Method for controlling plant diseases using biaryl compounds
The compound represented by Formula (I) or its derivatives offers an effective solution for controlling plant diseases, addressing the limitations of existing biaryl compounds by providing a targeted and efficient method for plant disease management.
Patent Information
- Application Number
- JP2025031519
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2025-02-28
- Publication Date
- 2025-06-03
AI Technical Summary
Current methods for controlling plant diseases are inadequate, as existing biaryl compounds primarily function as agricultural herbicides and do not effectively address plant disease control.
The use of a compound represented by Formula (I) or its N-oxide or salt, applied to plants or plant cultivation carriers, to control plant diseases. This compound is specifically designed to target and mitigate plant diseases effectively.
The application of the compound represented by Formula (I) or its derivatives effectively controls plant diseases, providing a novel and efficient method for plant disease management.
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Abstract
Description
Technical Field
[0001] The present invention relates to a method for controlling plant diseases using biaryl compounds.
Background Art
[0002] Patent Document 1 describes biaryl compounds as agricultural herbicides.
Prior Art Documents
Patent Documents
[0003]
Patent Document 1
Summary of the Invention
Problems to be Solved by the Invention
[0004] An object of the present invention is to provide an excellent method for controlling plant diseases.
Means for Solving the Problems
[0005] The present invention is as follows.
[0006] 〔1〕Formula (I)
[0007]
Chemical Formula
Advantages of the Invention
[0008] According to the present invention, plant diseases can be controlled.
Modes for Carrying Out the Invention
[0009] The substituents in the present invention will be described. The halogen atom means a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom. When the substituent is substituted with two or more halogen atoms or substituents, those halogen atoms or substituents may be the same or different from each other. The notation “optionally substituted with one or more substituents selected from Group X” (where X means any one of A, B, and C) in this specification means that when there are two or more substituents selected from Group X, those substituents may be the same or different from each other. The notation (R4)n in this specification means that when n is 2 or 3, the plurality of R4 may be the same or different from each other. The notation (R3)m in this specification means that when m is 2, 3, or 4, the plurality of R3 may be the same or different from each other. The notation "(R6)q" in this specification means that when q is 2, 3, 4, or 5, the plurality of R6s may each be the same or different. The notation "CX-CY" in this specification means that the number of carbon atoms is from X to Y. For example, the notation "C1-C6" means that the number of carbon atoms is from 1 to 6. The chain hydrocarbon group represents an alkyl group, an alkenyl group, or an alkynyl group. Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a 1,1-dimethylpropyl group, a 1,2-dimethylpropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group. Examples of the alkenyl group include a vinyl group, a 1-propenyl group, a 2-propenyl group, a 1-methyl-1-propenyl group, a 1-methyl-2-propenyl group, a 1,2-dimethyl-1-propenyl group, a 3-butenyl group, a 4-pentenyl group, and a 5-hexenyl group. Examples of the alkynyl group include an ethynyl group, a 1-propynyl group, a 2-propynyl group, a 1-methyl-2-propynyl group, a 1,1-dimethyl-2-propynyl group, a 2-butynyl group, a 4-pentynyl group, and a 5-hexynyl group. Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a tert-butoxy group, a pentyloxy group, and a hexyloxy group. Examples of the alkylsulfanyl group include a methylsulfanyl group, an ethylsulfanyl group, an isopropylsulfanyl group, and a hexylsulfanyl group. Examples of the alkylsulfinyl group include a methylsulfinyl group, an ethylsulfinyl group, an isopropylsulfinyl group, and a hexylsulfinyl group. Examples of the alkylsulfonyl group include a methanesulfonyl group, an ethanesulfonyl group, an isopropanesulfonyl group, and a hexanesulfonyl group. Examples of the alicyclic hydrocarbon include a cyclobutene ring, a cyclopentene ring, a cyclopentadiene ring, a cyclohexene ring, a cyclohexadiene ring, and a cycloheptene ring. Examples of the alicyclic hydrocarbon group include a cycloalkyl group or a cycloalkenyl group. Examples of the cycloalkyl group include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, and a cyclohexyl group. Examples of the cycloalkenyl group include a cyclopentenyl group and a cyclohexenyl group. Examples of the non-aromatic heterocyclic ring include a dihydrofuran ring, a dihydrothiophene ring, a dihydropyrrole ring, a 1,3-dioxole ring, a pyran ring, and a dihydropyran ring. Examples of the aromatic heterocyclic ring include a furan ring, a thiophene ring, a pyrrole ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, a triazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, and a pyrazine ring. Examples of the aromatic heterocyclic group include 5-membered aromatic heterocyclic groups such as a pyrrolyl group, a furanyl group, a thienyl group, a pyrazolyl group, an imidazolyl group, a triazolyl group, a tetrazolyl group, an oxazolyl group, an isoxazolyl group, a thiazolyl group, an isothiazolyl group, an oxadiazolyl group, and a thiadiazolyl group; and 6-membered aromatic heterocyclic groups such as a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group. Examples of the non-aromatic heterocyclic group include an aziridinyl group, an oxiranyl group, a thiiranyl group, an azetidinyl group, an oxetanyl group, a thietanyl group, a pyrrolidinyl group, a tetrahydrofuranyl group, a tetrahydrothienyl group, a pyrazolinyl group, a pyrazolidinyl group, an imidazolinyl group, an imidazolidinyl group, an oxazolinyl group, a thiazolinyl group, an oxazolidinyl group, a thiazolidinyl group, an isoxazolinyl group, an isoxazolidinyl group, an isothiazolinyl group, an isothiazolidinyl group, a dioxolanyl group, a dioxanyl group, a piperidyl group, a piperazinyl group, a morpholinyl group, a thiomorpholinyl group, a pyranyl group, a dihydropyranyl group, a tetrahydropyranyl group, a tetrahydrothiopyranyl group, an azepanyl group, an oxepanyl group, and a thiepanyl group.
[0010] Ring A6 in formula (I) is a group represented by formula (A6-1)
[0011]
Chemical formula
[0012]
Chemical formula
[0013] [Chemical formula] [In the formula, the symbols represent the same meanings as described above.] and the groups represented by are mentioned.
[0014] For this compound, one or more stereoisomers may exist. Examples of stereoisomers include enantiomers, diastereomers, atropisomers, and geometric isomers. The present invention includes each stereoisomer and a mixture of stereoisomers in any ratio.
[0015] The compound represented by formula (I) or its N-oxide may form acid addition salts such as hydrochloride, sulfate, nitrate, phosphate, acetate, benzoate, etc. by mixing with acids such as hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, acetic acid, benzoic acid, etc.
[0016] In this compound, when q is 2, 3, 4, or 5, two adjacent R6s and R6s, together with the carbon atom to which they are bonded, form a C5-C6 alicyclic hydrocarbon, a 5- or 6-membered non-aromatic heterocycle {the C5-C6 alicyclic hydrocarbon and the 5- or 6-membered non-aromatic heterocycle may be substituted with one or more substituents selected from group B}, a benzene ring, or a 5- or 6-membered aromatic heterocycle {the benzene ring and the 5- or 6-membered aromatic heterocycle may be substituted with one or more substituents selected from group C}. Specifically, 1) Formula (I-A)
[0017] [Chemical formula] in which, ring A6, D, R3, R4, m and n represent the same meanings as in [1], R6A, R6B and R6C are the same or different and represent the same meaning as R6 in [1] or a hydrogen atom, R6D and R6E, together with the carbon atom to which they are attached, form a C5-C6 alicyclic hydrocarbon, a 5- or 6-membered non-aromatic heterocyclic ring {the C5-C6 alicyclic hydrocarbon and the 5- or 6-membered non-aromatic heterocyclic ring may be substituted with one or more substituents selected from Group B}, a benzene ring, or a 5- or 6-membered aromatic heterocyclic ring {the benzene ring and the 5- or 6-membered aromatic heterocyclic ring may be substituted with one or more substituents selected from Group C}; or 2) In formula (I-A), ring A6, D, R3, R4, m and n represent the same meanings as in [1], R6A, R6B and R6E are the same or different and represent the same meaning as R6 in [1] or a hydrogen atom, R6C and R6D, together with the carbon atom to which they are attached, form a C5-C6 alicyclic hydrocarbon, a 5- or 6-membered non-aromatic heterocyclic ring {the C5-C6 alicyclic hydrocarbon and the 5- or 6-membered non-aromatic heterocyclic ring may be substituted with one or more substituents selected from Group B}, a benzene ring, or a 5- or 6-membered aromatic heterocyclic ring {the benzene ring and the 5- or 6-membered aromatic heterocyclic ring may be substituted with one or more substituents selected from Group C} is a compound.
[0018] Next, the method for producing this compound will be described.
[0019] Production Method A The compound represented by formula (I) (this compound A) can be produced by reacting the compound represented by formula (B1) (hereinafter referred to as compound (B1)) with the compound represented by formula (M1) (hereinafter referred to as compound (M1)) in the presence of a palladium catalyst and a base.
[0020] [Chemical formula] [In the formula, X51 represents a chlorine atom, a bromine atom, an iodine atom, or a triflyloxy group, Met51 represents B(OH)2 or a 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl group, and the other symbols represent the same meanings as described above.] The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include hydrocarbons such as hexane, toluene, and xylene (hereinafter referred to as hydrocarbons); ethers such as methyl tert-butyl ether (hereinafter referred to as MTBE), tetrahydrofuran (hereinafter referred to as THF), and 1,2-dimethoxyethane (hereinafter referred to as DME) (hereinafter referred to as ethers); halogenated hydrocarbons such as dichloromethane, chloroform, and chlorobenzene (hereinafter referred to as halogenated hydrocarbons); amides such as dimethylformamide (hereinafter referred to as DMF) and N-methylpyrrolidone (hereinafter referred to as NMP) (hereinafter referred to as amides); esters such as methyl acetate and ethyl acetate (hereinafter referred to as esters); nitriles such as acetonitrile and propionitrile (hereinafter referred to as nitriles); dimethyl sulfoxide (hereinafter referred to as DMSO), water, and mixtures of two or more of these. Examples of the palladium catalyst used in the reaction include palladium(II) acetate and [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride. Examples of the base used in the reaction include organic bases such as triethylamine and pyridine (hereinafter referred to as organic bases); alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as alkali metal carbonates); alkali metal hydrogen carbonates such as sodium hydrogen carbonate and potassium hydrogen carbonate (hereinafter referred to as alkali metal hydrogen carbonates); sodium fluoride and tripotassium phosphate. In the reaction, with respect to 1 mol of the compound (B1), the compound (M1) is usually used in a ratio of 0.5 to 2 mol, the palladium catalyst is usually used in a ratio of 0.01 to 0.3 mol, and the base is usually used in a ratio of 1 to 10 mol. The reaction temperature is usually in the range of 0 to 150 °C. The reaction time is usually in the range of 0.1 to 120 hours. After the reaction is completed, water is added to the reaction mixture, followed by extraction with an organic solvent, and post-treatment operations such as drying and concentrating the organic layer are carried out to isolate Compound A. Compound (M1) is known or can be produced according to known methods.
[0021] Production Method B The compound represented by formula (I) (Compound A herein) can also be produced by reacting the compound represented by formula (B2) (hereinafter referred to as Compound (B2)) with the compound represented by formula (M2) (hereinafter referred to as Compound (M2)) in the presence of a palladium catalyst and a base.
[0022]
Chemical formula
[0023] Production Method C The compound represented by formula (I-a) (hereinafter referred to as Compound (I-a)) can be produced by reacting an organolithium reagent generated by reacting the compound represented by formula (B3) (hereinafter referred to as Compound (B3)) with the compound represented by formula (M3) (hereinafter referred to as Compound (M3)) with the compound represented by formula (M4) (hereinafter referred to as Compound (M4)).
[0024]
Chemical formula
[0025] Next, a method for producing compound (I-a) from an organolithium reagent will be described. The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include hydrocarbons, ethers, and mixtures of two or more of these. In the reaction, compound (M4) is usually used in a proportion of 0.5 to 2 moles per mole of the organolithium reagent. The reaction temperature is usually in the range from -78 °C to the boiling point of the solvent. The reaction time is usually in the range of 0.1 to 120 hours. After completion of the reaction, water is added to the reaction mixture, followed by extraction with an organic solvent, and post-treatment operations such as drying and concentrating the organic layer, whereby compound (I-a) can be isolated. Compound (B3), compound (M3), and compound (M4) are either known or can be produced according to known methods.
