examples of such polymers include the commercially available ZELCON® 5126 (manufactured by DuPont) and MILEASE® T (manufactured by ICI).

[0144] Another preferred polymeric defouling agent is a sulfonation product of a substantially linear ester oligomer consisting of an oligomeric ester skeleton of terephthaloyl and oxyalkylene oxy repeating units and terminal portions covalently bonded to the skeleton. These defouling agents are fully described in US4,968,451. Other preferred polymeric defouling agents include terephthalic acid polyesters of US4,711,730, anionic terminal-capped oligomeric esters of US4,721,580, block polyester oligomeric compounds of US4,702,857, and anionic, particularly sulfoaloyl, terminal-capped terephthalic acid esters of US4,877,896. All of these cited patents are incorporated herein in their entirety.

[0145] Another preferred fouling agent is an oligomer having repeating units of terephthaloyl units, sulfoisoterephthaloyl units, oxyethyleneoxy and oxy-1,2-propylene units. The repeating units form the backbone of the oligomer and are preferably terminated with modified isethionate end caps. A particularly preferred fouling agent of this type contains about one sulfoisophthaloyl unit, five terephthaloyl units in a ratio of about 1.7 to about 1.8, oxyethyleneoxy and oxy-1,2-propyleneoxy units, and two end cap units of sodium 2-(2-hydroxyethoxy)-ethanesulfonate. The fouling agent also contains about 0.5% to about 20% of a crystal reduction stabilizer relative to the weight of the oligomer, preferably selected from the group consisting of xylenesulfonic acid, cumenesulfonic acid, toluenesulfonic acid, and mixtures thereof.

[0146] When used, the stain remover generally constitutes about 0.01% to about 10.0% by weight, typically about 0.1% to about 5%, preferably about 0.2% to about 3.0%, of the detergent composition as described herein.

[0147] <Polymer dispersant> Polymer dispersants can be advantageously used in the detergent compositions herein at levels ranging from about 0.1% to about 7% by weight, particularly in the presence of zeolite and / or layered silicate builders. Suitable polymer dispersants include polymer polycarboxylates and polyethylene glycols, but others known in the art may also be used. While not intended to be theoretical, polymer dispersants, when used in combination with other builders (including low molecular weight polycarboxylates), are thought to enhance the overall performance of the detergent builder by inhibiting crystal growth, suppressing the release of particulate soil, and preventing redeposition.

[0148] Polymer polycarboxylate materials can be produced by polymerizing or copolymerizing suitable unsaturated monomers, preferably in the form of an acid. Unsaturated monomeric acids that can be polymerized to form suitable polymer polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid, and methylenemalonic acid. The polymer polycarboxylates or monomer segments herein do not contain carboxylate radicals such as vinyl methyl ether, styrene, and ethylene, although it is appropriate for such segments to be present as long as they do not exceed about 40% by weight.

[0149] Particularly suitable polymeric polycarboxylates can be derived from acrylic acid. Such acrylic acid-based polymers useful in the present invention are water-soluble salts of polymerized acrylic acid. The average molecular weight of such polymers in acidic form is preferably in the range of about 2,000 to 10,000, more preferably about 4,000 to 7,000, and most preferably about 4,000 to 5,000. Water-soluble salts of such acrylic acid polymers include, for example, alkali metal, ammonium, and substituted ammonium salts. This type of soluble polymer is a known material. The use of this type of polyacrylate in detergent compositions is disclosed, for example, in US 3,308,067.

[0150] Acrylic acid / maleic acid copolymers can also be used as preferred components of dispersants / anti-reprecipitation agents. Examples of such materials include water-soluble salts of copolymers of acrylic acid and maleic acid. The average molecular weight of the acid form of such copolymers is preferably in the range of about 2,000 to 100,000, more preferably about 5,000 to 75,000, and most preferably about 7,000 to 65,000. The ratio of acrylate segments to maleic acid segments in such copolymers is generally in the range of about 30:1 to about 1:1, more preferably about 10:1 to 2:1. Examples of water-soluble salts of such acrylic acid / maleic acid copolymers include alkali metal salts, ammonium salts, and substituted ammonium salts. This type of soluble acrylic acid / maleic acid copolymer is a known material described in EP0193360A1, which also describes such polymers consisting of hydroxypropyl acrylate. Other useful dispersants include maleic acid / acrylic acid / vinyl alcohol terpolymers, such as acrylic acid / maleic acid / vinyl alcohol 45 / 45 / 10 terpolymers.

