COMPOSITIONS AND METHODS FOR REDUCING ANIMAL HAIR AND ADHESION TO FABRIC

By adding cationic surfactants and polymers to fabric treatment compositions, the adhesion of animal hair to fabrics is substantially reduced, addressing electrostatic issues and maintaining fabric quality.

BR112025017566A2Pending Publication Date: 2026-07-07COLGATE PALMOLIVE CO
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Patent Information

Application Number
BR112025017566
Authority / Receiving Office
BR · BR
Patent Type
Applications
Current Assignee / Owner
Priority Date
2023-02-27
Filing Date
2024-02-27
Publication Date
2026-07-07

AI Technical Summary

Technical Problem

Existing fabric treatment compositions fail to effectively reduce the adhesion of animal hair, primarily due to electrostatic attractive forces between fabrics and hair, leading to hygiene and aesthetic issues.

Method used

Incorporating cationic surfactants and polymers, such as dialkyl ester triethanolammonium methyl sulfate, silicone, and acrylamide-diallyldimethylammonium chloride copolymer, into fabric treatment compositions to modify surface potential and reduce hair adhesion during the washing cycle.

Benefits of technology

The composition significantly reduces animal hair adhesion to fabrics, outperforming traditional methods like drying sheets, and maintains fabric softness and ease of ironing.

✦ Generated by Eureka AI based on patent content.

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Abstract

Described herein are fabric care compositions that reduce or prevent the adhesion of pet hair to fabric. Methods of making and using these compositions for reducing or preventing the adhesion of pet hair to fabric, are also described.
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Description

1 / 44 COMPOSITIONS AND METHODS FOR REDUCING ANIMAL HAIR AND ADHESION TO FABRIC Cross-referencing to related patent applications.

[0001] This application claims priority over U.S. Application No. 63 / 487,168, entitled “Compositions and Methods for Reducing Pet Hair Adhesion to Fabric,” filed February 27, 2023, the contents of which are incorporated herein by reference in their entirety for all purposes. FUNDAMENTALS OF THE INVENTION

[0002] Fabric treatment compositions are generally used during the rinse or dry cycle of a washing process for softness, fragrance, static reduction, and ease of ironing. Typically, liquid fabric treatment compositions are used during the rinse cycle and are used during the dry cycle, usually incorporated into fabric substrates placed in the dryer.

[0003] The adhesion of animal hair to fabrics is a phenomenon that affects hygiene and aesthetics. State-of-the-art technologies aim to remove hair during washing, providing a literal application.

[0004] The interaction between animal hair and fabric can be multifaceted. A fairly large proportion, however, has been found to be based on the charge. Petition 870250073490, dated 08 / 20 / 2025, page 15 / 78 2 / 44 electrostatics and the resulting attractive forces between the tissue and the hair, which are distinguished by opposite surface electrical potentials.

[0005] Consequently, it would be useful to develop more economical fabric care compositions that reduce or prevent the adhesion of animal hair and are designed to meet this and other purposes. SUMMARY

[0006] This summary is intended merely to introduce a summary of this disclosure. Other areas of applicability of this disclosure will become apparent from the detailed description provided below. This summary does not limit the scope of the disclosure. Instead, its purpose is merely to present a detailed description below.

[0007] This invention describes a technology that makes fabrics less susceptible to hair adhesion, so that exposure during daily routines leads to a smaller amount of hair trapped on the surface. The invention and pet hair repellency are applied during the washing cycle.

[0008] Surprisingly, the addition of cationic surfactants and polymers to the washing process led to a substantial and persistent reduction in animal hair adhesion. It should be mentioned that this technology allows the application of surface potential modifying substances from an aqueous solution, thus enabling... Petition 870250073490, dated 08 / 20 / 2025, page 16 / 78 3 / 44 because the substances used act selectively on the tissue fibers and

[0009] This technological approach has proven to be superior to state-of-the-art solutions, including the melting process using drying sheets, as described above.

[0010] Some embodiments of the present invention provide a dialkyl ester triethanolammonium methyl sulfate; and an effective amount of an anti-adherent component comprising: a silicone and / or acrylamide copolymer and diallyldimethylammonium chloride, wherein the anti-adherent component is present in an amount effective to reduce the adhesion of pet hair to a fabric.

[0011] Other embodiments of the present invention provide a method for reducing or preventing the adhesion of pet hair to a liquid comprising: water; a dialkyl ester triethanolammonium methyl sulfate; I am a silicone and / or a copolymer of acrylamide and diallyldimethylammonium chloride, wherein the anti-adhesive component is present in an amount effective to reduce the adhesion of pet hair to a fabric.

[0012] In another form, the composition for tissue treatment te

[0013] In another embodiment, the fabric softener composition also includes a preservative; and a dye.

[0014] In another embodiment, the composition for tissue treatment is in the form of a liquid and has a viscosity of about 30 to about Petition 870250073490, dated 08 / 20 / 2025, page 17 / 78 4 / 44 of 500 cP, for example, about 30 to about 300 cP or about 30 to about 100 cP.

[0015] In another embodiment, the fabric softener mixture is a stable, water-soluble liquid mixture.

[0016] In another embodiment, the amount of esterquat and polyquaternium-7 in the fabric softener composition is based on the following Formula I: Y= - 0.0043X2 + 0.0649X - 0.0037, where x is the amount of esterquat to be substituted and Y is the amount of polyquaternium-7.

[0017] The foregoing and / or other aspects and utilities incorporated in this disclosure may also be obtained by providing a method for creating reduced esterquat, including determining the amount of esterquat in a unit of esterquat per x% by weight of polyquaternium-7; and creating a composition for treating fabrics to achieve performance equivalent to that of a known fabric treatment composition, at least in terms of one of a few aspects: softness, ease of ironing, and wrinkle reduction.

[0018] In another embodiment, the composition for treating tissues with esterquat.

[0019] In another embodiment, the composition for treating tissues, except esterquat and polyquaternium-7.

[0020] In another embodiment, the composition for treating tissues co Petition 870250073490, dated 08 / 20 / 2025, page 18 / 78 5 / 44

[0021] In another embodiment, the composition for treating fabrics with a reduced amount of esterquat also includes an aqueous carrier; from 0.3% by weight to 3% by weight of fragrance; 0.001% or more by weight of thickener; and 0.2% or less by weight of preservative.

[0022] co

[0023] According to embodiment 1, a liquid composition for tissue treatment is provided, comprising: Dialkyl ester triethanolammonium methyl sulfate; a silicone or copolymer of acrylamide and diallyldimethylammonium chloride; and more than about 50% by weight of water, for use in reducing or preventing the adhesion of animal hair to styrofoam.

[0024] According to embodiment 2, a liquid composition is provided for treating dialkyl ester triethanol ammonium methyl sulfate.

[0025] According to embodiment 3, a liquid composition is provided for treating dialkyl ester triethanol ammonium methyl sulfate.

[0026] According to modality 4, a liquid composition is provided for the previous treatment, with a weight of u

[0027] According to modality 5, a liquid composition is provided for treatment Petition 870250073490, dated 08 / 20 / 2025, page 19 / 78 6 / 44 previous, comprising from about 0.1% by weight to about 1% by weight of a silicone.

