Fungicidal mixture combination comprising sulphur

Abstract

The present invention relates to mixture combinations of active compounds comprising an effective amount of sulphur; an effective amount of at least one fungicide or its salt, for combatting or preventing fungal diseases of crop plants. Methods of controlling mites or insects comprising applying said combinations are also disclosed.

Description

[0001] FUNGICIDAL MIXTURE COMBINATION COMPRISING SULPHUR

[0002] RELATED APPLICATION / S

[0003] This application claims benefits of US Provisional Application No. 63 / 538,295 filed on September 14, 2023; the entire content of which is hereby incorporated by reference herein. Throughout this application, various publications are cited. Disclosures of the documents and publications referred to herein are hereby incorporated in their entireties by references into this application.

[0004] FIELD OF INVENTION

[0005] The present invention relates to mixture combinations of active compounds comprising an effective amount of sulphur; an effective amount of at least one fungicide or its salt, and at least one agrochemically acceptable excipient, for combatting or preventing fungal diseases of crop plants. A method for controlling or preventing fungal diseases in crop plants is also disclosed.

[0006] BACKGROUND OF INVENTION

[0007] Elemental sulphur as a potent pesticide is well known for ages. Sulphur is available primarily in its elemental form and formulations namely granules, pellets, powders, and so on are known for providing sulphur in a form for use as a fertilizer or a pesticide. Sulphur not only works as a fungicide but is also used as a supplementary plant nutrient. Furthermore, bio-sulfur fungicide is also widely known which is derived from agricultural sources. The said bio-sulphur is made by bacteria that turns hydrogen sulfide, which is a by-product of biogas production, into elemental sulfur. The origin of the process being farm waste, this organic sulphur has a different chemical structure and a smaller particle size, which makes it more effective than conventional sulphur. The formulation of sulphur alone is considered moderately effective against various fungal diseases such as powdery mildew or grey mildew.

[0008] The vulnerability of crops to fungal diseases makes fungal disease management one of the major components of the total crop production system. Various fungi are very harmful to crop plants and can significantly reduce crop yields and qualities. Actives like Sulphur or other Fungicides are compounds of natural or synthetic origin which act to protect plants against damage caused by fungi. In spite of the benefits derived from the use of fungicides in agriculture such as protection of crops and improved productivity, it is nowadays desirable to reduce the amount of fungicides used in the fields owing to the potential health risks associated with an intensive use of agrochemicals. Furthermore, repeated usage of a single fungicide often leads to the development of resistance to a specific or a group of fungicides.

[0009] The biological properties of known compounds are not entirely satisfactory in the areas of plant disease control, environmental and worker exposure, for example in particular, it has been observed that pathogens become, resistant to pesticides, which are at times administered in higher dosages to achieve the desired control, thereby leading to soil toxicity and other environmental hazards, besides higher costs. Another important issue associated with fungus attacks is the loss of nutrients which leads to a decrease in the overall yield of the crop.

[0010] Combinations of fungicides or mixture of one or more fungicides with other crop protection chemical are typically used to broaden spectrum of control, to minimize the doses of chemicals used, to retard resistance development and to reduce the cost of the treatment through additive effect. Although many combinations of one fungicidal agent with one or more crop protection chemicals have been studied, a synergistic effect is rarely attained.

[0011] There are some literatures available on fungicidal mixture comprising sulphur. EP2667720 discloses pesticidal composition comprising sulphur, a fungicide and an agrochemical excipient. Ene et al. (Stiinte Agricole Si Silvice, 23, 1990, p.285-293 ) relates to the use of Ziram instead of macozeb in fungicide mixtures against wheat leaf diseases at high concentrations or in association with sulphur. FR2585539 relates to a new combination fungicide comprising cymoxanil and wettable sulphur. Pauwels et al. (Mededelingen Van De Faculteit Landbouwwetenschappen, 31, 2, 1976, p. 687-682) relates to the control of cereal diseases with chlorothalonil and chlorothalonil, Maneb and sulphur.

[0012] Practical agricultural experience has shown that the repeated and exclusive application of an individual active compound such as sulphur in the control of fungi leads in many cases to a selection of those fungi which have developed natural or adapted resistance against the active compound in question. Effective control of these fungi with the active compound in question is then no longer possible.

[0013] Thus there is a need for a selective mixture of sulphur with other fungicidal compound that help prevent or overcome resistance. In order to reduce the risk of fungi becoming resistant to certain active compounds, mixtures of different fungicidal chemicals are nowadays conventionally employed for controlling various fungi. By combining judiciously active compounds having different mechanisms of action, it is possible to ensure successful control over a relatively long period of time.

[0014] Active agent mixtures are described in the literature. However, the control over the fungi does not always satisfy the needs of agriculture practice. Additionally, the efficacy of mixtures is not entirely satisfactory in cases of fungi control and / or toxicological and / or environmental effects. Random pesticidal compositions and mixtures do not exert a satisfactory controlling effect in most of the cases, and therefore, there is an urgent need for development of new pesticidal mixtures with one more crop protection chemical having some satisfactory controlling effects.

[0015] It is an object of the present invention to provide mixtures and compositions of judiciously selected crop protection chemicals which, when applied at a reduced total amount of active compounds, have improved activity against the harmful fungi. It is an object of the present invention to provide a broadened activity spectrum with prolonged control. It is a further object of the present invention to provide mixtures and compositions comprising sulphur which provide effective resistance management and fungi control, at application rates which are as low as possible.

[0016] It is an endeavor of the present invention to find that mixtures comprising sulphur and at least one further crop protection chemical are synergistically effective, being applied simultaneously, that is jointly or separately, or in succession, allows better control of fungi than is possible with the individual compounds alone, providing synergistic results and solving at least one of the challenges in the prior art by reducing the dosage rate or enhancing the spectrum of activity with prolonged control or facilitating resistance management.

[0017] It is further endeavor of the present invention to find that kind of mixtures of sulphur which also act as miticides along with insecticides with more efficiencies compared to each component of the mixtures, respectively. It is an object of the present invention to provide repellant activities against pests and also to result in higher yield of the crops.

[0018] In light of the above, there is endeavor in the present invention for a fungicidal mixture combination of crop protection chemicals comprising sulphur that exhibit synergistically enhanced action, a broader scope of activity, reduced dosage of treatment and increased yield of crops.

[0019] SUMMARY OF THE PRESENT INVENTION We have reasonably found that the object as described above is as a whole or in part achieved by the combination of active compounds defined below.

[0020] The present invention relates to a fungicidal mixture combination comprising, as active compounds:

[0021] A) an effective amount of a Sulphur, which includes a bio-sulphur; and

[0022] B) an effective amount of at least one fungicide chemical compound II selected from the groups (1) to (34):

[0023] (1) a phenylacetamide fungicide selected from a group comprising Cyflufenamid,

[0024] (2) a polysaccharide compound selected from group comprising Laminarin and Chitosan,

[0025] (3) a plant extract from beet which comprises Trimethyl glycine,

[0026] (4) a plant extract fungicide which is extracted from Melaleuca alternifolia,

[0027] (5) a plant extract fungicide extracted from a plant oil, which is selected from a group consisting of Eugenol, Geraniol, Thymol and any combination thereof,

[0028] (6) a plant extract fungicide which is selected from the group consisting of terpene hydrocarbons, terpene alcohol, terpene phenols and any combination thereof,

[0029] (7) a plant extract from cotyledons of lupine plantlets, which comprises polypeptides,

[0030] (8) a plant extract selected from Seaweed extracts which are derived from the extraction of macroalgae species,

[0031] (9) a plant extract fungicide which is extracted from Swinglea glutinosa,

[0032] (10) an amine fungicide selected from a group comprising Fenpropidin, Fenpropimorph and Spiroxamine,

[0033] (11) an oxysterol binding protein inhibitor compound selected from a group comprising Oxathiapiprolin and Fluoxapiprolin,

[0034] (12) a pyrimidine fungicide selected from a group comprising 5-fluoro-4-imino-3-methyl- l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one and bupirimate,

[0035] (13) a quinone inside inhibitor selected from a group comprising Fenpicoxamid, Florylpicoxamid, Cyazofamid and Amisulbrom,

[0036] (14) a quinone outside inhibitor selected from a group comprising Azoxystrobin, Picoxistrobin, Pyraclostrobin and Metyltetraprole,

[0037] (15) a succinate dehydrogenase inhibitor selected from a group comprising Isofetamid, Fluopyram and Pyrapropoyne, (16) a tetrazolyloxime fungicide selected from a group comprising Picarbutrazox,

[0038] (17) a benzamide fungicide selected from a group comprising Zoxamide, Fluopicolide and Fluopimomide,

[0039] (18) a benzophenone fungicide selected from a group comprising Metrafenone and Pyriofenone,

[0040] (19) an anilino-pyrimidine fungicide selected from a group comprising Cyprodinil and Pyrimethanil,

[0041] (20) an azanaphthalene fungicide selected from a group comprising Quinoxyfen and Proquinazid,

[0042] (21) a keto-reductase Inhibitor fungicide selected from a group comprising Fenhexamid and Fenpyrazamine,

[0043] (22) a guanidine fungicide selected from a group comprising Dodine,

[0044] (23) a phthalimide fungicide selected from a group comprising Folpet and Captan,

[0045] (24) a naphthodithiin fungicide selected from a group comprising Dithianon,

[0046] (25) a triazole fungicide selected from a group comprising Mefentrifluconazole, Ipfentrifluconazole and Tricyclazole,

[0047] (26) a thiazolidine fungicide selected from a group comprising Flutianil,

[0048] (27) a pyridine fungicide selected from a group comprising Aminopyrifen,

[0049] (28) a quinoline fungicide selected from a group comprising Quinofumelin, Ipflufenoquin and Tebufloquin,

[0050] (29) a phenylpyrrole fungicide selected from a group comprising Fludioxonil,

[0051] (30) a tubulin polymerization promoter selected from a group comprising Pyridachlometyl,

[0052] (31) a benzothiadiazole fungicide selected from a group comprising Acibenzolar-S- methyl,

[0053] (32) a thiazole carboxamide fungicide selected from a group comprising Isotianil,

[0054] (33) a benzothiazole fungicide selected from a group comprising Dichlobentiazox, and

[0055] (34) probiotic microbial species selected from a group comprising Bacillus, Lactococcus and Saccharomyces, wherein the amount of a Sulphur, which includes a bio-sulphur and the amount of the fungicide when applied together is more effective in treating a plant or soil against fungal infection than when each fungicide at the same amount is applied alone.

[0056] The present invention further specifically provides the mixture combination comprising a Sulphur, which includes a bio-sulphur and an effective amount of at least one fungicide chemical compound II selected from a group comprising Cyflufenamid, Laminarin, Chitosan, Trimethyl glycine from beet extract, plant extract from Melaleuca alternifolia, Eugenol, Geraniol, Thymol, terpene hydrocarbons, terpene alcohol, terpene phenols, cotyledons of lupine plantlets comprising polypeptides, Seaweed extracts which are derived from the extraction of macroalgae species, plant extract fungicide extracted from Swinglea glutinosa, Fenpropidin, Fenpropimorph, Spiroxamine, Oxathiapiprolin, Fluoxapiprolin, 5-fluoro-4-imino-3- methyl-l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one, Bupirimate,

[0057] Fenpicoxamid, Florylpicoxamid, Cyazofamid, Amisulbrom, Azoxystrobin, Picoxistrobin, Pyraclostrobin, Metyltetraprole, Isofetamid, Fluopyram, Pyrapropoyne, Picarbutrazox, Zoxamide, Fluopicolide, Fluopimomide, Metrafenone, Pyriofenone, Cyprodinil, Pyrimethanil, Quinoxyfen, Proquinazid, Fenhexamid, Fenpyrazamine, Dodine, Folpet, Captan, Dithianon, Mefentrifluconazole, Ipfentrifluconazole, Tricyclazole, Flutianil, Aminopyrifen, Quinofumelin, Ipflufenoquin, Tebufloquin, Fludioxonil, Pyridachlometyl, Acibenzolar-S-methyl, Isotianil, Dichlobentiazox, Bacillus, Lactococcus and Saccharomyces, and also agrochemically acceptable additives.

[0058] Furthermore, it is found in the present invention that simultaneous, that is jointly or separately, application of Sulphur and fungicide chemical compound II or successive application of Sulphur and one or more fungicide chemical compound II, as mentioned above, allows enhanced control of fungi compared to the control rates that are possible with the individual compounds.

[0059] The present invention provides the mixture combination, wherein the weight ratio of Sulphur and one or more fungicide chemical compound II, as mentioned above is from 1:100 to 100:1, and the amount of each active ingredient is about 0.1-99 wt. %, about 0.1-95 wt. %, or about 0.1-90 wt. %, based on the total weight of the mixture composition. The present invention provides mixture combination comprising Sulphur, which includes a bio-sulphur and one or more fungicide chemical compound II, as mentioned above, wherein the application rates of the mixture according to the invention are from 500 g / ha to 5000 g / ha.

[0060] The present invention further provides a mixture composition comprising a mixture of Sulphur, which includes a bio-sulphur and one or more fungicide chemical compound II, as mentioned above, comprising an agriculturally acceptable carrier, and further comprising at least one surfactant, solid diluent, liquid diluent, or a combination thereof.

[0061] The present invention also provides a method of treating a plant or soil against fungal infection comprising applying to the plant, propagation material of the plant, or soil

[0062] A) an effective amount of a Sulphur, which includes a bio-sulphur; and

[0063] B) an effective amount of at least one fungicide chemical compound II selected from the groups (1) to (34):

[0064] (1) a phenylacetamide fungicide selected from a group comprising Cyflufenamid,

[0065] (2) a polysaccharide compound selected from group comprising Laminarin and Chitosan,

[0066] (3) a plant extract from beet which comprises Trimethyl glycine,

[0067] (4) a plant extract fungicide which is extracted from Melaleuca alternifolia,

[0068] (5) a plant extract fungicide extracted from a plant oil, which is selected from a group consisting of Eugenol, Geraniol, Thymol and any combination thereof,

[0069] (6) a plant extract fungicide which is selected from the group consisting of terpene hydrocarbons, terpene alcohol, terpene phenols and any combination thereof,

[0070] (7) a plant extract from cotyledons of lupine plantlets, which comprises polypeptides,

[0071] (8) a plant extract selected from Seaweed extracts which are derived from the extraction of macroalgae species,

[0072] (9) a plant extract fungicide which is extracted from Swinglea glutinosa,

[0073] (10) an amine fungicide selected from a group comprising Fenpropidin, Fenpropimorph and Spiroxamine,

[0074] (11) an oxysterol binding protein inhibitor compound selected from a group comprising Oxathiapiprolin and Fluoxapiprolin,

[0075] (12) a pyrimidine fungicide selected from a group comprising 5-fluoro-4-imino-3-methyl- l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one and bupirimate, (13) a quinone inside inhibitor selected from a group comprising Fenpicoxamid, Florylpicoxamid, Cyazofamid and Amisulbrom,

[0076] (14) a quinone outside inhibitor selected from a group comprising Azoxystrobin, Picoxistrobin, Pyraclostrobin and Metyltetraprole,

[0077] (15) a succinate dehydrogenase inhibitor selected from a group comprising Isofetamid, Fluopyram and Pyrapropoyne,

[0078] (16) a tetrazolyloxime fungicide selected from a group comprising Picarbutrazox,

[0079] (17) a benzamide fungicide selected from a group comprising Zoxamide, Fluopicolide and Fluopimomide,

[0080] (18) a benzophenone fungicide selected from a group comprising Metrafenone and Pyriofenone,

[0081] (19) an anilino-pyrimidine fungicide selected from a group comprising Cyprodinil and Pyrimethanil,

[0082] (20) an azanaphthalene fungicide selected from a group comprising Quinoxyfen and Proquinazid,

[0083] (21) a keto-reductase Inhibitor fungicide selected from a group comprising Fenhexamid and Fenpyrazamine,

[0084] (22) a guanidine fungicide selected from a group comprising Dodine,

[0085] (23) a phthalimide fungicide selected from a group comprising Folpet and Captan,

[0086] (24) a naphthodithiin fungicide selected from a group comprising Dithianon,

[0087] (25) a triazole fungicide selected from a group comprising Mefentrifluconazole, Ipfentrifluconazole and Tricyclazole,

[0088] (26) a thiazolidine fungicide selected from a group comprising Flutianil,

[0089] (27) a pyridine fungicide selected from a group comprising Aminopyrifen,

[0090] (28) a quinoline fungicide selected from a group comprising Quinofumelin, Ipflufenoquin and Tebufloquin,

[0091] (29) a phenylpyrrole fungicide selected from a group comprising Fludioxonil,

[0092] (30) a tubulin polymerization promoter selected from a group comprising Pyridachlometyl,

[0093] (31) a benzothiadiazole fungicide selected from a group comprising Acibenzolar-S- methyl, (32) a thiazole carboxamide fungicide selected from a group comprising Isotianil,

[0094] (33) a benzothiazole fungicide selected from a group comprising Dichlobentiazox, and

[0095] (34) probiotic microbial species selected from a group comprising Bacillus, Lactococcus and Saccharomyces, so as to thereby treat the plant or soil against fungal infection, wherein the amount of sulphur applied is less than the fungicidally effective amount of sulphur when sulphur is used alone, and / or wherein the amount of the fungicide applied is less than the fungicidally effective amount of the fungicide when the fungicide is used alone.

[0096] The present invention also provides use of any one of the combinations, mixtures or compositions disclosed herein for combatting phytopathogenic diseases as well as mites on crop plants.

[0097] The present invention further provides use of any one of the combinations, mixtures or compositions disclosed herein for effectively repelling insects on crops.

