Black aluminum oxide ceramic and method for producing the same

By combining CoO, Cr2O3, and MoO3 ternary coloring with rare earth oxide sintering aids, and high-temperature humidified hydrogen and nitrogen sintering, the problems of insufficient blackness, poor thermal shock resistance, and low bonding strength of black alumina ceramics have been solved. This has resulted in a ceramic material with high light-shielding properties, high thermal shock resistance, and high strength, which is suitable for high-end semiconductor packaging.

CN122403948APending Publication Date: 2026-07-17NANJING TIANLANG ELECTRONIC EQUIP CO LTD
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Patent Information

Application Number
CN202610792462.4
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-06-03
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing black alumina ceramics have problems in high-end semiconductor packaging, such as insufficient black purity, poor thermal shock resistance, low metal-ceramic interface bonding strength, insufficient bending strength, and unstable performance due to the volatility of MoO3, making it difficult to meet the stringent requirements of high-temperature co-fired ceramics.

Method used

A ternary coloring system of CoO, Cr2O3, and MoO3 is adopted, combined with talc and rare earth oxides as sintering aids. The ceramic is prepared by high-temperature sintering at 1550℃~1650℃ in a humidified mixed atmosphere of hydrogen and nitrogen. This forms magnesium aluminum spinel and rare earth oxides to strengthen the grain boundaries, thereby improving the density and interfacial bonding strength of the ceramic.

Benefits of technology

It achieves high-purity black color, excellent light-shielding properties, thermal shock resistance, bending strength, and high metal-ceramic bonding strength in black alumina ceramics, meeting the long-term reliability requirements of high-end semiconductor packaging.

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Abstract

本发明公开了一种黑色氧化铝陶瓷及其制备方法,属于陶瓷封装材料技术领域,陶瓷主料为Al2O3,着色剂由CoO、Cr2O3、MoO3组成,助烧剂采用滑石粉、SiO2、CaCO3与稀土氧化物复合的双助烧体系。本发明通过三元着色体系拓宽可见光吸收范围,使黑色更纯、遮光性更优,利用MoO3显著提升陶瓷与钨 / 钼高温导体浆料的结合强度,通过滑石粉原位生成镁铝尖晶石提高抗热震性,通过稀土氧化物强化晶界提升抗弯强度,并采用1550℃~1650℃加湿氢气氮气混合气氛烧结,抑制MoO3高温挥发;产品兼具纯黑遮光、高抗热震、高强度与高界面结合力,工艺稳定可控,适合半导体高密度高温共烧陶瓷封装领域应用。
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Citation Information

Patent Citations

  • Black aluminum oxide ceramic and preparation method thereof

    CN117843350A