Macroscopically homogeneous cosmetic composition with an aqueous phase and an oily phase, a volatile hydrocarbon oil and a silicone elastomer with carboxylic acid functions

Abstract

Macroscopically homogeneous cosmetic composition with an aqueous phase and an oily phase, a volatile hydrocarbon oil and a silicone elastomer with carboxylic acid functions. The present invention relates to a skincare and / or makeup composition for keratinous materials, in particular skin, comprising, preferably in a physiologically acceptable medium: a) an oily phase comprising at least one volatile hydrocarbon oil H1; and b) an aqueous phase; etc.) at least one silicone elastomer with carboxylic acid functions; said composition having a product of weight ratios [A] X [B] ranging from 0.07 to 0.21 with [A] denoting the weight ratio of the quantity of silicone elastomer relative to the total weight of the composition to the total quantity of volatile hydrocarbon oil(s) relative to the total weight of the composition; [B] denoting the weight ratio of the quantity of aqueous phase relative to the total weight of the composition;the said oily and aqueous phases forming a macroscopically homogeneous mixture.

Description

Description Title of the invention: Macroscopically homogeneous cosmetic composition with an aqueous phase and an oily phase, a volatile hydrocarbon oil and a silicone elastomer with functions carboxylic acids Technical field

[0001] — The present invention aims to propose for the field of care and / or makeup keratin materials, especially skin, a new macroscopic composition homogeneous stitching comprising a) an oily phase comprising at least one volatile hydrocarbon oil, b) an aqueous phase and c) at least one elastomer of silicone with carboxylic acid functions.

[0002] = Cosmetic makeup compositions are commonly used for bring an aesthetic color to keratin materials such as skin, but also to beautify uneven skin by hiding spots and dys- chromies, to reduce the visibility of relief imperfections such as pores and wrinkles as well as pimples and acne marks.

[0003] — They are also looking for care and / or makeup products made from materials keratinous, especially skin which has a comfortable texture at the level sensory and application in particular which are easily sampled and spread easily on the area of ​​keratin material to be covered.

[0004] — Compositions comprising an oily phase and an aqueous phase forming a macroscopically homogeneous mixture (the distinction of the two immiscible phases between them not being observable to the naked eye) such as oil / water emulsions, water-in-oil emulsions or bi-gels are highly sought-after galenic forms by consumers for their creamy or gelled texture, their ease application on the skin and their sensoriality in cosmetics such as freshness, in the field of care, particularly in sunscreen compositions, in compositions anti-aging and in makeup such as foundations.

