Durable glass and process for producing the same

Abstract

This invention discloses a durable glass and its manufacturing process. The invention produces EVA adhesive sheets through mixing, heating, cooling and molding. Then, EVA adhesive sheets are applied to the first glass layer and the second glass layer respectively to form the first protective layer and the second protective layer. The first glass layer, the display layer and the second glass layer are then assembled in sequence to form the durable glass. The durable glass has excellent fire and water resistance, high temperature resistance, heat insulation, sealing, mechanical strength, toughness and anti-glare properties. It is also easy to clean and has a long service life.

Description

Technical Field

[0001] This invention relates to the field of glass technology, and in particular to a durable glass and its manufacturing process. Background Technology

[0002] Glass is an amorphous inorganic non-metallic material, generally made from a variety of inorganic minerals (such as quartz sand, borax, boric acid, barite, barium carbonate, limestone, feldspar, soda ash, etc.) as the main raw materials, with the addition of a small amount of auxiliary materials. In existing hardware doors and windows, glass is required as a component in building construction. However, as users' requirements for home quality gradually increase, the performance requirements for glass doors and windows are also becoming higher. Existing doors and windows have a short service life, and the glass is prone to cracking after a period of use, resulting in insufficient overall stability. Publication number CN108689612B discloses a fire-resistant glass. The fire-retardant liquid of this invention is prepared by the following method: first, the fire-retardant liquid is used to perform a displacement reaction on the glass surface, followed by tempering treatment. The fire-resistant glass of this invention has good high-temperature resistance, high fire resistance, strong impact resistance, excellent mechanical properties, and high safety in use, providing effective time guarantees for human escape and firefighting in fire environments. Moreover, the method of this invention is simple to operate, the preparation process conditions are mild, and the production cost of fire-resistant glass is reduced. Although the glass has excellent fire resistance and impact resistance, its sound insulation is average and its overall performance is insufficient. Summary of the Invention

[0003] In view of the shortcomings of the prior art, the purpose of this invention is to provide a durable glass with excellent performance and its manufacturing process.

[0004] To achieve the above objectives, the present invention provides a durable glass comprising, from bottom to top, a first glass layer, a first adhesive layer, a display layer, a second adhesive layer, and a second glass layer, wherein the first adhesive layer is used to adhere the first glass layer and the display layer, and the second adhesive layer is used to adhere the second glass layer and the display layer.

[0005] The beneficial effects of this invention are: durability, the durable glass improves overall durability by setting a multi-layer structure, that is, increases service life, and by setting a display layer, the patterns required by the user can be displayed, etc., and then the first adhesive layer and the second adhesive layer are used to bond the first glass layer, the display layer and the second glass layer together, which has excellent sealing performance, etc.

[0006] Furthermore, the first and second glass layers are semi-tempered glass. This invention, employing the above structure, improves safety, reduces the likelihood of detachment, and exhibits high thermal stability.

[0007] Furthermore, the first adhesive layer and the second adhesive layer are EVA adhesive patches.

[0008] Furthermore, the display layer is made of silk or silk fabric.

[0009] Further, the EVA adhesive patch comprises the following components: 30-60 parts of cis-1,4-polyisoprene; 20-28 parts of dimethylsiloxane; 15-25 parts of EVA thermoplastic elastomer; 6-10 parts of zinc borate; 8-18 parts of graphene; 4-8 parts of epoxy resin; 12-24 parts of polyacrylate emulsion; 5-9 parts of butyl acrylate; 4-10 parts of glyceryl rosin ester; 1-3 parts of plasticizer; and 1-3 parts of curing agent. With the above structure, the sealant of this invention possesses excellent fireproof and waterproof properties, high temperature resistance, heat insulation, crack resistance, and sealing performance.

