Silane compound
A silane compound with urethane or urea bonds forms a surface treatment layer with enhanced lubricity, solving the issue of slipperiness in existing compounds.
Patent Information
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- DAIKIN INDUSTRIES LTD
- Filing Date
- 2025-12-12
- Publication Date
- 2026-06-18
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Figure JPOXMLDOC01-APPB-C000001 
Figure JPOXMLDOC01-APPB-C000002 
Figure JPOXMLDOC01-APPB-C000003
Abstract
Description
Silane compound 【0001】 This disclosure relates to a silane compound. 【0002】 It is known that certain silane compounds can provide excellent water and oil repellency when used for surface treatment of a substrate (Patent Document 1). 【0003】 Japanese Patent Application Laid-Open No. 2019-44179 【0004】 An object of this disclosure is to provide a silane compound capable of forming a surface treatment layer exhibiting good slipperiness. 【0005】 This disclosure provides the following. [1] Formula (1): [In the formula: R 1 is each independently a monovalent group containing one or more Si atoms to which a hydroxyl group or a hydrolyzable group is not directly bonded, X 1 is a divalent to decavalent organic group having at least one urethane bond or a divalent to decavalent organic group having at least one urea bond, R Si is a monovalent group containing one Si atom to which a hydroxyl group or a hydrolyzable group is bonded, α is an integer of 1 to 9.]. A silane compound represented by [2] R 1 is represented by R 41 -(SiR 42 2 O) n1 -SiR 42 2 -(O) z0 -, n1 is an integer of 1 or more, z0 is 0 or 1, R 41 and R 42 are each independently a C 1-12 alkyl group, a phenyl group, or a group (A), The group (A) has the following formula: [In the formula: R 51 are each independently a group represented by R 53 -(SiR 53 2 -R 61 ) ma -, R 61 are each independently a single bond, an oxygen atom, or C 1-6It is an alkylene group, R 53 Each of these is independently a hydrocarbon group or R 51’ And R 51’ R 51 This is synonymous with, however, R 51 Medium, R 51’ The number of is 20 or less, and ma is an integer from 1 to 5, and R 52 Each of the following is an independent hydrocarbon group, where na is an integer from 1 to 3, and z is 0 or 1. The silane compound described in [1] is a group represented by ]. [3] X 1 Furthermore, -CO-, -COO-, -NR 2 -, -O-, -S-, -O-(CH 2 ) x -CONR 2 - or -O-(CH 2 ) x -CO- is included, R 2 The silane compound described in [1] or [2], wherein α is a hydrogen atom or a monovalent organic group, and x is an integer from 1 to 100. [4] α is 1, X 1 is, -(C s H 2s ) s1 - (X s ) s3 - (X U ) s4 - [In the formula: s are each independent integer greater than or equal to 1, s1 is an integer greater than or equal to 1, X s is a divalent group other than an alkylene group and a urethane bond, s3 is an integer greater than or equal to 0, X U is a urethane bond, s4 is an integer of 1 or more, where the order of the groups enclosed in parentheses is not particularly limited. A silane compound according to any one of [1] to [3], which is a divalent organic group represented by ]. [5] A silane compound according to [4], where s4 is 1. [6] X 1 teeth, It is a base represented by X L1γ1 is a carbon atom, a silicon atom, or a nitrogen atom, γ1 is an integer from 1 to 3, and γ2 is an integer from 0 to 2, provided that the sum of γ1 and γ2 is X L1 The value of the valence -1, R L1 Each is independent of the other, -(C s H 2s ) s11’ - (X s ) s13’ - (X U ) s14’ Represented by -, R L2 Each is independent of the other, -(C s H 2s ) s11” - (X s ) s13” - (X U ) s14” Represented by -, where s is an integer greater than or equal to 1, s11', s13', s14', s11'', s13'', and s14'' are each independently integers greater than or equal to 0, and at least one of s14' and s14'' is an integer greater than or equal to 1, X s These are, independently, divalent groups other than alkylene groups and urethane bonds, X U It is a urethane bond, R L1 and R L2 In this, the order of existence of each repeating unit enclosed in parentheses is not particularly limited, R Z The silane compound according to any one of [1] to [3], wherein each is independently a hydrogen atom or a hydrocarbon group. [7] The silane compound according to [6], wherein at least one of s14' and s14'' is 1. [8] The silane compound according to [6] or [7], wherein s14'' is 1. [9] α is 1, and X 1 is, -(C s H 2s ) s1 - (X s1 ) s5 - (X U1 ) s6 - [In the formula: s are each independent integer greater than or equal to 1, s1 is an integer greater than or equal to 1, X s1is a divalent group other than an alkylene group and a urea bond, s5 is an integer of 0 or more, X U1 is a urea bond, s6 is an integer of 1 or more, where the order of the groups enclosed in parentheses is not particularly limited. ] is a divalent organic group represented by, the silane compound according to any one of [1] to [3].
[10] s5 is 1, the silane compound according to [9].
[11] X 1 is a group represented by, X L1 is a carbon atom, a silicon atom or a nitrogen atom, γ1 is an integer of 1 to 3, γ2 is an integer of 0 to 2, provided that the sum of γ1 and γ2 is the valence of X L1 −1 value, R L1 are each independently, -(C s H 2s ) s11’ -(X s1 ) s51’ -(X U1 ) s61’ - represented by, R L2 are each independently, -(C s H 2s ) s11” -(X s1 ) s51” -(X U1 ) s61” - represented by, s is an integer of 1 or more, s11', s51', s61', s11", s51" and s61" are each independently integers of 0 or more, at least one of s61' and s61" is an integer of 1 or more, X s1 are each independently a divalent group other than an alkylene group and a urea bond, X U1 is a urea bond, R L1 and R L2 In, the order of existence of each repeating unit enclosed in parentheses is not particularly limited, R ZThe silane compound according to any one of [1] to [3], wherein each is independently a hydrogen atom or a hydrocarbon group.
[12] The silane compound according to
[11] , wherein at least one of s61' and s61'' is 1.
[13] The silane compound according to
[11] or
[12] , wherein s61'' is 1.
[14] R Si These are, independently, equation (S1): [In the formula: R 11 Each of these is independently a hydroxyl group or a hydrolyzable group, R 12 Each of the following is an independent monovalent organic group, and j1 is an integer from 0 to 3. A silane compound represented by any one of [1] to
[13] . A silane compound represented by any one of [1] to
[14] , which is any one of the following: CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 CH 2 CH2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 (It is an alkyl group or a phenyl group.) [CH 3 CH 2 CH 2 CH 2 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 It is an alkyl group or a phenyl group. ); [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 It is an alkyl group or a phenyl group. ); CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH2 CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2-NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 It is an alkyl group or a phenyl group. ); [CH 3 CH 2 CH 2 CH 2 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2-O-CH 2 -] 2 CR[CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 It is an alkyl group or a phenyl group. ); [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 )2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 It is an alkyl group or a phenyl group. ); [(CH 3 ) 3 SiO] 2 SiCH 3 -CH 2 CH 2 CH 2 O-(CH 2 CH 2 O) n6 -CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 -Si(OCH) 3 ) 3(wherein n6 is 1 to 30.)
[16] One of the following silane compounds as described in any one of [1] to
[15] : CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is between 10 and 100.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -NHC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is between 10 and 100.) [(CH 3 ) 3 SiO] 2 SiCH 3 -CH 2 CH 2 CH 2 O-(CH 2 CH 2 O) n6 -CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 -Si(OCH) 3 ) 3(wherein n6 is 1 to 30.)
[17] One of the following silane compounds as described in any one of [1] to
[16] : CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is 60.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -NHC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is 25.) [(CH 3 ) 3 SiO] 2 SiCH 3 -CH 2 CH 2 CH 2 O-(CH 2 CH 2 O) 9 -CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 -Si(OCH) 3 ) 3
[18] A composition comprising a silane compound according to any one of [1] to
[17] .
[19] A composition comprising a condensate of a silane compound according to any one of [1] to
[17] .
[20] A surface treatment agent comprising the composition according to
[18] or
[19] .
[21] The surface treatment agent according to
[20] , further comprising a solvent.
[22] The surface treatment agent according to
[21] , wherein the solvent is at least one selected from aliphatic hydrocarbons, aromatic hydrocarbons, esters, ketones, glycol ethers, ethers and siloxanes.
[23] The surface treatment agent according to
[22] , wherein the aliphatic hydrocarbon is at least one selected from hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane and mineral spirits.
[24] The surface treatment agent according to
[22] , wherein the ester is at least one selected from methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate and isobutyl acetate.
[25] The surface treatment agent according to
[22] , wherein the siloxane is at least one selected from hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane, octamethylcyclotetrasiloxane, and octamethylcyclopentasiloxane.
[26] The surface treatment agent according to any one of
[20] to
[25] , for vacuum deposition.
[27] The surface treatment agent according to any one of
[20] to
[25] , for wet coating.
[28] A pellet containing the surface treatment agent according to any one of
[20] to
[26] .
[29] An article comprising a substrate and a layer formed on the substrate from the surface treatment agent according to any one of
[20] to
[27] .
[30] The article according to
[29] , comprising an intermediate layer containing silicon dioxide between the substrate and the layer.
[31] The article according to
[30] , wherein the intermediate layer comprises alkali metal atoms.
[32] The article according to
[31] , wherein at least a portion of the alkali metal atoms are sodium atoms.
[33] The article according to any one of
[29] to
[32] , which is an optical member.
[34] A display, the article described in any one of
[29] to
[33] . 【0006】 According to this disclosure, it is possible to provide a silane compound that can form a surface treatment layer exhibiting good lubricity. 【0007】 In this specification, "monovalent organic group" means a monovalent group containing carbon. Monovalent organic groups are not particularly limited, but may be hydrocarbon groups or derivatives thereof. Derivatives of hydrocarbon groups mean groups having one or more N, O, S, Si, amide, sulfonyl, siloxane, carbonyl, carbonyloxy, etc., at the terminal or molecular chain of a hydrocarbon group. When simply referred to as "organic group," it means a monovalent organic group. Furthermore, "divalent organic group" means a divalent group containing carbon. Examples of such divalent organic groups include divalent groups obtained by removing one more hydrogen atom from an organic group. Similarly, trivalent or higher organic groups mean groups obtained by removing a predetermined number of hydrogen atoms from an organic group. 【0008】 As used herein, "hydrocarbon group" means a group containing carbon and hydrogen, obtained by removing a hydrogen atom from a hydrocarbon. Such hydrocarbon groups are not particularly limited, but include C 1-20 Examples of hydrocarbon groups include aliphatic hydrocarbon groups and aromatic hydrocarbon groups. The above-mentioned "aliphatic hydrocarbon group" may be linear, branched, or cyclic, and may be saturated or unsaturated. The hydrocarbon group may also contain one or more ring structures. The hydrocarbon group may be substituted with one or more substituents. 【0009】 In the use herein, the substituents of the "hydrocarbon group" are not particularly limited, but may be, for example, a halogen atom, or one or more halogen atoms. 1-6 alkyl group, C 2-6 Alkenyl group, C 2-6 Alkynyl group, C 3-10 Cycloalkyl groups, C 3-10Unsaturated cycloalkyl group, 5-10 membered heterocyclyl group, 5-10 membered unsaturated heterocyclyl group, C 6-10 Examples include one or more groups selected from aryl groups and heteroaryl groups with 5 to 10 members. 【0010】 As used herein, "hydrolyzable group" means a group that can undergo hydrolysis, that is, a group that can be removed from the main skeleton of a compound by hydrolysis. Examples of hydrolyzable groups include -OR h , -OCOR h -O-N=CR h 2 , -NR h 2 , - NHR h , or -NCO (wherein R in these formulas) h Examples include (where represents a substituted or unsubstituted C1-C4 alkyl group), preferably -OR h (That is, an alkoxy group.) h Examples include unsubstituted alkyl groups such as methyl, ethyl, propyl, isopropyl, n-butyl, and isobutyl groups; and substituted alkyl groups such as chloromethyl groups. Among these, alkyl groups, particularly unsubstituted alkyl groups, are preferred, and methyl or ethyl groups are more preferred. 【0011】 [Silane Compounds] The silane compounds of this disclosure are defined by formula (1): It is represented by R 1 Each of these is a monovalent group containing one or more Si atoms that are not directly bonded to a hydroxyl group or a hydrolyzable group, and X 1 is a 2-10 valent organic group having at least one urethane bond, or a 2-10 valent organic group having at least one urea bond, R Si α is a monovalent group containing one Si atom to which a hydroxyl group or hydrolyzable group is bonded, and α is an integer from 1 to 9. 【0012】 Here, "urethane bond" is -OC(=O)-NR 54 - or - NR 54 This means -C(=O)O-. 54Each of these is independently a hydrogen atom or a monovalent organic group, preferably a hydrogen atom, a phenyl group, and C 1-12 Alkyl alkyl group (preferably C 1-6 The group is an alkyl group (more preferably a methyl group) or an oxyalkylene-containing group having 1 to 12 carbon atoms (for example, an oxyalkylene-containing group having 1 to 10 carbon atoms), and is, for example, a hydrogen atom. 【0013】 "Urea bond" is -NR 55 -C(=O)-NR 55 - means R 55 Each of these is independently a hydrogen atom or a monovalent organic group, preferably a hydrogen atom, a phenyl group, and C 1-12 Alkyl alkyl group (preferably C 1-6 The group is an alkyl group, more preferably a methyl group), an oxyalkylene-containing group having 1 to 12 carbon atoms (for example, an oxyalkylene-containing group having 1 to 10 carbon atoms), and is, for example, a hydrogen atom. 【0014】 R 1 Each of these is a monovalent group containing one or more Si atoms that are not directly bonded to a hydroxyl group or a hydrolyzable group. 1 It may contain, for example, two or more Si atoms that are not directly bonded to a hydroxyl group or a hydrolyzable group, or it may contain 500 or fewer Si atoms, or it may contain 300 or fewer Si atoms. For example, R 1 This may contain, for example, 1 to 500 or 2 to 300 Si atoms that are not directly bonded to a hydroxyl group or a hydrolyzable group. 【0015】 R 1 In this context, a monovalent group containing one or more Si atoms that are not directly bonded to a hydroxyl group or a hydrolyzable group may also contain Si atoms to which a hydroxyl group or a hydrolyzable group is directly bonded. 【0016】 In one embodiment, a monovalent group containing one or more Si atoms that are not directly bonded to a hydroxyl group or a hydrolyzable group does not contain any Si atoms that are directly bonded to a hydroxyl group or a hydrolyzable group. 