A method for preparing camel hair antibacterial yarn and camel hair antibacterial yarn

By mixing three types of camel hair fibers and combining them with photosensitizer treatment, camel hair antibacterial yarn is prepared, which solves the problems of camel hair fibers being easily moldy and insect-eaten and having insufficient antibacterial rate, and achieves color diversity and high-efficiency antibacterial effect.

CN117684304BActive Publication Date: 2025-09-16XINJIANG UNIVERSITY
View PDF 2 Cites 0 Cited by

Patent Information

Application Number
CN202311552138.8
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-11-21
Publication Date
2025-09-16
Estimated Expiration
2043-11-21

AI Technical Summary

Technical Problem

Camel hair fiber is prone to mildew and insect damage, the yarn is monotonous in color, and its antibacterial rate against Staphylococcus aureus and Escherichia coli cannot reach 99.9%.

Method used

Three camel hair fiber bundles of different colors are mixed, and the photosensitizer Bengal rose red is loaded on the surface of the decolorized fiber. Combined with the drawing, roving and spinning processes, camel hair antibacterial yarn is prepared to ensure an antibacterial rate of 99.9%.

Benefits of technology

While ensuring the antibacterial effect, the bright colors caused by the photosensitizer in the soft yarn improve the color diversity and antibacterial properties of the camel hair yarn.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN117684304B_ABST
    Figure CN117684304B_ABST
Patent Text Reader

Abstract

The present application discloses a method for preparing camel hair antibacterial yarn and camel hair antibacterial yarn. The camel hair antibacterial yarn preparation method comprises: obtaining a fiber mixing ratio of a first camel hair fiber bundle, a second camel hair fiber bundle, and a third camel hair fiber bundle; producing the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle respectively; uniformly mixing the produced first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle to obtain a mixed fiber; using a drawing machine to straighten and parallelize the fibers within the mixed fiber; and obtaining the camel hair antibacterial yarn through coarse and fine spinning processes. The camel hair antibacterial yarn prepared by the camel hair antibacterial yarn preparation method of the present application is spun from a blend of three different colored fibers, which ensures an antibacterial effect while mitigating the overly bright color caused by the photosensitizer in the yarn.
Need to check novelty before this filing date? Find Prior Art

Description

Technical Field

[0001] The present application relates to the technical field of textile material preparation, and in particular to a method for preparing camel hair antibacterial yarn and the camel hair antibacterial yarn. Background Art

[0002] Camel hair is elastic, not easy to shrink, and has a smooth surface. The products made from it are light, soft, comfortable and warm. However, camel hair itself has a darker color (brown yellow, i.e. camel color), which makes the products processed from it monotonous in color and single in variety, making the added value of camel hair products low. Moreover, camel hair, as a protein-based fiber raw material, is prone to mildew and insect damage.

[0003] Existing camel hair fibers are prone to mildew and insect damage, their yarns are monotonous in color, and their antibacterial rates against Staphylococcus aureus and Escherichia coli cannot reach 99.9%.

[0004] Therefore, it is hoped that there will be a technical solution to solve or at least alleviate the above-mentioned deficiencies in the prior art. Summary of the Invention

[0005] The object of the present invention is to provide a method for preparing camel hair antibacterial yarn to at least solve one of the above technical problems.

[0006] One aspect of the present invention provides a method for preparing camel hair antibacterial yarn, the method comprising:

[0007] Obtaining a fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle;

[0008] respectively producing a first camel hair fiber bundle, a second camel hair fiber bundle, and a third camel hair fiber bundle;

[0009] uniformly mixing the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle to obtain mixed fibers;

[0010] A drawing frame is used to straighten and parallelize the fibers inside the blended fiber;

[0011] Camel hair antibacterial yarn is obtained through coarse yarn and fine yarn process.

