Fragrance mixture comprising aromatic nitriles

Abstract

This article presents novel fragrance compositions comprising or consisting of aromatic nitriles, specific secondary fragrances, and optional solvents. The nitriles, even at amounts below 5% by weight, are capable of modulating, enhancing, and / or improving the longevity of the secondary fragrance.

Description

Technical Field

[0001] This invention relates to the field of fragrances, and specifically to fragrance mixtures comprising aromatic nitrile compounds having modified aroma notes. Background Technology

[0002] In the fragrance industry, there is a huge demand for fragrance ingredients, especially scent notes, because they help perfumers expand their scent spectrum. The demand for certain fragrance ingredients is particularly urgent: these ingredients, requiring only a very small amount, can significantly influence and optimize other ingredients—for example, in terms of scent distinctiveness (i.e., the "modifying" effect), scent intensity, and longevity.

[0003] Related existing technologies Aromatic nitriles are well-known synthetic intermediates in the chemical industry [see March's Advanced Organic Chemistry, Reactions, Mechanisms and Structure, John Wiley and Sons, Inc., New York, 2007] and the fragrance industry.

[0004] A suitable process for preparing aromatic nitriles includes using a cyanide source, such as CuCN, KCN, NaCN, Zn(CN)2, TMSCN, or converting aryl halides into nitrile compounds [see Kim et al., Angewandte Chemie, Vol. 124, p 12114 ff (2012)].

[0005] EP 0550762 A1 (KAO) relates to a process for preparing nitrile compounds by heating an aldehyde oxime in the presence of one or more catalysts selected from alkali metal hydroxides, alkali metal alkoxides, alkaline earth metal hydroxides and alkaline earth metal alkoxides, and removing water generated during the reaction by distillation from the reaction system.

[0006] EP 2979682 A1 (SYMRISE) discloses a fragrance composition comprising an aromatic nitrile, such as 3,4-dimethylbenzonitrile, in a mixture with a specific solvent.

[0007] Purpose of the invention Therefore, the present invention aims to provide novel fragrance blends with improved performance. Specifically, the present invention seeks a class of primary fragrances that can adjust, enhance, and improve the longevity of other secondary fragrances when added in small amounts, preferably less than 5% by weight, more preferably less than 3% by weight, and most preferably less than 0.5% by weight. Summary of the Invention

[0008] The first object of the present invention relates to a spice mixture comprising or consisting of the following components: (a) at least one main spice conforming to general formula (I)

[0009] Where R 1 R 2 R 3 R 4 and R 5 Independently representing hydrogen; or representing straight-chain or branched C1-C. 10 Alkyl group, which may optionally be substituted with hydroxyl or C1-C4 alkyl; or representing straight-chain or branched C1-C4 alkyl groups. 10 Alkoxy groups, which may optionally be substituted with hydroxyl or C1-C4 alkyl groups.

[0010] (b) at least one secondary flavoring different from component (a), and optionally (c) At least one solvent, Wherein, the at least one secondary flavoring belongs to the flavoring group exhibiting at least one of the following aroma notes: Fruity notes; Woody notes; Floral fragrance; Aromatic / Herbal notes; Citrus notes; Spicy notes; and Green fragrance.

[0011] Surprisingly, aromatic nitrile compounds, particularly certain benzonitrs, especially 3,4-dimethylbenzonitrile, have been observed to improve the olfactory characteristics of a variety of specific secondary fragrance notes. Specifically, these nitrile compounds can impart greater volume, body, richness, and complexity to these secondary fragrance notes. They can enhance the spiciness, balsaminess, and sandalwood notes of scents such as orange, mango, hyacinth, and / or pepper. This is particularly remarkable because these nitrile compounds themselves have a strong cinnamon note. Furthermore, these nitrile compounds can also improve the longevity of secondary fragrance notes, especially in the presence of certain solvents.

[0012] In terms of specific fragrance categories, the following fragrance effects can be achieved:

[0013] Aromatic nitrile compounds The aromatic nitrile compounds constituting component (a) and hereinafter referred to as "main fragrance" are all known compounds that can be prepared according to standard organic chemistry procedures. For example, reference can be made to the applicant's previous application EP 2979682 A1. In a preferred embodiment, the composition according to the invention comprises an aromatic nitrile conforming to formula (II) as component (a).

[0014] Where R 2 R 3 Independently representing hydrogen, straight-chain or branched C1-C 10 Alkyl groups, which may optionally be substituted with hydroxyl groups or C1-C4 alkyl groups; or straight-chain or branched C1-C4 alkyl groups. 10 Alkoxy groups, which may optionally be substituted with hydroxyl or C1-C4 alkyl groups.

[0015] More preferably, the composition according to the invention comprises an aromatic nitrile compound conforming to the following general formula, wherein the substituent R of the aromatic nitrile is... 2 and R 3 Represents methyl.

[0016] Examples of suitable aromatic nitriles constituting component (a) include the following: 3,4-Dimethylbenzonitrile; 4-(2-methylpropyl)benzonitrile; 3-Methylbenzonitrile; 2-Methoxybenzonitrile; 3,4-Dimethoxybenzonitrile; 4-Methoxybenzonitrile and mixtures thereof.

[0017] The preferred compound is 3,4-dimethylbenzonitrile, which is available from Symrise AG.

[0018] Secondary spices As mentioned above, secondary fragrances can be categorized into one, two, or more of the following aroma categories, which are common and standard classifications in the fragrance industry: Fruity flavor; Woody scent; Floral fragrance; Aromatic / Herbal; citrus type; Spicy; and Green fragrance.

[0019] In other words, spices belonging to the same category share the same olfactory characteristics. Tables A through G below list examples for each category, but these examples are not intended to cover all possible cases.

[0020] Table A Examples of fragrances with fruity aroma

[0021] Table B Examples of fragrances with woody notes

[0022] Table C Examples of fragrances with floral notes

[0023] Table D Examples of fragrances with aromatic / herbal notes

[0024] Table E Examples of fragrances with citrus notes

[0025] Table F Examples of fragrances with green notes

[0026] Table G Examples of spices with spicy aroma

[0027] Binary, ternary and multi-component flavor blends Although the mixtures according to the invention may contain 1, 2, 3, 4, 5 or even more secondary flavorings selected from the above list, binary and ternary combinations are preferred.

[0028] Therefore, the first preferred embodiment refers to a binary mixture of components (a) and (b). In this case, the secondary flavoring (b) is preferably selected from the following group: Fruity Fragrance Notes: 2-Methylisovalerate butyl ester, acetylbutyryl, so-called "C14 aldehyde", so-called "C16 aldehyde", so-called "C18 aldehyde", allyl heptaate, amyl acetate, amyl butyrate, amyl hexanoate, amyl formate, anisylacetone, cis-2-tert-butylcyclohexyl acetate, 2-tert-butylcyclohexyl acetate, benzyl butyrate, benzoyl isobutyrate, benzyl isovalerate, butyl acetate, butyl butyrate, butyl n-octanoate, n-butyl formate, butyl isobutyrate, butyl isovalerate, butyl propionate, butyl salicylate, n-butyric acid, norber-5-enyl acetate, n-hexanoic acid, cyclohexyl acetate, cyclohexyl butyrate, (2E)-but-2-enoic acid 1-cyclohexyl ester, artemisia oil, δ-decanolide, γ-decanolide, diethyl malonate , ethyl butyrate, ethyl caprate, ethyl hexanoate, ethyl octanoate, ethyl formate, ethyl heptaate, ethyl octanoate, ethyl formate, ethyl heptaate, ethyl 3-hydroxyhexanoate, ethyl isobutyrate, ethyl isovalerate, ethyl laurate, ethyl acetylpropionate, ethyl 2-methylbutyrate, ethyl nonanoate, ethyl 3-phenylglycidyl propionate, ethyl valerate, ethyl 2-tert-butylcyclohexyl carbonate, ethyl 2,4-dimethyl-1,3-dioxolane-2-ethyl acetate, 4-(4-hydroxyphenyl)but-2-one, 4-(4-hydroxyphenyl)but-2-one methyl ether, tricyclic [5.2.1.0 2.6] Ethyl decane-2-carboxylate, (E)-but-2-enoic acid-4-methylpentane-2-ester, furfuryl acetate, propylheptyl lactone, heptanoic acid, heptyl acetate, propylcaprolactone, hexyl acetate, hexyl butyrate, hexyl hexanoate, hexyl octanoate, hexyl formate, hexyl isobutyrate, n-hexyl isovalerate, 2-methylbutyrate, hexyl propionate, isoamyl acetate, isoamyl butyrate, isoamyl n-octanoate, isobutyl butyrate, isobutyl isovalerate, isobutyric acid, 1,3-dimethyl-3-butenyl 2-methylpropionate, isopentenyl acetate, isopropyl acetate, isovaleric acid, isovaleraldehyde, (2-methyl-1,3-dioxane- Ethyl 2-methyl(2-ethyl)ethyl acetate, 4,4a,5,9b-tetrahydro-2,4-dimethyl-indeno[1,2-d]-1,3-dioxane, maltol isobutyrate, ethyl 2-methylvalerate, ethyl 3,5,5-trimethyl-hexanoate, methyl acetate, 2-methylbutyl acetate, 2-methylbutanal, methyl butyrate, methyl hexanoate, methyl octanoate, methyl butyrate, methyl thiol butyrate, 2-methylbutyric acid, 2,2-methylpentenoic acid, butyl nonanolide, norberyl-5-enyl acetate, butyl octanolide, propyl octanolide, 2-(ethoxymethyl)-1-methyl-3-(1-methylvinyl)- Cyclopentene, (E)-2-methylbut-2-enediol, 2-methylpentanoic acid-2-methylpentyl ester, n-propyl acetate, n-propyl propionate, (2E)but-2-enoic acid-1,1'-bicyclopentyl-2-yl ester, (E)-4-methyldec-3-en-5-ol, butyl undecyl lactone, n-valeric acid, propyl valerol.