[0005] — It has already been proposed, in published documents WO2015066161 (US20160200876), WO2015066165, WO2015066199, WO2015167963, WO20180165434 (US10918587B2), IPCOM000250448D, IPCOM000250657D, compositions of makeup based on silicone elastomers with carboxylic acid functions exhibiting good performance in terms of hold and durability. However, these polymers generally have a texture that is difficult to pick up and apply and have tendency to give makeup compositions whose consistency does not allow to easily pick up and spread the product on the skin. When used in compositions based on an oily phase and an aqueous phase forming a macroscopically homogeneous mixture like emulsions, these silicone elastomers tend to produce formulations which are unstable over time for which a separation of the phases (phase shift) is observed. The objective of this invention is to produce a macroscopically homogeneous care and / or makeup composition comprising an oily phase and an aqueous phase and comprising at least one silicone elastomer with carboxylic acid functions which is stable, has a sufficient, flexible and homogeneous consistency to be taken up and easily spread on the skin and good sensory properties such as freshness and lightness during application. Furthermore, the applicant noted that the composition according to the invention also makes it possible to obtain a water release effect when applied to the skin with the formation of droplets when spreading, also with good stability over time. During its research, the applicant unexpectedly discovered that this objective could be achieved with a composition for the care and / or makeup of keratin materials, in particular the skin, comprising, preferably in a physiologically acceptable medium: a) an oily phase comprising at least one volatile hydrocarbon oil H,; and (b) an aqueous phase; and c) at least one silicone elastomer with carboxylic acid functions; said composition having a product of weight ratios [A] X |B] ranging from 0.07 to 0.21 with [A] denoting the weight ratio of the quantity of silicone elastomer relative to the total weight of the composition to the total quantity of volatile hydrocarbon oil(s) relative to the total weight of the composition; [B] denoting the weight ratio of the quantity of aqueous phase relative to the total weight of the composition; said oily and aqueous phases forming a macroscopically homogeneous mixture. The compositions according to the invention are stable over time and have a sufficient, flexible and homogeneous consistency to be taken and easily spread on the skin. They also have a sensation of freshness and lightness during application. This discovery is the basis of the invention. The present invention relates to a composition for caring for and / or making up keratin materials, in particular the skin, comprising, preferably in a physiologically acceptable medium: a) an oily phase comprising at least one volatile hydrocarbon oil H,; and b) an aqueous phase; and c) at least one silicone elastomer with carboxylic acid functions; said composition having a product of weight ratios [A] X [B] ranging from 0.07 to 0.21 with [A] denoting the weight ratio of the quantity of silicone elastomer relative to the total weight of the composition to the total quantity of volatile hydrocarbon oil(s) relative to the total weight of the composition; [B] denoting the weight ratio of the quantity of aqueous phase relative to the total weight of the composition; said oily and aqueous phases forming a macroscopically homogeneous mixture. The invention also relates to a process for coating keratin materials, more particularly for making up and / or caring for keratin materials, such as the skin, characterized in that it comprises the application to the keratin materials of an emulsion as defined above. The invention relates more particularly to a process for making up and / or caring for the skin, characterized in that it comprises the application to the skin of a composition as defined above. Definitions In the context of the present invention, by “keratin materials” is meant the skin and more particularly areas such as the face, cheeks, hands, body, legs and thighs, the eye contour, the eyelids. By "physiologically acceptable" we mean compatible with the skin and / or its appendages, which has a pleasant color, odor and feel and which does not generate unacceptable discomfort (tingling, tightness) likely to discourage the consumer from using this composition. For the oily and aqueous phases of the composition of the invention, it is understood that "they form a macroscopically homogeneous mixture", by the fact that observation of the composition by eye does not allow the presence of the two immiscible phases to be distinguished between them. The identification of each of the two phases, their arrangement and their distribution within the composition can generally only be observed under a microscope. Oily phase The composition according to the invention for caring for and / or making up keratin materials comprises at least one fatty phase comprising at least one volatile hydrocarbon oil H,. By "oil" we mean a fatty substance that is liquid at room temperature (25°C) and atmospheric pressure (760mm Hg or 105 Pa). By "oily phase" is meant an organic phase which is liquid at room temperature (25°C) and atmospheric pressure containing at least one oil and possibly cosmetic additives which are soluble or miscible in said phase. The term “hydrocarbon oil” means an oil containing mainly hydrogen and carbon atoms and possibly one or more functions chosen from hydroxyl, ester, ether and carboxylic functions. For the purposes of the invention, the term "volatile oil" means any oil capable of evaporating on contact with the skin in less than one hour, at room temperature and atmospheric pressure. Volatile oil is a volatile cosmetic compound, liquid at room temperature, having in particular a non-zero vapor pressure, at room temperature and atmospheric pressure, in particular having a vapor pressure ranging from 2.66 Pa to 40,000 Pa, in particular ranging from 2.66 Pa to 13,000 Pa, and more particularly ranging from 2.66 Pa to 1,300 Pa. As an example of volatile hydrocarbon oil H, usable in the oily phase of the composition of the invention, mention may be made of hydrocarbon oils having from 8 to 16 carbon atoms, and in particular Cg-Cy5 isoalkanes of petroleum origin (also called isoparaffins) such as isododecane (also called 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane. Other oils sold under the trade names Isopar® or Permethyl®, branched C;-C,5 esters, isohexyl neopentanoate, and mixtures thereof may also be used. Other volatile hydrocarbon oils such as petroleum distillates, including those sold under the name Shell Solt by the company SHELL, may also be used. The volatile hydrocarbon oils H, which can be used in the compositions according to the invention, can be chosen from volatile linear alkanes comprising from 6 to 14 carbon atoms. As examples of linear alkanes suitable for the invention, mention may be made of the alkanes described in the patent applications of the company Cognis WO 2007 / 068371, or WO2008 / 155059 (mixtures of distinct alkanes differing by at least one carbon). These alkanes are obtained from fatty alcohols, themselves obtained from copra or palm oil. Examples of linear Cs-C;4 alkanes suitable for the invention include n-hexane (C5); n-heptane (C7), n-octane (C;), n-nonane (Cs), n-decane (C19), n-undecane (C1), n-dodecane (C;2), n-tridecane (C;3), n-tetradecane (C4), and mixtures thereof. Examples include n-dodecane (C;2) and n-tetradecane (C14) sold by Sasol under the references PARAFOL 12 97® and PARAFOL 14 97® respectively, as well as their mixtures. According to another embodiment, a mixture of n-dodecane and n-tetradecane is used. In particular, the dodecane / tetradecane mixture in the weight ratio 85 / 15 marketed by the company BIOSYNTHIS under the reference VEGELIGHT 1214® can be used. According to yet another embodiment, a mixture of volatile linear C1-C2 alkanes with INCI name: C9-12 ALKANE is used, such as the product marketed by the company BIOSYNTHIS under the reference VEGELIGHT SILK®. According to yet another embodiment, a mixture of n-undecane (C;1) and n-tridecane (C,;) is used, such as those obtained in examples 1 and 2 of application WO2008 / 155059 from the company Cognis and such as that sold under the trade name CETIOL ULTIMATE® by the company BASF. According to a particularly preferred embodiment, the volatile hydrocarbon oil H will be chosen from Cy-Cy5 isoalkanes of petroleum origin, and more particularly isododecane. According to a preferred embodiment of the invention, the oily phase is present in the composition in an amount ranging from 5 to 95% by weight, and more preferably from 10 to 90% by weight relative to the total weight of the composition. Aqueous phase The composition of the invention comprises an aqueous phase. This forms a macroscopically homogeneous mixture with the oily phase. The aqueous phase includes water and optionally water-soluble or water-miscible ingredients such as water-soluble solvents. A water suitable for the invention may be a floral water such as cornflower water and / or a mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or a thermal water. In the present invention, the term "water-soluble solvent" means a compound that is liquid at room temperature and miscible with water (miscibility in water greater than 50% by weight at 25°C and atmospheric pressure). The water-soluble solvents that can be used in the composition of the invention can also be volatile. Among the water-soluble solvents which may be used in the composition in accordance with the invention, mention may in particular be made of C2-C4 monoalcohols such as ethanol, isopropanol, glycols having from 2 to 8 carbon atoms such as ethylene glycol, propylene glycol, 1,3-butylene glycol, propanediol, pentylene glycol, glycerin and dipropylene glycol, C3-C4 ketones and C2-C4 aldehydes. According to a preferred embodiment, the weight ratio of the total quantity of volatile hydrocarbon oil(s) relative to the total weight of the composition] on the quantity of aqueous phase relative to the total weight of the composition is greater than 0.085 According to a particular form, the water is present in a concentration ranging from 5 to 95% by weight, and more particularly from 10 to 90% by weight, relative to the total weight of said composition. According to a particular form, the aqueous phase of the composition is present in a concentration ranging from 5 to 95% by weight, and more particularly from 10 to 90% by weight, relative to the total weight of said composition. According to a particular form, the non-solid compositions of the invention comprising an aqueous phase can be presented in different galenic forms such as - emulsions such as oil-water or water-oil emulsions where one of the two oily and aqueous phases is dispersed in the other so-called continuous phase in the form of droplets and the composition is macroscopically homogeneous to the naked eye; - macroscopically homogeneous bi-gels to the naked eye. The silicone era to function id boxyli The composition according to the invention for caring for and / or making up keratin materials comprises b) at least one silicone elastomer with carboxylic acid functions. The term "organopolysiloxane elastomer" means a soft, deformable organopolysiloxane with viscoelastic properties, including the consistency of a sponge or a soft sphere. Its modulus of elasticity is such that this material resists deformation and has a limited capacity for extension and contraction. This material is capable of returning to its original shape following stretching. It is generally partially or completely crosslinked and is non-cyclic. By “carboxylic acid functional silicone elastomer” is meant an organopolysiloxane elastomer comprising in its structure at least two carboxylic acid groups with at least one -COOH function. The composition according to the invention advantageously has an active material content of silicone elastomer with carboxylic acid functions ranging from 2 to 25% by weight relative to the weight of the composition. Preferably, this content ranges from 5 to 20% by weight relative to the weight of the composition. The silicone elastomers with carboxylic acid functions that can be used in the compositions of the invention can be chosen from those described in published documents WO2015066161 (US20160200876), WO2015066165, WO2015066199, WO2015167963, WO20180165434 (US10918587B2), IPCOM000250448D, IPCOM000250657D. According to a particular embodiment, the silicone elastomer with carboxylic acid functions is chosen from those corresponding to the following formula (I): [Chem.1] R°SI-O-(SIRRÉ-OLISIR -OLSIR REO-T IR, x 3 1 + +8 R',SI-O-[SIR"RLO1 SR -O-4,1SIR R"O-] SIR TS SIA A NARUTO PAYS 3 {P. [Chem.1] ?, 8 RS" CWY-WC,__ p2_ con Hoc” La È oO 2 ci. in which the radical X corresponds to the following formula (i) or formula (i*): |Chem 2] [Chem 3] qd) 46th — F0 eme —# R8— OH Ho © o in which W and W* independently denote an oxygen atom (O) or an N-R group where each radical R independently denotes a hydrogen atom (H) or a radical R!; Y is a divalent group; R'!, R', R4 RI6, R5 and R!S independently denote a substituted or unsubstituted hydrocarbyl group; R3 and R'* independently denote a divalent group; w and ww are independently integers ranging from 0 to 1000; x and xx are independently integers ranging from 1 to 100; y and yy are independently integers ranging from 0 to 1000; preferably, w and y are not simultaneously equal to 0 and ww and yy are not simultaneously equal to 0. By “substituted” is meant that one or more hydrogen atoms of the hydrocarbyl group is (are) replaced by an atom other than hydrogen (i.e. halogen) or that one or more carbon atoms is (are) replaced by an atom other than carbon such as a heteroatom like oxygen, sulfur or nitrogen. In formula (I), the lower and upper portions are the same or different siloxanes. In some particular embodiments, each siloxane chain comprises siloxane bonds (Si-O-Si) on their respective backbones. Each siloxane chain may include siloxane bonds separated by one or more divalent groups, for example a -CH,- linking group. Other examples of divalent groups may include polyether groups: for example, linking groups -CH,CH20- (i.e., ethylene oxide group), -CH(CH; )CH:0- (i.e., propylene oxide), etc. Combinations of different divalent groups may be present on their respective backbones. Each of the divalent groups may be single or repeated, i.e., 2 times, 5 times, 10 times, or even > 10 times, etc. In some embodiments, the siloxanes do not comprise a polyether group. In various embodiments, one or both of the siloxanes may comprise at least one [SiR'R?