A lithium ion battery composite separator and a method for preparing the same

By using a core-shell structure of acid-activated silicate nanotubes and cyclic phosphazene derivatives, the problems of low thermal stability and low ion conduction efficiency of lithium-ion battery separators at high temperatures were solved, and the dimensional stability and ion transport performance of the separators at high temperatures were improved, meeting the requirements of high-power lithium-ion batteries.

CN122418218APending Publication Date: 2026-07-17ZHEJIANG UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ZHEJIANG UNIV OF TECH
Filing Date
2026-05-19
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium-ion battery separators lack thermal stability at high temperatures, and traditional ceramic coatings have limited functionality and low ion conduction efficiency, failing to meet the requirements of high-power lithium-ion batteries.

Method used

A core-shell structure combining acid-activated silicate nanotubes and cyclic phosphazene derivatives is employed, which forms a heat-resistant framework and a flame-retardant barrier through covalent bonding. This promotes the interaction of lithium-ion solvation structures, improves ion transport efficiency, and enhances electrolyte affinity.

Benefits of technology

Maintaining membrane size stability at high temperatures reduces the risk of battery thermal runaway, improves ion conductivity and lithium-ion transference number, enhances electrolyte wettability, strengthens mechanical properties, and meets the requirements of high-power lithium-ion batteries.

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Abstract

本发明属于锂离子电池技术领域,尤其涉及一种锂离子电池复合隔膜及其制备方法。所述方法包括:以硅酸盐纳米管为基体制备复合纳米功能填料,将复合纳米功能填料、粘结剂和溶剂按比例混合均匀后得到浆料,将浆料涂覆于基膜表面,随后干燥即得到锂离子电池复合隔膜。本发明通过时序控制的酸活化‑原位聚合工艺,制备环状磷腈包覆硅铝酸盐纳米管核壳结构,所得复合隔膜兼具180 ℃耐热几乎无收缩、高离子电导率及优异电解液亲和性,且与现有产线兼容,适用于高安全锂离子电池。
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