[0029] Woody notes: 2-methyl-5-(5,5,6-trimethyl-bicyclo[2.2.1]-hept-2-yl)cyclohexanone, 1-(2-tert-butylcyclohexyl)oxybut-2-ol, 2H-indeno[4,5-b]furan, decahydro-2,2,6,6,7,8,8-heptamethyl, dodecylhydro-3,3-8,11a-tetramethyl-5H-3,5a-epoxynaphtho(2,1-c)oxazopyrrolidone, 3a,6,6,9a-tetramethyldodecylnaphtho[2,1-b]furan, (ethoxymethoxy)-cyclododecane, (E)- Ambrinol-13,18(28)-dien-8-ol, (4aR,5R,7aS,9R)-octahydro-2,2,5,8,8,9ahexamethyl-4H-4a,9-methylenechalcogenide[5,6-d]-1,3-dioxolane, (3aS,4aR,5R,7aS,9R,9aR)-octahydro-2,5,8,8,9a-pentamethyl-2-propyl-4H-4a,9-methyleneazono[5,6-d]-1,3-dioxolane, dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan, (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b] Furan, sage oil, 8α,9α-epoxyjunylene, (+) 2,6,9-trimethyl-2,5,9-cyclododecanetrien-1-ol, 2-methyl-3-({1,7,7-trimethylbicyclo[2.2.1]hept-2-yl}oxy)prop-1-ol, agarwood boya oil, β-2,2,3-tetramethylcyclopent-3-en-1-butanol, α-decahydro-2,2,4,8-tetramethyl-4,8-methyl-bridged chamomile-9-yl ester, (1R,3E,5S,9S)-4,11,11-trimethyl-8-methylene-bicyclo[7.2.0] Undec-3-en-5-ol, 1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-4H-inden-4-one, cedarwood oil, [3R-(3α,3aβ,6α,7β,8aα)]-octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methyleneazine+(3R,3aS,6R,7R,8aS)- Octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methylene chamomile ring, cedrene, cedrene alcohol, Cedrol, epoxycedrene, cedrene acetate, 3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran, cinnamon, cyclododecyl carboxylate, cyperus oil, dynamone, (Z)-3-methyl-5-(2,2,3-trimethyl-1-cyclopent-3-enyl)pent-4-en-2-ol, (E)-2-methyl-1-(6-methyl-6-bicyclo[2.2].1] Hepta-2-enyl)pent-1-en-3-ol mixture, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-pentanone, guaiac oil, guaiacol, guaiac acetate, rockrose resin, 2-cyclododecylprop-1-ol, 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphth-2-yl) Ethanol, cyclohexanebornyl ester, 1,7,7-trimethyl-bicyclo[2.2.1]hept-2-ylpropionate, 2H-2,4a-methylnaphthalene, [1-methyl-2-[(1,2,2-trimethylbicyclo[3.1.0]hex-3-yl)methyl]cyclopropyl]methanol (a mixture of diastereomers), 5-butyl-2-yl-2-(2,4-dimethyl-1-cyclohex-3-enyl)-5-methyl-1,3 -Dioxane, 4-(1-ethoxyvinyl)-3,3,5,5-tetramethyl-cyclohexane-1-one, methyl diisopentylmethanol, 1R,2S,7S,9S)-3,3,7-trimethyl-8-methylenetricyclo-[5.4.0.02,9]undecane, α-ethyl-2,2,6-trimethylcyclohexanepropanol, 1-methyl-1-methoxycyclododecane, 3,3-dimethyl-5-(2,2,3- Trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol, α-propyl-2,2,6-trimethyl-cyclohexanepropanol, 2,4-dimethyl-2-(1,1,4,4-tetramethyltetrahydronaphth-6-yl)-1,3-dioxolane, labdanum ethyl ketone, 3,7-dimethyl-7-methoxy-2-octanol, 1,3,6,7-tetramethylbicyclo[4.4].[0] Dec-7-en-2-ol carboxylate, 1,1-dimethoxy-cyclododecane, methoxy-cyclododecane, patchouli oil, 1-[4-(1,1-dimethylethyl)phenyl]-ethyl ketone, 1,1,5,5-tetramethylhexahydro-2H-2,4a-methylenebridgednaphthalene-8(5H)-one, 3,3-dimethyl-5-(2,2,3- Trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol, 3,7'-dimethyl-3,4,4a,5,8,8a-hexahydrospiro-(1,4-methylenenaphthalene-2(1H),2'-ethylene oxide), 2-(1,1-dimethylethyl)-4-methylcyclohexanol, 2-methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, 3-methyl-5-(2,2,3-trimethylcyclopenten-3-en-1-yl)penten-2-ol, sandalwood essential oil, (2E)-2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)buten-1-ol, 2-ethyl-4-(2,2,3-trimethylcyclopenten-3-en-1-yl)buten-2-buten-1-ol, sage Lactone, 1,3,4,5,6,7-hexahydro-7-methoxy-1,1,5,5-tetramethyl-2H-2,4a-methylnaphthalene, 1,1,5,5-tetramethyl-octahydro-2,4a-methylnaphthalene-8a-ol, 1-(2,2,6-trimethylcyclohexyl)hex-3-ol, trimofix, methyl cypressone, 1,3-dimethyl-3-phenylbutyl acetate, 4-methyl-4-phenylpentan-2-one, 4-cyclohexyl-4-methylpentan-2-one, vetiver oil, 4,8-dimethyl-2-prop-2-ylidene-3,3a,4,5,6,8a-hexahydro-1H-azulene-6-ol, (4,8-dimethyl-2-prop-2-ylidene-3,3a,4,5,6,8a-hexahydro-1H-azulene-6-yl) Acetate, 1',1',5',5'-tetramethylhexahydro-spiro[1,3-dioxolane-2,8'(5'H)-2H-2,4a-methylnaphthalene]. Floral Fragrance Notes: 4-(3-methylbutyl)cyclohexyl-1-ol, allyl-α-ionone, α-pentylcinnamaldehyde, phenethyl isopentyl ether, benzophenone, benzyl acetate, benzyl acetone, benzyl propionate, benzyl salicylate, 2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo[3.3.1]nonane, 2-methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal, 3-[4-(1,1-dimethylethyl)phenyl]propanal), Brazilian sandalwood essential oil, methylbenzodioxanone, nanmu oil, 3-(4-methoxyphenyl)-2-methylpropanal, (3-methoxy-2-methylpropyl)- Benzene, 2-methyl-4-(2,6,6-trimethyl-2(1)-cyclohexen-1-yl)butanal, α-isomethylionone, citronellol, citronellol acetate, citronellol butyrate, citronellol formate, citronellol isobutyrate, citronellol isovalerate, citronellol propionate, citronellol tert-methyl, o-methoxybenzyl ethyl ether, 3-(p-isopropylphenyl)-2-methylpropanal, 3-(4-isopropylphenyl)propanal, 1-(3,3-dimethylcyclohexane) Hexyl)ethanol acetate, cyclohexyl salicylate, 2-methyl-3-(4-tert-butylphenyl)propanol, 1,2,3,4,5,6,7,8-octahydro-5,5-dimethyl-2-naphthaldehyde, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, (E)-1-(2,6,6-trimethyl-1-cyclohexyl-1,3-dienyl)but-2-en-1-one, (2E)- 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2-buten-1-one, (E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)buten-2-en-1-one, (E)-1-(2,6,6-trimethyl-1-cyclohexenyl)buten-2-en-1-one, 1-(2,6,6-trimethyl-1-cyclohex-3-enyl)buten-2-en-1-one, trans, trans-2,4-decadienal, 2-pentyl-cyclopropen-1-ol, 2-pentylcyclopentanone, 4-(2,6,6-trimethyl-1-cyclohexenyl)-2-butanone, 3-methyl-2-pentyl-2-cyclopenten-1-one, tetrahydro-4-methyl-2-(2-methylpropyl)- 2H-pyran, methyl anthranilate, dimethyl disulfide, diphenyl ether, (E)-4-ethyloctyl-3-enonitrile, dimethyl sulfide, tetrahydro-4-methyl-2-phenyl-2H-pyran, 4-(octahydro-4,7-methane-5H-inden-5-ylidene)butanal, ethyl linalool acetal, ethyl 2-aminobenzoate, ethyl benzoate, ethyl linalool, cyclohexyl-1,3-diene-1-carboxylic acid, 2,6,6-trimethyl-ethyl ester, ethyl salicylate, farnesol, farnesyl acetate, 3-(3-isopropylphenyl)butanal, 4-methyl-2-(2-methylphenyl)tetrahydropyran-4-ol, 2,6-dimethyl-2-heptanol, 2-methyldecanoic acid, ethyl 2-acetyloctanoate, (2E)-3,7-Dimethyloctyl-2,6-dien-1-ol, geranium oil, geranium acetate, geranyl acetone, geranyl benzoate, geranyl butyrate, geranyl ethyl ether, geranyl formate, geranyl isobutyrate, geranyl isovalerate, geranyl methyl ether, geranyl propionate, geranyl ethyl propionate, 2-[5(6)-methyl-7(8)-(1-methylethyl)bicyclo[2.2.2]oct-5-en-2-yl]-1,3- Dioxolane, Geranium dihydropyran, Methyl 3-oxo-2-pentylcyclopentaneacetate, Methylene dioxinyl-methylpropionaldehyde, Cis-hexen-3-ester of salicylate, Hexyl benzoate, α-hexylcinnamaldehyde, Hexyl salicylate, 2,3-dihydro-1,1-dimethyl-1H-indene-aryl-propionaldehyde, Hydroxycitronellal, Indene, Tetrahydroindenedioxane, Indole, (3E)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one, 4-(2,6,6-trimethylcyclohex-1-en-1-yl) But-3-en-2-one, 4-(2,2,6-trimethyl-2-cyclohexenyl)3-methyl-3-buten-2-one, N-methylionone, non-2-enonitrile, 4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)- 3-Buten-2-one, 4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)-3-buten-2-one (main component), isoamyl acetate, isobutyl salicylate, isocyclogeraniol, 2-hexyl-2-cyclopenten-1-one, 1,5-dehydro-2,4-dideoxy-2-pentyl-3-acetic acid-pentitol, jasmine essential oil, tetrahydro-6-(2-pentenyl)-2H-pyran-2-one, 6-(pent-3-en-1-yl)-tetrahydro-2H-pyran-2-one, 3-methyl-2-[(2Z)-pent-2-en-1-yl] Cyclopent-2-en-1-one, 2-hexyl-2-cyclopenten-1-ol, 3-pentyl-4-tetrahydropyranyl acetate, tetrahydro-3-pentyl-2H-pyran-4-yl acetate, 1,3,4,6,7,8a-hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methylenenaphthalene-8(5H)-one, 5-hexyl-5-methylfuranone, decahydro-2,8,8-trimethylnaphthalene-2,4a-methyllactone, 3-(4-tert-butylphenyl)butanal, (4R)-4-(1-methylethyl)-1-cyclohexene-1-propanal, 2,5-dimethyl-2-indylethanol, linalool, linalool oxide, 4-(4-hydroxy-4-methyl-pentyl)-3-cyclohexene-1-carboxaldehyde, α-methyl-cyclohexylpropanol, β, β-3-trimethyl-phenylpropanol, (Z+E)-p-menthan-7-ol, 3-methyl-5-benzenepentanal, methyl anthranilate, methyl benzoate, methyl diphenyl ether, methyl geraniate, methyl heptynecarboxylic acid, (E)-3-methyl-4-(2,6,6-trimethyl-1-cyclohexyl-2-enyl)but-3-en-2-one, [(1R,Methyl acetate of 2R)-3-oxo-2-((Z)-pent-2-enyl)cyclopentyl]acetate, 2-naphthyl ethyl ketone, methyl octyne carboxylate, 2-methylvaleric acid, methyl salicylate, mimosa extract, 1-(4-isopropyl-cyclohexyl) Ethanol, 3-methyl-4-phenylbut-2-ol, 2,2-dimethyl-3-phenylprop-1-ol, octahydro-4,7-methylene-indene-5-methanol acetate, narcissus extract, methyl 2-nonenoate, nerol, neroli oil, 3,7,11-trimethyl-1,6,10-dodecanetrien-3-ol, ethyl 2-naphthyl ether, 2-methoxynaphthalene, 1-(3-methyl-1-benzofuran-2-yl) ethyl-1-one, neroli acetate, trans,cis-2,6-nonadienal, trans,trans-2,4-nonadienal, 2,6-nonadienol, 10-hydroxymethylene-2-pinene, neroli absolute, 4-(2-methylbut-2-yl)cyclohexyl-1-one, iris root extract, iris resin, citronella oil, 3-[(2Z)-3-hexenoxy]- Propanonitrile, 1,1-dimethoxynon-2-yne, n-nonanoic acid, amyl salicylate, 2-cyclohexyl-2-phenylacetonitrile, orange leaf oil, 2-methylpropionic acid-2-phenoxyethyl ester, 3-methyl-5-phenyl-1-pentanol, phenyl salicylate, phenethyl acetate, phenethyl alcohol, phenethyl benzoate, phenethyl butyrate, phenethyl isovalerate, methyl phenethyl ether, phenethyl phenylacetate, 2,2-dimethylpropionic acid-2-phenylethyl ester, phenethyl propionate, phenethyl salicylate, phenethyl ethyl acetate, phenylpropyl acetate, isoprene salicylate, 2,6,10-trimethyl-5,9-undecadien-1-ol, 2-hexylcyclopentanone, 2-heptylcyclopentanone, 2,3,6-trimethylcyclohexyl ethyl carbonate, 2,2-Dimethyl-6-methylenecyclohexanecarboxylate, α-(trichloromethyl)benzyl acetate, β-methylbenzyl alcohol, rose essential, tetrahydro-4-methyl-2-(2-methyl-1-propen-1-yl)-2H-pyran, 4-methyl-2-phenyl-3,6-dihydro-2H-pyran, 4-methyl-6-phenyl-3,6-dihydro-2H-pyran, 4-methylene-2-phenyltetrahydro-2H-pyran, 2-methyl-3-[4-(2-methylpropyl)phenyl]propanal, α-terpineol, tetrahydrolinalool, tetrahydrogeraniol, thiogeraniol, tuberose essential, (E)-4-methyldec-3-en-5-ol, 2, 2,5-Trimethyl-5-pentylcyclopentan-1-one, methyl 2-[[3-[4-(1,1-dimethylethyl)phenyl]-2-methylpropylene]amino]benzoate, 1-methyl-4-(4-methylpentyl)-3-cyclohexenaldehyde, 4-(4-methylpent-3-enyl)cyclohex-3-en-1-carboxaldehyde, violet leaf extract, methyl-4-cycloocten-1-yl carbonate, 2,6-nonadienonitrile, ylang-ylang oil, Aromatic / Herbal Notes: α-3,3-trimethylcyclohexyl methyl formate, artemisia oil, bornyl acetate, camphene, camphor D, L, wormwood oil, carvacrol, L-carvacrol, carvacrol-menthol, dextrorotatory carvacrol, levorotatory carvacrol, cedar leaf oil, 1,3,3-trimethyl-2-oxabicyclo[2.2.2]octane, clary sage oil, 3a,4,5,6,7,7a-hexahydro-1H-4,7-methyleneinden-5-yl-2-methylpropionate, p-cymene, cypress oil, dihydrocarvacrol, dill seed oil, 1-methoxyhexane, 1,3,3-trimethyl-2-oxabicyclo[2.2.2]octane, eucalyptus oil, fennelol, 1,3,3-trimethyl-2-norborneol acetate, firabsolute, fragrance Abies spp., 1-(3,3-dimethylcyclohexyl) ethyl ketone, 3a,4,5,6,7,7a-hexahydro-4,7-methylene indene-6-ol ester, tricyclodecenyl propionate, isoborneol, isoborneol acetate, isoborneol propionate, isobutyl menthone, isomenthone, 4-isopropylcyclohexanol, juniper berry oil, laurel oil, mixed lavender oil, lavender oil, oregano oil, peppermint essential oil, menthol, L-menthone / isomenthone Alcohols, menthyl acetate, (3,3,5-trimethylcyclohexyl) acetate, 6,6-dimethyl-2-norpinen-2-ethanol acetate, oregano oil, 4-tert-butylcyclohexyl acetate, Haitian oil, peppermint oil, pine needle extract, pine oil, 6,6-dimethylbicyclo[3.1.1]hept-2-en-2-propanal, octahydro-7-methyl-1,4-methylenenaphthalene-6(2H)-one, 4-acetoxy-4-methyl- 2-Propyltetrahydro-2H-pyran, spearmint oil, spikenard oil, tea tree oil, terpineol-4-ol, 2,6,6,10-tetramethyl-1-oxaspiro[4.5]dec-9-ene, turmeric oil, [1S-(1a,4a,5a)]4-methyl-1-(1-methylethyl)bicyclo[3.1.0]hexane-3-one, thyme oil, thymol, turpentine oil, 2-tert-butylcyclohexanol, artemisia oil and mixtures thereof.

