Method of washing dishware

Abstract

A method of washing dishware in an automatic dishwashing machine is provided comprising providing at least one soiled article; selecting an automatic dishwashing composition comprising: 1 to 99 wt%, based on dry weight of the automatic dishwashing composition, of a builder; 0.2 to 15 wt%, based on dry weight of the automatic dishwashing composition, of a nonionic surfactant; and 0.5 to 9 wt%, based on dry weight of the automatic dishwashing composition, of a carboxyalkyl tamarind; and applying the selected automatic dishwashing composition to the at least one soiled article in an automatic dishwashing machine to provide a cleaned article.

Description

METHOD OF WASHING DISHWARE

[0001] The present invention relates to a method of washing dishware. In particular, the present invention relates to a method of washing dishware in an automatic dishwashing machine, comprising: providing at least one soiled article; selecting an automatic dishwashing composition comprising: 1 to 99 wt%, based on dry weight of the automatic dishwashing composition, of a builder; 0.2 to 15 wt%, based on dry weight of the automatic dishwashing composition, of a nonionic surfactant; and 0.5 to 9 wt%, based on dry weight of the automatic dishwashing composition, of a carboxyalkyl tamarind; and applying the selected automatic dishwashing composition to the at least one soiled article in an automatic dishwashing machine to provide a cleaned article.

[0002] Dishwashing compositions are generally recognized as a class of detergent compositions distinct from those used for fabric washing or water treatment. Dishwashing compositions are expected by users to produce a film-free appearance on washed articles after a complete cleaning cycle.

[0003] Phosphate-free dishwashing compositions are increasingly desirable. Phosphate-free dishwashing compositions typically rely on non-phosphate builders, such as salts of citrate, carbonate, silicate, disilicate, bicarbonate, aminocarboxylate, and others to sequester calcium and magnesium from hard water, and upon drying, leave an insoluble visible deposit.

[0004] A family of polycarboxylate copolymers and their use as builders in detergent compositions and rinse aid compositions is disclosed by Christopher et al. in U.S. Patent No. 5,431,846 for use in the final rinse step of a dish or warewashing machine. Christopher et al. disclose block copolymers comprising from 20 to 95 mole % of monomer units derived from itaconic acid or a homologue thereof and from 5 to 80 mole % of monomer units derived from vinyl alcohol or a lower vinyl ester are excellent binders of divalent or polyvalent metals and are useful as potentially biodegradable builders in detergent compositions as well as in machine dishwashing compositions and anti-scaling rinse compositions.

[0005] A family of terpolymers and their use, among other things, as dispersants is disclosed by Swift et al in U.S. Patent No. 5,191,048. Swift et al teach a terpolymer comprising as polymerized units from about 15 to 55 mole percent of at least one first monomer selected from the group consisting of vinyl acetate, vinyl ethers and vinyl carbonates, from about 10 to 70 mole percent of at least one second monomer of an ethylenically unsaturated monocarboxylic acid, and from about 15 to 55 mole percent of at least one third monomer of an anhydride of a dicarboxylic acid and wherein said terpolymer is formed in a non-aqueoussystem such that less than about one more percent of the monomers are hydrolyzed during said polymerization.

[0006] Notwithstanding there remains a need for new dispersant polymers for use in dish washing applications. In particular, there remains a need for new dispersant polymers for use in dish washing applications, wherein the dispersant polymers provide effective low filming performance; are biosourced and biodegradable.

[0007] The present invention provides a method of cleaning an article in an automatic dishwashing machine, comprising: providing at least one soiled article; selecting an automatic dishwashing composition comprising: 1 to 99 wt%, based on dry weight of the automatic dishwashing composition, of a builder; 0.2 to 15 wt%, based on dry weight of the automatic dishwashing composition, of a nonionic surfactant; and 0.5 to 9 wt%, based on dry weight of the automatic dishwashing composition, of a carboxyalkyl tamarind; and applying the selected automatic dishwashing composition to the at least one soiled article in an automatic dishwashing machine to provide a cleaned article.