[0151] Another polymer material that can be included is polyethylene glycol (PEG). PEG can exhibit dispersant properties and act as a clay stain remover and anti-re-adhesion agent. Typical molecular weight ranges for these purposes are about 500 to about 100,000, preferably about 1,000 to about 50,000, and more preferably about 1,500 to about 10,000.

[0152] Polyaspartic acid and polyglutamic acid dispersants can also be used in combination with zeolite builders. Dispersants such as polyaspartic acid preferably have a molecular weight (average) of about 10,000.

[0153] <Foam inhibitors / Foam suppressants> When used in automated cleaning processes in particular, it is advantageous to add conventional anti-foaming agents to the composition. Suitable anti-foaming agents include, for example, natural or synthetic soaps containing a large amount of C18-C24 fatty acids. Suitable non-surface-active anti-foaming agents include, for example, mixtures thereof with organopolysiloxanes and fine, optionally silanized silica, as well as mixtures thereof with paraffin, wax, microcrystalline wax and silanized silica or bis-stearylethylenediamide. Mixtures of various anti-foaming agents, such as mixtures of silicone, paraffin, or wax, are also advantageous. Preferably, the anti-foaming agent, particularly silicone-containing anti-foaming agents and / or paraffin-containing anti-foaming agents, is supported on a granular, water-soluble, or dispersible carrier material. In particular in this case, a mixture of paraffin and bis-stearylethylenediamide is preferred.

[0154] Compounds for reducing or suppressing soap foam formation can be incorporated into the detergent composition of the present invention. Suppression of soap foam may be particularly important in so-called "high-concentration washing processes" and in front-loading European-style washing machines.

[0155] A wide variety of materials can be used as foam inhibitors, and foam inhibitors are well known to those skilled in the art. For example, see KIRK OTHMER ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY, THIRD EDITION, VOLUME 7, PAGES 430-447 (JOHN WILEY & SONS, INC., 1979). One category of foam inhibitors of particular interest includes monocarboxylic acid fatty acids and their soluble salts. Monocarboxylic acid fatty acids and their salts used as foam inhibitors typically have a hydrocarbyl chain of 10 to about 24 carbon atoms, preferably 12 to 18 carbon atoms. Suitable salts include alkali metal salts such as sodium salts, potassium salts, and lithium salts, as well as ammonium salts and alkanolammonium salts.

[0156] The detergent compositions herein may also contain non-surfactant foam inhibitors. These include, for example, high molecular weight hydrocarbons such as paraffins, fatty acid esters (e.g., fatty acid triglycerides), fatty acid esters of monohydric alcohols, and aliphatic C18-C40 ketones (e.g., stearone). Other streaks inhibitors include N-alkylated aminotriazines such as tri- to hexa-alkylmelamine or di- to tetra-alkyldiamine chlortriazines, propylene oxides formed as products of cyanuryl chloride with 2 to 3 moles of a primary or secondary amine containing 1 to 24 carbon atoms, and monostearyl phosphate esters such as monostearyl alcohol phosphate esters and monostearyl di-alkali metal (e.g., K, Na, and Li) phosphate esters and phosphate esters. Hydrocarbons such as paraffins and haloparaffins can be used in liquid form. Liquid hydrocarbons are liquid at room temperature and atmospheric pressure, have a pour point in the range of about -40°C to about 50°C, and a minimum boiling point of about 110°C (at atmospheric pressure) or higher. Preferably, waxy hydrocarbons having a melting point of about 100°C or less are also known to be used. Hydrocarbon foam inhibitors are known in the art and include aliphatic, alicyclic, aromatic, and heterocyclic saturated or unsaturated hydrocarbons having about 12 to about 70 carbon atoms. The term “paraffin” as used in this discussion of foam inhibitors is intended to include mixtures of true paraffins and cyclic hydrocarbons.