-0-] unit ("D" or R*,Si0,2 units). Typically, each siloxane has a repeat of D units, which generally constitute the linear portions of the siloxanes. The siloxanes also typically have terminal R*; Si0,- units ("M" units). In certain particular embodiments, one or both of the siloxanes may optionally be branched, partially branched and / or include a resin portion having a three-dimensional structure network. In such cases, the corresponding siloxane(s) may additionally comprise R*SiO4 units ("T" units) and / or SiO4 units ("Q" units). The branched or resinous character of the siloxane(s) may be attributed to the presence of T and / or Q units. The branched character of a siloxane may be attributed to side groups of one or more D units. According to particular embodiments, one or both of the siloxanes may be devoid of T units and / or units. The two siloxanes can be the same or different: i.e. one is linear and the other branched, or both siloxanes are linear. According to certain particular embodiments, the radicals R! independently denote an alkyl, aryl, alkenyl, alkaryl, or aralkyl radical. More particularly, the radicals RI denote an alkyl radical, preferably having from 1 to 20, from 1 to 15, from 1 to 10, from 1 to 6, from 1 to 4, or 1 or 2 carbon atoms such as, for example, methyl, ethyl, propyl, butyl, pentyl. More specifically, all R' radicals denote a methyl group (i.e. -CH:). Preferably, the radical R is a hydrocarbylene, heterohydrocarbylene, or organoheterylene group. In particular, R* is a group (CHz), where n is an integer ranging from 1 to 30, 1 to 25, 1 to 20, 1 to 15, 1 to 10, 1 to 5, or 1 to 3, and more particularly equal to 3. . According to various particular modes, each of the radicals R* and R° can independently designate a substituted or unsubstituted hydrocarbyl group, notably chosen from those defined previously for the radicals R'. According to certain embodiments, each radical R* independently denotes an alkyl, aryl (i.e. phenyl) group or a group (R'O)". When R* is a group (ReO), Re is preferably an alkyl or aryl (i.e. phenyl) radial and m is an integer ranging from 1 to 50, from 1225, from 1 to 10, from 1 to 5, or 1. The group (R°O), may be a polyether group (i.e. with ethylene oxide and / or propylene oxide units). According to particular embodiments, a radical R4 may be a divalent group of a silicone side chain of the siloxane. According to a particular mode, R* can designate an anhydride group of formula (1) [Chem 4] ) (1) $) — At i 0 T 0 in which R* has the same definition indicated previously. Preferably, the radicals R* denote an alkyl radical or a polyether group. Preferably, each radical R° is a radical R'. For example, each radical R° and R' is an alkyl group: i.e. methyl. Preferably, R'! is identical to or different from R', R'“ is identical to or different from R*, R'* is identical to or different from RS. Preferably, the radicals R° denote R! and / or the radicals R'° denote R!!, Preferably, w is an integer ranging from 0 to 1000, from 0 to 950, from 0 to 750, from 0 to 500, from 0 to 400, from 1 to 350, from 1 to 300, from 25 to 250, from 50 to 200, from 50 to 150, from 75 to 125, from 90 to 110, from 90 to 100, from 90 to 95, and more particularly is equal to 93. Preferably, x is an integer from 1 to 100, from 1 to 75, from 1 to 50, from 1 to 25, from 1 to 20, from 1 to 10, or from 1 to 5, and more particularly is equal to 3. Preferably, y is an integer ranging from 0 to 1000, from 0 to 950, from 0 to 750, from 0 to 500, from 0 to 400, from 1 to 350, from 1 to 300, from 1 to 250, from 1 to 200, from 1 to 150, from 1 to 100, from 1 to 75, from 1 to 50, from 1 to 25, from 1 to 20, from 1 to 15, from 1 to 10, or from 1 to 5. According to various embodiments, w and y are not simultaneously equal to 0. In some embodiments, the sum w+x+y varies from 25 to 1500, from 25 to 1000, from 25 to 900, from 25 to 800, from 25 to 700, from 25 to 600, from 25 to 500, from 25 to 400, from 25 to 300, from 50 to 200, from 75 to 150, from 85 to 125 or from 90 to 110. In some modes, x is at least 1, at least 10, at least 25, at least 50, at least 75, or at least 5. In particular embodiments, ww may be the same as or different from w, xx may be the same as or different from x and yy may be the same as or different from y. The units of formula (I), in particular those represented in brackets indexed by w, ww, X, XX, y or yy may be present in any order, randomly or in sequenced form. According to certain particular embodiments, the radicals R'!, identical or different, denote a linear, branched or cyclic C1-C29, C1-C5, C1-C0, C1-C6, C1-C1, C1-C2 alkyl radical such as methyl, ethyl, propyl, butyl, pentyl groups, etc. More preferably, the radicals R!! are a methyl group. According to certain particular modes, the radicals R!*, identical or different, denote an alkyl, aryl (i.e. phenyl) or (R'°O) radical,n When R' is a group (R'O)pms R'S denotes an alkyl or aryl (i.e. phenyl) group and mm is an integer ranging from 1 to 50, 1 to 25, 1 to 10, 1 to 5, or 1. The group (RS O)mm can be a polyether group (ie: with ethylene oxide and / or propylene oxide units). According to particular embodiments, the radicals R'* independently denote an alkyl radical having from 2 to 20, 2 to 15, 2 to 10, 2 to 5, or 2 carbon atoms. In other particular embodiments, R'* may be a divalent linking group of a silicone side chain of the siloxane. According to a particular mode, R'* can denote an anhydride group of formula (1) ) (1) R TO Ü Di THE) in which R* has the same definition indicated previously. Preferably, the radicals R14 denote an alkyl radical or a polyether group. Preferably, ww is an integer ranging from 0 to 1000, from 0 to 950, from 0 to 750, from 0 to 500, from 0 to 400, from 1 to 350, from 1 to 300, from 25 to 250, from 50 to 200, from 50 to 150, from 75 to 125, from 90 to 110, from 90 to 100, from 90 to 95, and more particularly 93. Preferably, xx is an integer ranging from 1 to 100, from 1 to 75, from 1 to 50, from 1 to 25, from 1 to 20, from 1 to 10 or from 1 to 5, and more particularly 3. Preferably, yy is an integer ranging from 0 to 1000, from 0 to 950, from 0 to 750, from 0 to 500, from 0 to 400, from 1 to 350, from 1 to 300, from 1 to 250, from 1 to 200, from 1 to 150, from 1 to 100, from 1 to 75, 1 to 50, 1 to 25, 1 to 20, 1 to 15, 1 to 10 or 1 to 5. In various embodiments, ww and yy are not simultaneously equal to 0. In some particular embodiments, the sum ww+xx+yy varies from 25 to 1500, from 25 to 1000, from 25 to 900, from 25 to 800, from 25 to 700, from 25 to 600, from 2 to 500, 25 to 400, from 25 to 300, from 50 to 200, from 75 to 150, from 85 to 125, or from 90 to 110. According to certain particular modes, xx is at least equal to 1, at least equal to 10, at least equal to 25, at least equal to 50, at least equal to 75, or at least equal to 85. The middle portion X of formula (I) corresponds to the radical X corresponding to the following formula (i) or formula (i'): ÿ ® RE_ÔTEWW'CX__rB3_ Hoc” D con he oh ô 0 ®. (dd) oO OO reset rs — Fee —m m8 OH Ho 0 o in which - each group W and W* independently denotes an oxygen atom (O) or an NR group, with R denoting a hydrogen atom (H) or a radical R!; preferably R is H; - R' is a divalent group, preferably a hydrocarbylene, a heterohydrocarbylene or an organoheterylene; in particular, R'* denotes a radical (CH2)nn where nn is an integer from 1 to 30, from 1 to 1, from 1 to 20, from 1 to 15, from 1 to 10, from 1 to 5, from 1 to 3, and more particularly 3; R'? may be identical or different with respect to R°; - each radical Y is a divalent group, in particular denotes a hydrocarbylene, heterohydrocarbylene or organoheterylene radical; in particular, Ÿ is a hydrocarbylene group having from 1 to 50, from 1 to 40, from 1 to 20, from 1 to 20, from 1 to 10, from 1 to 5, from 1 or 2 carbon atoms or may denote a group of the following formula (ii): [Chem 5] —Zje[ISIRER 6.0.1 ISIRÉRE-O-PISIRER10.0-15SHZIg— , in which - each RS, R° independently denotes a substituted or unsubstituted hydrocarbyl group, in particular chosen from an alkyl group (i.e. methyl), an aryl group (i.e. phenyl), a polyether group (i.e. with ethylene oxide and / or propylene oxide units); - each radical R"° independently denotes a substituted or unsubstituted hydrocarbyl group such as the radicals defined previously for R! and R*, in particular, R'° may be an alkyl group having from | to 20 carbon atoms or a polyether group or a divalent group linking a silicone side chain of the siloxane; - each radical Z independently comprises at least one hydrocarbylene, heterohydrocarbylene or organoheterylene group, in particular is a hydrocarbylene group having from 1 to 20, from 1 to 10, from 1 to 5, or 1 or carbon atom(s), in particular Z may include siloxane bonds separated by one or more divalent groups, for example a -CH,- linking group; other examples of divalent groups may include polyether groups: for example -CH,CH; 0- linking groups (i.e., ethylene oxide group), -CH(CH)CH.0- (ie, propylene oxide); - a is an integer from 0 to 1000, from 0 to 950, from 0 to 750, from 0 to 500, from 0 to 400, from 00 to 300, from 0 to 200, from 0 to 100, from 0 to 75, from 0 to 50, from 0 to 25, from 0 to 20 or - b is an integer from 1 to 1000, from 1 to 950, from 1 to 750, from 1 to 500, from 1 to 400, from 1 to 300, or from 1 to 200. - it is an integer ranging from 0 to 1000, from 0 to 950, from 0 to 750, from 0 to 500, from 0 to 400, from 0 to 300. from 0 to 200, from 0 to 100. - each d is equal to 0 or 1. In particular, at least one of the d is equal to 1 or both are equal to 1; the patterns of formula (ii) represented in brackets indexed by a, b, or c being present in any order, randomly or in sequenced form. According to a particular form, the siloxane of formula (ii) may be a resin of formula R*,SiO;4.y2. Preferably, a silicone resin has along its chain T and / or Q units with M units and optionally D units. The radicals R* may be chosen independently from a substituted (i.e.: hydroxyl, amine functions) or unsubstituted hydrocarbonyl group and s varies from 0 to 3. The R* groups which can be used may be those described previously for the radicals RS, R°, and R"°. Various combinations of such groups may be present. According to these particular cases, the silicone resin comprises a combination of M, D, T and / or Q units. It may include an MDT type resin, an MT type resin, an MDQ type resin, an MQ type resin or an MDTQ type resin. Each of the M, D and T units may contain different R* groups. The resin may have various molecular weights such as a number average molecular weight ranging from 800 to 500,000. According to a particular form of the invention, the silicone elastomers with carboxylic acid functions have a carboxyl equivalent ranging from 100 to 50,000, from 500 to 10,000, or 500 to 5,000, The carboxylic-functional silicone elastomers of formula (I) can be obtained according to one of the synthesis processes described in documents WO2015066161 (US20160200876). According to a first variant of the synthesis process, certain silicone elastomers with carboxylic acid functions can be obtained by reaction of 1) a first siloxane carrying pendant anhydride groups, 2) a second siloxane carrying pendant anhydride groups and 3) an organic polyol. According to a particular mode, one or more siloxanes different