【0017】In another embodiment, a monovalent group containing one or more Si atoms that are not directly bonded to a hydroxyl group or a hydrolyzable group contains one or more Si atoms that are directly bonded to a hydroxyl group or a hydrolyzable group. 【0018】 The above R 1 Preferably, R 41 - (SiR 42 2 O) n1 -SiR 42 2 - (O) z0 It is represented by -. 【0019】 n1 is an integer greater than or equal to 1, preferably an integer greater than or equal to 2, for example, an integer less than or equal to 500, specifically an integer less than or equal to 300. n1 may be an integer between 1 and 500, or an integer between 2 and 300. 【0020】 z0 is either 0 or 1. In one embodiment, z0 is 0. In one embodiment, z0 is 1. 【0021】 R 41 and R 42 Each of them is independent of C 1-12 Alkyl group, phenyl group, or (A) group: It is a base represented by . 【0022】 The above CC 1-12 The alkyl group may be linear or branched. In one embodiment, the above C 1-12 The alkyl group is linear. In another embodiment, the above C 1-12 Alkyl groups are branched chains. (See above C) 1-12 The alkyl group is preferably C 1-6 Alkyl alkyl group, comfort C 1-4 Alkyl groups, more preferably methyl or ethyl groups, and particularly preferably methyl groups. 【0023】 z is either 0 or 1. In one embodiment, z is 0. In another embodiment, z is 1. 【0024】 R 51 Each of them is independent of R 53 - (SiR 53 2 -R61 ) ma It is a base represented by -. 【0025】 R 61 Each of these independently comprises a single bond, an oxygen atom, or C 1-6 It is an alkylene group. 【0026】 R 61 C in 1-6 The alkylene group may be linear or branched. 1-6 The alkylene group is preferably C 1-4 Alkylene group, more preferably C 2-4 It may be an alkylene group. 【0027】 In one embodiment, R 61 is an oxygen atom, or C 1-6 It is an alkylene group. 【0028】 In one embodiment, R 61 This is an oxygen atom. 【0029】 In one embodiment, a portion R 61 is an oxygen atom, and other R 61 is C 1-6 It is an alkylene group. 【0030】 R 53 Each of these is independently a hydrocarbon group or R 51’ That is the case. 【0031】 R 53 The hydrocarbon group in the above-mentioned compound may preferably be an alkyl group or an aryl group. 【0032】 The alkyl group described above may be linear or branched. The alkyl group described above is preferably C 1-6 Alkyl alkyl group, comfort C 1-4 It is an alkyl group. The alkyl group is particularly preferably a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, or a tert-butyl group. 【0033】 The above aryl group may be monocyclic or polycyclic. The above aryl group is preferably C 6-20 Aryl group, more preferably C 6-10It is an aryl group. The above aryl group is particularly preferably a phenyl group. 【0034】 The above R 53 In one embodiment, an alkyl group, more preferably C 1-4 It is an alkyl group. 【0035】 In one embodiment, R 53 It does not contain an n-butyl group. 【0036】 In one embodiment, R 53 R 51’ That is the case. 【0037】 R 51’ R 51 This is synonymous with R 51’ R 53 - (SiR 53 2 O) ma -. However, R 51 Medium, R 51’ The number is 20 or less, preferably 10 or less, more preferably 6 or less, and even more preferably 3 or less. 【0038】 In one embodiment, R 53 Each of these is independently a hydrocarbon group. 【0039】 In one embodiment, R 53 Each of them is independent of R 51’ That is the case. 【0040】 In one embodiment, R 53 Each of these is independently a hydrocarbon group or R 51’ However, R 53 At least one of them is R 51’ And R 53 At least one of them is R 51’ That is the case. 【0041】 Each of ma is an independent integer between 1 and 5, preferably 1 or 2. 【0042】 R 52 Each of these is independently a hydrocarbon group. 【0043】 R 52The hydrocarbon group in the above is preferably an alkyl group or an aryl group. 【0044】 The alkyl group described above may be linear or branched. The alkyl group is preferably a C1-C6 alkyl group, more preferably a C1-C4 alkyl group. The alkyl group is particularly preferably a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, or a tert-butyl group. 【0045】 The above aryl group may be monocyclic or polycyclic. The above aryl is preferably C 6-20 The aryl group, more preferably C 6-10 The aryl group is, in particular, a phenyl group. 【0046】 The above R 52 The alkyl group is preferably an alkyl group having 1 to 4 carbon atoms. 【0047】 na is an integer between 1 and 3. In one embodiment, na is 2. In another embodiment, na is 3. Note that R 51’ If such a thing exists, then na is (R 61 -SiR 53 2 ) ma Each is selected independently. 【0048】 In one embodiment, R 41 C 1-12 It is an alkyl group. In another embodiment, R 41 is a phenyl group. In another embodiment, R 41 This is a (A) group. 【0049】 In one embodiment, R 41 It is a methyl group. 【0050】 In one embodiment, R 41 It is an ethyl group. 【0051】 In one embodiment, R 41 This is an iso-propyl group or an n-propyl group. Preferably, it is an n-propyl group. 【0052】 In one embodiment, R41 This is a tert-butyl group or an n-butyl group. Preferably, it is an n-butyl group. 【0053】 In one embodiment, R 41 This is a methyl group or an n-butyl group. 【0054】 In one embodiment, R 42 C 1-12 It is an alkyl group. In another embodiment, R 42 is a phenyl group. In another embodiment, R 42 This is a (A) group. 【0055】 In one embodiment, R 41 and R 42 Each of them is independent of C 1-12 It is an alkyl group or a phenyl group, preferably C 1-12 It is an alkyl group. 【0056】 In one embodiment, R 41 C 1-12 It is an alkyl group or a phenyl group, R 42 C 1-12 It is an alkyl group, a phenyl group or a (A) group, however R 42 At least one of them is an (A) group. Preferably, R 41 C 1-12 It is an alkyl group, R 42 C 1-12 It is an alkyl group or an (A) group, however R 42 At least one of them is an (A) group. 【0057】 In one embodiment, R 41 (A) group, R 42 is C 1-12 It is an alkyl group. 【0058】 In one embodiment, R 41 and R 42 Each of them is independent of C 1-12 It is an alkyl group or an (A) group, however R 41 and R 42 At least one of them is an (A) group. 【0059】 In one embodiment, R 41 , R42 and R 53 Each of them is independent of C 1-12 It is an alkyl group. 【0060】 In one embodiment, R 41 , R 42 and R 53 Each of them is independent of C 1-12 Alkyl alkyl group or R 51’ However, R 1 It contains at least one (A) group. 【0061】 In a preferred embodiment, in group (A), R 51 Each of them is independent of R 53 - (SiR 53 2 -R 61 ) ma It is a group represented by -, R 61 Each of these is independently an oxygen atom, or C 1-6 It is an alkylene group, R 53 Each of these is independently a hydrocarbon group, preferably C 1-4 It is an alkyl group, ma is 1 or 2, and R 52 Each of these is independently a hydrocarbon group, preferably C 1-4 It is an alkyl group, and Na is 1 or 2. 【0062】 R 1 Examples include, though not limited to, CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - [(CH 3 ) 3 SiO) 2 (CH 3 )Si-O-[Si(CH 3 )2 O] n1 Si(CH 3 ) 2 - [(CH 3 ) 3 SiO) 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 Examples of bases include n1, for example, an integer between 1 and 500. 【0063】 X 1 This is a 2- to 10-valent organic group having at least one urethane bond, or a 2- to 10-valent organic group having at least one urea bond. 1 The left side of the description is the base with α attached and enclosed in parentheses, and the right side is R Si They are then combined. 【0064】 In one embodiment, X 1 This is a divalent to decavalent organic group having at least one urethane bond. 【0065】 In one embodiment, X 1 It has at least one urethane bond but no urea bond. 【0066】 In one embodiment, X 1 This is a divalent to decavalent organic group having at least one urea bond. 【0067】 In one embodiment, X 1 It has at least one urea bond but no urethane bond. 【0068】 X 1 For example, this is a divalent organic group. That is, α is 1. 【0069】 X 1 For example, it is a trivalent organic group. That is, α is 2. 【0070】 X 1 For example, it is a tetravalent organic group. That is, α is 3. 【0071】 In one embodiment, X 1In addition to at least one urethane bond or at least one urea bond, it is a divalent organic group further containing -CO-, -COO-, -NR 2 -, -O-, -S-, -O-(CH 2 ) x -CONR 2 -, or -O-(CH 2 ) x -CO-. 【0072】 In one embodiment, X 1 further contains -CO-, -COO-, -NR 2 -, -OCONR 2 -, -NR 2 -CO-NR 2 -, -O-, -S-, -O-(CH 2 ) x -CONR 2 -, or -O-(CH 2 ) x -CO-. 【0073】 In one embodiment, X 1 in addition to at least one urethane bond, further contains -CO-, -COO-, -NR 2 -, -NR 2 -CO-NR 2 -, -O-, -S-, -O-(CH 2 ) x -CONR 2 -, or -O-(CH 2 ) x -CO-. 【0074】 In one embodiment, X 1 in addition to at least one urea bond, further contains -CO-, -COO-, -NR 2 -, -OCONR 2 -, -O-, -S-, -O-(CH 2 ) x -CONR 2 -, or -O-(CH 2 ) x -CO-. 【0075】 In one embodiment, X 1 is -(CH 2 CH2 It is a divalent organic group containing O)-. 【0076】 R 2 Each of these is independently a hydrogen atom or a monovalent organic group, preferably a hydrogen atom, a phenyl group, and C 1-12 Alkyl alkyl group (preferably C 1-6 R is an alkyl group (more preferably a methyl group) or an oxyalkylene-containing group having 1 to 12 carbon atoms (for example, an oxyalkylene-containing group having 1 to 10 carbon atoms), and is, for example, a hydrogen atom. 2 In one embodiment, R is a hydrogen atom. 2 In one embodiment, C 1-6 It is an alkyl group. 【0077】 x is an integer between 1 and 100. For example, x may be greater than or equal to 1, greater than or equal to 3, less than or equal to 50, or less than or equal to 30. x may be an integer between 1 and 50, or an integer between 3 and 30. 【0078】 The above X 1 In one embodiment, -(C s H 2s ) s1 - (X s ) s3 - (X U ) s4 This is a divalent organic group represented by -. Here, the order of the groups enclosed in parentheses is not particularly limited. That is, α is 1. 【0079】 X U This is a urethane bond, -OC(=O)-NR 54 - or - NR 54 -C(=O)O-. 【0080】 R 54 Each of these is independently a hydrogen atom or a monovalent organic group, preferably a hydrogen atom, a phenyl group, and C 1-12 Alkyl alkyl group (preferably C 1-6 The group is an alkyl group (more preferably a methyl group) or an oxyalkylene-containing group having 1 to 12 carbon atoms (for example, an oxyalkylene-containing group having 1 to 10 carbon atoms), and is, for example, a hydrogen atom. 【0081】 In one embodiment, XU is -OC(=O)-NR 54 -. In one embodiment, X U is -NR 54 -C(=O)O-. 【0082】 X s is a divalent group other than an alkylene group and a urethane bond. That is, X s1 is a divalent group that does not contain an alkylene group and a urethane bond. X s is preferably -O-, -S-, o-, m- or p-phenylene group, -CO-, -C(O)O-, -NR 2 -, -NR 2 -CO-NR 2 -, -O-, -S-, -O-(CH 2 ) x -CONR 2 - and O-(CH 2 ) x -CO- and is a group selected from the group consisting of, more preferably, -O-, -S-, o-, m- or p-phenylene group, -CO-, -C(O)O-, -NR 2 -, -O-, -S-, -O-(CH 2 ) x -CONR 2 - and -O-(CH 2 ) x -CO- and is a group selected from the group consisting of, even more preferably, -O- and -O-(CH 2 ) x -CONR 2 - and is particularly preferably -O-. 【0083】 R 2 is each independently a hydrogen atom or a monovalent organic group, preferably a hydrogen atom, a phenyl group, C 1-12 alkyl group (preferably C 1-6 alkyl group, more preferably a methyl group) or an oxyalkylene-containing group having 1 to 12 carbon atoms (for example, an oxyalkylene-containing group having 1 to 10 carbon atoms), for example, a hydrogen atom. 【0084】Each of s is an independent integer of 1 or more. Preferably, s is an integer of 10 or less, and more preferably an integer of 6 or less. Preferably, each of s is an independent integer of 1 to 10, and more preferably an integer of 1 to 6, for example, 1 or 2. 【0085】 - (C s H 2s )- is, for example, -CH 2 -ien-CHCH 3 -, -C(CH 3 ) 2 - can be cited. In one embodiment, - (C s H 2s ) - is -CH 2 - is. In one embodiment, - (C s H 2s ) - is -CHCH 3 - is. In one embodiment, - (C s H 2s )- is -C(CH 3 ) 2 - is the case. 【0086】 s1 is an integer greater than or equal to 1. Preferably, s1 is an integer between 1 and 100, more preferably between 1 and 30, and particularly preferably between 7 and 25. 【0087】 In one embodiment, s1 is an integer between 7 and 12, preferably between 10 and 12. 【0088】 In one embodiment, s1 is an integer between 16 and 30, preferably between 16 and 25, and particularly preferably between 18 and 22. 【0089】 s3 is an integer greater than or equal to 0, preferably an integer between 0 and 10, for example, an integer between 0 and 5, or an integer between 0 and 3. In one embodiment, s3 is 0. In one embodiment, s3 is 1. In one embodiment, s3 is 2. 【0090】 s4 is an integer greater than or equal to 1. In one embodiment, s4 is 0. In one embodiment, s4 is an integer from 1 to 5, for example, an integer from 1 to 3. In one embodiment, s4 is 1. In one embodiment, s4 is 2. 【0091】 In one embodiment, X 1 teeth, It is a group represented by R. L1 On the side (R 1 ) α And, R L2 On the side R Si And they are joined together. That is, R L1 X L1 The end located on the opposite side, and R 1 The bonding side and the other side bond together. 【0092】 X L1 is a carbon atom, a silicon atom, or a nitrogen atom. In one embodiment, X L1 is a carbon atom. In one embodiment, X L1 X is a silicon atom. In one embodiment, X L1 It is a nitrogen atom. 【0093】 R Z Each of these is independently a hydrogen atom or a monovalent organic group, preferably a hydrogen atom or a hydrocarbon group. 【0094】 In one embodiment, R Z This is a hydrogen atom. 【0095】 In one embodiment, R Z R is a monovalent organic group, preferably a hydrocarbon group. Z is preferably an alkyl group, and more preferably C 1-30 It is an alkyl group, and more preferably C 1-6 It is an alkyl group. In one embodiment, R Z C 1-12 It is an alkyl group, preferably C 1-3 It is an alkyl group, such as a methyl group, an ethyl group, or a propyl group. 【0096】 γ1 is an integer between 1 and 3, and γ2 is an integer between 0 and 2. However, the sum of γ1 and γ2 is X L1 This is the value of the valence -1. γ1 corresponds to α. 【0097】 In one embodiment, X L1γ1 is a carbon or silicon atom, γ2 is 3, and γ2 is 0. 【0098】 In one embodiment, X L1 γ1 is a carbon or silicon atom, γ1 is 2, and γ2 is 1. 【0099】 In one embodiment, X L1 γ1 is a carbon or silicon atom, γ1 is 1, and γ2 is 2. 【0100】 In one embodiment, X L1 is a nitrogen atom, γ1 is 2, and γ2 is 0. 【0101】 In one embodiment, X L1 is a nitrogen atom, γ1 is 1, and γ2 is 1. 【0102】 R L1 Each is independent of the other, -(C s H 2s ) s11’ - (X s ) s13’ - (X U ) s14’ It is represented by -. Here, the order of existence of each repeating unit enclosed in parentheses is not particularly limited. 【0103】 R L2 Each is independent of the other, -(C s H 2s ) s11” - (X s ) s13” - (X U ) s14” It is represented by -. Here, the order of existence of each repeating unit enclosed in parentheses is not particularly limited. 【0104】 's' has the same meaning as above. 【0105】 X s and X U These terms are equivalent to the above. 【0106】 s11' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 100, and more preferably an integer less than or equal to 50. For example, s11' is an integer between 0 and 100, specifically an integer between 1 and 50. 【0107】 s11'' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 100, and more preferably an integer less than or equal to 50. For example, s11'' is an integer between 0 and 100, specifically an integer between 1 and 50. 【0108】 s13' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 10, and more preferably an integer less than or equal to 5. For example, s13' is an integer between 0 and 10, specifically an integer between 1 and 5. 【0109】 s13'' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 10, and more preferably an integer less than or equal to 5. For example, s13'' is an integer between 0 and 10, specifically an integer between 1 and 5. 【0110】 s14' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 5, and more preferably an integer less than or equal to 3. For example, s14' is an integer between 0 and 5, specifically an integer between 1 and 3. 