58results about "Hydrocarbon by saturated bond conversion" patented technology

The invention relates to a process for carrying out metathesis reactions, wherein the process is carried out continuously and a ruthenium-containing catalyst is used.

A catalyst composition includes an oxygen compound of an element selected from Group IVB or Group IVA of the Periodic Table of the Elements; an oxygen compound of an element selected from Group VIB or Group VIA of the Periodic Table of the Elements; and at least about 1% by weight based upon total catalyst weight of fumed silica particles. The catalyst composition is advantageously employed in hydrocarbon conversion processes such as isomerization.

The invention is directed to methods of starting up reaction systems. The reaction systems are those that use catalysts that comprise molecular sieves, particularly metalloaluminophosphate molecular sieves, especially metalloaluminophosphate molecular sieves which are susceptible to loss of catalytic activity due to contact with water molecules. The methods provide appropriate mechanisms of heating and loading the activated molecular sieves to protect against loss of catalytic activity that can occur due to contact with water molecules.

A method of converting at least one first alkane to a mixture of at least one low molecular weight alkane (optionally also including additional lower and / or higher molecular weight alkanes) and at least one high molecular weight alkane, comprising: reacting a first alkane in the presence of dual catalyst system comprising a first catalyst (i.e., a hydrogen transfer catalyst and preferably an iridium pincer complex catalyst) and a second catalyst (i.e., a metathesis catalyst) to produce a mixture of low and high molecular weight alkanes.

A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a sulfated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component of at least one lanthanide element or yttrium component, which is preferably ytterbium, and at least one platinum-group metal component which is preferably platinum and a refractory-oxide binder having at least one platinum-group metal component dispersed thereon.

A porous silicon implant impregnated with a beneficial substance, such as a micromineral required for healthy physiology, is implanted subcutaneously and is entirely corroded away over the following months / year to release the micromineral in a controlled manner. In a second embodiment the implant may have a large number of holes which contain beneficial substance and which are closed by bio-errordable doors of different thickness so as to stagger the release of the beneficial substance over time as the doors are breached.

A process for increasing a yield of an isomerization zone by removing at least a portion of the C6 cyclic hydrocarbons from a stream prior to it being passed into the isomerization zone. Additionally, disproportionation reaction selectivity is also increased, producing valuable C3 hydrocarbons and C4 hydrocarbons. Also, a higher ring opening conversion of C5 cyclic hydrocarbons is observed. The isomerization zone may have an average operating temperature of at least 176° C. and an outlet molar ratio of hydrogen to hydrocarbon feed in the isomerization zone is less than about 0.2.

An apparatus is provided for directing a fluid in a radial reactor comprising: a vertically elongated conduit comprising a front face comprising a surface comprising apertures, two side faces, and a rear face and two ends, wherein an end of the front face and an end of the rear face are a distance D1 apart and wherein a second opposite end of the front face and a second corresponding end of the rear face are a distance D2 apart wherein D1 is greater than D2 and wherein a riser are connected to a top surface of said vertically elongated conduit to allow a gas stream to flow through the riser to the vertically elongated conduit.

Processes for the disproportionation and isomerization of a C7 hydrocarbon feed using a liquid catalyst comprising an ionic liquid and a carbocation promoter are described. The ionic liquid is unsupported, and the reactions occur at temperatures below about 200° C.

The invention relates to a method for improving yield of ethylene and propylene, which solves the problem of low yield of ethylene and propylene during lower olefins preparing process from conversion of methanol and dimethyl ether. The invention uses at least one of methanol and dimethyl ether and C4 hydrocarbon as materials, the materials enter into a reaction region from a distributor at the bottom of a fluidization bed reactor or from at least a position axially separated along the reaction region, and contact and react with a catalyst to generate an effluent containing ethylene, propylene and C4 hydrocarbon, the effluent is separated to obtain ethylene, propylene and C4 hydrocarbon; wherein, the C4 hydrocarbon material is from fresh mixed C4 hydrocarbon or mixed C4 hydrocarbon obtained by separation or mixtures thereof. In this way, the invention solves the problem well, and is useful in industrial production of ethylene and propylene.

A process for manufacturing a synthetic porous crystalline molecular sieve requires an aqueous reaction mixture comprising a source of X2O3 (X is a trivalent element), a source of YO2 (Y is a tetravalent element) and a source of MOH (M is an alkali metal). The H2O / MOH molar ratio is within the range of 70 to 126 and the source Of X2O3 and YO2 is an amorphous material containing both X2O3 and YO2 and having YO2 / X2O3 molar ratio of 15 or less. The molecular sieve products are useful as catalysts and / or absorbents. Such molecular sieves having MFI structure type, TON structure type or the structure type of zeolite beta and a composition involving the molar relationship (n) YO2:X2O3 wherein n is from 2 to less than 15 are novel compositions of matter.

A reverse disproportionation reaction of two hydrocarbon feeds allows production of a reaction mixture containing products with intermediate carbon numbers. The amount of at least one of the products with intermediate carbon numbers is equal to or greater than the amount formed from disproportionation of the hydrocarbon alone. A reverse disproportionation reaction mixture is also described.

The invention is directed to methods of starting up reaction systems. The reaction systems are those that use catalysts that comprise molecular sieves, particularly metalloaluminophosphate molecular sieves, especially metalloaluminophosphate molecular sieves which are susceptible to loss of catalytic activity due to contact with water molecules. The methods provide appropriate mechanisms of heating and loading the activated molecular sieves to protect against loss of catalytic activity that can occur due to contact with water molecules.

The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. Certain embodiments additionally comprise mixing at least a portion of the two effluents and contacting with an alkylation catalyst to provide enhanced yields of mono-alkylated aromatics that are suitable for use as a blend component of liquid transportation fuels or other value-added chemical products.

A process for increasing a yield of an isomerization zone by removing at least a portion of the C6 cyclic hydrocarbons from a stream prior to it being passed into the isomerization zone. Additionally, disproportionation reactions occur producing valuable C3 hydrocarbons and C4 hydrocarbons. Also, a higher ring opening conversion of C5 cyclic hydrocarbons is observed.