[0012] Optionally, the fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle and the third camel hair fiber bundle is obtained by the following method:

[0013] Obtaining the wavelength corresponding to the peak value of the K / S value of the third camel hair fiber bundle in the range of 400 nm to 700 nm with a wavelength interval of 5 nm, which is referred to as the wavelength to be used;

[0014] Obtaining a K / S value of the first camel hair fiber bundle and a K / S value of the second camel hair fiber bundle at a wavelength to be used;

[0015] Obtaining a relationship between K / S values ​​of the mixed color fiber according to the K / S values ​​of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle;

[0016] Under the wavelength to be used, the K / S value corresponding to the lowest photosensitizer concentration at which the antibacterial rate of the mixed fiber against Staphylococcus aureus and Escherichia coli reaches 99.9% is obtained by testing the K / S values ​​of the third camel hair fiber bundle at different photosensitizer concentrations;

[0017] According to the K / S values ​​of the first camel hair fiber bundle, the second camel hair fiber bundle and the third camel hair fiber bundle and their relationship with the K / S value of the mixed color fiber, the fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle and the third camel hair fiber bundle is obtained when the antibacterial rate of the mixed color fiber against Staphylococcus aureus and Escherichia coli reaches 99.9%.

[0018] Optionally, the step of testing the K / S values ​​of the third camel hair fiber bundle at different photosensitizer concentrations to obtain the K / S value corresponding to the lowest photosensitizer concentration at which the antibacterial rate of the mixed fiber against Staphylococcus aureus and Escherichia coli reaches 99.9% comprises:

[0019] The K / S value of the third fiber bundle loaded with different concentrations of the photosensitizer Bengal Rose was tested, and the antibacterial performance of the third fiber bundle at different K / S values ​​was tested to obtain the K / S value corresponding to the lowest photosensitizer concentration when the antibacterial performance reached 99.9%.

[0020] Optionally, the testing of the K / S value of the third fiber bundle when loaded with different concentrations of the photosensitizer Rose Bengal, and testing the antibacterial performance of the third fiber bundle at different K / S values ​​and obtaining the K / S value corresponding to the lowest photosensitizer concentration when the antibacterial performance reaches 99.9% includes:

[0021] Set up three parallel groups, put the antibacterial yarn into 24-well plates, add 100ul containing 10 4 -10 5 CFU / ml of bacterial solution, and 100 μl of bacterial solution was also added to the three adjacent blank wells as blank samples. After inoculation, the 24-well plate was irradiated under a xenon lamp equipped with a filter at a sample distance of 20 cm;

[0022] After the illumination period, 900 μl of autoclaved PBS was added to each well of a 24-well plate and manually stirred for 10 seconds using a pipette to resuspend the bacteria. The bacterial solution in each sample was then diluted five times at a 1:10 ratio, and 100 μl was scraped from each gradient onto the circular plate. The inoculated circular plates were then incubated at 37°C overnight.

[0023] The visible colonies on the circular plates were counted, and the bacterial survival rate after illumination was determined by the ratio of the colony counts on the circular plate of the light-irradiated antibacterial yarn to the colony count on the circular plate of the colony blank.

[0024] Optionally, the preparing the first camel hair fiber bundle includes:

[0025] The camel hair fibers were washed three times in 50° C. water to obtain a first fiber bundle.

[0026] Optionally, the preparing the second camel hair fiber bundle includes:

[0027] The camel hair fiber is chemically bleached to obtain bleached camel hair fiber, which is the second fiber bundle.

[0028] Optionally, preparing the third camel hair fiber bundle includes:

[0029] The photosensitizer Bengal rose is loaded on the surface of the decolorized fiber, that is, the third fiber bundle is dyed.

[0030] Optionally, the content of the photosensitizer Rose Bengal is not less than 3% owf.

[0031] The present application also provides a camel hair antibacterial yarn, which is prepared by the camel hair antibacterial yarn preparation method as described above.