[0157] Another preferred category of non-surfactant foam inhibitors is silicone-based foam inhibitors. This category includes the use of polyorganosiloxane oils such as polydimethylsiloxane, dispersions or emulsions of polyorganosiloxane oils or resins, and combinations of polyorganosiloxane and silica particles in which the polyorganosiloxane is chemiadsorbed or fused to silica. Silicone-based foam inhibitors are well known in the art.

[0158] Other silicone foam inhibitors are disclosed in US3,455,839, which is entirely incorporated herein, relating to compositions and processes for defoaming aqueous solutions by incorporating a small amount of polydimethylsiloxane fluid therein.

[0159] A mixture of silicone and silica silane is described, for example, in DE-OS2124526, which is incorporated herein in whole. Silicone defoamers and sud control agents in granular detergent compositions are disclosed in US4,652,392, which is incorporated herein in whole.

[0160] In preferred silicone foam inhibitors used herein, the solvent of the continuous phase consists of a specific polyethylene glycol or polyethylene-polypropylene glycol copolymer or a mixture thereof (preferably), or polypropylene glycol. The main silicone foam inhibitor is branched / crosslinked and preferably not linear.

[0161] The silicone foam inhibitors used herein preferably consist of polyethylene glycol and polyethylene glycol / polypropylene glycol copolymers, all having an average molecular weight of less than about 1000, preferably between about 100 and 800. The polyethylene glycol and polyethylene / polypropylene glycol copolymers used herein have a solubility in water at room temperature of about 2% by weight or more, preferably about 5% by weight or more.

[0162] Preferred solvents in this specification are polyethylene glycol having an average molecular weight of less than about 1000, more preferably between about 100 and 800, and most preferably between 200 and 400, and polyethylene glycol / polypropylene glycol copolymers, preferably PPG200 / PEG300. Preferably, the weight ratio of polyethylene glycol to polyethylene-polypropylene glycol copolymer is between about 1:1 and 1:10, most preferably between 1:3 and 1:6.

[0163] Preferred silicone foam inhibitors used herein do not contain polypropylene glycol with a molecular weight of 4,000. They also preferably do not contain ethylene oxide-propylene oxide block copolymers such as PLURONIC® L101.

[0164] Other foam inhibitors useful herein consist of secondary alcohols (e.g., 2-alkyl alkanols) and mixtures of such alcohols with silicone oils. Examples of secondary alcohols include C6-C16 alkyl alcohols having C1-C16 chains. A preferred alcohol is 2-butyl octanol, available from CONDEA under the trademark ISOFOL® 12. Mixtures of secondary alcohols are available from ENICHEM under the trademark ISALCHEM® 123. Mixed foam inhibitors typically consist of an alcohol-silicone mixture in a weight ratio of 1:5 to 5:1.

[0165] The compositions herein generally contain 0% to about 5% of foam inhibitors. When used as foam inhibitors, monocarboxylic acid fatty acids and their salts are commonly present in amounts up to about 5% by weight of the detergent composition. Preferably, about 0.5% to about 3% of fatty monocarboxylic acid foam inhibitors are used. Silicone foam inhibitors are typically used in amounts up to about 2.0% by weight of the detergent composition, although higher amounts may also be used. This upper limit is practical, mainly due to concerns about minimizing costs and the effectiveness of low amounts in effectively controlling foaming. Preferably, about 0.01% to about 1% of silicone foam inhibitors are used, more preferably about 0.25% to about 0.5%. When used herein, these weight percentage values ​​include any silica that can be used in combination with polyorganosiloxanes, and any auxiliary materials that can be used. Monostearyl phosphate foam inhibitors are generally used in amounts from about 0.1% to about 2% by weight of the composition. Hydrocarbon foam inhibitors are generally used in amounts ranging from about 0.01% to about 5.0%, although higher levels can also be used. Alcohol foam inhibitors are typically used in amounts ranging from 0.2% to 3% by weight of the finished composition.