[0028] According to embodiment 6, a liquid composition for tissue treatment is provided, according to any previous claim, with the weight of a silicone.

[0029] According to embodiment 7, a liquid composition for treating tissues is provided according to any previous embodiment, in which acrylamide copolymer and diallyldimethylammonium chloride is modified.

[0030] According to embodiment 8, a liquid composition for treating tissues according to embodiment 7 is provided, in which the acrylamide and diallyldimethylammonium chloride copolymer is modified with a linear or branched hydrocarbon.

[0031] According to embodiment 9, a liquid composition is provided for the previous treatment, with a weight of acrylamide copolymer and diallyldimethylammonium chloride.

[0032] According to embodiment 10, a liquid composition for treating tissues is provided according to any previous embodiment, comprising from about 0.05% by weight to about 1.5% by weight of acrylamide copolymer and diallyldimethylammonium chloride.

[0033] According to embodiment 11, a liquid composition for treating tissues is provided according to any previous embodiment, comprising from about 0.1% by weight to about 1.0% by weight of acrylamide copolymer and diallyldimethylammonium chloride.

[0034] According to embodiment 12, a liquid composition for tissue treatment is provided according to any claim. Petition 870250073490, dated 08 / 20 / 2025, page 20 / 78 7 / 44 previous, comprising from about 0.2% by weight to about 0.5% by weight of acrylamide copolymer and diallyldimethylammonium chloride.

[0035] According to embodiment 13, a liquid composition for tissue treatment is provided according to any previous embodiment, comprising about 0.3% by weight of acrylamide copolymer and diallyldimethylammonium chloride.

[0036] According to embodiment 14, a liquid composition is provided for the previous treatment, co copolymer

[0037] According to embodiment 15, a liquid composition is provided for treating the thickening system comprising from about 0.01% by weight to about 2% by weight of an acrylate copolymer.

[0038] According to embodiment 16, a liquid composition is provided for treatment and approximately 1.5% by weight of an acrylate copolymer.

[0039] According to embodiment 17, a liquid composition is provided for embodiments 14 to 16, wherein the thickening system comprises from about 0.1% by weight to about 1.0% by weight of an acrylate copolymer.

[0040] According to embodiment 18, a liquid composition is provided for embodiments 14 to 17, wherein the thickening system comprises from about 0.2% by weight to about 0.5% by weight of an acrylate copolymer.

[0041] According to modality 19, a liquid composition is provided for treatment Petition 870250073490, dated 08 / 20 / 2025, page 21 / 78 8 / 44 embodiments 14 to 18, wherein the thickening system comprises from about 0.3% by weight to about 0.4% by weight of an acrylate copolymer.

[0042] According to embodiment 20, a liquid composition for tissue treatment is provided, according to any previous embodiment, comprising from about 50% by weight to about 99% by weight of water.

[0043] According to embodiment 21, a liquid composition for tissue treatment is provided, according to any previous embodiment, comprising from about 75% by weight to about 98% by weight of water.

[0044] liquid for previous treatment, water.

[0045] According to modality 23, a liquid composition is provided for the previous treatment, with water.

[0046] According to embodiment 24, a liquid composition for tissue care is provided according to any previous embodiment, and electrostatics between animal hairs

[0047] According to modality 25, a liquid composition is provided for previous treatment, I optional less than 45, less than 44, less than 43, less than 42, less than 41, less than 40, less than 39, less than 38, less than 37, less than 36, Petition 870250073490, dated 08 / 20 / 2025, page 22 / 78 9 / 44 less than 35, less than 34, less than 33, less than 32, less than 31, less than 30, less than 29, less than 28, less than 27, less than 26, less than 25, less than 24, less than 23, less than 22, less than 21, or less than 20.

[0048] According to embodiment 26, a liquid composition for tissue treatment is provided, comprising: water; uu understanding: It is a copolymer of acrylamide and diallyldimethylammonium chloride, in which the non-stick component is present in an amount effective in reducing the adhesion of pet hair to a fabric.

[0049] According to modality 27, provided that it is a co-prevention of the adhesion of pet hair to a fabric. co-dialkyl ester triethanolammonium methyl sulfate; a silicone or copolymer of acrylamide and diallyldimethylammonium chloride; and more than about 50% by weight of water.

[0050] According to embodiment 28, provided that it is a co-dialkyl ester triethanolammonium methyl sulfate; a silicone or copolymer of acrylamide and diallyldimethylammonium chloride; and more than about 50% by weight of water, Petition 870250073490, dated 08 / 20 / 2025, page 23 / 78 10 / 44 where the composition reduces or prevents pet hair from adhering to a fabric.

[0051] According to embodiment 29, provided that it is the use of a composition described herein to reduce or prevent the adhesion of pet hair to a fabric.

[0052] According to embodiment 30, use is provided according to embodiment 29, wherein the composition is a liquid composition.

[0053] According to modality 31, the use of water is provided in accordance with the modality; uu co u an acrylamide and diallyldimethylammonium chloride copolymer.

[0054] According to embodiment 32, a method is provided for reducing or preventing the adhesion of pet hair to a fabric by applying to a fabric a liquid composition comprising: water; uu co u an acrylamide and diallyldimethylammonium chloride copolymer,

[0055] in which the non-stick component is present in an amount effective to reduce the adhesion of pet hair to a fabric. Petition 870250073490, dated 08 / 20 / 2025, page 24 / 78 11 / 44 BRIEF DESCRIPTION OF THE FIGURES

[0056] FIG. 1 represents the area for analysis of animal hair adhesion to the area within the circle.

[0057] FIG. 2 describes the various types of tissue used in evaluating the adhesion of animal hairs

[0058] FIG. 3 describes the results of the 2 comparative assessments of AFCM.

[0059] FIG. 4 depicts a graph of the main effects of animal hair adhesion.

[0060] FIG. 5 illustrates the results of a 2AFCM evaluation of animal hair adhesion of the present invention and a comparative composition.

[0061] FIG. 6A describes the benefit scores for animal hair adhesion.

[0062] FIG. 6B describes the benefit scores for animal hair adhesion.

[0063] FIG. 7 describes the results of u of two co

[0064] FIG. 8 depicts static load dissipation graphs for different u co. DETAILED DESCRIPTION

[0065] Reference will now be made in detail to the various modalities in this publication. As any examples given are illustrative and not restrictive. However, Petition 870250073490, dated 08 / 20 / 2025, p. 25 / 78 12 / 44 it will be evident to those skilled in the art that the invention can be practiced if and with not unnecessarily confusing aspects of the embodiments.

[0066] Throughout the descriptive report and claims, the following have no bearing unless the context clearly indicates otherwise. The phrases in some embodiments and in one embodiment, as used in this document, do not necessarily refer to any means that may be easily disclosed.