[0008] The present invention provides a method of washing dishware in an automatic dishwashing machine, comprising: providing at least one soiled article; selecting an automatic dishwashing composition comprising: 30 to 60 wt%, based on dry weight of the automatic dishwashing composition, of the builder; 4 to 8 wt%, based on dry weight of the automatic dishwashing composition, of the nonionic surfactant; 3 to 7 wt%, based on dry weight of the automatic dishwashing composition, of the carboxyalkyl tamarind; 1 to 53.5 wt%, based on dry weight of the automatic dishwashing composition, of the filler; 5 to 20 wt%, based on dry weight of the automatic dishwashing composition, of the bleaching agent;2.5 to 7.5 wt%, based on dry weight of the automatic dishwashing composition, of the bleach activator; and 2 to 4 wt%, based on dry weight of the automatic dishwashing composition, of the enzyme; and applying the selected automatic dishwashing composition to the at least one soiled article in an automatic dishwashing machine to provide a cleaned article.DETAILED DESCRIPTION

[0009] Surprisingly, it has been found that, the glassware can effective be cleaned with automatic dishwashing formulations having carboxyalkyl tamarind, providing good spotting and filming performance on glassware compared to formulations containing conventional dispersant polymers, while having the benefit of improving the overall sustainability of the dishwashing formulation (i.e., being biosourced and exhibiting improved biodegradability relative to conventional dispersant polymers such as polyacrylic acid).

[0010] Unless otherwise indicated, ratios, percentages, parts, and the like are by weight. Weight percentages (or wt%) in the composition are percentages of dry weight, i.e., excluding any water that may be present in the composition. Percentages of monomer units in the polymer are percentages of dry weight, i.e., excluding any water present in a polymer emulsion.

[0011] As used herein, unless otherwise indicated, the phrase "molecular weight" or MW refers to the weight average molecular weight as measured in a conventional manner with gel permeation chromatography (GPC) and conventional standards, such as polystyrene molecular weight standards. GPC techniques are discussed in detail in Modern Size Exclusion Liquid Chromatography - Practice of Gel Permeation and Gel Filtration Chromatography, Second Edition, A.M. Striegel, W. W. Yau, J. J. Kirkland, D. D. Bly; John Wiley & Sons, Inc. 2009. Molecular weights are reported herein in units of Daltons, or equivalently, g / mol.

[0012] Preferably, the method of washing dishware in an automatic dishwashing machine of the present invention, comprises: providing at least one soiled article (e.g., cookware, bakeware, tableware, dishware, flatware and / or glassware)(preferably, wherein the at least one soiled article includes soiled glassware); selecting an automatic dishwashing composition comprising: 1 to 99 wt% (preferably, 10 to 98 wt%; more preferably, 25 to 82.5 wt%; most preferably, 30 to 60 wt%), based on dry weight of the automatic dishwashing composition, of a builder (preferably, wherein the builder includes at least one of a carbonate, a bicarbonate, a citrate and a silicate); 0.2 to 15 wt% (preferably, 1 to 12 wt%; more preferably, 2 to 10 wt%; most preferably, 4 to 8 wt%), based on dry weight of the automatic dishwashing composition, of a nonionic surfactant (preferably, wherein the nonionic surfactant is a fatty alcohol alkoxylate); and 0.5 to 9 wt% (preferably, 0.75 to 8 wt%; more preferably, 1 to 7.5 wt%; most preferably, 3 to 7 wt%), based on dry weight of the automatic dishwashing composition, of a carboxyalkyl tamarind (preferably, wherein the carboxyalkyl is selected from the group consisting of carboxymethyl, carboxyethyl, carboxypropyl, carboxy butyl and mixtures thereof; more preferably, wherein the carboxyalkyl is selected from the group consisting of carboxymethyl, carboxyethyl and mistures thereof; most preferably, the carboxyalkyl is a carboxymethyl) (preferably, wherein the carboxyalkyl tamarind has a carboxyalkyl degree of substitution, DSCA, of 0.01 to 1.5 (preferably, 0.1 to 1; more preferably, 0.15 to 0.75; most preferably, 0.2 to 0.39) as measured according to ASTM D1439-15); and applying the selected automatic dishwashing composition to the at least one soiled article in an automatic dishwashing machine to provide a cleaned article.

[0013] Preferably, the selected automatic dishwashing composition of the present invention, comprises: a builder. Preferably, the builder used in the selected automatic dishwashing composition of the present invention, comprises at least one of a carbonate, a citrate and a silicate. Most preferably, the builder used in the selected automatic dishwashing composition of the present invention, comprises at least one of sodium carbonate, sodium bicarbonate, sodium citrate and citric acid.