[0032] Beneficial effects

[0033] The camel hair antibacterial yarn prepared by the camel hair antibacterial yarn preparation method of the present application is made by mixing and spinning fibers of three different colors. While ensuring the antibacterial effect, the overly bright color caused by the photosensitizer in the yarn is softened. BRIEF DESCRIPTION OF THE DRAWINGS

[0034] Figure 1 This is a schematic flow chart of a method for preparing camel hair antibacterial yarn provided in one embodiment of the present application.

[0035] Figure 2 This is a schematic diagram of the cross-sectional structure of the camel hair antibacterial yarn according to an embodiment of the present application. DETAILED DESCRIPTION

[0036] In order to make the purpose, technical solutions and advantages of the implementation of this application clearer, the technical solutions in the embodiments of this application will be described in more detail below in conjunction with the drawings in the embodiments of this application. In the drawings, the same or similar reference numerals throughout represent the same or similar elements or elements with the same or similar functions. The described embodiments are part of the embodiments of this application, not all of the embodiments. The embodiments described below with reference to the drawings are exemplary and are intended to be used to explain this application, and should not be understood as limitations on this application. Based on the embodiments in this application, all other embodiments obtained by ordinary technicians in this field without making creative work are within the scope of protection of this application. The embodiments of this application are described in detail below in conjunction with the drawings.

[0037] Figure 1 This is a schematic flow chart of a method for preparing camel hair antibacterial yarn provided in one embodiment of the present application.

[0038] like Figure 1 The method for preparing the camel hair antibacterial yarn includes:

[0039] Obtaining a fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle;

[0040] respectively producing a first camel hair fiber bundle, a second camel hair fiber bundle, and a third camel hair fiber bundle;

[0041] uniformly mixing the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle to obtain mixed fibers;

[0042] A drawing frame is used to straighten and parallelize the fibers inside the blended fiber;

[0043] Camel hair antibacterial yarn is obtained through coarse yarn and fine yarn process.

[0044] The camel hair antibacterial yarn prepared by the camel hair antibacterial yarn preparation method of the present application is made by mixing and spinning fibers of three different colors. While ensuring the antibacterial effect, the overly bright color caused by the photosensitizer in the yarn is softened.

[0045] In this embodiment, the fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle is obtained by the following method:

[0046] Obtaining the wavelength corresponding to the peak value of the K / S value of the third camel hair fiber bundle in the range of 400 nm to 700 nm with a wavelength interval of 5 nm, which is referred to as the wavelength to be used;

[0047] Obtaining a K / S value of the first camel hair fiber bundle and a K / S value of the second camel hair fiber bundle at a wavelength to be used;

[0048] Obtaining a relationship between K / S values ​​of the mixed color fiber according to the K / S values ​​of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle;

[0049] Under the wavelength to be used, the K / S value corresponding to the lowest photosensitizer concentration at which the antibacterial rate of the mixed fiber against Staphylococcus aureus and Escherichia coli reaches 99.9% is obtained by testing the K / S values ​​of the third camel hair fiber bundle at different photosensitizer concentrations;

[0050] According to the K / S values ​​of the first camel hair fiber bundle, the second camel hair fiber bundle and the third camel hair fiber bundle and their relationship with the K / S value of the mixed color fiber, the fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle and the third camel hair fiber bundle is obtained when the antibacterial rate of the mixed color fiber against Staphylococcus aureus and Escherichia coli reaches 99.9%.

[0051] In this way, we can accurately know at what ratio the mixed-color fiber can achieve an antibacterial rate of 99.9% against Staphylococcus aureus and Escherichia coli.

[0052] In this embodiment, the K / S value corresponding to the minimum photosensitizer concentration at which the antibacterial rate of the mixed fiber against Staphylococcus aureus and Escherichia coli reaches 99.9% is obtained by testing the K / S values ​​of the third camel hair fiber bundle at different photosensitizer concentrations. The K / S value includes:

[0053] The K / S value of the third fiber bundle loaded with different concentrations of the photosensitizer Bengal Rose was tested, and the antibacterial performance of the third fiber bundle at different K / S values ​​was tested to obtain the K / S value corresponding to the lowest photosensitizer concentration when the antibacterial performance reached 99.9%.