[0166] <Metal ion sequestering agents and chelating agents> Salts of polyphosphonic acids can be considered as metal ion sequestering agents or stabilizers for peroxide compounds and enzymes that are particularly sensitive to heavy metal ions. Here, for example, sodium salts of 1-hydroxyethane-1,1-diphosphonate, diethylenetriaminepentamethylenephosphonate, or ethylenediaminetetramethylenephosphonate are used in amounts from 0.1 to 5% by weight.

[0167] The detergent compositions herein may optionally contain one or more iron and / or manganese chelating agents. Such chelating agents can be selected from the group consisting of aminocarboxylates, aminophosphonates, polyfunctionally substituted aromatic chelating agents and mixtures thereof, all of which are defined below. While we do not intend to be bound by theory, the advantages of these substances are thought to be partly due to their exceptional ability to remove iron and manganese ions from cleaning solutions by forming soluble chelates. It is understood that some of the aforementioned detergent builders can function as chelating agents, and that if such detergent builders are present in sufficient quantities, they can provide both functions.

[0168] Examples of aminocarboxylates useful as chelating agents include ethylenediaminetetraacetate, N-hydroxyethylethylenediamine triacetate, nitrilotriacetate, ethylenediaminetetrapropionate, triethylenetetraamine hexaacetate, diethylenetriamine pentaacetate, and ethanol diglycine, their alkali metal, ammonium, and substituted ammonium salts, and mixtures thereof.

[0169] Aminophosphonates are also suitable as chelating agents in the compositions of the present invention, provided that the total phosphorus content in the detergent composition is at least low, and include ethylenediaminetetrakis(methylenephosphonate) as DEQUEST. Preferably, these aminophosphonates do not contain alkyl or alkenyl groups having more than about 6 carbon atoms.

[0170] Polyfunctional substituted aromatic chelating agents are also useful in the compositions of this specification. Preferred compounds of this type in the form of acids are dihydroxydisulfobenzenes, such as 1,2-dihydroxy-3,5-disulfobenzene.

[0171] Preferred biodegradable chelating agents used herein are ethylenediamine disuccinates ("EDDS"), particularly the [S,S] isomer.

[0172] When these chelating agents are used, they generally constitute about 0.1% to about 10% by weight of the detergent composition herein. More preferably, when chelating agents are used, they constitute about 0.1% to about 3.0% by weight of such composition.

[0173] <Clay stain remover / anti-re-adhesion agent> The detergent compositions of the present invention may optionally contain water-soluble ethoxylated amines having properties for removing clay stains and preventing re-adhesion. Granular detergent compositions containing these compounds typically contain water-soluble ethoxylated amines in an amount of about 0.01% to about 10.0% by weight, while liquid detergent compositions typically contain them in an amount of about 0.01% to about 5%.

[0174] The most preferred descaling and anti-redeposition agent is ethoxylated tetraethylenepentamine. Exemplary ethoxylated amines are further described in US4,597,898. Other groups of preferred clay descaling and anti-redeposition agents include cationic compounds disclosed in EP0111965A1, ethoxylated amine polymers disclosed in EP0111984A1, amphoteric polymers disclosed in EP0112592A1, and amine oxides disclosed in US4,548,744. Another type of preferred anti-redeposition agent includes carboxymethylcellulose (CMC) materials. These materials are well known in the art.

[0175] <Graying prevention agent> Graying inhibitors have the function of keeping dirt removed from fibers suspended in the cleaning solution, thereby preventing the dirt from re-adhering. Suitable for this purpose are mainly organic water-soluble colloids, such as water-soluble salts of (co)polymer carboxylic acids, adhesives, gelatin, ether carboxylic acids or ether sulfonic acid salts of starch or cellulose, or acidic sulfate ester salts of cellulose or starch. Water-soluble acid-containing polyamides are also suitable for this purpose. Furthermore, soluble starch preparations can also be used as the above-mentioned starches, such as decomposed starch and aldehyde starch. Polyvinylpyrrolidone can also be used. However, the use of cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof, as well as polyvinylpyrrolidone, is preferred, and these can be added, for example, in an amount of 0.1 to 5% by weight based on the composition.

