Preparation of multi-layer composite micro-nano filler for constructing hydrophilic environment of oil-repellent coating, oil-repellent coating and application thereof

By preparing multi-layered composite micro-nano fillers to construct hydrophilic and oleophobic coatings, the problem of oil agglomeration formation in high water-cut oil wells was solved, achieving stable oleophobic effect and resistance to mechanical damage in aquatic environments, suitable for high water-cut and low-temperature gathering and transportation conditions.

CN122302620APending Publication Date: 2026-06-30PETROCHINA CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
PETROCHINA CO LTD
Filing Date
2024-12-31
Publication Date
2026-06-30

AI Technical Summary

Technical Problem

In high water-cut oil wells, the formation of oil clumps under low-temperature conditions leads to deterioration of the produced medium's fluidity, increasing maintenance difficulty and equipment corrosion risk. Existing hydrophobic and oleophobic coatings lack stability and durability in high water-cut environments and are also costly.

Method used

Hydrophilic and oleophobic coatings are constructed by preparing multi-level composite micro- and nano-fillers. Micron-level fillers are etched and then combined with nano-level fillers, and combined with the deposition of hydrophilic macromolecules to form a multi-level protective oleophobic coating, which enhances the coating's resistance to mechanical damage and oleophobic effect.

Benefits of technology

It significantly improves the oleophobic properties of the coating in aquatic environments, reduces the adhesion between oil and the coating, enhances the coating's resistance to mechanical damage, is suitable for high water content and low temperature gathering and transportation conditions, and is easy to mass-produce and industrialize.

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Abstract

This invention specifically relates to a hydrophilic oleophobic coating, an oleophobic coating layer, and their applications constructed by preparing multi-layered composite micro / nano fillers. The oleophobic coating of this invention includes at least a composite filler, which is a micro / nano filler with a particle size of 15-80 μm, obtained by etching micron-sized fillers, followed by hydrophilic macromolecular deposition, composite with nano-sized fillers, and then crushing. This composite filler possesses a multi-layered micro / nano structure, which forms multi-level protection. This multi-level protection ensures that the coating formed by the coating retains a suitable microstructure even after mechanical damage, thus maintaining its oleophobic effect in aquatic environments and significantly enhancing the coating's resistance to mechanical damage.
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