【0111】 s14'' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 5, and more preferably an integer less than or equal to 3. For example, s14'' is an integer between 0 and 5, specifically an integer between 1 and 3. 【0112】 However, at least one of s14' and s14'' is 1 or more, for example, s14' and s14'' are 1 or more. 【0113】 In one embodiment, s14' is 1. 【0114】 In one embodiment, s14'' is 1. 【0115】 The above X 1 In one embodiment, -(C s H 2s ) s1 - (X s1 ) s5 - (X U1 ) s6This is a divalent organic group represented by -. Here, the order of the groups enclosed in parentheses is not particularly limited. That is, α is 1. 【0116】 X U1 This is a urea bond, and -NR 55 -C(=O)-NR 55 It is represented by -. 【0117】 R 55 Each of these is independently a hydrogen atom or a monovalent organic group, preferably a hydrogen atom, a phenyl group, and C 1-12 Alkyl alkyl group (preferably C 1-6 The group is an alkyl group, more preferably a methyl group), an oxyalkylene-containing group having 1 to 12 carbon atoms (for example, an oxyalkylene-containing group having 1 to 10 carbon atoms), and is, for example, a hydrogen atom. 【0118】 X s1 X is a divalent group other than an alkylene group and a urea bond. s1 X is a divalent group that does not contain alkylene groups or urea bonds. s1 Preferably, -O-, -S-, o-, m- or p-phenylene group, -CO-, -C(O)O-, -NR 2 -, -OC(=O)-NR 2 -, -NR 2 -C(=O)O-, -O-, -S-, -O-(CH 2 ) x -CONR 2 - and -O- (CH 2 ) x A group selected from the group consisting of -CO-, more preferably -O-, -S-, o-, m- or p-phenylene group, -CO-, -C(O)O-, -NR 2 -, -O-, -S-, -O-(CH 2 ) x -CONR 2 - and -O- (CH 2 ) x A group selected from the group consisting of -CO-, more preferably -O- and -O-(CH 2 ) x -CONR 2 A group selected from the group consisting of -, and particularly preferably -O-. 【0119】 R 2 Each of these is independently a hydrogen atom or a monovalent organic group, preferably a hydrogen atom, a phenyl group, and C 1-12 Alkyl alkyl group (preferably C 1-6 The group is an alkyl group (more preferably a methyl group) or an oxyalkylene-containing group having 1 to 12 carbon atoms (for example, an oxyalkylene-containing group having 1 to 10 carbon atoms), and is, for example, a hydrogen atom. 【0120】 s and s1 have the same meaning as described above. 【0121】 s5 is an integer greater than or equal to 0, preferably an integer between 0 and 10, for example, an integer between 0 and 5, or an integer between 0 and 3. In one embodiment, s5 is 0. In one embodiment, s5 is 1. In one embodiment, s5 is 2. 【0122】 s6 is an integer greater than or equal to 1. In one embodiment, s6 is 0. In one embodiment, s6 is an integer from 1 to 5, for example, an integer from 1 to 3. In one embodiment, s6 is 1. In one embodiment, s6 is 2. 【0123】 In one embodiment, X 1 teeth, It is a group represented by R. L1 On the side (R 1 ) α And, R L2 On the side R Si And they are joined together. That is, R L1 X L1 The end located on the opposite side, and R 1 The bonding side and the other side bond together. 【0124】 X L1 , R z γ1 and γ2 have the same meaning as described above. 【0125】 R L1 Each is independent of the other, -(C s H 2s ) s11’ - (X s1 ) s51’ - (X U1 ) s61’It is represented by -. Here, the order of existence of each repeating unit enclosed in parentheses is not particularly limited. 【0126】 R L2 Each is independent of the other, -(C s H 2s ) s11” - (X s1 ) s51” - (X U1 ) s61” It is represented by -. Here, the order of existence of each repeating unit enclosed in parentheses is not particularly limited. 【0127】 s, s11', s11", X s1 , and X U1 These terms are equivalent to the above. 【0128】 s51' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 10, and more preferably an integer less than or equal to 5. For example, s51' is an integer between 0 and 10, specifically an integer between 1 and 5. 【0129】 s51'' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 10, and more preferably an integer less than or equal to 5. For example, s51'' is an integer between 0 and 10, specifically an integer between 1 and 5. 【0130】 s61' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 5, and more preferably an integer less than or equal to 3. For example, s61' is an integer between 0 and 5, specifically an integer between 1 and 3. 【0131】 s61'' is an integer greater than or equal to 0, preferably an integer greater than or equal to 1, preferably an integer less than or equal to 5, and more preferably an integer less than or equal to 3. For example, s61'' is an integer between 0 and 5, specifically an integer between 1 and 3. 【0132】 However, at least one of s61' and s61'' is an integer of 1 or more, for example, s61' and s61'' are 1 or more. 【0133】 In one embodiment, s61' is 1. 【0134】In one embodiment, s61'' is 1. 【0135】 In one embodiment, X 1 It is represented by one of the following elements: X s and X U These are equivalent to the above. - (C s H 2s ) s11 -X U - (C s H 2s ) s12 - (wherein the formula: s are each independent integers of 1 or more, the value of s1 is the sum of s11 and s12, s11 and s12 are each independent integers from 0 to 100, preferably from 1 to 50, provided that s1 is an integer of 1 or more); - (C s H 2s ) s11 -X s - (C s H 2s ) s12 -X U - (C s H 2s ) s13 - (wherein the formula: s are each independent integers of 1 or more, the value of s1 is represented by s11, s12, and s13, each of which is an independent integer between 0 and 100, preferably between 1 and 50, provided that s1 is an integer of 1 or more); - (C s H 2s ) s11 -X U - (C s H 2s ) s12 -X s - (C s H 2s ) s13 - (wherein the formula: s are each independent integers of 1 or more, s1 is represented by s11, s12, and s13, s11, s12, and s13 are each independent integers from 0 to 100, preferably from 1 to 50, provided that s1 is an integer of 1 or more); - (C s H 2s ) s11 -X s - (C s H2s ) s12 -X U - (C s H 2s ) s13 -X s - (C s H 2s ) s14 - (In the formula: s are each independent integers of 1 or more, the value of s1 is the sum of s11, s12, s13, and s14, each independent integer between 0 and 100, preferably between 1 and 50, provided that s1 is an integer of 1 or more.); - (C s H 2s ) s11 -X U - (C s H 2s ) s12 -X s - (C s H 2s ) s13 -X U - (C s H 2s ) s14 - (wherein the formula: s are each independent integers of 1 or more, the value of s1 is the sum of s11, s12, s13, and s14, each independent integer between 0 and 100, preferably between 1 and 50, provided that s1 is an integer of 1 or more.); [-(C s H 2s ) s11 -X s -] γ1 R Z γ2 X L1 - (C s H 2s ) s12 -X U - (C s H 2s ) s13 - (wherein the formula: s are each independent integers of 1 or more, the value of s1 is the sum of s11, s12, and s13, s11, s12, and s13 are each independent integers from 1 to 100, preferably from 1 to 50, γ1 is an integer of 1 or more, γ2 is an integer of 0 or more, where the sum of γ1 and γ2 is XL1 The valence of is -1, and R Z is a hydrogen atom or a monovalent organic group, X L1 This is equivalent to the above, except that s1 is an integer greater than or equal to 1. 【0136】 In one embodiment, X 1 It is represented by one of the following elements: X s1 and X U1 These are equivalent to the above. - (C s H 2s ) s11 -X U1 - (C s H 2s ) s12 - (wherein the formula: s are each independent integers of 1 or more, the value of s1 is the sum of s11 and s12, s11 and s12 are each independent integers from 0 to 100, preferably from 1 to 50, provided that s1 is an integer of 1 or more); - (C s H 2s ) s11 -X s1 - (C s H 2s ) s12 -X U1 - (C s H 2s ) s13 - (wherein the formula: s are each independent integers of 1 or more, the value of s1 is represented by s11, s12, and s13, each of which is an independent integer between 0 and 100, preferably between 1 and 50, provided that s1 is an integer of 1 or more); - (C s H 2s ) s11 -X U1 - (C s H 2s ) s12 -X s1 - (C s H 2s ) s13- (wherein the formula: s are each independent integers of 1 or more, s1 is represented by s11, s12, and s13, s11, s12, and s13 are each independent integers from 0 to 100, preferably from 1 to 50, provided that s1 is an integer of 1 or more); - (C s H 2s ) s11 -X s1 - (C s H 2s ) s12 -X U1 - (C s H 2s ) s13 -X s1 - (C s H 2s ) s14 - (In the formula: s are each independent integers of 1 or more, the value of s1 is the sum of s11, s12, s13, and s14, each independent integer between 0 and 100, preferably between 1 and 50, provided that s1 is an integer of 1 or more.); - (C s H 2s ) s11 -X U1 - (C s H 2s ) s12 -X s1 - (C s H 2s ) s13 -X U1 - (C s H 2s ) s14 - (wherein the formula: s are each independent integers of 1 or more, the value of s1 is the sum of s11, s12, s13, and s14, each independent integer between 0 and 100, preferably between 1 and 50, provided that s1 is an integer of 1 or more.); [-(C s H 2s ) s11 -X s1 -] γ1 R Z γ2 X L1 - (C s H 2s ) s12 -XU1 - (C s H 2s ) s13 - (wherein the formula: s are each independent integers of 1 or more, the value of s1 is the sum of s11, s12, and s13, s11, s12, and s13 are each independent integers from 1 to 100, preferably from 1 to 50, γ1 is an integer of 1 or more, γ2 is an integer of 0 or more, where the sum of γ1 and γ2 is X L1 The valence of is -1, and R Z is a hydrogen atom or a monovalent organic group, X L1 This is equivalent to the above, except that s1 is an integer greater than or equal to 1. 【0137】 In one embodiment, X 1 is, -(CH 2 ) s11 - (CH 2 CH 2 O) n6 - (CH 2 ) s12 -X U - (CH 2 ) s13 It is represented as -. s11, s12, and s13 are each independent integers from 1 to 100, preferably from 1 to 50, and may also be integers from 1 to 10 or from 1 to 5. For example, s11 may be an integer from 1 to 5, s12 may be 2, and s13 may be an integer from 1 to 5. n6 is an integer from 1 to 30, preferably from 2 to 20, more preferably from 3 to 15. 【0138】 In one embodiment, X 1 is, -(CH 2 ) s11 - (CH 2 CH 2 O) n6 - (CH 2 ) s12 -X U1 - (CH 2 ) s13It is represented as -. s11, s12, and s13 are each independent integers from 1 to 100, preferably from 1 to 50, and may also be integers from 1 to 10 or from 1 to 5. For example, s11 may be an integer from 1 to 5, s12 may be 2, and s13 may be an integer from 1 to 5. n6 is an integer from 1 to 30, preferably from 2 to 20, more preferably from 3 to 15. 【0139】 R Si These can be expressed independently by equation (S1). 【0140】 R 11 These are, independently, hydroxyl groups or hydrolyzable groups. 【0141】 The above R 11 Preferably, each of these is independently a hydrolyzable group. 【0142】 R 12 These are each independently monovalent organic groups. Such monovalent organic groups are monovalent organic groups excluding the hydrolyzable groups mentioned above. 【0143】 The above R 12 In this, the monovalent organic group is preferably C 1-20 It is an alkyl group, more preferably C 1-6 An alkyl group, more preferably a methyl group. 【0144】 j1 is an integer from 0 to 3. However, in equation (S1), j1 is between 1 and 3 (SiR 11 j1 R 12 3-j1 There are at least two units. In other words, in formula (S1), there are at least two Si atoms to which a hydroxyl group or hydrolyzable group is attached. 【0145】 The above j1 is (SiR 11 j1 R 12 3-j1 Each unit is independently preferably an integer between 1 and 3, more preferably between 2 and 3, and even more preferably 3. 【0146】In one embodiment, formula (S1) does not contain a siloxane bond. 【0147】 In a preferred embodiment, formula (S1) is the following formula: where * is X 1 This represents the connection point. 【0148】 In one embodiment, α is 1, and X 1 Ha- (C s H 2s ) s1 - (X s ) s3 - (X U ) s4 Represented by -, R Si (S1) is a base represented by the equation. Here, the order of existence of each repeating unit enclosed in parentheses is not particularly limited. 【0149】 In one embodiment, α is γ1, and X 1 teeth It is a base represented by X L1 is a carbon atom, γ1 is 3, γ2 is 0, R Si is a group represented by (S1). 【0150】 In one embodiment, α is γ1, and X 1 teeth It is a base represented by X L1 is a carbon atom, γ1 is 2, γ2 is 1, R Z R is a hydrogen atom or a monovalent organic group. Si is a group represented by (S1). 【0151】 In one embodiment, α is γ1, and X 1 teeth It is a base represented by X L1 is a carbon atom, γ1 is 3, γ2 is 0, R L1 Each is independent of the other, -(C s H 2s ) s11’ - (X s ) s13’ - (X U ) s14’Represented by -, R L2 Each is independent of the other, -(C s H 2s ) s11’ - (X s ) s13” - (X U ) s14” Represented by -, where the order of existence of each repeating unit enclosed in parentheses is not particularly limited, R Si is a group represented by (S1). 【0152】 In one embodiment, α is γ1, and X 1 teeth It is a base represented by X L1 is a carbon atom, γ1 is 2, γ2 is 1, R L1 Each is independent of the other, -(C s H 2s ) s11’ - (X s ) s13’ - (X U ) s14’ Represented by -, R L2 Each is independent of the other, -(C s H 2s ) s11’ - (X s ) s13” - (X U ) s14” Represented by -, where the order of existence of each repeating unit enclosed in parentheses is not particularly limited, R Z R is a hydrogen atom or a hydrocarbon group. Si is a group represented by (S1). 【0153】 In one embodiment, α is 1, and X 1 Ha- (C s H 2s ) s1 - (X s1 ) s5 - (X U1 ) s6 Represented by -, R Si (S1) is a base represented by the equation. Here, the order of existence of each repeating unit enclosed in parentheses is not particularly limited. 【0154】In one embodiment, α is γ1, and X 1 teeth It is a base represented by X L1 is a carbon atom, γ1 is 3, γ2 is 0, R L1 Each is independent of the other, -(C s H 2s ) s11’ - (X s1 ) s51’ - (X U1 ) s61’ Represented by -, R L2 Each is independent of the other, -(C s H 2s ) s11’ - (X s1 ) s51” - (X U1 ) s61” Represented by -, where the order of existence of each repeating unit enclosed in parentheses is not particularly limited, R Si is a group represented by (S1). 【0155】 In one embodiment, α is γ1, and X 1 teeth It is a base represented by X L1 is a carbon atom, γ1 is 2, γ2 is 1, R L1 Each is independent of the other, -(C s H 2s ) s11’ - (X s1 ) s51’ - (X U1 ) s61’ Represented by -, R L2 Each is independent of the other, -(C s H 2s ) s11’ - (X s1 ) s51” - (X U1 ) s61” Represented by -, where the order of existence of each repeating unit enclosed in parentheses is not particularly limited, R Z R is a hydrogen atom or a hydrocarbon group. Si is a group represented by (S1). 【0156】Examples of compounds represented by formula (1) include those represented by the following formula: CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -OC(=O)NH-(CH 2 ) n3 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, and n3 is an integer from 1 to 60.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -OC(=O)NH-(CH 2 ) n3 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, and n3 is an integer from 1 to 60.) [(CH 3 ) 3 SiO] 2 (CH 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -OC(=O)NH-(CH 2 ) n3 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, and n3 is an integer from 1 to 60.) [(CH 3 ) 3 SiO] 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH3 ) 2 - (CH 2 ) n2 -OC(=O)NH-(CH 2 ) n3 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, and n3 is an integer from 1 to 60.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 30.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 30.