from the first two can be reacted with the 3 preceding reagents. According to a second variant of the synthesis process, certain silicone elastomers with carboxylic acid functions can be obtained by reaction of 1) a first siloxane carrying pendant anhydride groups, 2) a second siloxane carrying pendant anhydride groups and 3) an organic polyamine. According to a particular mode, one or more additional siloxanes different from the first two can be reacted with the 3 preceding reagents. According to a third variant of the synthesis process, certain silicone elastomers with carboxylic acid functions can be obtained by reacting 1) a first siloxane bearing pendant anhydride groups, 2) a second siloxane bearing pendant anhydride groups and 3) a third siloxane having at least two hydroxyl groups. According to a particular mode, one or more additional siloxanes different from the first two can be reacted with the 3 preceding reagents. According to a fourth variant of the synthesis process, certain silicone elastomers with carboxylic acid functions can be obtained by reacting 1) a first siloxane carrying pendant anhydride groups, 2) a second siloxane carrying pendant anhydride groups and 3) a third siloxane having pendant amine groups and / or terminal amine groups. According to a particular mode, one or more additional siloxanes different from the first two can be reacted with the 3 preceding reagents. According to a fifth variant of the synthesis process, certain silicone elastomers with carboxylic acid functions can be obtained by reaction of 1) a first siloxane carrying pendant hydroxyl groups, 2) a second siloxane bearing pendant hydroxyl groups and 3) a third siloxane having at least two terminal anhydride groups. According to a particular method, one or more additional siloxanes different from the first two can be reacted with the 3 preceding reagents. According to a sixth variant of the synthesis process, certain silicone elastomers with carboxylic acid functions can be obtained by reacting 1) a first siloxane bearing pendant amine groups, 2) a second siloxane bearing pendant amine groups and 3) a third siloxane having at least two terminal anhydride groups. According to a particular embodiment, one or more additional siloxanes different from the first two can be reacted with the 3 preceding reagents. According to a seventh variant of the synthesis process, certain silicone elastomers with carboxylic acid functions can be obtained by reacting 1) a first organic alcohol, 2) a second organic alcohol and 3) a siloxane having terminal anhydride groups. According to a particular embodiment, one or more additional organic alcohols different from the first two can be reacted with the 3 preceding reagents. Among the silicone elastomers with carboxylic acid function of formula (I), mention may be made of the following compounds 1 to 12 as described respectively in examples 4, 5, 7 to 16 of application WO2015066161 and compound 13 as described in application US20160200876 (example 15) and the examples of the patent: Y CH W SH 7+ + çe ' ; ' pe Si CHE vu … 78 {-si-o-hivgme- a nerprotiro Tes w Ï X CH, Ên, pri Ÿ The" ô [oH 0 X À 1 A du iv He-ÿ-0-1h-01L6-0 Hoi Gt, CH, CH Ÿ OH UT OUH in (compound 1) (compound 2) + #7 x Ho ne-frot io t{{o3ftrotfros cm 2? x CH, WCH, 2 7 P we © x # fe Loti Hkrot-betoti; He-gio-sirofgro}Fsio}si-eh, ON, CH, W 2, x CH, YOH pe gt, CH, ; LH, 'gs (compound 3) ne-ÿro-täco-H-3ro-[i-gro-t-pron CH, 10% 4 to ÎH, VOOH, { 7 / 4%} = Ph ES Gi oretot Fi merite jee ÊM, CM, w 2M X% CH, YCH, is 4) H, H, ÇH, (composes faith EL] Te Ho -cH, S pobfoireotett es O7 vote qH, SH, EF (compound 5) ÿ CN ps 6 1 qq He-ÿro-täro-itgro-t{grot-srou A, 4% UH ON 2 7 5H / ç- ( $ of on o-Ÿ 100 qe HOUR 5 CH, RG 454 5-0 d-0 ++sro4- $-cH, 2H, 2H W OH, X OH, VOH ÇH, H, CH CH, CH, (e été n HÉd-in, xê $ê, "ds, 5 > % Re <hS cr =) \=0 S fluent fs 4 A, ° qe *t Ï He 5 of pea rotf-o+ pe GR, CH, - CH CH, H, » - w C x GR to 5H 11 A CES (compound 6) wæ » X LH cn χ GH, 3 3 RE 5H, CH and pro-Hrottdro4Hiro-1éron CH, y 7H, + x ÊH, \ / ; 7x » rl But I rotrs-othrett that > ​​$- CH, 3H, EM TU CH VO Ou, XCH EM x CH, ê < ÇH, FH, ; Ft ; £H, bas (compound 7) He-si-0-{8p0-H{-550-h{-8-0-1-8-01, CH, / ° ÊM, w \ XCH \ = HO so This % NH HO / 0-4 is mains prone gogo trot ÊH, 2H, Ÿ CH WW CH, *OH (compound 8) Yv TH, FIGURE 1 FH. FF EF ke-ÿ-o-{-Sr0}{-$r0--$-04-5-0H, ÊH, Y CH W OX ÊH t £ s YF w LH, Te 4 ørh Crss HefroPprotaro-ttrro-Jfron OH, CH, Ÿ ùH, ŸW CH ŸCH, (compound 9) v HER HART dE HC-8i-0-{-8i-04{-8i-0-fi-0+-8i-0H, and, € v èm ww! x OH, > < OO wW * xg os “= , with # He King CA Er is © preneo on the pore structure {on tt, CH, CH CH, VW CH, * OH Hs 0 —L-is<0 H ; +GoH4 is YT° Ç t +4 = “ H w 0! x C > > y, Or WW CH, EH sh CH, 4 CH Re (CHLOHHE HD) 22 (CH,1297S1-0- SOS AEH)galC HDI 22 (0H5Olzs CH, CH, CH (compound 10) H i Ë tif Homes EL } Ro Blefi< Chin : 5 ° ; + IS 08 TO ! x * AUDE CS a 1e CE ô er af ù È Ï Clear Ÿ nf mm; o Ra mS met # f + RE S Homes; SN T ' < + Ç & . ENS & LAN Res and RAI E. af Hess NT NS d RA ci, er du = î Fa ai EEE em Fat Ï Ë is, be ER EL (compound 11) CH, CH zH, CH CH, (compound 12) =. Ÿ & to 3 Ÿ * A. 6 The ER IS WORD wandering, they are, I ÉH w LL XUH x H,É− 2 CH, - as H——6i——0H, € Fe A rs ; If not-fo-Fg=0-H-$-0-k{ai<0-}-8i—04, that is, CH OT UHR VO 64 XCR AA of, CH Ÿ th Ÿ According to a particular form, the composition of the invention contains at least compound 10 or compound 11 as defined above. Compound 10 is notably described in document US20160200876 (compound of example 15) and the examples of patent US10918587B2. Among the silicone elastomers with carboxylic acid functions which can be used in the compositions of the invention, mention may also be made of the silicone elastomer with the INCI name: HEXYL / SUCCINYL DIMETHICONE CROSSPOLYMER. According to a particular form, the silicone elastomers with carboxylic acid functions are in solid form. They can in particular be chosen from compounds 2 and 3 as defined previously. According to another particular form, the silicone elastomers with carboxylic acid functions are dispersed in at least one oil H, and are in the form of a gel. Oil H; may be chosen from volatile oils and / or non-volatile oils. By "non-volatile oil" is meant an oil remaining on the keratin material at room temperature (25°C) and atmospheric pressure (760 mm Hg) for at least several hours and having in particular a vapor pressure of less than 107 mm Hg. Hg (0.13 Pa). The oil or oils H may be chosen from hydrocarbon oils, silicone oils and their mixtures. For the purposes of the present invention, the term “silicone oil” means an oil comprising at least one Si-O group, and more particularly an organopolysiloxane. Among the volatile silicone oils H, which can be used in the compositions, mention may be made, for example, of volatile linear or cyclic silicone oils, in particular those having a viscosity less than or equal to 8 centistokes (8 106 mmm' / s), and in particular having from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups having from 1 to 10 carbon atoms. As linear volatile silicone oil H, which can be used in the invention, mention may be made of octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and mixtures thereof. As cyclic volatile silicone oil Hz which can be used in the invention, mention may be made of cyclomethicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethyl cyclohexasiloxane and mixtures thereof. Examples of linear non-volatile silicone oil Hz include polydimethylsiloxanes (also called dimethicones); alkyl dimethicones; vinylmethylmethicones and polydimethylsiloxanes modified with aliphatic groups and / or functional groups such as hydroxyl, thiol, carboxylic acid and / or amine groups. Examples of linear non-volatile hydrocarbon oil include: - synthetic esters, such as oils of formula R,COOR:, in which R, represents a residue of a linear or branched fatty acid containing from 1 to 40 carbon atoms, and R. represents a hydrocarbon chain, in particular, branched containing from 1 to 40 carbon atoms provided that the sum of the number of carbon atoms in the chains R1 and R2 is greater than or equal to 10; the esters may be, in particular, chosen from esters of alcohol and fatty acid, such as for example cetostearyl octanoate, esters of isopropyl alcohol, such as isopropyl myristate, isopropyl palmitate, ethyl palmitate, 2-ethylhexyl palmitate, stearate or isostearate isopropyl, isostearyl isostearate, octyl stearate, hydroxylated esters such as isostearyl lactate, octyl hydroxystearate, adipate diisopropyl, heptanoates, and in particular isostearyl heptanoate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, such as propylene glycol dioctanoate, cetyl octanoate, tridecyl octanoate, ethyl 2-hexyl 4-diheptanoate and palmitate, alkyl benzoate, polyethylene glycol diheptanoate, propylene glycol diethyl 2-hexanoate, and mixtures thereof, C,2-C;5 alcohol benzoates, hexyl laurate, neopentanoic acid esters, such as isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldocecyl neopentanoate, isononanoic acid esters, such as isononyl isononanoate, isotridecyl isononanoate, octyl isononanoate, hydroxylated esters such as isostearyl lactate, diisostearyl malate; and more particularly isodecyl neopentanoate; - di-alkyl carbonates, the 2 alkyl chains being able to be identical or different, such as dicaprylyl carbonate marketed under the name Cetiol CC®, by Cognis; - synthetic ethers having 10 to 40 carbon atoms such as Dicaprylyl ether. According to a preferred form of the invention, the oil or oils H; may be chosen from volatile hydrocarbon oils as described above for the oils H,. The oil or oils Hz may be identical to or different from the oil or oils H, present in the oily phase of the composition. According to a particular form of the invention, the oil or oils H, present in the oily dispersion of silicone elastomer with carboxylic acid functions is (are) identical to the oil or oils H, present in the oily phase of the composition. According to a more particularly preferred form of the invention, the oil H; present in the oily dispersion of silicone elastomer with carboxylic acid functions and the oil H, present in the oily phase of the composition denote a Cz-C,s isoalkane of petroleum origin, and more particularly isododecane. According to a preferred form, the oily dispersion of silicone elastomer with carboxylic acid functions comprises from 10 to 40% by weight of active silicone elastomer material, and more preferably from 20 to 35% by weight relative to the total weight of the oily dispersion. According to a preferred form, the composition of the invention comprises at least one silicone elastomer with carboxylic acid functions in dispersion in isododecane and in gel form. In particular, said silicone elastomer is chosen from compounds 1, 4 to 11 as defined above. According to a particularly preferred form, the composition of the invention comprises compound 10 or compound 11 in dispersion in isododecane and in gel form, and more particularly in an active material content equal to 30% by weight relative to the total weight of the dispersion. According to another particularly preferred form, the composition of the invention comprises a silicone elastomer with carboxylic acid functions in dispersion. in isododecane and in the form of a gel with the INCI name: ISODODECANE (and) HEXYL / SUCCINYL DIMETHICONE CROSSPOLYMER and more particularly in an active ingredient content equal to 30% by weight relative to the total weight of the dispersion such as the commercial product DOWSIL EL-7314 SILICONE ELASTOMER BLEND® sold by the company Dow Corning comprising 30% by weight of active ingredient of said silicone elastomer. According to the present invention, the weight ratio of the total quantity of volatile hydrocarbon oil(s) relative to the total weight of the composition to the quantity of silicone elastomer with carboxylic acid functions relative to the total weight of the composition varies from 3.8 to 12.0, and more preferably from 4.2 to 10. When the composition of the invention comprises an oily dispersion of silicone elastomer with carboxylic acid functions dispersed in at least one volatile hydrocarbon oil H, the weight ratio of the total amount of volatile hydrocarbon oil(s) H, and H> relative to the total weight of the composition to the amount of silicone elastomer with carboxylic acid functions relative to the total weight of the composition varies from 3.8 to 12.0 and more preferably from 4.2 to 10. Silicone resins: silicone resin polymers: According to a particular form, the composition of the invention may additionally comprise at least one silicone resin and / or at least one copolymer of silicone resin and silicone of dimethiconol type. A. Silicone resin The nomenclature for silicone resins (also called siloxane resins or silicone resins) is known as "MDTQ", the resin being described in terms of the different siloxane monomeric units it comprises, each of the letters "MDTQ" characterizing a type of unit. The letter "M" represents the Monofunctional unit of formula RIR2R3SiO,7, the silicon