[0098] The present invention also provides use of any one of the combinations, mixtures or compositions disclosed herein for treating a plant or soil against fungal infection.

[0099] The mixture combination of the present invention can be a synergistic mixture.

[0100] The present invention also provides a fungicidal composition comprising any one of the combinations or mixtures disclosed herein.

[0101] The present invention also provides a method of treating a plant or soil against fungal infection comprising applying an effective amount of any one of the combinations, mixtures or compositions disclosed herein to the plant, propagation material of the plant, or soil so as to thereby treat the plant or soil against fungal infection.

[0102] This present invention further provides a method for enhancing plant development comprising applying to the plant, a locus of the plant and / or propagation material of the plant an effective amount of the mixture of Sulphur and one or more fungicide chemical compound II, as mentioned above or the composition thereof, so as to thereby enhance plant development and greening effect.

[0103] This present invention also provides a method for regulating plant growth comprising applying to the plant, a locus of the plant and / or propagation material of the plant an effective amount of Sulphur and one or more fungicide chemical compound II, as mentioned above or the composition thereof, so as to thereby increasing plant growth and crop yield.

[0104] The present invention also provides a method of treating a plant or soil against infection by fungi selected from a group comprising Frosty pod (Moniliophthora roreri), Witches' broom (Moniliophthora perniciosa), Seedling blight / foliar&ear disease (Microdochium sp.), Botryosphaeria Panicle and Shoot Blight (Botryosphaeria dothidea), Band canker (Botryosphaeria dothidea), Black rot (Phyllosticta ampelicida), Black sigatoka (Pseudocercospora fijiensis ; Mycosphaerella fijiensis), Septoria (Zymoseptoria tritici), Ramularia leaf spot (Ramularia collo-cygni), Gray Leaf Spot (Cercospora zeae-maydis), Ramularia leaf spot (Ramularia areola), leaf spot of beet (Cercospora beticola), Ramularia leaf spot (Ramularia beticola), Yellow sigatoka (Pseudocercospora musae), Early leaf spot (Mycosphaerella arachidis), Late leaf spot (Mycosphaerella berkeleyi), Ashy leaf spot of pear (Mycosphaerella pyri), Leaf spot (Cercospora sp.), Septoria brown spot (Septoria glycines), Purple Seed Stain (Cercospora kikuchii), Scab (Cladosporium sp.), Leaf spot of hop (Pseudocercospora cantuariensis), White leaf spot (Neopseudocercosporella capsellae), Barn spot (Cercospora nicotianae), Sheath Blight (Rhizoctonia solani / Thanatephorus cucumeris), Rizoctonia (Rhizoctonia solani / Thanatephorus cucumeris), Damping off / root rot (Rhizoctonia solani / Thanatephorus cucumeris), Rizoctonia (Rhizoctonia solani / Thanatephorus cucumeris), Rhizoctonia root and crown rot (Rhizoctonia solani / Thanatephorus cucumeris), Pink Disease (Erythricium salmonicolor), Dead-arm (Diaporthe neoviticola), Eyespot (Kabatiella zeae), Powedery mildew (Blumeria graminis), Powdery mildew (Erysiphe cichoracearum), Powdery mildew (Sphaerotheca fuliginea), Powdery mildew (Erysiphe necator), Powdery mildew (Podosphaera macularis), Powdery mildew (Podosphaera leucotricha), Powdery mildew (Leveillula taurica / Oidium Neolycopersici), powdery mildew (Erysiphe betae / Erysiphe polygoni), Powdery mildew (Erysiphe sp.), Powdery mildew (Podosphaera pannosa), Downy mildew (Peronospora tabacina), Powdery mildew (Erysiphe sp. / Oidium sp), Powdery mildew (Leveillula Taurica), Powdery mildew (Erysiphe cruciferarum), Powdery mildew (Erysiphe diffusa), Aspergillus ear rot (Aspergillus sp.), Light leaf Spot (Pyrenopeziza brassicae), Bark canker of apple (Phlyctema vagabunda), Leaf spot (Blumeriella jaapii), Grey mold (Botrytis cinereal), Sclerotinia (Sclerotinia sclerotiorum), Grey mould, (Botrytis cinereal), Monilia (Monilinia spp. / Monilinia laxa / Monilia fructigena / Monilia fructicola), Botrytis blight (Botrytis cinereal), Grey mold (Botrytis sp.), White mould (Sclerotinia sp.), Sclerotinia stem rot or white mold (Sclerotinia sclerotiorum), Brown rot blossom (Monilinia fructicola), Grey mould (Botrytis cinereal), Grey mould (Botrytis cinereal), Botrytis Blossom and Shoot Blight(Botrytis cinereal), Leaf blotch of cereals (Rhynchosporium secalis), Fusarium head blight (Fusarium sp.), Maize Ear and Kernel Rot (Fusarium sp.), Eye rot (Neonectria galligena), Bakanae disease (Gibberella fujikuroi), Giberrella stalk and ear rot (Gibberella zeae), Coffee Wilt Disease (Gibberella xylarioides), Anthracnose of grapevine (Elsinoe ampelina), Crown and root rot (Phytophthora sp.), Black pod (Phytophthora palmivora / Phytophthora megakarya / Phytophthora capsica), Downy milde (Pseudoperonospora cubensis), Downy mildew (Plasmopara viticola), Downy mildew (Pseudoperonospora humul), Late blight (Phytophthora infestans), Downy mildew (Peronospora viciae / Phytopthora sp.), Late blight (Phytophthora infestans), Downy mildew (Hyaloperonospora parasitica), Downy mildew (Peronospora farinose), Coffee Berry Disease (Colletotrichum kahawae), Anthracnose (Colletotrichum sp.), Antracnose (Colletotrichum sp). Anthracnose (Colletotrichum musae), Anthracnose (Colletotrichum spp.), Anthracnose (Glomerella cingulate), Anthracnose (Colletotrichum graminicola), Anthracnose (Glomerella gossypii), Fruit rot (Glomerella cingulate), Red rot (Colletotrichum falcatum), Anthracnose (Colletotrichum destructivum), Leaf spot (Polystigma rubrum), Club rot (Plasmodiophora brassicae), Target spot (Corynesporacassiicola), Didymella pisi (Ascochyta rabiei), Boll rot (Ascochyta gossypiicola), Leaf spot of apple (Didymella pomorum), Leaf and pod spot (Didymella sp.), Shot-hole of stone fruit (Wilsonomyces carpophilus), Shot-hole of stone fruit (Wilsonomyces carpophilus), Phoma stem canker and leaf spot (Plenodomus lingam), black leg of beet (Neocamarosporium betae), Yellow spot (Pyrenophora triticirepentis / Drechslera tritici-repentis), Net blotch (Pyrenophora teres), Northern Corn Leaf Blight (Setosphaeria turcica), Southern corn leaf blight (Cochliobolus heterostrophus), Northern Corn Leaf Spot (Cochliobolus carbonum), Leaf blight (Alternaria spp. / Alternaria cucumerina), Alternaria (Alternaria alternate), Brown spot of pear (Pleospora allii), Alternaria blotch of apple (Alternaria mali / Alternaria sp.), Early blight (Alternaria sp.), Early blight (Alternaria sp.) Alternaria late blight (Alternaria sp.) Brown spot (Alternaria alternate), Brown spot (Alternaria alternate), Leaf spot (Alternaria sp.), Brown spot (Cochliobolus miyabeanus), Eyespot (Helminthosporium sacchari), Scab (Venturia inaequalis), Scab (Venturia pyrina), Scab (Venturia carpophila), Coffee Leaf Rust (Hemileia vastatrix), Asian soybean rust (Phakopsora pachyrhizi), Panama wilt (Phakopsora gossypii), Tropical cotton rust (Phakopsora gossypii), Brown rust (Puccinia recondite), Yellow rust (Puccinia striiformis), Rust (Uromyces betae), Common Rust (Puccinia sorghi), Rust (Uromyces sp.), Cotton rust(Puccinia schedonnardi), Southwestern cotton rust (Puccinia cacabata), Rust (Tranzschelia spp.), Rice Blast (Pyricularia oryzae), leaf curl (Taphrina spp. / Taphrina deformans), Common Smut (Ustilago maydis), Smut (Ustilago scitaminea), Esca of grapevine (Phaeomoniella chlamydospore), blossom blight (Monilinia laxa), and frosty pod rot disease (Moniliophthora roreri).

[0105] Target crops of the present invention for the areas of indication comprise cereals (wheat, barley, rye, oats, rice, sorghum and related crops); beet (sugar beet and fodder beet); pome fruits (apples, pears), stone fruit and soft fruit (plums, peaches, almonds, cherries, strawberries, raspberries and blackberries); leguminous plants (beans, lentils, peas, soybeans); oil plants (rape, mustard, poppy, olives, sunflowers, coconut, castor oil plants, cocoa beans, groundnuts); cucumber plants (marrows, cucumbers, melons); fibre plants (cotton, flax, hemp, jute); citrus fruit (oranges, lemons, grapefruit, mandarins); vegetables (spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, paprika); lauraceae (avocados, cinnamon, camphor); or plants such as maize, tobacco, nuts, coffee, sugar cane, tea, vines, hops, bananas and natural rubber plants, as well as ornamentals (flowers, shrubs, broadleaved trees and evergreens, such as conifers).

[0106] The present invention also provides a kit comprising any one of the combinations, mixtures or compositions disclosed herein.

[0107] The present invention also provides a process for the preparation any one of the combinations, mixtures or compositions disclosed herein from individual component parts. DETAILED DESCRIPTION OF THE PRESENT INVENTION Definitions

[0108] Prior to setting forth the present subject matter in detail, it may be helpful to provide definitions of certain terms to be used herein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as is commonly understood by one of skill in the art to which this subject matter pertains.

[0109] As used herein, the term "and / or" includes any and all combinations of one or more of the associated listed items. Expressions such as "at least one of," when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.

[0110] It will be understood that when an element is referred to as being "on" another element, it can be directly in contact with the other element or intervening elements may be present there between. In contrast, when an element is referred to as being "directly on" another element, there are no intervening elements present.

[0111] The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting. As used herein, the singular forms "a, ""an," and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise.

[0112] It will be understood that, although the terms first, second, third, etc., may be used herein to describe various elements, components, regions, layers, and / or sections, these elements, components, regions, layers, and / or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer, or section from another element, component, region, layer, or section. Thus, a first element, component, region, layer, or section discussed below could be termed a second element, component, region, layer, or section without departing from the teachings of the present embodiments.

[0113] The term "or" means "and / or." It will be further understood that the terms "comprises" and / or "comprising," or "includes" and / or "including" when used in this specification, specify the presence of stated features, regions, integers, steps, operations, elements, and / or components, but do not preclude the presence or addition of one or more other features, regions, integers, steps, operations, elements, components, and / or groups thereof.

[0114] "About" as used herein is inclusive of the stated value and means within an acceptable range of deviation for the particular value as determined by one of ordinary skill in the art, considering the measurement in question and the error associated with measurement of the particular quantity (i.e., the limitations of the measurement system). For example, "about" can mean within one or more standard deviations, or within ± 30%, 20%, 10%, 5% of the stated value.

[0115] As used herein, the term "combination" means an assemblage of agrochemicals for application either by simultaneous or contemporaneous application.

[0116] As used herein, the term "simultaneous" when used in connection with application of agrochemicals means that the agrochemicals are applied in an admixture, for example, a tank mix. For simultaneous application, the combination may be the admixture or separate containers each containing an agrochemical that are combined prior to application.

[0117] The term "a Sulphur" used herein means both conventional sulphur as well as bio-sulfur fungicide, wherein the latter may be derived from biological sources.

[0118] As used herein the term "prolonged control" means obtaining fungicidal activity over an extended period after the application of one or more fungicide for controlling fungi infestation of the plant or locus over an extended period of time, before and / or after an infestation or before and / or after damage due to fungi are shown.

[0119] As used herein, the term "effective" when used in connection with an amount of the combination, mixture or composition refers to an amount of the combination, mixture or composition that achieve a good level of control of the fungus, pathogen, and / or disease when applied to a plant, propagation material of the plant, or soil.

[0120] As used herein, the term "fungicidally effective amount" refers to an amount of the active component that is commercially recommended for use to control fungi. The commercially recommended amount for each active component, often specified as application rates of the commercial formulation, may be found on the label accompanying the commercial formulation. The commercially recommended application rates of the commercial formulation may vary depending on factors such as the plant species and the fungus to be controlled.

[0121] As used herein, the term "treating a plant or soil against fungal infection" includes, but is not limited to, protecting the plant or soil against fungal attack, preventing fungal infection of the plant or soil, controlling fungal disease infecting the plant or soil, and reducing fungal infection of the plant or soil.

[0122] As used herein, the term "more effective for controlling fungal disease" includes, but is not limited to, increasing efficacy of fungal disease control and reducing the amount of time needed to achieve a given level of fungal control.

[0123] As used herein, the term "more effective for protecting the plant or soil against fungal attack" includes, but is not limited to, prolonging the duration of protection against fungal attack after application and extending the protection period against fungal attack.

[0124] As used herein, the term "agriculturally acceptable inert additives" is defined as any substance that itself is not an active ingredient but is added to the composition such as thickening agent, sticking agents, surfactants, anti-oxidation agent, anti-foaming agents and thickeners.

[0125] As used herein, the term "tank mix" means that two or more chemical pesticides or compositions are mixed in the spray tank at the time of spray application.

[0126] As used herein, the term "ready mix" means a composition that may be applied to plants directly after dilution. The composition comprises the combination of the active ingredients. The term "mixture" or "combination" refers, but is not limited to, a combination in any physical form, e.g., blend, solution, alloy, or the like.

[0127] As used herein the term "plant" or "crop" includes reference to whole plants including cultivated plants, plant organs (e.g. leaves, stems, twigs, roots, trunks, limbs, shoots, fruits etc.), plant cells, or plant seeds. This term also encompasses plant crops such as fruits. The term "plant" may also include the propagation material thereof, which may include all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers, which can be used for the multiplication of the plant. It may also include spores, corms, bulbs, rhizomes, sprouts basal shoots, stolons, and buds and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil.

[0128] As used herein, the term "locus" includes a habitat, breeding ground, plant, propagation material, soil, area, material or environment in which a pest is growing or may grow.

[0129] As used herein, the term "cultivated plants" includes plants which have been modified by breeding, mutagenesis or genetic engineering. Genetically modified plants are plants, which genetic material has been modified by the use of recombinant DNA techniques. Typically, one or more genes have been integrated into the genetic material of such a plant in order to improve certain properties of the plant.

[0130] The term "plant health" comprises various sorts of improvements of plants that are not connected to the control of pests. For example, advantageous properties that may be mentioned are improved crop characteristics including: emergence, crop yields, protein content, oil content, starch content, more developed root system (improved root growth), improved stress tolerance (e.g. against drought, heat, salt, UV, water, cold), reduced ethylene (reduced production and / or inhibition of reception), increase in plant height, bigger leaf blade, less dead basal leaves, stronger tillers, greener leaf color, pigment content, photosynthetic activity, less input needed (such as fertilizers or water), less seeds needed, more productive tillers, earlier flowering, early grain maturity, less plant verse (lodging), increased shoot growth, enhanced plant vigor, increased plant stand and early and better germination; or any other advantages familiar to a person skilled in the art.

[0131] Throughout the application, descriptions of various embodiments use the term "comprising"; however, it will be understood by one of skill in the art, that in some specific instances, an embodiment can alternatively be described using the language "consisting essentially of" or "consisting of".

[0132] As used herein, the term "locus" includes a habitat, breeding ground, plant, propagation material, soil, area, material or environment in which a pest is growing or may grow.

[0133] As used herein the term "ha" refers to hectare.

[0134] As used herein, the term "g" refers to gram, and "L" or "I" refers to litre.

[0135] As used herein, the term "more effective" includes, but is not limited to, increasing efficacy of pesticidal disease control, prolonging protection and reducing the amount of time needed to achieve a given level of pesticidal control, prolonging the duration of protection against pest attack after application and extending the protection period against pest attack and / or reducing the amount of time needed to achieve a level of pest control compared to when each pesticide at the same amount is applied alone.

[0136] The term "enhancing crop plants" as used herein means improving one or more of plant quality, plant vigor, nutrient uptake, root system, tolerance to stress factors, and / or yield in a plant to which the mixture or composition described herein has been applied as compared to a control plant grown under the same conditions except to which the mixture or composition described herein has not been applied.

[0137] The term "enhancing roots system" as may be used herein means the roots system is improved qualitatively or quantitatively in a plant to which the mixture or composition described herein has been applied as compared to the roots systems in a control plant grown under the same conditions except to which the mixture or composition described herein has not been applied. Enhanced roots systems include but are not limited to improved visual appearance and composition of the roots system (i.e., improved color, density, and uniformity), increased root growth, a more developed root system, stronger and healthier roots, improved plant stand, and increased roots system weight. The term "improving plant quality" as used herein means that one or more traits are improved qualitatively or quantitatively in a plant to which the mixture or composition described herein has been applied as compared to the same trait in a control plant grown under the same conditions except to which the mixture or composition described herein has not been applied. Such traits include but are not limited to improved visual appearance and composition of the plant (i.e., improved color, density, uniformity, compactness), reduced ethylene (reduced production and / or inhibition of reception), improved visual appearance and composition of harvested material (i.e., seeds, fruits, leaves, vegetables, shoot / stem / cane), improved carbohydrate content (i.e., increased quantities of sugar and / or starch, improved sugar acid ratio, reduction of reducing sugars, increased rate of development of sugar), improved protein content, improved oil content and composition, improved nutritional value, reduction in anti-nutritional compounds, increased nutrient uptake, stronger and healthier roots, improved organoleptic properties (i.e., improved taste), improved consumer health benefits (i.e., increased levels of vitamins and antioxidants), improved post-harvest characteristics (i.e., enhanced shelf-life and / or storage stability, easier processability, easier extraction of compounds), and / or improved seed quality (i.e., for use in following seasons).

