Composite fabric and method for making the same
By using a windproof and breathable membrane in the composite fabric, utilizing the interpenetrating network structure formed by ethylene-butene copolymer and polyolefin elastomer, and adding mineral powder and phase change energy storage wax, the problem of micropore clogging is solved, achieving high breathability, moisture permeability, and windproof and waterproof properties.
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- SHANGHAI UNIV OF ENG SCI
- Filing Date
- 2025-07-10
- Publication Date
- 2026-07-03
AI Technical Summary
In existing composite fabrics, the micropores of the elastomer membrane are easily blocked by colloids, resulting in poor air and moisture permeability.
The membrane is windproof and breathable. It utilizes an interpenetrating network structure formed by ethylene-butene copolymer elastomer and polyolefin elastomer, and adds mineral powder and phase change energy storage wax. The membrane is formed by hot pressing to create an island structure, which ensures the membrane's air and moisture permeability and allows it to penetrate into the fabric fibers to form micropores.
It improves the windproof, waterproof and breathable properties of the composite fabric, and the fabric layers are firmly bonded, soft and resistant to rubbing, and not easy to delaminate or bubble.
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Abstract
Description
Technical Field
[0001] This invention belongs to the field of composite fabric technology, specifically relating to a composite fabric and its preparation method. Background Technology
[0002] Composite fabrics are created by directly heating and bonding fabric with an elastomer membrane to form a new composite fabric, thereby achieving windproof, moisture-wicking, UV protection, and skin-friendly properties.
[0003] Windproofness and breathability are important indicators for evaluating the warmth and comfort of composite fabrics. The windproofness of composite fabrics mainly depends on the performance of the resulting elastomeric membrane; the density of the elastomeric membrane determines the waterproof and windproof function of the composite fabric. The breathability of the fabric is mainly affected by the breathability of the elastomeric membrane material itself. Existing technologies using elastomeric membranes for composite fabrics include fluoropolymer microporous membranes and TPU microporous membranes. These membranes utilize their own micropores to enable the composite fabric to exhibit breathable and breathable properties.
[0004] However, since the elastomer membrane used in existing composite fabrics is a microporous membrane, when the fabric and the elastomer membrane are laminated using solvent adhesives or hot melt adhesives, the adhesive can easily penetrate into the micropores, causing blockage or sealing of the micropores in the elastomer membrane, thus resulting in poor air permeability and moisture permeability of the composite fabric. Summary of the Invention
[0005] To address the aforementioned technical problems, this invention provides a composite fabric and its preparation method. This invention develops a windproof and breathable membrane for composite fabrics, which itself does not possess a microporous structure. When the windproof and breathable membrane is heated and bonded to a fabric to form a composite fabric, during the heating and bonding process, the molten ethylene-butene copolymer elastomer in the windproof and breathable membrane gradually permeates into the fibers of the fabric. The fabric gradually absorbs the molten ethylene-butene copolymer, and the microporous structure of the windproof and breathable membrane begins to appear. As more ethylene-butene copolymer melts and seeps out, the microporous structure of the windproof and breathable membrane becomes more prominent, resulting in stronger breathability of the composite fabric.
[0006] The windproof and breathable membrane of this invention uses ethylene-butene copolymer elastomer as the main film-forming material and polyolefin elastomer as the reinforcing material. An interpenetrating network polymer is formed by mixing and heating the polyolefin elastomer and ethylene-butene copolymer elastomer, resulting in a composite thermoplastic elastomer. Then, by adding mineral powder, which has a high porosity, and under the flow of soft wax and softening oil, the composite thermoplastic elastomer forms a continuous sea, with the mineral powder forming dispersed islands, creating a sea-island structure, thus obtaining the windproof and breathable membrane. This invention utilizes the composite thermoplastic elastomer and soft wax to form a continuous and dense elastomer film, improving the windproof and waterproof properties of the composite fabric after lamination with the elastomer film; and, with the help of the mineral powder, achieves the breathability and moisture permeability of the composite fabric.