[0030] The citrus fragrance profile comprises 3,7-dimethyl-6-octen-1-onitrile, n-decanal, 6,6-dimethoxy-2,5,5-trimethylhex-2-ene, bergamot oil, ethyl 6-acetoxyhexanoate, citronella essential oil, citral diethyl acetal, citral, methyl 2,4-dimethyl-3-cyclohexene-1-acetate, citronellol oil, citronellol, (E)-3-methyl-5-phenylpentan-2-enenitrile and (Z)-3-methyl-5-phenylpentan-2-enenitrile, α-vinyl-α- 2,4,4,7-Tetramethyl-6-octen-3-one, (+ / -)-2,8-cyclothio-cis-p-menthane, 3-mercapto-β,4-dimethylcyclohexanethiol, cyclohexylethyl acetate, dihydromyrcenol, dihydromyrcenyl acetate, dimethyloctenone, ethyl linalyl acetate, eucalyptus oil, grapefruit oil, 3-methyl-5-phenylpentanilonitrile, lemon oil, lemongrass oil, 3,7-dimethyl-2(3),6-nonadienonitrile, 1-methyl-4-(1-methylvinyl)cyclohexene, lime oil, linalyl acetate, aromatic benzoate Linaloyl butyrate, linaloyl formate, linaloyl isobutyrate, linaloyl propionate, Litsea cubeba oil, (E)-2,12-tetraceneadiene nitrile and (E)-3,12-tetraceneadiene nitrile and (Z)-3,12-tetraceneadiene nitrile, (E)-2-dodecenal, orange oil, 2-methyl-4-propyl-1,3-oxothiacyclohexane, myrcene acetate, 3,5,5-trimethylhexyl acetate, (4R,4aS,6R)-6-isopropenyl-4,4a-dimethyl-4,4a,5,6,7,8-hexahydro-2(3H)- Naphthol, (3Z,6E)-8-ocimenol acetate, sweet orange oil, 2-ethyl-N-methyl-N-(3-methylphenyl)butyramide, 2,6-dimethyl-10-methylene-2,6,11-dodecanetrienal, (2S)-2-(1,1-dimethylpropoxy)propionate, mandarin orange oil, (E / Z)-6,10-dimethylundec-5,9-dien-2-ol acetate, terpineol acetate, tetrahydrolina acetate, tetrahydromyrcenol.

[0031] Green Fragrance Notes: Allyl isopentoxyacetate, sec-butyl 3-methylthiohydroxybutyrate, 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde (main component), allyl cyclohexyloxyacetate, dibutyl sulfide, 2-ethyl-3,5(6)-dimethylpyrazine, dimethylpyrazine-2,3, dimethylpyrazine-2,5, dimethylpyrazine-2,6, 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, ethylpyrazine-2, 2,4,6-trimethyl-4-phenyl-1,3-dioxane, gluconol, 1-(5,5-dimethyl-1-cyclohexen-1-yl)penten-4-penten-1-one, N,2-dimethyl-N-phenylbutyramide, 2-[6(5)-methyl-8(7)-(1-methylethyl)bicyclo[2.2.2] [Octo-5-en-2-yl]-1,3-dioxane, 3,3,5-trimethylcyclohexylethyl ether, trans-2-hexenal, trans-3-hexenol, cis-3-hexenol, trans-2-hexenol, 3-hexenyl acetate (cis / trans) cis-3-hexenyl acetate, trans-2-hexenyl acetate, cis-3-hexenol benzoate, cis-3-hexenyl butyl ester, cis-3-hexenyl hexanoate, cis-3-hexen-1-acetal, cis-3-hexenol carboxylate, cis-3-hexenyl isobutyrate, cis-3-hexenyl isovalerate, cis-3-hexenol lactate, cis-3,2-methylbutyrate hexenol ester, cis-3-hexenyl propionate, cis-3-hexen-1-yl tetroxide, cis-3-hexenyl tetroxide, (2,2-dimethoxy-1-methylethyl)benzene, 2-isobutyl-3-methoxypyrazine, 2,4,6-trimethyl-3-cyclohexen-1-carboxaldehyde, 2-isopropyl-3-methoxypyrazine, 2-isopropyl-4-methylthiazole, (Z )-Hex-3-en-1-ol methyl carbonate, (3E)-1-(1-methoxypropoxy)-3-hexene, 2,4-dimethyl-3-cyclohexenecarboxaldehyde, 2,4-dimethyl-tetrahydroindenedioxane, 2,6-dimethyl-5-heptenal, octahydro-1H-4,7-methyleneindene-1-carboxaldehyde, methyl-dihydrocyclopentylpyrazine, methyl 2-nonyneate, 2-methylpyrazine, 3,3,5-trimethylcyclohexyl acetate, 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, 3,5,6-trimethyl-3-cyclohexen-1-carboxaldehyde, cis-6-nonenol, 1-octen-3-ol, phenylacetaldehyde, phenylacetaldehyde dimethyl acetal, 8-ocimene-1-yl acetate, 5H,5M Cyclopentapyrazine, tetrahydro-2,4-dimethyl-4-phenyl-furan, 6-ethide-octahydro-5,8-methylene-2H-1-benzopyran, 1-spiro[4].5] Dec-7-en-7-yl-4-penten-1-one, 5-methyl-3-heptanone oxime, 1-phenylethanol acetate, 1-phenylethanol, 1-phenylethyl propionate, β-methylphenylpropanal, 2-propenyl-p-cymene, 4-vinyl-2-(2-methylpropyl)-1,3-dioxane, 2,4,6-trimethyl-4-phenyl-1,3-dioxane, 3-(methylthio)propyl butyrate, 2,4-dimethylcyclohex-3-en-1-carboxaldehyde, dimethyl-3-cyclohexen-1-carboxaldehyde, 2-{[(1E)-(2,4-dimethylcyclohex-3-en-1-yl) Methyl [methylene]amino}benzoate, sec-butyl 3-methylthiohydroxybutyrate, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, allyl cyclohexyloxyacetate, dibutyl sulfide, 2-ethyl-3,5(6)-dimethylpyrazine and mixtures thereof.

[0032] Spicy notes: Allspice oil, benzyl cinnamate, benzyl isoeugenol, caryophyllene, cinnamon oil, methyl cinnamyl alcohol, cinnamic acid, cinnamyl alcohol, cinnamaldehyde, cinnamon leaf oil, cinnamon essential oil, cinnamyl acetate, cinnamyl cinnamate, cinnamyl formate, cinnamyl isobutyrate, cinnamyl isovalerate, cinnamonitrile, clove bud oil, clove leaf oil, cumin oil, cuminol, cuminaldehyde, cuminonitrile, cuminyl acetate, dihydroeugenol, ethyl cinnamate, eugenol, eugenol methyl ether, eugenol acetate, ginger oil, 2-methoxycinnamaldehyde, isoamyl cinnamate, isobutyl cinnamate, isoeugenol, isoeugenol acetate, isoeugenol methyl ether, cinnamic acid Linaloyl ester, nutmeg oil, (5 or 6)-methyl-(7 or 8)-(1-methylethyl)bicyclo[2.2.2]oct-5-en-2-carbonaldehyde, methoxycinnamaldehyde, methyl cinnamate, methyl cinnamaldehyde, 2-ethoxy-4-(methoxymethyl)phenol, 7-methyl-3-methylene-1,6-octadiene, nutmeg oil, p-menthol-1,8-dien-7-aldehyde, phenethyl cinnamate, phenylpropanol, phenylpropanol, 3-phenylpropanoic acid, allspice oil, 2,3,3-trimethylindanone, 2,6,6-trimethylcyclohexane-1,3-dienylformaldehyde, 1,2-dimethoxybenzene and mixtures thereof.

[0033] In this case, the weight ratio (a):(b1+b2) of the primary flavoring (a) to the two secondary flavorings (b1, b2) in the mixture can be between about 0.1:99.9 and about 10:90, preferably between about 2:98 and about 3:97, and more preferably about 2.5:97.5.

[0034] Regardless of whether a binary or ternary mixture is obtained, in all cases, the preferred primary flavoring (a) is selected from the following group: 3,4-Dimethylbenzonitrile; 4-(2-methylpropyl)benzonitrile; 3-Methylbenzonitrile; 2-Methoxybenzonitrile; 3,4-Dimethoxybenzonitrile; 4-Methoxybenzonitrile and mixtures thereof.

[0035] The preferred primary flavoring (a) is 3,4-dimethylbenzonitrile.

[0036] solvent In another preferred embodiment, the fragrance mixture according to the invention comprises a fragrance-grade solvent (component c), such as water, benzyl alcohol, benzyl benzoate, diethyl phthalate, dipropylene glycol, ethanol, isopropyl myristate, triethyl citrate, dipropylene glycol methyl ether (Dowanol® DPM), petroleum fractions (e.g., IsoPar L (Exxon)), triacetin, and mixtures thereof.

[0037] Ethanol, dipropylene glycol, triethyl citrate, and mixtures thereof are particularly preferred.

[0038] The solvent content in the mixture can be up to 25% by weight, preferably about 1 to about 20% by weight, more preferably about 2 to about 15% by weight, and most preferably about 5 to about 10% by weight.

[0039] Regarding fragrance longevity, it has been found that the combination of 3,4-dimethylbenzonitrile, one or two preferred secondary fragrances, and a preferred solvent, especially ethanol, has the best effect.

[0040] Flavoring preparations Another object of the present invention relates to a fragrance preparation comprising a mixture as defined above, and at least 1, 2, 3, 4, 5 or more third-class fragrances or essential oils; preferably, these fragrances or essential oils are different from component (a), but may overlap with component (b).

[0041] Suitable spices and essential oils can be selected from the following group: alcohols, Aldehydes, Amines, amides, nitriles, esters, Ethers, Ketones lactones, and its mixtures.

[0042] The following sections will illustrate the above groups with various examples and, to the extent known to professionals, distinguish spices or essential oils by their trade names or common names.

[0043] alcohols Suitable alcohols known by their trade names to those skilled in the art include, for example, 1-(2-tert-butylcyclohexyl)oxobut-2-ol (139504-68-0; Amber Core), 2,6-di-tert-butyl-p-methylphenol (128-37-0; BHT Ionol), (Z)-3-methyl-5-(2,2,3-trimethyl-1-cyclopent-3-enyl)pent-4-en-2-ol (67801-20-1; Ebanol), 4-methyl-2-(2-methylpropyl)tetrahydropyran-4-ol (63500-71-0; Florosa / Pyranol), [(1R,2S)-1-methyl-2-[[(1R,3S,5S)-1,2,2-trimethyl-3-bicyclo[3.1.0]hexyl]methyl]cyclopropyl]methanol (198404-98-7; Javanol), (3R)-1-[(1R,6S)-2,2,6-trimethylcyclohexyl]hex-3-ol, (3S)-1-[(1R,6S)-2,2,6-trimethylcyclohexyl]hex-3-ol (70788-30-6; Norlimbanol), 3-methyl-5-phenylpentan-1-ol (55066-48-3; Benzoyl alcohol), (E)-3,3-dimethyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol (107898-54-4; polysantalinol), 5-(3-methylphenyl)pent-1-ol (25634-93-9; Rosaphen), 3-methyl-5-(2,2,3-trimethylcyclopenten-3-en-1-yl)pent-2-ol (1471313-03-7; 65113-99-7; sandalwood 210 (Sandalore)), (2E)-2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)- Buten-1-ol + 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol (106185-75-5; 28219-61-6; Sandranol), (E)-4-methyldecen-3-en-5-ol (81782-77-6; methyldecenol (Undecavertol)), 3-[5,5,6-trimethylbicyclo[2.2.1]hept-2-yl]cyclohexyl-1-ol (70955-71-4; Sandela) and mixtures thereof.