[0026] Production Method D Compound (I-a) can also be produced by reacting a Grignard reagent formed by reacting compound (B3) with a compound represented by formula (M5) (hereinafter referred to as compound (M5)) with compound (M4).
[0027]
Chemical formula
[0028] Production Method E Compound (I-a) can also be produced by reacting an organolithium reagent formed by reacting a compound represented by formula (M6) (hereinafter referred to as compound (M6)) with compound (M3) with a compound represented by formula (M7) (hereinafter referred to as compound (M7)).
[0029]
Chemical formula
[0030] Production Method F Compound (I-a) can also be produced by reacting a Grignard reagent formed by reacting compound (M6) with compound (M5) with compound (M7).
[0031]
Chemical formula
[0032] Production Method G The compound represented by formula (I-b) (hereinafter referred to as compound (I-b)) can be produced by dehydroxyating compound (I-a).
[0033]
Chemical formula
[0034] Next, a method for producing compound (I-b) by reaction with phosphorus tribromide will be described. The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include hydrocarbons, ethers, and mixtures of two or more of these. In the reaction, phosphorus tribromide is usually used in a proportion of 1 to 10 moles per 1 mole of compound (I-a). The reaction temperature is usually in the range from 0 °C to the boiling point of the solvent. The reaction time is usually in the range of 0.1 to 120 hours. After completion of the reaction, water is added to the reaction mixture, and the organic layer is washed with an alkaline aqueous solution (for example, a saturated aqueous sodium hydrogen carbonate solution) as necessary. Compound (I-b) can be isolated by performing post-treatment operations such as drying and concentrating the organic layer.
[0035] Production method H The compound represented by formula (I-c) (hereinafter referred to as compound (I-c)) can be produced by oxidizing compound (I-a).
[0036]
Chemical formula
[0037] Production method I Compound (I-a) can also be produced by reducing compound (I-c).
[0038]
Chemical formula
[0039] Production method J The compound represented by formula (I-d) (hereinafter referred to as compound (I-d)) can be produced by reacting compound (I-a) with the compound represented by formula (M8) (hereinafter referred to as compound (M8)) in the presence of a base.
[0040] [Chemical formula] [In the formula, X55 represents a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a mesyloxy group or a triflyloxy group, and the other symbols have the same meanings as described above.] The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include alcohols, nitriles, ethers, hydrocarbons, amides, DMSO, water, and mixtures of two or more of these. Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, organic bases, sodium hydride, and tripotassium phosphate. When X55 is a bromine atom, an iodine atom, or a triflyloxy group, the reaction may be carried out by adding a metal catalyst and a ligand as necessary. Examples of the metal catalyst used in the reaction include palladium catalysts such as palladium(II) acetate, [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride; nickel catalysts such as bis(cyclooctadiene)nickel(0), nickel(II) chloride; and copper catalysts such as copper(I) iodide, copper(I) chloride. When a metal catalyst is used in the reaction, the metal catalyst is usually used in a proportion of 0.01 to 1 mol per 1 mol of compound (I-a). Examples of the ligand used in the reaction include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, etc. When a ligand is used in the reaction, the ligand is usually used in a proportion of 0.01 to 1 mol per 1 mol of compound (I-a). In the reaction, compound (M8) is usually used in a proportion of 1 to 10 mol and the base is usually used in a proportion of 1 to 10 mol per 1 mol of compound (I-a). The reaction temperature is usually in the range of -20°C to 200°C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is completed, water is added to the reaction mixture, followed by extraction with an organic solvent, and post-treatment operations such as drying and concentrating the organic layer are performed to obtain compound (I-d). Compound (M8) is either known or can be produced according to known methods.
[0041] Reference Production Method A The compound represented by formula (C2) (hereinafter referred to as compound (C2)) can be produced by reacting an organolithium reagent formed by reacting compound (M6) with compound (M3) with the compound represented by formula (C1) (hereinafter referred to as compound (C1)).
[0042]
Chemical formula
[0043] Reference Production Method B Compound (C2) can also be produced by reacting a Grignard reagent formed by reacting compound (M6) with compound (M5) with compound (C1).
[0044]
Chemical formula
[0045] Reference Production Method C The compound represented by formula (C3) (hereinafter referred to as compound (C3)) can be produced by reacting compound (B1) with bis(pinacolato)diboron in the presence of a base and a palladium catalyst.
[0046]
Chemical formula
[0047] Reference Production Method D The compound represented by formula (C5) (hereinafter referred to as compound (C5)) can be produced by oxidizing the compound represented by formula (C4) (hereinafter referred to as compound (C4)).
[0048]
Chemical formula
[0049] Reference Production Method E The compound represented by formula (C6) (hereinafter referred to as compound (C6)) can be produced by thiocarbonylating compound (C5).
[0050]
Chemical formula
[0051] Reference production method F The compound represented by formula (C7) (hereinafter referred to as compound (C7)) can be produced by reacting compound (C5) with the compound represented by formula (M9) (hereinafter referred to as compound (M9)) or a salt of compound (M9).
[0052] [Chemical formula] [In the formula, the symbols have the same meanings as described above.] Examples of the salt of compound (M9) include hydrochloride and sulfate. The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, alcohols, and mixtures of two or more of these. A base may be added to the reaction as necessary. Examples of the base used in the reaction include organic bases; alkali metal carbonates; alkali metal hydrogen carbonates; sodium hydride and tripotassium phosphate. When a base is used in the reaction, the base is usually used in a ratio of 1 to 10 moles per 1 mole of compound (C5). In the reaction, compound (M9) is usually used in a ratio of 1 to 10 moles per 1 mole of compound (C5). The reaction temperature is usually in the range of 0 to 150 °C. The reaction time is usually in the range of 0.1 to 120 hours. After completion of the reaction, water is added to the reaction mixture, and extraction is carried out with an organic solvent. Compound (C7) can be isolated by performing post-treatment operations such as drying and concentrating the organic layer. The salt of compound (M9) is known or can be produced according to a known method.
[0053] Reference production method G The compound represented by formula (C9) (hereinafter referred to as compound (C9)) can be produced by reacting compound (M6) with the compound represented by formula (M11) (hereinafter referred to as compound (M11)).
[0054] [Chemical formula] [In the formula, the symbols have the same meanings as described above.] The reaction can be carried out according to Production Method A, using compound (M6) instead of compound (B1) and using compound (M11) instead of compound (M1). Also, the reaction can be carried out according to the method described in Angewandte Chemie International Edition, 2020, 59, 22460 - 22464, etc. Compound (M11) is known or can be produced according to known methods.
[0055] Reference Production Method H The compound represented by formula (B1 - 1) (hereinafter referred to as compound (B1 - 1)) can be produced by the cyclization reaction of the compound represented by formula (C14) (hereinafter referred to as compound (C14)).
[0056] [Chemical formula] [In the formula, R1v, R2v, R3v, R4v, R5v, R6v, R7v, and R8v are the same or different and are each a C1-C6 chain hydrocarbon group, a C3-C8 alicyclic hydrocarbon group, or a 3- to 8-membered non-aromatic heterocyclic group, which may be substituted with one or more substituents selected from Group A; the C3-C8 alicyclic hydrocarbon group and the 3- to 8-membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from Group B; a phenyl group which may be substituted with one or more substituents selected from Group C; OR26, NR27R28, C(O)R29, C(R30)=NOR31, a cyano group, a nitro group, a halogen atom, or a hydrogen atom; R9v is a C1-C6 chain hydrocarbon group, a C3-C8 alicyclic hydrocarbon group, or a 3- to 8-membered non-aromatic heterocyclic group, which may be substituted with one or more substituents selected from Group A; the C3-C8 alicyclic hydrocarbon group and the 3- to 8-membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from Group B; a phenyl group which may be substituted with one or more substituents selected from Group C; C(O)R29, or a hydrogen atom; and the other symbols have the same meanings as described above.] The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include alcohols, hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, DMSO, water, and mixtures of two or more of these. A base may be added to the reaction as necessary. Examples of the base used in the reaction include organic bases, alkali metal carbonates, alkali metal hydrogen carbonates, or phosphazene bases such as 1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)phosphoranilideneamino]-2λ5,4λ5-catenadi(phosphazene). In the reaction, the base is usually used in a proportion of 0.01 to 10 moles per 1 mole of the compound (C14). The reaction temperature is usually in the range of 0 to 150°C. The reaction time is usually in the range of 0.1 to 120 hours. After completion of the reaction, water is added to the reaction mixture, and extraction is carried out with an organic solvent. Then, post-treatment operations such as drying and concentrating the organic layer are performed to isolate the compound (B1-1). The reaction can also be carried out according to the methods described in Tetrahedron Letters, 2022, 89, 153599, Org. Lett, 2022, 24, 51, 9447, J. Am. Chem. Soc. 2014, 136, 35, 12217, etc. Compound (C14) can be produced according to known methods, for example, the methods described in Tetrahedron Letters, 2022, 89, 153599, Org. Lett, 2022, 24, 51, 9447, J. Am. Chem. Soc. 2014, 136, 35, 12217, etc.
[0057] Reference Production Method I The compound represented by formula (B1-2) (hereinafter referred to as compound (B1-2)) can be produced by reacting the compound represented by formula (C15) (hereinafter referred to as compound (C15)) with the compound represented by formula (M1-1) (hereinafter referred to as compound (M1-1)).
[0058]
Chemical formula
[0059] Reference production method J The compound represented by the formula (B1-3) (hereinafter referred to as compound (B1-3)) can be produced by reacting the compound represented by the formula (C16) (hereinafter referred to as compound (C16)) with the compound represented by the formula (M1-2) (hereinafter referred to as compound (M1-2)).
[0060]
Chemical formula
[0061] This compound can be used in admixture or combination with one or more components selected from the group consisting of the following groups (a), (b), (c), (d), (e), (f), (g), (h), (i) and (j) (hereinafter referred to as this component). The above-mentioned admixture or combination means using this compound and this component simultaneously, separately or at intervals of time. When this compound and this component are used simultaneously, this compound and this component may be contained in separate formulations or in one formulation. One aspect of the present invention is a composition (hereinafter referred to as Composition A) containing one or more components (i.e., this component) selected from the group consisting of the groups (a), (b), (c), (d), (e), (f), (g), (h), (i) and (j), and this compound.
[0062] Group (a) includes acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphorus insecticides), GABA-gated chloride ion channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-gated chloride ion channel allosteric modulators (e.g., macrolide insecticides), It consists of juvenile hormone mimics, multi-site inhibitors, chordotonal organ TRPV channel modulators, mite growth inhibitors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin-based insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, inhibitors of mitochondrial electron transport system complexes I, II, III, and IV, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ryanodine receptor modulators (e.g., diamide-based insecticides), chordotonal organ modulators, and other insecticidal, acaricidal, and nematicidal active ingredients. These are described in the classification based on the mode of action of IRAC.
[0063] Group (b) consists of nucleic acid synthesis inhibitors (e.g., phenylamide-based fungicides, acyl amino acid-based fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiration inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyrimidine-based fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., DMI fungicides such as triazoles), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, other site of action contact active fungicides, microbial fungicides, and other fungicidal active ingredients. These are described in the classification based on the mode of action of FRAC.
[0064] Group (c) is a group of plant growth regulating components.
[0065] Group (d) is a group of phytotoxicity reducing components.
[0066] Group (e) is a group of synergists.
[0067] Group (f) is a group of repellent components consisting of bird repellent components, insect repellent components, and animal repellent components.
[0068] Group (g) is a group of molluscicidal components.
[0069] Group (h) is a group of information - transmitting substances composed of pheromones and allelochemicals used by insects.
[0070] Group (i) is a group consisting of acetyl - CoA carboxylase (ACCase) inhibitors, acetolactate synthase (ALS) inhibitors, photosynthesis (photosystem II) inhibitors, photosystem I electron converters, protoporphyrinogen oxidase (PPO) inhibitors, phytoene desaturase system (PDS) inhibitors, 4 - hydroxyphenylpyruvate dioxygenase (4 - HPPD) inhibitors, carotenoid biosynthesis inhibitors, EPSP synthase inhibitors, glutamine synthase inhibitors, dihydropteroate (DHP) synthase inhibitors, microtubule polymerization inhibitors, mitosis / microtubule formation inhibitors, very - long - chain fatty acid (VLCFA) inhibitors, cellulose synthesis inhibitors, uncoupling agents, lipid synthesis inhibitors, indole - acetic - acid - like activators, auxin transport inhibitors, and other herbicidal active ingredients. These are described in the classification based on the mode of action of HRAC.