atom being linked to a single oxygen atom in the polymer comprising this unit. The letter "D" stands for a difunctional unit RIR2SiO,; in which the silicon atom is bonded to two oxygen atoms The letter "T" represents a Trifunctional unit of formula R1SiO4,. Such resins are described for example in "Encyclopedia of Polymer Science and Engineering, vol. 15, John and Wiley and Sons, New York, (1989), pp. 265-270, and US 2,676,182, US 3,627,851, US 3,772,247, US 5,248,739 or US 5,082,706, US 5,319,040, US 5,302,685 and US 4,935,484. In the patterns M, D, T defined above, R, namely R1, R2 and R3, represents a hydrocarbon radical (in particular alkyl) having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or even a hydroxyl group. Finally, the letter "Q" stands for a tetrafunctional unit SiO, in which the silicon atom is bonded to four oxygen atoms which are themselves bonded to the rest of the polymer. Various silicone resins with different properties can be obtained from these different units, the properties of these polymers varying according to the type of monomers (or units), the nature and number of the R radical, the length of the polymer chain, the degree of branching and the size of the pendant chains. As silicone resins which can be used in the compositions according to the invention, it is possible to use, for example, silicone resins of type MQ, type T or type MQT. MO resins: As an example of MQ type silicone resins, mention may be made of alkylsiloxysilicates of formula [(R1):Si0.2]x(SiO42)y (MQ units) in which x and y are integers ranging from 50 to 80, and such that the R1 group represents a radical as defined above, and preferably is an alkyl group having from 1 to 8 carbon atoms, or a hydroxyl group, preferably a methyl group. Examples of MQ silicone resins of the Trimethylsiloxysilicate type include those marketed under the reference SR1000® by General Electric, under the reference TMS 803® by Wacker, under the name "KF-7312J®" by Shin-Etsu, "DC 749®", "DC 593®" by Dow Corning. As silicone resins comprising MQ siloxysilicate units, mention may also be made of phenylalkylsiloxysilicate resins, such as phenylpropyldimethylsiloxysilicate (Silshine 151® marketed by General Electric). The preparation of such resins is described in particular in patent US5817302. T resins: As an example of T-type silicone resins, mention may be made of polysilsesquioxanes of formula (RSiO,;)x (T units) in which x is greater than 100 and such that the R group is an alkyl group having from 1 to 10 carbon atoms, said polysilsesquioxanes being able to further comprise Si-OH terminal groups. Preferably, polymethylsilsesquioxane resins in which R represents a methyl group can be used, such as those sold: - by the company Wacker under the reference Resin MK® such as Belsil PMS MK®: polymer comprising repeating units CH,SiO,» (T units), which may also comprise up to 1% by weight of units (CH).SiO, (D units) and having a weight average molecular weight of about 10000 g / mol, or - by the company SHIN-ETSU under the references KR-220L® which are composed of T units of formula CH;SiO32 and have Si-OH (silanol) end groups, under the reference KR-242A® which comprise 98% of T units and 2% of dimethyl D units and have Si-OH end groups or under the reference KR-251® comprising 88% of T units and 12% of dimethyl D units and have Si-OH end groups. MOT resins: As a resin comprising MQT units, those cited in document US 5,110,890 are known in particular. A preferred form of MQT type resins are MQT-propyl resins (also called MQTPr). Such resins usable in the compositions according to the invention are in particular those described and prepared in application WO 2005 / 075542, the content of which is incorporated herein by reference. MQ-T-propyl resin preferably comprises the units: (0)(R1:Si0.2); (ii) (R2.Sio2n2) (iii) (R3SiOy). and (iv) (SIO4w»)a with RI, R2 and R3 independently representing a hydrocarbon radical (in particular alkyl) having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or even a hydroxyl group and preferably an alkyl radical having from 1 to 8 carbon atoms or a phenyl group, a, b, c and d being mole fractions, a being between 0.05 and 0.5, b being between zero and 0.3, c being greater than zero, d being between 0.05 and 0.6, a+b+e+d=]l, provided that more than 40 mol% of the R3 groups of the siloxane resin are propyl groups. Preferably, the siloxane resin comprises the units: (D)(R1;Si10.4), (ii) (R2:Si022) (iii) (R3SiOy-). and (iv) (SiIO4)a with RI and R3 independently representing an alkyl group having from 1 to 8 carbon atoms, RI1 preferably being a methyl group and R3 being preferably a propyl group, a being between 0.05 and 0.5, preferably between 0.15 and 0.4, c being greater than zero, preferably between 0.15 and 0.4, d being between 0.05 and 0.6, preferably between 0.2 and 0.6, or between 0.2 and 0.55, a+b+c+d= 1, eta, b, this being molar fractions, provided that more than 40 mol% of the R3 groups of the siloxane resin are propyl groups. The siloxane resins which can be used according to the invention can be obtained by a process comprising the reaction of: A) an MQ resin comprising at least 80 mol% of (R13SiO1 / 2)a and (SiO42)a units with RI representing an alkyl group having from 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group, a and d being greater than zero, the ratio a / d being between 0.5 and 1.5; and B) a propyl resin T comprising at least 80 mol% of (R3Si037)e units, with R3 representing an alkyl group having from 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group, c being greater than zero, provided that at least 40 mol% of the R3 groups are propyl groups, where the mass ratio A / B is between 95:5 and 15:85, preferably the mass ratio A / B is 30:70. Advantageously, the mass ratio A / B is between 95:5 and 15:85. Preferably, the ratio A / B is less than or equal to 70:30. These preferred ratios have been found to allow comfortable depositions. Preferably, the composition according to the invention comprises, as silicone resin, at least one resin of MQ type, more particularly of Trimethylsiloxysilicate type, such as those marketed under the reference SR1000® by the company General Electric, under the reference TMS 803® by the company Wacker, under the name "KF-7312J®" by the company Shin-Etsu, "DC 749®", "DC 593®" by the company Dow Corning. According to a particular embodiment of the invention, the silicone resin is present in the composition in a dry matter content of resin ranging from 8 to 40% by weight relative to the total weight of the composition, preferably ranging from 10 to 35% by weight and more preferably from 15 to 30% by weight relative to the weight of the composition (A). A. Copolymer based on silicone resin and dime-type silicone fhiconol. Such copolymers are described, for example, in "Silicone Pressure Sensitive Adhesive," Sobieski and Tangney, Handbook of Pressure Sensitive Adhesive Technology (D. Satas Ed.), Von Nostrand Reinhold, New York. In the copolymer, the silicone resin is present at a rate of between 45 and 75% (relative to the total mass of silicone) and the dimethiconol-type silicone is present at a rate of between 25 and 55%, with the sum of the percentages of silicone resin and dimethiconol-type silicone being equal to 100. Preferably, the silicone resin is present at a rate of between 55 and 65% (relative to the total mass of silicone) and the dimethiconol-type silicone is present at a rate of between 35 and 45%, with the sum of the percentages of silicone resin and dimethiconol-type silicone being equal to 100. Preferably, the silicone resin according to the invention is the condensation product of SiO groups and Rs(SiO) (triorganosilyl) groups for which each R group is independently selected from methyl, ethyl, propyl or vinyl radicals and for which the ratio between the SiO functions and the R3 (SiO) functions of the silicone resin ranges from 0.6 to 0.9. Triorganosilyl groups that can be used to form the silicone resin may be trimethylsilyl, triethylsilyl, methylmethylpropylsilyl, dimethylvinylsilyl units and mixtures thereof. The trimethylsilyl group is preferred in the context of the invention. Preferably, the dimethiconol-type silicone according to the invention is a diorganopolysiloxane with terminal OH functions having a viscosity of between 100 and 100,000 cst at 25°C for which the substituents of the diorganopolysiloxane are independently chosen from methyl, ethyl, propyl or vinyl radicals. The diorganopolysiloxanes are preferably linear polymers. Examples of diorganopolysiloxane may be, in a non-limiting manner, a polydimethylsiloxane, an ethylmethylpolysiloxane, a copolymer of dimethylsiloxane and methylvinylsiloxane, and mixtures of such polymers or copolymers having OH ends. The preferred diorganopolysiloxane is a polydimethylsiloxane. Examples of synthesis of such a copolymer are for example described in US patent 5,162,410 or in patent CA 711756. The copolymers according to the present invention can therefore be prepared by heating the following mixture: - from 45% to 75% by mass of silicone resin being the condensation product of the SiO units; and R(Si0),n for which each R group is independently selected from methyl, ethyl, propyl or vinyl radicals and for which the ratio between the SiO functions and the R3(Si0) functions of the silicone resin ranges from 0.6 to 0.9; - from 25% to 55% by mass of diorganopolysiloxane with terminal OH functions having a viscosity of between 100 and 100,000 cst at 25°C for which the substituents of the diorganopolysiloxane are independently chosen from methyl, ethyl, propyl or vinyl radicals; - from 0.001% to 5% of a suitable catalyst, which is preferably an organic aliphatic amine compound preferably chosen from primary amines, secondary amines, tertiary amines, carboxylic acid salts of the amines mentioned above and quaternary ammonium salts. The mixture is heated to a temperature between 80°C and 160°C until the adhesive character of the resulting silicone copolymer is obtained. The preferred copolymers according to the invention are those with the INCI name TRIMETHYLSILOXYSILICATE / DIMETHICONOL CROSSPOLYMER such as the products marketed by Dow Corning under the references DOWSIL FC 5002 ID RESIN GUM®, DOWSIL FC-5001 CM RESIN GUM®, DOWSIL FC 5004 RESIN GUM®, DOWSIL FC 5002 ID RESIN GUM® (Dow Corning Chemical Company); and more particularly DOWSIL FC 5002 ID RESIN GUM® / DOW CORNING. The composition according to the invention advantageously has a content of copolymer based on silicone resin and dimethiconol type silicone ranging from 0.2 to 60% by weight relative to the weight of the composition. Preferably, this content ranges from 1 to 30% by weight relative to the weight of the composition. More specifically, the copolymer(s) based on silicone resin and dimethiconol-type silicone may in particular be present in the composition according to the invention in a content greater than 1.0% and up to 40% by weight relative to the total weight of the composition, preferably ranging from 1.5 to 20% by weight, and preferably ranging from 1.5 to 15% by weight. Additives The compositions according to the invention may also comprise additives commonly used in care and / or makeup products such as lipophilic active ingredients, hydrophilic active ingredients such as vitamins, solar UV filters, moisturizing agents such as polyols such as glycerin, propanediol, pentylene glycol, liposoluble coloring materials; lipophilic thickening or gelling agents; hydrophilic thickening or gelling agents; preservatives, perfumes and mixtures thereof. Powdered coloring matter According to a particular form of the invention, the composition according to the invention additionally comprises at least one pulverulent coloring material. Powdered coloring materials can be chosen from mineral pigments, organic pigments, pearlescent agents and their mixtures. “Pigments” means white or colored particles, mineral or organic, insoluble in an aqueous medium, intended to color and / or opacify the composition and / or the resulting deposit. These pigments may be white or colored, mineral and / or organic. According to a particular embodiment, the pigments used according to the invention are chosen from mineral pigments. The term "mineral pigment" means any pigment that meets the definition in the Ullmann Encyclopedia in the inorganic pigment chapter. Among the mineral pigments useful in the present invention, mention may be made of zirconium or cerium oxides, as well as zinc, iron (black, yellow or red) or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue, titanium dioxide, metal powders such as aluminum powder and copper powder. The following mineral pigments may also be used: Ta:Os, Ti:Os, Ti 203, TiO, ZrO, in mixture with TiO,, ZrO, Nb:O;, CeO., ZnS. The size of the pigment useful in the context of the present invention is generally greater than 100 nm and can range up to 10 μm, preferably from 200 nm to 5 μm, and more preferably from 300 nm to 1 μm. According to a particular form of the invention, the pigments have a size characterized by a D

