A sulfuric acid defluorination system and defluorination process

By employing silicon column and negative pressure technology in the sulfuric acid defluorination system to perform two defluorination operations, the problem of fluoride ion corrosion in sulfuric acid was solved, achieving efficient and stable defluorination and safe transportation.

CN118045400BActive Publication Date: 2026-05-26CHIZHOU TINCI HIGH TECH MATERIALS CO LTD
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Patent Information

Application Number
CN202410097591.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-01-24
Publication Date
2026-05-26
Estimated Expiration
2044-01-24

AI Technical Summary

Technical Problem

Fluoride ions in sulfuric acid solutions are toxic and corrosive. High concentrations of fluoride ions severely corrode steel, limiting the methods of transporting and storing sulfuric acid. Existing technologies are insufficient to effectively reduce the concentration of fluoride ions.

Method used

A sulfuric acid defluorination system is designed, which utilizes silicon column and negative pressure technology to perform two defluorination operations. Combined with the collection pipe to collect sulfuric acid, continuous defluorination is ensured under negative pressure. The silicon column reacts with sulfuric acid to generate silicon tetrafluoride gas, thereby reducing the concentration of fluoride ions.

Benefits of technology

It improved the defluorination effect of sulfuric acid, stabilized the negative pressure of the system, avoided the impact of negative pressure fluctuations, reduced corrosion of equipment, and achieved safe transportation of sulfuric acid.

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Abstract

This invention belongs to the field of sulfuric acid defluorination technology, and particularly relates to a sulfuric acid defluorination system and a defluorination process for the system. The defluorination tank has an inlet and an outlet. An inner tank is formed within the internal gap of the defluorination tank, creating a collection space A between the defluorination tank and the inner tank. A silicon column is placed within the internal gap of the inner tank, forming a primary defluorination space B between the inner tank and the silicon column. The inlet is located above the primary defluorination space B. The silicon column has a longitudinally arranged through hole, forming a secondary defluorination space C. In this sulfuric acid defluorination system, the silicon column is combined with negative pressure, allowing for two defluorination operations under negative pressure. The defluorination operation is continuous, improving the defluorination effect. Furthermore, by setting up a collection pipe, and having sulfuric acid enter the collection space A from the secondary defluorination space C through the collection pipe, the negative pressure value in the system can be kept stable, avoiding fluctuations in the negative pressure value from affecting the defluorination effect.
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