[0010] Further, the following components are included: 45 parts of cis-1,4-polyisoprene; 24 parts of dimethylsiloxane; 20 parts of EVA thermoplastic elastomer; 8 parts of zinc borate; 13 parts of graphene; 6 parts of epoxy resin; 18 parts of polyacrylate emulsion; 7 parts of butyl acrylate; 7 parts of glyceryl rosin ester; 2 parts of plasticizer; and 2 parts of curing agent.

[0011] This invention also includes a process for producing durable glass, comprising the following steps:

[0012] S1. Weigh out the following components according to the specified proportions: cis-1,4-polyisoprene, dimethylsiloxane, EVA thermoplastic elastomer, zinc borate, graphene, epoxy resin, polyacrylate emulsion, butyl acrylate, glyceryl rosin ester, plasticizer, and curing agent. Then add cis-1,4-polyisoprene, dimethylsiloxane, and EVA thermoplastic elastomer into a mixer and mix for 30-60 minutes.

[0013] S2. Add the epoxy resin, polyacrylate emulsion, butyl acrylate and glyceryl rosin ester weighed in step S1 into the mixing tank in sequence and mix until they are evenly mixed.

[0014] S3. Heat and mix the mixture from step S2 with the mixture from step S1 for 20-40 minutes, then add zinc borate, graphene, plasticizer, and curing agent in sequence, wherein the heating temperature is 100-200℃.

[0015] S4. Pour the mixture from step S3 into the mold, then let it stand to cool until it is completely cooled and solidified to form an EVA adhesive patch, and then open the mold to remove it;

[0016] S5. Cut the glass according to the set dimensions to form a first glass layer and a second glass layer. Then, both the first glass layer and the second glass layer are subjected to edge grinding, clamping, drilling, semi-tempering, cooling, cleaning, and drying. In the semi-tempering furnace, the upper temperature of the heating zone is 680-700℃, the lower temperature of the heating zone is 660-680℃, the heating time is 80-85s, the cooling air pressure is 35-40KPA, and the cooling time is 100-150s.

[0017] S6. Cut EVA adhesive sheets according to the first glass layer and the second glass layer to form the first adhesive layer and the second adhesive layer respectively. Then, stick the first adhesive layer on the first glass layer and stick the second adhesive layer on the second glass layer. Then, assemble the first glass layer, the display layer and the second glass layer in sequence to complete the assembly.

[0018] S7. Place the assembled glass from step S6 into a vacuum machine for vacuum treatment.

[0019] The beneficial effects of this invention are as follows: By using the above steps to obtain the sealant and the durable glass, EVA adhesive sheets are first prepared by mixing, heating, cooling and molding. Then, EVA adhesive sheets are applied to the first glass layer and the second glass layer respectively to form the first protective layer and the second protective layer. The first glass layer, the display layer and the second glass layer are then assembled in sequence to form the durable glass. This makes the durable glass have excellent fire and water resistance, high temperature resistance, heat insulation, sealing, mechanical strength, toughness and anti-glare properties. It is also easy to clean and has a long service life.

[0020] Furthermore, in step S1, the mixture is stirred for 45 minutes.

[0021] Furthermore, in step S3, the mixture is stirred for 30 minutes and heated to 150°C.

[0022] Furthermore, in step S5, the upper temperature of the heating zone is 690°C, the lower temperature of the heating zone is 670°C, the heating time is 82s, the cooling air pressure is 38KPA, and the cooling time is 125s. Attached Figure Description

[0023] Figure 1 This is an overall structural diagram of the present invention.

[0024] Wherein, 1 is the first glass layer, 2 is the first adhesive layer, 3 is the display layer, 4 is the second adhesive layer, and 5 is the second glass layer. Detailed Implementation

[0025] The technical solution of the present invention will be clearly and completely described below with reference to the accompanying drawings. Obviously, the described embodiments are some embodiments of the present invention, but not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative effort are within the scope of protection of the present invention.