[0054] In this embodiment, the testing of the K / S value of the third fiber bundle when loaded with the photosensitizer Rose Bengal at different concentrations, the testing of the antibacterial performance of the third fiber bundle at different K / S values, and the obtaining of the K / S value corresponding to the lowest photosensitizer concentration at which the antibacterial performance reaches 99.9% include:

[0055] Set up three parallel groups, put the antibacterial yarn into 24-well plates, add 100ul containing 10 4 -10 5 CFU / ml of bacterial solution, and 100 μl of bacterial solution was also added to the three adjacent blank wells as blank samples. After inoculation, the 24-well plate was irradiated under a xenon lamp equipped with a filter at a sample distance of 20 cm;

[0056] After the illumination period, 900 μl of autoclaved PBS was added to each well of a 24-well plate and manually stirred for 10 seconds using a pipette to resuspend the bacteria. The bacterial solution in each sample was then diluted five times at a 1:10 ratio, and 100 μl was scraped from each gradient onto the circular plate. The inoculated circular plates were then incubated at 37°C overnight.

[0057] The visible colonies on the circular plates were counted, and the bacterial survival rate after illumination was determined by the ratio of the colony counts on the circular plate of the light-irradiated antibacterial yarn to the colony count on the circular plate of the colony blank.

[0058] In this embodiment, preparing the first camel hair fiber bundle includes:

[0059] The camel hair fibers were washed three times in 50° C. water to obtain a first fiber bundle.

[0060] In this embodiment, preparing the second camel hair fiber bundle includes:

[0061] The camel hair fiber is chemically bleached to become decolorized fiber, which is the second fiber bundle.

[0062] In this embodiment, preparing the third camel hair fiber bundle includes:

[0063] The photosensitizer Bengal rose is loaded on the surface of the decolorized fiber, that is, the third fiber bundle is dyed.

[0064] In this embodiment, the content of the photosensitizer Rose Bengal is no less than 3% owf.

[0065] The present application is further described in detail below by way of examples. It should be understood that the examples do not constitute any limitation to the present application.

[0066] The preparation method of camel hair antibacterial yarn includes:

[0067] Obtaining a fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle;

[0068] respectively producing a first camel hair fiber bundle, a second camel hair fiber bundle, and a third camel hair fiber bundle;

[0069] uniformly mixing the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle to obtain mixed fibers;

[0070] A drawing frame is used to straighten and parallelize the fibers inside the blended fiber;

[0071] Camel hair antibacterial yarn is obtained through coarse yarn and fine yarn process.

[0072] In this embodiment, the fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle is obtained by the following method:

[0073] Obtaining the wavelength corresponding to the peak value of the K / S value of the third camel hair fiber bundle in the range of 400 nm to 700 nm with a wavelength interval of 5 nm, which is referred to as the wavelength to be used;

[0074] Obtaining a K / S value of the first camel hair fiber bundle and a K / S value of the second camel hair fiber bundle at a wavelength to be used;

[0075] Obtaining a relationship between K / S values ​​of the mixed color fiber according to the K / S values ​​of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle;

[0076] Under the wavelength to be used, the K / S value corresponding to the lowest photosensitizer concentration at which the antibacterial rate of the mixed fiber against Staphylococcus aureus and Escherichia coli reaches 99.9% is obtained by testing the K / S values ​​of the third camel hair fiber bundle at different photosensitizer concentrations;

[0077] According to the K / S values ​​of the first camel hair fiber bundle, the second camel hair fiber bundle and the third camel hair fiber bundle and their relationship with the K / S value of the mixed color fiber, the fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle and the third camel hair fiber bundle is obtained when the antibacterial rate of the mixed color fiber against Staphylococcus aureus and Escherichia coli reaches 99.9%.

