Residual mixture, perfumed composition comprising the mixture, and perfumed alcoholic solution

Abstract

The invention relates to a residual fragrance mixture comprising 30% disopropyl sebacate and 70% triheptanoin, the percentages being by weight of the total weight of the mixture. The invention also relates to a fragrance composition according to the preceding claim comprising from 5% to 30% of the residual fragrance mixture by weight of the total weight of the fragrance composition. Finally, the invention relates to a fragrance solution comprising alcohol as a diluent and from 3% to 30% of the fragrance composition by weight of the total weight of the fragrance solution. The invention is applicable in the fields of perfumery, cosmetics, detergents, and home fragrance to improve the lasting effect of the fragrance on any surface, whether skin, hair, or textiles.

Description

Title of the invention: Long-lasting mixture, perfumed composition comprising the mixture, and perfumed alcoholic solution. Technical field

[0001] The present invention relates to a fragrance longevity optimization mixture, a perfumed composition comprising the mixture, and a perfumed alcoholic solution comprising said composition. The invention finds particular application in the fields of perfumery, cosmetics, detergents, and home fragrance to improve longevity on any surface, such as skin, hair, or textiles. STATE OF THE ART

[0002] Improving the potency and longevity of perfumes is a constant challenge in the perfume industry. Consumers expect a product that delivers not only functional performance over time, but also emotional performance through fragrance.

[0003] Perfumes are commonly formulated in compositions containing alcohol as a solvent or diluent. Alcohol has the advantage and disadvantage of carrying aromatic molecules with it when it evaporates. The aromatic molecules are thus quickly absorbed by the user. However, the strength of the perfume diminishes rapidly and the fragrance does not last long.

[0004] Conversely, mixtures known in the state of the art for providing lasting power to perfumes, such as polycitronellol or sucrose acetate isobutyrate, tend to sequester the top notes, meaning that the intensity of the perfume is diminished a few seconds after application. Furthermore, existing solutions can cause changes in the olfactory profile of the perfume.

[0005] Moreover, at present, regulations relating to chemical compounds are constantly evolving and users are increasingly looking for natural products that comply with COSMOS type standards.

[0006] The present invention aims to provide a solution that optimizes the longevity of perfumes and meets these new requirements.

[0007] The other objects, features and advantages of the present invention will become apparent from an examination of the following description and accompanying drawings. It is understood that other advantages may be incorporated. SUMMARY

[0008] To achieve this objective, according to one embodiment, a residual mixture is provided comprising 30% of disopropyl sebacate, and 70% of triheptanoin, the percentages being by weight of the total weight of the mixture.

[0009] The selection of the compounds of the mixture according to the invention made it possible to obtain a very good residual fragrance efficiency of a perfumed composition or of a perfumed alcoholic solution in which it can be integrated.

[0010] According to another aspect, the invention relates to a perfumed composition comprising the residual mixture.

[0011] According to another aspect, the invention relates to a perfumed alcoholic solution comprising alcohol as a diluent and 3% to 30% perfume composition, by weight of the total weight of the perfumed alcoholic solution. BRIEF DESCRIPTION OF FIGURES

[0012] The aims, objects, features and advantages of the invention will become clearer from the detailed description of an embodiment thereof, which is illustrated by the following accompanying drawings in which:

[0013] [Fig.1] Fig.1 represents the results of the triangular tests at t=0 of example 3.

[0014] [Fig.2] Fig.2 represents the results of the skin test of the perfumed composition floral after 2 hours, according to example 4.

[0015] [Fig.3] Fig.3 represents the results on skin of the floral perfume composition after 4 hours, according to example 4.

[0016] [Fig.4] Fig.4 represents the results on skin of the floral perfume composition after 8 a.m., according to example 4.

[0017] [Fig.5] Fig.5 represents the results of the skin test of the perfumed composition citrusy after 2 hours, according to example 4.

[0018] [Fig.6] Fig.6 represents the results on skin of the perfumed composition citrus after 4 hours, according to example 4.

[0019] [Fig.7] Fig.7 represents the results on skin of the perfumed composition citrus after 8 a.m., according to example 4. DETAILED DESCRIPTION

[0020] Before proceeding with a detailed review of embodiments of the invention, optional features that may be used in combination or alternatively are listed below:

[0021] According to one example, the perfumed composition comprises from 5% to 30% of the residual mixture by weight of the total weight of the perfumed composition;

[0022] According to one example, the perfumed composition comprises 10% of the residual mixture by weight of the total weight of the perfumed composition.

[0023] According to one example, the perfumed alcoholic solution comprises alcohol as a diluent and 3% to 30% of the perfume composition, by weight of the total weight of the perfumed alcoholic solution. In another possibility, the alcoholic solution also comprises water as a diluent. By way of example, the alcohol is selected from ethanol, isopropanol, methoxymethylbutanol, and other diluents such as glycol ethers, for example, dipropylene glycol methyl ether.