[0044] Suitable alcohols known by their trade names to those skilled in the art include, for example, hexane-1-ol, octane-1-ol, decane-1-ol, dodecane-1-ol, borneol, isoborneol, citronellol, L-citronellol, dihydroeugenol, dihydromyrcenol, dimethylbenzyl alcohol, ethyl linalool, eugenol, geraniol, cis-3-hexenol, isoborneol cyclohexanol, linalool, nerolidol, phenethyl alcohol, phenethyl dimethyl alcohol, phenylpropanol, propenyl ethyl guaiacol, sulfonyl alcohol, α-terpineol, tetrahydrolinalool, thymol, and mixtures thereof.

[0045] Aldehydes Suitable aldehydes known by their trade names to those skilled in the art include, for example, 2,6,10-trimethylundecyl-9-enal (141-13-9; Farenal), α,3,3-trimethylcyclohexyl methyl formate (25225-08-5; Aphermate), 4-(1,1-dimethylethyl)phenylpropanal (18127-01-0; Bourgeonal), 6-methoxy-2,6-dimethyloctanal (929253-05-4; Calypsone), 4-methoxy-α-methylphenylpropanal (5462-06-6; Cancinal), and α,2,2,6-tetramethylcyclohexenylbutanal (65405-84-7; Cetonal, 8,8-dimethyl-1,2,3,4,5,6,7,8-octahydro-2-naphthaldehyde + 1,2,3,4,5,6,7,8-octahydro-5,5-dimethyl-2-naphthaldehyde (68991-96-8; 68991-97-9; Cyclomyral), 4-(octahydro-4,7-methylene-5H-indene-5-methylenebutyraldehyde (30168-23-1; Dupical), 4,8-dimethyl-4,9-decadienal (71077-31-1; Floral Super), 3-(4-ethylphenyl)-2,2-dimethylpropanal + 3-(2-ethylphenyl)-2,2-dimethylpropanal (67634-15-5; 67634-14-4; Florhydral), β-methyl-3-(1-methylethyl)-phenylpropanal (12509-85-5), methylenedioxyphenyl-methylpropanal (1205-17-0), α,4-dimethylphenylpropanal (41496-43-9), (Z,E)-2,4-dimethylcyclohexyl-3-en-1-carboxaldehyde (68039-49-6), 68737-61-1, Tripalal, Cyclal C, Vertocitral, 3-(4-tert-butylphenyl)butanal (80-54-6), (1R)-β,4-dimethyl-3-cyclohexyl-1-propanal (199445-85-7); Liminal), (4R)-4-(1-methylethyl)-1-cyclohexene-1-propanal (1378867-81-2; Lilybelle), (4S)-4-(1-methylethyl)-1-cyclohexene-1-propanal (1378867-82-3; Lilybelle isomer), 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde (130066-44-3; New Lily Aldehyde), 6-methyl-1-8-yl-methylethyl-bicyclo[2.2].2] Oct-5-en-2-carboxaldehyde (67845-30-1; Marseille aldehyde); (±)-2,6-dimethyl-5-heptenal (106-72-9; melon aldehyde), (E)-2,6,10-trimethylundecane-5,9-dienal (54082-68-7; Oncidal), 6,6-dimethylbicyclo[3.3.1]hept-2-en-2-propanal (33885-51-7; rosin acetaldehyde), 1-methyl-4-(4-methyl-3-pentenyl)cyclohex-3-en-1-carboxaldehyde + 6,6-dimethylbicyclo[3.3.1]hept-2-en-2-propanal (119652-81-2; 52475-86-2; Precyclemone) B), 3-Phenylacetaldehyde (16251-77-7; Trifernal), octahydro-5-methoxy-4,7-methylene-1H-indene-2-carboxaldehyde (86803-90-9; Scentenal), rel-(3aR,4R,5R,7R,7aR)-octahydro-4,7-methylene-1H-indene-5-aldehyde (145374-28-3; Vertral), 4-(4-methylpent-3-enyl)cyclohex-3-en-1-carboxaldehyde (37677-14-8; Vertomugal), and mixtures thereof.

[0046] In addition, aldehydes known by their trade names to those skilled in the art include, for example, hexanal, heptanal, octanal, 2-nonen-1-al, nonanal, decanal, undecenal, 2-methyldecenal, 10-undecenal, undecenal, dodecenal, 2-methylundecenal, anisaldehyde, benzaldehyde, citral, citronellol, cinnamaldehyde, cuminaldehyde, cyclamenaldehyde, dihydrocitronellol, trans-2-dodecenal, ethyl vanillin, geranialdehyde, jasmine aldehyde / piperaldehyde, trans-2-hexenal, α-hexylcinnamaldehyde, solanal (Hydratropic Aldehyde), hydroxycitronellol, ifocyclic citral, methoxycitronellol, neraldehyde, phenylacetaldehyde, tangerine, cyclamen homologues, vanillin, and mixtures thereof.

[0047] Amines, amides and nitriles Amines, amides, and nitriles known by their trade names to those skilled in the art include, for example, 3,7-dimethyloctyl-6-enonitrile (51566-62-2; citronellol), (E / Z)-3-methyl-5-phenylpentan-2-enonitrile (53243-59-7; 53243-60-0; 93893-89-1; citronellol), 3,7-dimethylnonan-2,6-dienonitrile (61792-11-8; citronellol), 4-[(3E)-4,8-dimethylnonan-3,7-dienyl]pyridine (38462-23-6; Maritim), tridecano-2-enonitrile (22629-49-8; Ozonil), 2-cyclohexyl-2-phenylacetonitrile (10461-98-0; Peonile), and mixtures thereof.

[0048] Amines, amides, and nitriles known by their trade names to those skilled in the art include, for example, indole.

[0049] esters Esters known by their trade names to those skilled in the art include, for example, cis-2-tert-butylcyclohexyl acetate + (2-tert-butylcyclohexyl) acetate (20298-69-5; 88-41-5; Argumex HC / LC), ethyl 3-methyl-3-phenylglycidyl (77-83-8; so-called "hexadecaldehyde"), 2-cyclohexyloxypropenyl-2-ene acetate (68901-15-5; cyclohexylene acetate), methyl 2,4-dihydroxy-3,6-dimethylbenzoate (4707-47-5; cyclohexylene acetate), 4-methylpentane-2-ester (E)-but-2-enoic acid (35206-51-0; Frutinat), and ethyl 2-ethyl-6,6-dimethylcyclohexyl-2-ene-1-carboxylate (57934-97-1; 77851-07-1; Hedione), methyl 3-oxo-2-pentylcyclopentaenoic acid (24851-98-7), propyl 2-(1-(3',3'-dimethyl-1'-cyclohexyl)ethoxy)-2-methylpropionate (141773-73-1); Hedione, 3a,4,5,6,7,7a-hexahydro-4,7-methylene-1H-indene-6-ol acetate (5413-60-5); tricyclodecenyl acetate, methyl [(Z)-hex-3-en]ol carbonate (67633-96-9); Leafovert, ethyl 2-methylpentanoate (39255-32-8); Manzanate), 2-[1-(3,3-dimethylcyclohexyl)ethoxy]-2-oxoethylpropionate (236391-76-7; Roman Musk), ethyl 2-cyclopent-2-en-1-yl acetate (15848-49-4; Sultanene), (1S,2R,5S)-5-methyl-2-(1-methylethyl)cyclohexanol acetate + [(1R,2S,5R)-5-methyl-2-prop-2-ylcyclohexanol]-acetate (29066-34-0; 89-48-5; Symfresh RF / Menthyl acetate), 3-hydroxy-2,2,4-trimethylpentyl 2-methanolpropionate (25265-77-4; Symfresh NX), (4-methyl-4-phenylpentyl-2-ol)-acetate (68083-58-9; Vertikolacetat), and mixtures thereof.

[0050] Esters known by their trade names to those skilled in the art include, for example, allyl isopentoxyacetate; allyl hexanoate; allyl cyclohexylpropionate; allyl heptaate; benzyl acetate; benzyl salicylate; citronellol acetate; dimethyl benzyl acetate; dimethyl benzyl butyrate; ethyl butyrate; ethyl hexanoate; ethyl trans / cis-2,4-decadienoate; ethyl 2-methylbutyrate; ethylene glycol brassinate; geraniol acetate; tricyclodecenyl propionate; cis / trans-3-hexyl acetate. Enyl esters; cis-3-hexenol acetate; cis-3-hexenol butyrate; cis-3-hexenol isobutyrate; cis-3-hexenol salicylate; hexyl acetate; hexyl butyrate; hexyl isobutyrate; hexyl salicylate; isoamyl acetate; isoborneol acetate; isobutyl acetate; isoeugenol acetate; linalyl acetate; methyl octyne carboxylate; nerol acetate; phenethyl butyrate; phenethyl cinnamate; isopentenyl acetate; styrax acetate; methyl o-aminobenzoate and mixtures thereof.

[0051] ethers Ethers known by their trade names to those skilled in the art include, for example, (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran (6790-58-5; ambergris ether), 5-hexyl-4-methyldihydrofuran-2-one (67663-01-8; Aprifloren), cyclohexadecyl-2-en-1-one (2550-59-6; 3100-36-5; 88642-03-9; Aurelione), 3,4-diethyl-2,5-dimethylcyclohexyl-2-en-1-one (68845-36-3; Azarbre), 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopentano(g)-2-benzopyran (1222-05-5; Gyra Musk), (2R,4S)-2-methyl-4-propyl-1,3-oxothiacyclohexane + 2-methyl-4-propyl-1,3-oxothiacyclohexane (59323-76-1, 261-699-8; Oxane), 3,7'-dimethyl-3,4,4a,5,8,8a-hexahydrospiro-(1,4-methylenenaphthalene-2(1H),2'-epoxyethylene) (41816-03-9; Rhubofix) and mixtures thereof.

[0052] Ethers known by their trade names to those skilled in the art include, for example, anethole; lime oxide; Nerolin Yara Yara; nerol and mixtures thereof.

[0053] Ketones Ketones known by their trade names to those skilled in the art include, for example, 7-methyl-3,4-dihydro-2H-1,5-benzodioxazolidin-3-one (249-320-4; citrullone), 1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-4H-indene-4-one (251-649-3; cashmereone), [3R-(3α,3aβ,6α,7β,8aα)]-octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methyleneol+(3R,3aS,6R,7R,8aS)-octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methyleneol (19870-74-7; 67874-81-1; Cedramber), 3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran (3738-00-9; ambroxol), 1-(5,5-dimethyl-1-cyclohexenyl)pent-4-en-1-one (56973-85-4; Dynasty ketone, Grupone), 1-[bis(2-hydroxypropyl)amino]prop-2-ol, 5-methylhept-2-en-4-one (102322-83-8; 81925-81-7; Filbertone), 4-(4-hydroxyphenyl)but-2-one (5471-51-2; Frambinon), (8E)-cyclohexadecyl-8-en-1-one (3100-36-5; Globanone), 4-(2,5,6,6-tetramethylcyclohexyl-2-enyl)but-3-en-2-one (201-219-6; methyl-iridanone); 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthyl-2-yl)acetone (54464-57-2; ambroxanone), cyclohexadecanone (2550-52-9; Isomuscone), 5,5,9,13-tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10].[04,9] Hexadecane (57345-19-4; Ketamber), 5-hexyl-5-methyloxacyclopentan-2-one (7011-83-8; Lactojasmone), (E)-3-methyl-4-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-3-en-2-one (127-51-5; Methyl IononeGamma Coeur), N-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1-en-3-one (1335-46-2; MethylIonone Gamma Pure), (5E)-3-methylcyclopentadecan-5-en-1-one; (5E)-3-methylcyclopentadecan-5-en-1-one (63314-79-4; 82356-51-2; Muskenone), 3-methylcyclopentadecan-1-one (541-91-3; Muskenone), 2-[2-(4-methyl-1-cyclohexyl-3-enyl)propyl]cyclopenta-1-one (95962-14-4; Nectaryl), 1-(3-methyl-1-benzofuran-2-yl) ethyl-1-one (23911-56-0; Nerolione), octahydro-7-methyl-1,4-methylenenaphthalene-6(2H)-one (41724-19-0; Plicatone), 1-(3,5,5,6,8,8-hexamethyl-6,7-dihydronaphthalene-2-yl) ethyl ketone + 1-(3,5,5,6,8,8-hexamethyl-6,7-dihydronaphthalene-2-yl) ethyl ketone (1506-02-1; 21145-77-7; musk), 2,2,5-trimethyl-5-pentylcyclopentan-1-one (65443-14-3; vanillone) and mixtures thereof.