[50] greater than 100 nm and which can go up to 10 μm, preferably from 200 nm to 5 μm, and more preferably from 300 nm to 1 μm. The sizes are measured by static light scattering using a commercial particle size analyzer such as the Master Sizer 3000® from Malvern, which allows the particle size distribution of all particles to be determined over a wide range from 0.01 µm to 1000 µm. The data are processed based on the classical Mie scattering theory. This theory is most suitable for size distributions ranging from submicron to multimicron and allows the determination of an "effective" particle diameter. This theory is notably described in the work of Van de Hulst, HC, "Light Scattering by Small Particles", Chapters 9 and 10, Wiley, New York, 1957. D

[50] represents the maximum size that 50% of the particles have by volume. According to a particular form of the invention, the mineral pigment comprises a lipophilic or hydrophobic coating, the latter being preferably present in the oily phase of the composition according to the invention. According to a particular embodiment of the invention, the pigments can be coated according to the invention with at least one compound chosen from metallic soaps; N-acylated amino acids or their salts; lecithin and its derivatives; trisostearyl isopropyl titanate; isostearyl sebacate; natural vegetable or animal waxes; polar synthetic waxes; fatty esters; phospholipids; silicone surfactants such as organopolysiloxanes, alkylalkoxysilanes such as triethoxycaprylylsilane; fluorinated surfactants such as perfluoroalkyl phosphates, perfluoropolyethers, polytetrafluoropolyethylenes (PTFE), perfluoroalkanes, perfluoroalkyl silazanes, polyoxides hexafluoropropylene, polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups; fluoro-silicone surfactants such as perfluoroalkyl dimethicones, perfluoroalkyl silanes and perfluoroalkyl trialkoxysilanes; and mixtures thereof. According to a preferred embodiment, the pigments may be coated according to the invention with an N-acylated amino acid or one of its salts which may comprise an acyl group having from 8 to 22 carbon atoms, such as for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl, cocoyl group. The amino acid may be, for example, lysine, glutamic acid or alanine. The salts of these compounds may be aluminum, magnesium, calcium, zirconium, zinc, sodium or potassium salts. Thus, according to a particularly preferred embodiment, the pigments may be coated with an N-acylated amino acid derivative which may in particular be a glutamic acid derivative and / or one of its salts, and more particularly a stearoyl glutamate, such as, for example, aluminum stearoyl glutamate. Examples of pigments treated with aluminum stearoyl glutamate include titanium dioxide pigments and black, red and yellow iron oxide pigments sold under the commercial reference NAI® by the company MIYOSHI KASEI. According to a preferred embodiment, the pigments may be coated according to the invention with isopropyl triisostearyl titanate. Examples of pigments treated with isopropyl titanium triisostearate (ITT) include those sold under the commercial reference BWBO-I2® (Iron Oxide CI77499 and Isopropyl Titanium triisostearate), BWYO-I® (Iron Oxide CI77492 and Isopropyl Titanium Triisostearate) and BWRO-I2® (Iron Oxide CI77491 and Isopropyl Titanium Triisostearate) by the company KOBO. The pigments that can be used according to the invention can also be organic pigments. By "organic pigment" is meant any pigment that meets the definition of the Ullmann encyclopedia in the organic pigment chapter. The organic pigment may in particular be chosen from nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, quinophthalone compounds. The organic pigment(s) may be chosen, for example, from carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, phthalocyanine blue, sorghum red, the blue pigments codified in the Color Index under the references CI 42090, 69800, 69825, 73000, 74100, 74160, the yellow pigments codified in the Color Index under the references CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000, 47005, the green pigments codified in the Color Index under the references CI 61565, 61570, 74260, the pigments oranges codified in the Color Index under the references CI11725, 15510, 45370, 71105, the red pigments codified in the Color Index under the references CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915, 75470, and the pigments obtained by oxidative polymerization of indole derivatives,phenolics as described in patent FR? 679 771. , These pigments may also be in the form of composite pigments as described in patent EP1184426. These composite pigments may be composed in particular of particles comprising an inorganic core at least partially covered with an organic pigment and at least one binder ensuring the fixing of the organic pigments on the core. The pigment can also be a lake. Lake refers to insolubilized dyes adsorbed onto insoluble particles, the resulting mixture remaining insoluble during use. Inorganic substrates on which dyes are adsorbed include, for example, alumina, silica, calcium sodium borosilicate or calcium aluminum borosilicate, and aluminum. Organic colorants include cochineal carmine. Other products known under the following names include: D&C Red 21 (CI 45380), D&C Orange 5 (CI 45370), D&C Red 27 (CI 45410), D&C Orange 10 (CI 45425), D&C Red 3 (CI 45430), D&C Red 4 (CI 15510), D&C Red 33 (CI 17200), D&C Yellow 5 (CI 19140), D&C Yellow 6 (CI 15985), D&C Green (CI 61570), D&C Yellow 10 (CI 77002), D&C Green 3 (CI 42053), D&C Blue 1 (CI 42090). Examples of lakes include the product known as D&C Red 7 (CI 15850:1). Preferably, the composition according to the invention comprises at least one pulverulent coloring material of the mineral pigment type, in particular chosen from metal oxides, and more particularly chosen from titanium dioxides, iron oxides, coated or not, and their mixtures. Pearlescent pigments can be chosen from white pearlescent pigments such as mica coated with titanium or bismuth oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with in particular ferric blue or chromium oxide, titanium mica with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride. Preferably, the pulverulent coloring matter(s) is (are) present, preferably, in the composition in a content ranging from 5 to 40% by weight, preferably from 10 to 30% by weight, more particularly from 15 to 25% by weight relative to the total weight of the composition. Fat-soluble coloring matters A composition according to the invention may further comprise at least one liposoluble coloring matter and preferably in an amount of at least 0.01% by weight relative to the total weight of the composition. For the purposes of the invention, the term “liposoluble coloring matter” means any generally organic, natural or synthetic compound, soluble in an oily phase or solvents miscible with a fatty substance and capable of coloring. For obvious reasons, this quantity is likely to vary significantly with regard to the intensity of the desired color effect and the color intensity provided by the coloring materials considered and its adjustment clearly falls within the skills of those skilled in the art. As liposoluble dyes suitable for the invention, mention may in particular be made of liposoluble dyes, synthetic or natural, such as, for example, DC Red 17, DC Red 21, DC Red 27, DC Green 6, DC Yellow 11, DC Violet 2, DC Orange 5, Sudan red, carotenes (B-carotene, lycopene), xanthophylls (capsanthin, capsorubin, lutein), palm oil, Sudan brown, quinoline yellow, annatto, curcumin. Water-soluble coloring matters A composition according to the invention may further comprise at least one water-soluble coloring matter and preferably in an amount of at least 0.01% by weight relative to the total weight of the composition. For the purposes of the invention, the term "water-soluble coloring matter" means any generally organic, natural or synthetic compound, soluble in an aqueous phase or water-miscible solvents and capable of coloring. As water-soluble dyes suitable for the invention, mention may in particular be made of synthetic or natural water-soluble dyes such as, for example, FDC Red 4, DC Red 6, DC Red 22, DC Red 28, DC Red 30, DC Red 33, DC Orange 4, DC Yellow 5, DC Yellow 6, DC Yellow 8, FDC Green 3, DC Green 5, FDC Blue 1, betanin (beetroot), carmine, copper chlorophyllin, methylene blue, anthocyanins (enocyanin, black carrot, hibiscus, elderberry), caramel, riboflavin. Cosmetic compositions The present invention also relates to a cosmetic composition comprising, in a physiologically acceptable medium, a composition as defined above. By “physiologically acceptable medium” is meant a medium particularly suitable for the application of a composition of the invention to the skin. The physiologically acceptable medium is generally adapted to the nature of the support on which the composition is to be applied, as well as to the aspect in which the composition is to be packaged. The compositions of the invention may be in the form of milks, creams or gels. Applications According to one embodiment, a composition of the invention may advantageously be in the form of a composition for caring for the skin, body or face, in particular the face. According to another embodiment, a composition of the invention may advantageously be in the form of a makeup composition for keratin materials, in particular the skin of the body or face, in particular the face. Thus, according to a sub-mode of this embodiment, a composition of the invention can advantageously be presented in the form of a base composition for makeup. A composition of the invention may advantageously be presented in the form of a foundation. Such compositions are in particular prepared according to the general knowledge of those skilled in the art. Throughout the description, including the claims, the expression "comprising a" should be understood as being synonymous with "comprising at least". The invention is illustrated in more detail by the examples and figures presented below. Unless otherwise indicated, the quantities indicated are expressed as a mass percentage. E 2 to 7 (invention) 1 and 8 (excluding invention) The following compositions were prepared. [Tables 1] [Ingredients Exl |Ex2 |Ex3 Ex4 Ex5 Ex6 Ex7 Ex8 excluding |inventi|inventi |inventi |inventi |inventi |inventi [excluding inventijon on on on on on inventi| on on ISODODECA |10. 25 3 34 10 20 13 20 NE (and) (either |(either |(either (either (either (either (either HEXYL / SUC |3% in |0.75% |1% in |10.2% |3% in |J6% in 13.9% |6% in CINYL DI- |matter |in matter in matter [matter |in matter METHICONE |dry |matter |active |active Jactive active |matter |dry CROSSPOLY |of e dry |of active |of active |of MER polym |of polym |of polym |of polym |of polym | (DOWSIL ELjère) |polym |re) polymer |re) polymer |re) 7314 ère) re) re) SILICONE ELASTOMER BLEND® / DO W CORNING. under gel form in dispersion at 30% by weight | in isododecane) | pop 24 es qe |1s pe qe Je 8 NE ms | [1 [1 E [1 [1 [1 [1 SILOXYSILI CATE at 75% in isododecane WATER pr Jo Jo Jo qe Jo Jo DISTILLED [A]=[ 0.096 [0.088 jo.108 (0.261 jo.185 [0.258 [0.254 [0.242 ratio of the 0.90 |o90 |o50 joso [070 |os0 |050 [0.06 [0.08 [0.10 [0.13 jo.15 [0.18 [0.20 [0.22 Protocol for preparing compositions The manufacturing of examples 1 to 8 was carried out using a Trilab® or Olsa Minilab® type reactor from VMI. The temperature was set to 20°C in order to maintain a manufacturing temperature of 20°C. The elastomer was pre-dispersed under shear. Isododecane was then gradually added to the elastomer until a homogeneous composition was obtained. Trimethylsiloxysilicate was then added, forming the fatty phase. The macroscopically homogeneous mixture of the phases was prepared by slowly introducing the aqueous phase into the fatty phase at a stirring speed of 4000 RPM for 15 minutes. The formula was then debottled under vacuum. Evaluation of the stability of the compositions All compositions of Examples 1 to 8 were packaged in a 30mL glass jar at room temperature (25°C). Stability was observed visually and evaluated at 24h in accordance with the following criteria: Stable: The composition is homogeneous without visible phase separation. Unstable: The composition is not homogeneous (visible phase separation). The results are described below: [Tables 2] Stability at |Ex1 |Ex2 |Ex3 |Ex4 |Ex5 |Ex6 |Ex7 |Ex8 24 hours |off |inventi|inventi |inventi [inventi [inventi |inventi [off inventijon on on on on on inventi| on on [Aspect Instabl [Stable |Stable |Stable |Stable [Stable |Stable |Instabl | ee [AIX[B] [0.06 |0.08 0.10 0.13 0.15 jo.18 0.20 [0.22 Examples 2 to 7 according to the invention having a product [A]X[B] ranging from 0.07 to 0.21 made it possible to obtain a pleasant texture, easily removed and spread on the skin, presenting a fresh and light sensation during application and good stability over time. Examples 1 and 8 outside the invention having a product [A]X[B] outside the range from 0.07 to 0.21 dephased after 24 hours and were considered unstable.