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4-OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4 -OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) [CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -] 3 C-(CH 2 ) n4 -OC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, and n5 is an integer from 1 to 60.) [CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2- (CH 2 ) n2 -O-(CH 2 ) n3 ] 3 C-(CH 2 ) n4 -OC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, and n5 is an integer from 1 to 60.) [CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -] 2 CR[(CH 2 ) n4 -OC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, n5 is an integer from 1 to 60, and R is C 1-30 It is an alkyl group or a phenyl group. ): [CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -] 2 CR[(CH 2 ) n4 -OC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3] (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, n5 is an integer from 1 to 60, and R is C 1-30 It is an alkyl group or a phenyl group. ); [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4 -OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 )n2 -O-(CH 2 ) n3 ] 3 C-(CH 2 ) n4 -OC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, and n5 is an integer from 1 to 60.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 ] 2 CR[(CH 2 ) n4 -OC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, n5 is an integer from 1 to 60, and R is C 1-30 (An alkyl group or a phenyl group.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) CH 3 CH 2 CH2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2 ) n4 -OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2 ) n4 -OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3(In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) [CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 ] 3 C-(CH 2 ) n4 -NHC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, and n5 is an integer from 1 to 60.) [CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 ] 3 C-(CH 2 ) n4 -NHC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, and n5 is an integer from 1 to 60.) [CH 3 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 ] 2 CR[(CH 2 )n4 -NHC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, n5 is an integer from 1 to 60, and R is C 1-30 It is an alkyl group or a phenyl group. ); [CH 3 CH 2 CH 2 CH 2 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 ] 2 CR[(CH 2 ) n4 -NHC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, n5 is an integer from 1 to 60, and R is C 1-30 It is an alkyl group or a phenyl group.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) [(CH 3 ) 3SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2 ) n4 -OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, and n4 is an integer from 1 to 60.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 ] 3 C-(CH 2 ) n4 -NHC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, and n5 is an integer from 1 to 60.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 ] 2 CR[(CH2 ) n4 -NHC(=O)NH-(CH 2 ) n5 -Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, n3 is an integer from 1 to 60, n4 is an integer from 1 to 60, n5 is an integer from 1 to 60, and R is C 1-30 (It is an alkyl group or a phenyl group.) 【0157】 In one embodiment, the compound represented by formula (1) is represented by the following formula: CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 30, n3 is an integer from 1 to 30, and n4 is an integer from 1 to 30.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 30, n3 is an integer from 1 to 30, and n4 is an integer from 1 to 30.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O]n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 30, n3 is an integer from 1 to 30, and n4 is an integer from 1 to 30.) [(CH 3 ) 3 SiO] 3 SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -OC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 30, n3 is an integer from 1 to 30, and n4 is an integer from 1 to 30.) 【0158】 In one aspect, the compound represented by formula (1) is represented by the following formula: [(CH 3 ) 3 SiO] 2 SiCH 3 -CH 2 CH 2 CH 2 O-(CH 2 CH 2 O) n6 -CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 -Si(OCH) 3 ) 3 (In the formula, n6 is an integer between 1 and 30, preferably between 2 and 20, and more preferably between 3 and 15.) 【0159】Examples of compounds represented by formula (1) include those represented by the following formula: CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3(wherein n1 is an integer between 1 and 500.) [CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -NHC(=O)NH-(CH 2 ) n3 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, and n3 is an integer from 1 to 30.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -NHC(=O)NH-(CH 2 ) n3 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, and n3 is an integer from 1 to 30.) [(CH 3 ) 3 SiO] 2 Si(CH 3 )O-[Si(CH 3 )2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -NHC(=O)NH-(CH 2 ) n3 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, and n3 is an integer from 1 to 30.) [(CH 3 ) 3 SiO] 3 SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -NHC(=O)NH-(CH 2 ) n3 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 60, and n3 is an integer from 1 to 30.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2 ) n3 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 30, and n3 is an integer from 1 to 30.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 30, n3 is an integer from 1 to 30, and n4 is an integer from 1 to 30.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 30, n3 is an integer from 1 to 30, and n4 is an integer from 1 to 30.) [(CH 3 ) 3 SiO] 3 SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) n2 -O-(CH 2 ) n3 -NHC(=O)NH-(CH 2 ) n4 -Si(OCH) 3 ) 3 (In the formula, n1 is an integer from 1 to 500, n2 is an integer from 1 to 30, n3 is an integer from 1 to 30, and n4 is an integer from 1 to 30.) 【0160】 In one embodiment, the compound represented by formula (1) has the following structure: CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 OC(=O)NHCH 2 CH2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 It is an alkyl group or a phenyl group. ); [CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 It is an alkyl group or a phenyl group. ); [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 (An alkyl group or a phenyl group.) CH 3 -[Si(CH 3 )2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O]n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [CH 3 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 )2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 It is an alkyl group or a phenyl group. ); [CH 3 CH 2 CH 2 CH 2 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 It is an alkyl group or a phenyl group. ); [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [(CH3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 -NHC(=O)NHCH 2 CH2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 (It is an alkyl group or a phenyl group.) 【0161】 In one embodiment, the compound represented by formula (1) has the following structure: CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is between 10 and 100.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -NHC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is between 10 and 100.) ((CH 3 ) 3 SiO) 2 SiCH 3 -CH 2 CH 2 CH 2 O-(CH 2 CH 2 O) n6 -CH 2 CH 2-OC(=O)NH-CH 2 CH 2 CH 2 -Si(OCH) 3 ) 3 (In the formula, n6 is 1 to 30, preferably 2 to 20, more preferably 3 to 15.) 【0162】 The following are specific examples of compounds represented by formula (1): CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is 60.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -NHC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (wherein n1 is 25.) [(CH 3 ) 3 SiO) 2 SiCH 3 -CH 2 CH 2 CH 2 O-(CH 2 CH 2 O) 9 -CH 2 CH2 -OC(=O)NH-CH 2 CH 2 CH 2 -Si(OCH) 3 ) 3 【0163】 [Manufacturing Method] The manufacturing method for the silane compounds of this disclosure will be described below. However, the manufacturing method for the silane compounds of this disclosure is not limited to the following method. 【0164】 (Manufacturing Method 1) The present manufacturing method includes (1a) a step of reacting a carbinol having a group containing a Si atom to which a hydroxyl group or hydrolyzable group is not directly bonded with a compound having a group containing a Si atom to which a hydroxyl group or hydrolyzable group is bonded. The silane compound of the present disclosure can be produced by the above step. 【0165】 Carbinols having a group containing a Si atom to which a hydroxyl group or hydrolyzable group is not directly bonded are represented, for example, by the following formula. In the formula: cn is an integer between 1 and 3, preferably 1; cm may be an integer between 1 and 500, an integer between 1 and 300, or an integer between 1 and 200; R CA1 Each of these is independently a hydrocarbon group, which may be, for example, an alkyl group having 1 to 12 carbon atoms, a methyl group, or an n-butyl group; R CA2 Each of these is independently a hydrocarbon group, which may be, for example, an alkyl group having 1 to 12 carbon atoms, or a methyl group; R CA3 This is a single-bonded or divalent organic group. The divalent organic group may be, for example, an alkylene group having 1 to 30 carbon atoms in which some of the methylene group may be replaced by oxygen atoms. 【0166】 Examples of the above-mentioned carbinols include polydimethylsiloxanes having hydroxyl groups at their termini, such as Cyraprene (trademark registered) FM-0411P, FM-0421, and FM-0425 manufactured by JNC Corporation, and MCR-C12 and MCR-C18 manufactured by Gelest. 【0167】 The terminal group of the above carbinol is CH3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - [(CH 3 ) 3 SiO) 2 (CH 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - [(CH 3 ) 3 SiO] 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - are some examples. 【0168】 In one embodiment, the terminal group of the above carbinol is CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - is the case. 【0169】 In one embodiment, the terminal group of the above carbinol is [(CH 3 ) 3 SiO] 2 (CH 3 )Si-O-[Si(CH 3 ) 2 O] n1Si(CH 3 ) 2 - [(CH 3 ) 3 SiO] 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - is the case. 【0170】 In one embodiment, the above-mentioned carbinol is represented by the following structure. (n is an integer between 1 and 500) 【0171】 Examples of compounds having a group containing a Si atom to which a hydroxyl group or a hydrolyzable group is bonded include (3-isocyanatopropyl)trimethoxysilane and (3-isocyanatopropyl)triethoxysilane. 【0172】 In the above reaction, the reaction temperature is not particularly limited. For example, the reaction temperature may be 0 to 200°C, 20 to 150°C, or 20 to 100°C. 【0173】 The above reaction can be carried out in a solvent. As a solvent, for example, at least one selected from the group consisting of diethyl ether, tetrahydrofuran, cyclopentyl methyl ether, ethylene glycol, dichloromethane, chloroform, benzene, toluene, and 1,3-bis(trifluoromethyl)benzene can be used. Preferably, at least one selected from the group consisting of acetonitrile, dichloromethane, chloroform, toluene, diethyl ether, and tetrahydrofuran can be used. Two or more of these solvents may be used in mixture form. The above reaction may also be carried out without a solvent. 【0174】A catalyst may be added to the above reaction. Examples of catalysts include dibutyltin dilaurate, tin(II) 2-ethylhexanoate, triethylamine, tris(2-ethylhexanoate)bismuth(III), bis(6-methylheptyl) 2,2'-[(dibutylstannylene)bisthio]bisacetate, di-n-octyltin oxide, tetraisopropyl orthotitanate, zinc, and bismuth. The above reaction may also be carried out without a catalyst. 【0175】 (Manufacturing Method 2) This manufacturing method involves (2a) a carbinol having a group containing a Si atom to which a hydroxyl group or hydrolyzable group is not directly bonded, and an olefin (-CH=CH) having a group containing a Si atom to which a hydroxyl group or hydrolyzable group is bonded. 2 (2b) a step of reacting compounds to produce an olefin-containing urethane compound, and a step of synthesizing a silane compound of the present disclosure from the obtained olefin-containing urethane compound. 【0176】 Step (2a) Carbinol has the same meaning as above. 【0177】 Examples of olefin compounds having a group containing a Si atom to which a hydroxyl group or hydrolyzable group is bonded include allyl isocyanate, 4-isocyanate-1-butene, 5-isocyanate-1-pentene, 6-isocyanate-1-hexene, 7-isocyanate-1-heptene, 10-isocyanate-1-decene, and 11-isocyanate-1-undecene. 【0178】 The above reaction temperature is not particularly limited. For example, the reaction temperature may be 0 to 200°C, 20 to 150°C, or 20 to 100°C. 【0179】 The above reaction is not particularly limited, but can be carried out by stirring for, for example, 1 to 60 minutes or 1 to 72 hours. 【0180】The above reaction can be carried out in a solvent. As a solvent, for example, at least one selected from the group consisting of diethyl ether, tetrahydrofuran, cyclopentyl methyl ether, ethylene glycol, dichloromethane, chloroform, benzene, toluene, and 1,3-bis(trifluoromethyl)benzene can be used. Preferably, at least one selected from the group consisting of acetonitrile, dichloromethane, chloroform, toluene, diethyl ether, and tetrahydrofuran can be used. Two or more of these solvents may be used in mixture form. The above reaction may also be carried out without a solvent. 【0181】 A catalyst may be added to the above reaction. Examples of catalysts include dibutyltin dilaurate, tin(II) 2-ethylhexanoate, triethylamine, tris(2-ethylhexanoate)bismuth(III), bis(6-methylheptyl) 2,2'-[(dibutylstannylene)bisthio]bisacetate, di-n-octyltin oxide, tetraisopropyl orthotitanate, zinc, and bismuth. The above reaction may also be carried out without a catalyst. 【0182】 Step (2b) The olefin-containing urethane compound contains an olefin at its end. 【0183】 The urethane compound contains the following formula: HSiR j27 m3 R j28 3-m3 [In the formula, R j27 Each of these is independently a hydroxyl group or a hydrolyzable group, R j28 Each of these is an independent monovalent organic group, and m3 is 1 to 3. A silane compound can be obtained by reacting it with the compound represented by [ ]. The above monovalent organic group does not contain a hydrolyzable group. The monovalent organic group has the same meaning as above. 【0184】 The reaction temperature, reaction time, solvent, and catalyst are the same as in step (2a). 【0185】(Manufacturing Method 3) The present manufacturing method includes (3a) a step of reacting an amine having a group containing a Si atom to which a hydroxyl group or hydrolyzable group is not directly bonded with a compound having a group containing a Si atom to which a hydroxyl group or hydrolyzable group is bonded. The silane compound of the present disclosure can be produced by the above step. 【0186】 Amine having a group containing a Si atom to which a hydroxyl group or hydrolyzable group is not directly bonded is represented, for example, by the following formula. In the formula: cn is an integer between 1 and 3, preferably 1; cm may be an integer between 1 and 500, an integer between 1 and 300, or an integer between 1 and 200; R CA1 Each of these is independently a hydrocarbon group, which may be, for example, an alkyl group having 1 to 12 carbon atoms, a methyl group, or an n-butyl group; R CA2 Each of these is independently a hydrocarbon group, which may be, for example, an alkyl group having 1 to 12 carbon atoms, or a methyl group; R CA3 This is a single-bonded or divalent organic group. The divalent organic group may be, for example, an alkylene group having 1 to 30 carbon atoms in which some of the methylene group may be replaced by oxygen atoms. 【0187】 The terminal group of the above amine is CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - [(CH 3 ) 3 SiO) 2 (CH 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2- [(CH 3 ) 3 SiO] 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - are some examples. 【0188】 In one aspect, the terminal group of the above amine is CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - is the case. 