A gradient composite glass solder for joining alumina to aluminum nitride ceramics and method

By designing a gradient composite glass solder with matched thermal expansion coefficients and a graded sintering method, the problems of thermal expansion coefficient mismatch and wettability in the connection of alumina and aluminum nitride ceramics were solved, achieving a high-strength and low-cost connection effect, which is suitable for modern microelectronic packaging and aerospace fields.

CN122165092APending Publication Date: 2026-06-09JUNYUAN ELECTRONIC TECHNOLOGY (HAINING) CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JUNYUAN ELECTRONIC TECHNOLOGY (HAINING) CO LTD
Filing Date
2026-01-30
Publication Date
2026-06-09

AI Technical Summary

Technical Problem

Existing technologies struggle to achieve high-strength bonding between alumina and aluminum nitride ceramics at low temperatures, and suffer from issues such as thermal expansion coefficient mismatch, poor wettability, and hydrolysis sensitivity, resulting in insufficient bonding strength and reliability.

Method used

A gradient composite glass brazing alloy is used. By designing two glass brazing alloys with matching coefficients of thermal expansion, they are coated on the surfaces of alumina and aluminum nitride ceramics respectively. Combined with a staged sintering method, the connection is achieved at a lower temperature, which relieves thermal stress and improves wettability and chemical compatibility.

Benefits of technology

It significantly improves the thermal shock resistance and long-term reliability of the connector, reduces production costs, and has superior performance that meets the requirements of electronic packaging substrates.

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Abstract

The application discloses a gradient composite glass solder for connecting alumina and aluminum nitride ceramics and a method, and belongs to the technical field of ceramic brazing. ‑6 / K~5.7*10 ‑6 / K; the second glass solder comprises, in percentage by weight, ZnO: 15~19 wt%, B2O3: 20~24 wt%, SiO2: 36~40 wt%, Al2O3: 6~10 wt%, TiO2: 1~4 wt%, Na2O: 3~8 wt%, Li2O: 1~3 wt% and CaO: 4~6 wt%, and the thermal expansion coefficient of the second glass solder is 6.0*10 ‑6 / K~7.0*10 ‑6 / K.
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