[0007] The composite fabric and its preparation method of the present invention are achieved through the following technical solution:
[0008] The first objective of this invention is to provide a composite fabric comprising a first fabric, a windproof and breathable membrane, and a second fabric; wherein the fibers of the first fabric and the second fabric are infiltrated into the windproof and breathable membrane by hot pressing.
[0009] The raw materials for preparing the windproof and breathable membrane, by weight percentage, include the following components: ethylene-butene copolymer elastomer: 39%~92.4%, polyolefin elastomer: 2%~15%, soft wax: 2%~13%, mineral powder: 3%~8%, softening oil: 0.1%~9%, ultraviolet absorber: 0.5%~3%, totaling 100%.
[0010] It should be noted that ethylene-butene copolymer elastomers, as the main film-forming material, possess the characteristic of high-temperature melting and physical cross-linking upon cooling to form elastomers. Ethylene-butene copolymers exhibit good heat resistance, weather resistance, and excellent mechanical properties. Their embrittlement temperature is below -70℃, and their maximum service temperature reaches 140℃. After 100 hours of ozone aging at 38℃, their performance decreases by less than 10%. The tensile elongation is greater than 500%, the tensile recovery rate is greater than 90%, and the tensile strength is greater than 20 kPa. Furthermore, ethylene-butene copolymer elastomers possess both plasticity and high elasticity, combining the properties of both plastics and rubber, and can be directly thermoplasticized without vulcanization. A composite thermoplastic elastomer with an interpenetrating network structure is formed by mixing and heating ethylene-butene copolymer elastomers and polyolefin elastomers. Preferably, the ethylene-butene copolymer elastomer is a mixture of low molecular weight ethylene-butene copolymer rubber and high molecular weight ethylene-butene copolymer rubber; the low molecular weight ethylene-butene copolymer rubber is 0.1 to 0.7 times the mass of the high molecular weight ethylene-butene copolymer rubber; the low molecular weight is less than 100,000; and the high molecular weight is greater than 150,000.
[0011] Polyolefin elastomers are elastomers that can be directly thermoplasticized without vulcanization. The role of polyolefin elastomers is to form an interpenetrating network structure with ethylene-butene copolymers, thereby forming a composite thermoplastic elastomer. This enhances the density and strength of the ethylene-butene copolymer elastomer, improving the windproof and waterproof properties of the composite fabric.
[0012] It should also be noted that the raw materials for preparing the windproof and breathable membrane also include phase change energy storage wax. When the elastomer membrane and fabric are heated and laminated, the phase change energy storage wax melts into a liquid and absorbs a large amount of energy. At this time, the phase change energy storage wax, together with the molten ethylene-butene copolymer, is impregnated into the fiber. When the composite fabric is further cooled, the phase change energy storage wax slowly releases latent heat, helping to prolong the solidification time of the ethylene-butene copolymer, delaying the physical cross-linking process of the ethylene-butene copolymer, and increasing the permeation effect of the ethylene-butene copolymer and the fiber. Therefore, the phase change energy storage wax has an auxiliary temperature control function. This invention, by adding phase change energy storage wax, allows the phase change energy storage wax to play a role in regulating and controlling the temperature during the lamination process of the elastomer membrane and fabric. Furthermore, during the lamination process of the elastomer membrane and the fabric, the amount of phase change energy storage wax added can be determined based on the temperature control and cooling function of the actual laminating machine. When the laminating machine has segmented and time-based temperature control and cooling functions, the effect of phase change energy storage wax is relatively low, and it can be added in small amounts or not at all, relying mainly on the cooling system of the laminating machine to regulate the physical crosslinking time of the ethylene-butene copolymer. When the laminating machine does not have segmented and time-based temperature control and cooling functions, phase change energy storage wax plays a crucial auxiliary role in temperature control. The content of the phase change energy storage wax should not exceed 13% of the windproof and breathable membrane. The molecular structure of the phase change energy storage wax is mainly composed of straight-chain alkanes, with low content of branched and cyclic hydrocarbons, thus making the phase change energy storage wax hard and brittle. Preferably, the phase change energy storage wax is a n-alkane wax.