[0014] Preferably, the selected automatic dishwashing composition of the present invention, comprises: 1 to 99 wt% (preferably, 10 to 98 wt%; more preferably, 25 to 82.5 wt%; most preferably, 30 to 60 wt%), based on dry weight of the automatic dishwashing composition, of a builder. Preferably, the selected automatic dishwashing composition of the present invention, comprises: > 1 wt% (preferably, > 10 wt%; more preferably, > 25 wt%; most preferably, > 30 wt%), based on dry weight of the automatic dishwashing composition, of the builder. Preferably, the selected automatic dishwashing composition of the present invention, comprises: < 99 wt% (preferably, < 98 wt%; more preferably, < 82.5 wt%; most preferably, < 60 wt%), based on dry weight of the automatic dishwashing composition, of the builder. Weight percentages of carbonates, citrates and silicates are based on the actual weights of the salts, including metal ions.

[0015] The term "carbonate(s)" as used herein and in the appended claims refers to alkali metal or ammonium salts of carbonate, bicarbonate, percarbonate, and / or sesquicarbonate. Preferably, the carbonate used in the automatic dishwashing composition (if any) is selected from the group consisting of carbonate salts of sodium, potassium and lithium (more preferably, salts of sodium or potassium; most preferably, salts of sodium). Percarbonate used in the automatic dishwashing composition (if any) is selected from salts of sodium, potassium, lithium and ammonium (more preferably, salts of sodium or potassium; most preferably, salts of sodium). Most preferably, the carbonate used in the automatic dishwashing composition (if any) includes at least one of sodium carbonate, sodium bicarbonate and sodium percarbonate. Preferably, when the builder used in the automatic dishwashing composition of the present invention includes carbonate, the automatic dishwashing composition preferably, comprises 0 to 97 wt% (preferably, 5 to 75 wt%; more preferably, 10 to 60 wt%; most preferably 20 to 50 wt%), based on dry weight of the automatic dishwashing composition, of carbonate.

[0016] The term "citrate(s)" as used herein and in the appended claims refers to alkali metal citrates and citric acid. Preferably, the citrate used in the automatic dishwashing composition (if any) is selected from the group consisting of citric acid and citrate salts of sodium,potassium and lithium (more preferably, salts of sodium or potassium; most preferably, salts of sodium). More preferably, the citrate used in the automatic dishwashing composition (if any) is sodium citrate and / or citric acid. Preferably, when the builder used in the automatic dishwashing composition of the present invention includes citrate, the automatic dishwashing composition preferably, comprises 0 to 97 wt% (preferably, 5 to 75 wt%; more preferably, 10 to 60 wt%; most preferably 20 to 40 wt%), based on dry weight of the automatic dishwashing composition, of the citrate.

[0017] The term "silicate(s)" as used herein and in the appended claims refers to alkali metal silicates. Preferably, the silicate used in the automatic dishwashing composition (if any) is selected from the group consisting of silicate salts of sodium, potassium and lithium (more preferably, salts of sodium or potassium; most preferably, salts of sodium). More preferably, the silicate used in the automatic dishwashing composition (if any) is sodium disilicate. Preferably, the builder used in the automatic dishwashing composition of the present invention includes a silicate. Preferably, when the builder used in the automatic dishwashing composition of the present invention includes a silicate, the automatic dishwashing composition preferably, comprises 0 to 97 wt% (preferably, 0.1 to 10 wt%; more preferably, 0.5 to 7.5 wt%; most preferably 0.75 to 3 wt%), based on dry weight of the automatic dishwashing composition, of the silicate(s).