[0138] As used herein, the term "plants" refers to any and all physical parts of a plant, including but not limited to seeds, seedlings, saplings, roots, tubers, stems, stalks, foliage, and fruits.

[0139] As used herein, the term "surfactant" means an agriculturally acceptable material which imparts emulsifiability, stability, spreading, wetting, dispersibility or other surface-modifying properties. Examples of suitable surfactants include non-ionic, anionic, cationic and ampholytic surfactants.

[0140] For purposes of better understanding the present teachings and in no way limiting the scope of the teachings, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are approximations that may vary depending upon the desired properties sought to be obtained. At the very least, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques. In this regard, use of the term "about" herein specifically includes ±10% from the indicated values in the range. In addition, the endpoints of all ranges directed to the same component or property herein are inclusive of the endpoints, are independently combinable, and include all intermediate points and ranges. Unless otherwise specified, references to percentages are by weight (wt.) percentages of the active compounds in the composition of this invention are based on the total weight of active ingredients in the composition, i.e., the active compounds themselves, exclusive of any amounts of solvents, carriers, dispersants, stabilizers or other materials which may be present.

[0141] It is further understood that where a parameter range is provided, all integers within that range, and tenths thereof, are also provided by the subject matter. For example, "0.1% to 50%" includes 0.1 %, 0.2 %, 0.3 %, 0.4 % etc. up to 50 %.

[0142] When a ratio herein is to be "X:l or higher", it is meant that the ratio is Y:l, where Y is X or greater, and when a ratio is herein to be "X:l or lower", it is meant that the ratio is Z:l, where Z is X or less. The same logic follows for ratios that are "1:X or higher" and "1:X or lower".

[0143] Fungicidal mixture combination

[0144] It has been surprisingly found that by combining a Sulphur with one or more crop fungicidal compounds, mixture combinations are produced, that exhibit a broad spectrum of control and high efficacy against a very wide range of fungi, as well as having long residual effect under different climate conditions. The mixtures and compositions of the present invention are based in part on the finding that application of the mixture combination of the present invention to a locus or area where fungicidal control is desired results in improved control of fungi and prevents further infestation.

[0145] In some embodiments, the combination provides a higher fungicidal activity than that envisaged on the basis of the sum of activities of each of Sulphur and the fungicides found therein. Such a combination allows the reduced dosages of the individual fungicide which can damage agriculturally important plants.

[0146] In an embodiment, the present invention relates to a fungicidal mixture combination comprising, as active compounds:

[0147] A) an effective amount of a Sulphur, which includes a bio-sulphur; and

[0148] B) an effective amount of at least one fungicide chemical compound II selected from the groups (1) to (34):

[0149] (1) a phenylacetamide fungicide selected from a group comprising Cyflufenamid,

[0150] (2) a polysaccharide compound selected from group comprising Laminarin and Chitosan,

[0151] (3) a plant extract from beet which comprises Trimethyl glycine, (4) a plant extract fungicide which is extracted from Melaleuca alternifolia,

[0152] (5) a plant extract fungicide extracted from a plant oil, which is selected from a group consisting of Eugenol, Geraniol, Thymol and any combination thereof,

[0153] (6) a plant extract fungicide which is selected from the group consisting of terpene hydrocarbons, terpene alcohol, terpene phenols and any combination thereof,

[0154] (7) a plant extract from cotyledons of lupine plantlets, which comprises polypeptides,

[0155] (8) a plant extract selected from Seaweed extracts which are derived from the extraction of macroalgae species,

[0156] (9) a plant extract fungicide which is extracted from Swinglea glutinosa,

[0157] (10) an amine fungicide selected from a group comprising Fenpropidin, Fenpropimorph and Spiroxamine,

[0158] (11) an oxysterol binding protein inhibitor compound selected from a group comprising Oxathiapiprolin and Fluoxapiprolin,

[0159] (12) a pyrimidine fungicide selected from a group comprising 5-fluoro-4-imino-3-methyl- l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one and Bupirimate,

[0160] (13) a quinone inside inhibitor selected from a group comprising Fenpicoxamid, Florylpicoxamid, Cyazofamid and Amisulbrom,

[0161] (14) a quinone outside inhibitor selected from a group comprising Azoxystrobin, Picoxistrobin, Pyraclostrobin and Metyltetraprole,

[0162] (15) a succinate dehydrogenase inhibitor selected from a group comprising Isofetamid, Fluopyram and Pyrapropoyne,

[0163] (16) a tetrazolyloxime fungicide selected from a group comprising Picarbutrazox,

[0164] (17) a benzamide fungicide selected from a group comprising Zoxamide, Fluopicolide and Fluopimomide,

[0165] (18) a benzophenone fungicide selected from a group comprising Metrafenone and Pyriofenone,

[0166] (19) an anilino-pyrimidine fungicide selected from a group comprising Cyprodinil and Pyrimethanil,

[0167] (20) an azanaphthalene fungicide selected from a group comprising Quinoxyfen and Proquinazid, (21) a keto-reductase Inhibitor fungicide selected from a group comprising Fenhexamid and Fenpyrazamine,

[0168] (22) a guanidine fungicide selected from a group comprising Dodine,

[0169] (23) a phthalimide fungicide selected from a group comprising Folpet and Captan,

[0170] (24) a naphthodithiin fungicide selected from a group comprising Dithianon,

[0171] (25) a triazole fungicide selected from a group comprising Mefentrifluconazole, Ipfentrifluconazole and Tricyclazole,

[0172] (26) a thiazolidine fungicide selected from a group comprising Flutianil,

[0173] (27) a pyridine fungicide selected from a group comprising Aminopyrifen,

[0174] (28) a quinoline fungicide selected from a group comprising Quinofumelin, Ipflufenoquin and Tebufloquin,

[0175] (29) a phenylpyrrole fungicide selected from a group comprising Fludioxonil,

[0176] (30) a tubulin polymerization promoter selected from a group comprising Pyridachlometyl,

[0177] (31) a benzothiadiazole fungicide selected from a group comprising Acibenzolar-S- methyl,

[0178] (32) a thiazole carboxamide fungicide selected from a group comprising Isotianil,

[0179] (33) a benzothiazole fungicide selected from a group comprising Dichlobentiazox, and

[0180] (34) probiotic microbial species selected from a group comprising Bacillus, Lactococcus and Saccharomyces.

[0181] It has now been surprisingly found that a composition comprising a combination of i) an effective amount of a Sulphur, which includes a bio-sulphur, when mixed in certain ratios with an effective amount of at least one fungicide chemical compound II selected from the group consisting of:

[0182] (1) a phenylacetamide fungicide selected from a group comprising Cyflufenamid,

[0183] (2) a polysaccharide compound selected from group comprising Laminarin and Chitosan,

[0184] (3) a plant extract from beet which comprises Trimethyl glycine,

[0185] (4) a plant extract fungicide which is extracted from Melaleuca alternifolia,

[0186] (5) a plant extract fungicide extracted from a plant oil, which is selected from a group consisting of Eugenol, Geraniol, Thymol and any combination thereof, (6) a plant extract fungicide which is selected from the group consisting of terpene hydrocarbons, terpene alcohol, terpene phenols and any combination thereof,

[0187] (7) a plant extract from cotyledons of lupine plantlets, which comprises polypeptides,

[0188] (8) a plant extract selected from Seaweed extracts which are derived from the extraction of macroalgae species,

[0189] (9) a plant extract fungicide which is extracted from Swinglea glutinosa,

[0190] (10) an amine fungicide selected from a group comprising Fenpropidin, Fenpropimorph and Spiroxamine,

[0191] (11) an oxysterol binding protein inhibitor compound selected from a group comprising Oxathiapiprolin and Fluoxapiprolin,

[0192] (12) a pyrimidine fungicide selected from a group comprising 5-fluoro-4-imino-3-methyl- l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one and Bupirimate,

[0193] (13) a quinone inside inhibitor selected from a group comprising Fenpicoxamid, Florylpicoxamid, Cyazofamid and Amisulbrom,

[0194] (14) a quinone outside inhibitor selected from a group comprising Azoxystrobin, Picoxistrobin, Pyraclostrobin and Metyltetraprole,

[0195] (15) a succinate dehydrogenase inhibitor selected from a group comprising Isofetamid, Fluopyram and Pyrapropoyne,

[0196] (16) a tetrazolyloxime fungicide selected from a group comprising Picarbutrazox,

[0197] (17) a benzamide fungicide selected from a group comprising Zoxamide, Fluopicolide and Fluopimomide,

[0198] (18) a benzophenone fungicide selected from a group comprising Metrafenone and Pyriofenone,

[0199] (19) an anilino-pyrimidine fungicide selected from a group comprising Cyprodinil and Pyrimethanil,

[0200] (20) an azanaphthalene fungicide selected from a group comprising Quinoxyfen and Proquinazid,

[0201] (21) a keto-reductase Inhibitor fungicide selected from a group comprising Fenhexamid and Fenpyrazamine,

[0202] (22) a guanidine fungicide selected from a group comprising Dodine,

[0203] (23) a phthalimide fungicide selected from a group comprising Folpet and Captan, (24) a naphthodithiin fungicide selected from a group comprising Dithianon,

[0204] (25) a triazole fungicide selected from a group comprising Mefentrifluconazole, Ipfentrifluconazole and Tricyclazole,

[0205] (26) a thiazolidine fungicide selected from a group comprising Flutianil,

[0206] (27) a pyridine fungicide selected from a group comprising Aminopyrifen,

[0207] (28) a quinoline fungicide selected from a group comprising Quinofumelin, Ipflufenoquin and Tebufloquin,

[0208] (29) a phenylpyrrole fungicide selected from a group comprising Fludioxonil,

[0209] (30) a tubulin polymerization promoter selected from a group comprising Pyridachlometyl,

[0210] (31) a benzothiadiazole fungicide selected from a group comprising Acibenzolar-S- methyl,

[0211] (32) a thiazole carboxamide fungicide selected from a group comprising Isotianil,

[0212] (33) a benzothiazole fungicide selected from a group comprising Dichlobentiazox, and

[0213] (34) probiotic microbial species selected from a group comprising Bacillus, Lactococcus and Saccharomyces, has a synergistically increased action on the control of fungal diseases in crop plants without causing phytotoxicity to the plants. A particular advantage of the composition according to the present invention is that this synergistic effect among the active components allows for a reduction of the total amount of sulphur or fungicide used on the crops while still having a good control of fungal diseases.

[0214] It has now been found that a combination comprising a Sulphur, which includes a biosulphur and at least one fungicide chemical compound II selected from the group consisting of:

[0215] (1) a phenylacetamide fungicide selected from a group comprising Cyflufenamid,

[0216] (2) a polysaccharide compound selected from group comprising Laminarin and Chitosan,

[0217] (3) a plant extract from beet which comprises Trimethyl glycine,

[0218] (4) a plant extract fungicide which is extracted from Melaleuca alternifolia,

[0219] (5) a plant extract fungicide extracted from a plant oil, which is selected from a group consisting of Eugenol, Geraniol, Thymol and any combination thereof,

[0220] (6) a plant extract fungicide which is selected from the group consisting of terpene hydrocarbons, terpene alcohol, terpene phenols and any combination thereof, (7) a plant extract from cotyledons of lupine plantlets, which comprises polypeptides,

[0221] (8) a plant extract selected from Seaweed extracts which are derived from the extraction of macroalgae species,

[0222] (9) a plant extract fungicide which is extracted from Swinglea glutinosa,

[0223] (10) an amine fungicide selected from a group comprising Fenpropidin, Fenpropimorph and Spiroxamine,

[0224] (11) an oxysterol binding protein inhibitor compound selected from a group comprising Oxathiapiprolin and Fluoxapiprolin,

[0225] (12) a pyrimidine fungicide selected from a group comprising 5-fluoro-4-imino-3-methyl- l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one and Bupirimate,

[0226] (13) a quinone inside inhibitor selected from a group comprising Fenpicoxamid, Florylpicoxamid, Cyazofamid and Amisulbrom,

[0227] (14) a quinone outside inhibitor selected from a group comprising Azoxystrobin, Picoxistrobin, Pyraclostrobin and Metyltetraprole,

[0228] (15) a succinate dehydrogenase inhibitor selected from a group comprising Isofetamid, Fluopyram and Pyrapropoyne,

[0229] (16) a tetrazolyloxime fungicide selected from a group comprising Picarbutrazox,

[0230] (17) a benzamide fungicide selected from a group comprising Zoxamide, Fluopicolide and Fluopimomide,

[0231] (18) a benzophenone fungicide selected from a group comprising Metrafenone and Pyriofenone,

[0232] (19) an anilino-pyrimidine fungicide selected from a group comprising Cyprodinil and Pyrimethanil,

[0233] (20) an azanaphthalene fungicide selected from a group comprising Quinoxyfen and Proquinazid,

[0234] (21) a keto-reductase Inhibitor fungicide selected from a group comprising Fenhexamid and Fenpyrazamine,

[0235] (22) a guanidine fungicide selected from a group comprising Dodine,

[0236] (23) a phthalimide fungicide selected from a group comprising Folpet and Captan,

[0237] (24) a naphthodithiin fungicide selected from a group comprising Dithianon, (25) a triazole fungicide selected from a group comprising Mefentrifluconazole, Ipfentrifluconazole and Tricyclazole,

[0238] (26) a thiazolidine fungicide selected from a group comprising Flutianil,

[0239] (27) a pyridine fungicide selected from a group comprising Aminopyrifen,

[0240] (28) a quinoline fungicide selected from a group comprising Quinofumelin, Ipflufenoquin and Tebufloquin,

[0241] (29) a phenylpyrrole fungicide selected from a group comprising Fludioxonil,

[0242] (30) a tubulin polymerization promoter selected from a group comprising Pyridachlometyl,

[0243] (31) a benzothiadiazole fungicide selected from a group comprising Acibenzolar-S- methyl,

[0244] (32) a thiazole carboxamide fungicide selected from a group comprising Isotianil,

[0245] (33) a benzothiazole fungicide selected from a group comprising Dichlobentiazox, and

[0246] (34) probiotic microbial species selected from a group comprising Bacillus, Lactococcus and Saccharomyces, has an increased action on protecting plant or soil against fungal attack, preventing fungal infection of plant or soil, controlling fungal disease infecting plant or soil, and reducing fungal infection of plant or soil without causing phytotoxicity to the plant. The increased action can be a synergistically increased action. A particular advantage of the combination according to the present invention is that this synergistic effect among the active components allows for a reduction of the total amount of Sulphur or fungicide used on the plant or soil while still having a good effect of treating the plant or soil against fungal infection. Synergism occurs when the effect of two or more compounds exceeds the effect of the compounds when used alone.

[0247] In an embodiment, the fungicide chemical compound II is Cyflufenamid.

[0248] In an embodiment, the fungicide chemical compound II is at least one of Laminarin and Chitosan. In a specific embodiment, the fungicide chemical compound II is Laminarin. In another specific embodiment, the fungicide chemical compound II is Chitosan.

[0249] In an embodiment, the fungicide chemical compound II is Trimethyl glycine.

[0250] In an embodiment, the fungicide chemical compound II is plant extract from Melaleuca alternifolia. In an embodiment, the fungicide chemical compound II is at least one of Eugenol, Geraniol, Thymol and any combination thereof from a plant oil. In a specific embodiment, the fungicide chemical compound II is Eugenol. In another specific embodiment, the fungicide chemical compound II is Geraniol. In another specific embodiment, the fungicide chemical compound II is Thymol.

[0251] In an embodiment, the fungicide chemical compound II is at least one of terpene hydrocarbons, terpene alcohol, terpene phenols and any combination thereof. In a specific embodiment, the fungicide chemical compound II is terpene hydrocarbons. In another specific embodiment, the fungicide chemical compound II is terpene alcohol. In another specific embodiment, the fungicide chemical compound II is terpene phenols.

[0252] In an embodiment, the fungicide chemical compound II is at least one of polypeptides which is a plant extract from cotyledons of lupine plantlets.

[0253] In an embodiment, the fungicide chemical compound II is at least one of Seaweed extracts derived from the extraction of macroalgae species.

[0254] In an embodiment, the fungicide chemical compound II is at least one of plant extract from Swinglea glutinosa.

[0255] In an embodiment, the fungicide chemical compound II is at least one of Fenpropidin, Fenpropimorph and Spiroxamine. In a specific embodiment, the fungicide chemical compound II is Fenpropidin. In another specific embodiment, the fungicide chemical compound II is Fenpropimorph. In another specific embodiment, the fungicide chemical compound II is Spiroxamine.

[0256] In an embodiment, the fungicide chemical compound II is at least one of Oxathiapiprolin and Fluoxapiprolin. In a specific embodiment, the fungicide chemical compound II is Oxathiapiprolin. In another specific embodiment, the fungicide chemical compound II is Fluoxapiprolin.

[0257] In an embodiment, the fungicide chemical compound II is at least one of 5-fluoro-4- imino-3-methyl-l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one and Bupirimate. In a specific embodiment, the fungicide chemical compound II is 5-fluoro-4-imino-3-methyl-l- [(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one. In another specific embodiment, the fungicide chemical compound II is Bupirimate. In an embodiment, the fungicide chemical compound II is at least one of Fenpicoxamid, Florylpicoxamid, Cyazofamid and Amisulbrom. In a specific embodiment, the fungicide chemical compound II is Fenpicoxamid. In another specific embodiment, the fungicide chemical compound II is Florylpicoxamid. In another specific embodiment, the fungicide chemical compound II is Cyazofamid. In another specific embodiment, the fungicide chemical compound II is Amisulbrom.