[0078] In this embodiment, it can be obtained from the Kubel-Kamunck (KM) theory:

[0079] Where: (K / S)λ is the ratio of the absorption coefficient to the scattering coefficient of the fiber at wavelength λ; R λ is the reflectivity of the fiber at a certain wavelength.

[0080] In this embodiment, the K / S value of the mixed color fiber at a wavelength interval of 5 nm from 400 nm to 700 nm has the following relationship with the K / S value of the single color fiber:

[0081] (K / S) λ =C1(K / S) λ +C2(K / S) λ +…+C n (K / S) λ (Formula 1-2)

[0082] C1+C2+…+C n =1 (Formula 1-3)

[0083] Where: (K / S) λIt is the ratio of the absorption coefficient to the scattering coefficient of the mixed-color fiber and the single-color fiber at a certain wavelength; C is the proportion of single-color fiber in the mixed-color fiber.

[0084] In this embodiment, it is found through testing that, under the wavelength conditions to be used, by testing the various K / S values ​​of the third camel hair fiber bundle at different photosensitizer concentrations, the K / S value corresponding to the minimum photosensitizer concentration that can make the antibacterial rate of the mixed fiber against Staphylococcus aureus and Escherichia coli reach 99.9% is obtained. In this embodiment, when the K / S value is greater than 25 at 560nm, the antibacterial rate of the fiber against Staphylococcus aureus and Escherichia coli reaches 99.9%.

[0085] In this embodiment, the proportional relationship between the three fiber bundles is obtained based on the K / S values ​​of the three fiber bundles measured in S1, as well as Formula 1-1, Formula 1-2, Formula 1-3 and the mixed fiber K / S value of 25:

[0086]

[0087] Wherein, C1 represents the first camel hair fiber bundle, C2 represents the second camel hair fiber bundle, and C3 represents the third camel hair fiber bundle.

[0088] In this embodiment, the testing of the K / S value of the third fiber bundle when loaded with the photosensitizer Rose Bengal at different concentrations, the testing of the antibacterial performance of the third fiber bundle at different K / S values, and the obtaining of the K / S value corresponding to the lowest photosensitizer concentration at which the antibacterial performance reaches 99.9% include:

[0089] S1. Set up three parallel groups, put the antibacterial yarn (about 30 mg) into 24-well plates, add 100 μl of 10 4 -10 5 CFU / ml of bacterial solution, 100 μl of bacterial solution was also added to the three adjacent blank wells as blank samples. After inoculation, the 24-well plate was illuminated for a certain period of time under a xenon lamp (300 W) equipped with a filter (λ ≥ 420 nm) at a distance of 20 cm from the sample;

[0090] After illumination, add 900 μL of autoclaved PBS (phosphate-buffered saline) to each well of a 24-well plate and manually agitate for 10 seconds to resuspend the bacteria. Subsequently, dilute the bacterial solution from each sample five times at a 1:10 ratio (add 100 μL of the solution to the next dilution gradient of 900 μL of PBS). Scrape 100 μL of the solution from each gradient onto a circular plate (using LB-agar medium) and incubate the inoculated circular plates overnight at 37°C.

[0091] S3. Count the visible colonies on the circular plates. The bacterial survival rate after illumination is determined by the ratio of the colony counts on the circular plate with the antibacterial yarn to the colony count on the circular plate with the blank sample.

[0092] In this embodiment, preparing the first camel hair fiber bundle includes: washing the camel hair fibers in 50° C. water three times to obtain the first fiber bundle.

[0093] In this embodiment, making the second camel hair fiber bundle includes: chemically bleaching the camel hair fibers into bleached camel hair fibers, namely the second fiber bundle;

[0094] In this embodiment, the preparation of the third camel hair fiber bundle includes: dyeing the decolorized fiber surface with the photosensitizer Rose Bengal and the groups on the fiber through the action of covalent bonds, thereby dyeing the third fiber bundle.

[0095] In this embodiment, the content of the photosensitizer Rose Bengal is not less than 3% owf.