[0067] As used in this document, the term or is an inclusive operator, and is equivalent to the term and / or, unless the context clearly indicates otherwise. "Being co" clearly indicates less one among A, B, and C includes modalities that contain A, B, or C, multiple instances of A, B, or C, or combinations of A / B, A / C, B / C, A / B / B / B / C, A / B / C, etc. Furthermore, throughout descriptive reporting, the meaning of "a," "an," and "the" includes plural referents. The meaning of "in" includes "in" and "about."

[0068] It will also be understood that, although the terms first, second, etc. may be used in this document to describe various elements These terms are used only to distinguish one element from another. By Petition 870250073490, dated 08 / 20 / 2025, p. 26 / 78 13 / 44 For example, a first object, component, or step could be called a second object, component, or step, and similarly, a second object, component, or step could be called a first object, co-object, co-both, objects, components, or steps, respectively, but they should not be considered the same object, component, or step. It will be further understood that the terms includes, including, comprises, and / or comprising, when used in this descriptive report, specify the presence of features, steps, operations, elements, and / or co-other features, steps, operations, elements, components, and / or groups thereof. Furthermore, as used in this document, the term "to have" refers to the determination or response to detection, depending on the context.

[0069] All physical properties defined below are measured in 20° to 25° Celsius, unless otherwise indicated.

[0070] When referring to any numerical range of values ​​in this document, the number and / or fraction between the stated minimum and maximum of the range, as well as 0.9%, all above and including 5.95%, 5.97%, and 5.99%, among many others, is used. The same applies to each other numerical property and / or range it clearly states.

[0071] Additionally, all numerical values ​​are approximately or approximately experiential Petition 870250073490, dated 08 / 20 / 2025, p. 27 / 78 14 / 44 It should be noted that all numerical values ​​and ranges disclosed in this document are approximate values ​​and ranges, regardless of the use of "approximately" in conjunction with them.

[0072] Unless otherwise specified, all percentages and quantities expressed in this document and elsewhere in the descriptive report shall be understood as referring to percentages by weight. The quantities provided are based on the active weight of the material. Unless otherwise specified, all quantities of a co co can

[0073] With regard to procedures, methods, techniques and workflows that are in accordance with some modalities, some operations in the procedures, methods, techniques and workflows disclosed in this document may be combined and / or the order of some

[0074] A composition for treating fabrics, as disclosed herein, includes a fabric softening agent and an anti-adherent component that works for treating an aqueous carrier.

[0075] The composition for treating fabrics includes one or more fabric softening agents, which is a cationic softener selected from esterquats, imidazolinium quaternary cations, diammonium methyl sulfate, dichloride of certain compounds with the following formula: Petition 870250073490, dated 08 / 20 / 2025, p. 28 / 78 15 / 44 Formula 1: R1 (CH2)q—OC—R4 where R4 is an aliphatic hydrocarbon group with 8 to 22 carbon atoms, R2 and R3 represent (CH2)s-R5, where R5 is an alkoxycarbonyl group containing 8 to 22 carbon atoms, benzyl, phenyl, C1-C-4 alkyl-substituted phenyl, OH or H; Ri is (CH2)t-R6, where R6 is benzyl, phenyl, C1-C4 alkyl-substituted phenyl, OH or H; q, s, et, each independently, are an integer from 1 to 3; and X- is a softener-compatible anion.

[0076] Esterquat can be produced by the reaction of about 1.65 (1.5 to 1.75) mole of fatty acid methyl ester with one mole of alkane amine, followed by quaternization with dimethyl sulfate (more details on this). 3,915,867, which is incorporated herein in its entirety for all purposes). The use of these ratios controls the amount of each of monoesterquat, diesterquat, and triesterquat within the co-alkanol; it is desirable to increase the amount of diesterquat and minimize the amount of triesterquat to increase the amount of diesterquat. By selecting a ratio of approximately 1.65, the triesterquat can be minimized while increasing the monoesterquat. For example, when producing the esterquat by reacting the methyl fatty acid with an alkane amine at approximately 1.7:1, or approximately 1.65:1, the triesterquat can be minimized while increasing the monoesterquat. Petition 870250073490, dated 08 / 20 / 2025, p. 29 / 78 16 / 44

[0077] Monoesterquat is more water-soluble than triesterquat. Depending on Al, more or less monoesterquat is preferable. At high AI levels (typically at least 7%), more monoesterquat is preferable to triesterquat so that the esterquat is more water-soluble, allowing it to be distributed to the fabric during use. At reduced AI levels (typically down to 3%), less monoesterquat is preferable because, during use, the esterquat is desired to leave the solution and deposit on the fabric to soften it. They are adjusted to balance the solubility and distribution of the esterquat.

[0078] In certain embodiments, the reaction products are 50-65% by weight of diesterquat, 20-40% by weight of monoester, and 25% or less by weight of triester. In other embodiments, the amount of diesterquat is 52-60%, 53-58%, or 53-55% by weight. In other embodiments, the amount of monoesterquat is 30-40% or 35-40% by weight. In other embodiments, the amount of triesterquat is 1-12% or 8-11% by weight.

[0079] The percentages, by weight, of mono-, di-, and tri-esterquats, as described above, are determined by a quantitative analytical method. The percentages are necessary due to the presence of 10% to 15%, by weight, of non-quaternized species, such as... Consequently, normalized weight percentages refer to the % by weight of each of monoesterquat, diesterquat, and triesterquat; the % by weight is based on the total amount of monoesterquat, diesterquat, and triesterquat in the composition.

[0080] And saturated co Petition 870250073490, dated 08 / 20 / 2025, p. 30 / 78 17 / 44 Esterquat compositions using this percentage of saturated fatty acids do not have the processing disadvantages of 100% saturated materials. When used to soften fabrics, these compositions provide good fabric softness perception to the consumer while retaining good fragrance distribution. In other embodiments, the amount is at least 50, 55, 60, 65, or 70 up to 75%. In other embodiments, the amount does not exceed 70, 65, 60, 55, or 50 up to 45%. In other embodiments, the amount is 50 to 70%, 55 to 65%, or 57.5 to 67.5%. For example, the percentage of saturated fatty acids based on the total weight of fatty acids can be approximately 45 to approximately 75%, approximately 45 to approximately 70%, approximately 45 to approximately 65%, approximately 45 to approximately 60%, approximately 45 to approximately 55%, approximately 70%, approximately 55 to approximately 75%, approximately 65%; approximately 60 to approximately 75%, approximately 60 to approximately 70%, approximately 65 to 75%.

[0081] In one embodiment, the percentage of fatty acid chains that are saturated is aci In this method, this can be obtained from a 50:50 ratio of hard:soft fatty acid. By hard, it is understood that the fatty acid is almost completely hydrogenated; by soft, it is understood that the fatty acid is only partially hydrogenated. And this partially hydrogenated fatty acid can be used. AND Petition 870250073490, dated 08 / 20 / 2025, p. 31 / 78 In a 18 / 44 formulation, the ratio is approximately 50:50. Since in these specific formulations, each of the hard and soft fatty acids covers ranges for different levels of saturation (hydrogenation), the actual percentage of fatty acids that are completely saturated can vary. In certain saturated and

[0082] The percentage of saturated fatty acids can be achieved using u percentage quantities of saturated fatty acids.