[0024] According to one example, the perfumed alcoholic solution comprises 15% perfumed composition by weight of the total weight of the perfumed alcoholic solution.

[0025] According to another aspect, the invention relates to a cosmetic base comprising the perfumed mixture or composition or the alcoholic solution.

[0026] According to another aspect, the invention relates to a detergent base comprising the perfumed mixture or composition or the alcoholic solution.

[0027] According to another aspect, the invention relates to a toilet water comprising the perfumed mixture or composition or the alcoholic solution.

[0028] According to another aspect, the invention relates to the use of the mixture or the perfumed composition or the alcoholic solution to improve the longevity of a perfume.

[0029] A parameter "approximately equal to / greater than / less than" or "of the order of" a given value means that this parameter is equal to / greater than / less than the given value, to within 10% or even 5% of that value.

[0030] For the purposes of this disclosure, the expression "A and / or B" means (A), (B) or (A and B). For the purposes of this disclosure, the expression "A, B and / or C" means (A), (B), (C), (A and B), (A and C), (B and C), or (A, B and C).

[0031] According to the invention, "mixture" and "residual mixture" refer to a mixture comprising diisopropyl sebacate and triheptanoin. For the purposes of the present invention, "mixture" and "residual mixture" shall be used interchangeably.

[0032] By "composition" is meant a composition comprising the mixture according to the invention. Typically, this composition is a perfumed composition.

[0033] The term "perfume composition" means a composition comprising a mixture of perfume substances, said perfume substances being in an isolated state, in solution or in suspension, in their usual diluents, solvents or co-ingredients. Such a composition is intended to provide a pleasant olfactory component. A perfume composition may also be called a perfume.

[0034] By "pleasant odor" is meant an odor which is detected by the human sense of smell and which is perceived as pleasant.

[0035] By "alcoholic solution" is understood a solution which includes alcohol as a solvent or diluent which may or may not be supplemented with water to form a hydroalcoholic solution.

[0036] By “perfuming substance” is meant one or more perfumed raw materials of natural or synthetic origin.

[0037] By "stable" is meant a composition that does not degrade over time and whose components do not react with each other. By "stable" is meant that the homogeneity, color, olfactory intensity, olfactory quality, and / or viscosity of the composition are maintained. More specifically, the composition according to the present invention is stable under accelerated aging after 24 hours under UV light (Suntest) and after 2 months at 25°C and 45°C compared to a sample kept at 5°C, protected from light.

[0038] Percentages are understood as mass percentage, that is to say, weight relative to a weight of the complex or composition.

[0039] The present invention relates to a mixture comprising diisopropyl sebacate and triheptanoin. Advantageously, the mixture consists of diisopropyl sebacate and triheptanoin.

[0040] Diisopropyl sebacate is a compound of CAS No.: 7491-02-3, EINECS No.: 231-306-4 and IUP name AC: l,10-bis(propan-2-yl) decanedioate.

[0041] Triheptanoin is a compound of CAS No.: 620-67-7, EINECS No.: 210-647-2 and IUP name AC: 1,3-bis(heptanoyloxy)propan-2-yl heptanoate or 2,3-di(heptanoyloxy)propyl heptanoate or propane-1,2,3-triyl triheptanoate or Propane-1,2,3-triyl triheptanoate.

[0042] Advantageously, it has been identified that the mixture comprising 30% diisopropyl sebacate and 70% triheptanoin, the percentages being by weight of the total weight of the mixture, exhibits very good residual olfactory profile efficacy of a composition in which it is incorporated.

[0043] The mixture according to the invention is advantageously an emollient mixture. Being emollient, the mixture improves the longevity of the fragrance without sequestering the top notes, as is the case with prior art compositions which are film-forming.

[0044] Preferably, the mixture consists of 30% diisopropyl sebacate and 70% triheptanoin, the percentages being by weight of the total weight of the mixture.

[0045] The compounds of the residual mixture are not classified according to EC Regulation No. 1272 / 2008.

[0046] According to a preferred possibility, the mixture is used in a composition.

[0047] The invention relates to an advantageously perfumed composition comprising the mixture as described above.

[0048] The composition comprises from 5% to 30% of the mixture by weight of the total weight of the composition.

[0049] By way of example, the composition comprises 10% of the mixture by weight of the total weight of the composition, i.e. 3% of diisopropyl sebacate and 7% of triheptanoin, the percentages being by weight of the total weight of the composition.

[0050] The composition is advantageously a perfumed composition, that is to say a composition comprising one or a mixture of perfumed substances also generically referred to as perfume.

[0051] According to a preferred embodiment, the perfumed composition comprises the residual mixture, preferably from 5 to 30% and one or a mixture of perfume substances or perfume, preferably in an amount between 70% and 95%, optionally additives may be added.

[0052] Advantageously, the mixture and composition are stable.

[0053] A perfumed composition according to the invention may include esters, ethers, alcohols, aldehydes, ketones, lactones, acetals, nitriles, phenols, acids, terpenes, nitrogenous or sulfurous heterocyclic compounds, saturated or unsaturated, and products of natural origin.