[0096] In this embodiment, using a drawing frame to straighten and parallelize the fibers inside the mixed fiber includes:

[0097] A drawing frame is used to straighten and parallelize the fibers, and at least three blending processes are used to fully mix them and reduce color difference.

[0098] In this embodiment, the camel hair antibacterial yarn is obtained through the roving and spun yarn processes, including:

[0099] Yarn is obtained through coarse yarn and fine yarn processes; the coarse yarn adopts the process principle of "heavy pressure, small rear zone drafting, and large twist coefficient", appropriately reduces the machine speed, and the process configuration concentrates on the front zone drafting to facilitate the control of floating fibers and improve the yarn quality; the fine yarn uses a larger twist coefficient to increase the density of the yarn in the spinning section, reduce the twisting triangle area, control the temperature and humidity in the workshop, reduce the yarn hairiness, and improve the yarn strength.

[0100] In this embodiment, camel hair fibers are treated by chemical bleaching. During this process, the whiteness of the fibers is improved and the strength is reduced. By optimizing the bleaching process, the damage to the fiber strength during this process is reduced.

[0101] When the third fiber bundle is loaded with the photosensitizer Bengal rose red, the photosensitizer can combine with the fiber surface groups through van der Waals forces and hydrogen bonds under weakly acidic conditions, thereby being loaded on the camel hair fiber, giving the second fiber bundle antibacterial properties under visible light. The loading ratio is not less than 3% owf, thereby ensuring the antibacterial effect of the fiber bundle.

[0102] The proportions of the first fiber bundle, the second fiber bundle, and the third fiber bundle in the mixed fiber are calculated using the KM theory.

[0103] The present application also provides a camel hair antibacterial yarn, which is prepared by the camel hair antibacterial yarn preparation method as described above.

[0104] The present invention loads the photosensitizer on the fiber by combining it with the fiber surface groups through van der Waals forces and hydrogen bonds, giving it the ability to effectively resist bacteria and other microorganisms on the yarn surface under visible light. It is made by blending three fibers of different colors, which not only ensures the antibacterial effect but also softens the overly bright color caused by the photosensitizer in the yarn.

[0105] It should be noted that, in this document, relational terms such as first and second, etc., are used only to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply any actual relationship or order between these entities or operations. Moreover, the terms "comprises", "includes" or any other variants thereof are intended to cover non-exclusive inclusion, so that a process, method, article or device that includes a series of elements includes not only those elements, but also other elements that are not explicitly listed, or also includes elements that are inherent to such process, method, article or device. In addition, it is clear that the word "comprises" does not exclude other units or steps. The multiple units, modules or devices stated in the device claim may also be implemented by one unit or overall device through software or hardware.

[0106] Although the present invention has been described in detail above using general descriptions and specific embodiments, it will be apparent to those skilled in the art that modifications and improvements may be made based on the present invention. Therefore, such modifications and improvements, which do not depart from the spirit of the present invention, are intended to be within the scope of protection claimed herein.

Claims

1. A method for preparing camel hair antibacterial yarn, characterized in that: The method for preparing the camel hair antibacterial yarn comprises: Obtaining a fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle; respectively producing a first camel hair fiber bundle, a second camel hair fiber bundle, and a third camel hair fiber bundle; uniformly mixing the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle to obtain mixed fibers; A drawing frame is used to straighten and parallelize the fibers inside the blended fiber; Camel hair antibacterial yarn is obtained through coarse and fine yarn processes; The fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle is obtained by the following method: Obtaining the wavelength corresponding to the peak value of the K / S value of the third camel hair fiber bundle in the range of 400 nm to 700 nm with a wavelength interval of 5 nm, which is referred to as the wavelength to be used; Obtaining a K / S value of the first camel hair fiber bundle and a K / S value of the second camel hair fiber bundle at a wavelength to be used; Obtaining a relationship between K / S values ​​of the mixed color fiber according to the K / S values ​​of the first camel hair fiber bundle, the second camel hair fiber bundle, and the third camel hair fiber bundle; Under the wavelength to be used, the K / S value corresponding to the lowest photosensitizer concentration at which the antibacterial rate of the mixed fiber against Staphylococcus aureus and Escherichia coli reaches 99.9% is obtained by testing the K / S values ​​of the third camel hair fiber bundle at different photosensitizer concentrations; According to the K / S values ​​of the first camel hair fiber bundle, the second camel hair fiber bundle and the third camel hair fiber bundle and their relationship with the K / S value of the mixed fiber, the fiber mixing ratio of the first camel hair fiber bundle, the second camel hair fiber bundle and the third camel hair fiber bundle is obtained when the antibacterial rate of the mixed fiber against Staphylococcus aureus and Escherichia coli reaches 99.9%.