[0083] Fatty acids can be any fatty acid that is used to manufacture esterquats for fabric softening. Examples of fatty acids include synthesized tallow. In certain embodiments, the fatty acid is tallow. For example, the esterquat can be u L1 / 90, commercially available from Kao Chemicals, Tokyo, Japan.

[0084] Although esterquat can be supplied in solid form, it is generally possible to dispense esterquat from a fabric softener towel in the laundry. And

[0085] AI refers to the active weight of the combined quantities of monoesterquat, diesterquat, and triesterquat. Distributed Al refers to the mass (and pile te pile u certain Petition 870250073490, dated 08 / 20 / 2025, p. 32 / 78 In the 19 / 44 modes, the distributed Al is 2.8 to 7, 2.8 to 6, 2.8 to 5, 3 to 8, 3 to 7, 3 to 6, 3 to 5, 4 to 8, 4 to 7, 4 to 6, or 4 to 5 grams per stack.

[0086] In one embodiment, the fabric treatment composition includes 20% or less by weight of fabric softener, based on the total weight of the fabric treatment composition. In certain embodiments, the fabric treatment composition includes 15% or less of quaternized triethanolamine diester.Normally, when included, the agent's weight is approximately 0.5 to approximately 20% by weight, approximately 0.5 to approximately 15% by weight, approximately 0.5 to approximately 10% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 3% by weight, approximately 0.5 to approximately 2% by weight, approximately 0.5 to approximately 1% by weight; approximately 1 to approximately 20% by weight, approximately 1 to approximately 15%, approximately 1 to approximately 5%, approximately 1 to approximately 2%, approximately 1.5 to approximately 15% by weight, approximately 1.5 to approximately 10% by weight, approximately 1.5 to approximately 5% by weight, approximately 1.5 to approximately 3% by weight, approximately 1.5 to approximately 2% by weight; from about 2 to about 20% by weight, about 2 to about 15 to about 5% by weight, about 2 to about 3% by weight; from about 3 to about 20% by weight, about 3 to about 15% by weight, about 3 to about 10. Petition 870250073490, dated 08 / 20 / 2025, page 33 / 78 20 / 44 approximately 20% by weight, approximately 5 to approximately 15% by weight, approximately 5 to approximately 10% by weight, or any range or subrange thereof, based on the total weight of the composition for tissue treatment.

[0087] The composition for treating fabrics also includes a non-stick component. The non-stick component may be selected from one or more co-softening agents, such as those disclosed herein. In some embodiments, the non-stick component consists of co-softening agents, such as those described herein. The non-stick component and / or co-softening agent may be a polyquaternium polymer. According to one embodiment, the co-softening agent is a stable, water-soluble, liquid polyquaternium polymer. For example, the non-stick component and / or co-softening agent may be polyquaternium-7. Polyquaternium-7 (PQ7) is a copolymer of acrylamide and diallyldimethylammonium chloride, and is typically represented by the following chemical formula: (CsH5nI)C1N1N1C5H5NO1N1. Polyquaternium-7 is commercially available as NOVERITE 300 from Lubrizol Corporation, Wickliffe, Ohio, and as FLOCARE LS737 from SNF Floerger, Andrézieux, France.

[0088] Some embodiments of the present invention provide a liquid composition for treating fabrics comprising: a dialkyl diethanol ammonium methyl sulfate; a silicone or copolymer of acrylamide and diallyl dimethyl ammonium chloride; and more than about 50% by weight of water; for use in reducing or preventing the adhesion of pet hair to a fabric. Some embodiments provide a liquid composition for treating fabrics comprising from about 0.5% by weight to about 5% by weight of a dialkyl diethanol ammonium methyl sulfate. Other embodiments provide a liquid composition for treating fabrics comprising from about 1% by weight to about 4% by weight of a dialkyl diethanol ammonium methyl sulfate. Other embodiments provide a liquid composition for treating fabrics. Petition 870250073490, dated 08 / 20 / 2025, page 34 / 78 21 / 44 comprising from about 3.0% by weight to about 3.5% by weight of a dialkyl ester ammonium methyl sulfate triethanol.

[0089] Some embodiments of the present invention provide a co 0.1% by weight to about 1% by weight of silicone. In some embodiments, the liquid composition for tissue treatment comprises from about 0.25% by weight to about 0.5% by weight of silicone.

[0090] a dimethicone) and combinations thereof. The term “amino silicone” may refer to any silicone comprising at least one primary, secondary or tertiary amine or quaternary ammonium group (i.e., a quaternized group).

[0091] Non-limiting examples of silicones include dimethiconol, di aa co silicone quaternium-80, silicone quaternium-1, silicone quaternium-2, silicone quaternium-2, panthenol succinate, silicone quaternium-3, silicone quaternium-4, silicone quaternium-5, silicone quaternium-6, silicone quaternium-7, silicone quaternium-8, silicone quaternium-9, silicone quaternium-10, silicone quaternium-11, silicone quaternium-12, silicone quaternium-15, silicone quaternium-16, silicone quaternium-16 / glycidoxy dimethicone crosspolymer, silicone quaternium-17, silicone quaternium-18, silicone quaternium-20, silicone quaternium-21 or u co

[0092] The weight-average molecular weight (Mw) of silicone preferably ranges from 2,000 to 1,000,000, for example, from 3,500 to 200,000. And Petition 870250073490, dated 08 / 20 / 2025, page 35 / 78 22 / 44 preferably from 2,000 to 200,000, for example, 5,000 to 100,000 or 10,000 to 50,000.

[0093] In some embodiments, the acrylamide-diallyldimethylammonium chloride copolymer is modified. In other embodiments, the acrylamide-diallyldimethylammonium chloride copolymer is modified with a linear or branched hydrocarbon. In some embodiments, the co 0.01% by weight to about 2% by weight of acrylamide-diallyldimethylammonium chloride copolymer. In other embodiments, the liquid composition for tissue treatment according to any of the preceding claims, acrylamide-diallyldimethylammonium chloride copolymer. Still other embodiments provide liquid compositions for tissue treatment comprising from about 0.1% by weight to about 1.0% by weight of acrylamide-diallyldimethylammonium chloride copolymer. Certain embodiments provide a liquid composition for tissue treatment of acrylamide-diallyldimethylammonium chloride copolymer. Other embodiments provide a liquid composition for tissue treatment according to any of the preceding claims, comprising about 0.3% by weight, or about 0.35% by weight, or about 0.4% by weight of acrylamide-diallyldimethylammonium chloride copolymer.

[0094] Other embodiments of the present invention provide a thickening system; in some embodiments, the thickening system comprises from about 0.01% by weight to about 2% by weight of an acrylate copolymer. In other embodiments, the thickening system comprises from about 0.05% by weight to about 1.5% by weight of an acrylate copolymer. Petition 870250073490, dated 08 / 20 / 2025, page 36 / 78 23 / 44 models provide a thickening system comprising approximately 0.1% by weight to about 1.0% by weight of an acrylate copolymer. While other embodiments provide a thickening system comprising from about 0.2% by weight to about 0.5% by weight of an acrylate copolymer. Still other embodiments provide a thickening system comprising from about 0.3% by weight to about 0.4% by weight of an acrylate copolymer.