[0176] <Fluorescent whitening agents and UV adsorbents> Any fluorescent whitening agent or other whitening or brightening agent known in the art can be incorporated into the detergent compositions herein, typically at levels of about 0.05% to about 1.2% by weight. Commercially available fluorescent whitening agents useful in the present invention can be classified into subgroups including, but are not limited to, stilbenes, pyrazolines, coumarins, carboxylic acids, methyncyanines, dibenzothiophene-5,5-dioxide, azoles, five-membered and six-membered heterocyclic compounds, and other miscellaneous agent derivatives.

[0177] Preferred whitening agents include those from VERONA's PHORWHITE® series. Other whitening agents disclosed in this document include: TINOPAL® UNPA, TINOPAL CBS, and TINOPAL 5BM; available from CIBA-GEIGY; ARTIC WHITE® CC and ARTIC WHITE CWD; available from HILTON-DAVIS; 2-(4-strylphenyl)-2H-naphthol[1,2-D]triazole; 4,4'-bis-(1,2,3-triazol-2-yl)-stilbene; 4,4'-bis(stryl)bisphenyl; and aminocoumarin. Specific examples of these whitening agents include 4-methyl-7-diethyl-aminocoumarin; 1,2-bis(-benzimidazole-2-yl)ethylene; 1,3-diphenyl-furazoline; 2,5-bis(benzoxazole-2-yl)thiophene; 2-stryl-naphtho-[1,2-D]oxazole; and 2-(stilben-4-yl)-2H-naphtho-[1,2-D]triazole. In this specification, anionic glossing agents are preferred.

[0178] The composition may contain, for example, a derivative of diaminostilbenndisulfonic acid or an alkali metal salt thereof as a fluorescent whitening agent. Suitable fluorescent whitening agents include, for example, salts of 4,4'-bis-(2-anilino-4-morpholino-1,3,5-triazinyl-6-amino)stilbenn-2,2'-di-sulfonic acid, or compounds with similar structures containing a diethanolamino group, methylamino group, anilino group, or 2-methoxyethylamino group instead of a morpholino group. Substituted diphenylstyryl type whitening agents may also exist, such as alkali metal salts of 4,4'-bis(2-sulfostyryl)diphenyl, 4,4'-bis(4-chloro-3-sulfostyryl)diphenyl, or 4-(4-chlorostyryl)-4'-(2-sulfostyryl)diphenyl. Mixtures of the whitening agents mentioned may also be used.

[0179] Furthermore, UV adsorbents can be added. These are compounds with a clear ability to absorb ultraviolet light, and by protecting against UV radiation penetrating the fibers, they not only improve the photostability of colorants and pigments for the skin of the wearer of the textile product, but also contribute as UV stabilizers. Generally, efficient non-radioactive inactivating compounds are mainly benzophenone derivatives substituted with hydroxyl and / or alkoxy groups at the 2 and / or 4 positions. Also suitable are substituted benzotriazoles, acrylates (cinnamic acid derivatives) with a phenyl substitution at the 3 position, acrylates optionally having a cyano group at the 2 position, salicylates, organic NI complexes, and natural substances such as umbelliferone and endogenous urocanic acid. In preferred embodiments, the UV adsorbents absorb UV-A and UV-B radiation and possible UV-C radiation and re-emit blue wavelength light, thus they also have a fluorescence whitening effect. Preferred UV adsorbents include triazine derivatives, such as hydroxyaryl-1,3,5-triazine, sulfonated 1,3,5-triazine, O-hydroxyphenyl-benzo¬triazole and 2-aryl-2H-benzotriazole, as well as bis(anilinotriazinyl-amino)stilbendisulfonic acid and their derivatives. UV-absorbing pigments such as titanium dioxide can also be used as UV adsorbents.

[0180] <Dye transfer inhibitors> The detergent composition of the present invention may also contain one or more materials effective in inhibiting the transfer of dye from one fabric to another during the washing process. Generally, such dye transfer inhibitors include polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese phthalocyanines, peroxidases, and mixtures thereof. When used, these dye transfer inhibitors typically occupy about 0.01% to about 10% by weight, preferably about 0.01% to about 5% by weight, and more preferably about 0.05% to about 2% by weight of the composition.