[0026] In the description of this invention, it should be noted that the terms "center," "upper," "lower," "left," "right," "vertical," "horizontal," "inner," and "outer," etc., indicate the orientation or positional relationship based on the orientation or positional relationship shown in the accompanying drawings. They are used only for the convenience of describing the invention and for simplifying the description, and do not indicate or imply that the device or element referred to must have a specific orientation, or be constructed and operated in a specific orientation. Therefore, they should not be construed as limitations on the invention. Furthermore, the terms "first," "second," and "third" are used for descriptive purposes only and should not be construed as indicating or implying relative importance. Example 1:

[0027] See appendix Figure 1 A durable glass comprises, from bottom to top, a first glass layer 1, a first adhesive layer 2, a display layer 3, a second adhesive layer 4, and a second glass layer 5, wherein the first adhesive layer 2 is used to adhere the first glass layer 1 and the display layer 3, and the second adhesive layer 4 is used to adhere the second glass layer 5 and the display layer 3.

[0028] In this embodiment, the first glass layer 1 and the second glass layer 5 are semi-tempered glass.

[0029] In this embodiment, the first adhesive layer 2 and the second adhesive layer 4 are EVA adhesive patches.

[0030] In this embodiment, the EVA adhesive patch comprises the following components: 30 parts of cis-1,4-polyisoprene; 20 parts of dimethylsiloxane; 15 parts of EVA thermoplastic elastomer; 6 parts of zinc borate; 8 parts of graphene; 4 parts of epoxy resin; 12 parts of polyacrylate emulsion; 5 parts of butyl acrylate; 4 parts of glyceryl rosin ester; 1 part of plasticizer; and 1 part of curing agent.

[0031] In this embodiment, the display layer 3 is made of silk or silk fabric.

[0032] This embodiment also includes a manufacturing process for durable glass, comprising the following steps:

[0033] S1. Weigh out the following components according to the specified proportions: cis-1,4-polyisoprene, dimethylsiloxane, EVA thermoplastic elastomer, zinc borate, graphene, epoxy resin, polyacrylate emulsion, butyl acrylate, glyceryl rosin ester, plasticizer, and curing agent. Then add cis-1,4-polyisoprene, dimethylsiloxane, and EVA thermoplastic elastomer into a mixer and mix for 30 minutes.

[0034] S2. Add the epoxy resin, polyacrylate emulsion, butyl acrylate, and glyceryl rosin ester weighed in step S1 into the mixing tank in sequence and mix until they are evenly mixed.

[0035] S3. Heat and mix the mixture from step S2 with the mixture from step S1 for 20 minutes, then add zinc borate, graphene, plasticizer, and curing agent in sequence, wherein the heating temperature is 100℃.

[0036] S4. Pour the mixture from step S3 into the mold, then let it stand to cool until it is completely cooled and solidified to form an EVA adhesive patch. Then open the mold and remove the EVA adhesive patch.

[0037] S5. Cut the glass according to the set dimensions to form a first glass layer 1 and a second glass layer 5. Then, both the first glass layer 1 and the second glass layer 5 are subjected to edge grinding, clamping, drilling, semi-tempering, cooling, cleaning, and drying. In the semi-tempering furnace, the upper temperature of the heating zone is 680℃, the lower temperature of the heating zone is 660℃, the heating time is 80s, the cooling air pressure is 35KPA, and the cooling time is 100s. The cooling method can be a cooling air grid.

[0038] S6. Cut EVA adhesive sheets according to the first glass layer 1 and the second glass layer 5 to form the first adhesive layer 2 and the second adhesive layer 4 respectively. Then, stick the first adhesive layer 2 on the first glass layer 1 and stick the second adhesive layer 4 on the second glass layer 5. Then, assemble the first glass layer 1, the display layer 3 and the second glass layer 5 in sequence to complete the assembly.

[0039] S7. The glass laminated in step S6 is placed in a vacuum machine for vacuum treatment to obtain the durable glass of this embodiment.

