Solid-state electrolyte ceramic sheet and solid-state lithium ion battery

By combining a Zr/Ge co-doped LATP ceramic matrix with an amorphous Al2O3 thin layer, the bulk ion transport and interfacial stability of solid-state lithium-ion batteries were optimized, the interfacial impedance problem of NASICON-type solid electrolyte ceramic sheets was solved, and the electrochemical performance and cycle stability of the battery were improved.

CN122136455APending Publication Date: 2026-06-02JIANGSU RELIANCE ENERGY TECHNOLOGY CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JIANGSU RELIANCE ENERGY TECHNOLOGY CO LTD
Filing Date
2026-04-21
Publication Date
2026-06-02

AI Technical Summary

Technical Problem

The high interfacial impedance of existing NASICON-type solid electrolyte ceramic sheets leads to reduced electrochemical performance of solid lithium-ion batteries and low capacity retention over long cycles.

Method used

A structural design combining a Zr/Ge co-doped LATP ceramic matrix with an amorphous Al2O3 thin layer was adopted. A continuous amorphous Al2O3 thin layer was deposited on the side of the ceramic matrix facing the negative electrode using atomic layer deposition technology to form an inorganic interface layer with a thickness of 1-5 nm, thereby optimizing bulk ion transport and interface stability.

Benefits of technology

It significantly improves the ionic conductivity, interfacial impedance, cycle stability, and rate performance of solid-state lithium-ion batteries, solves the core bottleneck of LATP-based solid electrolytes, and achieves long-term electrochemical performance stability and efficient lithium-ion transport.

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Abstract

This invention relates to the field of lithium-ion battery technology, and more particularly to a solid electrolyte ceramic sheet and a solid lithium-ion battery. The solid electrolyte ceramic sheet is a Zr / Ge co-doped LATP ceramic sheet, comprising a ceramic substrate and an inorganic interface layer disposed on the surface of the ceramic substrate. The inorganic interface layer is disposed on at least one side surface of the ceramic substrate facing the negative electrode. The general chemical formula of the ceramic substrate is Li. 1+x Al x Ti 2‑x‑y1‑y2 Zr y1 Ge y2 (PO4)3, where x = 0.25–0.40, y1 = 0.03–0.15, and y2 = 0.03–0.10. This invention addresses the core bottlenecks of LATP-based solid electrolytes by synergistically optimizing bulk ion transport and stabilizing interfacial chemistry, resulting in significant improvements in ionic conductivity, interfacial impedance, cycle stability, and rate performance of the prepared solid-state lithium-ion batteries.
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