[0054] Examples of esters include, but are not limited to, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, phenylethyl acetate, l,l-dimethyl-2-phenylethyl acetate, linalyl benzoate, ethylmethylphenyl glycinate, allylcyclohexyl propionate, styrallyl propionate, benzyl salicylate, methyl-3-oxo-2-pentylcyclopentane acetate, prop-2-enyl-2,3-methylbutoxy acetate (allyl amyl glycolate, 2-propenyl ester of 3-methylbutoxyacetic acid), phenylmethyl ester of acetic acid, isoamyl acetate (isopentyl acetate), acetate of cis-hex-3-enyl ((Z)-hex-3-enyl acetate), citronellyl acetate (3,7-dimethyl-6-octen-l-ol acetate), hexyl acetate, isobomyl acetate (bicyclo[2.2.1]heptan-2-ol,l,7,7-trimethyl exo-acetate), methanyl acetate (alpha,alpha,4-trimethylcyclohexylmethyl acetate), ethyl acetate,prenyl acetate (3-methyl-2-butenyl acetate), terpenyl acetate (4-methyl-1-propan-2-yl-1-cyclohex-2-enyl acetate), alpha-3,3-trimethylcyclohexylmethyl formate, 3-methylbutyl butanoate (isoamyl butyrate), alpha,alpha-dimethylphenethyl butanoate, 3-dihydrodicyclopentadien-2,3-yl prop-2-enyl acetate, 3-cyclohexyl propanoate (allyl cyclohexane propionate), allyl heptanoate (2-propenyl heptanoate), 2-phenoxyethyl 2-methylpropanoate (phenoxyethyl isobutyrate), ethyl 2-methylpentanoate, ethyl 2-methylbutyrate (ester ethyl of 2-methylbutanoic acid), l,4-dioxacycloheptadecane-5,17-dione (ethylene brassylate), (2S)-2-propyl-l,l-dimethylpropoxy propanoate ((2S)-Propyl ester of 2-(l,l-dimethylpropoxy)-propanoic acid), 2-tert-butylcyclohexyl acetate (2-(l,l-dimethylethyl)cyclohexyl acetate), salicylate of, ci-3-hexenyl, [(lS)-3-(4-methylpent-3-enyl)-l-cyclohex-3-enyl]methyl acetate, 3-pentyltetrahydro[2H]pyranyl acetate, linalyl propionate, cedryl acetate, anisyl acetate, nopyl acetate, neryl acetate, 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate, 3a,4,5,6,7,7a-hexahydro-4,7-methano-lH-inden-6-yl propanoate, 2-propenyl 3-cyclohexanepropanoate, 1,2,3-triethyl 2-hydroxypropane-l,2,3-tricarboxylate, acetate (2E)-3,7-dimethylocta-2,6-dien-l-yl, 3,5,5-trimethylhexyl acetate, 3,7-dimethyl-octa-l,6-diene-3-yl acetate, cis-3,7-dimethyl-2,6-octadienyl ethanoate, 1-methylethyl ester of tetradecanoic acid, 3-methylbutyl ester of 2-hydroxybenzoic acid, phenylmethyl ester of 2-hydroxybenzoic acid, 2-hexyl ester of 2-hydroxybenzoic acid, methyl ester of 2-hydroxybenzoic acid, ethyl ester of acetoacetic acid, 3,7-dimethyl-octa-l,6-dien-3-yl acetate, ester 1,2-Diethyl 1,2-benzenedicarboxylic acid, (Z)-hex-3-enyl 2-methylpropanoate, (4-methyl-1-propan-2-yl-1-cyclohex-2-enyl acetate, 3α,4,5,6,7,7α-hexahydro-4,7-methanoinden-6-yl acetate, ethyl 2,3-epoxy-3-phenylbutyrate, methyl 2-aminobenzoate, methyl 2-(methylamino)benzoate, methyl benzoate, methyl 2,4-dihydroxy-3,6-dimethylbenzoate, (3R-(3α,3β,6β,7β,8α))-octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3α,7-methanoazulene acetate, and salicylate of hexyl. Preferably, examples of esters include, but are not limited to, linalyl propionate, cedryl acetate, anisyl acetate, nopyl acetate, neryl acetate, (3R-(3alpha,3beta,6beta,7beta,8alpha))-octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methanoazulene and hexyl salicylate.

[0055] Examples of ethers include, but are not limited to, benzyl ether, ethyl ether, ambergris, diphenyl oxide, 4,6,6,7,8,8-hexamethyl-l,3,4,6,7,8-hexahydrocyclopenta[g]isochromene, carane amber, l,l-dimethoxy-2,2,5-trimethyl-4-hexene, (ethoxymethoxy)cyclododecane, (E)-l-methoxy-4-(l-propenyl)-benzene, l-methoxy-4-(2-propenyl)-benzene and 2-naphthyl ethyl ether. Preferably, examples of ethers include, but are not limited to, 1,1-dimethoxy-2,2,5-trimethyl-4-hexene and 2-naphthyl ethyl ether.