[0040] This durable glass, due to its multi-layered structure, first undergoes a series of mixing, heating, and molding processes to produce EVA adhesive sheets. After being bonded to the glass, these sheets exhibit excellent sealing and waterproof properties. Then, through cutting, edge grinding, clamping, drilling, semi-tempering, cooling, cleaning, and drying, the first glass layer 1 and the second glass layer 5 of the semi-tempered glass are produced. These first and second glass layers 1 and 5 possess excellent fire and water resistance, high temperature resistance, heat insulation, mechanical strength, toughness, and anti-glare properties. The display layer 3 can be made of silk or fabric with corresponding patterns according to the user's needs. Using the above methods, thinner glass can be produced, with the first glass layer 1 and the second glass layer 5 reaching a thickness of 2mm, and the overall laminated durable glass reaching a thickness of 5mm.

[0041] To protect the outer surfaces of the first glass layer 1 and the second glass layer 5, a glass coating liquid can be applied to the outer surfaces of the first glass layer 1 and the second glass layer 5 to form a protective layer, further protecting the first glass layer 1 and the second glass layer 5 and giving the first glass layer 1 and the second glass layer 5 characteristics such as high temperature resistance, corrosion resistance, and scratch resistance. The components of the glass coating liquid can be silane coupling agent, nano silica, ethanol, and deionized water. The preparation method is as follows: mix silane coupling agent, nano silica, and ethanol in a ratio of 4:1:5, then add an appropriate amount of deionized water and stir directly until completely dissolved. Example 2:

[0042] See appendix Figure 1 A durable glass comprises, from bottom to top, a first glass layer 1, a first adhesive layer 2, a display layer 3, a second adhesive layer 4, and a second glass layer 5, wherein the first adhesive layer 2 is used to adhere the first glass layer 1 and the display layer 3, and the second adhesive layer 4 is used to adhere the second glass layer 5 and the display layer 3.

[0043] In this embodiment, the first glass layer 1 and the second glass layer 5 are semi-tempered glass.

[0044] In this embodiment, the first adhesive layer 2 and the second adhesive layer 4 are EVA adhesive patches.

[0045] In this embodiment, the EVA adhesive patch comprises the following components: 60 parts of cis-1,4-polyisoprene; 28 parts of dimethylsiloxane; 25 parts of EVA thermoplastic elastomer; 10 parts of zinc borate; 18 parts of graphene; 8 parts of epoxy resin; 24 parts of polyacrylate emulsion; 9 parts of butyl acrylate; 10 parts of glyceryl rosin ester; 3 parts of plasticizer; and 3 parts of curing agent.

[0046] In this embodiment, the display layer 3 is made of silk or silk fabric.

[0047] This embodiment also includes a manufacturing process for durable glass, comprising the following steps:

[0048] S1. Weigh out the following components according to the specified proportions: cis-1,4-polyisoprene, dimethylsiloxane, EVA thermoplastic elastomer, zinc borate, graphene, epoxy resin, polyacrylate emulsion, butyl acrylate, glyceryl rosin ester, plasticizer, and curing agent. Then add cis-1,4-polyisoprene, dimethylsiloxane, and EVA thermoplastic elastomer into a mixer and mix for 60 minutes.

[0049] S2. Add the epoxy resin, polyacrylate emulsion, butyl acrylate, and glyceryl rosin ester weighed in step S1 into the mixing tank in sequence and mix until they are evenly mixed.

[0050] S3. Heat and mix the mixture from step S2 with the mixture from step S1 for 40 minutes, then add zinc borate, graphene, plasticizer, and curing agent in sequence, wherein the heating temperature is 200℃.

[0051] S4. Pour the mixture from step S3 into the mold, then let it stand to cool until it is completely cooled and solidified to form an EVA adhesive patch. Then open the mold and remove the EVA adhesive patch.