Claims

Claims

1. Composition for care and / or makeup of keratin materials, in particular the skin, comprising, preferably in a physiological medium- logically acceptable: a) an oily phase comprising at least one hydrocarbon oil volatile H, ; and (b) an aqueous phase; and c) at least one silicone elastomer with carboxylic acid functions; said composition having a product of weight ratios [A] X [B] ranging from 0.07 to 0.21 with [A] denoting the weight ratio of the amount of silicone elastomer relative to the total weight of the composition over the total quantity of volatile hydrocarbon oil(s) relative to the total weight of the composition ; [B] denoting the weight ratio of the quantity of aqueous phase per ratio to the total weight of the composition; said oily and aqueous phases forming a macro-mixture therein even stinging.

2. A composition according to claim 1, or the volatile hydrocarbon oil H, is chosen from Cz-C;5 isoalkanes of petroleum origin (also called isoparaffins), and more particularly isododecane.

3. Composition according to claim 1, or the volatile hydrocarbon oil H, is chosen from volatile linear alkanes comprising from 6 to 14 carbon atoms.

4. A composition according to claim 3, or the volatile hydrocarbon oil H, is: - a mixture of n-dodecane and n-tetradecane; - a mixture of volatile linear C9-C12 alkanes with INCI name: C9-12 ALKANE; or - a mixture of n-undecane (C1 1) and n-tridecane (C13).

