A method for preparing high-purity trivalent vanadium sulfate crystal based on solvent replacement method and preparing 3.5-valence vanadium electrolyte

The preparation of high-purity trivalent vanadium sulfate crystals by solvent displacement crystallization method solves the preparation problem in the existing technology, realizes the preparation of high-purity and stable vanadium sulfate crystals, reduces production and transportation costs, and allows for on-site preparation of electrolyte.

CN122406240APending Publication Date: 2026-07-17SICHUAN DEV XINGXIN VANADIUM ENERGY TECH CO LTD
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Patent Information

Application Number
CN202610428495.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to efficiently prepare high-purity, stable trivalent vanadium sulfate crystals, resulting in high production costs, inconvenient transportation, and complex processes for vanadium electrolyte production.

Method used

A solvent displacement crystallization method was adopted. After preparing a high-concentration vanadium oxysulfate solution, electrolysis was performed, and a specific organic solvent was added to induce crystal precipitation. Combined with solid-liquid separation, washing and drying, high-purity vanadium sulfate crystals were obtained and mixed with vanadium oxysulfate to prepare a 3,5-valent vanadium electrolyte.

Benefits of technology

This technology enables the preparation of high-purity, high-stability vanadium sulfate crystals, reducing production costs, simplifying the process, and allowing for on-site preparation of electrolytes at energy storage power stations, thus reducing transportation costs.

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Abstract

本发明为一种基于溶剂置换结晶法制备高纯三价硫酸钒晶体及配制3.5价钒电解液的方法。该方法主要包括以下步骤:(1)将钒渣浸出液经过还原、萃取、反萃后制备出硫酸氧钒水溶液;(2)对硫酸氧钒水溶液进行电解还原获得三价硫酸钒溶液;(3)向三价硫酸钒溶液中加入特定溶剂促使晶体析出;(4)过滤得到三价硫酸钒晶体与结晶母液,母液减压蒸馏后可循环利用;(5)干燥后三价硫酸钒晶体与硫酸氧钒晶体混溶制备3.5价钒电解液。本发明采用溶剂置换法进行结晶工艺步骤简单,设备要求常规,溶剂可循环,成功制备出高纯三价硫酸钒晶体的同时,实现了“固态运输,现场配制”,极大降低了电解液的包装运输成本以及电解液生产成本。
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