【0189】 In one aspect, the terminal group of the above amine is [(CH 3 ) 3 SiO] 2 (CH 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - [(CH 3 ) 3 SiO] 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - is the case. 【0190】 In one embodiment, the above amine is represented by the following structure: CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) 2 -NH 2 IEEE CH 3 CH2 CH 2 CH 2 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 2 -NH 2 、 [(CH 3 ) 3 SiO) 2 (CH) 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 2 -NH 2 、 [(CH 3 ) 3 SIO 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 2 -NH 2 CH 3 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 3 -NH 2 CH 3 CH 2 CH 2 CH 2 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 3 -NH 2 、 [(CH 3 ) 3 SiO) 2 (CH) 3 )Si-O-[Si(CH 3 ) 2 O]n1 Si(CH) 3 ) 2 -(CH) 2 ) 3 -NH 2 、 [(CH 3 ) 3 SIO 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 3 -NH 2 CH 3 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 10 -NH 2 CH 3 CH 2 CH 2 CH 2 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 10 -NH 2 、 [(CH 3 ) 3 SiO) 2 (CH) 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 10 -NH 2 、 [(CH 3 ) 3 SIO 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 10 -NH 2 CH3 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 11 -NH 2 CH 3 CH 2 CH 2 CH 2 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 11 -NH 2 、 [(CH 3 ) 3 SiO) 2 (CH) 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 11 -NH 2 、 [(CH 3 ) 3 SIO 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 11 -NH 2 CH 3 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 16 -NH 2 CH 3 CH 2 CH 2 CH 2 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2-(CH) 2 ) 16 -NH 2 、 [(CH 3 ) 3 SiO) 2 (CH) 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 16 -NH 2 、 [(CH 3 ) 3 SIO 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 16 -NH 2 CH 3 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 18 -NH 2 CH 3 CH 2 CH 2 CH 2 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 18 -NH 2 、 [(CH 3 ) 3 SiO) 2 (CH) 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 18 -NH 2 、 [(CH 3 ) 3 SIO3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 18 -NH 2 CH 3 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 22 -NH 2 CH 3 CH 2 CH 2 CH 2 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 22 -NH 2 、 [(CH 3 ) 3 SiO) 2 (CH) 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 22 -NH 2 、 [(CH 3 ) 3 SIO 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 22 -NH 2 CH 3 -[Si(CH) 3 ) 2 O] n1 Si(CH) 3 ) 2 -(CH) 2 ) 29 -NH2 IEEE CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) 29 -NH 2 , [(CH 3 ) 3 SiO) 2 (CH 3 )Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) 29 -NH 2 , [(CH 3 ) 3 SiO] 3 Si-O-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 - (CH 2 ) 29 -NH 2 (n1 is an integer between 1 and 500, independently of each other.) 【0191】 Examples of compounds having a group containing a Si atom to which a hydroxyl group or a hydrolyzable group is bonded include (3-isocyanatopropyl)trimethoxysilane and (3-isocyanatopropyl)triethoxysilane. 【0192】 In the above reaction, the reaction temperature is not particularly limited. For example, the reaction temperature may be 0 to 200°C, 20 to 150°C, or 20 to 100°C. 【0193】The above reaction can be carried out in a solvent. As a solvent, for example, at least one selected from the group consisting of diethyl ether, tetrahydrofuran, cyclopentyl methyl ether, ethylene glycol, dichloromethane, chloroform, benzene, toluene, and 1,3-bis(trifluoromethyl)benzene can be used. Preferably, at least one selected from the group consisting of acetonitrile, dichloromethane, chloroform, toluene, diethyl ether, and tetrahydrofuran can be used. Two or more of these solvents may be used in mixture form. The above reaction may also be carried out without a solvent. 【0194】 A catalyst may be added to the above reaction. Examples of catalysts include dibutyltin dilaurate, tin(II) 2-ethylhexanoate, triethylamine, tris(2-ethylhexanoate)bismuth(III), bis(6-methylheptyl) 2,2'-[(dibutylstannylene)bisthio]bisacetate, di-n-octyltin oxide, tetraisopropyl orthotitanate, zinc, and bismuth. The above reaction may also be carried out without a catalyst. 【0195】 [Composition] The compositions of the present disclosure comprise at least one compound selected from the group consisting of silane compounds of the present disclosure and condensates obtained by the condensation of at least a portion of the silane compounds. 【0196】 In one embodiment, the composition of the Disclosure comprises a silane compound of the Disclosure. 【0197】 In one embodiment, the compositions of the Disclosure comprise condensates of the silane compounds of the Disclosure. 【0198】 The compositions of this disclosure are preferably used as surface treatment agents or as components of surface treatment agents. 【0199】 [Surface treatment agent] The surface treatment agent of the present disclosure preferably comprises the above composition. 【0200】 The surface treatment agent of this disclosure contains at least one silane compound represented by formula (1). 【0201】In one embodiment, the surface treatment agent of the present disclosure is at least one compound represented by formula (1) itself. 【0202】 The surface treatment agent of this disclosure contains a condensate of at least one silane compound represented by formula (1). 【0203】 In one embodiment, the content of the silane compound represented by formula (1) above may be preferably 0.1 to 50.0% by mass, more preferably 1.0 to 30.0% by mass, even more preferably 5.0 to 25.0% by mass, and particularly preferably 10.0 to 20.0% by mass, relative to the total surface treatment agent. 【0204】 In another embodiment, the content of the silane compound represented by formula (1) above may be preferably 0.001 to 30% by mass, more preferably 0.01 to 10% by mass, even more preferably 0.05 to 5% by mass, and particularly preferably 0.05 to 2% by mass, relative to the total surface treatment agent. 【0205】 In one embodiment, the surface treatment agent of the present disclosure may contain a silane compound represented by formula (1) and a condensate obtained by condensing at least a portion of the silane compound represented by formula (1). 【0206】 In the above embodiment, the content of the condensate may be preferably 40% by mass or less, more preferably 30% by mass or less, relative to the total of the silane compound represented by formula (1) and the condensate. Here, the content of the condensate can be determined, for example, from the ratio of peak positions and areas in GPC (gel permeation chromatography). 【0207】 The above composition, preferably, further, It contains the compound represented by . x3 is an integer between 6 and 80. R Si This is synonymous with the above. 【0208】 The content of the compound represented by formula (2) is preferably 0.1 to 30% by mass, more preferably 0.5 to 10% by mass, even more preferably 1 to 3% by mass, and particularly preferably 1 to 2% by mass, relative to the total of the compound represented by formula (1) and the compound represented by formula (2). 【0209】The compound represented by formula (2) may be present in the composition as one type or as two or more types. 【0210】 The surface treatment agents disclosed herein may include solvents, silicone compounds (non-reactive) that can be understood as silicone oils (hereinafter referred to as "silicone oils"), amine compounds, alcohols, catalysts, surfactants, polymerization inhibitors, sensitizers, and the like. 【0211】 In one embodiment, the surface treatment agent of the present disclosure is R 90 Contains compounds represented by -OH. 90 is a monovalent organic group, preferably C 1-20 Alkyl alkyl group or C 3-20 These are alkylene groups, and these groups may be substituted with one or more substituents. Examples of substituents include hydroxyl groups, -OR 91 (Here, R 91 is C 1-10 Alkyl alkyl group, preferably C 1-3 Examples include alkyl groups (for example, a methyl group). 【0212】 In one embodiment, the surface treatment agent of the present disclosure is R 81 OR 82 , R 83 n8 C 6 H 6-n8 , R 84 R 85 R 86 Si-(O-SiR 87 R 88 ) m8 -R 89 , and (OSiR 87 R 88 ) m9 [In the formula R 81 ~R 89 Each of these is independently a monovalent organic group having 1 to 10 carbon atoms, m8 is an integer from 1 to 6, m9 is an integer from 3 to 8, and n8 is an integer from 0 to 6. The solvent may be selected from the compounds represented by [ ]. 【0213】 The monovalent organic group having 1 to 10 carbon atoms may be linear, branched, or may even contain a cyclic structure. 【0214】 In one embodiment, the monovalent organic group having 1 to 10 carbon atoms may contain an oxygen atom, a nitrogen atom, or a halogen atom. 【0215】 In another embodiment, the monovalent organic group having 1 to 10 carbon atoms does not contain a halogen atom. 【0216】 In a preferred embodiment, the monovalent organic group having 1 to 10 carbon atoms is a hydrocarbon group which may be substituted with a halogen, preferably an unsubstituted hydrocarbon group. 【0217】 In one embodiment, the hydrocarbon group is a straight chain. 【0218】 In another embodiment, the hydrocarbon group is a branched chain. 【0219】 In another embodiment, the hydrocarbon group includes a cyclic structure. 【0220】 In one embodiment, the solvent is R 81 OR 82 That is the case. 【0221】 R 81 and R 82 Each of these is independently preferably a hydrocarbon group having 1 to 8 carbon atoms, more preferably C 1-6 an alkyl group, or C 5-8 It may be a cycloalkyl group. 【0222】 In one embodiment, the solvent is R 83 n8 C 6 H 6-n8 That is the case. 【0223】 C 6 H 6-n8 This is an n8 valent benzene ring. That is, R 83 n8 C 6 H 6-n8 This is n8 R 83 This is a benzene substituted with [substance name]. 【0224】 R 83 Each of these is a halogen, or a C which may be substituted with a halogen. 1-6 It can be an alkyl group. 【0225】 n8 is preferably an integer between 1 and 3. 【0226】 In one embodiment, the solvent is R 84 R 85 R 86 Si-(O-SiR 87 R 88 ) m8 -R 89 That is the case. 【0227】 In one embodiment, the solvent is (OSiR 87 R 88 ) m9 (OSiR) 87 R 88 ) m9 This involves multiple OSIRs 87 R 88 It is a cyclic siloxane formed by the ring-like bonding of units. 【0228】 R 84 ~R 89 Each of these is independently a hydrogen atom, or C 1-6 an alkyl group, preferably C 1-6 alkyl group, more comfortably C 1-3 The alkyl group is more preferably a methyl group. 【0229】 m8 is preferably an integer from 1 to 6, more preferably an integer from 1 to 5, and even more preferably 1 to 2. 【0230】 m9 is preferably an integer between 3 and 6, more preferably an integer between 3 and 5. 【0231】 The solvent is preferably at least one selected from aliphatic hydrocarbons, aromatic hydrocarbons, esters, ketones, glycol ethers, ethers, and siloxanes. 【0232】In one embodiment, the solvent may be, for example, aliphatic hydrocarbons such as hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, and mineral spirits; aromatic hydrocarbons such as benzene, toluene, xylene, naphthalene, and solvent naphtha; esters such as methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate, isobutyl acetate, cellosolve acetate, propylene glycol methyl ether acetate, carbitol acetate, diethyl oxalate, ethyl pyruvate, ethyl-2-hydroxybutyrate, ethyl acetate acetate, amyl acetate, methyl lactate, ethyl lactate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 2-hydroxyisobutyrate, and ethyl 2-hydroxyisobutyrate; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, 2-hexanone, cyclohexanone, methylaminoketone, and 2-heptanone; and ethyl cellosolve. Glycol ethers such as methyl cellosolve, methyl cellosolve acetate, ethyl cellosolve acetate, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monobutyl ether acetate, dipropylene glycol dimethyl ether, and ethylene glycol monoalkyl ether; glycols such as ethylene glycol and propylene glycol; cyclic ethers such as tetrahydrofuran, tetrahydropyran, and dioxane; amides such as N,N-dimethylformamide, N,N-dimethylacetamide, and N-methylpyrrolidone; diethylene glycol monoethyl ether acetate; polyfluoroaromatic hydrocarbons (e.g., 1,3-bis(trifluoromethyl)benzene); polyfluoroaliphatic hydrocarbons (e.g., C 6 F 13 CH 2 CH 3(For example, AsahiClean® AC-6000 manufactured by Asahi Glass Co., Ltd.), 1,1,2,2,3,3,4-heptafluorocyclopentane (for example, Zeolora® H manufactured by Nippon Zeon Co., Ltd.); fluorinated hydrocarbons such as 1,1,2-trichloro-1,2,2-trifluoroethane, 1,2-dichloro-1,1,2,2-tetrafluoroethane, 1,1-dichloro-1,2,2,3,3-pentafluoropropane (HCFC225), and 1,3-bis(trifluoromethyl)benzene; hydrofluoroethers (HFE) (for example, perfluoropropyl methyl ether (C) 3 F 7 OCH 3 ) (For example, Novec® 7000 manufactured by Sumitomo 3M Limited), perfluorobutyl methyl ether (C 4 F 9 OCH 3 ) (For example, Novec™ 7100 manufactured by Sumitomo 3M Limited), perfluorobutyl ethyl ether (C 4 F 9 OC 2 H 5 ) (For example, Novec™ 7200 manufactured by Sumitomo 3M Limited), perfluorohexyl methyl ether (C 2 F 5 CF(OCH) 3 ) C 3 F 7 ) (for example, Novec™ 7300 manufactured by Sumitomo 3M Limited) or other alkyl perfluoroalkyl ethers (the perfluoroalkyl group and alkyl group may be linear or branched), or CF 3 CH 2 OCF 2 CHF 2Examples include ethers such as cyclopentyl methyl ether (for example, Asahiclean® AE-3000 manufactured by Asahi Glass Co., Ltd.), hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, octamethylcyclotetrasiloxane, octamethylcyclopentasiloxane, decamethylcyclopentasiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane, and dimethyl sulfoxide. Alternatively, mixed solvents of two or more of these are also possible. Among these, aliphatic hydrocarbons, esters, glycol ethers, and siloxanes are preferred. For example, hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, mineral spirits, methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate, isobutyl acetate, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, methanol, ethanol, iso-propanol, n-butanol, isobutanol, tert-butanol, sec-butanol, diethylene glycol monomethyl ether, hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane, octamethylcyclotetrasiloxane, and octamethylcyclopentasiloxane are preferred. 【0233】 The silicone oil is not particularly limited, but for example, the following general formula (3a): R 1a - (SiR 3a 2 -O) a1 -SiR 3a 2 -R 1a ...(3a) [wherein: R 1a Each is independently a hydrogen atom or a hydrocarbon group, and R 3a Examples of compounds represented by [ ] include each being independently a hydrogen atom or a hydrocarbon group, where a1 is 2 to 3000. 【0234】The above R 3a Each of these is independently either a hydrogen atom or a hydrocarbon group. Such hydrocarbon groups may be substituted. 【0235】 R 3a Each of these is independently preferably an unsubstituted hydrocarbon group or a hydrocarbon group substituted with a halogen atom. The halogen atom is preferably a fluorine atom. 【0236】 R 3a Each of these C atoms may be independently substituted, preferably with a halogen atom. 1-6 Alkyl or aryl group, more preferably C 1-6 It is an alkyl group or an aryl group. 【0237】 The above CC 1-6 The alkyl group may be linear or branched, but is preferably linear. 1-6 The alkyl group is preferably C 1-3 An alkyl group, more preferably a methyl group. 【0238】 The above aryl group is preferably a phenyl group. 【0239】 In one embodiment, R 3a Each of them is independent of C 1-6 Alkyl alkyl group, preferably C 1-3 An alkyl group, more preferably a methyl group. 【0240】 In another embodiment, R 3a This is a phenyl group. 【0241】 In another embodiment, R 3a This is a methyl group or a phenyl group, preferably a methyl group. 【0242】 The above R 1a Each of these is independently a hydrogen atom or a hydrocarbon group, and the above R 3a It is synonymous with [the above]. 