[0181] More specifically, polyamine N-oxide polymers preferred for use herein are described in US6,491,728, which is incorporated herein by reference.

[0182] Any polymer backbone can be used as long as the formed amine oxide polymer is water-soluble and has dye transfer inhibitory properties. Examples of suitable polymer backbones are polyvinyl, polyalkylene, polyester, polyether, polyamide, polyimide, polyacrylate, and mixtures thereof. These polymers include random or block copolymers in which one monomer is an amine N-oxide and the other monomer is an N-oxide. Amine N-oxide polymers typically have an amine-to-amine N-oxide ratio of 10:1 to 1:1,000,000. However, the number of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerization or appropriate degree of N-oxidation. Polyamine oxides can be obtained at almost any degree of polymerization. Typically, the average molecular weight is in the range of 500 to 1,000,000; more preferably 1,000 to 500,000; most preferably 5,000 to 100,000. This preferred class of materials can be called "PVNO".

[0183] The most preferred polyamine N-oxide useful in the detergent compositions of this specification is poly(4-vinylpyridine-N-oxide) having an average molecular weight of about 50,000 and an amine-to-amine N-oxide ratio of about 1:4.

[0184] Copolymers of N-vinylpyrrolidone and N-vinylimidazole polymers (collectively referred to as "PVPVI") are also preferred for use herein. Preferably, PVPVI has an average molecular weight in the range of 5,000 to 1,000,000, more preferably 5,000 to 200,000, and most preferably 10,000 to 20,000. PVPVI copolymers typically have a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of 1:1 to 0.2:1, more preferably 0.8:1 to 0.3:1, and most preferably 0.6:1 to 0.4:1. These copolymers may be linear or branched.

[0185] The compositions of the present invention may also use polyvinylpyrrolidone ("PVP") having an average molecular weight of about 5,000 to about 400,000, preferably about 5,000 to about 200,000, and more preferably about 5,000 to about 50,000. PVP is known to those skilled in the field of detergents. The compositions containing PVP may also contain polyethylene glycol ("PEG") having an average molecular weight of about 500 to about 100,000, preferably about 1,000 to about 10,000. The ppm-based ratio of PEG to PVP supplied to the cleaning solution is preferably about 2:1 to about 50:1, and more preferably about 3:1 to about 10:1.

[0186] The detergent compositions herein may also optionally contain certain hydrophilic fluorescent whitening agents, in amounts of about 0.005% to 5% by weight, which also provide dye migration inhibitory properties. When used, the compositions herein preferably contain about 0.01% to 1% by weight of such fluorescent whitening agents.

[0187] One preferred whitening agent is 4,4',-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-S-triazine-2-yl)amino]-2,2'-stilbendisulfonic acid and its disodium salt. This particular type of brightener is commercially available from CIBA-GEIGY CORPORATION under the trade name TINOPAL-UNPA-GX®. TINOPAL-UNPA-GX is a preferred hydrophilic fluorescent whitening agent useful in the detergent compositions described herein.

[0188] Another preferred whitening agent is 4,4'-bis[(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-S-triazine-2-yl)amino]2,2'-stilbendisulfonate disodium salt. This particular whitening agent is marketed by CIBA-GEIGY under the trade name TINOPAL 5BM-GX®.

[0189] Another preferred whitening agent is 4,4'-bis[(4-anilino-6-morphilino-S-triazine-2-yl)amino]2,2'-stilbendisulfonic acid, sodium salt. This particular type of glossing agent is commercially marketed by CIBA-GEIGY under the trade name TINOPAL AMS-GX®.

[0190] The specific fluorescent whitening agent species selected for use in the present invention offer particularly effective dye transfer inhibition advantages when used in combination with the selected polymeric dye transfer inhibitors described herein. The combination of such selected polymer materials (e.g., PVNO and / or PVPVI) and such selected fluorescent whitening agents (e.g., TINOPAL UNPA-GX, TINOPAL 5BM-GX, and / or TINOPAL AMS-GX) provides significantly better dye transfer inhibition in aqueous cleaning solutions than either of these two detergent composition components used alone. Without being bound by theory, it is thought that such whitening agents function in this way because they have a high affinity for fabrics in the cleaning solution and therefore deposit relatively quickly on these fabrics. The degree to which a whitening agent adheres to the fabric in the cleaning solution can be defined by a variable called the "abandonment coefficient." The abandonment coefficient is generally the ratio of a) the whitening agent material attached to the fabric to b) the initial whitening agent concentration in the cleaning solution. In the present invention, whitening agents with a relatively high abandonment coefficient are most suitable for inhibiting dye transfer.