[0013] Soft wax possesses flexibility, extensibility, and viscosity, and exhibits good compatibility with composite thermoplastic elastomers. During mixing with composite thermoplastic elastomers, it acts as a plasticizer, improving the flowability of the mixture. While maintaining the elasticity and softness of the composite thermoplastic elastomer, it does not compromise its tensile and recovery properties, and offers advantages such as low migration and exudation, good stability, and resistance to aging and yellowing. Furthermore, the formation of a continuous and dense elastomer film using the composite thermoplastic elastomer and soft wax achieves the waterproof and windproof properties of the composite fabric.
[0014] Mineral powder is porous, breathable, moisture-permeable, and non-melting, remaining in a porous solid state throughout the thermoplastic processing with composite thermoplastic elastomers; furthermore, the deformation difference between mineral powder and composite thermoplastic elastomers is significant. Due to interfacial deformation, micropores easily form in the composite thermoplastic elastomer. Moreover, since composite thermoplastic elastomers and soft waxes are highly hydrophobic and have poor breathability and moisture permeability, this invention utilizes the porous hydrophilicity of mineral powder to achieve the breathability and moisture permeability of the windproof and moisture-permeable membrane. Preferably, the mineral powder is one of calcium carbonate, quartz sand, talc, montmorillonite, kaolin, and bentonite.
[0015] Softening oil is used to adjust the fluid properties of the melt. Considering material compatibility: softening oil has high compatibility with ethylene-butene copolymer elastomers, but low compatibility with polyolefin elastomers; to improve compatibility when mixed, the amount of softening oil added needs to be controlled in the raw materials for preparing the windproof and breathable membrane. Preferably, the softening oil is white mineral oil with a viscosity greater than 35 cSt.
[0016] This invention provides UV protection by adding a UV absorber to absorb UV light in the 320nm-400nm wavelength range and outdoor UV light, thereby reducing or inhibiting the UV oxidation process of the polymer. Preferably, the UV absorber is one of benzotriazole and benzophenone.
[0017] A second objective of this invention is to provide a method for preparing the aforementioned composite fabric, comprising the following steps:
[0018] S1. Weigh out the corresponding mass of raw materials according to the proportion of raw materials for the preparation of the windproof and breathable membrane, and set aside for later use.
[0019] S2. Mix ethylene-butene copolymer elastomer and polyolefin elastomer at 60℃~100℃ to obtain composite thermoplastic elastomer.
[0020] S3. Add soft wax, mineral powder, softening oil and ultraviolet absorber to the composite thermoplastic elastomer, stir evenly, and then add phase change energy storage wax in batches to obtain a windproof and moisture-permeable membrane.
[0021] S4. The first fabric, the windproof and breathable membrane, and the second fabric are stacked in sequence to form a sandwich structure. After heating, pressure is applied to mechanically bond the fabric and the windproof and breathable membrane together to obtain a composite fabric.
[0022] Preferably, the mixing time in S1 is 10 min to 20 min, which is used to mix the polyolefin elastomer and the ethylene-butene copolymer elastomer evenly to form a composite thermoplastic elastomer of interpenetrating network polymer.
[0023] To ensure the mineral powder, softening oil, and ultraviolet absorber are fully dispersed in the composite thermoplastic elastomer, a continuous sea is formed by the composite thermoplastic elastomer and dispersed islands by the flowing wax and softening oil, resulting in a sea-island structure and a windproof and breathable membrane. In process S3 of this invention, mechanical stirring is employed; preferably, the stirring time in S3 is 20-30 minutes.