[0258] In an embodiment, the fungicide chemical compound II is at least one of Azoxystrobin, Picoxistrobin, Pyraclostrobin and Metyltetraprole. In a specific embodiment, the fungicide chemical compound II is Azoxystrobin. In another specific embodiment, the fungicide chemical compound II is Picoxistrobin. In another specific embodiment, the fungicide chemical compound II is Pyraclostrobin. In another specific embodiment, the fungicide chemical compound II is Metyltetraprole.

[0259] In an embodiment, the fungicide chemical compound II is at least one of Isofetamid, Fluopyram and Pyrapropoyne. In a specific embodiment, the fungicide chemical compound II is Isofetamid. In another specific embodiment, the fungicide chemical compound II is Fluopyram. In another specific embodiment, the fungicide chemical compound II is Pyrapropoyne.

[0260] In an embodiment, the fungicide chemical compound II is Picarbutrazox.

[0261] In an embodiment, the fungicide chemical compound II is at least one of Zoxamide, Fluopicolide and Fluopimomide. In a specific embodiment, the fungicide chemical compound II is Zoxamide. In another specific embodiment, the fungicide chemical compound II is Fluopicolide. In another specific embodiment, the fungicide chemical compound II is Fluopimomide.

[0262] In an embodiment, the fungicide chemical compound II is at least one of Metrafenone and Pyriofenone. In a specific embodiment, the fungicide chemical compound II is Metrafenone. In another specific embodiment, the fungicide chemical compound II is Pyriofenone.

[0263] In an embodiment, the fungicide chemical compound II is at least one of Cyprodinil and Pyrimethanil. In a specific embodiment, the fungicide chemical compound II is Cyprodinil. In another specific embodiment, the fungicide chemical compound II is Pyrimethanil. In an embodiment, the fungicide chemical compound II is at least one of Quinoxyfen and Proquinazid. In a specific embodiment, the fungicide chemical compound II is Quinoxyfen. In another specific embodiment, the fungicide chemical compound II is Proquinazid.

[0264] In an embodiment, the fungicide chemical compound II is at least one of Fenhexamid and Fenpyrazamine. In a specific embodiment, the fungicide chemical compound II is Fenhexamid. In another specific embodiment, the fungicide chemical compound II is Fenpyrazamine.

[0265] In an embodiment, the fungicide chemical compound II is Dodine.

[0266] In an embodiment, the fungicide chemical compound II is at least one of Folpet and Captan. In a specific embodiment, the fungicide chemical compound II is Folpet. In another specific embodiment, the fungicide chemical compound II is Captan.

[0267] In an embodiment, the fungicide chemical compound II is Dithianon.

[0268] In an embodiment, the fungicide chemical compound II is at least one of Mefentrifluconazole, Ipfentrifluconazole and Tricyclazole. In a specific embodiment, the fungicide chemical compound II is Mefentrifluconazole. In another specific embodiment, the fungicide chemical compound II is Ipfentrifluconazole. In another specific embodiment, the fungicide chemical compound II is Tricyclazole.

[0269] In an embodiment, the fungicide chemical compound II is Flutianil.

[0270] In an embodiment, the fungicide chemical compound II is Aminopyrifen.

[0271] In an embodiment, the fungicide chemical compound II is at least one of Quinofumelin, Ipflufenoquin and Tebufloquin. In a specific embodiment, the fungicide chemical compound II is Quinofumelin. In another specific embodiment, the fungicide chemical compound II is Ipflufenoquin. In another specific embodiment, the fungicide chemical compound II is Tebufloquin.

[0272] In an embodiment, the fungicide chemical compound II is Fludioxonil.

[0273] In an embodiment, the fungicide chemical compound II is Pyridachlometyl.

[0274] In an embodiment, the fungicide chemical compound II is Acibenzolar-S-methyl.

[0275] In an embodiment, the fungicide chemical compound II is Isotianil.

[0276] In an embodiment, the fungicide chemical compound II is Dichlobentiazox.

[0277] In an embodiment, the fungicide chemical compound II is at least one of Bacillus, Lactococcus and Saccharomyces. In a specific embodiment, the fungicide chemical compound II is Bacillus. In another specific embodiment, the fungicide chemical compound II is Lactococcus. In another specific embodiment, the fungicide chemical compound II is Saccharomyces.

[0278] The weight ratio between Sulphur, which includes a bio-sulphur and at least one fungicide chemical compound II, as defined above, varies depending upon various conditions such as the type of the formulation, weather conditions, the type of crop and the type of fungi.

[0279] In one embodiment, the weight ratio of Sulphur to the fungicide chemical compound II is from about 1:100 to 100:1. In another embodiment, the weight ratio of the Sulphur to the fungicide chemical compound II is from about 1:50 to 50:1.

[0280] The weight ratio of the Sulphur to the fungicide chemical compound II may be any inbetween range selected from the above indicated ratios.

[0281] In one embodiment, the weight ratio of Sulphur to phenylacetamide fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to phenylacetamide fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to phenylacetamide fungicide may be any in-between range selected from the above indicated ratios.

[0282] In a specific embodiment, the weight ratio of Sulphur to Cyflufenamid is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Cyflufenamid is from about 1:50 to 50:1.

[0283] In one embodiment, the weight ratio of Sulphur to polysaccharide compound is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to polysaccharide compound fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to polysaccharide compound may be any in-between range selected from the above indicated ratios.

[0284] In a specific embodiment, the weight ratio of Sulphur to Laminarin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Laminarin is from about 1:50 to 50:1.

[0285] In a specific embodiment, the weight ratio of Sulphur to Chitosan is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Chitosan is from about 1:50 to 50:1.

[0286] In one embodiment, the weight ratio of Sulphur to a plant extract from beet is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a plant extract from beet is from about 1:50 to 50:1. The weight ratio of Sulphur to a plant extract from beet may be any in-between range selected from the above indicated ratios. In a specific embodiment, the weight ratio of Sulphur to Trimethyl glycine is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Trimethyl glycine is from about 1:50 to 50:1.

[0287] In one embodiment, the weight ratio of Sulphur to plant extract fungicide from Melaleuca alternifolia is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to plant extract fungicide from Melaleuca alternifolia is from about 1:50 to 50:1. The weight ratio of Sulphur to plant extract fungicide from Melaleuca alternifolia may be any inbetween range selected from the above indicated ratios.

[0288] In one embodiment, the weight ratio of Sulphur to a plant oil is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a plant oil is from about 1:50 to 50:1. The weight ratio of Sulphur to a plant oil may be any in-between range selected from the above indicated ratios.

[0289] In a specific embodiment, the weight ratio of Sulphur to Eugenol is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Eugenol is from about 1:50 to 50:1.

[0290] In a specific embodiment, the weight ratio of Sulphur to Geraniol is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Geraniol is from about 1:50 to 50:1.

[0291] In a specific embodiment, the weight ratio of Sulphur to Thymol is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Thymol is from about 1:50 to 50:1.

[0292] In one embodiment, the weight ratio of Sulphur to Terpene compounds from plant extract is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Terpene compounds from plant extract is from about 1:50 to 50:1. The weight ratio of Sulphur to Terpene compounds from plant extract may be any in-between range selected from the above indicated ratios.

[0293] In a specific embodiment, the weight ratio of Sulphur to terpene hydrocarbons is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to terpene hydrocarbons is from about 1:50 to 50:1. In a specific embodiment, the weight ratio of Sulphur to terpene alcohol is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to terpene alcohol is from about 1:50 to 50:1.

[0294] In a specific embodiment, the weight ratio of Sulphur to terpene phenol is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to terpene phenol is from about 1:50 to 50:1.

[0295] In one embodiment, the weight ratio of Sulphur to polypeptides from cotyledons of lupine plantlets is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to polypeptides from cotyledons of lupine plantlets is from about 1:50 to 50:1. The weight ratio of Sulphur to polypeptides from cotyledons of lupine plantlets may be any inbetween range selected from the above indicated ratios.

[0296] In one embodiment, the weight ratio of Sulphur to Seaweed extracts from macroalgae species is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Seaweed extracts from macroalgae species is from about 1:50 to 50:1. The weight ratio of Sulphur to Seaweed extracts from macroalgae species may be any in-between range selected from the above indicated ratios.

[0297] In one embodiment, the weight ratio of Sulphur to plant extract from Swinglea glutinosa is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to plant extract from Swinglea glutinosa is from about 1:50 to 50:1. The weight ratio of Sulphur to plant extract from Swinglea glutinosa may be any in-between range selected from the above indicated ratios.

[0298] In one embodiment, the weight ratio of Sulphur to amine fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to amine fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to amine fungicide may be any in-between range selected from the above indicated ratios.

[0299] In a specific embodiment, the weight ratio of Sulphur to Fenpropidin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fenpropidin is from about 1:50 to 50:1.

[0300] In a specific embodiment, the weight ratio of Sulphur to Fenpropimorph is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fenpropimorph is from about 1:50 to 50:1. In a specific embodiment, the weight ratio of Sulphur to Spiroxamine is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Spiroxamine is from about 1:50 to 50:1.

[0301] In one embodiment, the weight ratio of Sulphur to an oxysterol binding protein inhibitor compound is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to an oxysterol binding protein inhibitor compound is from about 1:50 to 50:1. The weight ratio of Sulphur to an oxysterol binding protein inhibitor compound may be any in-between range selected from the above indicated ratios.

[0302] In a specific embodiment, the weight ratio of Sulphur to Oxathiapiprolin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Oxathiapiprolin is from about 1:50 to 50:1.

[0303] In a specific embodiment, the weight ratio of Sulphur to Fluoxapiprolin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fluoxapiprolin is from about 1:50 to 50:1.

[0304] In one embodiment, the weight ratio of Sulphur to pyrimidine fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to pyrimidine fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to pyrimidine fungicide may be any inbetween range selected from the above indicated ratios.

[0305] In a specific embodiment, the weight ratio of Sulphur to 5-fluoro-4-imino-3-methyl-l- [(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to 5-fluoro-4-imino-3-methyl-l-[(4- methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one is from about 1:50 to 50:1.

[0306] In a specific embodiment, the weight ratio of Sulphur to Bupirimate is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Bupirimate is from about 1:50 to 50:1.

[0307] In one embodiment, the weight ratio of Sulphur to a quinone inside inhibitor is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a quinone inside inhibitor is from about 1:50 to 50:1. The weight ratio of Sulphur to a quinone inside inhibitor may be any in-between range selected from the above indicated ratios. In a specific embodiment, the weight ratio of Sulphur to Fenpicoxamid is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fenpicoxamid is from about 1:50 to 50:1.

[0308] In a specific embodiment, the weight ratio of Sulphur to Florylpicoxamid is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Florylpicoxamid is from about 1:50 to 50:1.

[0309] In a specific embodiment, the weight ratio of Sulphur to Cyazofamid is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Cyazofamid is from about 1:50 to 50:1.

[0310] In a specific embodiment, the weight ratio of Sulphur to Amisulbrom is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Amisulbrom is from about 1:50 to 50:1.

[0311] In one embodiment, the weight ratio of Sulphur to a quinone outside inhibitor is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a quinone outside inhibitor is from about 1:50 to 50:1. The weight ratio of Sulphur to a quinone outside inhibitor may be any in-between range selected from the above indicated ratios.

[0312] In a specific embodiment, the weight ratio of Sulphur to Azoxystrobin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Azoxystrobin is from about 1:50 to 50:1.

[0313] In a specific embodiment, the weight ratio of Sulphur to Picoxistrobin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Picoxistrobin is from about 1:50 to 50:1.

[0314] In a specific embodiment, the weight ratio of Sulphur to Pyraclostrobin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Pyraclostrobin is from about 1:50 to 50:1.

[0315] In a specific embodiment, the weight ratio of Sulphur to Metyltetraprole is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Metyltetraprole is from about 1:50 to 50:1.

[0316] In one embodiment, the weight ratio of Sulphur to a succinate dehydrogenase inhibitor is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a succinate dehydrogenase inhibitor is from about 1:50 to 50:1. The weight ratio of Sulphur to a succinate dehydrogenase inhibitor may be any in-between range selected from the above indicated ratios.

[0317] In a specific embodiment, the weight ratio of Sulphur to Isofetamid is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Isofetamid is from about 1:50 to 50:1.

[0318] In a specific embodiment, the weight ratio of Sulphur to Fluopyram is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fluopyram is from about 1:50 to 50:1.

[0319] In a specific embodiment, the weight ratio of Sulphur to Pyrapropoyne is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Pyrapropoyne is from about 1:50 to 50:1.

[0320] In one embodiment, the weight ratio of Sulphur to a tetrazolyloxime fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a tetrazolyloxime fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a tetrazolyloxime fungicide may be any in-between range selected from the above indicated ratios.

[0321] In a specific embodiment, the weight ratio of Sulphur to Picarbutrazox is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Picarbutrazox is from about 1:50 to 50:1.

[0322] In one embodiment, the weight ratio of Sulphur to a benzamide fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a benzamide fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a benzamide fungicide may be any inbetween range selected from the above indicated ratios.

[0323] In a specific embodiment, the weight ratio of Sulphur to Zoxamide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Zoxamide is from about 1:50 to 50:1.

[0324] In a specific embodiment, the weight ratio of Sulphur to Fluopicolide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fluopicolide is from about 1:50 to 50:1.

[0325] In a specific embodiment, the weight ratio of Sulphur to Fluopimomide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fluopimomide is from about 1:50 to 50:1. In one embodiment, the weight ratio of Sulphur to a benzophenone fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a benzophenone fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a benzophenone fungicide may be any in-between range selected from the above indicated ratios.

[0326] In a specific embodiment, the weight ratio of Sulphur to Metrafenone is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Metrafenone is from about 1:50 to 50:1.

[0327] In a specific embodiment, the weight ratio of Sulphur to Pyriofenone is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Pyriofenone is from about 1:50 to 50:1.

[0328] In one embodiment, the weight ratio of Sulphur to an anilino-pyrimidine fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to an anilino- pyrimidine fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to an anilino- pyrimidine fungicide may be any in-between range selected from the above indicated ratios.

[0329] In a specific embodiment, the weight ratio of Sulphur to Cyprodinil is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Cyprodinil is from about 1:50 to 50:1.

[0330] In a specific embodiment, the weight ratio of Sulphur to Pyrimethanil is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Pyrimethanil is from about 1:50 to 50:1.

[0331] In one embodiment, the weight ratio of Sulphur to an azanaphthalene fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to an azanaphthalene fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to an azanaphthalene fungicide may be any in-between range selected from the above indicated ratios.

[0332] In a specific embodiment, the weight ratio of Sulphur to Quinoxyfen is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Quinoxyfen is from about 1:50 to 50:1.

[0333] In a specific embodiment, the weight ratio of Sulphur to Proquinazid is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Proquinazid is from about 1:50 to 50:1. In one embodiment, the weight ratio of Sulphur to a keto-reductase Inhibitor fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a ketoreductase Inhibitor fungicide from plant extract is from about 1:50 to 50:1. The weight ratio of Sulphur to a keto-reductase Inhibitor fungicide from plant extract may be any in-between range selected from the above indicated ratios.

[0334] In a specific embodiment, the weight ratio of Sulphur to Fenhexamid is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fenhexamid is from about 1:50 to 50:1.

[0335] In a specific embodiment, the weight ratio of Sulphur to Fenpyrazamine is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fenpyrazamine is from about 1:50 to 50:1.

[0336] In one embodiment, the weight ratio of Sulphur to a guanidine fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a guanidine fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a guanidine fungicide may be any inbetween range selected from the above indicated ratios.

[0337] In a specific embodiment, the weight ratio of Sulphur to Dodine is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Dodine is from about 1:50 to 50:1.

[0338] In one embodiment, the weight ratio of Sulphur to a phthalimide fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a phthalimide fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a phthalimide fungicide may be any in-between range selected from the above indicated ratios.

[0339] In a specific embodiment, the weight ratio of Sulphur to Folpet is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Folpet is from about 1:50 to 50:1.

[0340] In a specific embodiment, the weight ratio of Sulphur to Captan is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Captan is from about 1:50 to 50:1.

[0341] In one embodiment, the weight ratio of Sulphur to a naphthodithiin fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a naphthodithiin fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a naphthodithiin fungicide may be any in-between range selected from the above indicated ratios. In a specific embodiment, the weight ratio of Sulphur to Dithianon is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Dithianon is from about 1:50 to 50:1.

[0342] In one embodiment, the weight ratio of Sulphur to a triazole fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a triazole fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a triazole fungicide may be any inbetween range selected from the above indicated ratios.

[0343] In a specific embodiment, the weight ratio of Sulphur to Mefentrifluconazole is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Mefentrifluconazole is from about 1:50 to 50:1.

[0344] In a specific embodiment, the weight ratio of Sulphur to Ipfentrifluconazole is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Ipfentrifluconazole is from about 1:50 to 50:1.

[0345] In a specific embodiment, the weight ratio of Sulphur to Tricyclazole is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Tricyclazole is from about 1:50 to 50:1.

[0346] In one embodiment, the weight ratio of Sulphur to a thiazolidine fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a thiazolidine fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a thiazolidine fungicide may be any in-between range selected from the above indicated ratios.

[0347] In a specific embodiment, the weight ratio of Sulphur to Flutianil is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Flutianil is from about 1:50 to 50:1.

[0348] In one embodiment, the weight ratio of Sulphur to a pyridine fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a pyridine fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a pyridine fungicide may be any inbetween range selected from the above indicated ratios.