[0054] Ketones known by their trade names to those skilled in the art include, for example, daemonones; α-daemonones; β-daemonones; δ-daemonones; -Dihydroionone; Dihydrojasmone; Ethyl maltol; γ-caprolactone; α-ionone; - Ionone; Jasmolactone; Jasmolactone CNC; cis-jasmone; Maltol; Methyl ionone and mixtures thereof.

[0055] lactones Lactones known by their trade names to those skilled in the art include, for example, 5-heptyloxetane-2-one (104-67-6; so-called "aldehyde C14"), 5-pentyloxetane-2-one (203-219-1; so-called "aldehyde C18"), (9Z)-17-oxocycloheptadec-9-en-1-one (28645-51-4; okra lactone), (12E)-1-oxetane-hexadecane-12-en-2-one + (3E)-oxetane-hexadecane-3-en-2-one (111879-80-2; 34902-57-3; Globalide); 16-oxetane-hexadecane-1-one (106-02-5; Supra Macrolide) and mixtures thereof.

[0056] In addition, lactones known by their trade names to those skilled in the art include, for example, butyl-decyl lactone; propyl-decyl lactone; propyl-octyl lactone; Rose Oxide High Cis and mixtures thereof.

[0057] Essential oils and extracts Suitable spices and aromatic oils can also be selected from essential oils, extracts, and other fragrances, such as: ambrette seed absolute; amygdalin essential oil; angelica root oil; almond oil; artemisia oil; basil oil; laurel oil; beeswax absolute; benzoin gum; bergamot oil; agarwood essential oil; Brazilian sandalwood oil; juniper oil; guavakan oil; caraway oil; cardamom absolute / oil; carrot seed oil; cinnamon oil; Egyptian acacia absolute; Cassis Abs. Burgundy; Castroreum Abs. Cedarwood leaf oil; Cedarwood essential oil; Atlantic cedarwood essential oil; Celery seed oil; Blue chamomile essential oil; Roman chamomile essential oil; Cinnamon bark essential oil; Cinnamon leaf oil; Rockrose absolute; Rockrose oil; Taiwan / Java lemongrass oil; Clary sage essential oil; Clove bud oil; Clove leaf oil; Coconut oil; Copa balsam oil; Coriander oil; Custard oil; Cypress essential oil; Cyperus rotundus oil; Artemisia argyi oil; Dill oil; Dynamone; Elemi balsam oil / Gum; Tarragon oil; Lemon eucalyptus oil; Sweet fennel oil; Fir balsam absolute; Fucus veitchii absolute; Glehnia littoralis oil; Geranium oil; Ginger extract / oil; White grapefruit essential oil; Guaiac oil; Ancient rue balsam oil; Hay oil; Rockrose resin extract; Immortelle oil; Jasmine oil; Jasmine flower oil; Juniper berry oil; Rockrose absolute / Rockrose resin; Laurel leaf oil; Lavender oil; White lavender oil; Lemon essential oil; Lemon oil terpenes; Winter-harvested lemon oil; Lemongrass oil; Lentisque Abs.; Lime oil; Lime oil terpenes; Litsea cubeba oil; Angelica pubescens oil; Mace essential oil with low safrole content; Nutmeg oil; Magnolia flower oil; Magnolia leaf oil; Orange oil; Marigold essential oil; Peppermint oil; Silver acacia oil; Tree moss extract; Myrrh oil; Myrtle oil; Narcissus absolute oil; Neroli essential oil; Nutmeg oil; Frankincense oil; Red myrrh oil / Resins; Neroli absolute; Orange oil; Oregano oil; Osmanthus essential oil; Palmarosa oil; Parsley leaf oil; Parsley seed oil; Patchouli oil; Black pepper oil; Pepper oil / Sichuan pepper absolute; Peppermint oil; Peruvian balsam oil; Bitter orange leaf absolute; Lemon orange leaf oil; Allspice leaf oil; Pine needle absolute; Pine needle oil; Pink pepper leaf oil; Red berry extract; Red berry oil; Rose absolute; Rosemary oil; Rum CO2 extract; Sage oil; Sandalwood oil; Spearmint oil; Nardostachys oil; Star anise oil; Styrax oil; Sweet almond oil; Marigold oil; Brazilian mandarin oil; Tea tree oil; Thuja oil; Thyme oil; Sichuan pepper oil; Tonka bean absolute; Tuberose absolute; Turmeric oil; Turmeric oil; Vanilla absolute; Vetiver oil / Absolute extract; Violet leaf absolute; Wheat bran absolute; Artemisia oil; Ylang-ylang oil and mixtures thereof.

[0058] Another object of the present invention relates to a method for preparing the flavoring preparation, the method comprising or consisting of the following steps: (i) Provide a spice blend as defined above; (ii) Provide at least one, two, three, four, five or more types of third-category spices, particularly those selected from the list above, and (iii) Add about 1 to about 100 parts of component (i) to 900 to 999 parts of component (ii) to obtain 1,000 parts of the formulation.

[0059] Consumer products Another object of this application relates to a consumer product, more specifically a cosmetic, detergent, or household product, which is obtained by the following steps: (i) Providing flavor mixtures or fragrance preparations as defined above; (ii) To provide a cosmetic, detergent, or household base composition; (iii) Add about 10 to about 100 parts of component (i) to 990 to 999 parts of component (ii) to obtain 1,000 parts of the product.

[0060] In addition, protection is also sought for a method of preparing cosmetics, detergents, or household products, which includes or comprises the following steps: (i) Providing flavor mixtures or fragrance preparations as defined above; (ii) To provide a cosmetic, detergent, or household base composition; (iii) Add about 10 to about 100 parts of component (i) to 990 to 999 parts of component (ii) to obtain 1,000 parts of the product.

[0061] The term "base formulation" refers to a complete consumer product, such as a shampoo, lotion, liquid detergent, or fabric softener, which is only lacking the addition of the fragrance mixture or flavoring preparation according to the present invention. For the avoidance of doubt, step (iii) means mixing a specific amount of the fragrance mixture or flavoring preparation with a corresponding amount of the base formulation to make 1000 parts or 100% by weight.

[0062] Industrial applications Another object of the present invention relates to a method for adjusting, enhancing, and / or prolonging the lasting power of a fragrance, comprising or consisting of the following steps: Provide at least one main flavoring conforming to general formula (I)

[0063] Where R 1 R 2 R 3 R 4 and R 5 Independently representing hydrogen; or representing straight-chain or branched C1-C. 10Alkyl group, which may optionally be substituted with hydroxyl or C1-C4 alkyl; or representing straight-chain or branched C1-C4 alkyl groups. 10 Alkoxy groups, which may optionally be substituted with hydroxyl or C1-C4 alkyl groups, Provide at least one secondary flavoring agent different from component (a), said at least one secondary flavoring agent exhibiting at least one of the following aroma notes: Fruity aroma; Woody aroma; Floral fragrance; Aromatic / Herbal; Tangerine; Spicy; and Green fragrance, Optionally, at least one solvent may be provided. Mixed components (i), (ii), and optional (iii).

[0064] The preferred embodiment of the main spice is selected from the group including 3,4-Dimethylbenzonitrile; 4-(2-methylpropyl)benzonitrile; 3-Methylbenzonitrile; 2-Methoxybenzonitrile; 3,4-Dimethoxybenzonitrile; 4-Methoxybenzonitrile and mixtures thereof.

[0065] The preferred main fragrance to be used in this method is 3,4-dimethylbenzonitrile.

[0066] Preferred secondary flavorings are selected from the group consisting of menthol acetate, myrcene, phellandrene, phenoxyethyl isobutyrate, 2-ethyl-4-(2,2,3-trimethylcyclopent-3-enyl)-but-2-en-1-ol, 1-hydroxy-2,2,4-trimethyl-3-pentyl isobutyrate and 3-hydroxy-2,2,4-trimethyl-1-pentyl isobutyrate and mixtures thereof.

[0067] The solvent is selected from the group consisting of water, benzyl alcohol, benzyl benzoate, diethyl phthalate, dipropylene glycol, ethanol, isopropyl myristate, triethyl citrate, dipropylene glycol methyl ether, petroleum fractions, triacetin, and mixtures thereof.

[0068] Preferred solvents are selected from the group consisting of ethanol, dipropylene glycol, triethyl citrate, and mixtures thereof.

[0069] In a preferred embodiment The main fragrance is 3,4-dimethylbenzonitrile; Secondary flavorings are selected from menthol acetate, myrcene, phellandrene, phenoxyethyl isobutyrate, 2-ethyl-4-(2,2,3-trimethylcyclopentan-3-enyl)-but-2-en-1-ol, 1-hydroxy-2,2,4-trimethyl-3-pentyl isobutyrate and 3-hydroxy-2,2,4-trimethyl-1-pentyl isobutyrate and mixtures thereof; and The solvent is selected from the group consisting of ethanol, dipropylene glycol, triethyl citrate, and mixtures thereof.

[0070] In a more preferred embodiment The main fragrance is 3,4-dimethylbenzonitrile; Secondary flavorings are selected from menthol acetate, myrcene, phellandrene, phenoxyethyl isobutyrate, 2-ethyl-4-(2,2,3-trimethylcyclopentan-3-enyl)-but-2-en-1-ol, 1-hydroxy-2,2,4-trimethyl-3-pentyl isobutyrate and 3-hydroxy-2,2,4-trimethyl-1-pentyl isobutyrate and mixtures thereof; and The solvent is ethanol.

[0071] In addition, protection is required for at least one main spice conforming to general formula (I).

[0072] Where R 1 R 2 R 3 R 4 and R 5 Independently representing hydrogen; or representing straight-chain or branched C1-C. 10 Alkyl group, which may optionally be substituted with hydroxyl or C1-C4 alkyl; or representing straight-chain or branched C1-C4 alkyl groups. 10 Alkoxy groups, which may optionally be substituted with hydroxyl or C1-C4 alkyl groups, Used to adjust, enhance, and / or improve the longevity of at least one fragrance, wherein the at least one secondary fragrance exhibits at least one of the following fragrance notes: Fruity aroma; Woody aroma; Floral fragrance; Aromatic / Herbal; Tangerine; Spicy; and Green fragrance.

[0073] Preferably, the primary flavoring is added to the secondary flavoring in an amount of about 0.1% to about 30% by weight, more preferably about 2% to about 5% by weight – based on the final product.

[0074] Example Examples 1-10 Olfactory evaluation of a binary fragrance mixture containing 3,4-dimethylbenzonitrile and fruity flavorings

[0075] Examples 11-20 Olfactory evaluation of a binary fragrance mixture containing 3,4-dimethylbenzonitrile and woody fragrance.

[0076] Examples 21-32 Olfactory evaluation of binary fragrance mixtures containing 3,4-dimethylbenzonitrile and floral fragrance notes

[0077] Examples 32-41 Olfactory evaluation of binary fragrance mixtures containing 3,4-dimethylbenzonitrile and aromatic / herbal fragrance notes

[0078] Examples 42-51 Olfactory evaluation of a binary fragrance mixture containing 3,4-dimethylbenzonitrile and citrus fragrance notes

[0079] Examples 52-61 Olfactory evaluation of binary fragrance mixtures containing 3,4-dimethylbenzonitrile and spicy flavorings

[0080] Examples 62-71 Olfactory evaluation of a binary fragrance mixture containing 3,4-dimethylbenzonitrile and green fragrance notes

[0081] Examples 72-75 Olfactory evaluation of the three-element flavor mixture

[0082] Example 76 Spicy Flavorings

[0083] Example 77 woody essence

[0084] Example 78 Floral fragrance

[0085] Example 79 Fragrances

[0086] Example 80 Citrus flavoring

[0087] Example 81 Spicy Flavorings

[0088] Example 82 Green Flavoring

[0089] Formulation Examples The following Examples F1 to F55 illustrate various formulations for cosmetic and detergent compositions. Formulation 1 represents any of the fragrance mixtures according to Examples 1 to 75.

[0090] Table F1 Liquid soap; clear (per % bw)

[0091] Table F2 Synthetic soap, liquid (by weight % bw)

[0092] Table F3 A body wash for bathing (dosage percentage: % bw)

[0093] Table F4 A bath lotion containing triclosan (dosage percentage: % bw)

[0094] Table F5 Sensitive area cleaning solution (dosage percentage: % bw)

[0095] Table F6 Liquid soap (by weight % bw)

[0096] Table F7 Shampoo (dosage is % bw)

[0097] Table F8 2-in-1 Shampoo (dosage is % bw)

[0098] Table F9 Anti-dandruff shampoo (dosage: % bw)

[0099] Table F10 Conditioner containing Crinipan, rinse out (using % bw).