[0071] Group (j) is a group of biocontrol materials composed of bacteria, fungi, yeasts, protozoa, viruses, natural products, insects, mites, and mollusks having a control effect on pests (such as insecticidal activity, acaricidal activity, nematicidal activity, fungicidal activity, etc.), herbicidal activity, or plant - growth - regulating effects on rhizobia, mycorrhizal fungi, etc. Specifically, group (j) is divided into subgroup (j - 1): bacteria, subgroup (j - 2): fungi and yeasts, subgroup (j - 3): protozoa, subgroup (j - 4): viruses, subgroup (j - 5): nematodes, subgroup (j - 6): natural products, subgroup (j - 7): insects, subgroup (j - 8): mites, and subgroup (j - 9): mollusks.
[0072] Examples of combinations of this component and this compound are described below. For example, alanycarb + SX means the combination of alanycarb and SX. Note that the abbreviation SX means any one of the present compounds selected from the compound groups SX1 to SX65. Further, all of the present components described below are known components and can be obtained from commercially available preparations or produced by known methods. When the present component is a microorganism, it can also be obtained from a microorganism depository institution. The numbers in parentheses represent CAS RN (registered trademark).
[0073] Combination of the present component of the above group (a) and the present compound: Abamectin + SX, Acephate + SX, Acequinocyl + SX, Acetamiprid + SX, Acetic acid + SX, Acetoprole + SX, Acrinathrin + SX, Acynonapyr + SX, Afidopyropen + SX, Afoxolaner + SX, Alanycarb + SX, Aldicarb + SX, Allethrin + SX, Alpha-cypermethrin + SX, Alpha-endosulfan + SX, Aluminium phosphide + SX, Amitraz + SX, Azamethiphos + SX, Azinphos-ethyl + SX, Azinphos-methyl + SX, Azocyclotin + SX, Bendiocarb + SX, Benfluthrin + SX, Benfuracarb + SX, Bensultap + SX, Bentioflumin + SX, Benzoic acid + SX, Benzoximate + SX, Benzpyrimoxan + SX, Beta-cyfluthrin + SX, Beta-cypermethrin + SX, Bifenazate + SX, Bifenthrin + SX, Bilobalide + SX, Bioallethrin + SX, Bioresmethrin + SX,Bistrifluron + SX, Bisulflufen + SX, Borax + SX, Boric Acid + SX, Broflanilide + SX, Bromopropylate + SX, Buprofezin + SX, Butyric Acid + SX, Butocarboxim + SX, Butoxycarboxim + SX, Cadusafos + SX, Calcium Phosphide + SX, Carbaryl + SX, Carbofuran + SX, Carbosulfan + SX, Cartap Hydrochloride + SX, Cartap + SX, Chinomethionat + SX, Chlorantraniliprole + SX, Chlordane + SX, Chlorethoxyfos + SX, Chlorfenapyr + SX, Chlorfenvinphos + SX, Chlorfluazuron + SX, Chlormephos + SX, Chloropicrin + SX, Chlorpyrifos + SX, Chlorpyrifos-methyl + SX, Chromafenozide + SX, Citric Acid + SX, Clofentezine + SX, Clothianidin + SX, Coumaphos + SX, Cryolite + SX, Cyanophos + SX,Cyantraniliprole + SX, Cybenzoxasulfyl + SX, Cyclaniliprole + SX, Cyclobutrifluram + SX, Cycloprothrin + SX, Cycloxaprid + SX, Cyenopyrafen + SX, Cyetpyrafen + SX, Cyflumetofen + SX, Cyfluthrin + SX, Cyhalodiamide + SX, Cyhalothrin + SX, Cyhexatin + SX, Cypermethrin + SX, Cyphenothrin + SX, Cyproflanilide + SX, Cyromazine + SX, Dazomet + SX, Deltamethrin + SX, Demeton-S-methyl + SX, Diafenthiuron + SX, Diatomaceous earth + SX, Diazinon + SX, Dichlorvos + SX, Dicloromezotiaz + SX, Dicofol + SX, Dicrotophos + SX, Diflovidazin + SX, Diflubenzuron + SX, Dimefluthrin + SX, Dimethoate + SX, Dimethylvinphos + SX, Dimpropyridaz + SX, Dinotefuran + SX, Disodium octaborate + SX,Disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, Doramectin + SX, Emamectin-benzoate + SX, Empenthrin + SX, Endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate) + SX, Epsilon-metofluthrin + SX, Epsilon-momfluorothrin + SX, Esfenvalerate + SX, Ethiofencarb + SX, Ethion + SX, Ethiprole + SX, Ethoprophos + SX, Etofenprox + SX, Etoxazole + SX, Famphur + SX, Fenamiphos + SX, Fenazaquin + SX, Fenbutatin oxide + SX, Fenitrothion + SX, Fenmezoditiaz + SX, Fenobucarb + SX, Fenoxycarb + SX, Fenpropathrin + SX, Fenpyroximate + SX, Fenthion + SX, Fenvalerate + SX, Fipronil + SX, Flometoquin + SX, Flonicamid + SX, Fluacrypyrim + SX, Fluazaindolizine + SX,Fluazuron + SX, Flubendiamide + SX, Fluchlordiniliprole + SX, Flucycloxuron + SX, Flucythrinate + SX, Fluensulfone + SX, Flufenoprox + SX, Flufenoxuron + SX, Flufiprole + SX, Flumethrin + SX, Flupentiofenox + SX, Flupyradifurone + SX, Flupyrimin + SX, Flupyroxystrobin + SX, Fluralaner + SX, Fluvalinate + SX, Fluxametamide + SX, Formetanate + SX, Fosthiazate + SX, Fumaric acid + SX, Furamethrin + SX, Furathiocarb + SX, Gamma-cyhalothrin + SX, Halfenprox + SX, Halofenozide + SX, Heptafluthrin + SX, Heptenophos + SX, Hexaflumuron + SX, Hexythiazox + SX, Potassium salt of hop beta acid + SX, Hydramethylnon + SX, Imicyafos + SX, Imidacloprid + SX,Imidaclothiz + SX, Imiprothrin + SX, Indazapyroxamet + SX, Indoxacarb + SX, Isocycloseram + SX, Isofenphos + SX, Isoflualanam + SX, Isoprocarb + SX, Isopropyl - O - (methoxyaminothiophosphoryl) salicylate + SX, Isoxathion + SX, Kadethrin + SX, Kappa - tefluthrin + SX, Kappa - bifenthrin + SX, Lactic acid + SX, Lambda - cyhalothrin + SX, Lavandulyl senecioate + SX, Ledprona + SX, Lenoremycin + SX, Lepimectin + SX, Lime sulfur + SX, Lotilaner + SX, Lufenuron + SX, Machine oil + SX, Malathion + SX, Malic acid + SX, Mecarbam + SX, Meperfluthrin + SX, Metaflumizone + SX, Metam + SX, Methamidophos + SX, Methidathion + SX, Methiocarb + SX, Methomyl + SX, Methoxychlor + SX,Methoxyfenozide + SX, Methyl bromide + SX, Metofluthrin + SX, Metolcarb + SX, Metoxadiazone + SX, Mevinphos + SX, Milbemectin + SX, Milbemycin oxime + SX, Mivorilaner + SX, Modoflaner + SX, Momfluorothrin + SX, Monocrotophos + SX, Moxidectin + SX, Naled + SX, Nicofluprole + SX, Nicotine + SX, Nicotine-sulfate + SX, Nitenpyram + SX, Novaluron + SX, Noviflumuron + SX, Omethoate + SX, Organic acid + SX, Oxalic acid + SX, Oxamyl + SX, Oxazosulfyl + SX, Oxydemeton-methyl + SX, Parathion + SX, Parathion-methyl + SX, Permethrin + SX, Phenothrin + SX, Phenthoate + SX, Phorate + SX, Phosalone + SX, Phosmet + SX, Phosphamidon + SX, Phosphine + SX, Phoxim + SX, Pioxaniliprole + SX, Piperflanilide + SX, Pirimicarb + SX, Pirimiphos-methyl + SX, Prallethrin + SX, Profenofos + SX, Profluthrin + SX, Propionic acid + SX, Propargite + SX, Propetamphos + SX, Propoxur + SX, Propylene glycol alginate + SX, Prothiofos + SX, Pyflubumide + SX, Pymetrozine + SX, Pyraclofos + SX, Pyrethrins + SX, Pyridaben + SX, Pyridalyl + SX, Pyridaphenthion + SX, Pyrifluquinazone + SX, Pyrimidifen + SX, Pyriminostrobin + SX, Pyriprole + SX, Pyriproxyfen + SX, Quinalphos + SX,Resmethrin + SX, Sarolaner + SX, Selamectin + SX, Sigma-cypermethrin + SX, Silafluofen + SX, Sodium borate + SX, Sodium metaborate + SX, Spidoxamat + SX, Spinetoram + SX, Spirobudifen + SX, Spirodiclofen + SX, Spiromesifen + SX, Spiropidion + SX, Spirotetramat + SX, Sulfiflumin + SX, Sulfluramid + SX, Sulfotep + SX, Sulfoxaflor + SX, Sulfoxamyl + SX, Sulfur + SX, Sulfuryl fluoride + SX, Tartar emetic + SX, Tartaric acid + SX, Tau-fluvalinate + SX, Tebufenozide + SX, Tebufenpyrad + SX, Tebupirimfos + SX, Teflubenzuron + SX, Tefluthrin + SX, Temephos + SX, Terbufos + SX, Tetrachlorantraniliprole + SX, Tetrachlorvinphos + SX, Tetradifon + SX, Tetramethrin + SX,Tetramethylfluthrin + SX, Tetraniliprole + SX, Theta-cypermethrin + SX, Thiacloprid + SX, Thiamethoxam + SX, Thiocyclam + SX, Thiodicarb + SX, Thiofanox + SX, Thiometon + SX, Thiosultap-disodium + SX, Thiosultap-monosodium + SX, Tigolaner + SX, Tiorantraniliprole + SX, Tioxazafen + SX, Tolfenpyrad + SX, Tralomethrin + SX, Transfluthrin + SX, Triazamate + SX, Triazophos + SX, Trichlorfon + SX, Trifluenfuronate + SX, Triflumezopyrim + SX, Triflumuron + SX, Trimethacarb + SX, Trioxyflanilide + SX, Tyclopyrazoflor + SX, Umifoxolaner + SX, Vadescana + SX, Vamidothion + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX, Xylylcarb + SX, Zeta-cypermethrin + SX,Zinc phosphide + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-N-ethyl-3-(3,3,3-trifluoropropanesulfinyl)propanamide (1477923-37-7) + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, 2-({2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}imino)-3-(2,2,2-trifluoroethyl)-1,3-thiazolidin-4-one (1445683-71-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methanesulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methanesulfonyl)propanamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7) + SX, 4-[5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, (S)-2-chloro-N-(3-ethylpentan-2-yl)furan-3-carboxamide + SX。,
[0074] Combination of this component of group (b) and this compound: acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, benthiavalicarb-isopropyl + SX, benzovindiflupyr + SX, bifemetstrobin + SX, binapacryl + SX, biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin-S + SX, Bordeaux mixture + SX, boscalid + SX, bromothalonil + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, carbendazim + SX, carboxin + SX, carpropamid + SX, chinomethionat + SX, chloroinconazide + SX, chloroneb + SX,Chlorothalonil + SX, Chlozolinate + SX, Copper(II) acetate + SX, Copper(II) hydroxide + SX, Copper oxychloride + SX, Copper(II) sulfate + SX, Coumoxystrobin + SX, Cyazofamid + SX, Cyflufenamid + SX, Cymoxanil + SX, Cyproconazole + SX, Cyprodinil + SX, Dichlobentiazox + SX, Dichlofluanid + SX, Diclocymet + SX, Diclomezine + SX, Dicloran + SX, Diethofencarb + SX, Difenoconazole + SX, Diflumetorim + SX, Dimethachlone + SX, Dimethirimol + SX, Dimethomorph + SX, Dimoxystrobin + SX, Diniconazole + SX, Diniconazole-M + SX, Dinocap + SX, Dipotassium hydrogenphosphite + SX, Dipymetitrone + SX, Dithianon + SX, Dodecylbenzenesulphonic acid bisethylenediamine copper(II) salt + SX,Dodemorph + SX, Dodine + SX, Edifenphos + SX, Enoxastrobin + SX, Epoxiconazole + SX, Etaconazole + SX, Ethaboxam + SX, Ethirimol + SX, Etridiazole + SX, Famoxadone + SX, Fenamidone + SX, Fenaminstrobin + SX, Fenarimol + SX, Fenbuconazole + SX, Feneptamidoquin + SX, Fenfuram + SX, Fenhexamid + SX, Fenopyramid + SX, Fenoxanil + SX, Fenpiclonil + SX, Fenpicoxamid + SX, Fenpropidin + SX, Fenpropimorph + SX, Fenpyrazamine + SX, Fentin acetate + SX, Fentin chloride + SX, Fentin hydroxide + SX, Ferbam + SX, Ferimzone + SX, Florylpicoxamid + SX, Fluazinam + SX, Flubeneteram + SX, Fludioxonil + SX, Flufenoxadiazam + SX, Flufenoxystrobin + SX,Fluindapyr + SX, Flumetylsulforim + SX, Flumorph + SX, Fluopicolide + SX, Fluopyram + SX, Fluopimomide + SX, Fluoroimide + SX, Fluoxapiprolin + SX, Fluoxastrobin + SX, Fluoxytioconazole + SX, Fluquinconazole + SX, Fluquinometoate + SX, Flusilazole + SX, Flusulfamide + SX, Flutianil + SX, Flutolanil + SX, Flutriafol + SX, Fluxapyroxad + SX, Folpet + SX, Fosetyl + SX, Fosetyl-aluminium + SX, Fuberidazole + SX, Furalaxyl + SX, Furametpyr + SX, Galquin + SX, Guazatine + SX, Hexaconazole + SX, Hymexazole + SX, Imazalil + SX, Imibenconazole + SX, Iminoctadine + SX, Iminoctadine triacetate + SX, Iminoctadine trialbesilate + SX, Inpyrfluxam + SX, Iodocarb + SX,Ipconazole + SX, Ipflufenoquin + SX, Iprobenfos + SX, Iprodione + SX, Iprovalicarb + SX, Isofetamid + SX, Isoflucypram + SX, Isoprothiolane + SX, Isopyrazam + SX, Isotianil + SX, Kresoxim-methyl + SX, Mancozeb + SX, Mandestrobin + SX, Mandipropamid + SX, Maneb + SX, Mefentrifluconazole + SX, Mepanipyrim + SX, Mepronil + SX, Meptyldinocap + SX, Metalaxyl + SX, Metalaxyl-M + SX, Metarylpicoxamid + SX, Metconazole + SX, Methasulfocarb + SX, Metiram + SX, Metominostrobin + SX, Metrafenone + SX, Methyltetraprole + SX, Mineral oils + SX, Myclobutanil + SX, Naftifine + SX, Nuarimol + SX, Octhilinone + SX, Ofurace + SX, Orysastrobin + SX,Oxadixyl + SX, Oxathiapiprolin + SX, Oxine - copper + SX, Oxolinic acid + SX, Oxpoconazole + SX, Oxpoconazole fumarate + SX, Oxycarboxin + SX, Oxytetracycline + SX, Pefurazoate + SX, Penconazole + SX, Pencycuron + SX, Penflufen + SX, Penthiopyrad + SX, Phenamacril + SX, Phosphorous acid + SX, Phthalide + SX, Picarbutrazox + SX, Picoxystrobin + SX, Piperalin + SX, Potassium hydrogencarbonate + SX, Potassium dihydrogenphosphite + SX, Probenazole + SX, Prochloraz + SX, Procymidone + SX, Propamidine + SX, Propamocarb + SX, Propiconazole + SX, Propineb + SX, Proquinazid + SX, Prothiocarb + SX, Prothioconazole + SX, Pydiflumetofen + SX, Pyraclostrobin + SX, Pyrametostrobin + SX,Pyraoxystrobin + SX, Pyrapropoyne + SX, Pyraziflumid + SX, Pyrazophos + SX, Pyribencarb + SX, Pyributicarb + SX, Pyridachlometyl + SX, Pyrifenox + SX, Pyrimethanil + SX, Pyrimorph + SX, Pyriofenone + SX, Pyrisoxazole + SX, Pyroquilon + SX, Quinconazole + SX, Quinofumelin + SX, Quinoxyfen + SX, Quintozene + SX, Saccharin + SX, Saccharin sodium + SX, Saccharin potassium + SX, Saccharin calcium + SX, Saccharin ammonium + SX, Saccharin salt + SX, Seboctylamine + SX, Sedaxane + SX, Silthiofam + SX, Simeconazole + SX, Sodium carbonate peroxhydrate + SX, Sodium hydrogencarbonate + SX, Spiroxamine + SX, Sulfur + SX, Tebuconazole + SX, Tebufloquin + SX, Teclofthalam + SX, Tecnazene + SX, Terbinafine + SX, Tetraconazole + SX, Thiabendazole + SX,Thifluzamide + SX, Thiophanate + SX, Thiophanate-methyl + SX, Thiram + SX, Tiadinil + SX, Tolclofos-methyl + SX, Tolfenpyrad + SX, Tolprocarb + SX, Tolylfluanid + SX, Triadimefon + SX, Triadimenol + SX, Triazoxide + SX, Triclopyricarb + SX, Tricyclazole + SX, Tridemorph + SX, Trifloxystrobin + SX, Triflumizole + SX, Triforine + SX, Triticonazole + SX, Validamycin + SX, Valifenalate + SX, Vinclozolin + SX, Zinc thiazole + SX, Zineb + SX, Ziram + SX, Zoxamide + SX, 3-(Difluoromethyl)-N-methoxy-1-methyl-N-[(1R)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-48-7) + SX, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1S)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-49-8) + SX, 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide (141573-94-6) + SX, 3-(difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide (1513466-73-3) + SX, N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055589-28-9) + SX,N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylmethanimidamide (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylmethanimidamide (2101814-55-3) + SX, N'-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylmethanimidamide (1817828-69-5) + SX, [4-(difluoromethoxy)phenyl]methyl 4-[(N-ethyl-N-methylamino)methylidene]amino-2,5-dimethylbenzoate + SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, α-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229605-96-2) + SX, (αS)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-46-5) + SX, (αR)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-02-3) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S, 5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX, (1S, 2R, 5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol ( 1801930-07-3) + SX, (1R,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-53-8) + SX, (1S,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-54-9) + SX, (1R,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-55-0) + SX, (1S,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-56-1) + SX, (1R,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-57-2) + SX, (1S,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-58-3) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (1791398-02-1) + SX, methyl (1R,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-90-2) + SX, methyl (1S,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-91-3) + SX, methyl (1R,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-92-4) + SX,methyl (1S,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-93-5) + SX, methyl (1R,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-94-6) + SX, methyl (1S,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-95-7) + SX, methyl (1R,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-22-3) + SX, methyl (1S,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-23-4) + SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) + SX, (1R,2S,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S,2R,(5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, (1R,2R,3R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-08-4) + SX, (1S,2S,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-10-8) + SX, (1R,2R,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-13-1) + SX, (1S,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-16-4) + SX, (1R,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-20-0) + SX, (1S,2R,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-24-4) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX, methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-33-8) + SX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952305-97-3) + SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, 2-(difluoromethyl)-N-[(3R)-3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952306-00-1) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX, 5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-[(1S)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide + SX, N-[(1R)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide (2132414-06-1) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N'-ethyl-N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-acetyl-2-(ethanesulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9) + SX,3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromoindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX,3,3,3-trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide + SX, N-methoxy-N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-diethyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one + SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, ethyl 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylate + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine + SX, ethyl 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, ethyl 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-(Difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[Acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-Methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-Methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2,6-Difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(Oxetan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(Oxolan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(Oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX,5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX,3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, methyl ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl (Z)-2-(5-cyclopentyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-(5-cyclohexyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-[(3-isopropyl-1H-pyrazol-1-yl)-2-methylphenoxy]-3-methoxyprop-2-enoate + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one + SX, rel-N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[2-(pyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2S)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2R)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-(2-{6-[(1E)-(methoxyimino)ethyl]pyridin-2-yl}-2-(1-methylpyrazol-4-yl)propyl)-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(5-methylpyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-dichlorophenyl)isoxazole-3-carboxamide + SX, methyl 6-(2-{[5-(2,4-difluorophenyl)isoxazole-3-carbonyl]amino}-1-methyl-1-(1-methylpyrazol-4-yl)ethyl)pyridine-3-carboxylate + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-3-(2,4-difluorophenyl)-1,2,4-oxadiazole-5-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-Thiadiazole-2-carboxamide + SX, N-[2-(5-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,6-difluoropyridin-3-yl)-1,3,4-thiadiazole-2-carboxamide + SX.,
[0075] Combination of this component of group (c) and this compound: 1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 1,3,5-triazinane-2,4,6-trithione + SX, 2,3,5-triiodobenzoic acid + SX, IAA ((1H-indol-3-yl)acetic acid) + SX, IBA (4-(1H-indol-3-yl)butyric acid) + SX, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat-chloride + SX, chlorpropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, cyclanilide + SX, cyprosulfamide + SX, daminozide + SX, decan-1-ol + SX,dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat + SX, ethephon + SX, etychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX, Gibberellin A + SX, Gibberellin A3 + SX, inabenfide + SX, Kinetin + SX, lipochitooligosaccharide MOR116 + SX, lipochitooligosaccharide SP104 + SX, maleic hydrazide + SX, mefluidide + SX, mepiquat-chloride + SX, methyl-alpha-D-mannopyranoside + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione-calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, pyroglutamic acid + SX, sintofen + SX, sodium 1-naphthaleneacetate + SX, sodium cyanate + SX, thidiazuron + SX, titanium apatite + SX,Triapenthenol + SX, Tribufos + SX, Trinexapac-ethyl + SX, Uniconazole-P + SX, 2-(Naphthalen-1-yl)acetamide + SX, [4-Oxo-4-(2-phenylethyl)amino]butyric acid + SX, Methyl 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate + SX, 3-[(6-Chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, Strigolactone + SX, (1E)-1-[[1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-5-oxo-2H-pyrrol-2-yl]oxymethylene]-3,3a,4,8b-tetrahydroindeno[2,1-b]pyrrol-2-one as described in International Publication No. WO 2018 / 145979 + SX, (2R)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one as described in International Publication No. WO 2018 / 145979 + SX, (2S)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one as described in International Publication No. WO 2018 / 145979.,
[0076] Combination of the present component and the present compound of the above group (d): Allidochlor + SX, Benoxacor + SX, Cloquintocet + SX, Cloquintocet-mexyl + SX, Cyometrinil + SX, Cyprosulfamide + SX, Dichlormid + SX, Dicyclonone + SX, Dimepiperate + SX, Disulfoton + SX, Dymron + SX, Fenchlorazole + SX, Fenchlorazole-ethyl + SX, Fenclorim + SX, Flurazole + SX, Furilazole + SX, Fluxofenim + SX, Hexim + SX, Isoxadifen + SX, Isoxadifen-ethyl + SX, Jiecaowan + SX, Jiecaoxi + SX, Mecoprop + SX, Mefenpyr + SX, Mefenpyr-ethyl + SX, Mefenpyr-diethyl + SX, Mephenate + SX, Metcamifen + SX, Oxabetrinil + SX, 1,8-Naphthalic anhydride + SX, Octane-1,8-diamine + SX, AD-67 (4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5] decane) + SX, CL-304415 (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) + SX, CSB (1-bromo-4-[(chloromethyl)sulfonyl]benzene) + SX, DKA-24 (2,2-dichloro-N-[2-oxo-2-(2-propenylamino)ethyl]-N-(2-propenyl)acetamide) + SX, MG191 (2-(dichloromethyl)-2-methyl-1,3-dioxolane) + SX, MG-838 (2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate) + SX, PPG-1292 (2,2-dichloro-N-(1,3-dioxan-2-ylmethyl)-N-(2-propenyl)acetamide) + SX, R-28725 (3-(dichloroacetyl)-2,2-dimethyl-1,3-oxazolidine) + SX, R-29148 (3-(dichloroacetyl)-2,2,5-trimethyl-1,3-oxazolidine) + SX, TI-35 (1-(dichloroacetyl)azepane) + SX。
[0077] Combination of this component of group (e) and this compound: 1-Dodecyl-1H-imidazole + SX, N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide + SX, Bucarpolate + SX, N,N-dibutyl-4-chlorobenzenesulfonamide + SX, Dietholate + SX, Diethylmaleate + SX, Jiajizengxiaolin + SX, Octachlorodipropyl ether + SX, Perbutin + SX, Piperonyl butoxide + SX, Piperonyl cyclonene + SX, Piprotal + SX, Propyl isome + SX, Safroxan + SX, Sesamex + SX, Sesamolin + SX, Sulfoxide + SX, Verbutin + SX, DMC (1,1-bis(4-chlorophenyl)ethanol) + SX, FDMC (1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethanol) + SX, ETN (1,2-epoxy-1,2,3,4-tetrahydronaphthalene) + SX, ETP (1,1,1-trichloro-2,3-expoxypropane) + SX, PSCP (phenylsaligenin cyclic phosphate) + SX, TBPT (S,S,S-tributyl phosphorotrithioate) + SX, TPP (triphenyl phosphate) + SX。
[0078] Combination of the main component of the above group (f) and this compound: Anthraquinone + SX, Chloralose + SX, Acrep + SX, Butopyronoxyl + SX, Camphor + SX, d-Camphor + SX, Carboxide + SX, Dibutyl phthalate + SX, Deet + SX, Dimethyl carbate + SX, Dimethyl phthalate + SX, Dibutyl succinate + SX, Dibutyl adipate + SX, Ethohexadiol + SX, Hexamide + SX, Icaridin + SX, Methoquin-butyl + SX, Methylneodecanamide + SX, 2-(Octylthio)ethanol + SX, Butoxypolypropylene glycol + SX, Oxamate + SX, Quwenzhi + SX, Quyingding + SX, Zengxiaon + SX, Rebemide + SX, Copper naphthenate + SX, Zinc naphthenate + SX.