[0349] In a specific embodiment, the weight ratio of Sulphur to Aminopyrifen is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Aminopyrifen is from about 1:50 to 50:1. In one embodiment, the weight ratio of Sulphur to a quinoline fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a quinoline fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a quinoline fungicide may be any inbetween range selected from the above indicated ratios.

[0350] In a specific embodiment, the weight ratio of Sulphur to Quinofumelin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Quinofumelin is from about 1:50 to 50:1.

[0351] In a specific embodiment, the weight ratio of Sulphur to Ipflufenoquin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Ipflufenoquin is from about 1:50 to 50:1.

[0352] In a specific embodiment, the weight ratio of Sulphur to Tebufloquin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Tebufloquin is from about 1:50 to 50:1.

[0353] In one embodiment, the weight ratio of Sulphur to a phenylpyrrole fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a phenylpyrrole fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a phenylpyrrole fungicide may be any in-between range selected from the above indicated ratios.

[0354] In a specific embodiment, the weight ratio of Sulphur to Fludioxonil is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Fludioxonil is from about 1:50 to 50:1.

[0355] In one embodiment, the weight ratio of Sulphur to a tubulin polymerization promoter is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a tubulin polymerization promoter is from about 1:50 to 50:1. The weight ratio of Sulphur to a tubulin polymerization promoter may be any in-between range selected from the above indicated ratios.

[0356] In a specific embodiment, the weight ratio of Sulphur to Pyridachlometyl is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Pyridachlometyl is from about 1:50 to 50:1.

[0357] In one embodiment, the weight ratio of Sulphur to a benzothiadiazole fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a benzothiadiazole fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a benzothiadiazole fungicide may be any in-between range selected from the above indicated ratios.

[0358] In a specific embodiment, the weight ratio of Sulphur to Acibenzolar-S-methyl is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Acibenzolar-S- methyl is from about 1:50 to 50:1.

[0359] In one embodiment, the weight ratio of Sulphur to a thiazole carboxamide fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a thiazole carboxamide fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a thiazole carboxamide fungicide may be any in-between range selected from the above indicated ratios.

[0360] In a specific embodiment, the weight ratio of Sulphur to Isotianil is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Isotianil is from about 1:50 to 50:1.

[0361] In one embodiment, the weight ratio of Sulphur to a benzothiazole fungicide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to a benzothiazole fungicide is from about 1:50 to 50:1. The weight ratio of Sulphur to a benzothiazole fungicide may be any in-between range selected from the above indicated ratios.

[0362] In a specific embodiment, the weight ratio of Sulphur to Dichlobentiazox is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Dichlobentiazox is from about 1:50 to 50:1.

[0363] In one embodiment, the weight ratio of Sulphur to probiotic microbial species is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to probiotic microbial species is from about 1:50 to 50:1. The weight ratio of Sulphur to probiotic microbial species may be any in-between range selected from the above indicated ratios.

[0364] In a specific embodiment, the weight ratio of Sulphur to Bacillus is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Bacillus is from about 1:50 to 50:1.

[0365] In a specific embodiment, the weight ratio of Sulphur to Lactococcus is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Lactococcus is from about 1:50 to 50:1. In a specific embodiment, the weight ratio of Sulphur to Saccharomyces is from about 1:100 to 100:1. In another embodiment, the weight ratio of Sulphur to Saccharomyces is from about 1:50 to 50:1.

[0366] In an embodiment, the mixture combination of the present invention may be applied pre-sowing or post-sowing, pre-emergence, or early-post-emergence of the crop. The mixture combination may be applied via in furrow spray, foliar application, broadcast, basal application, soil application, soil incorporation or soil injection.

[0367] In a further embodiment, the mixture combination is applied in non-crop areas which include but are not limited to, commercial areas, residential areas, lawns, ornamental plants, shrubs, trees, parks, livestock areas, warehouses, food storage facilities, grain bins, turfgrass, pastures, grasslands, rangelands, fallow land, rights-of-way, golf courses, parks, along roadsides, power-lines, pipelines, railways, forests, well sites, and equipment yards.

[0368] In yet another embodiment, the crop plants include but are not limited to cereals (wheat, barley, rye, oats, rice, sorghum and related crops); beet (sugar beet and fodder beet); pome fruits (apples, pears), stone fruit and soft fruit (plums, peaches, almonds, cherries, strawberries, raspberries and blackberries); leguminous plants (beans, lentils, peas, soybeans); oil plants (rape, mustard, poppy, olives, sunflowers, coconut, castor oil plants, cocoa beans, groundnuts); cucumber plants (marrows, cucumbers, melons); fibre plants (cotton, flax, hemp, jute); citrus fruit (oranges, lemons, grapefruit, mandarins); vegetables (spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, paprika); lauraceae (avocados, cinnamon, camphor); or plants such as maize, tobacco, nuts, coffee, sugar cane, tea, vines, hops, bananas and natural rubber plants, as well as ornamentals (flowers, shrubs, broadleaved trees and evergreens, such as conifers).

[0369] In further embodiment, the crop plants include cultivated plants which tolerate the action of herbicides, fungicides, or insecticides as a result of breeding and / or genetically engineered methods.

[0370] In an embodiment, the target fungi include but are not limited to Frosty pod (Moniliophthora roreri), Witches' broom (Moniliophthora perniciosa), Seedling blight / foliar&ear disease (Microdochium sp.), Botryosphaeria Panicle and Shoot Blight (Botryosphaeria dothidea), Band canker (Botryosphaeria dothidea), Black rot (Phyllosticta ampelicida), Black sigatoka (Pseudocercospora fijiensis ; Mycosphaerella fijiensis), Septoria (Zymoseptoria tritici), Ramularia leaf spot (Ramularia collo-cygni), Gray Leaf Spot (Cercospora zeae-maydis), Ramularia leaf spot (Ramularia areola), leaf spot of beet (Cercospora beticola), Ramularia leaf spot (Ramularia beticola), Yellow sigatoka (Pseudocercospora musae), Early leaf spot (Mycosphaerella arachidis), Late leaf spot (Mycosphaerella berkeleyi), Ashy leaf spot of pear (Mycosphaerella pyri), Leaf spot (Cercospora sp.), Septoria brown spot (Septoria glycines), Purple Seed Stain (Cercospora kikuchii), Scab (Cladosporium sp.), Leaf spot of hop (Pseudocercospora cantuariensis), White leaf spot (Neopseudocercosporella capsellae), Barn spot (Cercospora nicotianae), Sheath Blight (Rhizoctonia solani / Thanatephorus cucumeris), Rizoctonia (Rhizoctonia solani / Thanatephorus cucumeris), Damping off / root rot (Rhizoctonia solani / Thanatephorus cucumeris), Rizoctonia (Rhizoctonia solani / Thanatephorus cucumeris), Rhizoctonia root and crown rot (Rhizoctonia solani / Thanatephorus cucumeris), Pink Disease (Erythricium salmonicolor), Dead-arm (Diaporthe neoviticola), Eyespot (Kabatiella zeae), Powedery mildew (Blumeria graminis), Powdery mildew (Erysiphe cichoracearum), Powdery mildew (Sphaerotheca fuliginea), Powdery mildew (Erysiphe necator), Powdery mildew (Podosphaera macularis), Powdery mildew (Podosphaera leucotricha), Powdery mildew (Leveillula taurica / Oidium Neolycopersici), powdery mildew (Erysiphe betae / Erysiphe polygoni), Powdery mildew (Erysiphe sp.), Powdery mildew (Podosphaera pannosa), Downy mildew (Peronospora tabacina), Powdery mildew (Erysiphe sp. / Oidium sp), Powdery mildew (Leveillula Taurica), Powdery mildew (Erysiphe cruciferarum), Powdery mildew (Erysiphe diffusa), Aspergillus ear rot (Aspergillus sp.), Light leaf Spot (Pyrenopeziza brassicae), Bark canker of apple (Phlyctema vagabunda), Leaf spot (Blumeriella jaapii), Grey mold (Botrytis cinereal), Sclerotinia (Sclerotinia sclerotiorum), Grey mould, (Botrytis cinereal), Monilia (Monilinia spp. / Monilinia laxa / Monilia fructigena / Monilia fructicola), Botrytis blight (Botrytis cinereal), Grey mold (Botrytis sp.), White mould (Sclerotinia sp.), Sclerotinia stem rot or white mold (Sclerotinia sclerotiorum), Brown rot blossom (Monilinia fructicola), Grey mould (Botrytis cinereal), Grey mould (Botrytis cinereal), Botrytis Blossom and Shoot Blight(Botrytis cinereal), Leaf blotch of cereals (Rhynchosporium secalis), Fusarium head blight (Fusarium sp.), Maize Ear and Kernel Rot (Fusarium sp.), Eye rot (Neonectria galligena), Bakanae disease (Gibberella fujikuroi), Giberrella stalk and ear rot (Gibberella zeae), Coffee Wilt Disease (Gibberella xylarioides), Anthracnose of grapevine (Elsinoe ampelina), Crown and root rot (Phytophthora sp.), Black pod (Phytophthora palmivora / Phytophthora megakarya / Phytophthora capsica), Downy milde (Pseudoperonospora cubensis), Downy mildew (Plasmopara viticola), Downy mildew (Pseudoperonospora humul), Late blight (Phytophthora infestans), Downy mildew (Peronospora viciae / Phytopthora sp.), Late blight (Phytophthora infestans), Downy mildew (Hyaloperonospora parasitica), Downy mildew (Peronospora farinose), Coffee Berry Disease (Colletotrichum kahawae), Anthracnose (Colletotrichum sp.), Antracnose (Colletotrichum sp). Anthracnose (Colletotrichum musae), Anthracnose (Colletotrichum spp.), Anthracnose (Glomerella cingulate), Anthracnose (Colletotrichum graminicola), Anthracnose (Glomerella gossypii), Fruit rot (Glomerella cingulate), Red rot (Colletotrichum falcatum), Anthracnose (Colletotrichum destructivum), Leaf spot (Polystigma rubrum), Club rot (Plasmodiophora brassicae), Target spot (Corynesporacassiicola), Didymella pisi (Ascochyta rabiei), Boll rot (Ascochyta gossypiicola), Leaf spot of apple (Didymella pomorum), Leaf and pod spot (Didymella sp.), Shot-hole of stone fruit (Wilsonomyces carpophilus), Shot-hole of stone fruit (Wilsonomyces carpophilus), Phoma stem canker and leaf spot (Plenodomus lingam), black leg of beet (Neocamarosporium betae), Yellow spot (Pyrenophora triticirepentis / Drechslera tritici-repentis), Net blotch (Pyrenophora teres), Northern Corn Leaf Blight (Setosphaeria turcica), Southern corn leaf blight (Cochliobolus heterostrophus), Northern Corn Leaf Spot (Cochliobolus carbonum), Leaf blight (Alternaria spp. / Alternaria cucumerina), Alternaria (Alternaria alternate), Brown spot of pear (Pleospora allii), Alternaria blotch of apple (Alternaria mali / Alternaria sp.), Early blight (Alternaria sp.), Early blight (Alternaria sp.) Alternaria late blight (Alternaria sp.) Brown spot (Alternaria alternate), Brown spot (Alternaria alternate), Leaf spot (Alternaria sp.), Brown spot (Cochliobolus miyabeanus), Eyespot (Helminthosporium sacchari), Scab (Venturia inaequalis), Scab (Venturia pyrina), Scab (Venturia carpophila), Coffee Leaf Rust (Hemileia vastatrix), Asian soybean rust (Phakopsora pachyrhizi), Panama wilt (Phakopsora gossypii), Tropical cotton rust (Phakopsora gossypii), Brown rust (Puccinia recondite), Yellow rust (Puccinia striiformis), Rust (Uromyces betae), Common Rust (Puccinia sorghi), Rust (Uromyces sp.), Cotton rust(Puccinia schedonnardi), Southwestern cotton rust (Puccinia cacabata), Rust (Tranzschelia spp.), Rice Blast (Pyricularia oryzae), leaf curl (Taphrina spp. / Taphrina deformans), Common Smut (Ustilago maydis), Smut (Ustilago scitaminea), Esca of grapevine (Phaeomoniella chlamydospore), and blossom blight (Monilinia laxa). The weight ratio between Sulphur and at least one fungicide chemical compound II, as defined above, varies depending upon various conditions such as the type of the formulation, weather conditions, the type of crop and the type of fungi.

[0371] In an embodiment, the present invention provides mixture combination comprising a Sulphur and one or more fungicide chemical compound II, as defined above, wherein the application rates of the mixture according to the invention are from 500 g / ha to 5000 g / ha. In another embodiment, the application rate of the mixture according to the invention are from 1000 g / ha to 5000 g / ha.

[0372] In another embodiment, Sulphur, and the fungicide chemical compound II, as defined above, can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.

[0373] That is, each of Sulphur, and the fungicide chemical compound II may be applied jointly or in succession. In one example, Sulphur, and the fungicide chemical compound II are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and the fungicide chemical compound II are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and the fungicide chemical compound II are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0374] For example, Sulphur, and Cyflufenamid can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Cyflufenamid are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Cyflufenamid are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Cyflufenamid are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0375] For example, Sulphur, and Laminarin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Laminarin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Laminarin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Laminarin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0376] For example, Sulphur, and Chitosan can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Chitosan are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Chitosan are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Chitosan are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0377] For example, Sulphur, and Trimethyl glycine from beet extract can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Trimethyl glycine from beet extract are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Trimethyl glycine from beet extract are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Trimethyl glycine from beet extract are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0378] For example, Sulphur, and plant extract from Melaleuca alternifolia can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and plant extract from Melaleuca alternifolia are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and plant extract from Melaleuca alternifolia are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and plant extract from Melaleuca alternifolia are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0379] For example, Sulphur, and Eugenol can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Eugenol are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Eugenol are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Eugenol are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0380] For example, Sulphur, and Geraniol can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Geraniol are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Geraniol are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Geraniol are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0381] For example, Sulphur, and Thymol can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Thymol are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Thymol are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Thymol are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0382] For example, Sulphur, and terpene hydrocarbons can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and terpene hydrocarbons are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and terpene hydrocarbons are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and terpene hydrocarbons are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0383] For example, Sulphur, and terpene alcohol can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and terpene alcohol are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and terpene alcohol are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and terpene alcohol are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0384] For example, Sulphur, and terpene phenols can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and terpene phenols are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and terpene phenols are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and terpene phenols are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0385] For example, Sulphur, and plant extract from cotyledons of lupine plantlets can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and plant extract from cotyledons of lupine plantlets are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and plant extract from cotyledons of lupine plantlets are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and plant extract from cotyledons of lupine plantlets are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0386] For example, Sulphur, and Seaweed extracts from the extraction of macroalgae species can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Seaweed extracts from the extraction of macroalgae species are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Seaweed extracts from the extraction of macroalgae species are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Seaweed extracts from the extraction of macroalgae species are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0387] For example, Sulphur, and plant extract fungicide extracted from Swinglea glutinosa can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and plant extract fungicide extracted from Swinglea glutinosa are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and plant extract fungicide extracted from Swinglea glutinosa are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and plant extract fungicide extracted from Swinglea glutinosa are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0388] For example, Sulphur, and Fenpropidin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fenpropidin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fenpropidin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fenpropidin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration. For example, Sulphur, and Fenpropimorph can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fenpropimorph are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fenpropimorph are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fenpropimorph are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0389] For example, Sulphur, and Spiroxamine can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Spiroxamine are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Spiroxamine are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Spiroxamine are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0390] For example, Sulphur, and Oxathiapiprolin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Oxathiapiprolin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Oxathiapiprolin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Oxathiapiprolin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0391] For example, Sulphur, and Fluoxapiprolin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fluoxapiprolin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fluoxapiprolin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fluoxapiprolin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0392] For example, Sulphur, and 5-fluoro-4-imino-3-methyl-l-[(4-methylphenyl)sulfonyl]-3,4- dihydropyrimidin-2(lH)-one can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and 5-fluoro-4-imino-3-methyl-l- [(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and 5-fluoro-4-imino-3-methyl-l-[(4-methylphenyl)sulfonyl]-3,4- dihydropyrimidin-2(lH)-one are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and 5-fluoro-4-imino- 3-methyl-l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0393] For example, Sulphur, and Bupirimate can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Bupirimate are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Bupirimate are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Bupirimate are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0394] For example, Sulphur, and Fenpicoxamid can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fenpicoxamid are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fenpicoxamid are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fenpicoxamid are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0395] For example, Sulphur, and Florylpicoxamid can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Florylpicoxamid are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Florylpicoxamid are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Florylpicoxamid are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0396] For example, Sulphur, and Cyazofamid can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Cyazofamid are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Cyazofamid are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Cyazofamid are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0397] For example, Sulphur, and Amisulbrom can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Amisulbrom are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Amisulbrom are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Amisulbrom are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0398] For example, Sulphur, and Azoxystrobin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Azoxystrobin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Azoxystrobin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Azoxystrobin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0399] For example, Sulphur, and Picoxistrobin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Picoxistrobin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Picoxistrobin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Picoxistrobin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0400] For example, Sulphur, and Pyraclostrobin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Pyraclostrobin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Pyraclostrobin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Pyraclostrobin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0401] For example, Sulphur, and Metyltetraprole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Metyltetraprole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Metyltetraprole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Metyltetraprole are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration. For example, Sulphur, and Isofetamid can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Isofetamid are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Isofetamid are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Isofetamid are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0402] For example, Sulphur, and Fluopyram can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fluopyram are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fluopyram are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fluopyram are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0403] For example, Sulphur, and Pyrapropoyne can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Pyrapropoyne are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Pyrapropoyne are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Pyrapropoyne are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0404] For example, Sulphur, and Picarbutrazox can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Picarbutrazox are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Picarbutrazox are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Picarbutrazox are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0405] For example, Sulphur, and Zoxamide can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Zoxamide are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Zoxamide are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Zoxamide are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0406] For example, Sulphur, and Fluopicolide can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fluopicolide are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fluopicolide are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fluopicolide are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0407] For example, Sulphur, and Fluopimomide can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fluopimomide are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fluopimomide are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fluopimomide are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0408] For example, Sulphur, and Metrafenone can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Metrafenone are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Metrafenone are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Metrafenone are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0409] For example, Sulphur, and Pyriofenone can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Pyriofenone are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Pyriofenone are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Pyriofenone are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0410] For example, Sulphur, and Cyprodinil can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Cyprodinil are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Cyprodinil are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Cyprodinil are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0411] For example, Sulphur, and Pyrimethanil can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Pyrimethanil are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Pyrimethanil are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Pyrimethanil are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration. For example, Sulphur, and Quinoxyfen can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Quinoxyfen are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Quinoxyfen are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Quinoxyfenare formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0412] For example, Sulphur, and Proquinazid can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Proquinazid are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Proquinazid are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Proquinazid formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0413] For example, Sulphur, and Fenhexamid can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fenhexamid are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fenhexamid are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fenhexamid formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0414] For example, Sulphur, and Fenpyrazamine can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fenpyrazamine are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fenpyrazamine are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fenpyrazamine formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0415] For example, Sulphur, and Dodine can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Dodine are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Dodine are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Dodine formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0416] For example, Sulphur, and Folpet can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Folpet are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Folpet are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Folpet formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0417] For example, Sulphur, and Captan can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Captan are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Captan are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Captan formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0418] For example, Sulphur, and Dithianon can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Dithianon are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Dithianon are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Dithianon formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0419] For example, Sulphur, and Mefentrifluconazole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Mefentrifluconazole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Mefentrifluconazole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Mefentrifluconazole formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0420] For example, Sulphur, and Ipfentrifluconazole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Ipfentrifluconazole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Ipfentrifluconazole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Ipfentrifluconazole formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0421] For example, Sulphur, and Tricyclazole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Tricyclazole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Tricyclazole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Tricyclazole formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0422] For example, Sulphur, and Flutianil can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Flutianil are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Flutianil are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Flutianil formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0423] For example, Sulphur, and Aminopyrifen can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Aminopyrifen are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Aminopyrifen are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Aminopyrifen formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0424] For example, Sulphur, and Quinofumelin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Quinofumelin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Quinofumelin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Quinofumelin formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0425] For example, Sulphur, and Ipflufenoquin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Ipflufenoquin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Ipflufenoquin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Ipflufenoquin formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration. For example, Sulphur, and Tebufloquin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Tebufloquin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Tebufloquin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Tebufloquin formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0426] For example, Sulphur, and Fludioxonil can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Fludioxonil are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Fludioxonil are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Fludioxonil formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0427] For example, Sulphur, and Pyridachlometyl can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Pyridachlometyl are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Pyridachlometyl are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Pyridachlometyl formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0428] For example, Sulphur, and Acibenzolar-S-methyl can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Acibenzolar-S-methyl are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Acibenzolar-S-methyl are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Acibenzolar-S-methyl formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0429] For example, Sulphur, and Isotianil can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Isotianil are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Isotianil are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Isotianil formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0430] For example, Sulphur, and Dichlobentiazox can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Dichlobentiazox are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Dichlobentiazox are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Dichlobentiazox formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0431] For example, Sulphur, and Bacillus can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Bacillus are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Bacillus are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Bacillus formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0432] For example, Sulphur, and Lactococcus can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Lactococcus are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Lactococcus are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Lactococcus formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0433] For example, Sulphur, and Saccharomyces can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures. In one example, Sulphur, and Saccharomyces are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations. In a further example, Sulphur, and Saccharomyces are prepared separately, and the formulations are mixed when diluted to a predetermined concentration. In another example, Sulphur, and Saccharomyces formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.