[0095] In some forms, the liquid compositions for treatment and co co

[0096] In some forms, the liquid compositions for treatment and co co

[0097] In some forms, liquid compositions for treating pet hair and fabric.

[0098] In other modalities, the liquid composition for tissue treatment provides a Hair Adhesion Benefit Score of less than 50, optionally less than 49, less than 48, less than 47, less than 46, less than 45, less than 44, less than 43, less than 42, less than 41, less than 40, less than 39, less than 38, less than 37, less than 36, less than 31, less than 26, less than 21 or Petition 870250073490, dated 08 / 20 / 2025, p. 37 / 78 24 / 44 to be evaluated as described in Example 2. For example, the Hair Adhesion benefit score can be evaluated by visual assessment of two fabric samples: one washed with detergent and the other fabric sample washed under the same conditions, but only with detergent, and where the visual assessment is greater than the two fabric samples washed with detergent alone (if more hair) than the fabric sample washed with detergent alone, I to treat

[0099] Some embodiments of the present invention provide a dialkyl ester triethanolammonium methyl sulfate; and an effective amount of an anti-adherent component comprising: a silicone; and / or acrylamide and diallyldimethylammonium chloride copolymer; wherein the anti-adherent component is present in an amount effective to reduce the adhesion of pet hair to a fabric.

[0100] Other embodiments of the present invention provide a co-prevention of hair adhesion of an acrylamide and diallyldimethylammonium chloride copolymer; and more than about 50% by weight of water. Other embodiments of the present invention provide a dialkyl ester of triethanolamine methyl sulfate; a silicone; or an acrylamide and diallyldimethylammonium chloride copolymer; and more than about 50% by weight of water. Petition 870250073490, dated 08 / 20 / 2025, page 38 / 78 25 / 44 of water; in which the composition reduces or prevents pet hair from adhering to a fabric.

[0101] Other embodiments of the present invention provide for the use of a liquid composition comprising: water; a dialkyl ester of triethanolammonium methyl sulfate; and an effective amount of an anti-adherent component comprising: a silicone; and / or an acrylamide and diallyldimethylammonium chloride copolymer.

[0102] Other embodiments of the present invention provide a method for reducing / preventing the adhesion of pet hair to a fabric, the method comprising: applying to a fabric any of the following compositions: water; a dialkyl ester of triethanolammonium methyl sulfate; and an effective amount of an anti-adherent component comprising: a silicone; and / or an acrylamide and diallyldimethylammonium chloride copolymer; wherein the anti-adherent component is present in an amount effective to reduce the adhesion of pet hair to a fabric.

[0103] As described in this document, the inventors discovered surprising PQ7 offers considerable advantages. For example, PQ7 is typically supplied as a liquid dispersion. This facilitates its use in continuous manufacturing systems. PQ7 also forms stable mixtures compared to other liquid dispersions. Petition 870250073490, dated 08 / 20 / 2025, page 39 / 78 26 / 44 cannot be achieved by other polyquaternium polymers (e.g., Polyquaternium 67, Polyquaternium 5, etc.). The use of PQ7 also exhibited improved fragrance distribution at some key contact points that can treat tissues, including hydroxyethylcellulose dimethyl diallylammonium chloride copolymer (PQ-4), a terpolymer of acrylic acid, methacrylamide-propyl trimethylammonium chloride, and methyl acrylate (PQ-47).

[0104] In one embodiment, the tissue treatment composition includes up to 0.30% by weight of an anti-adherent component (e.g., polyquaternium-7), based on the total weight of the tissue treatment composition. And it includes 0.05 or 0.05. For example, the tissue treatment composition may include 0.5% and

[0105] In another embodiment, the amount of non-stick component and / or co-sticking agent can determine the amount of fabric to be replaced. That is, the inventors have discovered surprising fabrics (e.g., esterquat) of a known composition for co-stick care (e.g., wrinkle reduction, dispersion, etc.) by replacing them with a non-stick component and / or co-sticking agent with the characteristics of that amount of co-stick. Petition 870250073490, dated 08 / 20 / 2025, page 40 / 78 27 / 44 composition for tissue treatment can be determined by the following formula. Formula 2: Y = -0.0043X² + 0.0649X - 0.0037 where X is the amount of fabric softener (e.g., esterquat) to be replaced, and Y is the amount of non-stick component and / or co-softener (e.g., PQ7) needed to provide u of fabrics.

[0106] Formula 2 can be used to reduce the amount of agent a containing agent a by about 0.06% of anti-adherent component (e.g., polyquaternium-7). That is, a known tissue treatment composition containing esterquat can be modified to include 1% by weight less esterquat for every 0.06% by weight of polyquaternium-7 added. In another embodiment, 2% by weight of esterquat can be replaced by about 0.11% by weight polyquaternium-7, or 3% by weight of esterquat can be replaced by about 0.15% by weight polyquaternium-7.

[0107] In some embodiments, the combination of the fabric softening agent (e.g., esterquat) and the non-stick component (e.g., fabric softener). The stable liquid mixture that does not separate when stored at the temperature of the water-soluble mixture. Petition 870250073490, dated 08 / 20 / 2025, page 41 / 78 28 / 44

[0108] The fabric treatment composition may be substantially free of fabric softeners, except for the fabric softening agent and the non-stick component. For example, in some embodiments, the fabric treatment composition is substantially free of any fabric softening agents, except for esterquat. In some embodiments, the fabric treatment composition is substantially free of any fabric softening agents and co-softening agents, except, respectively, for esterquat and polyquaternium-7.

[0109] Esterquats can be considered a cationic surfactant. And substantial tissues. For example, the composition for tissue treatment is substantially free of detergent surfactants. In another embodiment, the composition for tissue treatment

[0110] Aqueous carrier. For example, it may include water as a carrier. In certain embodiments, the amount of water is at least 30%, 40%, 50%, 60%, 70%, 80%, or 85% by weight of the composition; the tissues include 25% or more by weight of water, based on the total weight of the composition; or 75% or more by weight of water, based on the total weight of the composition for treatment. Petition 870250073490, dated 08 / 20 / 2025, page 42 / 78 29 / 44

[0111] In some embodiments, the tissue treatment composition may be a low-water or concentrated formulation intended to be diluted before use. In such embodiments, the tissue treatment composition E 30%, 20%, 15%, or 10% by weight of the composition. For example, the composition of water is 30% or less by weight of water, based on the total weight of the composition.

[0112] The composition for treating fabrics may also include other fabric and dextrose coatings such as fragrances, preservatives, colorants such as dyes or pigments, aging agents, etc.

[0113] In some embodiments, the tissue treatment composition must be easy to conform to and must exceed 500 centipoise (cP) for ready-to-use tissue treatment compositions, preferably not more than 250 cP, and 10,000 cP for a tissue treatment composition intended for dilution before use. In one embodiment, the tissue treatment composition te 200 cP. A 25°C using a Brookfield RVTD digital viscometer with spindle 2 at 50 rpm.