[0024] To ensure the phase change energy storage wax is uniformly dispersed in the composite thermoplastic elastomer and that the two are mutually absorbed and integrated, this invention employs a phased addition method. The phase change energy storage wax is added to the composite thermoplastic elastomer in stages, and then mixed evenly by mechanical stirring or kneading until the phase change energy storage wax and the composite thermoplastic elastomer are fully adsorbed and mixed. Furthermore, the heating temperature during the stirring process is controlled at 60℃~100℃ to ensure that the phase change wax is in a molten state and that the melt is completely adsorbed by the ethylene-butene copolymer, resulting in a windproof and breathable membrane.
[0025] Preferably, the pressure applied in S4 is 15 MPa to 50 MPa, and the heating temperature is 120°C to 180°C.
[0026] Preferably, the first fabric and the second fabric are made of the same material.
[0027] Compared with the prior art, the present invention has the following beneficial effects:
[0028] The composite fabric of this invention comprises a first fabric, a windproof and breathable membrane, and a second fabric. Fibers from the first and second fabrics are infiltrated into the windproof and breathable membrane via hot pressing. The raw materials for preparing the windproof and breathable membrane include ethylene-butene copolymer elastomer, polyolefin elastomer, soft wax, mineral powder, softening oil, and ultraviolet absorber. This invention obtains a composite thermoplastic elastomer through an interpenetrating network polymer formed by polyolefin elastomer and ethylene-butene copolymer elastomer. The composite thermoplastic elastomer and soft wax form a continuous and dense elastomer film, thereby improving the windproof and waterproof properties of the composite fabric after lamination with the windproof and breathable membrane. By adding mineral powder, which has a high porosity, under the flow of soft wax and softening oil, the composite thermoplastic elastomer forms a continuous sea, with the mineral powder as dispersed islands, creating a sea-island structure, thus obtaining the windproof and breathable membrane. The island structure achieves the waterproof and windproof properties of the composite fabric, while the porous mineral powder provides breathability and moisture permeability.
[0029] The windproof and breathable membrane prepared by this invention does not have a microporous structure itself. When the windproof and breathable membrane is heated and bonded to a fabric to form a composite fabric, during the heating and bonding process, the high-temperature molten ethylene-butene copolymer elastomer gradually penetrates into the fabric fibers. The fabric gradually absorbs the molten ethylene-butene copolymer, and the microporous structure begins to appear. As more ethylene-butene copolymer elastomer melts and seeps out, the microporous structure of the windproof and breathable membrane becomes more prominent, and the breathability of the composite fabric becomes stronger. In addition, when the molten ethylene-butene copolymer elastomer cools, a cross-linking reaction occurs again, forming cross-linked elastomers both inside and outside the fabric fiber structure. This results in both sides of the fabric lamination layer being elastomer materials, which are firmly bonded, soft and elastic, resistant to rubbing without creases, washable, and difficult to delaminate, bubble, or peel. Detailed Implementation
[0030] The following embodiments are provided to specifically describe the present invention. It should be noted that the following embodiments are only used to further illustrate the present invention and should not be construed as limiting the scope of protection of the present invention. Some non-essential improvements and adjustments made to the present invention by those skilled in the art based on the content of the present invention still fall within the scope of protection of the present invention. In the description of the present invention, unless otherwise specified, all reagents used are commercially available, and all methods used are conventional techniques in the art.
[0031] Example 1
[0032] This embodiment provides a method for preparing composite fabrics.
[0033] S1. Weigh the corresponding mass of the raw materials according to the following mass percentage ratio and set aside:
[0034] Ethylene-butene copolymer elastomer: 80.5%, polyolefin elastomer: 3%, soft wax: 4%, calcium carbonate: 6%, white mineral oil: 2%, benzotriazole: 1.5%, phase change energy storage wax: 3%, total 100%.
[0035] The ethylene-butene copolymer elastomer is a mixture of low molecular weight Baling Petrochemical YH-501T and high molecular weight Baling Petrochemical YH-504T; wherein the mass ratio of Baling Petrochemical YH-501T to Baling Petrochemical YH-504T is 10:90.