【0243】 R 1a Each of these C atoms may be independently substituted, preferably with a halogen atom. 1-6 Alkyl or aryl group, more preferably C 1-6It is an alkyl group or an aryl group. 【0244】 In one embodiment, R 1a Each of them is independent of C 1-6 Alkyl alkyl group, preferably C 1-3 An alkyl group, more preferably a methyl group. 【0245】 In another embodiment, R 1a This is a phenyl group. 【0246】 In another embodiment, R 1a This is a methyl group or a phenyl group, preferably a methyl group. 【0247】 The above a1 is between 2 and 1500. a1 is preferably 5 or more, more preferably 10 or more, even more preferably 15 or more, for example 30 or more, or 50 or more. a1 is preferably 1000 or less, more preferably 500 or less, even more preferably 200 or less, even more preferably 150 or less, for example 100 or less, or 80 or less. 【0248】 a1 can preferably be 5 to 1000, more preferably 10 to 500, even more preferably 15 to 200, and even more preferably 15 to 150. 【0249】 Another silicone oil is (3b) below: R 1a -R SO2 -R 3a ...(3b) [wherein: R 1a Each of these is independently a hydrocarbon group, and R 3a Each of these is independently a hydrocarbon group, and R SO2 This is a divalent siloxane-containing group, preferably -R S -SiR 75 2 - and R S The formula is as follows: [In the formula: R 73 Each of them is independently a single bond, C 1-12 Alkylene group, -R 76 -O-R 76 -, -R 78 -R 77 -R 78 -, -R78 -R 77 -R 79 -R 77 -R 78 -, -R 78 -R 77 -R 79 -R 76 -R 79 -R 77 -R 78 -, or -R 79 -R 76 -R 79 -R 77 -R 79 -R 76 -R 79 - and R 74 Each of them is independent of C 1-12 Alkylene group, -R 76 -O-R 76 -, -R 78 -R 77 -R 78 -, -R 78 -R 77 -R 79 -R 77 -R 78 -, -R 78 -R 77 -R 79 -R 76 -R 79 -R 77 -R 78 -, or -R 79 -R 76 -R 79 -R 77 -R 79 -R 76 -R 79 - and R 76 Each of them is independent of C 1-6 It is an alkylene group, R 77 Each of these is independently a phenylene group or a naphthylene group, which may be substituted, and R 78 Each of these is independently a single bond, or C 1-6 It is an alkylene group, R 79 Each of these is independently a single bond or an oxygen atom, and R 75Each of the following is an independent hydrocarbon group, where x is an integer from 0 to 500, y is an integer from 0 to 500, z is an integer from 0 to 500, x + y + z is 1 or greater, and the order of existence of each repeating unit enclosed in parentheses with x, y, or z is arbitrary in the formula. This is a group represented by ]. Examples of compounds represented by ] are shown. 【0250】 The above-mentioned silicone oil may have an average molecular weight of 500 to 1,000,000, preferably 1,000 to 100,000. The molecular weight of the silicone oil can be measured using GPC. 【0251】 Examples of the above silicone oil include -(SiR 3a 2 -O) a1 A linear or cyclic silicone oil in which a1 is 30 or less may be used. Linear silicone oils may be so-called straight silicone oils and modified silicone oils. Examples of straight silicone oils include dimethyl silicone oil, methylphenyl silicone oil, and methylhydrogen silicone oil. Examples of modified silicone oils include straight silicone oils modified with alkyl, aralkyl, polyether, higher fatty acid ester, fluoroalkyl, amino, epoxy, carboxyl, alcohol, etc. An example of a cyclic silicone oil is cyclic dimethylsiloxane oil. 【0252】 The above-mentioned silicone oil may be included in the composition of the present disclosure in an amount of, for example, 0 to 50% by mass, preferably 0.001 to 30% by mass, and more preferably 0.1 to 5% by mass. 【0253】 In the compositions of the present disclosure, such silicone oil may be included in an amount of, for example, 0 to 300 parts by mass, preferably 0 to 100 parts by mass, more preferably 0 to 50 parts by mass, and even more preferably 0 to 10 parts by mass, based on 100 parts by mass of the total of the compounds of the present disclosure (the sum of the two or more compounds, and so on). 【0254】 Silicone oil contributes to improving the surface lubricity of the surface-treated layer. 【0255】 Examples of catalysts include acids (e.g., acetic acid, hydrochloric acid, nitric acid, sulfuric acid, phosphoric acid, sulfonic acid, p-toluenesulfonic acid, trifluoroacetic acid, etc.), bases (e.g., sodium hydroxide, potassium hydroxide, ammonia, triethylamine, diethylamine, etc.), transition metals (e.g., Ti, Ni, Sn, Zr, Al, B, Si, Ta, Nb, Mo, W, Cr, Hf, V, etc.), sulfur-containing compounds having lone pairs of electrons in their molecular structure, or nitrogen-containing compounds (e.g., sulfoxide compounds, aliphatic amine compounds, aromatic amine compounds, phosphate amide compounds, amide compounds, urea compounds, etc.). 【0256】 Examples of the above-mentioned aliphatic amine compounds include diethylamine and triethylamine. Examples of the above-mentioned aromatic amine compounds include aniline and pyridine. 【0257】 In a preferred embodiment, the transition metal is included as a transition metal compound represented by M-R (wherein M is a transition metal atom and R is a hydrolyzable group). By making the transition metal compound a compound in which a transition metal and a hydrolyzable group are bonded, transition metal atoms can be more efficiently incorporated into the surface treatment layer, further improving the friction durability and chemical resistance of the surface treatment layer. 【0258】 The above-mentioned hydrolyzable group refers to a group that can undergo hydrolysis, similar to the hydrolyzable group relating to the above-mentioned compound; that is, a group that can be removed from the transition metal atom by hydrolysis. Examples of hydrolyzable groups include -OR m , -OCOR m -O-N=CR m 2 , -NR m 2 , - NHR m , -NCO, halogen (in these formulas, R m C is either substituted or non-substituted. 1-4 Examples include (indicating an alkyl group). 【0259】 In a preferred embodiment, the hydrolyzable group is -OR mThe alkoxy group is preferably methoxy or ethoxy. By using an alkoxy group as the hydrolyzable group, transition metal atoms can be more efficiently incorporated into the surface treatment layer, further improving the friction durability and chemical resistance of the surface treatment layer. 【0260】 In one embodiment, the hydrolyzable group may be the same as the hydrolyzable group contained in the compound described above. By making the hydrolyzable group in the compound and the transition metal compound the same, the effect can be reduced even if such hydrolyzable groups are exchanged with each other. 【0261】 In another embodiment, the hydrolyzable group may be different from the hydrolyzable group contained in the compound described above. By making the hydrolyzable group in the compound different from that in the transition metal compound, the reactivity of hydrolysis can be controlled. 【0262】 In one embodiment, the hydrolyzable group and the hydrolyzable group contained in the compound may be interchangeable in the composition. 【0263】 In a preferred embodiment, the transition metal compound is Ta(OR m ) 5 (In the formula, R m C is either substituted or non-substituted. 1-4 It is an alkyl group.) Preferably Ta(OCH 2 CH 3 ) 5 , or Si (OR m ) 1-m1 R m’ m1 (In the formula, R m C is either substituted or non-substituted. 1-4 It is an alkyl group, R m’ C 1-4 It is an alkyl group, and m1 is 0 or 1. Preferably, it may be tetraethoxysilane, methyltrimethoxysilane, methyltriethoxysilane, tetraisopropoxysilane, dimethyldiethoxysilane, or dimethyldimethoxysilane. 【0264】The catalyst may be present in the composition in an amount of, for example, 0.0002% by mass or more. Preferably, the catalyst is present in an amount of 0.02% by mass or more, and more preferably 0.04% by mass or more, relative to the total composition. The catalyst may be present in an amount of, for example, 10% by mass or less, and particularly 1% by mass or less, relative to the total composition. The composition of this disclosure, by containing the catalyst at the above concentrations, can contribute to the formation of a surface treatment layer with better durability. 【0265】 The content of the catalyst is preferably 0 to 10% by mass, more preferably 0 to 5% by mass, and particularly preferably 0 to 1% by mass, relative to the compound of this disclosure. 【0266】 The catalyst promotes the hydrolysis and dehydration condensation of the compounds of the Disclosure, thereby facilitating the formation of the layer formed by the composition of the Disclosure. 【0267】 Other components besides those listed above include, for example, tetraethoxysilane, methyltrimethoxysilane, 3-aminopropyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, and methyltriacetoxysilane. 【0268】 In addition to the components described above, the compositions of this disclosure may contain trace amounts of impurities such as Pt, Rh, Ru, 1,3-divinyltetramethyldisiloxane, triphenylphosphine, NaCl, KCl, and silane condensates. 【0269】 In one embodiment, the surface treatment agent of the present disclosure is for a dry coating method, preferably for vacuum deposition. 【0270】 In one embodiment, the surface treatment agent of the present disclosure is for wet coating, preferably immersion coating. 【0271】 The surface treatment agent disclosed herein can be impregnated into porous materials, such as porous ceramic materials, or metal fibers, such as steel wool compressed into a cotton-like form, to form pellets. These pellets can be used, for example, in vacuum deposition. 【0272】 [Articles] The articles of this disclosure are described below. 【0273】The articles of this disclosure include a substrate and a layer (surface treatment layer) formed on the surface of the substrate from the composition of this disclosure (e.g., a surface treatment agent). 【0274】 The substrates usable in this disclosure may consist of, for example, glass, resin (natural or synthetic resin, such as common plastic materials), metal, ceramics, semiconductors (silicon, germanium, etc.), fibers (textiles, nonwovens, etc.), fur, leather, wood, ceramics, stone, building materials, sanitary products, or any other suitable material. 【0275】 For example, if the article to be manufactured is an optical component, the material constituting the surface of the substrate may be an optical component material, such as glass or transparent plastic. Also, if the article to be manufactured is an optical component, some layer (or film), such as a hard coat layer or an anti-reflective layer, may be formed on the surface (outermost layer) of the substrate. Either a single-layer anti-reflective layer or a multi-layer anti-reflective layer may be used for the anti-reflective layer. An example of an inorganic material that can be used for the anti-reflective layer is SiO 2 SiO, ZrO 2 , TiO 2 ,TiO,Ti 2 O 3 Ti 2 O 5 Al 2 O 3 Ta 2 O 5 Ta 3 O 5 , Nb 2 O 5 , HfO 2 Si 3 N 4 , CEO 2 , MgO, Y 2 O 3 , SnO 2 MgF 2 WO 3 These are some examples. These inorganic materials may be used individually or in combination of two or more (for example, as a mixture). When a multilayer anti-reflective layer is used, the outermost layer is SiO 2It is preferable to use and / or SiO. If the article to be manufactured is an optical glass component for a touch panel, a thin film using a transparent electrode, such as indium tin oxide (ITO) or indium zinc oxide, may be present on a part of the surface of the substrate (glass). The substrate may also have an insulating layer, an adhesive layer, a protective layer, a decorative frame layer (I-CON), an atomizing film layer, a hard coating film layer, a polarizing film, a phase difference film, and a liquid crystal display module, depending on its specific specifications. 【0276】 The shape of the substrate is not particularly limited and may be, for example, a plate, a film, or other form. Furthermore, the surface area of the substrate on which the surface treatment layer is to be formed may be at least a part of the substrate surface and can be appropriately determined according to the intended use and specific specifications of the article to be manufactured. 【0277】 In one embodiment, the substrate may consist of a material that originally has hydroxyl groups, at least on its surface. Examples of such materials include glass, metals (especially base metals) on which a native oxide film or thermal oxide film is formed on the surface, ceramics, semiconductors, etc. Alternatively, if the material has insufficient hydroxyl groups, such as resins, or if it does not originally have hydroxyl groups, the substrate can be pretreated to introduce or increase hydroxyl groups on its surface. Examples of such pretreatment include plasma treatment (e.g., corona discharge) and ion beam irradiation. Plasma treatment can introduce or increase hydroxyl groups on the substrate surface and can also be suitably used to clean the substrate surface (remove foreign matter, etc.). Another example of such pretreatment is a method in which an interfacial adsorbent having carbon-carbon unsaturated bond groups is formed in the form of a monolayer on the substrate surface by the LB method (Langmuir-Bludget method) or chemical adsorption method, and then the unsaturated bonds are cleaved in an atmosphere containing oxygen or nitrogen. 【0278】 In another embodiment, such a substrate may consist of a material in which at least its surface portion is made of another reactive group, such as a silicone compound having one or more Si-H groups, or an alkoxysilane. 【0279】In a preferred embodiment, the substrate is glass. Preferred glass includes sapphire glass, soda-lime glass, alkali aluminosilicate glass, borosilicate glass, alkali-free glass, crystal glass, quartz glass, and crystallized glass, with chemically strengthened soda-lime glass, chemically strengthened alkali aluminosilicate glass, and chemically bonded borosilicate glass being particularly preferred. 【0280】 In one embodiment, the article of the present disclosure may include an intermediate layer containing silicon oxide between the substrate and the surface treatment layer. By providing such an intermediate layer, the adhesion between the substrate (e.g., glass) and the surface treatment layer is improved, and the durability is enhanced. 【0281】 In a preferred embodiment, the intermediate layer may contain an alkali metal in addition to silicon oxide. 【0282】 Examples of the alkali metals mentioned above include lithium, sodium, and potassium. Preferably, at least a portion of the alkali metal is sodium. 【0283】 The thickness of the intermediate layer is not particularly limited, but is preferably 1 to 200 nm, and particularly preferably 1 to 20 nm. By setting the thickness of the intermediate layer to be above the lower limit of the above range, the effect of improving adhesion by the intermediate layer is further enhanced. 【0284】 The silicon dioxide intermediate layer described above can be formed by applying a silicon dioxide precursor to the surface of the substrate. If the intermediate layer contains alkali metal atoms, it can be formed by applying a composition containing a silicon dioxide precursor and an alkali metal source to the surface of the substrate. 【0285】Examples of silicon oxide precursors include silicic acid, partial condensates of silicic acid, alkali metal silicates, silane compounds having a hydrolyzable group bonded to a silicon atom, and partial hydrolyzable condensates of the silane compounds. Silicic acid and its partial condensates can be dehydrated and condensed to produce silicon oxide, while alkali metal silicates can be converted to silicic acid or its partial condensates using an acid or cation exchange resin, and the resulting silicic acid or partial condensates can be dehydrated and condensed to produce silicon oxide. Examples of hydrolyzable groups in silane compounds having a hydrolyzable group bonded to a silicon atom include alkoxy groups and chlorine atoms. The hydrolyzable group in the silane compound can be hydrolyzed to a hydroxyl group, and the resulting silanol compound can be dehydrated and condensed to produce silicon oxide. Examples of silane compounds having a hydrolyzable group bonded to a silicon atom include alkoxysilanes such as tetraalkoxysilanes and alkyltrialkoxysilanes, and tetrachlorosilanes. 