[0018] Preferably, the selected automatic dishwashing composition of the present invention, comprises: 0.2 to 15 wt% (preferably, 1 to 12 wt%; more preferably, 2 to 10 wt%; most preferably, 4 to 8 wt%), based on dry weight of the automatic dishwashing composition, of a nonionic surfactant. More preferably, the selected automatic dishwashing composition of the present invention, comprises: 0.2 to 15 wt% (preferably, 1 to 12 wt%; more preferably, 2 to 10 wt%; most preferably, 4 to 8 wt%), based on dry weight of the automatic dishwashing composition, of a nonionic surfactant; wherein the non-ionic surfactant is selected from the group consisting of polyoxyalkylene surfactants, polyalkylene glycol esters, polyoxyethylene derivatives of fatty acid esters of polyhydric alcohols, fatty acid esters of polyalkoxylated polyhydric alcohols, polyalkoxylated natural fats and oils, polyalkylene oxide block copolymers, alkyl polyglucosides, sucrose esters and mixtures thereof. Still more preferably, the selected automatic dishwashing composition of the present invention, comprises: 0.2 to 15 wt% (preferably, 1 to 12 wt%; more preferably, 2 to 10 wt%; most preferably, 4 to 8 wt%), based on dry weight of the automatic dishwashing composition, of a nonionic surfactant; wherein the non-ionic surfactant includes a fatty alcohol alkoxylate. Most preferably, the selected automatic dishwashing composition of the present invention,comprises: 0.2 to 15 wt% (preferably, 1 to 12 wt%; more preferably, 2 to 10 wt%; most preferably, 4 to 8 wt%), based on dry weight of the automatic dishwashing composition, of a nonionic surfactant; wherein the non-ionic surfactant is a fatty alcohol alkoxylate according to formula IIIwherein vr is an average of 5 to 100 (preferably, 6 to 75; more preferably, 7 to 60; most preferably, 8 to 50); wherein R4is selected from the group consisting of a hydrogen and a linear or branched C1-20 alkyl group (preferably, a hydrogen, and a linear or branched C1-20 alkyl group; more preferably, a hydrogen and a linear C1-20 alkyl group); wherein R5is selected from the group consisting of a linear or branched C1-20 alkyl group and a linear or branched C1-4 hydroxyalkyl group (preferably, a linear or branched C1-20 alkyl group; more preferably, a linear C1-20 alkyl group); wherein each R6is independently selected from the group consisting of a hydrogen, a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group, a 2-butyl group and a 2-methyl-2-butyl group (preferably, a hydrogen, a methyl group and an ethyl group); and with the proviso that sum of the total number of carbon atoms in R4and Rsis 5 to 21 (preferably, 6 to 20 carbon atoms; more preferably, 7 to 20 carbon atoms).

[0019] Preferably, the selected automatic dishwashing composition of the present invention, comprises: 0.5 to 9 wt% (preferably, 0.75 to 8 wt%; more preferably, 1 to 7.5 wt%; most preferably, 3 to 7 wt%), based on dry weight of the automatic dishwashing composition, of a carboxyalkyl tamarind (preferably, wherein the carboxyalkyl is selected from the group consisting of carboxymethyl, carboxyethyl, carboxypropyl, carboxy butyl and mixtures thereof; more preferably, wherein the carboxyalkyl is selected from the group consisting of carboxymethyl, carboxyethyl and mistures thereof; most preferably, the carboxyalkyl is a carboxymethyl) (preferably, wherein the carboxyalkyl tamarind has a carboxyalkyl degree of substitution, DSCA, of 0.01 to 1.5 (preferably, 0.1 to 1 ; more preferably, 0.15 to 0.75; most preferably, 0.2 to 0.39) as measured according to ASTM D1439-15). More preferably, the selected automatic dishwashing composition of the present invention, comprises: 0.5 to 9 wt% (preferably, 0.75 to 8 wt%; more preferably, 1 to 7.5 wt%; most preferably, 3 to 7 wt%), based on dry weight of the automatic dishwashing composition, of a carboxyalkyl tamarind (preferably, wherein the carboxyalkyl is selected from the group consisting ofcarboxymethyl, carboxyethyl, carboxypropyl, carboxy butyl and mixtures thereof; more preferably, wherein the carboxyalkyl is selected from the group consisting of carboxymethyl, carboxyethyl and mistures thereof; most preferably, the carboxyalkyl is a carboxymethyl) (preferably, wherein the carboxyalkyl tamarind has a carboxyalkyl degree of substitution, DSCA, of 0.01 to 1.5 (preferably, 0.1 to 1 ; more preferably, 0.15 to 0.75; most preferably, 0.2 to 0.39) as measured according to ASTM D1439-15); wherein the carboxyalkyl tamarind comprises a base tamarind gum substituted with carboxy alkyl groups; wherein 90 to 100 mol% (preferably, 92 to 100 mol%; more preferably, 95 to 100 mol%; still more preferably, 98 to 100 mol%; most preferably, 99 to 100 mol%) of the carboxyalkyl substitutions are on galactose moieties of the base tamarind gum.