[0056] Examples of alcohols include, but are not limited to, menthol ([1R-(lalpha,2beta,5alpha)]-5-methyl-2-isopropylcyclohexanol), citronellol, geraniol, linalool (e.g., ethyl linalool and tetrahydro linalool), phenylethyl alcohol, terpineol, 2,6-dimethylheptan-2-ol, 2-methyl-l-phenylpropan-2-ol (dimethyl phenyl carbinol), 3-methyl-5-[2,2,3-trimethylcyclopent-3-en-l-yl]pent-4-en-2-ol, 2-phenylethanol, 2-ethyl-4-(2,2,3-trimethyl-l-cyclopent-3-enyl)but-2-en-l-ol, (E)-4-methyldec-3-en-5-ol, alcohol cinnamic acid (3-phenyl-2-propen-l-ol), 2,6-dimethyloct-7-en-2-ol, alpha,beta,2,2,3-pentamethylcyclopent-3-ene-l-butanol, 3-(5,5,6-trimethylbicycl o[2.2.1]hept-2-yl) cyclohexan-l-ol (IBCH), cis-3-hexen-l-ol, methyl-trimethylbicyclo-hexylmethyl-cyclopropyl methanol benzyl alcohol, endo-l,7,7-trimethyl-bicyclo-[2.2.1]heptan-2-ol, 3,7-dimethyl-6-octen-l-ol, 3,7-dimethyl-l-octanol, (2E)-3,7-dimethyl-2,6-octadien-l-ol, cis-3,7-dimethyl-2,6-octadien-l-ol, 3,7-dimethyl-octa-l,6-diene-3-ol, 2-(4-methyl-l-cyclohex-3-enyl)propan-2-ol, 4-methyl-l-(l-methyl thyl)-3-cyclohexen-l-ol, (IR, 2S, 5R)-5-methyl-2-(l-methylethyl)-cyclohexanol, (2E)-3,7-dimethyl-2,6-octadien-l-ol and 3-methylbutan-l-ol. Preferably, examples of alcohols include, but are not limited to, alpha,beta,2,2,3-pentamethylcyclopent-3-ene-1-butanol, 3-(5,5,6-trimethylbicyclo[2.2.l]hept-2-yl)cyclohexan-l-ol (IBCH), cis-3-hexenol, methyl-trimethylbicyclo-hexylmethyl-cyclopr opyl methanol, 3-methylbutan-l-ol, ethyl linalool, tetrahydro linalool and [1R-(lalpha,2beta,5alpha)]-5-methyl-2-isopropylcyclohexanol (menthol).

[0057] Examples of aldehydes include, but are not limited to, linear alkanals comprising between 8 and 18 carbon atoms, citral, citronellal, cyclamen aldehyde, hydroxycitronellal, 3-(4-tert-butylphenyl)-2-methylpropanal, 3-(4-tert-butylphenyl)propanal, 2,6,1O-trimethylundec-9-enal, 4(octahydro-4,7-methano[5H]inden-5-ylidene)butanal, 3-(3-propan-2-ylphenyl)butanal, 7-hydroxy-3,7-dimethyloctanal (hydroxycitronellal, 3,7-dimethyl-7-hydroxy-octane-1-al), 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde, octahydro-5-methoxy-4,7-methano-1H-indene-2-carboxaldehyde, alpha-methylcinnamic aldehyde (2-methyl-3-phenyl-2-propenal), 4-methoxybenzaldehyde (anisic aldehyde), C10 aldehyde (decanal), undec-10-enal, C12 aldehyde (lauric or dodecanal), methylnonyl acetaldehyde (2-methylundecanal), C6 aldehyde, C6 aldehyde (hexanal), cinnamic aldehyde (3-phenyl-2-propenal), 3-ethyloxy-4-hydroxybenzaldehyde (ethylvanillin),hexyl cinnamic aldehyde (2-benzylideneheptanal), 3-phenylbutanal (3-phenylbutyraldehyde), 2,4-dimethylcyclohex-3-ene-l-carbaldehyde, 5-heptanal, 2,6-dimethylhept-5-enal, 4-hydroxy-3-methoxybenzaldehyde (Vanillin), alpha-methyl-1,3-benzodioxole-5-propionaldehyde, 4-isopropylbenzaldehyde, 3,7-dimethyl-6-octenal, 3,7-dimethyl-2,6-octadienal, 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-l-carboxaldehyde, trans-hex-2-enal, 2,4,6-trimethyl-3-cyclohexene-l-carboxaldehyde, 2-(4-tert-butylbenzyl)propionaldehyde and benzaldehyde. Preferably, examples of aldehydes include, but are not limited to, 2,4-dimethylcyclohex-3-ene-l-carbaldehyde, 5-heptanal, 2,6-dimethyl-hept-5-enal, 4-hydroxy-3-methoxybenzal dehyde (vanillin), alpha-methyl-l,3-benzodioxole-5-propionaldehyde, and benzaldehyde.