[0434] In some embodiments, an amount of Sulphur and an amount of a phenylacetamide fungicide if applied together are more effective than when Sulphur, at the same amount, and the phenylacetamide fungicide at the same amount, is applied alone.

[0435] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a phenylacetamide fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0436] In some embodiments, (i) the amount of Sulphur and (ii) an amount of Cyflufenamid in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0437] In some embodiments, an amount of Sulphur and an amount of a polysaccharide compound if applied together are more effective than when Sulphur, at the same amount, and the polysaccharide compound at the same amount, is applied alone.

[0438] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a polysaccharide compound in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0439] In some embodiments, an amount of Sulphur and an amount of a plant extract from beet which comprises Trimethyl glycine if applied together are more effective than when Sulphur, at the same amount, and the plant extract from beet which comprises Trimethyl glycine at the same amount, is applied alone.

[0440] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a plant extract from beet which comprises Trimethyl glycine in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0441] In some embodiments, an amount of Sulphur and an amount of a plant extract fungicide which is extracted from Melaleuca alternifolia if applied together are more effective than when Sulphur, at the same amount, and the plant extract fungicide which is extracted from Melaleuca alternifolia at the same amount, is applied alone.

[0442] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a plant extract fungicide which is extracted from Melaleuca alternifolia in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0443] In some embodiments, an amount of Sulphur and an amount of a plant extract fungicide extracted from a plant oil if applied together are more effective than when Sulphur, at the same amount, and the plant extract fungicide extracted from a plant oil at the same amount, is applied alone.

[0444] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a plant extract fungicide extracted from a plant oil in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0445] In some embodiments, an amount of Sulphur and an amount of terpene hydrocarbons if applied together are more effective than when Sulphur, at the same amount, and terpene hydrocarbons at the same amount, is applied alone.

[0446] In some embodiments, (i) the amount of Sulphur and (ii) an amount of terpene hydrocarbons in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone. In some embodiments, an amount of Sulphur and an amount of terpene alcohol if applied together are more effective than when Sulphur, at the same amount, and terpene alcohol at the same amount, is applied alone.

[0447] In some embodiments, (i) the amount of Sulphur and (ii) an amount of terpene alcohol in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0448] In some embodiments, an amount of Sulphur and an amount of terpene phenols if applied together are more effective than when Sulphur, at the same amount, and terpene phenols at the same amount, is applied alone.

[0449] In some embodiments, (i) the amount of Sulphur and (ii) an amount of terpene phenols in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0450] In some embodiments, an amount of Sulphur and an amount of a plant extract from cotyledons of lupine plantlets if applied together are more effective than when Sulphur, at the same amount, and the plant extract from cotyledons of lupine plantlets at the same amount, is applied alone.

[0451] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a plant extract from cotyledons of lupine plantlets in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0452] In some embodiments, an amount of Sulphur and an amount of seaweed extract if applied together are more effective than when Sulphur, at the same amount, and the seaweed extract at the same amount, is applied alone.

[0453] In some embodiments, (i) the amount of Sulphur and (ii) an amount of seaweed extract in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone. In some embodiments, an amount of Sulphur and an amount of plant extract from Swinglea glutinosa if applied together are more effective than when Sulphur, at the same amount, and the plant extract from Swinglea glutinosa at the same amount, is applied alone.

[0454] In some embodiments, (i) the amount of Sulphur and (ii) an amount of plant extract from Swinglea glutinosa in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0455] In some embodiments, an amount of Sulphur and an amount of an amine fungicide if applied together are more effective than when Sulphur, at the same amount, and the amine fungicide at the same amount, is applied alone.

[0456] In some embodiments, (i) the amount of Sulphur and (ii) an amount of an amine fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0457] In some embodiments, an amount of Sulphur and an amount of an oxysterol binding protein inhibitor compound if applied together are more effective than when Sulphur, at the same amount, and the oxysterol binding protein inhibitor compound at the same amount, is applied alone.

[0458] In some embodiments, (i) the amount of Sulphur and (ii) an amount of an oxysterol binding protein inhibitor compound in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0459] In some embodiments, an amount of Sulphur and an amount of a pyrimidine fungicide if applied together are more effective than when Sulphur, at the same amount, and the pyrimidine fungicide at the same amount, is applied alone.

[0460] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a pyrimidine fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone. In some embodiments, an amount of Sulphur and an amount of a quinone inside inhibitor if applied together are more effective than when Sulphur, at the same amount, and the quinone inside inhibitor at the same amount, is applied alone.

[0461] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a quinone inside inhibitor in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0462] In some embodiments, an amount of Sulphur and an amount of a quinone outside inhibitor if applied together are more effective than when Sulphur, at the same amount, and the quinone outside inhibitor at the same amount, is applied alone.

[0463] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a quinone outside inhibitor in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0464] In some embodiments, an amount of Sulphur and an amount of a succinate dehydrogenase inhibitor if applied together are more effective than when Sulphur, at the same amount, and the succinate dehydrogenase inhibitor at the same amount, is applied alone.

[0465] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a succinate dehydrogenase inhibitor in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0466] In some embodiments, an amount of Sulphur and an amount of a tetrazolyloxime fungicide if applied together are more effective than when Sulphur, at the same amount, and the tetrazolyloxime fungicide at the same amount, is applied alone.

[0467] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a tetrazolyloxime fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0468] In some embodiments, an amount of Sulphur and an amount of a benzamide fungicide if applied together are more effective than when Sulphur, at the same amount, and the benzamide fungicide at the same amount, is applied alone. In some embodiments, (i) the amount of Sulphur and (ii) an amount of a benzamide fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0469] In some embodiments, an amount of Sulphur and an amount of a benzophenone fungicide if applied together are more effective than when Sulphur, at the same amount, and the benzophenone fungicide at the same amount, is applied alone.

[0470] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a benzophenone fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0471] In some embodiments, an amount of Sulphur and an amount of an anilino-pyrimidine fungicide if applied together are more effective than when Sulphur, at the same amount, and the anilino-pyrimidine fungicide at the same amount, is applied alone.

[0472] In some embodiments, (i) the amount of Sulphur and (ii) an amount of an anilino- pyrimidine fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0473] In some embodiments, an amount of Sulphur and an amount of an azanaphthalene fungicide if applied together are more effective than when Sulphur, at the same amount, and the azanaphthalene fungicide at the same amount, is applied alone.

[0474] In some embodiments, (i) the amount of Sulphur and (ii) an amount of an azanaphthalene fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0475] In some embodiments, an amount of Sulphur and an amount of a keto-reductase Inhibitor fungicide if applied together are more effective than when Sulphur, at the same amount, and the keto-reductase Inhibitor fungicide at the same amount, is applied alone.

[0476] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a keto-reductase Inhibitor fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0477] In some embodiments, an amount of Sulphur and an amount of a guanidine fungicide if applied together are more effective than when Sulphur, at the same amount, and the guanidine fungicide at the same amount, is applied alone.

[0478] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a guanidine fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0479] In some embodiments, an amount of Sulphur and an amount of a phthalimide fungicide if applied together are more effective than when Sulphur, at the same amount, and the phthalimide fungicide at the same amount, is applied alone.

[0480] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a phthalimide fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0481] In some embodiments, an amount of Sulphur and an amount of a naphthodithiin fungicide if applied together are more effective than when Sulphur, at the same amount, and the naphthodithiin fungicide at the same amount, is applied alone.

[0482] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a naphthodithiin fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0483] In some embodiments, an amount of Sulphur and an amount of a triazole fungicide if applied together are more effective than when Sulphur, at the same amount, and the triazole fungicide at the same amount, is applied alone.

[0484] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a triazole fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone. In some embodiments, an amount of Sulphur and an amount of a thiazolidine fungicide if applied together are more effective than when Sulphur, at the same amount, and the thiazolidine fungicide at the same amount, is applied alone.

[0485] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a thiazolidine fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0486] In some embodiments, an amount of Sulphur and an amount of a pyridine fungicide if applied together are more effective than when Sulphur, at the same amount, and the pyridine fungicide at the same amount, is applied alone.

[0487] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a pyridine fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0488] In some embodiments, an amount of Sulphur and an amount of a quinoline fungicide if applied together are more effective than when Sulphur, at the same amount, and the quinoline fungicide at the same amount, is applied alone.

[0489] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a quinoline fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0490] In some embodiments, an amount of Sulphur and an amount of a phenylpyrrole fungicide if applied together are more effective than when Sulphur, at the same amount, and the phenylpyrrole fungicide at the same amount, is applied alone.

[0491] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a phenylpyrrole fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0492] In some embodiments, an amount of Sulphur and an amount of a tubulin polymerization promoter if applied together are more effective than when Sulphur, at the same amount, and the tubulin polymerization promoter at the same amount, is applied alone. In some embodiments, (i) the amount of Sulphur and (ii) an amount of a tubulin polymerization promoter in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0493] In some embodiments, an amount of Sulphur and an amount of a benzothiadiazole fungicide if applied together are more effective than when Sulphur, at the same amount, and the benzothiadiazole fungicide at the same amount, is applied alone.

[0494] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a benzothiadiazole fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0495] In some embodiments, an amount of Sulphur and an amount of a thiazole carboxamide fungicide if applied together are more effective than when Sulphur, at the same amount, and the thiazole carboxamide fungicide at the same amount, is applied alone.

[0496] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a thiazole carboxamide fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0497] In some embodiments, an amount of Sulphur and an amount of a benzothiazole fungicide if applied together are more effective than when Sulphur, at the same amount, and the benzothiazole fungicide at the same amount, is applied alone.

[0498] In some embodiments, (i) the amount of Sulphur and (ii) an amount of a benzothiazole fungicide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0499] In some embodiments, an amount of Sulphur and an amount of probiotic microbial species if applied together are more effective than when Sulphur, at the same amount, and the probiotic microbial species at the same amount, is applied alone.

[0500] In some embodiments, (i) the amount of Sulphur and (ii) an amount of probiotic microbial species in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against fungal infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.

[0501] In a further embodiment, the mixture combination of active compounds of the invention comprising: (i) a Sulphur; and (ii) at least one fungicide chemical compound II, is synergistically effective for controlling fungi compared to when compound (i) at the same amount, and compound (ii) at the same amount, is applied alone, after several hours to several days of applications.

[0502] In yet another embodiment, the synergistic composition may be applied in various mixtures or combinations of Sulphur, and one fungicide chemical compound II, as defined above, for example in a single "ready-for-use" form, or in a combined spray mixture composed from separate formulations of the single active ingredients, such as a "tank-mix" form.

[0503] In yet another embodiment, the composition is applied in the form of a ready-for-use formulation comprising Sulphur, and one fungicide chemical compound II, as defined above. This formulation can be obtained by combining the active ingredients in an effective amount with an agriculturally acceptable carrier, a surfactant or other application-promoting adjuvant customarily employed in formulation technology.

[0504] According to an embodiment, the composition comprises at least one additional component selected from the group of surfactants, solid diluents and liquid diluents. Such compositions can be formulated using agriculturally acceptable carriers, surfactants or other application-promoting adjuvants customarily employed in formulation technology and formulation techniques that are known in the art.

[0505] Examples of suitable solid carriers potentially useful in the present compositions include but are not limited to mineral earths such as silica gels, silicates, talc, kaolin, sericite, attaclay, limestone, bentonite, lime, chalk, bole, mirabilite, loess, clay, dolomite, zeolite, diatomaceous earth, calcium carbonate, calcium sulfate, magnesium sulfate, magnesium oxide, sodium carbonate and bicarbonate, and sodium sulfate; ground synthetic materials; fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal, and nutshell meal; cellulose powders; and other solid carriers.

[0506] Examples of suitable liquid carriers potentially useful in the present compositions include but are not limited to water; aromatic hydrocarbons such as alkylbenzenes and alkylnaphthalenes; alcohols such as cyclohexanol, and decanol; ethylene glycol; polypropylene glycol; dipropropylene glycol; N,N-dimethylformamide; dimethylsulfoxide; dimethylacetamide; N-alkylpyrrolidones such as N-methyl-2-pyrrolidone; paraffins; various oils such as olive, castor, linseed, tung, sesame, corn, peanut, cotton-seed, soybean, rape-seed, or coconut oil; fatty acid esters; ketones such as cyclohexanone, 2-heptanone, isophorone, and 4-hydroxy-4-methyl-2- pentanone; and the like.

[0507] The present composition may be employed or prepared in any conventional form, for example, as wettable powders (WP), emulsion concentrates (EC), microemulsion concentrates (MEC), water-soluble powders (SP), water-soluble concentrates (SL), suspoemulsion (SE), oil dispersions (OD), concentrated emulsions (BW) such as oil-in-water and water-in-oil emulsions, sprayable solutions or emulsions, capsule suspensions (CS), suspension concentrates (SC), suspension concentrates, dusts (DP), oil-miscible solutions (OL), seed-dressing products, granules (GR) in the form of microgranules, spray granules, coated granules and absorption granules, granules for soil application or broadcasting, water-soluble granules (SG), water- dispersible granules (WDG), ULV formulations, microcapsules or waxes. These individual formulation types are known in the art.

[0508] Examples of suitable surfactants include, but are not limited to, non-ionic, anionic, cationic and ampholytic types such as alkoxylated fatty alcohols, ethoxylated polysorbate (e.g. tween 20), ethoxylated castor oil, lignin sulfonates, fatty acid sulfonates (e.g. lauryl sulfonate), phosphate esters such as phosphate esters of alcohol alkoxylates, phosphate esters of alkylphenol alkoxylates and phosphate esters of styrylphenol ethoxylates, condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, alkylarylsulfonates, ethoxylated alkylphenols and aryl phenols, polyalkylene glycols, sorbitol esters, alkali metal, sodium salts of lignosulphonates, tristyrylphenol ethoxylate phosphate esters, aliphatic alcohol ethoxylates, alkylphenol ethoxylates, ethylene oxide / propylene oxide block copolymers, graft copolymers and polyvinyl alcohol-vinyl acetate copolymers. Other surfactants known in the art may be used as desired.