【0286】 Examples of alkali metal sources include alkali metal hydroxides and water-soluble alkali metal salts. Examples of water-soluble alkali metal salts include alkali metal carbonates, alkali metal bicarbonates, alkali metal hydrochlorides, and alkali metal nitrates. Alkali metal hydroxides and alkali metal carbonates are preferred as alkali metal sources. 【0287】 Furthermore, alkali metal silicates can be used as silicon oxide precursors and alkali metal sources. Alkali metal silicates can be converted to silicon oxide via silicic acid, but a small amount of alkali metal may remain in the silicon oxide produced during this process. Therefore, by adjusting the amount of residual alkali metal atoms, silicon oxide containing a predetermined amount of alkali metal atoms can be obtained. 【0288】 The alkali metal atom concentration in the intermediate layer can be measured using various surface analysis devices, such as TOF-SIMS, XPS, and XRF. 【0289】The proportion of alkali metal atoms in the total atoms of the intermediate layer can be obtained by XPS depth profiling using ion sputtering. This is done by repeatedly alternating between XPS measurement and surface etching using an ion gun built into the XPS instrument. 【0290】 In the intermediate layer, the average concentration of alkali metals in the region with a depth of 1 nm or less from the surface in contact with the surface treatment layer is determined by obtaining a depth profile of alkali metal atom concentrations using TOF-SIMS (time-of-flight secondary ion mass spectrometry) depth profiling by ion sputtering, and then calculating the average value of alkali metal atom concentrations in that profile. TOF-SIMS depth profiling by ion sputtering is performed by repeatedly alternating between TOF-SIMS measurement and surface etching using an ion gun built into the TOF-SIMS instrument. 【0291】 The articles of this disclosure can be manufactured by forming a layer of the surface treatment agent of this disclosure on the surface of the substrate, and post-treating this layer as necessary, thereby forming a layer from the surface treatment agent of this disclosure. 【0292】 Layer formation of the surface treatment agent of this disclosure can be carried out by applying the surface treatment agent to the surface of a substrate so as to cover the surface. The coating method is not particularly limited. For example, wet coating and dry coating methods can be used. 【0293】 Examples of wet coating methods include immersion coating, spin coating, flow coating, spray coating, roll coating, gravure coating, wipe coating, squeegee coating, die coating, inkjet, casting, Langmuir-Bludget method, and similar methods. 【0294】Examples of dry coating methods include vapor deposition (usually vacuum deposition), sputtering, CVD, and similar methods. Specific examples of vapor deposition methods (usually vacuum deposition) include resistance heating, electron beams, high-frequency heating using microwaves, ion beams, and similar methods. Specific examples of CVD methods include plasma CVD, optical CVD, thermal CVD, and similar methods. 【0295】 Furthermore, coating using the atmospheric pressure plasma method is also possible. 【0296】When using a wet coating method, the surface treatment agents of the present disclosure may be diluted with a solvent before being applied to the substrate surface. From the viewpoint of the stability of the composition of the present disclosure and the volatility of the solvent, the following solvents are preferably used: aliphatic hydrocarbons such as hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, and mineral spirits; aromatic hydrocarbons such as benzene, toluene, xylene, naphthalene, and solvent naphtha; methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate, isobutyl acetate, cellosolve acetate, propylene glycol methyl ether acetate, and carboxymethyl acetate. Esters such as tol, diethyl oxalate, ethyl pyruvate, ethyl-2-hydroxybutyrate, ethyl acetacetate, amyl acetate, methyl lactate, ethyl lactate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 2-hydroxyisobutyrate, ethyl 2-hydroxyisobutyrate; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, 2-hexanone, cyclohexanone, methylaminoketone, 2-heptanone; ethyl cellosolve, methyl cellosol Glycol ethers such as methyl cellosolve acetate, ethyl cellosolve acetate, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monobutyl ether acetate, dipropylene glycol dimethyl ether, and ethylene glycol monoalkyl ether; alcohols such as methanol, ethanol, iso-propanol, n-butanol, isobutanol, tert-butanol, sec-butanol, 3-pentanol, octyl alcohol, 3-methyl-3-methoxybutanol, and tert-amyl alcohol; glycols such as ethylene glycol and propylene glycol; cyclic ethers such as tetrahydrofuran, tetrahydropyran, and dioxane; amides such as N,N-dimethylformamide, N,N-dimethylacetamide, and N-methylpyrrolidone;Ether alcohols such as methyl cellosolve, cellosolve, isopropyl cellosolve, butyl cellosolve, and diethylene glycol monomethyl ether; diethylene glycol monoethyl ether acetate; polyfluoroaromatic hydrocarbons (e.g., 1,3-bis(trifluoromethyl)benzene); polyfluoroaliphatic hydrocarbons (e.g., C; 6 F 13 CH 2 CH 3 (For example, AsahiClean® AC-6000 manufactured by Asahi Glass Co., Ltd.), 1,1,2,2,3,3,4-heptafluorocyclopentane (for example, Zeolora® H manufactured by Nippon Zeon Co., Ltd.); fluorinated hydrocarbons such as 1,1,2-trichloro-1,2,2-trifluoroethane, 1,2-dichloro-1,1,2,2-tetrafluoroethane, 1,1-dichloro-1,2,2,3,3-pentafluoropropane (HCFC225), and 1,3-bis(trifluoromethyl)benzene; CF 3 CH 2 OH, CF 3 CF 2 CH 2 OH, (CF 3 ) 2 Fluorine-containing alcohols such as CHOH; hydrofluoroethers (HFE) (e.g., perfluoropropyl methyl ether (C) 3 F 7 OCH 3 ) (For example, Novec® 7000 manufactured by Sumitomo 3M Limited), perfluorobutyl methyl ether (C 4 F 9 OCH 3 ) (For example, Novec™ 7100 manufactured by Sumitomo 3M Limited), perfluorobutyl ethyl ether (C 4 F 9 OC 2 H 5 ) (For example, Novec™ 7200 manufactured by Sumitomo 3M Limited), perfluorohexyl methyl ether (C 2 F 5 CF(OCH) 3 ) C 3 F 7) (for example, Novec™ 7300 manufactured by Sumitomo 3M Limited) or other alkyl perfluoroalkyl ethers (the perfluoroalkyl group and alkyl group may be linear or branched), or CF 3 CH 2 OCF 2 CHF 2 (For example, AsahiClean® AE-3000 manufactured by Asahi Glass Co., Ltd.), ethers such as cyclopentyl methyl ether; siloxanes such as hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, octamethylcyclotetrasiloxane, octamethylcyclopentasiloxane, decamethylcyclopentasiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane; dimethyl sulfoxide, etc. These solvents can be used alone or as a mixture of two or more. Among these, aliphatic hydrocarbons, esters, glycol ethers, alcohols, ether alcohols, and siloxanes are preferred. For example, hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, mineral spirits, methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate, isobutyl acetate, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, methanol, ethanol, iso-propanol, n-butanol, isobutanol, tert-butanol, sec-butanol, diethylene glycol monomethyl ether, hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane, octamethylcyclotetrasiloxane, and octamethylcyclopentasiloxane are preferred. 【0297】 In one aspect, when using the wet coating method, the solvent is, for example, R 90 Compounds represented by -OH can be used. 90 is a monovalent organic group, preferably C 1-20 Alkyl alkyl group or C 3-20These are alkylene groups, and these groups may be substituted with one or more substituents. Examples of substituents include hydroxyl groups, -OR 91 (Here, R 91 is C 1-10 Alkyl alkyl group, preferably C 1-3 Examples include alkyl groups (for example, a methyl group). 【0298】 When using the dry coating method, the surface treatment agent of this disclosure may be subjected to the dry coating method as is, or it may be diluted with the solvent described above before being subjected to the dry coating method. 【0299】 The layer formation of the surface treatment agent is preferably carried out such that the surface treatment agent of the present disclosure is present in the layer together with a catalyst for hydrolysis and dehydration condensation. For convenience, in the case of a wet coating method, the surface treatment agent of the present disclosure may be diluted with a solvent, and the catalyst may be added to the diluted solution of the surface treatment agent of the present disclosure immediately before application to the substrate surface. In the case of a dry coating method, the surface treatment agent of the present disclosure with the catalyst added may be directly vapor-deposited (usually by vacuum deposition), or a pellet-like material impregnated with the surface treatment agent of the present disclosure with the catalyst added may be used for vapor deposition (usually by vacuum deposition). 【0300】 Any suitable acid or base, transition metals (e.g., Ti, Ni, Sn, Zr, Al, B, etc.), sulfur-containing compounds having lone pairs of electrons in their molecular structure, or nitrogen-containing compounds (e.g., sulfoxide compounds, aliphatic amine compounds, aromatic amine compounds, phosphate amide compounds, amide compounds, urea compounds, etc.) can be used as catalysts. Examples of acid catalysts include acetic acid, formic acid, trifluoroacetic acid, hydrochloric acid, nitric acid, sulfuric acid, phosphoric acid, sulfonic acid, methanesulfonic acid, and p-toluenesulfonic acid. Examples of base catalysts include ammonia, sodium hydroxide, potassium hydroxide, and organic amines such as triethylamine and diethylamine. Examples of transition metals, aliphatic amine compounds, and aromatic amine compounds are the same as those mentioned above. 【0301】The surface treatment layer included in the articles of this disclosure may have high abrasion resistance. In addition to high abrasion resistance, the surface treatment layer may also have water repellency, oil repellency, stain resistance (e.g., preventing the adhesion of dirt such as fingerprints), waterproofness (preventing water from entering electronic components, etc.), surface slipperiness (or lubricity, e.g., ease of wiping away dirt such as fingerprints and excellent tactile feel to the fingers), and chemical resistance, and may be suitably used as a functional thin film. 【0302】 Accordingly, this disclosure also relates to optical materials having the above-mentioned surface treatment layer as the outermost layer. 【0303】 As optical materials, a wide variety of optical materials are preferred, in addition to optical materials related to displays, as exemplified below: for example, displays such as cathode ray tubes (CRTs; e.g., PC monitors), liquid crystal displays, plasma displays, organic EL displays, inorganic thin-film EL dot matrix displays, rear projection displays, fluorescent display tubes (VFDs), and field emission displays (FEDs), or protective plates for such displays, or materials on which an anti-reflective coating has been applied to their surface. 【0304】 The articles of this disclosure may be optical components, but are not limited to these. Examples of optical components include: lenses such as those in eyeglasses; front protective plates, anti-reflective plates, polarizing plates, and anti-glare plates for displays such as PDPs and LCDs; touch panel sheets for devices such as mobile phones and personal digital assistants; disc surfaces of optical discs such as Blu-ray (registered trademark) discs, DVD discs, CD-Rs, and MOs; optical fibers; and display surfaces of watches. 【0305】 Furthermore, the articles of this disclosure may be medical devices or medical materials. Also, articles having layers obtained by this disclosure may be automotive interior and exterior components. Examples of exterior components include: windows, light covers, and exterior camera covers. Examples of interior components include: instrument panel covers, navigation system touch panels, and decorative interior components. 【0306】The thickness of the above layer is not particularly limited. In the case of optical components, the thickness of the above layer may be in the range of, for example, 1 to 50 nm, preferably 1 to 30 nm, and more preferably 1 to 15 nm, from the viewpoint of optical performance, abrasion resistance, and antifouling properties. 【0307】 For X-ray photoelectron spectroscopy (XPS) analysis to measure the atomic composition and constituent atom ratios of the surface treatment layer, the PHI5000VersaProbeII from ULVAC-PHI can be used. XPS analysis conditions include a 25W monochromatic AlKα X-ray source, a 1400 μm × 300 μm photoelectron detection area, a photoelectron detection angle in the range of 20 to 90 degrees (e.g., 20, 45, 90 degrees), and a pass energy of 23.5 eV. For sputtering, gas cluster ion beams or Ar ions can be used. Using the above apparatus and measurement conditions, the peak areas of C1s, O1s, and Si2p can be observed, and the atomic ratios of carbon, oxygen, and silicon can be calculated to determine the composition of the surface treatment layer and the intermediate layer. 【0308】 Furthermore, depth analysis can also be performed. For XPS analysis, the measurement conditions include using a monochromatic AlKα X-ray source at 25W, a photoelectron detection area of 1400 μm × 300 μm, a photoelectron detection angle in the range of 20 to 90 degrees (e.g., 20 degrees, 45 degrees, 90 degrees), and a pass energy of 23.5 eV. Ar ions, gas cluster ions, C60 ions, etc., can be used as sputtering ions. Etching from 1 to 100 nm by sputtering can also be performed to obtain the composition of the coating film at each etching depth. 【0309】 By adjusting the photoelectron detection angle in the XPS analysis described above, the detection depth can be adjusted as needed. For example, by setting a shallow angle close to 20 degrees, the detection depth can be set to about 3 nm, while by setting a deep angle close to 90 degrees, the detection depth can be set to about 10-something nm. 【0310】The silicon dioxide-containing intermediate layer described above can be formed by applying a silicon dioxide precursor to the surface of the substrate. If the intermediate layer contains an alkali metal, it can be formed by applying a composition containing a silicon dioxide precursor and an alkali metal source to the surface of the substrate. 【0311】 Examples of silicon oxide precursors include silicic acid, partial condensates of silicic acid, alkali metal silicates, silane compounds having a hydrolyzable group bonded to a silicon atom, and partial hydrolyzable condensates of the silane compounds. Silicic acid and its partial condensates can be dehydrated and condensed to produce silicon oxide, while alkali metal silicates can be converted to silicic acid or its partial condensates using an acid or cation exchange resin, and the resulting silicic acid or partial condensates can be dehydrated and condensed to produce silicon oxide. Examples of hydrolyzable groups in silane compounds having a hydrolyzable group bonded to a silicon atom include alkoxy groups and chlorine atoms. The hydrolyzable group in the silane compound can be hydrolyzed to a hydroxyl group, and the resulting silanol compound can be dehydrated and condensed to produce silicon oxide. Examples of silane compounds having a hydrolyzable group bonded to a silicon atom include alkoxysilanes such as tetraalkoxysilanes and alkyltrialkoxysilanes, and tetrachlorosilanes. 