[0058] Examples of ketones include, but are not limited to, ionones, isomethylionone, methyl cedryl, (E)-l-(2,6,6-trimethyl-l-cyclohex-2-enyl)but-2- en-1 -one (alpha-damascone), 3-methyl-2-[(2Z)-pent-2-en-1 -yl]cyclopent-2-en-1 -one (cis-jasmone), 4-(4-methoxyphenyl)-butan-2-one, 4(3)-(4-methylpent-3-enyl)cyclohex-3-enecarbaldehyde, methyl cedryl ketone, 7-methylbenzo[b][l,4]dioxepin-3-one, l,7,7-trimethylbicyclo[2,2,l]heptan-2-one, l-benzopyran-2-one (Coumarin), l-(2,6,6-trimethyl-l-cyclohex-3-enyl)but-2-en-l-one, butan-2,3-dione (Diacetyl), l-(l,2,3,4,5,6,7,8-octahydro-2,3,8,8,-tetramethyl-2-naphthyl)ethan-l-one, irones, l-(2-naphthalenyl)ethanone (2-acetonaphtone), menthone, carvone, 3-methyl-2-pentyl-2-cyclopentenone, l-(2,6,6-trimethyl-3-cyclohexen-l-yl)-2-buten-l-one, 1-(2,6,6-trimethyl-2-cyclohexenyl)hepta-1,6-dien-3-one, 2-ethyl-3-hydroxy-4H-pyran-4-one, (5R)-2-methyl-5-prop-1-en-2-ylcyclohex-2-en-1-one, 1 -(6-tert-butyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl)ethanone, l-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-l-one, 4-(2,6,6-trimethylcyclohex-2-enyl)-but-3-ene-2-one, octan-2-one and 1,3,4,6,7,8a-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalen-8(5H)-one. Preferably, examples of ketones include, but are not limited to, irones, l-(2-naphthalenyl)ethanone (2-acetonaphtone), menthone, carvone, 3-methyl-2-pentyl-2-cyclopentenone and l,3,4,6,7,8a-Hexahydro-l,l,5,5-tetramethyl-2H-2,4a-methanonaphthalen-8(5H)-one.

[0059] Examples of lactones include, but are not limited to, gamma decalactone (decan-4-olide), gamma undecalactone (undecan-4-olide), cis-jasmone lactone, gamma undecalactone, delta octalacone, delta decalactone, and hexahydro-3,6-dimethyl-2(3H)-benzofuranone. Preferably, examples of lactones include, but are not limited to, gamma undecalactone, delta octalacone, delta decalactone, and hexahydro-3,6-dimethyl-2(3H)-benzofuranone.

[0060] Examples of acetals include, but are not limited to, 2,4-dimethyl tetrahydroindenodioxine, phenylacetaldehyde diacetal, phenylacetaldehyde glyceryl acetal, citral diethyl acetal, citral dimethyl acetal, 2,6-octadienal, 1,1-dimethoxy-2-phenylethane, and 3,7-dimethyl isomerized acid. Preferably, examples of acetals include, but are not limited to, phenylacetaldehyde glyceryl acetal, citral diethyl acetal, citral dimethyl acetal, 2,6-octadienal, and 3,7-dimethyl isomerized acid.

[0061] Examples of nitriles include, but are not limited to, 3,7-dimethyloct-6-ene nitrile (citronellyl nitrile), tridec-2-enenitrile, 3-phenyl-2-propenenitrile, dodecanenitrile, and 3,7-dimethylnona-2,6-dienenitrile. Preferably, examples of nitriles include, but are not limited to, tridec-2-enenitrile, 3-phenyl-2-propenenitrile, dodecanenitrile, and 3,7-dimethylnona-2,6-dienenitrile.

[0062] Examples of phenols include, but are not limited to, eugenol (2-methoxy-4-(2-propenyl)-phenol), iso-eugenol, 5-methyl-2-(l-methylethyl)-phenol, 2- ethoxy-4-methylphenol, 2,6-di-tert-butyl-p-cresol and 2-ethoxy-4-(methoxymethyl)-phenol.

[0063] Examples of acids include, but are not limited to, pentanoic acid, butyric acid and 2-methylpent-2-en-l-oic acid.

[0064] Examples of terpenes such as cyclic (e.g., sesquiterpenic) or non-cyclic terpene hydrocarbons include, but are not limited to, limonene, l-methyl-4-isopropenyl-l-cyclohexene, l-methyl-4-isopropyl-1,4-cyclohexadiene, 7-methyl-3-methyleneocta-1,6-diene, 1-methyl-4-(1-methylethyl)-1,3-cyclohexadiene, 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane, 2,2-dimethyl-3-methylenebicyclo-[2.2.1]heptane, [1R,(1R*,4E,9S*)]-4,11,1 l-Trimethyl-8-methylene-bicyclo[7.2.0]undec-4-ene, l-methyl-4-(l-methylethyl)benzene, and sesquiterpene-containing essential oils. Preferably, examples of terpenes include, but are not limited to, sesquiterpene-containing essential oils.