[0100] Table F11 A leave-in conditioner containing zinc pyrithione (applied at % bw).

[0101] Table F12 Conditioner containing UV protection factors (at % bw)

[0102] Table 13 Shower gel (per % bw)

[0103] Table F14 Shaving cream (by % bw)

[0104] Table F15 Hair removal cream (dosage percentage: % bw)

[0105] Table F16 Aftershave (dosage at % bw)

[0106] Table F17 Deodorant in roll-on gel form (dosage % bw)

[0107] Table F18 Transparent deodorizing and antiperspirant roll-on (dosage percentage: % bw)

[0108] Table F19 Deodorizing stick (dosage percentage: % bw)

[0109] Table F20 Zirconium suspension colloidal antiperspirant stick (dosage: % bw)

[0110] Table F21 Deodorizing spray containing SymClariol (dosage percentage: % bw)

[0111] Table F22 Antiperspirant (dosage at % bw)

[0112] Table F23 Deodorizing spray containing triclosan (dosage percentage: % bw)

[0113] Table F24 O / W emulsion (in % bw)

[0114] Table F25 Body lotion (per % bw)

[0115] Table F26 Ointment (dosage in % bw)

[0116] Table F27 Ointment (dosage in % bw)

[0117] Table F28 Hand cream and body cream (using % bw)

[0118] Table F29 Face cream (using % bw)

[0119] Table F30 Moisturizing body cream (dosage is % bw)

[0120] Table F31 Anti-wrinkle cream (dosage is % bw)

[0121] Table F32 Functional skin disinfectant oil (dosage percentage: % bw)

[0122] Table F33 Ointment for infected wounds (dosage: % bw)

[0123] Table F34 Moisturizing and disinfecting face mask (dosage is % bw)

[0124] Table F35 Disinfectant gel can be sprayed (dosage is % bw).

[0125] Table F36 Mineral cleaning and rinsing gel (by % bw)

[0126] Table F37 Anti-acne lotion (dosage: % bw)

[0127] Table F38 Cosmetic sunscreen composition (in % bw)

[0128] Table F39 Sunscreen spray (dosage percentage: % bw)

[0129] Table F40 Sunscreen spray, O / W, SPE 15-20 (dosage is % bw)

[0130] Table F41 Sunscreen ointment (w / o), SPF 40 (dosage is % bw)

[0131] Table F42 Sunscreen lotion (W / O) (Amount used is % bw)

[0132] Table F43 After-sun gel (dosage: % bw)

[0133] Table F44 After-sun lotion (using % bw)

[0134] Table F45 Hair styling gel (use at % bw)

[0135] Table F46 Silicone oil emulsion (volume as % bw)

[0136] Table F47 Microemulsion gel (dosage % bw)

[0137] Table F48 Gel-based air freshener (dosage percentage: % bw)

[0138] Table F49 Cleaning agent. APC liquid. Alkaline pH 8-10 (dosage is % bw)

[0139] Table F50 Fabric softener (at a rate of % bw)

[0140] Table F51 Liquid detergent (volume as % bw)

[0141] Table F52 Liquid detergent concentrate (volume as % bw)

[0142] Table F53 Toilet cleaner (dosage percentage: % bw)

[0143] Table F54 Dishwashing detergent concentrate (dosage in % bw)

[0144] Table F55 Dishwashing detergent concentrate (dosage in % bw)

[0145] Table F56 Wet wipe solution (volume as % bw)

Claims

1. A spice mixture comprising or consisting of the following ingredients: (a) at least one main spice conforming to general formula (I) Where R 1 R 2 R 3 R 4 and R 5 Independently representing hydrogen; or representing straight-chain or branched C1-C. 10 Alkyl group, which may optionally be substituted with hydroxyl or C1-C4 alkyl; or representing straight-chain or branched C1-C4 alkyl groups. 10 Alkoxy groups, which may optionally be substituted with hydroxyl or C1-C4 alkyl groups, (b) at least one secondary flavoring different from component (a), and optionally (c) At least one solvent, Wherein, the at least one secondary flavoring belongs to the flavoring group exhibiting at least one of the following aroma notes: Fruity notes; Woody notes; Floral fragrance; Aromatic / Herbal notes; Citrus notes; Spicy notes; and Green fragrance.

2. The spice mixture according to claim 1, wherein component (a) conforms to formula (II). Where R 2 R 3 Independently representing hydrogen, straight-chain or branched C1-C 10 Alkyl groups, which may optionally be substituted with hydroxyl groups or C1-C4 alkyl groups; or straight-chain or branched C1-C4 alkyl groups. 10 Alkoxy groups, which may optionally be substituted with hydroxyl or C1-C4 alkyl groups.

3. The spice mixture according to claim 1 or 2, wherein the primary spice (a) is selected from the group comprising: 3,4-Dimethylbenzonitrile; 4-(2-methylpropyl)benzonitrile; 3-Methylbenzonitrile; 2-Methoxybenzonitrile; 3,4-Dimethoxybenzonitrile; 4-Methoxybenzonitrile and mixtures thereof.

4. The fragrance mixture according to any one of claims 1 to 3, wherein the primary fragrance is 3,4-dimethylbenzonitrile.

5. The fragrance mixture according to any one of claims 1 to 4, wherein the secondary fragrance (b) having a fruity aroma is selected from the group consisting of butyl 2-methylisovalerate, acetobutyryl, so-called "C14 aldehyde", and so-called "C16 aldehyde". The so-called "C18 aldehyde", allyl heptaate, pentyl acetate, pentyl butyrate, pentyl hexanoate, pentyl formate, anisyl acetone, cis-2-tert-butylcyclohexyl acetate, 2-tert-butylcyclohexyl acetate, benzyl butyrate, benzoyl isobutyrate, benzyl isovalerate, butyl acetate, butyl butyrate, butyl n-octanoate, n-butyl formate, butyl isobutyrate, butyl isovalerate, butyl propionate, butyl salicylate, n-butyric acid, norber-5-enyl acetate, n-hexanoic acid, cyclohexyl acetate, cyclohexyl butyrate, 1-cyclohexanol (2E)-but-2-enoic acid, artemisia oil, δ-decanolide, γ-decanolide, diethyl malonate , ...6] Ethyl decane-2-carboxylate, (E)-but-2-enoic acid-4-methylpentane-2-ester, furfuryl acetate, propyl-heptyl lactone, heptanoic acid, heptyl acetate, propyl-caprolactone, hexyl acetate, hexyl butyrate, hexyl hexanoate, hexyl octanoate, hexyl formate, hexyl isobutyrate, n-hexyl isovalerate, hexyl 2-methylbutyrate, hexyl propionate, isoamyl acetate, isoamyl butyrate, isoamyl n-octanoate, isobutyl butyrate, isobutyl isovalerate, isobutyric acid, 1,3-dimethyl-3-butenyl 2-methylpropionate, isopentenyl acetate, isopropyl acetate, isovaleric acid, isovaleraldehyde, (2-methyl-1,3-dioxane- Ethyl 2-methyl(2-ethyl)ethyl acetate, 4,4a,5,9b-tetrahydro-2,4-dimethyl-indeno[1,2-d]-1,3-dioxane, maltol isobutyrate, ethyl 2-methylvalerate, ethyl 3,5,5-trimethyl-hexanoate, methyl acetate, 2-methylbutyl acetate, 2-methylbutanal, methyl butyrate, methyl hexanoate, methyl octanoate, methyl butyrate, methyl thiol butyrate, 2-methylbutyric acid, 2,2-methylpentenoic acid, butyl nonanolide, norberyl-5-enyl acetate, butyl octanolide, propyl octanolide, 2-(ethoxymethyl)-1-methyl-3-(1-methylvinyl)- Cyclopentene, (E)-2-methylbut-2-enic acid diethyl ester, 2-methylpentanoic acid-2-methylpentyl ester, n-propyl acetate, n-propyl propionate, (2E)-but-2-enoic acid-1,1'-bicyclopentyl-2-yl ester, (E)-4-methyldec-3-en-5-ol, butyl undecyl lactone, n-valeric acid, propiovalerol.

6. The fragrance mixture according to any one of claims 1 to 5, wherein the secondary fragrance (b) having a woody aroma is selected from the group comprising 2-methyl-5-(5,5,6-trimethyl-bicyclo[2.2.1]-hept-2-yl)cyclohexanone, 1-(2-tert-butylcyclohexyl)oxybut-2-ol, 2H-indeno[4,5-b]furan, decahydro-2,2,6,6,7,8,8-heptamethyl, dodecylhydro-3,3-8,11a-tetramethyl-5H-3,5a-epoxynaphtho(2,1-c)oxazophene, 3a,6,6,9a-tetramethyldodecylnaphtho[2,1-b]furan, (ethoxymethoxy)-cyclododecane, (E)- Ambrinol-13,18(28)-dien-8-ol, (4aR,5R,7aS,9R)-octahydro-2,2,5,8,8,9ahexamethyl-4H-4a,9-methylenechalcogenide[5,6-d]-1,3-dioxolane, (3aS,4aR,5R,7aS,9R,9aR)-octahydro-2,5,8,8,9a-pentamethyl-2-propyl-4H-4a,9-methyleneazono[5,6-d]-1,3-dioxolane, dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan, (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b] Furan, sage oil, 8α,9α-epoxy-cypressane, (+) 2,6,9-trimethyl-2,5,9-cyclododecanetrien-1-ol, 2-methyl-3-({1,7,7-trimethylbicyclo[2.2.1]hept-2-yl}oxy)prop-1-ol, agarwood boya oil, β-2,2,3-tetramethylcyclopent-3-en-1-butanol, α-decahydro-2,2,4,8-tetramethyl-4,8-methyl-bridged chamomile-9-yl ester, (1R,3E,5S,9S)-4,11,11-trimethyl-8-methylene-bicyclo[7.2.]0] Undec-3-en-5-ol, 1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-4H-indene-4-one, cedarwood oil, [3R-(3α,3aβ,6α,7β,8aα)]-octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methyleneazine+(3R,3aS,6R,7R,8aS)- Octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methylene chamomile ring, cedrene, cedrol, Cedrol, epoxycedorane, cedrene acetate, 3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran, cinnamon, cyclododecyl carboxylate, cyperus oil, dynamone, (Z)-3-methyl-5-(2,2,3-trimethyl-1-cyclo (E)-2-methyl-1-(6-methyl-6-bicyclo[2.2.1]hept-2-enyl)pent-1-en-3-ol mixture, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-pentanone, guaiac oil, guaiacol, guaiac acetate, rockrose resin, 2-cyclododecylprop-1-ol, 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphth-2-yl) Ethanol, cyclohexanebornyl ester, 1,7,7-trimethyl-bicyclo[2.2.1]hept-2-ylpropionate, 2H-2,4a-methylnaphthalene, [1-methyl-2-[(1,2,2-trimethylbicyclo[3.1.0]hex-3-yl)methyl]cyclopropyl]methanol (a mixture of diastereomers), 5-butyl-2-yl-2-(2,4-dimethyl-1-cyclohex-3-enyl)-5-methyl-1,3 -Dioxane, 4-(1-ethoxyvinyl)-3,3,5,5-tetramethyl-cyclohexane-1-one, methyl diisopentylmethanol, 1R,2S,7S,9S)-3,3,7-trimethyl-8-methylenetricyclo-[5.4.0.02,9]undecane, α-ethyl-2,2,6-trimethylcyclohexanepropanol, 1-methoxy-1-methylcyclododecane, 3,3-dimethyl-5-(2,2,3- Trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol, α-propyl-2,2,6-trimethyl-cyclohexanepropanol, 2,4-dimethyl-2-(1,1,4,4-tetramethyltetrahydronaphth-6-yl)-1,3-dioxolane, labdanum ethyl ketone, 3,7-dimethyl-7-methoxy-2-octanol, 1,3,6,7-tetramethylbicyclo[4.4].[0] Dec-7-en-2-ol carboxylate, 1,1-dimethoxy-cyclododecane, methoxy-cyclododecane, patchouli oil, 1-[4-(1,1-dimethylethyl)phenyl]-ethyl ketone, 1,1,5,5-tetramethylhexahydro-2H-2,4a-methylenebridgednaphthalene-8(5H)-one, 3,3-dimethyl-5-(2,2,3- Trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol, 3,7'-dimethyl-3,4,4a,5,8,8a-hexahydrospiro-(1,4-methylenenaphthalene-2(1H),2'-ethylene oxide), 2-(1,1-dimethylethyl)-4-methylcyclohexanol, 2-methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, 3-methyl-5-(2,2,3-trimethylcyclopenten-3-en-1-yl)penten-2-ol, sandalwood essential oil, (2E)-2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)buten-1-ol, 2-ethyl-4-(2,2,3-trimethylcyclopenten-3-en-1-yl)buten-2-buten-1-ol, sage Lactone, 1,3,4,5,6,7-hexahydro-7-methoxy-1,1,5,5-tetramethyl-2H-2,4a-methylnaphthalene, 1,1,5,5-tetramethyl-octahydro-2,4a-methylnaphthalene-8a-ol, 1-(2,2,6-trimethylcyclohexyl)hex-3-ol, trimofix, methyl cypressone, 1,3-dimethyl-3-phenylbutyl acetate, 4-methyl-4-phenylpentan-2-one, 4-cyclohexyl-4-methylpentan-2-one, vetiver oil, 4,8-dimethyl-2-prop-2-ylidene-3,3a,4,5,6,8a-hexahydro-1H-azulene-6-ol, (4,8-dimethyl-2-prop-2-ylidene-3,3a,4,5,6,8a-hexahydro-1H-azulene-6-yl) Acetate, 1',1',5',5'-tetramethylhexahydro-spiro[1,3-dioxolane-2,8'(5'H)-2H-2,4a-methylbridged naphthalene].