[0114] To adjust viscosity, the composition for tissue treatment may include u Petition 870250073490, dated 08 / 20 / 2025, page 43 / 78 30 / 44 have a high molecular weight. For example, the thickener may be a crosslinked cationic polymer such as FLOSOFT DP200. FLOSOFT DP200 is commercially available through SNF Floerger and is described in U.S. Patent No. 6,864,223 to Smith et al. FLOSOFT DP200 is a water-soluble crosslinked cationic polymer derived from the polymerization of 5 to 100 mg percent of cationic vinyl addition monomer, 0 to 95 mg percent of acrylamide, and 70 to 300 ppm of a bifunctional vinyl addition monomer crosslinking agent.

[0115] Other suitable thickeners are water-soluble crosslinked cationic vinyl polymers that are crosslinked using a crosslinking agent of 300 ppm, preferably 75 to 200 ppm, and more preferably 80 to 150 ppm. These polymers are further described in US Patent 4,806,345, and other polymers that may be used are disclosed in WO 90 / 12862. Generally, such polymers are prepared as water-in-oil emulsions, in which the crosslinked polymers are dispersed in mineral oil, which may contain surfactants. During the manufacture of the finished product, in contact with the aqueous phase, the emulsion inverts, allowing the polymer copolymer to provide long-term stability to the composition for tissue treatment during storage and permitting the presence of relatively high levels of electrolytes without affecting the stability of the composition. Additionally, the amount of thickener is between 0.001 and 0.35. Petition 870250073490, dated 08 / 20 / 2025, page 44 / 78 31 / 44

[0116] In one embodiment, the tissue treatment composition includes no more than 0.5% or less by weight of thickener, based on the total weight of the tissue treatment composition. In other embodiments, the tissue treatment composition includes 0.1% or less based on the total weight of the tissue treatment composition.

[0117] The composition for fabric treatment may include one or more fragrances, aromatic oils, or perfumes. As used in this document, fragrance refers to and includes any non-water-soluble perfumed substance or mixture of substances, including natural odoriferous substances (i.e., obtained by extraction from a flower, herb, bloom, or plant), artificial (i.e., a mixture of natural oils or oil constituents), and / or synthetically produced. As used in this document, fragrance, or perfume, refers to odoriferous materials capable of imparting a desirable fragrance to fabrics, and encompasses conventional materials commonly used in detergent compositions to provide a pleasant fragrance and / or to counteract other commonly used fragrances. Fragrance materials include, but are not limited to, materials such as conventional materials such as...

[0118] The composition for fabric treatment may include fragrance-free, encapsulated fragrances, or u

[0119] In other embodiments, the composition for treating fabrics may be supplied with any desired amount of fragrance. Petition 870250073490, dated 08 / 20 / 2025, page 45 / 78 32 / 44 depending on user preference. In certain versions, the total amount of fragrance is from 0.3% by weight to 3% by weight based on the total weight of the product.

[0120] The tissue treatment composition may include one or more preservatives. The one or more preservatives may include one or more organic acids, such as lactic acid of varying grades. In other modalities, the tissue treatment composition may also include isothiazolinones as preservatives. For example, the one or more preservatives may include a mixture of isothiazolinones (OIT / MIT / CIT). Suitable isothiazolinone preservatives include isothiazolinones sold under the brand name KATHON DP3 and available from Rohm & Haas.

[0121] And includes 0.2% preservative or 0.10% or less by weight of preservative, based on the total weight of the product. EXAMPLES Example 1

[0122] Table 1 (below) describes exemplary compositions (prepared by technique. Table 1 Ingredient Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 % by weight Water 95.2065 95.2565 95.1123 95.1543 94.8043 Petition 870250073490, dated 08 / 20 / 2025, page 46 / 78 33 / 44 Fragrance 0.79 0.74 0.84 0.84 0.84 Lactic acid (88%) 0.0625 0.0625 0.0625 0.0625 0.0625 Preservative 0.02 0.02 0.02 0.02 0.02 Dialkyl ester triethanolammonium methyl sulfate 3.271 3.271 3.271 3.271 3.271 Cationic Acrylate Thickener 0.35 0.35 0.35 0.35 0.35 Modified polydimethylsiloxane, emulsion 0.3 0.3 — 0.3 0.35 Modified polyquaternium-7 -- -- 0.342 -- 0.3 Example 2

[0123] To evaluate the formula under the most challenging conditions, a heterogeneous sample of pet hair is obtained from a grooming salon. The sample consists of hair samples from different dog breeds, with no further treatment applied after receiving the samples, including short and long hair, as well as in the presence of contaminants such as dust, dander, nails, and other unidentified components. The use of this complex mixture was selected as the worst-case scenario; and, as such, as the best option to evaluate the reduction of pet hair adhesion.

[0124] To determine the best way to assess the benefit, different types of tissue and methods of animal hair adhesion are used to determine The fabrics were selected taking into consideration their manufacturing materials, their popularity, and how differences in manufacturing techniques and surface roughness could affect the perceived benefit. The selected fabrics were cardigan, denim, and cotton.

[0125] For the analysis, 15 cm x 15 cm squares are cut from each type of fabric and marked with a circle 11.5 cm in diameter. This circle is drawn to define an area of ​​exposure between the animal hairs adhering to the fabric, which is restricted to the defined area (see FIG. 1). Petition 870250073490, dated 08 / 20 / 2025, page 47 / 78 34 / 44

[0126] For the exposure of tissues to animal hair, direct contact between the hair and the tissues is forced. Three different methods for adhering animal hair are used to obtain the most reproducible results.

[0127] Table 2 (below) describes the methods employed. The methods were identified as: A) Light; B) Medium; and C) Strong, to express the degree of physical contact between animal hair and fabric. For handling animal hair, rubber gloves were used to protect the fabrics. Large contaminants, such as nails and dirt particles, were detected. Table 2 Method | Amount of Hair Used (g) | Contact Time with Fabric (sec) | Type of Interaction [Animal Hair] [Fabric] | A | 1 | 60 | Light: Animal hair is deposited on the fabric covering the entire area of ​​the circle. After covering the entire area, place a 300g stainless steel container over the hair for 10 seconds, then remove and leave the Pet-Hair in contact with the fabric for 50 seconds. The animal hair is removed after 10 seconds of manual agitation. | B | 1 | 60 | Medium: Animal hair is deposited on the fabric covering the entire area of ​​the circle. After the entire area is covered, a stainless steel container is used to cover the animal hair (without applying pressure). Then, a circular motion is applied across the entire area of ​​the circle to rub the hair into the area for 60 seconds. | C | 1 | 60 | Strong: Animal hair is deposited on the fabric covering the entire area of ​​the circle.After the entire area is covered, the Pet-Hair is pressed against the fabric using a PET cap wrapped in aluminum foil. Then, a circular motion is applied across the entire area to rub the hairs into the area for 60 seconds.

[0128] Animal hairs adhered to all fabrics tested (jeans, cardigan and black cotton), however, the black cotton fabric allowed the Petition 870250073490, dated 08 / 20 / 2025, page 48 / 78 35 / 44 better contrast and thus facilitated the visual assessment of the tissues (see FIG. 2).

