Method for handling dihydrogen by means of a liquid organic hydrogen carrier and associated industrial plant

The method addresses the challenges of hazardous and costly dihydrogen handling by using lactone and terminal diol compounds with Cu-based catalysts and adiabatic conditions, achieving efficient and economical dihydrogen storage and release.

WO2025196503A1 Publication Date: 2025-09-25TECHNIP ENERGIES FRANCE SAS
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Patent Information

Application Number
PCT/IB2025/000103
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-03-19
Filing Date
2025-03-18
Publication Date
2025-09-25

AI Technical Summary

Technical Problem

Existing methods for handling dihydrogen using liquid organic hydrogen carriers involve hazardous and toxic compounds, expensive catalysts, and high energy costs, diminishing their economic viability.

Method used

A method involving a lactone as the first organic compound and a terminal diol as the second organic compound, utilizing Cu-based catalysts and adiabatic conditions for hydrogenation and dehydrogenation reactions, with the dehydrogenation step occurring in a gaseous phase where the lactone condenses, offsetting the endothermic reaction by heat generated from condensation.

Benefits of technology

This approach reduces energy consumption, maintains reaction efficiency, and uses safer, less toxic compounds, facilitating cost-effective dihydrogen handling and storage.

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Abstract

The disclosure relates to a method (100) for handling dihydrogen, comprising : a step of providing a first organic compound (104); then a hydrogenation step (102), comprising submitting the first organic compound to a hydrogenation reaction in the presence of dihydrogen, so as to obtain a second organic compound (106); then a step (110) of conditioning the second organic compound for storage and / or transport; and storing and / or transporting the conditioned second organic compound; then a dehydrogenation step (108), comprising submitting the second organic compound to a dehydrogenation reaction, so as to obtain dihydrogen and the first organic compound. The first organic compound is a lactone and the second organic compound is a terminal diol.
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