[0020] The selected automatic dishwashing composition of the present invention, optionally further comprises: an additive. Preferably, the selected automatic dishwashing composition of the present invention, further comprises: an additive selected from the group consisting of a phosphonate (e.g., hydroxy ethylidene diphosphonic acid (HEDP)); an alkaline source; a bleaching agent (e.g., sodium percarbonate, sodium perborate); a bleach activator (e.g., tetraacetylethylenediamine (TAED)); a bleach catalyst (e.g., manganese(ll) acetate, cobalt(ll) chloride, bis(TACN)magnesium trioxide diacetate); an enzyme (e.g., protease, amylase, lipase, or cellulase); a foam suppressant; a coloring agent; a fragrance; an additional builder; an antibacterial agent; a filler; a deposit control polymer and mixtures thereof. More preferably, the selected automatic dishwashing composition of the present invention, further comprises an additive, wherein the additive is selected from the group consisting of a bleaching agent, a bleach activator, an enzyme, a filler and mixtures thereof. Still more preferably, the selected automatic dishwashing composition of the present invention, further comprises an additive, wherein the additive includes a bleaching agent (e.g., sodium percarbonate, sodium perborate); a bleach activator (e.g., tetraacetylethylenediamine (TAED)) and an enzyme (e.g., protease, amylase, lipase, or cellulase). Most preferably, the selected automatic dishwashing composition of the present invention, further comprises an additive, wherein the additive includes a bleaching agent, wherein the bleaching agent includes sodium percarbonate; a bleach activator, wherein the bleach activator includes tetraacetylethylenediamine (TAED); and an enzyme, wherein the enzyme includes a protease and an amylase.

[0021] Preferably, the selected automatic dishwashing composition of the present invention optionally further comprises 0 to 15 wt% (preferably, 0.1 to 15 wt%; more preferably, 0.5 to 10 wt%; still more preferably, 0.75 to 7.5 wt%; most preferably, 1 to 5 wt%), based on dryweight of the automatic dishwashing composition, of a phosphonate. More preferably, the selected automatic dishwashing composition of the present invention comprises 0 to 15 wt% (preferably, 0.1 to 15 wt%; more preferably, 0.5 to 10 wt%; still more preferably, 0.75 to 7.5 wt%; most preferably, 1 to 5 wt%), based on dry weight of the automatic dishwashing composition, of a phosphonate; wherein the phosphonate has a weight average molecular weight of < 1,000 Daltons. Still more preferably, the selected automatic dishwashing composition of the present invention comprises 0 to 15 wt% (preferably, 0. 1 to 15 wt%; more preferably, 0.5 to 10 wt%; still more preferably, 0.75 to 7.5 wt%; most preferably, 1 to 5 wt%), based on dry weight of the automatic dishwashing composition, of a phosphonate; wherein the phosphonate comprises at least one of 1 -hydroxy ethylidene- 1 , 1 -diphosphonic acid (HEDP) and a salt of 1-hydroxyethylidene- 1,1 -diphosphonic acid. Most preferably, the selected automatic dishwashing composition of the present invention comprises 0 to 15 wt% (preferably, 0.1 to 15 wt%; more preferably, 0.5 to 10 wt%; still more preferably, 0.75 to 7.5 wt%; most preferably, 1 to 5 wt%), based on dry weight of the automatic dishwashing composition, of a phosphonate; wherein the phosphonate is selected from the group consisting of 1-hydroxyethylidene- 1,1 -diphosphonic acid (HEDP) and salts thereof.

[0022] Fillers included in the selected automatic dishwashing composition are preferably inert, water-soluble substances, typically sodium or potassium salts (e.g., sodium sulfate, potassium sulfate, sodium chloride, potassium cloride). In tablets and powders, fillers are typically present in amounts ranging from 0 wt% to 75 wt% (preferably, 1 to 53.5 wt%). Fillers included in gel formulations typically include those mentioned for use in tablets and powders and also water. Fragrances, dyes, foam suppressants, enzymes and antibacterial agents usually total no more than 10 wt%, alternatively no more than 5 wt%, of the automatic dishwashing composition.