2. The method for preparing camel hair antibacterial yarn according to claim 1, wherein: The K / S value corresponding to the minimum photosensitizer concentration at which the antibacterial rate of the mixed fiber against Staphylococcus aureus and Escherichia coli reaches 99.9% is obtained by testing the K / S values ​​of the third camel hair fiber bundle at different photosensitizer concentrations. The K / S value includes: The K / S value of the third fiber bundle loaded with different concentrations of photosensitizer Bengal Rose Red was tested, and the antibacterial performance of the third camel hair fiber bundle at different K / S values ​​was tested, and the K / S value corresponding to the lowest photosensitizer concentration when the antibacterial performance reached 99.9% was obtained.

3. The method for preparing camel hair antibacterial yarn according to claim 2, wherein: The testing of the K / S value of the third fiber bundle when loaded with the photosensitizer Rose Bengal at different concentrations, testing the antibacterial performance of the third fiber bundle at different K / S values, and obtaining the K / S value corresponding to the lowest photosensitizer concentration when the antibacterial performance reaches 99.9% includes: Set up three parallel groups, put the antibacterial yarn into 24-well plates, add 100ul containing 10 4 -10 5 CFU / ml of bacterial solution, and 100 μl of bacterial solution was also added to the three adjacent blank wells as blank samples. After inoculation, the 24-well plate was irradiated under a xenon lamp equipped with a filter at a sample distance of 20 cm; After the illumination period, 900 μl of autoclaved PBS was added to each well of a 24-well plate and manually stirred for 10 seconds using a pipette to resuspend the bacteria. The bacterial solution in each sample was then diluted five times at a 1:10 ratio, and 100 μl was scraped from each gradient onto the circular plate. The inoculated circular plates were then incubated at 37°C overnight. The visible colonies on the circular plates were counted, and the bacterial survival rate after illumination was determined by the ratio of the colony counts on the circular plate of the light-irradiated antibacterial yarn to the colony count on the circular plate of the colony blank.

4. The method for preparing camel hair antibacterial yarn according to claim 3, wherein: The preparation of the first camel hair fiber bundle comprises: The camel hair fibers were washed three times in 50° C. water to obtain a first fiber bundle.

5. The method for preparing camel hair antibacterial yarn according to claim 4, wherein: The preparation of the second camel hair fiber bundle comprises: The camel hair fiber is chemically bleached to obtain bleached camel hair fiber, which is the second fiber bundle.

6. The method for preparing camel hair antibacterial yarn according to claim 5, wherein: The preparation of the third camel hair fiber bundle comprises: The photosensitizer Bengal rose is loaded on the surface of the decolorized fiber, that is, the third fiber bundle is dyed.

7. The method for preparing camel hair antibacterial yarn according to claim 6, wherein: The content of the photosensitizer Bengal rose is not less than 3% owf.

8. A camel hair antibacterial yarn, characterized in that: The camel hair antibacterial yarn is prepared by the camel hair antibacterial yarn preparation method according to any one of claims 1 to 7.

Citation Information

Patent Citations

  • Multicolor antibacterial polyester-cotton fabric and preparation method thereof

    CN116856184A

  • Light-activated antimicrobial article and method of use

    WO2011008441A1