[0509] Other ingredients, such as wetting agents, anti-foaming, adhesives, neutralizers, thickeners, binders, sequestrates, fertilizers, biocides, stabilizers, buffers or anti-freeze agents, may also be added to the present compositions in order to increase the stability, density, and viscosity of the described compositions.

[0510] Aqueous use forms can be prepared from emulsion concentrates, suspensions, pastes, wettable powders or water-dispersible granules by adding water. To prepare emulsions, pastes or oil dispersions, the components of the compositions either as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetting agent, tackifier, dispersant or emulsifier. Alternatively, it is also possible to prepare concentrates comprising active ingredient, wetting agent, tackifier, dispersant or emulsifier and, if desired, a solvent or oil, which are suitable for dilution with water.

[0511] In an embodiment, the amount of the mixture of active ingredients in the composition is about 0.1-99 wt. %, about 0.1-95 wt. %, or about 0.1-90 wt. %, based on the total weight of the composition. In another embodiment, the amount of the mixture of active ingredients in the composition is about 1-70 wt. %, based on the total weight of the composition. In yet another embodiment, the amount of the mixture of active ingredients in the composition is about 1-50 wt. %, based on the total weight of the composition. In yet another embodiment, the amount of the mixture of active ingredients in the composition is about 1-40 wt. %, based on the total weight of the composition. In yet another embodiment, the amount of the mixture of active ingredients in the composition is about 1-30 wt. %, based on the total weight of the composition. In yet another embodiment, the amount of the mixture of active ingredients in the composition is about 1-20 wt. %, based on the total weight of the composition. In yet another embodiment, the amount of the mixture of active ingredients in the composition is about 1-10 wt. %, based on the total weight of the composition. The remaining components in the formulation are for example the carrier and additives.

[0512] In an embodiment, the amount of the mixture of active ingredients in the composition is from about 0.1%, 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5% to about 90%, 93%, 95%, 98%, 99% based on the total weight of the composition.

[0513] In another embodiment, the present invention provides a kit comprising a synergistic pesticidal composition as described herein, or components thereof. Such kits may comprise, in addition to the aforementioned active components, one or more additional active and / or inactive ingredients, either within the provided pesticidal composition or separately. As noted above, the compositions, kits and methods described herein exhibit a synergistic effect. A synergistic effect exists wherever the action of a combination of active components is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount (or an effective amount of a synergistic composition or combination) is an amount that exhibits greater fungicidal activity than the sum of the activities of the individual components.

[0514] METHOD OF USE

[0515] In an embodiment, the present invention provides a method of treating a crop plant or soil against fungal infection comprising applying to the crop plant, propagation material of the plant, or soil

[0516] A) an effective amount of a Sulphur; and

[0517] B) an effective amount of at least one fungicide chemical compound II selected from the groups (1) to (34):

[0518] (1) a phenylacetamide fungicide selected from a group comprising Cyflufenamid,

[0519] (2) a polysaccharide compound selected from group comprising Laminarin and Chitosan,

[0520] (3) a plant extract from beet which comprises Trimethyl glycine,

[0521] (4) a plant extract fungicide which is extracted from Melaleuca alternifolia,

[0522] (5) a plant extract fungicide extracted from a plant oil, which is selected from a group consisting of Eugenol, Geraniol, Thymol and any combination thereof,

[0523] (6) a plant extract fungicide which is selected from the group consisting of terpene hydrocarbons, terpene alcohol, terpene phenols and any combination thereof,

[0524] (7) a plant extract from cotyledons of lupine plantlets, which comprises polypeptides,

[0525] (8) a plant extract selected from Seaweed extracts which are derived from the extraction of macroalgae species,

[0526] (9) a plant extract fungicide which is extracted from Swinglea glutinosa,

[0527] (10) an amine fungicide selected from a group comprising Fenpropidin, Fenpropimorph and Spiroxamine,

[0528] (11) an oxysterol binding protein inhibitor compound selected from a group comprising Oxathiapiprolin and Fluoxapiprolin, (12) a pyrimidine fungicide selected from a group comprising 5-fluoro-4-imino-3-methyl- l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one and bupirimate,

[0529] (13) a quinone inside inhibitor selected from a group comprising Fenpicoxamid, Florylpicoxamid, Cyazofamid and Amisulbrom,

[0530] (14) a quinone outside inhibitor selected from a group comprising Azoxystrobin, Picoxistrobin, Pyraclostrobin and Metyltetraprole,

[0531] (15) a succinate dehydrogenase inhibitor selected from a group comprising Isofetamid, Fluopyram and Pyrapropoyne,

[0532] (16) a tetrazolyloxime fungicide selected from a group comprising Picarbutrazox,

[0533] (17) a benzamide fungicide selected from a group comprising Zoxamide, Fluopicolide and Fluopimomide,

[0534] (18) a benzophenone fungicide selected from a group comprising Metrafenone and Pyriofenone,

[0535] (19) an anilino-pyrimidine fungicide selected from a group comprising Cyprodinil and Pyrimethanil,

[0536] (20) an azanaphthalene fungicide selected from a group comprising Quinoxyfen and Proquinazid,

[0537] (21) a keto-reductase Inhibitor fungicide selected from a group comprising Fenhexamid and Fenpyrazamine,

[0538] (22) a guanidine fungicide selected from a group comprising Dodine,

[0539] (23) a phthalimide fungicide selected from a group comprising Folpet and Captan,

[0540] (24) a naphthodithiin fungicide selected from a group comprising Dithianon,

[0541] (25) a triazole fungicide selected from a group comprising Mefentrifluconazole, Ipfentrifluconazole and Tricyclazole,

[0542] (26) a thiazolidine fungicide selected from a group comprising Flutianil,

[0543] (27) a pyridine fungicide selected from a group comprising Aminopyrifen,

[0544] (28) a quinoline fungicide selected from a group comprising Quinofumelin, Ipflufenoquin and Tebufloquin,

[0545] (29) a phenylpyrrole fungicide selected from a group comprising Fludioxonil,

[0546] (30) a tubulin polymerization promoter selected from a group comprising Pyridachlometyl, (31) a benzothiadiazole fungicide selected from a group comprising Acibenzolar-S- methyl,

[0547] (32) a thiazole carboxamide fungicide selected from a group comprising Isotianil,

[0548] (33) a benzothiazole fungicide selected from a group comprising Dichlobentiazox, and

[0549] (34) probiotic microbial species selected from a group comprising Bacillus, Lactococcus and Saccharomyces, so as to thereby treat the crop plant or soil against fungal infection, wherein the amount of sulphur applied is less than the fungicidally effective amount of sulphur when sulphur is used alone, and / or wherein the amount of the fungicide applied is less than the fungicidally effective amount of the fungicide when the fungicide is used alone.

[0550] In a further embodiment, the present invention also provides use of any one of the combinations, mixtures or compositions disclosed herein for combatting phytopathogenic diseases as well as mites on crop plants.

[0551] In another embodiment, the invention also provides a method of treating a crop plant or soil against infection by fungi selected from a group comprising Frosty pod (Moniliophthora roreri), Witches' broom (Moniliophthora perniciosa), Seedling blight / foliar&ear disease (Microdochium sp.), Botryosphaeria Panicle and Shoot Blight (Botryosphaeria dothidea), Band canker (Botryosphaeria dothidea), Black rot (Phyllosticta ampelicida), Black sigatoka (Pseudocercospora fijiensis ; Mycosphaerella fijiensis), Septoria (Zymoseptoria tritici), Ramularia leaf spot (Ramularia collo-cygni), Gray Leaf Spot (Cercospora zeae-maydis), Ramularia leaf spot (Ramularia areola), leaf spot of beet (Cercospora beticola), Ramularia leaf spot (Ramularia beticola), Yellow sigatoka (Pseudocercospora musae), Early leaf spot (Mycosphaerella arachidis), Late leaf spot (Mycosphaerella berkeleyi), Ashy leaf spot of pear (Mycosphaerella pyri), Leaf spot (Cercospora sp.), Septoria brown spot (Septoria glycines), Purple Seed Stain (Cercospora kikuchii), Scab (Cladosporium sp.), Leaf spot of hop (Pseudocercospora cantuariensis), White leaf spot (Neopseudocercosporella capsellae), Barn spot (Cercospora nicotianae), Sheath Blight (Rhizoctonia solani / Thanatephorus cucumeris), Rizoctonia (Rhizoctonia solani / Thanatephorus cucumeris), Damping off / root rot (Rhizoctonia solani / Thanatephorus cucumeris), Rizoctonia (Rhizoctonia solani / Thanatephorus cucumeris), Rhizoctonia root and crown rot (Rhizoctonia solani / Thanatephorus cucumeris), Pink Disease (Erythricium salmonicolor), Dead-arm (Diaporthe neoviticola), Eyespot (Kabatiella zeae), Powedery mildew (Blumeria graminis), Powdery mildew (Erysiphe cichoracearum), Powdery mildew (Sphaerotheca fuliginea), Powdery mildew (Erysiphe necator), Powdery mildew (Podosphaera macularis), Powdery mildew (Podosphaera leucotricha), Powdery mildew (Leveillula taurica / Oidium Neolycopersici), powdery mildew (Erysiphe betae / Erysiphe polygoni), Powdery mildew (Erysiphe sp.), Powdery mildew (Podosphaera pannosa), Downy mildew (Peronospora tabacina), Powdery mildew (Erysiphe sp. / Oidium sp), Powdery mildew (Leveillula Taurica), Powdery mildew (Erysiphe cruciferarum), Powdery mildew (Erysiphe diffusa), Aspergillus ear rot (Aspergillus sp.), Light leaf Spot (Pyrenopeziza brassicae), Bark canker of apple (Phlyctema vagabunda), Leaf spot (Blumeriella jaapii), Grey mold (Botrytis cinereal), Sclerotinia (Sclerotinia sclerotiorum), Grey mould, (Botrytis cinereal), Monilia (Monilinia spp. / Monilinia laxa / Monilia fructigena / Monilia fructicola), Botrytis blight (Botrytis cinereal), Grey mold (Botrytis sp.), White mould (Sclerotinia sp.), Sclerotinia stem rot or white mold (Sclerotinia sclerotiorum), Brown rot blossom (Monilinia fructicola), Grey mould (Botrytis cinereal), Grey mould (Botrytis cinereal), Botrytis Blossom and Shoot Blight(Botrytis cinereal), Leaf blotch of cereals (Rhynchosporium secalis), Fusarium head blight (Fusarium sp.), Maize Ear and Kernel Rot (Fusarium sp.), Eye rot (Neonectria galligena), Bakanae disease (Gibberella fujikuroi), Giberrella stalk and ear rot (Gibberella zeae), Coffee Wilt Disease (Gibberella xylarioides), Anthracnose of grapevine (Elsinoe ampelina), Crown and root rot (Phytophthora sp.), Black pod (Phytophthora palmivora / Phytophthora megakarya / Phytophthora capsica), Downy milde (Pseudoperonospora cubensis), Downy mildew (Plasmopara viticola), Downy mildew (Pseudoperonospora humul), Late blight (Phytophthora infestans), Downy mildew (Peronospora viciae / Phytopthora sp.), Late blight (Phytophthora infestans), Downy mildew (Hyaloperonospora parasitica), Downy mildew (Peronospora farinose), Coffee Berry Disease (Colletotrichum kahawae), Anthracnose (Colletotrichum sp.), Antracnose (Colletotrichum sp). Anthracnose (Colletotrichum musae), Anthracnose (Colletotrichum spp.), Anthracnose (Glomerella cingulate), Anthracnose (Colletotrichum graminicola), Anthracnose (Glomerella gossypii), Fruit rot (Glomerella cingulate), Red rot (Colletotrichum falcatum), Anthracnose (Colletotrichum destructivum), Leaf spot (Polystigma rubrum), Club rot (Plasmodiophora brassicae), Target spot (Corynesporacassiicola), Didymella pisi (Ascochyta rabiei), Boll rot (Ascochyta gossypiicola), Leaf spot of apple (Didymella pomorum), Leaf and pod spot (Didymella sp.), Shot-hole of stone fruit (Wilsonomyces carpophilus), Shot-hole of stone fruit (Wilsonomyces carpophilus), Phoma stem canker and leaf spot (Plenodomus lingam), black leg of beet (Neocamarosporium betae), Yellow spot (Pyrenophora triticirepentis / Drechslera tritici-repentis), Net blotch (Pyrenophora teres), Northern Corn Leaf Blight (Setosphaeria turcica), Southern corn leaf blight (Cochliobolus heterostrophus), Northern Corn Leaf Spot (Cochliobolus carbonum), Leaf blight (Alternaria spp. / Alternaria cucumerina), Alternaria (Alternaria alternate), Brown spot of pear (Pleospora allii), Alternaria blotch of apple (Alternaria mali / Alternaria sp.), Early blight (Alternaria sp.), Early blight (Alternaria sp.) Alternaria late blight (Alternaria sp.) Brown spot (Alternaria alternate), Brown spot (Alternaria alternate), Leaf spot (Alternaria sp.), Brown spot (Cochliobolus miyabeanus), Eyespot (Helminthosporium sacchari), Scab (Venturia inaequalis), Scab (Venturia pyrina), Scab (Venturia carpophila), Coffee Leaf Rust (Hemileia vastatrix), Asian soybean rust (Phakopsora pachyrhizi), Panama wilt (Phakopsora gossypii), Tropical cotton rust (Phakopsora gossypii), Brown rust (Puccinia recondite), Yellow rust (Puccinia striiformis), Rust (Uromyces betae), Common Rust (Puccinia sorghi), Rust (Uromyces sp.), Cotton rust(Puccinia schedonnardi), Southwestern cotton rust (Puccinia cacabata), Rust (Tranzschelia spp.), Rice Blast (Pyricularia oryzae), leaf curl (Taphrina spp. / Taphrina deformans), Common Smut (Ustilago maydis), Smut (Ustilago scitaminea), Esca of grapevine (Phaeomoniella chlamydospore), blossom blight (Monilinia laxa), and frosty pod rot disease (Moniliophthora roreri).

[0552] In an embodiment, target crops of the present invention for the areas of indication comprise cereals (wheat, barley, rye, oats, rice, sorghum and related crops); beet (sugar beet and fodder beet); pome fruits (apples, pears), stone fruit and soft fruit (plums, peaches, almonds, cherries, strawberries, raspberries and blackberries); leguminous plants (beans, lentils, peas, soybeans); oil plants (rape, mustard, poppy, olives, sunflowers, coconut, castor oil plants, cocoa beans, groundnuts); cucumber plants (marrows, cucumbers, melons); fibre plants (cotton, flax, hemp, jute); citrus fruit (oranges, lemons, grapefruit, mandarins); vegetables (spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, paprika); lauraceae (avocados, cinnamon, camphor); or plants such as maize, tobacco, nuts, coffee, sugar cane, tea, vines, hops, bananas and natural rubber plants, as well as ornamentals (flowers, shrubs, broadleaved trees and evergreens, such as conifers). In a further embodiment, the present invention provides use of any one of the combinations, mixtures or compositions disclosed herein for effectively repelling insects on crops.

[0553] In an embodiment, the present invention also provides use of any one of the combinations, mixtures or compositions disclosed herein for treating a plant or soil against fungal infection.

[0554] In an embodiment, the mixture combination of the present invention can be a synergistic mixture.

[0555] In an embodiment, the present invention also provides a fungicidal composition comprising any one of the combinations or mixtures disclosed herein.

[0556] In an embodiment, the present invention also provides a method of treating a plant or soil against fungal infection comprising applying an effective amount of any one of the combinations, mixtures or compositions disclosed herein to the plant, propagation material of the plant, or soil so as to thereby treat the plant or soil against fungal infection.

[0557] In an embodiment, this present invention further provides a method for enhancing plant development comprising applying to the plant, a locus of the plant and / or propagation material of the plant an effective amount of the mixture of Sulphur and one or more fungicide chemical compound II, as mentioned above or the composition thereof, so as to thereby enhance plant development and greening effect.

[0558] In an embodiment, this present invention also provides a method for regulating plant growth comprising applying to the plant, a locus of the plant and / or propagation material of the plant an effective amount of Sulphur and one or more fungicide chemical compound II, as mentioned above or the composition thereof, so as to thereby increasing plant growth and crop yield.

[0559] Each embodiment disclosed herein is contemplated as being applicable to each of the other disclosed embodiments. Thus, all combinations of the various elements described herein are within the scope of the invention. In addition, the elements recited in the composition embodiments can be used in the combination, mixture (including synergistic mixture), package, method and use embodiments described herein and vice versa.

[0560] The present invention is illustrated and further described in more detail with reference to the following non-limiting examples. The following examples illustrate the practice of the present subject matter in some of its embodiments but should not be construed as limiting the scope of the present subject matter. Other embodiments will be apparent to one skilled in the art from consideration of the specification and examples. It is intended that the specification, including the examples, is considered exemplary only without limiting the scope and spirit of the present subject matter.

[0561] EXAMPLES

[0562] The representative experiments were conducted by applying commercially available formulations of Sulphur and other mixture partners, alone or with their tank-mixed compositions. The compositions were diluted with water.

[0563] The active ingredients used in the experiments are having following formulation types and the concentrations:

[0564] Each formulation with active ingredient is diluted with water and biological efficacy trials on target fungi were conducted.

[0565] Each formulation with active ingredient is diluted with water and trials to assess the biological activity on plants and yield are conducted.