[0023] The selected automatic dishwashing composition of the present invention, optionally further comprises: an alkaline source. Suitable alkaline sources include, without limitation, alkali metal carbonates and alkali metal hydroxides, such as sodium or potassium carbonate, bicarbonate, sesquicarbonate, sodium, lithium, or potassium hydroxide, or mixtures of the foregoing. Sodium hydroxide is preferred. The amount of alkaline source in the selected automatic dishwashing composition of the present invention (if any) is at least 1 wt% (preferably, at least 20 wt%) and up to 80 wt% (preferably, up to 60 wt%), based on dry weight of the automatic dishwashing composition.

[0024] The selected automatic dishwashing composition of the present invention, optionally further comprises: a bleaching agent (e.g., sodium percarbonate). The amount of thebleaching agent in the selected automatic dishwashing composition of the present invention (if any) is preferably at a concentration of 1 to 25 wt% (more preferably, 5 to 20 wt%), based on dry weight of the automatic dishwashing composition.

[0025] The selected automatic dishwashing composition of the present invention, optionally further comprises: a bleach activator (e.g., tetraacetylethylenediamine (TAED)). The amount of the bleach activator in the selected automatic dishwashing composition of the present invention (if any) is preferably at a concentration of 1 to 10 wt% (more preferably, 2.5 to 7.5 wt%), based on dry weight of the automatic dishwashing composition.

[0026] Preferably, the selected automatic dishwashing composition of the present invention, optionally further comprises: an enzyme (e.g., protease, amylase, lipase, cellulase). More preferably, the selected automatic dishwashing composition of the present invention, optionally further comprises: 0 to 10 wt% (preferably, 0.5 to 7.5 wt%; more preferably, 1 to 5 wt%; most preferably, 2 to 4 wt%), based on the dry weight of the automatic dishwashing composition, of an enzyme. Most preferably, the selected automatic dishwashing composition of the present invention, further comprises: 0 to 10 wt% (preferably, 0.5 to 7.5 wt%; more preferably, 1 to 5 wt%; most preferably, 2 to 4 wt%), based on the dry weight of the automatic dishwashing composition, of an enzyme, wherein the enzyme comprises a mixutre of protease and amylase.

[0027] Preferably, the selected automatic dishwashing composition of the present invention comprises < 1 wt% (preferably, < 0.5 wt%; more preferably, < 0.2 wt%; still more preferably, < 0.1 wt%; yet still more preferably, < 0.01 wt%; most preferably, < the detectable limit), based on dry weight of the automatic dishwashing composition, of phosphate. Preferably, the selected automatic dishwashing composition of the present invention is phosphate free.

[0028] Preferably, the selected automatic dishwashing composition of the present invention comprises < 1 wt% (preferably, < 0.5 wt%; more preferably, < 0.2 wt%; still more preferably, < 0.1 wt%; yet still more preferably, < 0.01 wt%; most preferably, < the detectable limit), based on dry weight of the automatic dishwashing composition, of builders selected from the group consisting of nitrilotriacetic acid; ethylenediaminetetraacetic acid; diethylenetriaminepentaacetic acid; glycine-N,N-diacetic acid; methyl glycine-N,N-diacetic acid; 2-hydroxyethyliminodiacetic acid; glutamic acid-N,N-diacetic acid;3 -hydroxy-2,2 ’-iminodissuccinate; S,S -ethylenediaminedisuccinate aspartic acid-diacetic acid; N,N’ -ethylene diamine disuccinic acid; iminodisuccinic acid; aspartic acid; aspartic acid-N,N-diacetic acid; beta- alaninediacetic acid; polyaspartic acid; salts thereof and mixtures thereof. Most preferably, the selected automatic dishwashing composition of thepresent invention contains 0 wt% of builders selected from the group consisting of nitrilotriacetic acid; ethylenediaminetetraacetic acid; diethylenetriaminepentaacetic acid; glycine-N,N-diacetic acid; methyl glycine-N,N-diacetic acid; 2-hydroxyethyliminodiacetic acid; glutamic acid-N,N-diacetic acid; 3-hydroxy-2,2’-iminodissuccinate;S,S-ethylenediaminedisuccinate aspartic acid-diacetic acid; N,N’ -ethylene diamine disuccinic acid; iminodisuccinic acid; aspartic acid; aspartic acid-N,N-diacetic acid; beta-alaninediacetic acid; polyaspartic acid; salts thereof and mixtures thereof.