[0065] Examples of nitrogenous or sulfurous heterocyclic compounds, saturated or unsaturated, include, but are not limited to, indole, 1,3-benzopyrrole, tetrahydro-4-methyl-2-(2-methyl-l-propenyl)-2H-pyrane, 2-methyl-pyrazine, 4-methyl-5-hydroxyethyl thiazole (2-(4-methylthiazol-5-yl)ethanol), 6-tert-butylquinoline, 6-(isopropyl)quinoline, cis-2-methyl-4-propyl-l,3-oxathiane and the pyrazines. Preferably, examples of nitrogenous or sulfurous heterocyclic compounds, saturated or unsaturated, include, but are not limited to, 6-tert-butylquinoline, 6-(isopropyl)quinoline, cis-2-methyl-4-propyl-1,3-oxathiane and pyrazines.

[0066] Examples of products of natural origin include, but are not limited to, essential oils extracted from the different parts of plants (flowers, stems, leaves, fruits, bark, roots, woody parts, herbs, needles, sap and gums), resinoids, concretes, or absolutes obtained from the latter.Preferably, examples of products of natural origin include, but are not limited to, white wormwood (Artemisia herba-alba) oil, lemon peel extract, eucalyptus globulus leaf oil, Dipterocarpus turbinatus balsam oil, Pogostemon cablin leaf oil, Rosmarinus officinalis leaf oil, Juniperus virginiana oil, Mentha arvensis leaf oil, Mentha viridis leaf oil, Citrus aurantium dulcis peel oil, Citrus aurantium dulcis peel extract, Mediterranean cypress (Cupressus sempervirens) leaf oil, patchouli (Pogostemon cablin) leaf oil, Texas cedar (Juniperus mexicana) oil, and oil of Hybrid Lavandula (Lavandula Hybrida). .

[0067] The fragrance composition may include ingredients of natural or synthetic origin. The choice of this fragrance composition depends on the desired odor effect and on the nature of the product containing it.

[0068] Preferably, the perfumed composition does not include allergenic substances or preferably includes 10 or fewer allergenic substances, preferably 5 or fewer allergenic substances.

[0069] According to one aspect, the invention relates to an alcoholic solution comprising from 3 to 30% of the composition and at least one diluent, preferably, the alcoholic solution comprises 15% of the perfumed composition.

[0070] By way of example, the alcoholic solution comprises 10% of the composition by weight of the total weight of the solution, i.e. 0.3% of diisopropyl sebacate and 0.7% of triheptanoin, the percentages being by weight of the total weight of the composition.

[0071] Preferably, the diluent, or at least one diluent, is an alcohol. The alcohol used as a diluent is chosen to suit the final application; by way of preferred example, the alcohol is chosen from ethanol, isopropanol, methoxymethylbutanol, and other diluents such as glycol ethers, for example, dipropylene glycol methyl ether. Alternatively, the diluent, or at least one diluent, may be a mixture of alcohol and water.

[0072] Preferably, the alcoholic solution comprises from 25 to 80% alcohol by weight of the total weight of the solution. According to one possibility, the alcoholic solution also comprises from 0 to 60% water by weight of the total weight of the solution.

[0073] The alcoholic solution according to the invention is intended to be applied (by spreading for example) or sprayed onto a support such as skin, hair, or a textile for example.

[0074] The perfumed solution according to the invention may further comprise bactericidal, bacteriostatic, insecticidal and repellent agents.

[0075] The present invention also relates to a cosmetic base comprising the mixture or perfumed composition or alcoholic solution of the present invention.

[0076] The term “cosmetic base” means a cosmetic product or a personal care product in the form of a cream, emulsion, foam, wax, oil, lotion, gel, suspension, solution, powder, balm, serum, mask, or scrub. Examples of cosmetic products include, but are not limited to, perfumes (finished, i.e., usable directly on the skin: skin perfumes), eau de parfum, eau de toilette, pet perfumes, hair products, shaving and aftershave products, essential oils, skin care products, deodorants, antiperspirants, skin cleansers, depilatory products, self-tanning products, sunscreens, makeup products, etc. Examples of hygiene products include, but are not limited to, wipes, talcum powder, diapers, bibs, handkerchiefs, and towels. paper, soaps, shower gel, shampoos and other body cleaning products, oral care, feminine hygiene products, etc.

[0077] Such products may be intended for both humans and animals.

[0078] The present invention also relates to a detergent base comprising the mixture or perfumed composition or alcoholic solution of the present invention.

[0079] The term "detergent base" means maintenance or cleaning products. Examples of maintenance or cleaning products include, but are not limited to, surface, textile and dishwashing detergents, bleaching agents, fabric softeners, conditioners, paint strippers, varnishes and other household products.