[0036] S2. Mix the ethylene-butene copolymer elastomer and the polyolefin elastomer, and heat and stir at 60°C for 10 minutes to obtain a composite thermoplastic elastomer.
[0037] S3. Add soft wax, calcium carbonate, white mineral oil and benzotriazole to the composite thermoplastic elastomer in sequence, stir for 20 minutes to obtain a thermoplastic rubber mixture; add phase change energy storage wax to the thermoplastic rubber mixture in two batches, and stir at 70°C to obtain a windproof and moisture-permeable membrane.
[0038] S4. Nylon is selected as the first and second fabrics. Nylon, windproof and breathable membrane and nylon are stacked in sequence to form a sandwich structure. After being heated by a covering machine, pressure is applied. The heating temperature is 120℃, the pressure is 15Mpa and the speed is 1.2m / s to obtain the composite fabric.
[0039] Example 2
[0040] This embodiment provides a method for preparing composite fabrics.
[0041] S1. Weigh out the corresponding mass of the preparation raw materials according to the formula, and set aside for later use:
[0042] Ethylene-butene copolymer elastomer: 92.4%, polyolefin elastomer: 2%, soft wax: 2%, white mineral oil: 0.1%, talc: 2%, benzophenone: 0.5%, total 100%.
[0043] The ethylene-butene copolymer elastomer is a mixture of low molecular weight Baling Petrochemical YH-502T and high molecular weight Baling Petrochemical YH-604T; wherein the mass ratio of Baling Petrochemical YH-502T to Baling Petrochemical YH-604T is 40:60.
[0044] S2. Mix the ethylene-butene copolymer elastomer and the polyolefin elastomer, and heat and stir at 100°C for 20 minutes to obtain a composite thermoplastic elastomer.
[0045] S3. Add soft wax, talc and benzophenone to the composite thermoplastic elastomer in sequence, stir for 30 minutes to obtain a windproof and breathable membrane.
[0046] S4. Select polyester as the first and second fabrics, and stack polyester, windproof and breathable membrane and polyester in sequence to form a sandwich structure. Heat and press through a covering machine. The heating temperature is 150℃, the pressure is 30Mpa and the speed is 5m / s to obtain the composite fabric.
[0047] The difference between this embodiment and Embodiment 1 is as follows:
[0048] Phase change energy storage wax was not added in this embodiment.
[0049] Example 3
[0050] This embodiment provides a method for preparing composite fabrics.
[0051] S1. Weigh the corresponding mass of the raw materials according to the following mass percentage ratio and set aside:
[0052] Ethylene-butene copolymer elastomer: 39%, polyolefin elastomer: 15%, soft wax: 13%, quartz sand: 8%, white mineral oil: 9%; benzotriazole: 3%, phase change energy storage wax: 13%, total 100%.
[0053] The ethylene-butene copolymer elastomer is a mixture of low molecular weight Baling Petrochemical YH-501T and high molecular weight Baling Petrochemical YH-604T; wherein the mass ratio of Baling Petrochemical YH-501T to Baling Petrochemical YH-604T is 20:80.
[0054] S2. Mix the ethylene-butene copolymer elastomer and the polyolefin elastomer, and heat and stir at 80°C for 15 minutes to obtain a composite plastic elastomer.
[0055] S3. Add soft wax, quartz sand, white mineral oil and benzotriazole to the composite thermoplastic elastomer in sequence, stir for 20 minutes to obtain a thermoplastic rubber mixture; add phase change energy storage wax to the thermoplastic rubber mixture in 5 portions, and stir at 70°C to obtain a windproof and moisture-permeable membrane.
[0056] S4. Select cotton fabric as the first and second fabrics, and stack cotton fabric, windproof and breathable membrane and cotton fabric in sequence to form a sandwich structure. Heat and press through a covering machine. The heating temperature is 180℃, the pressure is 50Mpa, and the speed is 8m / s to obtain the composite fabric.
