A kind of eutectic solvent oriented molecular imprinting polymer and its preparation method and the separation method of polycyclic aromatic hydrocarbon components in coal tar anthracene oil

The method of preparing molecularly imprinted polymers by eutectic solvent-directed polymers has solved the problem of separating carbazole and anthracene in coal tar, achieving efficient, low-toxicity and high-yield separation, and is suitable for the separation of polycyclic aromatic hydrocarbon components in coal tar anthracene oil.

CN122404607APending Publication Date: 2026-07-17INST OF COAL CHEM CHINESE ACAD OF SCI
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-11
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to efficiently separate carbazole and anthracene from coal tar due to their small polarity difference and eutectic effect, resulting in low yields in crystallization methods. Traditional solvent extraction methods are highly toxic and lack selectivity, while molecular imprinting methods have insufficient material recognition capabilities.

Method used

By employing eutectic solvent-guided molecularly imprinted polymers, a DES prepolymer is formed through hydrogen bond acceptors and hydrogen bond donors. This prepolymer is then combined with styrene and 4-vinylpyridine to form a bifunctional polymer network, thereby preparing a polymer with specific pore size and polar recognition capabilities, achieving efficient separation of carbazole and anthracene.

Benefits of technology

It achieves highly selective and efficient separation of carbazole and anthracene, reduces the toxicity of traditional solvents, improves separation yield and material stability, and is suitable for industrial applications.

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Abstract

本申请提供了一种低共熔溶剂导向分子印迹聚合物及其制备方法和煤焦油蒽油中多环芳烃组分的分离方法。所述低共熔溶剂导向分子印迹聚合物由所述制备方法制得,所述制备方法包括:将低共熔溶剂DES功能单体与模板分子混合加热,形成DES预聚液;DES预聚液与苯乙烯、4‑乙烯基吡啶混合,加致孔剂分散均匀,得复合预聚液;复合预聚液与交联剂、引发剂混合成油相,聚乙烯醇溶液为水相,油相中加入水相进行预分散、聚合和固化,最后筛分、洗脱和干燥;所述低共熔溶剂DES功能单体包括氢键受体和氢键供体。本申请提供一种煤焦油蒽油中多环芳烃组分的分离方法:将煤焦油蒽油进行预处理,使用本申请提供的低共熔溶剂导向分子印迹聚合物进行吸附、洗脱。
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