[0079] Combination of the main component of the above group (g) and this compound: Bis(tributyltin) oxide + SX, Allicin + SX, Bromoacetamide + SX, Calcium arsenate + SX, Cloethocarb + SX, Copper sulfate + SX, Fentin + SX, Ferric phosphate + SX, Metaldehyde + SX, Niclosamide + SX, Paris green + SX, Pentachlorophenol + SX, Sodium ferric EDTA + SX, Sodium pentachlorophenoxide + SX, Tazimcarb + SX, Tralopyril + SX, Tributyltin oxide + SX, Trifenmorph + SX.
[0080] Combination of this component of group (h) and this compound: (4Z,7Z)-deca-4,7-dien-1-yl acetate + SX, (2E)-dec-2-en-1-ol + SX, (4Z)-dec-4-en-1-yl acetate + SX, (5Z)-dec-5-en-1-ol + SX, (5Z)-dec-5-en-1-yl acetate + SX, (8Z)-dec-8-en-1-ol + SX, (7Z,13Z,16Z,19Z)-docosa-7,13,16,19-tetraen-1-ly isobutylate + SX, (7Z)-dodec-7-en-1-yl acetate + SX, (8Z)-dodec-8-en-1-ol + SX, (8E)-dodec-8-en-1-yl acetate + SX, (8Z)-dodec-8-en-1-yl acetate + SX, (9E)-dodec-9-en-1-yl acetate + SX, (9Z)-dodec-9-en-1-yl acetate + SX, (3Z)-dodec-3-en-1-yl (2E)-but-2-enoate + SX, (7E,9E)-dodeca-7,9-dien-1-yl acetate + SX, (7E,9Z)-dodeca-7,9-dien-1-yl acetate + SX, (7Z,9E)-dodeca-7,9-dien-1-yl acetate + SX, (8E,10E)-dodeca-8,10-dien-1-ol + SX, (8E,10E)-dodeca-8,10-dien-1-yl acetate + SX, (6Z)-henicos-6-en-1-one + SX, (9Z)-hexadec-9-enal + SX, (9Z)-hexadec-9-en-1-yl acetate + SX, (10Z)-hexadec-10-en-1-yl acetate + SX, (11Z)-hexadec-11-enal + SX, (11Z)-hexadec-11-en-1-ol + SX, (11Z)-hexadec-11-en-1-yl acetate + SX, (13Z)-hexadec-13-en-11-yn-1-yl acetate + SX, (7Z,11Z)-hexadeca-7,11-dienal + SX, (7E,11E)-hexadeca-7,11-dien-1-yl acetate + SX, (7E,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (7Z,11E)-hexadeca-7,11-dien-1-yl acetate + SX, (7Z,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (10E,12E)-hexadeca-10,12-dienal + SX, (11Z,13Z)-hexadeca-11,13-dienal + SX, (7Z,11Z,13Z)-hexadeca-7,11,13-trienal + SX, (7Z,11Z,13E)-hexadeca-7,11,13-trienal + SX, (13Z)-icos-13-en-10-one + SX, (2E)-6-methylhept-2-en-4-ol + SX, (11Z)-octadec-11-en-1-ol + SX, (11Z)-octadec-11-enal + SX, (13Z)-octadec-13-enal + SX, (2E,13Z)-octadeca-2,13-dien-1-ol + SX, (2E,13Z)-octadeca-2,13-dien-1-yl acetate + SX, (2Z,13Z)-octadeca-2,13-dien-1-yl acetate + SX, (3E,13Z)-octadeca-3,13-dien-1-ol + SX, (3E,13Z)-octadeca-3,13-dien-1-yl acetate + SX, (3Z,13Z)-octadeca-3,13-dien-1-ol + SX, (3Z,13Z)-octadeca-3,13-dien-1-yl acetate + SX, (7Z)-tetradec-7-enal + SX, (7Z)-tetradec-7-en-2-one + SX, (9Z)-tetradec-9-en-1-ol + SX, (9Z)-tetradec-9-en-1-yl acetate + SX, (11Z)-tetradec-11-enal + SX,(11E)-tetradec-11-en-1-yl acetate + SX, (11Z)-tetradec-11-en-1-yl acetate + SX, (3E,8Z)-tetradeca-3,8-dien-1-yl acetate + SX, (4E,10Z)-tetradeca-4,10-dien-1-yl acetate + SX, (8E,10Z)-tetradeca-8,10-dienal + SX, (9E,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,12E)-tetradeca-9,12-dien-1-yl acetate + SX, (3E,8Z,11Z)-tetradeca-3,8,11-trien-1-yl acetate + SX, (9E)-tricos-9-ene + SX, (4E)-tridec-4-en-1-yl acetate + SX, (4Z)-tridec-4-en-1-yl acetate + SX, allyl isothiocyanate + SX, 4-allylanisole + SX, 3-carene + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + eugenol + 2-phenylethyl propionate + SX, (Z)-2-(3,3-dimethylcyclohexylidene)ethanol + SX, (4R,8R)-4,8-dimethyldecanal + SX, (4R,8S)-4,8-dimethyldecanal + SX, 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo[3,2,1]octane + SX, 1,7-dioxaspiro[5,5]undecane + SX, dodecan-1-ol + SX, dodecyl acetate + SX, ethyl (2E,4Z)-deca-2,4-dienoate + SX, ethyl 4-methyloctanoate + SX, (2R,5R)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (2R,5S)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (E)-β-farnesene + SX, farnesyl alcohol + SX, ferrugineol + SX, geranyl hexanoate + SX, (E)-2-hexenyl butyrate + SX, (E)-2-hexenyl butyrate + hexyl butyrate + (E)-4-oxo-2-hexenal + SX, hexyl butyrate + SX, jasmone + SX, 3-ketopetromyzonol-24-sulfate ammonium salt + SX, methyl 2,6,10-trimethyldodecanoate + SX, methyl (2E,4E)-hepta-2,4-dienoate + SX, 2-methylbut-3-en-1-ol + SX, 2-(1-methyl-2-prop-1-en-2-ylcyclobutyl)ethanol + SX, 3-methylcyclohex-2-en-1-one + SX, (-)-4-methylheptan-3-ol + SX, 4-methylnonan-5-ol + SX, 4-methylnonan-5-one + SX, 14-methyloctadec-1-ene + SX, nepetalactone + SX, ocimene + SX, 1,2-octanediol + SX, oct-1-en-3-ol + SX, (R)-oct-1-en-3-ol + SX, olean + SX, 4-(3-oxobutyl)phenyl acetate + SX, (E)-4-oxo-2-hexenal + SX, pentacosane + SX, penta-termanone + SX, phenylacetaldehyde + SX, putrescine + SX, tetradecan-1-ol + SX,tetradecyl acetate + SX, tricosane + SX, tridecan-2-one + SX, 1,2,4-trimethoxybenzene + SX, trimethylamine + SX, trimethylamine hydrochloride + SX, 2-(undecyloxy)ethanol + SX, querciverol + SX, α-terpinene + SX, α-terpineol + SX, α-terpinoline + SX, animal tissue hydrolysate + SX, beet molasses-urea hydrolysate + SX, camphene + SX, capilure + SX, ceralure + SX, chalcogran + SX, codlelure + SX, codlemone + SX, copaene + SX, cosmolure + SX, cucujolide VIII + SX, cuelure + SX, cyclotene + SX, disparlure + SX, dominicalure + SX, endobrevicomin + SX, eugenol + SX, exitlure + SX, exobrevicomin + SX, farnesol + SX, ferrolure + SX, frontalin + SX, german cockroach pheromone + SX, gossyplure + SX, gossyplure HF + SX,Grandlure + SX, Grandlure I + SX, Grandlure II + SX, Grandlure III + SX, Grandlure IV + SX, Hexalure + SX, Ipsdienol + SX, Ipsenol + SX, Japonilure + SX, Lavandin oil + SX, Lineatin + SX, Litlue + SX, Looplure + SX, Medlure + SX, Megatomoic acid + SX, Methyl eugenol + SX, Multistriatin + SX, Muscalure + SX, Nerolidol + SX, Orfralure + SX, Oryctalure + SX, Ostramone + SX, Peachflure + SX, Prodenialure B + SX, Rescalure + SX, Rhyncolure + SX, Siglure + SX, Sordidin + SX, Sulcatol + SX, Trimedlure + SX, Trimedlure A + SX, Trimedlure B1 + SX, Trimedlure B2 + SX, Trimedlure C + SX, Trunc-call + SX, (E)-Verbenol + SX, (Z)-Verbenol + SX, Trans-verbenol + SX,(S)-verbenone + SX.,
[0081] Combination of the essential component of the above group (i) and this compound: 2,3,6-TBA (2,3,6-trichlorobenzoic acid) + SX, 2,3,6-TBA dimethylammonium + SX, 2,3,6-TBA lithium salt + SX, 2,3,6-TBA potassium salt + SX, 2,3,6-TBA sodium salt + SX, 2,4-D + SX, 2,4-D choline salt + SX, 2,4-D biproamine + SX, 2,4-D doboxyl + SX, 2,4-D 2-ethylhexyl + SX, 2,4-D 3-butoxypropyl + SX, 2,4-D ammonium + SX, 2,4-D butotyl + SX, 2,4-D butyl + SX, 2,4-D diethylammonium + SX, 2,4-D dimethylammonium + SX, 2,4-D diolamine salt + SX, 2,4-D dodecylammonium + SX, 2,4-D ethyl + SX, 2,4-D heptylammonium + SX, 2,4-D isobutyl + SX, 2,4-D isooctyl + SX, 2,4-D isopropyl + SX, 2,4-D isopropylammonium + SX, 2,4-D lithium salt + SX, 2,4-D mepty + SX, 2,4-D methyl(2,4-D-methyl) + SX, 2,4-D octyl + SX, 2,4-D pentyl + SX, 2,4-D propyl + SX, 2,4-D sodium salt + SX, 2,4-D tefuryl + SX, 2,4-D tetradecylammonium + SX, 2,4-D triethylammonium + SX, 2,4-D tris(2-hydroxypropyl)ammonium + SX, 2,4-D trolamine salt + SX, 2,4-DB + SX, 2,4-DB choline salt + SX, 2,4-DB biproamine + SX, 2,4-DB butyl + SX, 2,4-DB dimethylammonium + SX, 2,4-DB isooctyl + SX, 2,4-DB potassium salt + SX, 2,4-DB sodium salt + SX, acetochlor + SX, acifluorfen + SX, acifluorfen-sodium + SX, aclonifen + SX, ACN (2-amino-3-chloronaphthalene-1,4-dione) + SX, alachlor + SX, alloxydim + SX, ametryn + SX, amicarbazone + SX, amidosulfuron + SX, aminocyclopyrachlor + SX,Aminocyclopyrachlor-methyl + SX, Aminocyclopyrachlor-potassium + SX, Aminopyralid + SX, Aminopyralid choline salt + SX, Aminopyralid-potassium + SX, Aminopyralid-tripromine + SX, Amiprophos-methyl + SX, Amitrole + SX, Anilofos + SX, Asulam + SX, Atrazine + SX, Azafenidin + SX, Azimsulfuron + SX, Beflubutamid + SX, Benazolin-ethyl + SX, Bencarbazone + SX, Benfluralin + SX, Benfuresate + SX, Benquitrione + SX, Bensulfuron + SX, Bensulfuron-methyl + SX, Bensulide + SX, Bentazon + SX, Benthiocarb + SX, Benzfendizone + SX, Benzobicyclon + SX, Benzofenap + SX, Benzthiazuron + SX, Bialafosbialaphos + SX, Bicyclopyrone + SX, Bifenox + SX, Bipyrazone + SX, Bispyribac + SX,bispyribac-sodium + SX, bixlozone + SX, bromacil + SX, bromobutide + SX, bromofenoxim + SX, bromoxynil + SX, bromoxynil-octanoate + SX, butachlor + SX, butafenacil + SX, butamifos + SX, butroxydim + SX, butylate + SX, cafenstrole + SX, carbetamide + SX, carfentrazone + SX, carfentrazone-ethyl + SX, chlomethoxyfen + SX, chloramben + SX, chloridazon + SX, chlorimuron + SX, chlorimuron-ethyl + SX, chlorobromuron + SX, chlorotoluron + SX, chloroxuron + SX, chlorpropham + SX, chlorsulfuron + SX, chlorthal-dimethyl + SX, chlorthiamid + SX, cinflubrolin + SX, cinidon + SX, cinidon-ethyl + SX, cinmethylin + SX, cinosulfuron + SX, clethodim + SX, clodinafop + SX,Clodinafop-propargyl + SX, Clomazone + SX, Clomeprop + SX, Clopyralid + SX, Clopyralid choline salt + SX, Clopyralid-methyl + SX, Clopyralid-olamine + SX, Clopyralid-potassium + SX, Clopyralid-tris(2-hydroxypropyl)ammonium + SX, Cloransulam + SX, Cloransulam-methyl + SX, Cumyluron + SX, Cyanazine + SX, Cycloate + SX, Cyclopyranil + SX, Cyclopyrimorate + SX, Cyclosulfamuron + SX, Cycloxydim + SX, Cyhalofop + SX, Cyhalofop-butyl + SX, Cypyrafluone + SX, Dalapon + SX, Dazomet + SX, Desmedipham + SX, Desmetryn + SX, Di-allate + SX, Dicamba + SX, Dicamba choline salt + SX, Dicamba-biproamine + SX, Dicamba -trolamine + SX, Dicamba-diglycolamine + SX,Dicamba-dimethylammonium + SX, Dicamba-diolamine + SX, Dicamba-isopropylammonium + SX, Dicamba-methyl + SX, Dicamba-olamine + SX, Dicamba-potassium + SX, Dicamba-sodium + SX, Dichlobenil + SX, Dichlorprop choline salt + SX, Dichlorprop-biproamine + SX, Dichlorprop-2-ethylhexyl + SX, Dichlorprop-butotyl + SX, Dichlorprop-dimethylammonium + SX, Dichlorprop-ethylammonium + SX, Dichlorprop-isoctyl + SX, Dichlorprop-methyl + SX, Dichlorprop-P + SX, Dichlorprop-P choline salt + SX, Dichlorprop-P-biproamine + SX, Dichlorprop-P-etexyl + SX, Dichlorprop-P-dimethylammonium + SX, Dichlorprop-potassium + SX, Dichlorprop-sodium + SX, Diclofop + SX,Diclofop-methyl + SX, Diclosulam + SX, Difenoxuron + SX, Difenzoquat + SX, Difenzoquat metilsulfate + SX, Diflufenican + SX, Diflufenzopyr + SX, Diflufenzopyr - sodium + SX, Dimefuron + SX, Dimepiperate + SX, Dimesulfazet + SX, Dimethachlor + SX, Dimethametryn + SX, Dimethenamid + SX, Dimethenamid - P + SX, Dinitramine + SX, Dinoseb + SX, Dinoterb + SX, Dioxopyritrione + SX, Diphenamid + SX, Diquat - dibromide + SX, DSMA (Disodium methylarsonate) + SX, Dithiopyr + SX, Diuron + SX, DNOC (2 - methyl - 4,6 - dinitrophenol) + SX, Epyrifenacil + SX, Esprocarb + SX, Ethalfluralin + SX, Ethametsulfuron + SX, Ethametsulfuron - methyl + SX, Ethidimuron + SX, Ethofumesate + SX, Ethoxyfen - ethyl + SX, Ethoxysulfuron + SX, Etobenzanid + SX, Fenoxaprop + SX, Fenoxaprop - ethyl + SX, Fenoxaprop - P + SX,fenoxaprop-P-ethyl + SX, fenoxasulfone + SX, fenpyrazone + SX, fenquinotrione + SX, fentrazamide + SX, fenuron + SX, feproxydim + SX, flamprop-M + SX, flazasulfuron + SX, florasulam + SX, florpyrauxifen + SX, florpyrauxifen-benzyl + SX, fluazifop + SX, fluazifop-butyl + SX, fluazifop-P + SX, fluazifop-P-butyl + SX, fluazolate + SX, flucarbazone + SX, flucarbazone-sodium + SX, flucetosulfuron + SX, fluchloraminopyr + SX, fluchloraminopyr-tefuryl + SX, flufenacet + SX, flufenoximacil + SX, flufenpyr + SX, flufenpyr-ethyl + SX, flumetsulam + SX, flumetsulam + SX, flumiclorac + SX, flumiclorac-pentyl + SX, flumioxazin + SX, fluometuron + SX,Fluoroglycofen-ethyl + SX, Flupoxam + SX, Flupropanate + SX, Flupyrsulfuron + SX, Flupyrsulfuron-methyl-sodium + SX, Flurenol + SX, Fluridone + SX, Flurochloridone + SX, Fluroxypyr + SX, Fluroxypyr-butometyl + SX, Fluroxypyr-meptyl + SX, Flurtamone + SX, Flusulfinam + SX, Fluthiacet + SX, Fluthiacet-methyl + SX, Fomesafen + SX, Fomesafen-sodium + SX, Foramsulfuron + SX, Fosamine + SX, Glufosinate + SX, Glufosinate-ammonium + SX, Glufosinate-P + SX, Glufosinate-P-ammonium + SX, Glufosinate-P-sodium + SX, Glyphosate + SX, Glyphosate choline salt + SX, Glyphosate-isopropylammonium + SX, Glyphosate-biproamine + SX, Glyphosate-ammonium + SX, Glyphosate-diammonium + SX, Glyphosate-potassium + SX, Glyphosate-sodium + SX, Glyphosate-trimesium + SX, Halauxifen + SX, Halauxifen-benzyl + SX, Halauxifen-methyl + SX, Halosafen + SX, Halosulfuron + SX, Halosulfuron-methyl + SX, Haloxyfop + SX,Haloxyfop-etotyl + SX, Haloxyfop-methyl + SX, Haloxyfop-P + SX, Haloxyfop-P-etotyl + SX, Haloxyfop-P-methyl + SX, Hexazinone + SX, Icafolin + SX, Icafolin-methyl + SX, Imazamethabenz + SX, Imazamethabenz-methyl + SX, Imazamox + SX, Imazamox-ammonium + SX, Imazamox-sodium + SX, Imazapic + SX, Imazapic-ammonium + SX, Imazapyr + SX, Imazapyr-ammonium + SX, Imazapyr-isopropylammonium + SX, Imazaquin + SX, Imazaquin-ammonium + SX, Imazethapyr + SX, Imazethapyr-ammonium + SX, Imazosulfuron + SX, Indanofan + SX, Indaziflam + SX, Indolauxipyr + SX, Indolauxipyr-cyanomethyl + SX, Iodosulfuron + SX, Iodosulfuron-methyl-sodium + SX,Iofensulfuron + SX, Iofensulfuron-sodium + SX, Ioxynil + SX, Ioxynil-octanoate + SX, Ipfencarbazone + SX, Iptriazopyrid + SX, Isoproturon + SX, Isouron + SX, Isoxaben + SX, Isoxachlortole + SX, Isoxafenacil + SX, Isoxaflutole + SX, Lactofen + SX, Lenacil + SX, Linuron + SX, Maleic hydrazide + SX, MCPA choline salt + SX, MCPA-biproamine + SX, MCPA-etexyl + SX, MCPA-butotyl + SX, MCPA-butyl + SX, MCPA-dimethylammonium + SX, MCPA-diolamine + SX, MCPA-ethyl + SX, MCPA-isobutyl + SX, MCPA-isoctyl + SX, MCPA-isopropyl + SX, MCPA-methyl + SX, MCPA-olamine + SX, MCPA-sodium + SX, MCPA-trolamine + SX, MCPB (4-(4-chloro-2-methylphenoxy)butanoic acid) + SX,MCPB choline salt + SX, MCPB-biproamine + SX, MCPB-ethyl + SX, MCPB-methyl + SX, MCPB-sodium + SX, mecoprop choline salt + SX, mecoprop-biproamine + SX, mecoprop-2-ethylhexyl + SX, mecoprop-dimethylammonium + SX, mecoprop-diolamine + SX, mecoprop-ethadyl + SX, mecoprop-isoctyl + SX, mecoprop-methyl + SX, mecoprop-potassium + SX, mecoprop-sodium + SX, mecoprop-trolamine + SX, mecoprop-P + SX, mecoprop-P choline salt + SX, mecoprop-P-2-ethylhexyl + SX, mecoprop-P-dimethylammonium + SX, mecoprop-P-isobutyl + SX, mecoprop-P-potassium + SX, mefenacet + SX, mesosulfuron + SX, mesosulfuron-methyl + SX, mesotrione + SX, metam + SX, metamifop + SX,Metamitron + SX, Metazachlor + SX, Metazosulfuron + SX, Methabenzthiazuron + SX, Methiozolin + SX, Methyldymron + SX, Metobromuron + SX, Metolachlor + SX, Metoxuron + SX, Metosulam + SX, Metproxybicyclone + SX, Metribuzin + SX, Metsulfuron + SX, Metsulfuron-methyl + SX, Molinate + SX, Monolinuron + SX, Naproanilide + SX, Napropamide + SX, Napropamide-M + SX, Naptalam + SX, Neburon + SX, Nicosulfuron + SX, Norflurazon + SX, Oleic acid + SX, Orbencarb + SX, Orthosulfamuron + SX, Oryzalin + SX, Oxadiargyl + SX, Oxadiazon + SX, Oxasulfuron + SX, Oxaziclomefone + SX, Oxyfluorfen + SX, Paraquat + SX, Paraquat-dichloride + SX, Pebulate + SX, Pelargonic acid + SX, Pendimethalin + SX, Penoxsulam + SX, Pentanochlor + SX, Pentoxazone + SX, Pethoxamid + SX, Phenisopham + SX,phenmedipham + SX, picloram, picolinafen + SX, picolinafen + SX, pinoxaden + SX, piperophos + SX, pretilachlor + SX, primisulfuron + SX, primisulfuron-methyl + SX, prodiamine + SX, profluazol + SX, profoxydim + SX, prometon + SX, prometryn + SX, propachlor + SX, propanil + SX, propaquizafop + SX, propazine + SX, propham + SX, propisochlor + SX, propoxycarbazone + SX, propoxycarbazone-sodium + SX, propyrisulfuron + SX, propyzamide + SX, prosulfocarb + SX, prosulfuron + SX, pyraclonil + SX, pyraquinate + SX, pyrasulfotole + SX, pyrazolynate + SX, pyrazosulfuron + SX, pyrazosulfuron-ethyl + SX, pyrazoxyfen + SX, pyribenzoxim + SX, pyributicarb + SX,Pyridafol + SX, Pyridate + SX, Pyriflubenzoxim + SX, Pyriftalid + SX, Pyriminobac + SX, Pyriminobac-methyl + SX, Pyrimisulfan + SX, Pyrithiobac + SX, Pyrithiobac-sodium + SX, Pyroxasulfone + SX, Pyroxsulam + SX, Quinclorac + SX, Quinmerac + SX, Quizalofop + SX, Quizalofop-ethyl + SX, Quizalofop-tefuryl + SX, Quizalofop-P + SX, Quizalofop-P-ethyl + SX, Quizalofop-P-tefuryl + SX, Rimisoxafen + SX, Rimsulfuron + SX, Saflufenacil + SX, Sethoxydim + SX, EPTC (S-ethyl N,N-dipropylcarbamothioate) + SX, Siduron + SX, Simazine + SX, Simetryn + SX, S-metolachlor + SX, MSMA (sodium hydrogen methylarsonate) + SX, Sulcotrione + SX, Sulfentrazone + SX, Sulfometuron + SX, Sulfometuron-methyl + SX,Sulfosulfuron + SX, Swep + SX, TCA (2,2,2 - trichloroacetic acid) + SX, TCA - ammonium + SX, TCA - calcium + SX, TCA - ethadyl + SX, TCA - magnesium + SX, TCA - sodium + SX, Tebutam + SX, Tebuthiuron + SX, Tefuryltrione + SX, Tembotrione + SX, Tepraloxydim + SX, Terbacil + SX, Terbumeton + SX, Terbuthylazine + SX, Terbutryn + SX, Tetflupyrolimet + SX, Thaxtomin A + SX, Thenylchlor + SX, Thiazopyr + SX, Thidiazimin + SX, Thiencarbazone + SX, Thiencarbazone - methyl + SX, Thifensulfuron + SX, Thifensulfuron - methyl + SX, Tiafenacil + SX, Tiocarbazil + SX, Tolpyralate + SX, Topramezone + SX, Tralkoxydim + SX, Triafamone + SX, Tri - allate + SX, Triasulfuron + SX, Triaziflam + SX,Tribenuron + SX, tribenuron-methyl + SX, triclopyr + SX, triclopyr-butotyl + SX, triclopyr-ethyl + SX, triclopyr-triethylammonium + SX, tridiphane + SX, trietazine + SX, trifloxysulfuron + SX, trifloxysulfuron-sodium + SX, trifludimoxazin + SX, trifluralin + SX, triflusulfuron + SX, triflusulfuron-methyl + SX, tripyrasulfone + SX, tritosulfuron + SX, vernolate + SX, 4-(4-fluorophenyl)-6-[(2-hydroxy-6-oxo-1-cyclohexen-1-yl)carbonyl]-2-methyl-1,2,4-triazine-3,5(2H,4H)-dione + SX, 2-chloro-N-(1-methyl-1H-tetrazol-5-yl)-3-(methylthio)-4-(trifluoromethyl)benzamide + SX, 2-methyl-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-(methanesulfonyl)-4-(trifluoromethyl)benzamide + SX, 1-{2-chloro-6-[(5-chloropyrimidin-2-yl)oxy]phenyl}-4,4,4-trifluorobutan-1-one (2052297-97-7) + SX.,
[0082] Combination of the main component of the above group (j) and this compound:
[0083] Subgroup (j-1): Combination of the main component of bacteria and this compound: Acidovorax wautersii + SX, Agrobacterium radiobacter strain K1026 + SX, Agrobacterium radiobacter strain K84 + SX, Agrobacterium vitis strain VAR03-1 + SX, Arthrobacter globiformis + SX, Arthrobacter globiformis + Erwinia gerundensis + SX, Azorhizobium spp. + SX, Azorhizobium caulinodans strain ZB-SK-5 + SX, Azospirillum amazonense + SX, Azospirillum brasilense + SX, Azospirillum brasilense strain XOH + SX, Azospirillum brasilense strain Ab-V5 + SX, Azospirillum brasilense strain Ab-V6 + SX, Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Azotobacter + SX,Azotobacter chroococcum + SX, Azotobacter chroococcum strain H23 + SX, Azotobacter salinestris strain CECT9690 + SX, Azotobacter vinelandii strain ATCC12837 + SX, Bacillus acidocaldarius + SX, Bacillus acidoterrestris + SX, Bacillus agri + SX, Bacillus albolactis + SX, Bacillus alcalophilus + SX, Bacillus alvei + SX, Bacillus aminoglucosidicus + SX, Bacillus aminovorans + SX, Bacillus amyloliquefaciens strain PTA-4838 (Aveo (trademark) EZ Nematicide) + SX, Bacillus amyloliquefaciens strain AH2 + SX, Bacillus amyloliquefaciens strain AT79 + SX, Bacillus amyloliquefaciens strain AT332 + SX, Bacillus amyloliquefaciens strain B3 + SX,Bacillus amyloliquefaciens strain BV03 + SX, Bacillus amyloliquefaciens strain CECT7657 + SX, Bacillus amyloliquefaciens strain D203 + SX, Bacillus amyloliquefaciens strain D747 + SX, Bacillus amyloliquefaciens strain DB101 + SX, Bacillus amyloliquefaciens strain DB102 + SX, Bacillus amyloliquefaciens strain ENV503 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain GB03 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain IT-45 + SX, Bacillus amyloliquefaciens strain MBI600 + SX,Bacillus amyloliquefaciens strain R6-CDX + SX, Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens subsp. Plantarum strain D747 + SX, Bacillus amylolyticus + SX, Bacillus aneurinolyticus + SX, Bacillus atrophaeus + SX, Bacillus atrophaeus strain Abi05 + SX, Bacillus azotoformans + SX, Bacillus badius + SX, Bacillus cereus strain Ar56 + SX, Bacillus cereus strain B4 + SX, Bacillus cereus strain BP01 + SX, Bacillus cereus strain bromelia + SX, Bacillus cereus strain CIL + SX, Bacillus cereus CNCM strain I-1562 + SX, Bacillus cereus strain DGA34 + SX, Bacillus cereus strain N6 + SX, Bacillus cereus strain N7 + SX,Bacillus cereus strain peumo + SX, Bacillus cereus strain UW85 + SX, Bacillus chitinosporus strain AQ746 + SX, Bacillus chitinosporus strain CM-1 + SX, Bacillus circulans + SX, Bacillus coagulans strain TQ33 + SX, Bacillus fastidiosus + SX, Bacillus firmus strain GB-126 + SX, Bacillus firmus strain I-1582 + SX, Bacillus firmus strain NCIM2637 + SX, Bacillus lacticola + SX, Bacillus lactimorbus + SX, Bacillus lactis + SX, Bacillus lautus + SX, Bacillus lentimorbus + SX, Bacillus lentus + SX, Bacillus licheniformis strain copihue + SX, Bacillus licheniformis strain B000106 + SX, Bacillus licheniformis strain DSM17236 + SX,Bacillus licheniformis strain FMCH001 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus maroccanus + SX, Bacillus medusa + SX, Bacillus megaterium strain ATCC10778 + SX, Bacillus megaterium strain NCIM2087 + SX, Bacillus megaterium strain YFM3.25 + SX, Bacillus methylotrophicus strain BAC-9912 + SX, Bacillus methylotrophicus strain C1 + SX, Bacillus methylotrophicus isolate UFPEDA20 + SX, Bacillus metiens + SX, Bacillus mojavensis strain R3 + SX, Bacillus mojavensis strain SR11 + SX, Bacillus mycoides strain AQ726 + SX, Bacillus mycoides isolate J + SX, Bacillus nematocida + SX, Bacillus nigrificans + SX,Bacillus nigrum + SX, Bacillus popilliae + SX, Bacillus psychrosaccharolyticus + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain CCTB05 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus safensis strain HCX-01 + SX, Bacillus siamensis strain KCTC 13613 + SX, Bacillus simplex strain CGF2856 + SX, Bacillus smithii + SX, Bacillus sp. strain AQ175 + SX, Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b + SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus subtilis strain AFS032321 + SX, Bacillus subtilis strain antumavida + SX, Bacillus subtilis strain AP-01 + SX, Bacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain B246 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain BV02 + SX, Bacillus subtilis strain BV09 + SX, Bacillus subtilis strain C-3102 + SX, Bacillus subtilis strain CCTB04 + SX, Bacillus subtilis strain CX-9060 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain DB102 + SX, Bacillus subtilis strain FMCH002 + SX,Bacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX, Bacillus subtilis strain IAB / BS03 + SX, Bacillus subtilis strain MBI600 + SX, Bacillus subtilis strain DSM17231 + SX, Bacillus subtilis strain N5 + SX, Bacillus subtilis strain NCIM2063 + SX, Bacillus subtilis strain NCIM8872 + SX, Bacillus subtilis strain NSRS89-24 + SX, Bacillus subtilis strain PAH17 + SX, Bacillus subtilis strain QST30002 / AQ30002 + SX, Bacillus subtilis strain QST30004 / AQ30004 + SX, Bacillus subtilis strain QST713 + SX, Bacillus subtilis strain QST714 + SX, Bacillus subtilis strain RTI477 + SX,Bacillus subtilis strain S1 + SX, Bacillus subtilis strain S2 + SX, Bacillus subtilis strain SEIBS23 + SX, Bacillus subtilis strain UFPEDA764 + SX, Bacillus subtilis strain Y1336 + SX, Bacillus subtilis strain YL13 + SX, Bacillus subtillis subsp. natto + SX, Bacillus subtilis var. Amyloliquefaciens strain FZB24 + SX, Bacillus tequilensis strain 10b + SX, Bacillus tequilensis strain NII-0943 + SX, Bacillus thuringiensis strain 4042 + SX, Bacillus thuringiensis strain anemophila + SX, Bacillus thuringiensis strain AQ52 + SX, Bacillus thuringiensis strain BD#32 + SX, Bacillus thuringiensis strain CR-371 + SX, Bacillus thuringiensis strain EX297512 + SX,Bacillus thuringiensis subsp. aizawai strain ABTS-1857 + SX, Bacillus thuringiensis subsp. aizawai strain GC-91 + SX, Bacillus thuringiensis subsp. aizawai strain NB200 + SX, Bacillus thuringiensis subsp. aizawai Serotype H-7 + SX, Bacillus thuringiensis subsp. galleriae strain SDS-502 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 serotype H-14 + SX, Bacillus thuringiensis subsp. israelensis strain BMP144 + SX, Bacillus thuringiensis subsp. israelensis strain D142 + SX, Bacillus thuringiensis subsp. israelensis strain EG2215 + SX,Bacillus thuringiensis subsp. israelensis strain SA3A + SX, Bacillus thuringiensis subsp. israelensis strain SUM-6218 + SX, Bacillus thuringiensis subsp. israelensis strain VCRC B17 serotype 11-14 + SX, Bacillus thuringiensis subsp. japonensis + SX, Bacillus thuringiensis subsp. Kurstaki CrylA delta endotoxins + SX, Bacillus thuringiensis subsp. Kurstaki CrylC delta endotoxins + SX, Bacillus thuringiensis subsp. Kurstaki strain 3A3B + SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351 + SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306 + SX,Bacillus thuringiensis subsp. Kurstaki strain EG2348 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2371 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2424 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7673 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7826 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki strain F810 + SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1 + SX, Bacillus thuringiensis subsp. Kurstaki strain M-200 + SX, Bacillus thuringiensis subsp. Kurstaki strain NCIM2514 + SX, Bacillus thuringiensis subsp. Kurstaki strain PB54 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12 + SX, Bacillus thuringiensis subsp. Kurstaki strain VBTS-2546 + SX, Bacillus thuringiensis subsp. Kurstaki strain Z-52, serotype H-3a,3b + SX, Bacillus thuringiensis subsp. morrisoni + SX, Bacillus thuringiensis subsp. tenebriosis strain NB 176 + SX, Bacillus thuringiensis subsp. tenebriosis strain SA-10 + SX, Bacillus thuringiensis subsp. thuringiensis strain MPPL002 + SX, Bacillus thuringiensis subsp. var. colmeri + SXBacillus thuringiensis subsp. var. darmstadiensis strain 24-91 + SX, Bacillus thuringiensis subsp. var. dendrolimus + SX, Bacillus thuringiensis subsp. var. galleriae + SX, Bacillus thuringiensis subsp. var. japonensis strain buibui + SX, Bacillus thuringiensis subsp. var. aegypti + SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. sandiego strain M-7 + SX, Bacillus thuringiensis var. T36 + SX, Bacillus velezensis + SX, Bacillus velezensis isolate CNPSo3602 + SX, Bacillus velezensis strain ABi19 + SX, Bacillus velezensis strain FZB42 + SX, Bacillus velezensis strain FZB45 + SX, Bacillus velezensis strain NRRL B-41580 + SXBacillus velezensis strain RTI301 + SX, Bradyrhizobium spp. + SX, Bradyrhizobium elkanii + SX, Bradyrhizobium elkanii strain SEMIA 587 + SX, Bradyrhizobium elkanii strain SEMIA 5019 + SX, Bradyrhizobium japonicum + SX, Bradyrhizobium japonicum strain TA-11 + SX, Bradyrhizobium japonicum strain USDA 110 + SX, Bradyrhizobium japonicum strain WB74 + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Bradyrhizobium lupini strain LL13 + SX, Bradyrhizobium spp. (Arachis) + SX, Bradyrhizobium spp. (Vigna) + SX, Brevibacillus brevis strain maguellines I + SX, Brevibacillus