[0052] S5. Cut the glass according to the set dimensions to form a first glass layer 1 and a second glass layer 5. Then, both the first glass layer 1 and the second glass layer 5 are subjected to edge grinding, clamping, drilling, semi-tempering, cooling, cleaning, and drying. In the semi-tempering furnace, the upper temperature of the heating zone is 700℃, the lower temperature of the heating zone is 680℃, the heating time is 85s, the cooling air pressure is 40KPA, and the cooling time is 150s. The cooling method can be a cooling air grid.

[0053] S6. Cut EVA adhesive sheets according to the first glass layer 1 and the second glass layer 5 to form the first adhesive layer 2 and the second adhesive layer 4 respectively. Then, stick the first adhesive layer 2 on the first glass layer 1 and stick the second adhesive layer 4 on the second glass layer 5. Then, assemble the first glass layer 1, the display layer 3 and the second glass layer 5 in sequence to complete the assembly.

[0054] S7. The glass laminated in step S6 is placed in a vacuum machine for vacuum treatment to obtain the durable glass of this embodiment.

[0055] This durable glass, due to its multi-layered structure, first undergoes a series of mixing, heating, and molding processes to produce EVA adhesive sheets. After being bonded to the glass, these sheets exhibit excellent sealing and waterproof properties. Then, through cutting, edge grinding, clamping, drilling, semi-tempering, cooling, cleaning, and drying, the first glass layer 1 and the second glass layer 5 of the semi-tempered glass are produced. These first and second glass layers 1 and 5 possess excellent fire and water resistance, high temperature resistance, heat insulation, mechanical strength, toughness, and anti-glare properties. The display layer 3 can be made of silk or fabric with corresponding patterns according to the user's needs. Using the above methods, thinner glass can be produced, with the first glass layer 1 and the second glass layer 5 reaching a thickness of 2mm, and the overall laminated durable glass reaching a thickness of 5mm.

[0056] To protect the outer surfaces of the first glass layer 1 and the second glass layer 5, a glass coating liquid can be applied to the outer surfaces of the first glass layer 1 and the second glass layer 5 to form a protective layer, further protecting the first glass layer 1 and the second glass layer 5 and giving the first glass layer 1 and the second glass layer 5 characteristics such as high temperature resistance, corrosion resistance, and scratch resistance. The components of the glass coating liquid can be silane coupling agent, nano silica, ethanol, and deionized water. The preparation method is as follows: mix silane coupling agent, nano silica, and ethanol in a ratio of 4:1:5, then add an appropriate amount of deionized water and stir directly until completely dissolved. Example 3:

[0057] This embodiment is the best embodiment; see appendix. Figure 1 A durable glass comprises, from bottom to top, a first glass layer 1, a first adhesive layer 2, a display layer 3, a second adhesive layer 4, and a second glass layer 5, wherein the first adhesive layer 2 is used to adhere the first glass layer 1 and the display layer 3, and the second adhesive layer 4 is used to adhere the second glass layer 5 and the display layer 3.

[0058] In this embodiment, the first glass layer 1 and the second glass layer 5 are semi-tempered glass.

[0059] In this embodiment, the first adhesive layer 2 and the second adhesive layer 4 are EVA adhesive patches.

[0060] In this embodiment, the EVA adhesive patch comprises the following components: 45 parts of cis-1,4-polyisoprene; 24 parts of dimethylsiloxane; 20 parts of EVA thermoplastic elastomer; 8 parts of zinc borate; 13 parts of graphene; 6 parts of epoxy resin; 18 parts of polyacrylate emulsion; 7 parts of butyl acrylate; 7 parts of glyceryl rosin ester; 2 parts of plasticizer; and 2 parts of curing agent.

[0061] In this embodiment, the display layer 3 is made of silk or silk fabric.

[0062] This embodiment also includes a manufacturing process for durable glass, comprising the following steps:

[0063] S1. Weigh out the following components according to the specified proportions: cis-1,4-polyisoprene, dimethylsiloxane, EVA thermoplastic elastomer, zinc borate, graphene, epoxy resin, polyacrylate emulsion, butyl acrylate, glyceryl rosin ester, plasticizer, and curing agent. Then add cis-1,4-polyisoprene, dimethylsiloxane, and EVA thermoplastic elastomer into a mixer and mix for 45 minutes.

