Acrylate emulsion as well as preparation method and application thereof

High solid content acrylate emulsion is prepared through seed emulsion polymerization technology, which is used to prepare pressure-sensitive adhesives, which solves the problem of slow drying speed of emulsion-type pressure-sensitive adhesives, and achieves faster drying speed and better bonding strength.

CN119638901APending Publication Date: 2025-03-18CHINA PETROLEUM & CHEMICAL CORP +1
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Patent Information

Application Number
CN202311199459.4
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-09-15
Publication Date
2025-03-18

AI Technical Summary

Technical Problem

The drying problem of existing emulsion-type pressure-sensitive adhesives is prominent, especially in pressure-sensitive adhesive products with large amounts of glue, which leads to a slow drying speed and is difficult to achieve the thickness required by the product.

Method used

A preparation method of an acrylate emulsion is adopted to form a core-shell structure emulsion with a high solid content through seed emulsion polymerization, and the solid content of the emulsion is increased to more than 60 wt%, and is used to prepare pressure-sensitive adhesives. The method includes contacting the seed emulsion monomer and other emulsifiers in the presence of a first initiator, forming material A and material B, and adding a fourth anionic emulsifier after the polymerization reaction, adjusting the pH to 8-9, to obtain an acrylate emulsion.

Benefits of technology

The drying speed of the pressure-sensitive adhesive is improved, the glueing process is reduced, and the film is transparent and bubble-free, improving the bonding strength.

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Abstract

The invention relates to the field of emulsion polymerization, and discloses an acrylate emulsion and a preparation method and application thereof.According to the method, an emulsion with the high solid content is prepared through seed emulsion polymerization, and an emulsion with the solid content reaching 60 wt% is synthesized and used as a pressure-sensitive adhesive, and the drying speed can be increased. Core-shell particles are formed through seed emulsion polymerization, and the polymer composition of seeds in a core region is different from the polymer composition of a shell layer, so that the bonding strength can be improved.
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