Production method of cyclohexylbenzene

By using a metal/USY molecular sieve catalyst to carry out the alkyl transfer reaction between benzene and polycyclohexylbenzene under a hydrogen atmosphere, the problems of high reaction temperature, low selectivity and short catalyst life in the prior art are solved, and a high-efficiency and low-energy consumption preparation of cyclohexylbenzene is achieved.

CN119707620AActive Publication Date: 2025-03-28CHINA PETROLEUM & CHEMICAL CORP +1
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Patent Information

Application Number
CN202311269582.9
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-09-28
Publication Date
2025-03-28
Estimated Expiration
2043-09-28

AI Technical Summary

Technical Problem

In the prior art, the transfer reaction between benzene and polycyclohexylbenzene alkyl has problems such as high reaction temperature, low selectivity of cyclohexylbenzene, high selectivity of methylcyclopentylbenzene by-product, and short catalyst life.

Method used

The metal/USY molecular sieve is used as a catalyst to carry out an alkyl transfer reaction under a hydrogen atmosphere. By adjusting the composition and process conditions of the catalyst, the reaction temperature is reduced, the catalyst life is extended, and the formation of key impurities is reduced.

Benefits of technology

It realizes efficient preparation of cyclohexylbenzene at lower reaction temperatures, improves the selectivity and product purity of cyclohexylbenzene, extends the service life of the catalyst, and reduces separation energy consumption.

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Abstract

The invention discloses a production method of cyclohexylbenzene. According to the method, benzene and dicyclohexylbenzene are used as raw materials, a metal / USY molecular sieve is used as a catalyst, in a hydrogen atmosphere, a transalkylation reaction is carried out to prepare cyclohexylbenzene, and the molar ratio of hydrogen to benzene is 0.1-1.0. According to the method disclosed by the invention, relatively high dicyclohexylbenzene conversion rate and relatively high cyclohexylbenzene selectivity can be obtained at relatively low reaction temperature, and the yield of cyclohexylbenzene is improved.
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