[0064] S2. Add the epoxy resin, polyacrylate emulsion, butyl acrylate, and glyceryl rosin ester weighed in step S1 into the mixing tank in sequence and mix until they are evenly mixed.

[0065] S3. Heat and mix the mixture from step S2 with the mixture from step S1 for 30 minutes, then add zinc borate, graphene, plasticizer, and curing agent in sequence, wherein the heating temperature is 150℃.

[0066] S4. Pour the mixture from step S3 into the mold, then let it stand to cool until it is completely cooled and solidified to form an EVA adhesive patch, and then open the mold to remove it.

[0067] S5. Cut the glass according to the set dimensions to form a first glass layer 1 and a second glass layer 5. Then, both the first glass layer 1 and the second glass layer 5 are subjected to edge grinding, clamping, drilling, semi-tempering, cooling, cleaning, and drying. In the semi-tempering furnace, the upper temperature of the heating zone is 690℃, the lower temperature of the heating zone is 670℃, the heating time is 82s, the cooling air pressure is 38KPA, and the cooling time is 125s. The cooling method can be a cooling air grid.

[0068] S6. Cut EVA adhesive sheets according to the first glass layer 1 and the second glass layer 5 to form the first adhesive layer 2 and the second adhesive layer 4 respectively. Then, stick the first adhesive layer 2 on the first glass layer 1 and stick the second adhesive layer 4 on the second glass layer 5. Then, assemble the first glass layer 1, the display layer 3 and the second glass layer 5 in sequence to complete the assembly.

[0069] S7. Place the assembled glass from step S6 into a vacuum machine for vacuum treatment.

[0070] This durable glass, due to its multi-layered structure, first undergoes a series of mixing, heating, and molding processes to produce EVA adhesive sheets. After being bonded to the glass, these sheets exhibit excellent sealing and waterproof properties. Then, through cutting, edge grinding, clamping, drilling, semi-tempering, cooling, cleaning, and drying, the first glass layer 1 and the second glass layer 5 of the semi-tempered glass are produced. These first and second glass layers 1 and 5 possess excellent fire and water resistance, high temperature resistance, heat insulation, mechanical strength, toughness, and anti-glare properties. The display layer 3 can be made of silk or fabric with corresponding patterns according to the user's needs. Using the above methods, thinner glass can be produced, with the first glass layer 1 and the second glass layer 5 reaching a thickness of 2mm, and the overall laminated durable glass reaching a thickness of 5mm.

[0071] To protect the outer surfaces of the first glass layer 1 and the second glass layer 5, a glass coating liquid can be applied to the outer surfaces of the first glass layer 1 and the second glass layer 5 to form a protective layer, further protecting the first glass layer 1 and the second glass layer 5 and giving the first glass layer 1 and the second glass layer 5 characteristics such as high temperature resistance, corrosion resistance, and scratch resistance. The components of the glass coating liquid can be silane coupling agent, nano silica, ethanol, and deionized water. The preparation method is as follows: mix silane coupling agent, nano silica, and ethanol in a ratio of 4:1:5, then add an appropriate amount of deionized water and stir directly until completely dissolved.

[0072] The embodiments described above are merely preferred embodiments of the present invention and are not intended to limit the present invention in any way. Any person skilled in the art can make more possible variations and modifications to the technical solutions of the present invention, or modify them into equivalent embodiments, without departing from the scope of the present invention. Therefore, all equivalent changes made based on the concept of the present invention without departing from the scope of the present invention should be covered within the protection scope of the present invention.