[0191] Of course, it will be understood that other conventional fluorescent whitening agent compounds can be optionally used in this composition to provide a conventional "whitening" effect on fabrics, rather than a true dye transfer inhibitory effect. Such uses are conventionally known in detergent products.

[0192] <Thickening agent> The composition may also include general thickeners and anti-deposition compositions, as well as viscosity modifiers such as polyacrylates, polycarboxylic acids, polysaccharides and their derivatives, polyurethanes, polyvinylpyrrolidone, castor oil derivatives, quaternized and / or ethoxylated hexamethylenediamine and other polyamine derivatives, and any mixtures thereof. Preferred compositions have a viscosity of 10,000 mPa*s or less, as measured with a Brookfield viscometer at a temperature of 20°C and a shear rate of 50 min-1.

[0193] <Inorganic salts> Further preferred components of the composition are water-soluble inorganic salts such as bicarbonates, carbonates, amorphous silicates, or mixtures thereof; alkali carbonates and amorphous silicates are particularly used, mainly sodium silicates with a molar ratio of Na2O:SiO2 of 1:1 to 1:4.5, preferably 1:2 to 1:3.5. Preferred compositions contain alkali salts, builders and / or cobuilders, preferably sodium carbonate, zeolites, crystalline, layered sodium silicates and / or trisodium citrate in amounts of anhydrous substances of 0.5 to 70% by weight, preferably 0.5 to 50% by weight, and especially 0.5 to 30% by weight.

[0194] <Fragrances and colorants> The composition may further contain typical detergent and cleansing composition components such as fragrances and / or colorants, preferably colorants that do not leave any or are negligible color on the fabric being washed. The preferred total amount of colorant added is 1% by weight or less, preferably 0.1% by weight or less, based on the composition. The composition may also contain a white pigment, such as TiO2. [Industrial applicability]

[0195] Another object of the present invention relates to a method for increasing, improving, and / or adjusting the fragrance of a fragrance that originally has balsamic and / or leather notes, comprising or consisting of the following steps: (a) The process of providing at least one first fragrance with notes of balsamic vinegar and / or leather; (b) A step of providing p-tolylmethanol; (c) Adding to at least the first fragrance an amount of p-tolylmethanol sufficient to increase, improve and / or modulate the original scent notes of the first fragrance.

[0196] The use of p-tolylmethanol is also claimed for increasing, improving and / or modulating the fragrance of fragrances which originally have balsamic and / or leathery fragrance notes.

[0197] To avoid any doubt, it should be noted that all of the preferred embodiments already described above, in particular the mixtures, combinations, amounts used, etc., are common to the processes claimed as well as to the use claimed, so there is no need to repeat them. Further, the indication of an effective amount preferably means the addition of from about 0.1% to about 2% by weight, preferably from about 0.5% to about 1% by weight of p-tolylmethanol relative to said first fragrance.

[0198] The ultimate object of the present invention relates to the use of p-tolylmethanol as a fragrance.

Examples

[0199] <Examples 1 to 16> Fragrance modification by addition of p-tolylmethanol

[0200] Small amounts of p-tolylmethanol (pTM) from 0.1% to 1% by weight were added to various first fragrances having balsamic or leathery notes. As a result, fragrance modification was determined by 5 experienced perfumers. The results are shown in Table 1. Fragrance modification by addition of p-tolylmethanol

Table 8-1

Table 8-2

[0201] Tables 2 to 4 below show typical fragrance compositions containing p-tolylmethanol. Fragrance Composition I [Table 9]