[0057] The difference between this embodiment and Embodiment 1 is as follows:
[0058] The proportions of each component in this embodiment are different from those in Example 1.
[0059] Example 4
[0060] This embodiment provides a method for preparing composite fabrics.
[0061] S1. Weigh the corresponding mass of the raw materials according to the following mass percentage ratio and set aside:
[0062] Ethylene-butene copolymer elastomer: 92.4%, polyolefin elastomer: 2%, soft wax: 2%, calcium carbonate: 3%, white mineral oil: 0.1%; benzotriazole: 0.5%, total 100%.
[0063] The ethylene-butene copolymer elastomer is a mixture of low molecular weight Baling Petrochemical YH-502T and high molecular weight Baling Petrochemical YH-504T; wherein the mass ratio of Baling Petrochemical YH-502T to Baling Petrochemical YH-504T is 30:70.
[0064] S2. Mix the ethylene-butene copolymer elastomer and the polyolefin elastomer, and heat and stir at 70°C for 20 minutes to obtain a composite plastic elastomer.
[0065] S3. Add soft wax, calcium carbonate, white mineral oil and benzotriazole to the composite thermoplastic elastomer in sequence, stir for 20 minutes to obtain a windproof and breathable membrane.
[0066] S4. Select polyester as the first and second fabrics, and stack polyester, windproof and breathable membrane and polyester in sequence to form a sandwich structure. Heat and press through a covering machine. The heating temperature is 150℃, the pressure is 30Mpa and the speed is 5m / s to obtain the composite fabric.
[0067] The difference between this embodiment and Embodiment 1 is as follows:
[0068] Phase change energy storage wax was not added in this embodiment.
[0069] Comparative Example 1
[0070] This comparative example provides a method for preparing a composite fabric.
[0071] S1. Weigh out the corresponding mass of the preparation raw materials according to the formula, and set aside for later use:
[0072] Ethylene-butene copolymer elastomer: 84%, soft wax: 3%, talc: 1%, white mineral oil: 12%.
[0073] The ethylene-butene copolymer elastomer is a mixture of low molecular weight Baling Petrochemical YH-501T and high molecular weight Baling Petrochemical YH-504T; wherein the mass ratio of Baling Petrochemical YH-501T to Baling Petrochemical YH-504T is 10:90.
[0074] S2. Mix the ethylene-butene copolymer with soft wax, talc, and white mineral oil, and heat and stir at 80°C for 20 minutes to obtain an ethylene-butene copolymer mixture.
[0075] S4. Select polyester as the first and second fabrics, and stack polyester, windproof and breathable membrane and polyester in sequence to form a sandwich structure. Heat and press through a covering machine. The heating temperature is 150℃, the pressure is 30Mpa and the speed is 5m / s to obtain the composite fabric.
[0076] The difference between this comparative example and Example 1 is that no polyolefin elastomer was added in this comparative example.
[0077] 1. Moisture permeability test
[0078] According to the evaluation of windproof and moisture-permeable properties of textiles in FZ / T 01149-2019 standard, the specific evaluation standards for windproof and moisture-permeable properties are shown in Table 1. Air permeability was tested according to GB / T 5453, using the composite fabrics of Examples 1-4 and Comparative Example 1. The pressure drop across the composite fabric was set to 100 Pa, and the test area was 20 square centimeters. Measurements are expressed in mm / s. Moisture permeability was tested according to GB / T 12704.1-2009, where water was allowed to pass vertically through a unit area sample within a specified time under specified temperature and humidity conditions on both sides of the composite fabric. Vapor mass was expressed in grams per square meter over 24 hours. The test results for air permeability and moisture permeability are shown in Table 2.
[0079] Table 1 Evaluation Grade Standards for Composite Fabrics
[0080]
[0081] Table 1 shows the evaluation standards for windproof and moisture-permeable properties of textiles according to the FZ / T 01149-2019 standard. The composite fabric prepared by this invention was tested and evaluated for windproof and moisture-permeable properties in accordance with this standard.