[0080] The present invention also relates to weed killers and fertilizers comprising the mixture or perfumed composition or alcoholic solution of the present invention.

[0081] The present invention also relates to a toilet water or room fragrance comprising the mixture or perfumed composition or alcoholic solution of the present invention.

[0082] By "eau de toilette" we mean products intended to perfume the body, and in particular fine perfumery perfumes, also called skin perfume, eaux de parfum or eaux de toilette.

[0083] The term "air fragrance" refers to products intended to scent the air. Air fragrance products may, but are not limited to, be contained in aerosols, vaporizers, sprays, candles, scented gels, solid carriers, oil burners, incense, beads, and fragrance diffusers. The air fragrance of the present invention may be used in enclosed public, professional, or private spaces; for example, cars, homes, office buildings, public transportation, museums, historical monuments, churches, cellars, schools, restaurants, cinemas, hospitals, factories, water or waste treatment plants, shops, and hotels. The air fragrance may also be used in air conditioning systems.

[0084] The present invention also relates to perfumed materials comprising, or coated, by the mixture or by the perfumed composition or the alcoholic solution according to the invention, in particular polymers for example plastics, macromolecules such as cellulose or textiles etc.

[0085] The perfumed mixture or composition or alcoholic solution according to the invention is intended to be used in concentrated or non-concentrated form in cosmetic bases, detergent bases or toilet waters or room fragrances or on perfumed materials.

[0086] The present invention also relates to the use of the mixture or perfumed composition or the alcoholic solution according to the invention to prepare a cosmetic base, a detergent base or a toilet water or a room fragrance or a perfumed material.

[0087] The present invention also relates to the use of the mixture, the perfumed composition, the alcoholic solution according to the invention, the cosmetic base, the detergent base or a toilet water or a room fragrance or a perfumed material.

[0088] In a particular embodiment, the perfumed mixture or composition or the alcoholic solution of the present invention improves the longevity of the perfume while respecting its olfactory profile.

[0089] According to one aspect, the invention relates to a method for preparing a finished perfumed product comprising: incorporating an amount of the mixture or perfumed composition or an alcoholic solution as described above to prepare a finished product, the finished product being chosen from a group consisting of a cosmetic base, a detergent base, or an eau de toilette or eau de toilette, or a room fragrance or a perfumed material.

[0090] The present invention will be described in more detail with the help of the following examples, which are purely illustrative.

[0091] Example 1: Floral composition containing the residual mixture

[0092] [Table 1] Designation Quantity W / W Percentage (%) Residual Mixture 0.11 10.00 Hedione without BHT 0.324 29.45 Musk T 0.25 22.73 Florosa 0.125 11.36 Ethyl linalool 0.06 5.45 Mandarin Italy Yellow Extra 0.035 3.18 Isoraldeine 95 0.035 3.18 Linalyl acetate 0.035 3.18 Natural Lemon HE Argentina 0.03 2.73 Helional 0.022 2.00 Phenyl ethyl alcohol 0.017 1.55 Blackcurrant 345 B 0.011 1.00 Hexyl salicylate 0.011 1.00 Benzyl acetate 0.1% max ale benz 0.011 1.00 Pure citronellol 0.007 0.64 Mayol 0.006 0.55 Cis-3 hexenol 0.002 0.18 Styralyl acetate 0.002 0.18 Evernyl 0.001 0.09 Damascenone 0.001 0.09 C14 aldehyde 0.001 0.09 Ambrofix 0.001 0.09 Sandalore extra 0.001 0.09 Cyclogalbanate 0.001 0.09 Calone Fine 0.0005 0.05 Lauryl aldehyde NB 0.0005 0.05 Total 1.10 100.00

[0093] Example 2: Citrus composition containing the residual mixture

[0094] [Tables2] Product Name Quantity W / P Percentage (%) Residual Blend 0.1000 10.00 BHT-free Hedione 0.2230 22.30 Iso E Super 0.1050 10.50 Natural Orange Terpenes 0.1000 10.00 Musk T (Ethylene Brassylate) 0.0800 8.00 Natural Bergamot Furocoumarin-free 0.0750 7.50 Natural Sweet Mediterranean Orange Essential Oil 0.0600 6.00 Linalyl Acetate 0.0514 5.14 Extra Yellow Italian Mandarin 0.0250 2.50 Grapefruit Methyl 0.0250 2.50 Beta Dihydro Ionone 0.0250 2.50 Ambrofix 0.0200 2.00 Herbanate 0.0200 2.00 Hydroxycitronellal 0.0200 2.00 Linalool 0.0200 2.00 Natural Ginger (China) 0.0200 2.00 Beta-pinene 95 0.0150 1.50 Gamma-terpinene 0.0100 1.00 Natural Large Green Basil (Egypt) HE 0.0020 0.20 Damascenone 0.0020 0.20 Trans-2-dodecenal 0.0010 0.10 Natural Pink Peppercorn CO2 Extract 0.0005 0.05 Dimetol 0.0001 0.01 Total 1.0000 100.00

[0095] Example 3: Triangular tests of sensory analysis

[0096] The compositions of Examples 1 and 2 are used at 15% in hydroalcoholic solution compared to 15% hydroalcoholic solutions of the control compositions in which the residual mixture is replaced by DPG (Dipropylene glycol) to compare the olfactory performance at t=0 (in a triangular test) and the potency over time (in a skin persistence test at t=2h, 4h, and 8h). The alcoholic solution comprises 15% of the perfumed composition, 6% water, and 79% ethanol; more precisely, the alcoholic solution in this example is a hydroalcoholic solution.