7. The fragrance mixture according to any one of claims 1 to 6, wherein the secondary fragrance (b) having a floral aroma is selected from the group comprising 4-(3-methylbutyl)cyclohexane-1-ol, allyl-α-ionone, α-pentylcinnamaldehyde, phenethyl isopentyl ether, benzophenone, benzyl acetate, benzyl acetone, benzyl propionate, benzyl salicylate, 2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo[3.3.1]nonane, 2-methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal, 3-[4-(1,1-dimethylethyl)phenyl]propanal), Brazilian sandalwood essential oil, methylbenzodioxanone, nanmu oil, 3-(4-methoxyphenyl)-2-methylpropanal, (3-methoxy-2-methylpropyl)- Benzene, 2-methyl-4-(2,6,6-trimethyl-2(1)-cyclohexen-1-yl)butanal, α-isomethylionone, citronellol, citronellol acetate, citronellol butyrate, citronellol formate, citronellol isobutyrate, citronellol isovalerate, citronellol propionate, citronellol tert-methyl, o-methoxybenzyl ethyl ether, 3-(p-isopropylphenyl)-2-methylpropanal, 3-(4-isopropylphenyl)propanal, 1-(3,3-dimethylcyclohexane) Hexyl)ethanol acetate, cyclohexyl salicylate, 2-methyl-3-(4-tert-butylphenyl)propanol, 1,2,3,4,5,6,7,8-octahydro-5,5-dimethyl-2-naphthaldehyde, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, (E)-1-(2,6,6-trimethyl-1-cyclohexyl-1,3-dienyl)but-2-en-1-one, (2E)- 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2-buten-1-one, (E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)buten-2-en-1-one, (E)-1-(2,6,6-trimethyl-1-cyclohexenyl)buten-2-en-1-one, 1-(2,6,6-trimethyl-1-cyclohex-3-enyl)buten-2-en-1-one, trans, trans-2,4-decadienal, 2-pentyl-cyclopropen-1-ol, 2-pentylcyclopentanone, 4-(2,6,6-trimethyl-1-cyclohexenyl)-2-butanone, 3-methyl-2-pentyl-2-cyclopenten-1-one, tetrahydro-4-methyl-2-(2-methylpropyl)- 2H-pyran, methyl anthranilate, dimethyl disulfide, diphenyl ether, (E)-4-ethyloctyl-3-enenitrile, dimethyl sulfide, tetrahydro-4-methyl-2-phenyl-2H-pyran, 4-(octahydro-4,7-methane-5H-inden-5-ylidene)butanal, ethyl linalool acetal, ethyl 2-aminobenzoate, ethyl benzoate, ethyl linalool, cyclohexyl-1,3-diene-1-carboxylic acid, 2,6,6-Trimethyl-ethyl ester, ethyl salicylate, farnesol, farnesyl acetate, 3-(3-isopropylphenyl)butanal, 4-methyl-2-(2-methylphenyl)tetrahydropyran-4-ol, 2,6-dimethyl-2-heptanol, 2-methyldecanoic acid, ethyl 2-acetyloctanoate, (2E)-3,7-dimethyloct-2,6-dien-1-ol, geranium oil, geranium acetate, geranyl acetone, geranium benzoate, geranium butyrate, geranyl ethyl ether, geranium formate, geranium isobutyrate, geranium isovalerate, geranyl methyl ether, geranium propionate, geranium ethyl propionate, 2-[5(6)-methyl-7(8)-(1-methylethyl)bicyclo[2.2.2]oct-5-en-2-yl]-1,3- Dioxolane, Geranium dihydropyran, Methyl 3-oxo-2-pentylcyclopentaneacetate, Methylene dioxinyl-methylpropionaldehyde, Cis-hexen-3-ester of salicylate, Hexyl benzoate, α-hexylcinnamaldehyde, Hexyl salicylate, 2,3-dihydro-1,1-dimethyl-1H-indene-aryl-propionaldehyde, Hydroxycitronellal, Indene, Tetrahydroindenedioxane, Indole, (3E)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one, 4-(2,6,6-trimethylcyclohex-1-en-1-yl) But-3-en-2-one, 4-(2,2,6-trimethyl-2-cyclohexenyl)3-methyl-3-buten-2-one, N-methylionone, non-2-enonitrile, 4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)- 3-Buten-2-one, 4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)-3-buten-2-one (main component), isoamyl acetate, isobutyl salicylate, isocyclogeraniol, 2-hexyl-2-cyclopenten-1-one, 1,5-dehydro-2,4-dideoxy-2-pentyl-3-acetic acid-pentitol, jasmine essential oil, tetrahydro-6-(2-pentenyl)-2H-pyran-2-one, 6-(pent-3-en-1-yl)-tetrahydro-2H-pyran-2-one, 3-methyl-2-[(2Z)-pent-2-en-1-yl] Cyclopent-2-en-1-one, 2-hexyl-2-cyclopenten-1-ol, 3-pentyl-4-tetrahydropyranyl acetate, tetrahydro-3-pentyl-2H-pyran-4-yl acetate, 1,3,4,6,7,8a-hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methylenenaphthalene-8(5H)-one, 5-hexyl-5-methylfuranone, decahydro-2,8,8-trimethylnaphthalene-2,4a-methyllactone, 3-(4-tert-butylphenyl)butanal, (4R)-4-(1-methylethyl)-1-cyclohexene-1-propanal, 2,5-dimethyl-2-indylethanol, linalool, linalool oxide, 4-(4-hydroxy-4-methyl-pentyl)-3-cyclohexene-1-carboxaldehyde, α-methyl-cyclohexylpropanol, β,β-3-Trimethyl-phenylpropanol, (Z+E)-p-menthan-7-ol, 3-methyl-5-benzylpentanal, methyl anthranilate, methyl benzoate, 2-methoxybiphenyl, methyl geraniate, methyl heptynecarboxylate, (E)-3-methyl-4-(2,6,6-trimethyl-1-cyclohexyl-2-enyl)but-3-en-2-one, [(1R,2R)-3-oxo-2-((Z)-pent-2-enyl)cyclopentyl]acetate, 2-naphthyl ethyl ketone, methyl octynecarboxylate, 2-methylvaleric acid, methyl salicylate, mimosa extract, 1-(4-isopropyl-cyclohexyl) Ethanol, 3-methyl-4-phenylbut-2-ol, 2,2-dimethyl-3-phenylprop-1-ol, octahydro-4,7-methylene-indene-5-methanol acetate, narcissus extract, methyl 2-nonenoate, nerol, neroli oil, 3,7,11-trimethyl-1,6,10-dodecanetrien-3-ol, ethyl 2-naphthyl ether, 2-methoxynaphthalene, 1-(3-methyl-1-benzofuran-2-yl) ethyl-1-one, neroli acetate, trans,cis-2,6-nonadienal, trans,trans-2,4-nonadienal, 2,6-nonadienol, 10-hydroxymethylene-2-pinene, neroli absolute, 4-(2-methylbut-2-yl)cyclohexyl-1-one, iris root extract, iris resin, citronella oil, 3-[(2Z)-3-hexenoxy]- Propanonitrile, 1,1-dimethoxynon-2-yne, n-nonanoic acid, amyl salicylate, 2-cyclohexyl-2-phenylacetonitrile, orange leaf oil, 2-methylpropionic acid-2-phenoxyethyl ester, 3-methyl-5-phenyl-1-pentanol, phenyl salicylate, phenethyl acetate, phenethyl alcohol, phenethyl benzoate, phenethyl butyrate, phenethyl isovalerate, methyl phenethyl ether, phenethyl phenylacetate, 2,2-dimethylpropionic acid-2-phenylethyl ester, phenethyl propionate, phenethyl salicylate, phenethyl ethyl acetate, phenylpropyl acetate, isoprene salicylate, 2,6,10-trimethyl-5,9-undecadien-1-ol, 2-hexylcyclopentanone, 2-heptylcyclopentanone, 2,3,6-trimethylcyclohexyl ethyl carbonate, 2,2-Dimethyl-6-methylenecyclohexanecarboxylate, α-(trichloromethyl)benzyl acetate, β-methylphenylpentanol, rose essential, tetrahydro-4-methyl-2-(2-methyl-1-propen-1-yl)-2H-pyran, 4-methyl-2-phenyl-3,6-dihydro-2H-pyran, 4-methyl-6-phenyl-3,6-dihydro-2H-pyran, 4-methylene-2-phenyltetrahydro-2H-pyran, 2-methyl-3-[4-(2-methylpropyl)phenyl]propanal, α-terpineol, tetrahydrolinalool, tetrahydrogeraniol, thiogeraniol, tuberose essential, (E)-4-methyldec-3-en-5-ol, 2,2,5-trimethyl-5-pentylcyclopentanol-1-one, 2-[[3-[4-(1,Methyl benzoate (1-dimethylethyl)phenyl]-2-methylpropylidene]amino]benzoate, 1-methyl-4-(4-methylpentyl)-3-cyclohexenecarboxaldehyde, 4-(4-methylpent-3-enyl)cyclohex-3-en-1-carboxaldehyde, violet leaf extract, methyl-4-cyclooctene-1-yl carbonate, 2,6-nonadienonitrile, ylang-ylang oil.

8. The fragrance mixture according to any one of claims 1 to 7, wherein the secondary fragrance (b) having an aromatic / herbal note is selected from the group comprising α-3,3-trimethylcyclohexyl methyl formate, artemisia oil, bornyl acetate, camphene, camphor D,L, wormwood oil, carvacrol, L-carvacrol, carvacrol-menthol, dextrorotatory carvacrol, levulin, cedarwood leaf oil, 1,3,3-trimethyl-2-oxabicyclo[2.2.2] Octane, Clary Sage Oil, 3a,4,5,6,7,7a-hexahydro-1H-4,7-methyleneinden-5-yl-2-methylpropionate, p-cymene, Cypress Oil, Dihydrocarvone, Dill Seed Oil, 1-Methoxyhexane, 1,3,3-trimethyl-2-oxabicyclo[2.2.2]octane, Eucalyptus Oil, Fanol, 1,3,3-trimethyl-2-norborneol acetate, firabsolute, fragrance Abies spp., 1-(3,3-dimethylcyclohexyl) ethyl ketone, 3a,4,5,6,7,7a-hexahydro-4,7-methylene indene-6-ol ester, tricyclodecenyl propionate, isoborneol, isoborneol acetate, isoborneol propionate, isobutyl menthone, isomenthone, 4-isopropylcyclohexanol, juniper berry oil, laurel oil, mixed lavender oil, lavender oil, oregano oil, peppermint essential oil, menthol, L-menthone / isomenthone Alcohols, menthyl acetate, (3,3,5-trimethylcyclohexyl) acetate, 6,6-dimethyl-2-norpinen-2-ethanol acetate, oregano oil, 4-tert-butylcyclohexyl acetate, Haitian oil, peppermint oil, pine needle extract, pine oil, 6,6-dimethylbicyclo[3.1.1]hept-2-en-2-propanal, octahydro-7-methyl-1,4-methylenenaphthalene-6(2H)-one, 4-acetoxy-4-methyl- 2-Propyltetrahydro-2H-pyran, spearmint oil, spikenard oil, tea tree oil, terpineol-4-ol, 2,6,6,10-tetramethyl-1-oxaspiro[4.5]dec-9-ene, turmeric oil, [1S-(1a,4a,5a)]4-methyl-1-(1-methylethyl)bicyclo[3.1.0]hexane-3-one, thyme oil, thymol, turpentine oil, 2-tert-butylcyclohexanol, artemisia oil and mixtures thereof.