[0029] Preferably, the selected automatic dishwashing composition of the present invention comprises < 1 wt% (preferably, < 0.5 wt%; more preferably, < 0.1 wt%; still more preferably, < 0.01 wt%; yet still more preferably, < 0.001 wt%; most preferably, < the detectable limit), based on dry weight of the automatic dishwashing composition, of alkali metal formate. Preferably, the selected automatic dishwashing composition of the present invention is formate free.

[0030] Preferably, the selected automatic dishwashing composition of the present invention has a pH (at 1 wt% in water) of at least 9 (preferably, > 10; more preferably, > 11.5). Preferably, the selected automatic dishwashing composition of the present invention has a pH (at 1 wt% in water) of no greater than 13.

[0031] Preferably, the selected automatic dishwashing composition of the present invention can be formulated in any typical form, e.g., as a tablet, powder, block, monodose, sachet, paste, liquid or gel. More preferably, the selected automatic dishwashing composition of the present invention is formulated as a tablet, powder, granules or block. Most preferably, the selected automatic dishwashing composition of the present invention is formulated as a powder or granules (preferably, as granules).

[0032] Preferably, the selected automatic dishwashing composition of the present invention is an anhydrous formulation. More preferably, the selected automatic dishwashing composition of the present invention is an anhydrous formulation containing < 10 wt% (preferably, < 5 wt%; more preferably, < 2 wt%; most preferably, < 1 wt%), based on weight of the automatic dishwashing composition, of water.

[0033] Preferably, the selected automatic dishwashing composition of the present invention comprises < 1 wt% (preferably, < 0.5 wt%; more preferably, < 0.2 wt%; still more preferably, < 0.1 wt%; yet still more preferably, < 0.01 wt%; most preferably, < the detectable limit), based on dry weight of the automatic dishwashing composition, of phosphate (measured as elemental phosphorus). Preferably, the selected automatic dishwashing composition of the present invention is phosphate free.

[0034] Preferably, the method of washing dishware in an automatic dishwashing machine of the present invention is performed under typical operating conditions for which consumer automatic dishwashing machines are designed for use. For example, automatic dishwashing machines are typically operated with water temperatures during the washing process of 20 °C to 85 °C (preferably 30 °C to 70 °C). Typical concentrations of the selected automatic dishwashing composition used in the method of washing dishware in an automatic dishwashing machine of the present invention as a percentage of total liquid in the dishwasher are 0.02 to 1 wt% (preferably from 0.03 to 0.7 wt%).

[0035] Some embodiments of the present invention will now be described in detail in the following Examples.Comparative Examples C1-C2 and Example 1; Automatic dishwashing compositions

[0036] Dishwashing compositions were prepared in each of Comparative Examples C1-C2 and Example 1 having the component formulations identified in TABLE 1.TABLE 1Procedure for preparing food soil

[0037] The STIWA food soil described in TABLE 2 was prepared by the following procedure. a) Bringing the water to a boil. b) Mixing in a paper cup the instant gravy, the benzoic acid and the starch; and then adding the mixture to the boiling water. c) Adding the milk and margarine to the product of (b). d) Letting the product of (c) cool down to approximately 40 °C, and then adding mixture to a kitchen mixer (Polytron). e) Combining in another paper cup, the egg yolk, the ketchup and the mustard and mixing with a spoon. f) Adding the product of (e) to the mixture of (d) in the blender with continuous stirring. g) Letting the product of (f) stir in the blender for 5 minutes. h) The freezing the product food soil mixture from (g). i) 50 g of the frozen slush is placed into the dishwasher at beginning of the main wash.T BLE 2Dishwashing Test Conditions

[0038] Machine: Miele SS-ADW, Model G1223SC Labor. Wash at 65 °C - 30 min wash cycle, followed by two rinse cycles with a rinse water temperature of 65 °C and a final 30 minute drying step. After the drying cycle was complete, the dishwasher door was opened for 30 minutes to allow the steam to evaporate. Water: initial water supplied to the dishwasher had a target conductivity of 1,260 to 1,360 ps / cm. Food soil: 50 g of the composition noted in TABLE 2 was introduced to the wash liquor frozen in a cup. Each dishwashing composition from Comparative Examples C1-C2 and Example 1 were tested. The food soil was added at the beginning of the wash cycle. The test detergents were also charged to the dishwasher at the beginning of the wash cycle. The test detergents were eachdosed at 15.29 g per wash (based on solids). The number of wash cycles used in this experiment to generate filming and spotting was 15.Filming and Spotting Evaluation

