Fire-retardant and heat-insulating formaldehyde-free plywood and preparation method thereof

By combining polyphenol amine-grafted birch plywood with borosilicate hybrid surface modifiers and thermally triggered self-crosslinking adhesives, a multi-layer composite structure is formed, which solves the problems of insufficient flame retardancy and thermal insulation performance of formaldehyde-free plywood, achieves stable interfacial bonding and complex heat transfer paths, and improves the overall performance of the material.

CN122401573APending Publication Date: 2026-07-17CHONGZUO GUANGLIN DIFEN NEW MATERIAL TECH CO LTD +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHONGZUO GUANGLIN DIFEN NEW MATERIAL TECH CO LTD
Filing Date
2026-04-10
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing formaldehyde-free plywood has shortcomings in flame retardancy and thermal insulation performance. Its interface structure is unstable and heat transfer is singular, making the material easy to burn in hot environments and with poor thermal stability.

Method used

A multi-layered composite structure was formed by combining polyphenol amine-grafted birch wood boards with a borosilicate hybrid surface modifier and a heat-triggered self-crosslinking adhesive. This structure includes a polyphenol amine interface layer, a borosilicate hybrid layer, and a polymer network of the heat-triggered self-crosslinking adhesive, which enhances the interfacial bonding stability and the complexity of the heat transfer pathway.

Benefits of technology

It significantly improves the flame retardant and thermal insulation properties of plywood, stabilizes the interfacial bonding, reduces the release of aldehydes, and improves the structural stability and heat transfer characteristics of the material in thermal environments.

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Abstract

本发明公开有一种阻燃保温的无醛胶合板及其制备方法,属于胶合板制备技术领域,用于解决传统胶合板的阻燃性能和保温性能有待进一步提高的技术问题,本发明中,首先对桦木板进行羧醛活化处理并进一步构建多酚胺接枝界面层,在木材表层形成富含酚羟基和胺基的界面过渡结构;随后在其表面引入硼硅多酚修饰结构,构建含硅氧网络的有机‑无机复合界面层;同时制备含磷氮协同阻燃寡聚体的热触发自交联胶合剂,并将其用于桦木板之间的胶合,由此在板材内部形成由木材基体、多酚胺界面层、硼硅多酚修饰层以及热触发自交联胶合剂固化形成的聚合物网络共同构成的多层结构体系,使界面结构稳定性、表层结构连续性以及材料内部结构协同状态得到优化。
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