9. The fragrance mixture according to any one of claims 1 to 8, wherein the secondary fragrance (b) having a citrus aroma is selected from the group comprising 3,7-dimethyl-6-octen-1-onitrile, n-decanal, 6,6-dimethoxy-2,5,5-trimethylhex-2-ene, bergamot oil, ethyl 6-acetoxyhexanoate, citronella essential oil, citral diacetal, citral, methyl 2,4-dimethyl-3-cyclohexene-1-acetate, citronellol oil, citronellol, (E)-3-methyl-5-phenylpentan-2-enenitrile and (Z)-3-methyl-5-phenylpentan-2-enenitrile, α-vinyl-α- 2,4,4,7-Tetramethyl-6-octen-3-one, (+ / -)-2,8-cyclothio-cis-p-menthane, 3-mercapto-β,4-dimethylcyclohexanethiol, cyclohexylethyl acetate, dihydromyrcenol, dihydromyrcenyl acetate, dimethyloctenone, ethyl linalyl acetate, eucalyptus oil, grapefruit oil, 3-methyl-5-phenylpentanilonitrile, lemon oil, lemongrass oil, 3,7-dimethyl-2(3),6-nonadienonitrile, 1-methyl-4-(1-methylvinyl)cyclohexene, lime oil, linalyl acetate, aromatic benzoate Linaloyl butyrate, linaloyl formate, linaloyl isobutyrate, linaloyl propionate, Litsea cubeba oil, (E)-2,12-tetraceneadiene nitrile and (E)-3,12-tetraceneadiene nitrile and (Z)-3,12-tetraceneadiene nitrile, (E)-2-dodecenal, orange oil, 2-methyl-4-propyl-1,3-oxothiacyclohexane, myrcene acetate, 3,5,5-trimethylhexyl acetate, (4R,4aS,6R)-6-isopropenyl-4,4a-dimethyl-4,4a,5,6,7,8-hexahydro-2(3H)- Naphthol, (3Z,6E)-8-ocimenol acetate, sweet orange oil, 2-ethyl-N-methyl-N-(3-methylphenyl)butyramide, 2,6-dimethyl-10-methylene-2,6,11-dodecanetrienal, (2S)-2-(1,1-dimethylpropoxy)propionate, mandarin orange oil, (E / Z)-6,10-dimethylundec-5,9-dien-2-ol acetate, terpineol acetate, tetrahydrolina acetate, tetrahydromyrcenol.

10. The fragrance mixture according to any one of claims 1 to 9, wherein the secondary fragrance (b) having a green note is selected from the group comprising allyl isopentoxyacetate, sec-butyl 3-methylthiohydroxybutyrate, 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde (main component), allyl cyclohexyloxyacetate, dibutyl sulfide, 2-ethyl-3,5(6)-dimethylpyrazine, dimethylpyrazine-2,3, dimethylpyrazine-2,5, dimethylpyrazine-2,6, 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, ethylpyrazine-2, 2,4,6-trimethyl-4-phenyl-1,3-dioxane, gluconol, 1-(5,5-dimethyl-1-cyclohexen-1-yl)penten-4-penten-1-one, N,2-dimethyl-N-phenylbutyramide, 2-[6(5)- Methyl-8(7)-(1-methylethyl)bicyclo[2.2.2]oct-5-en-2-yl]-1,3-dioxane, 3,3,5-trimethylcyclohexylethyl ether, trans-2-hexenal, trans-3-hexenol, cis-3-hexenol, trans-2-hexenol, 3-hexenyl acetate (cis / trans) cis-3-hexenyl acetate, trans-2-hexenyl acetate, cis-3-hexenol benzoate, cis-3-hexenyl butyl ester, cis-3-hexenyl hexanoate, cis-3-hexen-1-acetal, cis-3-hexenol carboxylate, cis-3-hexenyl isobutyrate, cis-3-hexenyl isovalerate, cis-3-hexenol lactate, cis-3,2-methylbutyrate hexenol ester, cis-3-hexenyl propionate, cis-3-hexen-1-yl tetroxide, cis-3-hexenyl tetroxide, (2,2-dimethoxy-1-methylethyl)benzene, 2-isobutyl-3-methoxypyrazine, 2,4,6-trimethyl-3-cyclohexen-1-carboxaldehyde, 2-isopropyl-3-methoxypyrazine, 2-isopropyl-4-methylthiazole, (Z )-Hex-3-en-1-ol methyl carbonate, (3E)-1-(1-methoxypropoxy)-3-hexene, 2,4-dimethyl-3-cyclohexenecarboxaldehyde, 2,4-dimethyl-tetrahydroindenedioxane, 2,6-dimethyl-5-heptenal, octahydro-1H-4,7-methyleneindene-1-carboxaldehyde, methyl-dihydrocyclopentylpyrazine, methyl 2-nonyneate, 2-methylpyrazine, 3,3,5-trimethylcyclohexyl acetate, 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, 3,5,6-trimethyl-3-cyclohexen-1-carboxaldehyde, cis-6-nonenol, 1-octen-3-ol, phenylacetaldehyde, phenylacetaldehyde dimethyl acetal, 8-ocimene-1-yl acetate, 5H,5M Cyclopentapyrazine, tetrahydro-2,4-dimethyl-4-phenyl-furan, 6-ethide-octahydro-5,8-methylene-2H-1-benzopyran, 1-spiro[4].5] Dec-7-en-7-yl-4-penten-1-one, 5-methyl-3-heptanone oxime, 1-phenylethanol acetate, 1-phenylethanol, 1-phenylethyl propionate, β-methylphenylpropanal, 2-propenyl-p-cymene, 4-vinyl-2-(2-methylpropyl)-1,3-dioxane, 2,4,6-trimethyl-4-phenyl-1,3-dioxane, 3-(methylthio)propyl butyrate, 2,4-dimethylcyclohexyl-3-en-1-carboxaldehyde, dimethyl-3-cyclohexyl-1-carboxaldehyde, 2-{[(1E)-(2,4-dimethylcyclohexyl-3-en-1-yl)methylene] Methyl aminobenzoate, sec-butyl 3-methylthiohydroxybutyrate, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, allyl cyclohexyloxyacetate, dibutyl sulfide, 2-ethyl-3,5(6)-dimethylpyrazine and mixtures thereof.

11. The fragrance mixture according to any one of claims 1 to 10, wherein the secondary fragrance (b) having a spicy aroma is selected from the group comprising allspice oil, benzyl cinnamate, benzyl isoeugenol, caryophyllene, cinnamon oil, methyl cinnamyl alcohol, cinnamic acid, cinnamyl alcohol, cinnamaldehyde, cinnamon leaf oil, cinnamon essential oil, cinnamyl acetate, cinnamyl cinnamate, cinnamyl formate, cinnamyl isobutyrate, cinnamyl isovalerate, cinnamonitrile, clove bud oil, clove leaf oil, cumin oil, cuminol, cuminaldehyde, cuminonitrile, Cumin acetate, dihydroeugenol, ethyl cinnamate, eugenol, eugenol methyl ether, eugenol acetate, ginger oil, 2-methoxycinnamonaldehyde, isoamyl cinnamate, isobutyl cinnamate, isoeugenol, isoeugenol acetate, isoeugenol methyl ether, linaloyl cinnamate, nutmeg oil, (5 or 6)-methyl-(7 or 8)-(1-methylethyl)bicyclo[2.2.2]oct-5-ene-2-carbonaldehyde, methoxycinnamonaldehyde, cinnamic acid Methyl ester, methyl cinnamaldehyde, 2-ethoxy-4-(methoxymethyl)phenol, 7-methyl-3-methylene-1,6-octadiene, nutmeg oil, p-menthol-1,8-dien-7-aldehyde, phenethyl cinnamate, phenylpropanol, phenylpropanol, 3-phenylpropanoic acid, allspice oil, 2,3,3-trimethylindanone, 2,6,6-trimethylcyclohexane-1,3-dienylformaldehyde, 1,2-dimethoxybenzene and mixtures thereof.

12. The spice mixture according to any one of claims 1 to 11, comprising one, two, three or more spices selected from component (b).

13. The spice mixture according to any one of claims 1 to 12, wherein the weight ratio of the primary spice to the secondary spice in the mixture is from about 0.1:99.9 to about 30:70 by weight percentage.

14. The spice mixture according to any one of claims 1 to 13, wherein the weight ratio of the primary spice to the secondary spice in the mixture is from about 1:99 to about 5:95 by weight percentage.

15. The fragrance mixture according to any one of claims 1 to 14, wherein the solvent (c) is selected from the group consisting of water, benzyl alcohol, benzyl benzoate, diethyl phthalate, dipropylene glycol, ethanol, isopropyl myristate, triethyl citrate, dipropylene glycol methyl ether, petroleum fractions, triacetin, and mixtures thereof.

16. The fragrance mixture according to any one of claims 1 to 15, wherein the solvent (c) is selected from the group consisting of ethanol, dipropylene glycol, triethyl citrate, and mixtures thereof.

17. The fragrance mixture according to any one of claims 1 to 16, wherein the solvent (c) in the mixture may be up to 25% by weight.

18. A fragrance preparation comprising a fragrance mixture according to any one of claims 1 to 17 and at least 1, 2, 3, 4, 5 or more third-class fragrances different from components (a) and (b).

19. A method for preparing a flavoring preparation, comprising or consisting of the following steps: (i) Providing a spice mixture according to any one of claims 1 to 17, (ii) Provide at least 1, 2, 3, 4, 5 or more types of third-class spices, and (iii) Add about 1 to about 100 parts of component (i) to 900 to 999 parts of component (ii) to obtain 1,000 parts of the formulation.

20. A cosmetic, detergent, or household product obtained by the following steps: (i) Providing a fragrance mixture according to any one of claims 1 to 17 or a flavoring preparation according to claim 18, (ii) To provide a cosmetic, detergent, or household base composition; (iii) Add about 10 to about 100 parts of component (i) to 990 to 999 parts of component (ii) to obtain 1,000 parts of the product.

21. A method for preparing cosmetics, detergents, or household products, comprising or consisting of the following steps: (i) to provide a mixture according to any one of claims 1 to 17 or a flavoring preparation according to claim 18, (ii) To provide a cosmetic, detergent, or household base composition; (iii) Add about 10 to about 100 parts of component (i) to 990 to 999 parts of component (ii) to obtain 1,000 parts of the product.

22. A method for adjusting, enhancing, and / or prolonging the lasting power of a fragrance, comprising or consisting of the following steps: (i) Provide at least one main flavoring conforming to general formula (I) Where R 1 R 2 R 3 R 4 and R 5 Independently representing hydrogen; or representing straight-chain or branched C1-C. 10 Alkyl group, which may optionally be substituted with hydroxyl or C1-C4 alkyl; or representing straight-chain or branched C1-C4 alkyl groups. 10 Alkoxy groups, which may optionally be substituted with hydroxyl or C1-C4 alkyl groups, (ii) Providing at least one secondary flavoring that is different from component (a), said at least one secondary flavoring exhibiting at least one of the following aroma notes: Fruity aroma; Woody aroma; Floral fragrance; Aromatic / Herbal; Tangerine; Spicy; and Green fragrance, (iii) Optionally, at least one solvent is provided. (iv) Mixed components (i), (ii) and optional (iii).

23. The method of claim 22, wherein the primary flavoring is selected from the group comprising... 3,4-Dimethylbenzonitrile; 4-(2-methylpropyl)benzonitrile; 3-Methylbenzonitrile; 2-Methoxybenzonitrile; 3,4-Dimethoxybenzonitrile; 4-Methoxybenzonitrile and mixtures thereof.

24. The method according to claim 22 and / or 23, wherein the primary fragrance is 3,4-dimethylbenzonitrile.

25. The method according to any one of claims 22 to 24, wherein the solvent is selected from the group consisting of water, benzyl alcohol, benzyl benzoate, diethyl phthalate, dipropylene glycol, ethanol, isopropyl myristate, triethyl citrate, dipropylene glycol methyl ether, petroleum fractions, triacetin, and mixtures thereof.

26. The method according to any one of claims 22 to 25, wherein the solvent is selected from the group consisting of ethanol, dipropylene glycol, triethyl citrate, and mixtures thereof.

27. At least one main flavoring conforming to general formula (I) Where R 1 R 2 R 3 R 4 and R 5 Independently representing hydrogen; or representing straight-chain or branched C1-C. 10 Alkyl group, which may optionally be substituted with hydroxyl or C1-C4 alkyl; or representing straight-chain or branched C1-C4 alkyl groups. 10 Alkoxy groups, which may optionally be substituted with hydroxyl or C1-C4 alkyl groups, Used to adjust, enhance, and / or improve the longevity of at least one secondary fragrance component (a), said at least one secondary fragrance component exhibiting at least one of the following fragrance notes: Fruity aroma; Woody aroma; Floral fragrance; Aromatic / Herbal; Tangerine; Spicy; and Green fragrance.

28. The use according to claim 27, wherein the primary flavoring is added to the secondary flavoring in an amount of about 0.1 to about 30% by weight, based on the final mixture.

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