5. Composition according to any one of the preceding claims, where the oily phase is present in an amount ranging from 5 to 95% in weight, and more preferably from 10 to 90% by weight relative to the total weight of the composition.

6. A composition according to any preceding claim, wherein water is present in a concentration ranging from 5 to 95% by weight, and more particularly from 10 to 90% by weight, relative to the total weight of said composition.

7. A composition according to any preceding claim, wherein the aqueous phase is present in a concentration ranging from 5 to 95% by weight, and more particularly from 10 to 90% by weight, relative to the total weight of said composition.

8. Composition according to any one of the preceding claims, comprising an active ingredient content of silicone elastomer carboxylic acid functions ranging from 2 to 25% by weight, preferably ranging from 5 to 20% by weight relative to the weight of the com- position.

9. A composition according to any preceding claim, wherein the weight ratio of the total quantity of volatile oil(s) hydro- carbonaceous(s) relative to the total weight of the composition] on the quantity of aqueous phase relative to the total weight of the composition is greater than 0.085

10. | A composition according to any preceding claim, wherein the silicone elastomer with carboxylic acid functions is chosen among those corresponding to the following formula (I): R°SI-O-(SIR RE-CL,(SIR"-O-LISIR R°-0-1,SIR*, x Ç 0 And, 4 R°,SI-O-[SIRR"*-04219IR 0-4, 1SIR"R*04 SRE th in which the radical X corresponds to formula (i) or to formula (i') next: g ® RE_CWY-W"GX pit > con Hoe”” oO Q di Oo 2 rmafhrerr its «pre call > put back #5— — F——0u ris TS LT HO to 2 2 Q pu 2 RE CWY-WOS__ laughed. > con Ho” Ô 2 G) in which W and W* independently denote an oxygen atom (O) or an NR group where each radical R independently denotes a hydrogen atom (H) or an R' radical; Y is a divalent group; R!, R!, R4, R'4, R5 and R!* independently denote a substituted or unsubstituted hydrocarbyl group; R* and R'* independently denote a divalent group; w and ww are independently integers ranging from 0 to 1000; x and xx are independently integers ranging from 1 to 100; y and yy are independently integers ranging from 0 to 1000; preferably, w and y are not simultaneously equal to 0 and ww and yy are not simultaneously equal to 0.

11. Composition according to claim 7, wherein the silicone elastomer of formula (I) is chosen from the following compounds 1 to 12: Tu TS LR 25 1 05 126 ne-pro-Hirodtrot{-t-o4r0n ÊH, Y 0H, w ï x CH, f #Æ- C = Gh, Pt Th era PB Lerrehres 9 Ÿ y years QC +* / 1e Qa 20 di ju + SK, frs ' qe LE ottpmo 1b-ot4 ho-—ÿro-to-i8-0-1{-8-0}-8=0i CH, ÙH Ÿ Oh Ÿ CH, * CH, (compound 1) se ES 7e, T5 54 He-ÿ-o-{-8p0-H-850-H{g-0-}-5-0H, ÊH, > + x CH, WCH, > {> 4 a À 255 kc-gro-hsro-Hroi-Fsro-i-sron, Gt, ÊH, w ù& x CH TOH (compound 2) in EE CA 1 GE Herfrodero-Hi-eco{-dro-d-fccn CH, Y} x CH, WCH, # > L° 2 # j ; = HO & “which is or fe Ve CA Car from V5 H,C-io-Hs-oH-si-ot{-si-o-8i-cH, 15 Si-0-1 CH, CH, w@ 7H, X CH, YCH, (compound 3) it ss sn, = é, Et e He-si-e- $r-0 jte scoeb-$rt +8 4) CR, * gx CH W CH, : and PA - ° WwW TH XX ' Ho u Ta» of "0450 - GH, CH, y ( _ 0 #eso-hs-oH S-0H1-8i-07-8-0H, ÊH, CH, W CH x CH, YCH (compound 4) 4 54 LH, Fa , 56 H,C-8imo-8 pottfrosHfrote OH, Gti, a ; _ Ê > 3 % Yes, { <, NN 7 ; 7 different methods H, CH — QH ÊH, CH, Y wx (compound 5) th, 6H, Phase w 0 metro Hrotefro trot is NL OH w Lx CR < χ ES faith - ; Lu me Pt ​​er rare M ên, Ÿ CH W £n *% ên, (compound 6) PET it 7 He-8-0-Harponpi-see-bLu8t0-buéten ' Le FA H ta, + T Fe ' * or % ; SH Ho / 0-4 # Sp re qe € pH H,9-—"8i—0-5- sn T1 hf ÿrror}Sren, CH, CH Ÿ OH WW OCH OX CH (compound 7) rte per ÿs T4 $He Fre-réco-Hgira-it= : $-ott-on, fcornpach 5} DH + CH W | xXêH, and. 94 4, , GR çH, notre tdottdi Li obéir, SH, + ÜH, WW $ QH, X _f 3 # He : ao--É--0H, $ $ H,6——5-—CH, was CES E…20, RES ; Hey” > " with HA sad <> $ < and NES 2 ri gs 4 1 HeproPprotri=oFtpro-tfron CH, CH, Ÿ ÊK Ÿ OÛHR, XCH, çH, gs Hz and H,0<8i<0-{<-04-6i-0—H—8i-05-SI-CH, 2H, € x 2H, w * OH, s * qe PA * £ se 5 os go Fosr 504 ; 164, EH, OH, Ÿ CH, W OM Ÿ* CH, (compound 9) He 35 ,; SH, The ; en, nfrotéotts “a-}-ÿr0-}- $CH, OH, 7 OY CH W CU XX to Le odirothgotté-ot4; »e—ÿ-0-{#-0-}{;#-0-{-5-0-i-5-0, être 7 64 U OL ŸUH $C Re (CH )2H1CÇ0) ZE (CH n77$-9-$i-0= SITHEM ga [CHOT mi HQ2s CH, ÊH, CH | CH, (compound 10 pme re p # cmt ) Hi Sin EE + 4 a 7 sr C Air + a = 20 WRITE Ÿ CE * to T cmebuens +4 + ; : + 4.4 = a 4 ea” 4, NE $ 2 8 ppp ETS 5 for SSI + ri sacs ; —® mecs - *e Has j Cas Rs $ € with Bert £n 0H (compound 11) NE PP A EE me-é-o-h8-04F4m0 profit pots CH, ok, < YO ÊM w À XCH, fie H,0-6f-0h, weighed H,6-——6{-——0ht, Ps x H6-—"3"01E èH VO CR Y ÈH CH, mot 4" en, CH, H, Pa ui ui 1 ep som Ho-ts-=-0h, ÊR, OH YOU VO CH *R, (compound 12)

12. A composition according to claim 11, wherein the carboxylic acid functional silicone elastomer is compound 10 or compound 11.

13. A composition according to any one of claims | to 9, wherein the silicone elastomer with carboxylic acid functions is that of INCI name: HEXYL / SUCCINYL DIMETHICONE CROSSPOLYMER.

14. A composition according to any preceding claim, wherein the carboxylic-functional silicone elastomer is dispersed in at least one oil H, and in gel form; preferably chosen from volatile hydrocarbon oils, volatile silicone oils, and their mixtures.

15. A composition according to claim 14, wherein the oil H, is a hy- volatile carbon selected from those defined for oil H, in any one of claims | to 4.

16. A composition according to claim 14 or 15, wherein oil H, and oil H, are identical, in particular denote isododecane.

17. | A composition according to any one of claims 14 to 16, wherein the oily dispersion of silicone elastomer with carbo-acid functions carboxylic acids comprise 10 to 40% by weight of active ingredient of silicone elastomer, and more preferably 20 to 35% in weight relative to the total weight of the oily dispersion.

18. A composition according to any one of claims 14 to 17, wherein the silicone elastomer with carboxylic acid functions is in dispersion in isododecane and in gel form.

19. A composition according to claim 12, wherein the silicone elastomer has carboxylic acid functions is compound 10 or compound 11 and present in the isododecane-based dispersion at a matter content active 30% by weight.

20. Composition according to claim 13, comprising at least silicone elastomer in gel form dispersed in isododecane having the INCI name: ISODODECANE (and) HEXYL / SUCCINYL DIMETHICONE CROSSPOLYMER, and more particularly exclusively at an active ingredient content of 30% by weight in the dispersion based on isododecane.

21. Composition according to any one of the preceding claims, further comprising at least one silicone resin and / or at least one co- polymer of silicone resin and dimethiconol type silicone.

22. Composition according to claim 21, wherein the silicone resin is a MQ resin, and more particularly of the Trimethylsiloxysilicate type.

23. Composition according to claim 21, where the resin copolymer co- silicone resin polymer and dimethiconol type silicone is a copolymer with INCI name: TRIMETHYLSILOXYSILICATE / DIME- THICONOL CROSSPOLYMER.

24. A composition according to any preceding claim, additionally comprising at least one additive chosen from UV filters solar; C2-C4 monoalcohols such as ethanol, hy- dratants such as polyols such as glycerin, propanediol, pen- tylene glycol; powdery coloring matters, co- lipophilic thickening or gelling agents; preservatives, perfumes and their mixtures.

25. | Process for coating keratin materials, more particularly makeup and / or care of keratin materials, such as skin, characterized in that it comprises the application to keratin materials tinics of a composition as defined in any one of the previous claims,