[0129] Regarding the different methods of animal hair adhesion, method A allowed for better reproducibility for animal hair deposition because less handling was required for its removal. Thus, for the remaining evaluations, cotton fabrics and method A were used for animal hair deposition on the fabric and subsequent benefit assessment. Example 2

[0130] The evaluation of the benefits was done by determining the amount of animal hair Table 3 Parameter Conditions Water Volume 60 L Wash Load Size 2.5 Kg Laundry Detergent Type Ariel Dobel Power Powder (P&G) Liquid Fabric Softener Dosage 34 mL / wash load Dryer Sheet 1 drying sheet / wash load Water Hardness Tap water (no hard water used) Drying Setting Tumble Dryer, 1 hour

[0131] Groups of black cotton fabrics (15 cm x 15 cm) are treated individually and tested. In Table 3 (aci and tissues are dry and the tissue is used to define the area in contact with the animal hair. The samples are ar Petition 870250073490, dated 08 / 20 / 2025, page 49 / 78 36 / 44

[0132] Handling animal tissues and hair is always done with laboratory gloves. The procedure for adhering animal hair to tissues is as follows: 1. Weigh 1g of animal hair. 2. Remove any large particles, adhesive material, or any other debris. 3. flat surface. 4. Take the animal's hairs (from the laboratory) and unravel them to prevent large tangles from settling on the tissues (a confounding factor for visual assessments). 5. Place the animal hairs on the black cotton fabric, in the marked area of ​​the circle, trying to cover the entire inner surface, avoiding placing hairs outside the circle. 6. fifty (50) seconds. 7. Remove pet hair manually by grasping the fabric by both corners and shaking gently. 8. Cover the fabric with aluminum foil to prevent animal hair from getting in. [0 133] Visual assessments were conducted using the 2AFCM (untrained panelists u participants are asked to choose the piece of tissue with the most hairs. [01 34] To assess the benefit score of the Pelo Membership, aa 2, while aa Petition 870250073490, dated 08 / 20 / 2025, page 50 / 78 37 / 44 A frequency analysis is performed to determine which sample has the highest score for Hair Adhesion benefit (most often selected as hairier). The higher the score for hair adhesion benefit, the more hair adheres to the tissue and the less benefit is perceived by the panelists.

[0135] To evaluate the potential benefits of different treatment formulas 1. Detergent Only 2. Exemplary liquid composition of the present invention 3. Drying Sheets

[0136] Washing with black cotton fabrics is done according to the example, the detergent was compared eight (8) times with an exe composition, times with drying sheets and eight (8) times with an exe composition, the results are Table 4 Detergent Formula Drying Sheet Ex. 3 Ex. 3 Score 48 38 33 25

[0137] As can be seen in FIG. 3, an exemplary composition of the present invention is significantly different from drying sheets. Example 3

[0138] The Pet Hair Adhesion Benefit Score estimates the reduction in pet hair. Petition 870250073490, dated 08 / 20 / 2025, page 51 / 78 38 / 44 the benefit. The impact of certain ingredients on pet hair adhesion is evaluated.

[0139] As shown in FIG. 4, the greater the amount of esterquat (ESQ), the less the benefit (more hair adheres). On the other hand, modified polyquaternium-7 (mPQ7) shows a curved behavior that may be associated with its polyelectrolyte nature. As the amount of this CO on the surface increases, so does the dissipation of electrical charge. However, if the concentration continues to increase, it may be possible to obtain an excess of positive charge on the tissue surface which, instead of helping to reduce the adhesion of animal hairs, becomes the main reason for the formation of static charge.

[0140] The Membership Benefit Scores for various co are described below in Table 5. Table 5 Prototype ESQ mPQ7 HC303 Silsoft CLX-E Coat Adhesion Benefit Score - Coat Adhesion 1 3.271 0.7 — 0.3 37 2 4.138 — — — 43 3 3.271 0.7 0.6 — 40 4 4.138 0.7 0.6 0.6 49 5 3.271 0.35 — 0.6 28 6 5.006 — — 0.6 51 7 5.006 0.7 — — 40 8 3.271 — 0.3 — 30 9 4.138 0.35 0.3 0.3 36 10 5.006 0.7 0.3 0.6 44 11 5.006 0.35 0.6 — 40 12 3.271 — 0.6 0.6 32 13 5.006 — 0.6 0.3 37 14 3.271 0.342 — — 39 ESQ: Dialkylester triethanol ammonium methyl sulfate (Esterquat) mPQ7: Modified polyquaternium 7 Petition 870250073490, dated 08 / 20 / 2025, page 52 / 78 39 / 44 HC303: silicone SILSOFT CLX-E: silicone Example 4

[0141] A 2AFCM evaluation is conducted to compare the Hair Adhesion benefit scores between the ESQ-based technology (Ex. Comp. 1) and an exemplary composition of the present invention (ESQ + mPQ7). The results are described in FIG. 5. Exe

[0142] To evaluate the benefits of exemplary liquid compositions for tissue care of the present invention, simultaneous evaluations and cats. The treatments treat treatments 3) or the use of an exemplary composition of the present invention (Ex. 4). Table 6 Sample # Black Cotton Squares Washed Wash Load Washes, Detergent and Fabric Softener Dosages Comp. Ex. 2 (Tide® Liquid (P&G)) 6 2.5 Kg no washes: 1 Detergent: 100mL Fabric Softener: 0mL Comp. Ex. 3 (Bounce Dryer Sheet, Pet Hair & Lint Protector) 6 2.5 Kg no washes: 1 Detergent: 100mL Dryer sheet: 1 / wash load Ex. 4 6 2.5 Kg no washes: 1 Detergent: 100mL Fabric softener: 34 mL / wash load Ex. 4 6 2.5 Kg no washes: 5 Detergent: 100mL Fabric softener: 34 mL / wash load * Example 4 is evaluated in 1 single wash and 5 cumulative washes.

[0143] As shown in FIGS. 6A and 6B, the Coat Adhesion benefit scores are shown for coat assessments of Petition 870250073490, dated 08 / 20 / 2025, page 53 / 78 40 / 44 dogs and cats. From the figures, it can be observed that there is a smaller amount of animal hair adhering to the tissues after treatment with a co

[0144] Similar trends can be observed in both evaluations: samples treated only with detergent (Ex. Comp. 2) are selected with adhered sheets. Drying sheets (Ex. Comp. 3) followed as the second of the present invention (Ex. 4) demonstrated the lowest amount of animal hair. Example 6

[0145] A 2AFCM evaluation is conducted to compare the Hair Adhesion benefit scores between two silicone-based compositions (Ex. 4); and one based on ESQ + silicone + mPQ7 technology (Ex. 5) The results are described in FIG. 7. Example 7

[0146] Samples of Acrilan are washed. After a single wash, the The initial static charge and static charge dissipation are measured using a 3M 718 static sensor. Dry acrylic samples are rubbed twenty (20) times with a balloon to form static charge and five (5) times with the 3M 718 static sensor manufacturer. The main measurement scheme can be seen in Table 1, where continuous measurements over time could be taken. Table 7 Petition 870250073490, dated 08 / 20 / 2025, page 54 / 78 41 / 44 Measurement Time 0 sec Time 20 sec Time 40 sec Time 60 sec Time 120 sec Comp. Ex. 2 kV initial load kV kV kV Final load kV Ex. 4 kV initial load kV kV kV Final load kV

[0147] The effect of ambient humidity is tested to verify if there is There is some significant variation due to moisture absorption. The data is collected and plotted for comparison.