[0082] Table 2. Air permeability and moisture permeability data of the composite fabrics prepared in Examples 1-4 and Comparative Example 1
[0083]
[0084] Table 2 shows the air permeability and moisture permeability data of the composite fabrics prepared in Examples 1-4 and Comparative Example 1. As can be seen from Table 2, Examples 1-4 all meet the Level III standard for excellent windproof and moisture permeability. Comparative Example 1 only achieves Level I air permeability, indicating general windproof performance, but its moisture permeability does not meet the standard. This demonstrates that the composite fabric prepared by this invention has excellent windproof and moisture permeability.
[0085] Although preferred embodiments of the invention have been described, those skilled in the art, upon learning the basic inventive concept, can make other changes and modifications to these embodiments, all of which fall within the scope of the invention.
[0086] Obviously, those skilled in the art can make various modifications and variations to this invention without departing from its spirit and scope. If these modifications and variations fall within the scope of equivalents of this invention, then this invention also intends to include these modifications and variations.
Claims
1. A composite fabric, characterized by, The composite fabric includes a first fabric, a windproof and breathable membrane, and a second fabric; the fibers of the first fabric and the second fabric are infiltrated into the windproof and breathable membrane by hot pressing. The windproof and breathable membrane, by mass percentage, comprises the following components in its preparation: SEBS: 39%~92.4%, polyolefin elastomer: 2%~15%, soft wax: 2%~13%, mineral powder: 3%~8%, softening oil: 0.1%~9%, ultraviolet absorber: 0.5%~3%, phase change energy storage wax: 0%~13%, totaling 100%. The windproof and breathable membrane is prepared by the following method: Weigh out the corresponding mass of raw materials according to the proportion of raw materials for the preparation of the windproof and breathable membrane, and set aside for later use; SEBS and polyolefin elastomers are mixed at 60℃~100℃ to obtain a composite thermoplastic elastomer; Add soft wax, mineral powder, softening oil and ultraviolet absorber to the composite thermoplastic elastomer, stir evenly, and then add phase change energy storage wax in batches to obtain a windproof and moisture-permeable membrane. The SEBS is composed of low molecular weight SEBS and high molecular weight SEBS; the mass of the low molecular weight SEBS is 0.1 to 0.7 times that of the high molecular weight SEBS. The low molecular weight SEBS is either Baling Petrochemical YH-501T or Baling Petrochemical YH-502T. The high molecular weight SEBS is either Baling Petrochemical YH-504T or Baling Petrochemical YH-604T.
2. The composite fabric of claim 1, wherein, The phase change energy storage wax is a n-alkane wax.
3. The composite facing material of claim 1, wherein, The mineral powder is one of calcium carbonate, quartz sand, talc, montmorillonite, kaolin, and bentonite.
4. The composite facing material of claim 1, wherein, The softening oil is white mineral oil.
5. A method of producing the composite fabric according to any one of claims 1 to 4, characterized by, Includes the following steps: Weigh out the corresponding mass of raw materials according to the proportion of raw materials for the preparation of the windproof and breathable membrane, and set aside for later use; SEBS and polyolefin elastomers are mixed at 60℃~100℃ to obtain a composite thermoplastic elastomer; Add soft wax, mineral powder, softening oil and ultraviolet absorber to the composite thermoplastic elastomer, stir evenly, and then add phase change energy storage wax in batches to obtain a windproof and moisture-permeable membrane. A sandwich structure is formed by stacking the first fabric, the windproof and breathable membrane, and the second fabric in sequence. After heating and applying pressure, the first fabric, the windproof and breathable membrane, and the second fabric are combined together through mechanical action to obtain a composite fabric.
6. The method of claim 5, wherein the composite fabric is prepared by the steps of: The pressure applied is 15 MPa to 50 MPa, and the heating temperature is 120°C to 180°C.