[0039] After each of 15 wash cycles under the above dishwashing test conditions, the glass tumblers, wine glasses and stainless steel butter dishes were dried in open air. After drying, filming and spotting ratings were determined by trained evaluators by observations of glass tumblers and wine glasses in a light box with controlled illumination from below. Glass tumblers, wine glasses and stainless steel butter dishes were rated for filming and spotting according to ASTM method ranging from 1 (no film / spots) to 5 (heavily filmed / spotted). An average value of 1 to 5 for filming and spotting was determined as reported in TABLE 3. Also reported in T BLE 3 are the values for overall spot, overall film and overall shine (i.e., overall spot + overall film) for each dishwashing composition. Observations of the stainless steel butter dishes with controlled illumination from above are reported in TABLE 4.TABLE 3TABLE 4

Claims

We claim:

1. A method of washing dishware in an automatic dishwashing machine, comprising: providing at least one soiled article; selecting an automatic dishwashing composition comprising:1 to 99 wt%, based on dry weight of the automatic dishwashing composition, of a builder;0.2 to 15 wt%, based on dry weight of the automatic dishwashing composition, of a nonionic surfactant; and0.5 to 9 wt%, based on dry weight of the automatic dishwashing composition, of a carboxyalkyl tamarind; and applying the selected automatic dishwashing composition to the at least one soiled article in an automatic dishwashing machine to provide a cleaned article.

2. The method of claim 1 , wherein the automatic dishwashing composition is a solid.

3. The method of claim 2, wherein the automatic dishwashing composition comprises < 10 wt%, based on weight of the automatic dishwashing composition, of water.

4. The method of claim 3, wherein the builder is selected from the group consisting of carbonate, bicarbonate, citrate, silicate and mixtures thereof.

5. The method of claim 4, wherein the automatic dishwashing composition comprises less than 0.1 wt%, based on dry weight of the automatic dishwashing composition, of phosphate, measured as elemental phosphorus.

6. The method of claim 5, wherein the automatic dishwashing composition comprises 0 wt%, based on the dry weight of the dishwashing detergent formulation, of builders selected from the group consisting of nitrilotriacetic acid; ethylenediaminetetraacetic acid; diethylenetriaminepentaacetic acid; glycine-N,N-diacetic acid; methyl glycine-N,N-diacetic acid; 2-hydroxyethyliminodiacetic acid; glutamic acid-N,N-diacetic acid; 3-hydroxy-2,2’-iminodissuccinate; S,S-ethylenediaminedisuccinate aspartic acid-diacetic acid; N,N’ -ethylene diamine disuccinic acid; iminodisuccinic acid; aspartic acid; aspartic acid-N,N-diacetic acid; beta-alaninediacetic acid; polyaspartic acid; salts thereof and mixtures thereof.

7. The method of claim 6, further comprising an additive.

8. The method of claim 7, wherein the additive is selected from the group consisting of a bleaching agent, a bleach activator, an enzyme, a filler, and mixtures thereof.

9. The method of claim 8, wherein the additive includes a mixture of a filler, a bleaching agent; a bleach activator and an enzyme.

10. The method of claim 9, wherein the automatic dishwashing composition comprises:30 to 60 wt%, based on dry weight of the automatic dishwashing composition, of the builder;4 to 8 wt%, based on dry weight of the automatic dishwashing composition, of the nonionic surfactant;3 to 7 wt%, based on dry weight of the automatic dishwashing composition, of the carboxyalkyl tamarind;1 to 53.5 wt%, based on dry weight of the automatic dishwashing composition, of the filler;5 to 20 wt%, based on dry weight of the automatic dishwashing composition, of the bleaching agent;2.5 to 7.5 wt%, based on dry weight of the automatic dishwashing composition, of the bleach activator; and2 to 4 wt%, based on dry weight of the automatic dishwashing composition, of the enzyme.

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