Calcium phosphate stone as well as preparation method and application thereof

By preparing and applying calcium phosphate to absorb and convert lead elements released in perovskite solar cells, the problem of difficulty in removing and recycling lead elements in the prior art is solved, and efficient lead element reuse and environmental protection effects are achieved.

CN119706776APending Publication Date: 2025-03-28LANZHOU UNIV
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Patent Information

Application Number
CN202411803620.9
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-09
Publication Date
2025-03-28

AI Technical Summary

Technical Problem

The prior art is difficult to effectively remove the lead element released after aging in perovskite solar cells, and the recycling of lead element cannot be achieved, resulting in high environmental pollution and manufacturing costs.

Method used

By preparing a calcium phosphate stone with the chemical formula of CaxMgy(HPO4)z(PO4)2(x+y-z)/3, the material is used to absorb the lead ions in the leaching solution of the battery, and the absorbed lead ions are released by solution stirring method, and converted into lead iodide for reuse.

Benefits of technology

It realizes efficient absorption and reuse of lead elements, reduces the preparation cost of perovskite solar cells, reduces environmental pollution, and improves the recycling rate of resources.

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Abstract

The invention provides a calcium phosphate stone and a preparation method and application thereof, the chemical formula of the calcium phosphate stone is CaxMgy (HPO4) z (PO4) 2 (x + y-z) / 3, X is more than or equal to 5 and less than or equal to 20, Y is more than or equal to 0.1 and less than or equal to 5, and Z is more than or equal to 0 and less than or equal to 3. The calcium phosphate stone is efficiently synthesized through the simple preparation method, then the calcium phosphate stone is used for absorbing the lead element released by the aged perovskite solar cell device through the solution stirring method, lead iodide is prepared again for reuse, the process is simple, the cost is low, and environmental pollution is reduced.
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