[0566] Activity of the compositions on quantitative and qualitative data on yield is evaluated with reference to several attributes:

[0567] Following experimentations were done with various mixtures of Sulphur on different types of fungi, the result of which are summarized in the below tables:

[0568] Table 1:

[0569] Table 2:

[0570] Table 3:

[0571] Table 4:

[0572] Table 5:

[0573] Table 6:

[0574] Other representative experiments may also be carried out to determine the synergistic effect or other improved biological effects of the mixture combination which comprises a mixture of i) an effective amount of a sulphur and ii) an effective amount of at least one fungicide selected from the groups consisting of Cyflufenamid, Laminarin, Chitosan, Trimethyl glycine from beet extract, plant extract from Melaleuca alternifolia, Eugenol, Geraniol, Thymol, terpene hydrocarbons, terpene alcohol, terpene phenols, cotyledons of lupine plantlets comprising polypeptides, Seaweed extracts which are derived from the extraction of macroalgae species, plant extract fungicide extracted from Swinglea glutinosa, Fenpropidin, Fenpropimorph, Spiroxamine, Oxathiapiprolin, Fluoxapiprolin, 5-fluoro-4-imino-3-methyl-l-[(4- methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one, Bupirimate, Fenpicoxamid, Florylpicoxamid, Cyazofamid, Amisulbrom, Azoxystrobin, Picoxistrobin, Pyraclostrobin, Metyltetraprole, Isofetamid, Fluopyram, Pyrapropoyne, Picarbutrazox, Zoxamide, Fluopicolide, Fluopimomide, Metrafenone, Pyriofenone, Cyprodinil, Pyrimethanil, Quinoxyfen, Proquinazid, Fenhexamid, Fenpyrazamine, Dodine, Folpet, Captan, Dithianon, Mefentrifluconazole, Ipfentrifluconazole, Tricyclazole, Flutianil, Aminopyrifen, Quinofumelin, Ipflufenoquin, Tebufloquin, Fludioxonil, Pyridachlometyl, Acibenzolar-S-methyl, Isotianil, Dichlobentiazox, Bacillus, Lactococcus and Saccharomyces, and also their agrochemically acceptable additives.

[0575] In a representative example, a mixture combination may be prepared by thoroughly mixing sulphur (weight %) with Cyflufenamid (weight %). Also, in a separate experiment, mixture combination may be prepared by thoroughly mixing sulphur (weight %) with Laminarin (weight %). In another experiment, mixture combination may be prepared by thoroughly mixing sulphur (weight %) with Chitosan (weight %).

[0576] Different concentrations of each of the active ingredients may be applied to different fungi. The percent control may be determined sometime after treatment. The observed percent control of the fungicidal composition against the different species of fungi is expected to be higher than the expected percentage control according to Colby's equation. Therefore, the mixture combination comprising sulphur (weight %) and a fungicide such as Cyflufenamid, Laminarin and Chitosan (weight %) is expected to show synergistic effect against the different species of fungi.

[0577] A synergistic effect exists whenever the action of an active ingredient combination is greater than the sum of the actions of the individual components.

[0578] In the field of agriculture, it is often understood that the term "synergy" is as defined by Colby S. R. in an article entitled "Calculation of the synergistic and antagonistic responses of herbicide combinations" published in the journal Weeds, 1967, 15, p. 20-22. The action expected for a given combination of two active components can be calculated as follows:

[0579] E = X + Y - XY / 100 in which E represents the expected effect, e.g. percentage of fungi control, for the combination of the active ingredients at defined doses (for example equal to x and y respectively), X is the effect, e.g. percentage of pest control, observed for compound (I) at a defined dose (equal to x), Y is the effect, e.g. percentage of fungi control, observed for compound (II) at a defined dose (equal to y). Here, efficacy or percent inhibition is determined in %. 0% means efficacy that corresponds to the Control, i.e., as if no treatment had been applied. Whereas, a percent inhibition of 100% means that complete control is observed. When the percent control observed for the combination is greater than E, there is a synergistic effect. When the percent control observed for the combination is equal to E, there is an additive effect and wherein the percent control observed for the combination is lower than E, there is an antagonistic effect.

[0580] In some embodiments, the mixture is synergistic for enhancing crop plant. In some embodiments, the mixture is synergistic for enhancing plant development. In some other embodiments, the mixture is synergistic for enhancing root system. In some embodiments, the mixture is synergistic for improving plant quality. In some embodiments, the mixture is synergistic for regulating plant growth. In some embodiments, the mixture is synergistic for controlling different species of fungi.

[0581] While the present disclosure of the invention may be susceptible to various modifications and alternative forms, specific embodiments have been described by way of example in detail herein. However, it is understood that the present disclosure is not intended to be limited to the particular forms disclosed. Rather, the present disclosure is to cover all modifications, equivalents, and alternatives falling within the scope of the present disclosure as defined by the following claims and their legal equivalents.

Claims

WHAT IS CLAIMED IS:

1. a fungicidal mixture combination comprising, as active compounds:A) an effective amount of a Sulphur which includes a bio-sulphur; andB) an effective amount of at least one fungicide chemical compound II selected from the groups (1) to (34):(1) a phenylacetamide fungicide selected from a group comprising Cyflufenamid,(2) a polysaccharide compound selected from group comprising Laminarin and Chitosan,(3) a plant extract from beet which comprises Trimethyl glycine,(4) a plant extract fungicide which is extracted from Melaleuca alternifolia,(5) a plant extract fungicide extracted from a plant oil, which is selected from a group consisting of Eugenol, Geraniol, Thymol and any combination thereof,(6) a plant extract fungicide which is selected from the group consisting of terpene hydrocarbons, terpene alcohol, terpene phenols and any combination thereof,(7) a plant extract from cotyledons of lupine plantlets, which comprises polypeptides,(8) a plant extract selected from Seaweed extracts which are derived from the extraction of macroalgae species,(9) a plant extract fungicide which is extracted from Swinglea glutinosa,(10) an amine fungicide selected from a group comprising Fenpropidin, Fenpropimorph and Spiroxamine,(11) an oxysterol binding protein inhibitor compound selected from a group comprising Oxathiapiprolin and Fluoxapiprolin,(12) a pyrimidine fungicide selected from a group comprising 5-fluoro-4-imino-3-methyl- l-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(lH)-one and Bupirimate,(13) a quinone inside inhibitor selected from a group comprising Fenpicoxamid, Florylpicoxamid, Cyazofamid and Amisulbrom,(14) a quinone outside inhibitor selected from a group comprising Azoxystrobin, Picoxistrobin, Pyraclostrobin and Metyltetraprole,(15) a succinate dehydrogenase inhibitor selected from a group comprising Isofetamid, Fluopyram and Pyrapropoyne,(16) a tetrazolyloxime fungicide selected from a group comprising Picarbutrazox,(17) a benzamide fungicide selected from a group comprising Zoxamide, Fluopicolide and Fluopimomide,(18) a benzophenone fungicide selected from a group comprising Metrafenone and Pyriofenone,(19) an anilino-pyrimidine fungicide selected from a group comprising Cyprodinil and Pyrimethanil,(20) an azanaphthalene fungicide selected from a group comprising Quinoxyfen and Proquinazid,(21) a keto-reductase Inhibitor fungicide selected from a group comprising Fenhexamid and Fenpyrazamine,(22) a guanidine fungicide selected from a group comprising Dodine,(23) a phthalimide fungicide selected from a group comprising Folpet and Captan,(24) a naphthodithiin fungicide selected from a group comprising Dithianon,(25) a triazole fungicide selected from a group comprising Mefentrifluconazole, Ipfentrifluconazole and Tricyclazole,(26) a thiazolidine fungicide selected from a group comprising Flutianil,(27) a pyridine fungicide selected from a group comprising Aminopyrifen,(28) a quinoline fungicide selected from a group comprising Quinofumelin, Ipflufenoquin and Tebufloquin,(29) a phenylpyrrole fungicide selected from a group comprising Fludioxonil,(30) a tubulin polymerization promoter selected from a group comprising Pyridachlometyl,(31) a benzothiadiazole fungicide selected from a group comprising Acibenzolar-S- methyl,(32) a thiazole carboxamide fungicide selected from a group comprising Isotianil,(33) a benzothiazole fungicide selected from a group comprising Dichlobentiazox, and(34) probiotic microbial species selected from a group comprising Bacillus, Lactococcus and Saccharomyces.

2. The mixture combination of claim 1, wherein the weight ratio of Sulphur and at least one fungicide chemical compound II as defined in claim 1, is from 1:100 to 100:1.

3. The mixture combination of claim 1, wherein Sulphur and at least one fungicide chemical compound II as defined in claim 1, are applied jointly or in a succession.

4. The mixture combination of any one of claims 1-3, wherein the mixture is selected from the group comprising:1) Sulphur and Cyflufenamid,2) Sulphur and Laminarin,3) Sulphur and Chitosan,4) Sulphur and beet extract which comprises Trimethyl glycine,5) Sulphur and plant extract from Melaleuca alternifolia,6) Sulphur and Eugenol,7) Sulphur and Geraniol,8) Sulphur and Thymol,9) Sulphur and terpene hydrocarbons,10) Sulphur and terpene alcohol,11) Sulphur and terpene phenols,12) Sulphur and plant extract from cotyledons of lupine plantlets, which comprises polypeptides,13) Sulphur and Seaweed extract from the extraction of macroalgae species,14) Sulphur and plant extract from Swinglea glutinosa,15) Sulphur and Fenpropidin,16) Sulphur and Fenpropimorph,17) Sulphur and Spiroxamine,18) Sulphur and Oxathiapiprolin,19) Sulphur and Fluoxapiprolin,20) Sulphur and 5-fluoro-4-imino-3-methyl-l-[(4-methylphenyl)sulfonyl]-3,4- dihydropyrimidin-2(lH)-one,21) Sulphur and Bupirimate,22) Sulphur and Fenpicoxamid,23) Sulphur and Florylpicoxamid,24) Sulphur and Cyazofamid,25) Sulphur and Amisulbrom,26) Sulphur and Azoxystrobin,27) Sulphur and Picoxistrobin,28) Sulphur and Pyraclostrobin,29) Sulphur and Metyltetraprole,30) Sulphur and Isofetamid,31) Sulphur and Fluopyram,32) Sulphur and Pyrapropoyne,33) Sulphur and Picarbutrazox,34) Sulphur and Zoxamide,35) Sulphur and Fluopicolide,36) Sulphur and Fluopimomide,37) Sulphur and Metrafenone,38) Sulphur and Pyriofenone,39) Sulphur and Cyprodinil,40) Sulphur and Pyrimethanil,41) Sulphur and Quinoxyfen,42) Sulphur and Proquinazid,43) Sulphur and Fenhexamid,44) Sulphur and Fenpyrazamine,45) Sulphur and Dodine,46) Sulphur and Folpet,47) Sulphur and Captan,48) Sulphur and Dithianon,49) Sulphur and Mefentrifluconazole,50) Sulphur and Ipfentrifluconazole,51) Sulphur and Tricyclazole,52) Sulphur and Flutianil,53) Sulphur and Aminopyrifen,54) Sulphur and Quinofumelin,55) Sulphur and Ipflufenoquin,56) Sulphur and Tebufloquin,57) Sulphur and Fludioxonil,58) Sulphur and Pyridachlometyl,59) Sulphur and Acibenzolar-S-methyl,60) Sulphur and Isotiani I,61) Sulphur and Dichlobentiazox,62) Sulphur and Bacillus,63) Sulphur and Lactococcus, and64) Sulphur and Saccharomyces5. The mixture combination of any one of claims 1-4, wherein the mixture is selected from the group comprising:1) Sulphur and Laminarin2) Sulphur and Beet extract3) Sulphur and Chitosan6. The mixture combination of any one of claims 1-5, wherein the mixture exhibits synergistic effects.

7. The mixture combination of any one of claims 1-6, wherein the application rates of the mixture are from 500 g / ha to 5000 g / ha.

8. A fungicidal composition comprising: (i) the mixture combination of any one of claims 1-7; and (ii) an agriculturally acceptable carrier.

9. The fungicidal composition of claim 8, further comprising at least one surfactant, solid diluent, liquid diluent, or a combination thereof.

10. A method of treating a crop plant or soil against fungi comprising applying an effective amount of the mixture combination of any one of claims 1-7 or the composition of claim 8 or 9, so as to thereby treat the plant or soil against fungal infection.

11. The method of treating a crop plant or soil against fungi according to claim 10, wherein the fungi are selected from a group comprising Moniliophthora roreri, Moniliophthora perniciosa, Microdochium sp., Botryosphaeria dothidea, Phyllosticta ampelicida, Pseudocercospora fijiensis, Mycosphaerella fijiensis, Zymoseptoria tritici, Ramularia collo-cygni, Cercospora zeae-maydis, Ramularia areola, Cercospora beticola, Ramularia beticola, Pseudocercospora musae, Mycosphaerella arachidis, Mycosphaerella berkeleyi, Mycosphaerella pyri, Cercospora sp., Septoria glycines, Cercospora kikuchii, Cladosporium sp.,Pseudocercospora cantuariensis, Neopseudocercosporella capsellae, Cercospora nicotianae, Rhizoctonia solani / Thanatephorus cucumeris, Rhizoctonia solani / Thanatephorus cucumeris, Rhizoctonia solani / Thanatephorus cucumeris, Rhizoctonia solani / Thanatephorus cucumeris, Rhizoctonia solani / Thanatephorus cucumeris, Erythricium salmonicolor, Diaporthe neoviticola, Kabatiella zeae, Blumeria graminis, Erysiphe cichoracearum, Sphaerotheca fuliginea, Erysiphe necator, Podosphaera macularis, Podosphaera leucotricha, Leveillula taurica / Oidium Neolycopersici, Erysiphe betae / Erysiphe polygoni, Erysiphe sp., Podosphaera pannosa, Peronospora tabacina, Erysiphe sp. / Oidium sp, Leveillula Taurica, Erysiphe cruciferarum, Erysiphe diffusa, Aspergillus sp., Pyrenopeziza brassicae, Phlyctema vagabunda, Blumeriella jaapii, Botrytis cinereal, Sclerotinia sclerotiorum, Botrytis cinereal, Monilinia spp. / Monilinia laxa / Monilia fructigena / Monilia fructicola, Botrytis cinereal, Botrytis sp., Sclerotinia sp., Sclerotinia sclerotiorum, Monilinia fructicola, Botrytis cinereal, Botrytis cinereal, Botrytis Blossom, Botrytis cinereal, Rhynchosporium secalis, Fusarium sp., Neonectria galligena, Gibberella fujikuroi, Giberrella stalk, Gibberella zeae, Gibberella xylarioides, Elsinoe ampelina, Phytophthora sp., Phytophthora palmivora / Phytophthora megakarya / Phytophthora capsica, Pseudoperonospora cubensis, Plasmopara viticola, Pseudoperonospora humul, Phytophthora infestans, Peronospora viciae / Phytopthora sp., Phytophthora infestans, Hyaloperonospora parasitica, Peronospora farinose, Colletotrichum kahawae, Colletotrichum sp., Colletotrichum sp., Colletotrichum musae, Colletotrichum spp., Glomerella cingulate, Colletotrichum graminicola, Glomerella gossypii, Glomerella cingulate, Colletotrichum falcatum, Colletotrichum destructivum, Polystigma rubrum, Plasmodiophora brassicae, Corynesporacassiicola, Ascochyta rabiei, Ascochyta gossypiicola, Didymella pomorum, Didymella sp., Wilsonomyces carpophilus, Wilsonomyces carpophilus, Plenodomus lingam, Neocamarosporium betae, Pyrenophora triticirepentis / Drechslera tritici-repentis, Pyrenophora teres, Setosphaeria turcica, Cochliobolus heterostrophus, Cochliobolus carbonum, Alternaria spp. / Alternaria cucumerina, Alternaria alternate, Pleospora allii, Alternaria mali, Alternaria sp., Alternaria alternate, Cochliobolus miyabeanus, Helminthosporium sacchari, Venturia inaequalis, Venturia pyrina, Venturia carpophila, Hemileia vastatrix, Phakopsora pachyrhizi, Phakopsora gossypii, Puccinia recondite, Puccinia striiformis, Uromyces betae, Puccinia sorghi, Uromyces sp., Puccinia schedonnardi, Puccinia cacabata, Tranzschelia spp., Pyricularia oryzae, Taphrina spp. / Taphrina deformans,Ustilago maydis, Ustilago scitaminea, Phaeomoniella chlamydospore, Monilinia laxa, and Moniliophthora roreri.

12. The method of treating crop plants or soil against fungi according to claim 10, wherein the crop plants are selected from a group comprising cereals (wheat, barley, rye, oats, rice, sorghum and related crops); beet (sugar beet and fodder beet); pome fruits (apples, pears), stone fruit and soft fruit (plums, peaches, almonds, cherries, strawberries, raspberries and blackberries); leguminous plants (beans, lentils, peas, soybeans); oil plants (rape, mustard, poppy, olives, sunflowers, coconut, castor oil plants, cocoa beans, groundnuts); cucumber plants (marrows, cucumbers, melons); fibre plants (cotton, flax, hemp, jute); citrus fruit (oranges, lemons, grapefruit, mandarins); vegetables (spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, paprika); lauraceae (avocados, cinnamon, camphor); or plants such as maize, tobacco, nuts, coffee, sugar cane, tea, vines, hops, bananas and natural rubber plants, as well as ornamentals (flowers, shrubs, broadleaved trees and evergreens, such as conifers).

13. A method for enhancing plant development comprising applying to the plant, a locus of the plant and / or propagation material of the plant an effective amount of the mixture combination of any one of claims 1-7 or the composition of claim 8 or 9, so as to thereby enhance plant development and greening effect.

14. A method for regulating plant growth comprising applying to the plant, a locus of the plant and / or propagation material of the plant an effective amount of the mixture combination of any one of claims 1-7 or the composition of claim 8 or 9, so as to thereby increasing plant growth and crop yield.

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