Claims

1. A durable glass comprising, from bottom to top, a first glass layer (1), a first adhesive layer (2), a display layer (3), a second adhesive layer (4), and a second glass layer (5), characterized in that: The first adhesive layer (2) is used to adhere the first glass layer (1) to the display layer (3), and the second adhesive layer (4) is used to adhere the second glass layer (5) to the display layer (3). The first adhesive layer (2) and the second adhesive layer (4) are EVA adhesive patches; The EVA adhesive patch comprises the following components: 30-60 parts of cis-1,4-polyisoprene; 20-28 parts of dimethylsiloxane; 15-25 parts of EVA thermoplastic elastomer; 6-10 parts of zinc borate; 8-18 parts of graphene; 4-8 parts of epoxy resin; 12-24 parts of polyacrylate emulsion; 5-9 parts of butyl acrylate; 4-10 parts of glyceryl rosin ester; 1-3 parts of plasticizer; and 1-3 parts of curing agent.

2. The durable glass according to claim 1, wherein: The first glass layer (1) and the second glass layer (5) are semi-tempered glass.

3. The durable glass according to claim 2, wherein: The display layer (3) is made of silk or silk fabric.

4. A durable glass according to claim 3, wherein: 45 parts of cis-1,4-polyisoprene; 24 parts of dimethylsiloxane; 20 parts of EVA thermoplastic elastomer; 8 parts of zinc borate; 13 parts of graphene; 6 parts of epoxy resin; 18 parts of polyacrylate emulsion; 7 parts of butyl acrylate; 7 parts of glyceryl rosin ester; 2 parts of plasticizer; 2 parts of curing agent.

5. A process for producing a durable glass according to claim 4, characterized in that: Includes the following steps: S1. Weigh out the following components according to the specified proportions: cis-1,4-polyisoprene, dimethylsiloxane, EVA thermoplastic elastomer, zinc borate, graphene, epoxy resin, polyacrylate emulsion, butyl acrylate, glyceryl rosin ester, plasticizer, and curing agent. Then add cis-1,4-polyisoprene, dimethylsiloxane, and EVA thermoplastic elastomer into a mixer and mix for 30-60 minutes. S2. Add the epoxy resin, polyacrylate emulsion, butyl acrylate and glyceryl rosin ester weighed in step S1 into the mixing tank in sequence and mix until they are evenly mixed. S3. Heat and mix the mixture from step S2 with the mixture from step S1 for 20-40 minutes, then add zinc borate, graphene, plasticizer, and curing agent in sequence, wherein the heating temperature is 100-200℃. S4. Pour the mixture from step S3 into the mold, then let it stand to cool until it is completely cooled and solidified to form an EVA adhesive patch, and then open the mold to remove it; S5. Cut the glass according to the set size to form a first glass layer (1) and a second glass layer (5). Then, both the first glass layer (1) and the second glass layer (5) are ground, clamped, drilled, semi-tempered, cooled, cleaned and dried. In the semi-tempered tempering furnace, the upper temperature of the heating zone is 680-700℃, the lower temperature of the heating zone is 660-680℃, the heating time is 80-85s, the cooling air pressure is 35-40kPa, and the cooling time is 100-150s. S6. Cut EVA adhesive sheets according to the first glass layer (1) and the second glass layer (5) to form the first adhesive layer (2) and the second adhesive layer (4) respectively. Then, stick the first adhesive layer (2) on the first glass layer (1) and stick the second adhesive layer (4) on the second glass layer (5). Then, combine the first glass layer (1), the display layer (3) and the second glass layer (5) in sequence to complete the assembly. S7. Place the assembled glass from step S6 into a vacuum machine for vacuum treatment.

6. A process for producing a durable glass according to claim 5, characterized in that: Stir for 45 minutes in step S1.

7. A process for producing a durable glass according to claim 5, characterized in that: Stir for 30 minutes in step S3 and heat at 150°C.

8. The manufacturing process for durable glass according to claim 5, characterized in that: In step S5, the upper temperature of the heating zone is 690℃, the lower temperature of the heating zone is 670℃, the heating time is 82s, the cooling air pressure is 38kPa, and the cooling time is 125s.

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