[0097] Method

[0098] The panelists are given two identical samples and one different sample. They are asked to identify the different product. If enough panelists give the correct answer, the products are considered different. If enough panelists give the incorrect answer, the products are considered identical. The differentiation threshold is set according to the number of panelists for a confidence level of 0.95 and according to the table of differentiation thresholds found in ISO 4120:2021.

[0099] In our case, we have 21 participants. The differentiation threshold is therefore 12 correct answers for a confidence level of 0.95.

[0100] Results

[0101] At t=0, no significant difference was identified between the solutions without the residual mixture and with the residual mixture, nor in the alcoholic solution. including the citrus perfume composition nor on the alcoholic solution including the floral perfume composition.

[0102] The formulated residual mixture therefore does not cause any change in the olfactory profile of the compositions in alcoholic solution at t=0. [Fig.1].

[0103] We therefore do not observe a sequestering effect of the top notes.

[0104] Example 4: Skin persistence test on alcoholic solutions of compositions with and without mixture

[0105] Method

[0106] The compositions of Examples 1 and 2, as well as the control compositions in which the residual mixture is replaced by DPG (Dipropylene glycol), are used at 15% in alcoholic solution and then applied to the arms of a volunteer. One arm is treated with the alcoholic solution comprising 15% of the perfumed composition containing 10% of the residual mixture, and the other arm with the alcoholic solution comprising 15% of the control perfumed composition containing 10% DPG. The alcoholic solution is composed identically to Example 3.

[0107] The panel assesses the intensity of the fragrance by comparing the two arms, then completes a questionnaire in sequential monadic format. The strengths are rated on a linear scale from 1 (Very weak) to 10 (very strong).

[0108] The panel evaluates the different intensities on scales generated by the FIZZ Biosystemes software. The responses are then automatically recorded by this software at the end of the questionnaire.

[0109] The data are processed and analyzed using statistical tests and FIZZ Treatments specifically adapted for sensory analysis. Standard processing will be performed, namely an analysis of variance (or ANOVA), which is the statistical model used to compare sample means.

[0110] Results

[0111] For the alcoholic solution containing the floral fragrance composition, we therefore observed +30% intensity thanks to the residual mixture at 2h, +22% at 4h and +29% at 8h compared to the alcoholic solution containing the composition without the residual mixture. Figures 2 to 4.

[0112] For the alcoholic solution containing the citrus fragrance composition, we obtained +12% intensity thanks to the residual mixture at 2h, +21% at 4h and +17% at 8h compared to the alcoholic solution containing the composition without the residual mixture. Figures 5 to 7.

[0113] Some perfumers have found that by 2 a.m. the heart notes were already expressing themselves for the alcoholic solution containing the unblended composition, while the alcoholic solution containing the blended composition was still in the top notes. The addition The mixture therefore prolongs the duration of each olfactory experience in the perfume's olfactory pyramid.

Claims

Demands

1. Residual mixture comprising 30% disopropyl sebacate, and 70% triheptanoin, the percentages being by weight of the total weight of the mixture.

2. Perfumed composition comprising the residual mixture of claim 1.

3. Perfumed composition according to the preceding claim comprising from 5% to 30% of the residual mixture by weight of the total weight of the perfumed composition.

4. Perfumed composition according to the preceding claim comprising 10% of the residual mixture by weight of the total weight of the perfumed composition.

5. Perfumed alcoholic solution comprising alcohol as a diluent and 3% to 30% perfumed composition according to any one of claims 2 to 4, by weight of the total weight of the perfumed alcoholic solution.

6. Perfumed alcoholic solution according to the preceding claim comprising 15% of the perfumed composition by weight of the total weight of the perfumed alcoholic solution.

7. Cosmetic base comprising the mixture according to claim 1 or the perfumed composition according to any one of claims 2 to 4 or the alcoholic solution according to any one of claims 5 to 6.

8. Detergent base comprising the mixture according to claim 1 or the perfumed composition according to any one of claims 2 to 4 or the alcoholic solution according to any one of claims 5 to 6.

9. Eau de toilette comprising the mixture according to claim 1 or the perfumed composition according to any one of claims 2 to 4 or the alcoholic solution according to any one of claims 5 to 6

10. J d U. Use of the mixture according to claim 1 or the perfumed composition according to any one of claims 2 to 4 or the alcoholic solution according to any one of claims 5 to 6, to improve the longevity of a perfume.

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