Method for producing positive electrode active material for nonaqueous electrolyte secondary battery, positive electrode active material for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery

A controlled heat-treatment process for lithium transition metal composite oxides with high Ni content stabilizes the crystal structure, addressing resistance and cycle characteristic issues, achieving high capacity and low resistance in non-aqueous electrolyte secondary batteries.

WO2026140977A1PCT designated stage Publication Date: 2026-07-02PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD

Patent Information

Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
Filing Date
2025-12-15
Publication Date
2026-07-02

AI Technical Summary

Technical Problem

Lithium transition metal composite oxides with high Ni content face issues of increased battery resistance and deteriorated cycle characteristics due to Mn dissolution and spinel phase precipitation during charging and discharging, which hinder achieving high battery capacity and improved cycle characteristics.

Method used

A manufacturing method involving controlled heat-treatment processes for a Ni-containing hydroxide and Li-containing compound, including specific temperature ranges and oxygen stream firing, to produce a lithium transition metal composite oxide with a stable crystal structure and high particle strength, minimizing Mn leaching and spinel phase formation.

Benefits of technology

The method enables high battery capacity with low resistance and improved cycle characteristics by stabilizing the crystal structure and preventing Mn dissolution, thus enhancing the performance of non-aqueous electrolyte secondary batteries.

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Abstract

Provided is a method for producing a positive electrode active material for a nonaqueous electrolyte secondary battery, which includes: a first firing step for heat-treating an Ni-containing hydroxide; a mixing step for mixing a fired product obtained in the first firing step and an Li-containing compound; and a second firing step for heat-treating the mixture obtained in the mixing step at a temperature of 600°C to 900°C inclusive. The method for producing a positive electrode active material for a nonaqueous electrolyte secondary battery is characterized in that: the Ni-containing hydroxide is represented by the composition formula Ni(1 - x - y - z)MnxAlyMz(OH)2 (0 < x ≤ 0.1, 0 ≤ y ≤ 0.05, 0 ≤ z ≤ 0.1, x + y + z ≤ 0.1); and the heating temperature in the first firing step is not lower than 200°C but lower than 350°C.
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