[0202] The evaluation was conducted in 10% ethanol. Compared to the fragrance composition without pTM, the new fragrance blend is more harmonious. The caramel facet is stronger, and the presence of pTM enhances the cappuccino character. The pyrazine component is balanced and no longer dominant. Fragrance Composition II [Table 10]

[0203] The evaluation was conducted in 10% ethanol. Adding pTM changed the leather notes from smooth leather to suede. The blend became softer, and the birch tar notes decreased. pTM harmonized the notes and improved performance. Fragrance Composition III [Table 11]

[0204] The evaluation was conducted at 11% in the deodorant (aerosol). pTM reduces technical solvent notes, bringing more gourmand and leather facets to the fragrance without shifting the fragrance in a different direction or interfering with the deodorant profile. Overall performance was also improved.

Claims

1. (a) at least one first fragrance having balsamic and / or leather scent notes, (b) p-tolylmethanol (pTM) and (c) At least one solvent selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol, and triethyl citrate, A fragrance mixture containing or consisting solely of [the specified element].

2. The fragrance mixture according to claim 1, wherein the first fragrance is selected from the group consisting of ethyl vanillin, vanillin, propenyl guaetol, coumarin delta octalactone, benzyl cinnamate, 3-phenylpropanol, methyl lytone, furaneol, isopropylcyclohexanol, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1-penten-3-one, cade oil, styrax oil, 2,3,3-trimethylindanone, butylquinoline, isobutylquinoline, and mixtures thereof.

3. The fragrance mixture according to claim 1, wherein the first fragrance and the p-tolylmethanol (pTM) are present in an amount ranging from 98:2% by weight to 99.9:0.5% by weight relative to the mixture.

4. The fragrance mixture according to claim 1, wherein the p-tolylmethanol (pTM) is present in an amount ranging from 0.1 to 2% by weight relative to the mixture.

5. The fragrance mixture according to claim 4, wherein the p-tolylmethanol (pTM) is present in an amount ranging from 0.5 to 1% by weight relative to the mixture.

6. The fragrance mixture according to claim 1, wherein the solvent is present in the mixture in an amount ranging from 10 to 90% by weight.

7. A fragrance composition comprising the mixture described in claim 1 and at least one second fragrance different from the first fragrance and the pTM.

8. The fragrance composition according to claim 7, wherein the second fragrance is selected from the group consisting of the following. Table 1-1 Table 1-2 Table 1-3 Table 1-4 Table 1-5

9. The fragrance composition according to claim 7, wherein either the pTM or the fragrance mixture described in claim 1 is present in an amount ranging from 0.01 to 2% by weight relative to the fragrance composition.

10. A cosmetic or personal care product comprising the fragrance mixture of claim 1 or the fragrance composition of claim 7.

11. A detergent product comprising the fragrance mixture of claim 1 or the fragrance composition of claim 7.

12. A formulation comprising 0.01 to 2% by weight of the fragrance mixture described in claim 1 or the fragrance composition described in claim 7. The personal care product according to claim 10 or the detergent product according to claim 11.

13. A method for increasing, improving, and / or adjusting the scent of a fragrance that originally has balsamic and / or leather notes: (a) A step of providing at least one first fragrance with notes of balsamic vinegar and / or leather, (b) A step of providing p-tolylmethanol, including or consisting of A method comprising adding to at least the first fragrance an amount of p-tolylmethanol sufficient to increase, improve and / or modulate the original scent notes of the first fragrance.

14. The method according to claim 13, wherein the p-tolylmethanol (pTM) is added to the first fragrance in an amount ranging from 0.1 to 2% by weight.

15. The method according to claim 14, wherein the p-tolylmethanol (pTM) is added to the first fragrance in an amount ranging from 0.5 to 1% by weight.

16. The use of p-tolylmethanol to enhance, improve, and / or modulate the fragrance of a fragrance that originally has balsamic and / or leather notes.

17. The use according to claim 16, wherein the p-tolylmethanol (pTM) is added to the fragrance in an amount ranging from 0.1 to 2% by weight.

18. The use according to claim 17, wherein the p-tolylmethanol (pTM) is added to the fragrance in an amount ranging from 0.5 to 1% by weight.

19. Use of p-tolylmethanol as a fragrance.

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