[0148] The results are described in Table 8 (below). Two treatments KV is measured and compared between treatments.

[0149] As demonstrated by the data described in Table 8 (below), the static charge is lower after treatment with a fast static exec composition of the present invention, compared to treatment with detergent alone. Table 8 ENVIRONMENT TREATMENT TIME (SECONDS) 0 20 40 60 120 AMBIENT TEMPERATURE DETERGENT 2.55 KV 2.56 KV 2.36 KV 2.4 KV 2.36 KV Ex. 4 2.32 KV 1.37 KV 1.06 KV 0.92 KV 0.6 KV CONDITIONING Conditioning chamber / room 25 ± 2°C and 50 ± 5% relative humidity DETERGENT 5.8 KV 5.1 KV 4.6 KV 4.5 KV 3.91 KV Ex. 4 2 KV 1 KV 0.71 KV 0.5 KV 0.28 KV Example 8

[0150] An in-home consumer assessment was conducted to evaluate the included 340 volunteers, with approximately the same number of male and female volunteers, who currently own a dog or cat. Petition 870250073490, dated 08 / 20 / 2025, page 55 / 78 42 / 44 residing in the volunteer's residence. Specifically, each volunteer was instructed to wash their clothes and / or fabrics for two weeks using only u their clothes and / or fabrics only co volunteers received samples of Exemplary Composition 1 for use during u for use of u after using Exemplary Composition 1 during the two-week period.

[0151] Based on the research analyzed, 74.7% of volunteers reported that it repelled pet hair, while 8.5% of volunteers concluded that it repelled fabric detergent and 16.8% of volunteers were unsure if the Exemplary Composition performed better than using only fabric detergent. Example 9

[0152] A benefit assessment was made by determining the amount of animal hair treated as described in the Examples above. Specifically, a predetermined amount of fabric containing 50% cotton and 50% polyester. The fabric samples were u under the following conditions: a water volume of 60 L; a wash load size of 34 mL of detergent per wash load; and, optionally, 34 mL of Petition 870250073490, dated 08 / 20 / 2025, pp. 56 / 78 43 / 44 Example 1 composition by wash load. The fabric samples and T-shirts were then machine dried for one hour.

[0153] The tissues were then visually assessed and a one-proportion z-test was used to compare an observed proportion with a theoretical one with a 95% confidence level using the following equation: z = (p-p0) / ^(p0(1-p0) / n) where: p = observed proportion of the sample; p0 = hypothetical proportion of the population; en = sample size.

[0154] A summary of the results of the benefits assessment is shown in Tables 9-12. Table 9 Dog hair 1 Comp. Ex. 2 Comp. Ex. 2 & Specimen Composition 1 No Difference Original Data 92% 6% 3% Divide Equally 93% 8% 0% z-statistic 9.42 p-value (one-tailed) 0 p-value (two-tailed) 0 Significant difference with 95% confidence Table 10 Cat hair 1 Comp. Ex. 2 Comp. Ex. 2 & Specimen Composition 1 No Difference Original Data 98% 3% 0% Divide Equally 98% 3% 0% z-statistic 10.52 p-value (one-tailed) 0 p-value (two-tailed) 0 Significant difference with 95% confidence Table 11 Dog hair 2 Comp. Ex. 2 Comp. Ex. 2 & Specimen Composition 1 No Difference Original Data 98% 3% 0% Divide Equally 98% 3% 0% z-statistic 10.52 p-value (one-tailed) 0 p-value (two-tailed) 0 Significant difference with 95% confidence Table 12 Cat hair 2 Comp. Ex. 2 Comp. Ex. 2 & Sample Composition 1 No Difference Original Data 99% 1% 0% Divide Equally 99% 1% 0% Petition 870250073490, dated 08 / 20 / 2025, pp. 57 / 78 44 / 44 z-statistic 10.74 p-value (one-tailed) 0 p-value (two-tailed) 0 Significant difference with 95% confidence

[0155] The present disclosure has been described with reference to the examples described, it will be perceived by those skilled in the art that changes may be made to the preceding detailed description. This disclosure is intended to be interpreted as including all such modifications and changes as are within the scope of the appended or equivalent claims. Petition 870250073490, dated 08 / 20 / 2025, pp. 58 / 78

Claims

1 / 2 CLAIMS 1. Liquid composition for treating fabrics, characterized in that it comprises: dialkyl ester triethanolammonium methyl sulfate; a silicone or copolymer of acrylamide and diallyldimethylammonium chloride; and more than about 50% by weight of water, for use in reducing or preventing the adhesion of pet hair to a fabric.

2. Liquid composition for tissue treatment, according to claim 1, characterized in that it comprises from about 0.5% by weight to about 5% by weight of a triethanol dialkyl ester ammonium methyl sulfate.

3. Liquid composition for tissue treatment, according to any of the preceding claims, characterized in that it comprises from about 0.1% by weight to about 1% by weight of a silicone.

4. Liquid composition for tissue treatment, according to any of the preceding claims, characterized in that the acrylamide-diyldimethylammonium chloride copolymer is modified.

5. Liquid composition for treating tissues, according to any of the preceding claims, characterized in that it comprises from about 0.01% by weight to about 2% by weight of acrylamide acopolymer and diallyldimethylammonium chloride.

6. Liquid composition for treating tissues, according to any of the preceding claims, characterized in that it comprises from about 0.05% by weight to about 1.5% by weight of acrylamide copolymer and diallyldimethylammonium chloride.

7. Liquid composition for tissue treatment, according to any of the preceding claims, Petition 870250073490, dated 20 / 08 / 2025, page 73 / 78 2 / 2 characterized in that it further comprises a thickening system comprising an acrylate copolymer.

8. Liquid composition for treating tissues, according to any of the preceding claims, characterized in that it comprises from about 50% by weight to about 99% by weight of water.

9. Liquid composition for treating fabrics, characterized in that it comprises: water; a dialkyl ester of triethanolammonium methyl sulfate; and an effective amount of an anti-adherent component comprising: a silicone and / or a copolymer of acrylamide and diallyldimethylammonium chloride, wherein the anti-adherent component is present in an amount effective to reduce the adhesion of pet hair to a fabric.

10. Method for reducing or preventing the adhesion of pet hair to a fabric, the method being characterized in that it comprises: applying to a fabric a liquid composition comprising: water; a dialkyl ester of triethanolammonium methyl sulfate; and an effective amount of an anti-adherent component comprising: a silicone; and / or a copolymer of acrylamide and diallyldimethylammonium chloride, wherein the anti-adherent component is present in an amount effective to reduce the adhesion of pet hair to a fabric. Petition 870250073490, dated 20 / 08 / 2025, pp. 74 / 78