【0312】 Examples of alkali metal sources include alkali metal hydroxides and water-soluble alkali metal salts. Examples of water-soluble alkali metal salts include alkali metal carbonates, alkali metal bicarbonates, alkali metal hydrochlorides, and alkali metal nitrates. Alkali metal hydroxides and alkali metal carbonates are preferred as alkali metal sources. 【0313】 Furthermore, alkali metal silicates can be used as silicon oxide precursors and alkali metal sources. Alkali metal silicates can be converted to silicon oxide via silicic acid, but a small amount of alkali metal may remain in the silicon oxide produced during this process. Therefore, by adjusting the amount of residual alkali metal, silicon oxide containing a predetermined amount of alkali metal atoms can be obtained. 【0314】The thickness of the above-mentioned intermediate layer is not particularly limited, but is, for example, in the range of 1 to 50 nm, preferably 1 to 30 nm, more preferably 2 to 15 nm, and even more preferably 3 to 10 nm. 【0315】 The silane compounds, surface treatment agents containing said silane compounds, and articles obtained using said surface treatment agents have been described in detail above. However, this disclosure is not limited to those exemplified above. 【0316】 The present disclosure will be described below with reference to examples, but the present disclosure is not limited to the following examples. 【0317】 (Synthesis Example 1) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 2.0 g of OH (average molecular weight 4,800) and 0.48 mL of (3-isocyanatopropyl)trimethoxysilane were added, and the mixture was stirred at 55°C for 1 hour, then at 65°C for 3 hours, and then at 70°C for 5 hours. After washing with methanol, the mixture was concentrated to obtain 1.5 g of compound (1). 【0318】 Compound (1) (n is 60.) 【0319】 1H-NMR (400 MHz, CHLOROFORM-D) δ 4.87 (s, 1H), 4.20-4.18 (t, 2H), 3.60-3.53 (m, 9H), 3.43-3.40 (t, 2H), 3.30-3.26 (t, 2H), 3.18-3.13 (m, 2H), 1.75-1.69 (m, 2H), 1.64-1.58 (m, 2H), 1.34-1.24 (m, 4H), 0.89-0.85 (t, 3H), 0.69-0.60 (m, 2H), 0.54-0.49 (m, 4H), 0.21 - -0.09 (m) 【0320】 (Synthesis Example 2) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -NH 2 2.0 g of (average molecular weight 2,000) and 1.0 mL of (3-isocyanatopropyl)trimethoxysilane were added, and the mixture was stirred at 55°C for 1 hour, then at 65°C for 3 hours, and then at 70°C for 5 hours. After washing with methanol, the mixture was concentrated to obtain 1.4 g of compound (2). 【0321】 Compound (2) (n is 25.) 【0322】 1 H-NMR (400 MHz, CHLOROFORM-D) δ 6.02 (br, 2H), 3.60-3.53 (m, 9H), 3.43-3.40 (m, 4H), 1.75-1.69 (m, 2H), 1.64-1.58 (m, 4H), 1.34-1.24 (m, 4H), 0.89-0.85 (t, 3H), 0.69-0.60 (m, 2H), 0.54-0.49 (m, 2H), 0.21 - -0.09 (m) 【0323】 (Synthesis Example 3) ((CH 3 )3 SiO) 2 SiCH 3 (CH 2 ) 3 O(CH 2 CH 2 O) 10 3.01 g of H, 19.9 ml of acetonitrile, 0.92 g of (3-isocyanatopropyl)trimethoxysilane, and 0.03 g of dibutyltin dilaurate were added and the mixture was stirred at 60°C for 6 hours. Subsequently, the compound (3) ((CH) was purified. 3 ) 3 SiO) 2 SiCH 3 (CH 2 ) 3 O(CH 2 CH 2 O) 10 CONHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 2.56 g was obtained. 【0324】 Compound (3) 【0325】 1 H-NMR (400 MHz, CHLOROFORM-D) δ[ppm]: -0.099 (s), -0.030-0.015 (s), 0.309-0.352 (m), 0.507-0.549 (t), 1.426-1.531 (m), 3.022-3.073 (t), 3.283-3.319 (t), 3.448-3.618 (m), 3.666-3.780 (m), 4.082-4.105 (m), 【0326】 Compound (4): monoTRIETHOXYSILYLETHYL-TERMINATED POLYDIMETHYLSILOXANE (MCR-XT11, manufactured by Gelest, Inc.) was used. 【0327】 <Preparation of Surface Treatment Agent> The surface treatment agent was prepared by dissolving the compound in a solvent as shown in Table 1. The concentration of the compound in the solvent was 20% by weight. 【0328】 【0329】 <Formation of Intermediate and Surface Treatment Layers> The surface treatment agent prepared above was vacuum deposited onto chemically strengthened glass (Corning Gorilla Glass, 0.7 mm thick). Specifically, 0.1 g of the surface treatment agent was filled into a molybdenum boat in the vacuum deposition apparatus, and the inside of the vacuum deposition apparatus was subjected to a pressure of 3.0 × 10⁻¹⁰ -3 The pressure was reduced to below Pa. Then, silicon dioxide was deposited using an electron beam deposition method, followed by heating the boat using a resistance heating method to form a surface treatment layer. After that, the surface treatment layer was obtained by heating it in an oven at 150°C for 1 hour. 【0330】 <Evaluation of Slipperiness> To evaluate the tactile feel, the coefficient of dynamic friction was measured using a Labthink FPT-F1. After forming the surface treatment layer, the excess on the surface was wiped off with ethanol, and then the coefficient of dynamic friction was measured. The measurement conditions are as follows: Friction material: Urethane sheet (thickness 2 mm) Contact surface: 2 cm Load: 200 gf Friction speed: 5 mm / sec 【0331】 (Evaluation criteria for slipperiness) Less than 0.5: 3 (Excellent) 0.5 or more and less than 1.0: 2 (Good) 1.0 or more: 1 (Poor) 【0332】 The evaluation results for slipperiness are shown in Table 2. 【0333】 【0334】 The silane compounds, compositions containing silane compounds, and articles of this disclosure can be suitably used in a wide variety of applications.
Claims
Equation (1): [In the formula: R 1 Each of these is a monovalent group containing one or more Si atoms that are not directly bonded to a hydroxyl group or a hydrolyzable group. X 1 This is a 2-10 valent organic group having at least one urethane bond, or a 2-10 valent organic group having at least one urea bond. R Si This is a monovalent group containing one Si atom to which a hydroxyl group or hydrolyzable group is bonded. α is an integer between 1 and 9. A silane compound represented by the formula. R 1 is R 41 -(SiR 42 2 O) n1 -SiR 42 2 -(O) z0 represented by, n1 is an integer greater than or equal to 1, z0 is either 0 or 1. R 41 and R 42 Each of them is independent of C 1-12 It is an alkyl group, a phenyl group, or a (A) group, The aforementioned (A) group is given by the following formula: [In the formula: R 51 Each of them is independent of R 53 - (SiR 53 2 -R 61 ) ma It is a base represented by -, R 61 Each of these independently comprises a single bond, an oxygen atom, or C 1-6 It is an alkylene group, R 53 Each of these is independently a hydrocarbon group or R 51’ And, R 51’ R 51 It is synonymous with, However, R 51 Medium, R 51’ The number is 20 or less, Each of ma is an independent integer between 1 and 5. R 52 Each of these is independently a hydrocarbon group, na is an integer from 1 to 3. z is either 0 or 1. The base represented by The silane compound according to claim 1. X 1 Furthermore, -CO-, -COO-, -NR 2 -, -O-, -S-, -O-(CH 2 ) x -CONR 2 - or -O-(CH 2 ) x Including -CO-, R 2 is a hydrogen atom or a monovalent organic group, x is an integer between 1 and 100. The silane compound according to claim 1 or 2. α is 1, X 1 is, -(C s H 2s ) s1 - (X s ) s3 - (X U ) s4 - [In the formula: Each of s is an independent integer greater than or equal to 1. s1 is an integer greater than or equal to 1, X s These are divalent groups other than alkylene groups and urethane bonds, s3 is a non-negative integer, X U It is a urethane bond, s4 is an integer greater than or equal to 1, Here, the order of the bases enclosed in parentheses is not particularly limited. A silane compound according to any one of claims 1 to 3, wherein the divalent organic group is represented by . The silane compound according to claim 4, wherein s4 is 1. X 1 teeth, It is a base represented by, X L1 These are carbon atoms, silicon atoms, or nitrogen atoms. γ1 is an integer between 1 and 3. γ2 is an integer between 0 and 2. However, the sum of γ1 and γ2 is X L1 The value of the valence -1, R L1 Each is independent of the other, -(C s H 2s ) s11’ - (X s ) s13’ - (X U ) s14’ It is represented by -, R L2 Each is independent of the other, -(C s H 2s ) s11” - (X s ) s13” - (X U ) s14” It is represented by -, s is an integer greater than or equal to 1, s11', s13', s14', s11'', s13'', and s14'' are each independent integers of 0 or greater. At least one of s14' and s14'' is an integer of 1 or more. X s These are, independently, divalent groups other than alkylene groups and urethane bonds. X U It is a urethane bond, R L1 and R L2 In this context, the order of existence of each repeating unit enclosed in parentheses is not particularly limited. R Z Each of these is independently a hydrogen atom or a hydrocarbon group. A silane compound according to any one of claims 1 to 3. The silane compound according to claim 6, wherein at least one of s14' and s14'' is 1. The silane compound according to claim 6, wherein s14'' is 1. α is 1, X 1 is, -(C s H 2s ) s1 - (X s1 ) s5 - (X U1 ) s6 - [In the formula: Each of s is an independent integer greater than or equal to 1. s1 is an integer greater than or equal to 1, X s1 These are divalent groups other than alkylene groups and urea bonds, s5 is a non-negative integer, X U1 This is a urea bond, s6 is an integer greater than or equal to 1, Here, the order of the bases enclosed in parentheses is not particularly limited. A silane compound according to any one of claims 1 to 3, wherein the divalent organic group is represented by . The silane compound according to claim 9, wherein s5 is 1. X 1 teeth, It is a base represented by, X L1 These are carbon atoms, silicon atoms, or nitrogen atoms. γ1 is an integer between 1 and 3. γ2 is an integer between 0 and 2. However, the sum of γ1 and γ2 is X L1 The value of the valence -1, R L1 is, independently of each other, -(C s H 2s ) s11’ -(X s1 ) s51’ -(X U1 ) s61’ represented by, R L2 is each independently represented by -(C s H 2s ) s11” -(X s1 ) s51” -(X U1 ) s61” and is represented by - s is an integer greater than or equal to 1, s11', s51', s61', s11'', s51'', and s61'' are each independent integers of 0 or greater. At least one of s61' and s61'' is an integer of 1 or more. X s1 These are, independently, divalent groups other than alkylene groups and urea bonds. X U1 This is a urea bond, R L1 and R L2 In this context, the order of existence of each repeating unit enclosed in parentheses is not particularly limited. R Z Each of these is independently a hydrogen atom or a hydrocarbon group. A silane compound according to any one of claims 1 to 3. The silane compound according to claim 11, wherein at least one of s61' and s61'' is 1. The silane compound according to claim 11, wherein s61'' is 1. R Si These are, independently, equation (S1): [In the formula: R 11 Each of these is independently a hydroxyl group or a hydrolyzable group, R 12 Each of these is independently a monovalent organic group, j1 is an integer between 0 and 3. Represented by, A silane compound according to any one of claims 1 to 13. The silane compound according to any one of claims 1 to 14, which is one of the following: CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [television] 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [television] 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [television] 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 (It is an alkyl group or a phenyl group.) [television] 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 (It is an alkyl group or a phenyl group.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 OC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 OC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 (It is an alkyl group or a phenyl group.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [television] 3 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [television] 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [television] 3 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 (It is an alkyl group or a phenyl group.) [television] 3 CH 2 CH 2 CH 2 -[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 (It is an alkyl group or a phenyl group.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -NHC(=O)NHCH 2 CH 2 OC(=O)CH(CH 3 )CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 ] 3 C-CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is an integer between 1 and 500.) [[(CH 3 ) 3 SiO] 2 (CH 3 )SiO-[(Si(CH 3 ) 2 O) n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 -] 2 CR[CH 2 -NHC(=O)NHCH 2 CH 2 CH 2 Si(OCH) 3 ) 3 ] (In the formula, n1 is an integer from 1 to 500, and R is C 1-30 (It is an alkyl group or a phenyl group.) [(CH 3 ) 3 SiO] 2 SiCH 3 -CH 2 CH 2 CH 2 O-(CH 2 CH 2 O) n6 -CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 -Si(OCH) 3 ) 3 (In the formula, n6 is between 1 and 30.) The silane compound according to any one of claims 1 to 15, which is one of the following: CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is between 10 and 100.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -NHC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is between 10 and 100.) [(CH 3 ) 3 SiO] 2 SiCH 3 -CH 2 CH 2 CH 2 O-(CH 2 CH 2 O) n6 -CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 -Si(OCH) 3 ) 3 (In the formula, n6 is between 1 and 30.) The silane compound according to any one of claims 1 to 16, which is one of the following: CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -O-CH 2 CH 2 -OC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is 60.) CH 3 CH 2 CH 2 CH 2 -[Si(CH 3 ) 2 O] n1 Si(CH 3 ) 2 -CH 2 CH 2 CH 2 -NHC(=O)NH-CH 2 CH 2 CH 2 Si(OCH) 3 ) 3 (In the formula, n1 is 25.) [CH] 3 ) 3 SIO 2 SiCH 3 -CH 2 CH 2 CH 2 O-(CH) 2 CH 2 O) 9 -CH 2 CH 2 -OC(=0)NH-CH 2 CH 2 CH 2 -Si(OCH) 3 ) 3 A composition comprising the silane compound described in any one of claims 1 to 17. A composition comprising a condensate of a silane compound according to any one of claims 1 to 17. A surface treatment agent comprising the composition according to claim 18 or 19. Furthermore, the surface treatment agent according to claim 20, comprising a solvent. The surface treatment agent according to claim 21, wherein the solvent is at least one selected from aliphatic hydrocarbons, aromatic hydrocarbons, esters, ketones, glycol ethers, ethers, and siloxanes. The surface treatment agent according to claim 22, wherein the aliphatic hydrocarbon is at least one selected from hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, and mineral spirits. The surface treatment agent according to claim 22, wherein the esters are at least one selected from methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate, and isobutyl acetate. The surface treatment agent according to claim 22, wherein the siloxanes are at least one selected from hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane, octamethylcyclotetrasiloxane, and octamethylcyclopentasiloxane. A surface treatment agent according to any one of claims 20 to 25, for use in vacuum deposition. A surface treatment agent according to any one of claims 20 to 25, for wet coating. A pellet containing a surface treatment agent according to any one of claims 20 to 26. An article comprising a base material and a layer formed on the base material from a surface treatment agent according to any one of claims 20 to 27. The article according to claim 29, further comprising an intermediate layer containing silicon dioxide between the substrate and the layer. The article according to claim 30, wherein the intermediate layer contains alkali metal atoms. The article according to claim 31, wherein at least a portion of the alkali metal atoms are sodium atoms. An article according to any one of claims 29 to 32, which is an optical component. An article according to any one of claims 29 to 33, which is a display.