brevis strain 2904 + SX, Brevibacillus brevis strain SS86-3 + SX,Brevibacillus brevis strain SS86-4 + SX, Brevibacillus brevis strain SS86-5 + SX, Brevibacillus laterosporus strain ATCC64 + SX, Brevibacillus laterosporus strain BPM3 + SX, Brevibacillus laterosporus strain G4 + SX, Brevibacillus laterosporus strain NCIMB 41419 + SX, Brevibacillus laterosporus strain NRS1111 + SX, Brevibacillus laterosporus strain NRS1645 + SX, Brevibacillus laterosporus strain NRS1647 + SX, Burkholderia ambifaria strain AMMD + SX, Burkholderia cenocepacia strain A396 + SX, Burkholderia cenocepacia strain Ral-3 + SX, Burkholderia cepacia type Wisconsin strain J82 + SX, Burkholderia cepacia type Wisconsin strain M54 + SX,Burkholderia cepacia + SX, Burkholderia gladii strain BA-7 + SX, Burkholderia rinojensis strain A396 + SX, Chromobacterium subtsugae strain PRAA4-1T + SX, Corynebacterium flavescens strain B2575 + SX, Corynebacterium glutamicum + SX, Delftia acidovorans + SX, Delftia acidovorans strain RAY209 + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Erwinia gerundensis + SX, Gluconacetobacter diazotrophicus strain IMI504853 + SX, Klebsiella variicola 137 + SX, Kosakonia cowanii strain SYM00028 + SX, Lactobacillus acidophilus + SX, Lactobacillus brevis + SX, Lactobacillus casei strain LPT-111 + SX, Lactobacillus plantarum + SX,Lactobacillus spp. + SX, Lysobacter antibioticus strain 13-1 + SX, Lysobacter enzymogenes strain B25 + SX, Lysobacter enzymogenes strain C3 + SX, Metylobacterium spp. + SX, Methylobacterium isolate ISO01 + SX, Methylobacterium isolate ISO02 + SX, Methylobacterium isolate ISO03 + SX, Methylobacterium isolate ISO04 + SX, Methylobacterium isolate ISO07 + SX, Methylobacterium isolate ISO09 + SX, Methylobacterium isolate ISO10 + SX, Methylobacterium isolate ISO11 + SX, Methylobacterium symbioticum + SX, Mesorhizobium spp. + SX, Mesorhizobium ciceri + SX, Mesorhizobium huakii + SX, Mesorhizobium loti + SX, Paenibacillus alvei strain 2771 + SX,Paenibacillus alvei strain 46C3 + SX, Paenibacillus alvei strain III2E + SX, Paenibacillus alvei strain III3DT-1A + SX, Paenibacillus alvei strain T36 + SX, Paenibacillus macerans + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Paenibacillus polymyxa strain H-5 + SX, Paenibacillus popilliae + SX, Pantoea agglomerans strain E325 + SX, Pantoea vagans strain C9-1 + SX, Pasteuria nishizawae strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria ramose + SX, Pasteuria usgae + SX, Pectobacterium carotovorum + SX, Pasteuria thornei + SX, Pseudomonas aeruginosa strain PN1 + SX, Pseudomonas aeruginosa strain WS-1 + SX, Pseudomonas aureofaciens strain TX-1 + SX, Pseudomonas alcaligenes + SX, Pseudomonas cepacia type Wisconsin strain J82 + SX,Pseudomonas cepacia type Wisconsin strain M54 + SX, Pseudomonas chlororaphis strain 63-28 + SX, Pseudomonas chlororaphis strain AFS009 + SX, Pseudomonas chlororaphis strain MA342 + SX, Pseudomonas entomophilla strain 1257 + SX, Pseudomonas fluorescens isolate Pf-5 + SX, Pseudomonas fluorescens strain 1629RS + SX, Pseudomonas fluorescens strain A506 + SX, Pseudomonas fluorescens strain ACK55 + SX, Pseudomonas fluorescens strain CL145A + SX, Pseudomonas fluorescens strain D7 + SX, Pseudomonas fluorescens strain G7090 + SX, Pseudomonas fluorescens biover B strain XJ3 + SX, Pseudomonas fluorescens biover B strain XS18 + SXPseudomonas fluorescens biover A strain LRS12 + SX, Pseudomonas proradix + SX, Pseudomonas putida strain CECT8538 + SX, Pseudomonas reactans + SX, Pseudomonas resinovorans + SX, Pseudomonas rhodesiae strain HAI-0804 + SX, Pseudomonas sp. strain CAB-02 + SX, Pseudomonas sp. strain DSMZ13134 + SX, Pseudomonas syringae strain 742RS + SX, Pseudomonas syringae strain ESC-10 + SX, Pseudomonas syringae strain ESC-11 + SX, Pseudomonas syringae strain MA-4 + SX, Pseudomonas trivialis + SX, Rhizobium etli + SX, Rhizobium galegae + SX, Rhizobium leguminosarum bv. Phaseoli + SX, Rhizobium leguminosarum bv. Trifolii + SX,Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Rhodococcus globerulus strain AQ719 + SX, Saccharopolyspora spinosa + SX, Serratia entomophila strain 626 + SX, Serratia marcescens strain 35 + SX, Serratia marcescens strain SRM + SX, Serratia nematodiphila strain S-CSR-0024 + SX, Sphingobacterium nematocida strain ZY-71-1 + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX, Streptomyces acidiscabies strain RL-110T + SX, Streptomyces candidus strain Y21007-2 + SX, Streptomyces colombiensis + SX, Streptomyces galbus strain QST6047 + SX, Streptomyces globosus strain LZH-48 + SX,Streptomyces goshikiensis + SX, Streptomyces griseofuscus strain 200101 + SX, Streptomyces griseoviridis strain K61 + SX, Streptomyces jalisciencis isolate CM-CNRG0001 + SX, Streptomyces jofer isolate CM-CNRG0002 + SX, Streptomyces lavendulae + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Streptomyces microflavus strain AQ6121 + SX, Streptomyces prasinus + SX, Streptomyces rimosus + SX, Streptomyces saraceticus + SX, Streptomyces sp. strain NRRL No.B-30145 + SX, Streptomyces sp. strain WYE20 + SX, Streptomyces sp. strain WYE 324 + SX, Streptomyces venezuelae + SX,Thiobacillus spp. + SX, Variovorax paradoxus strain GF4526 + SX, Virgibacillus pantothenticus strain ATCC14576 + SX, Virgibacillus pantothenticus strain DSM491 + SX, Wolbachia pipientis + SX, Xanthomonas campestris pv poae + SX, Xanthomonas campestris + SX, Xenorhabdus luminescens + SX, Xenorhabdus nematophila + SX.,
[0084] Subgroup (j-2): Combination of this component and this compound of fungi and yeasts Acaulospora spp. + SX, Acaulospora longula + SX, Alternaria destruens + SX, Alternaria destruens strain 59 + SX, Ambispora spp. + SX, Ambispora leptoticha + SX, Ampelomyces quisqualis strain AQ10 + SX, Ampelomyces quisqualis strain RSAQ7690 + SX, Ampelomyces quisqualis strain M-10 + SX, Archaeospora spp. + SX, Arkansas Fungus 18 + SX, Arthrobotrys dactyloides + SX, Arthrobotrys superba + SX, Aschersonia aleyrodis + SX, Aspergillus flavus strain AF36 + SX, Aspergillus flavus strain MUCL54911 + SX, Aspergillus flavus strain NRRL21882 + SX, Aureobasidium pullulans strain DSM14940 + SX, Aureobasidium pullulans strain DSM14941 + SX,Aureobasidium pullulans strain YBCA5 + SX, Beauveria bassiana isolate B21 + SX, Beauveria bassiana isolate B33 + SX, Beauveria bassiana isolate CBMAI1306 + SX, Beauveria bassiana strain 147 + SX, Beauveria bassiana strain 203 + SX, Beauveria bassiana strain 447 + SX, Beauveria bassiana strain ANT-03 + SX, Beauveria bassiana strain ATCC74040 + SX, Beauveria bassiana strain ATP02 + SX, Beauveria bassiana strain CFL-A + SX, Beauveria bassiana strain CG716 + SX, Beauveria bassiana strain ESALQ PL63 + SX, Beauveria bassiana strain GHA + SX, Beauveria bassiana strain HF23 + SX, Beauveria bassiana strain IBCB66 + SX, Beauveria bassiana strain IMI389521 + SX,Beauveria bassiana strain J25 + SX, Beauveria bassiana strain NCIM1216 ATCC26851 + SX, Beauveria bassiana strain NPP111B005 + SX, Beauveria bassiana strain PL63 + SX, Beauveria bassiana strain PPRI 5339 + SX, Beauveria bassiana strain R444 + SX, Beauveria bassiana strain ZJU435 + SX, Beauveria brongniartii + SX, Beauveria brongniartii isolate IMBST95.031 + SX, Beauveria brongniartii isolate IMBST95.041 + SX, Candida oleophila strain O + SX, Candida oleophila isolate I-182 + SX, Candida saitoana + SX, Candida spp. + SX, cell walls of Saccharomyces cerevisiae strain LAS117 + SX, Chaetomium cupreum + SX, Chlorella + SX, Chondrostereum purpureum + SX,Cladosporium cladosporioides strain H39 + SX, Claroideoglomus spp. (formerly Glomus spp.) + SX, Claroideoglomus claroideum (formerly Glomus claroideum) + SX, Claroideoglomus etunicatum (formerly Glomus etunicatum) + SX, Claroideoglomus luteum + SX, Clonostachys rosea strain ACM941 + SX, Clonostachys rosea strain CR-7 + SX, Clonostachys rosea strain IDAC 040913-01 + SX, Clonostachys rosea strain J1446 + SX, Colletotrichum gloeosporioides + SX, Conidiobolus obscurus + SX, Conidiobolus thromboide + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-08 + SX, Cryphonectria parasitica + SX, Cryptococcus albidus + SX,Cryptococcus flavescens + SX, Cylindrobasidium laeve + SX, Dactyllela ellipsospora + SX, Dectylaria thaumasia + SX, Dilophosphora alopecuri + SX, Diversispora spp. + SX, Enterococcus faecium + SX, Entomophthora virulenta + SX, Entrophospora spp. + SX, Entyloma ageratinae + SX, Epicoccum nigrum + SX, Funneliformis spp. (formerly Glomus spp.) + SX, Funneliformis mosseae (formerly Glomus mosseae) + SX, Fusarium oxysporum strain Fo47 + SX, Fusarium oxysporum strain RS-21 + SX, Fusarium oxysporum strain RS-25 + SX, Fusarium proliferatum strain NCIM1101 + SX, Geosiphon spp. + SX, Gigaspora spp. + SX, Gigaspora margarita + SX, Gigaspora rosea + SX,Gliocladium catenulatum strain J1446 + SX, Gliocladium roseum + SX, Gliocladium virens strain GL-21 + SX, Glomus spp. + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus etunicatum + SX, Glomus iranicum + SX, Glomus monosporum + SX, Hirsutella minnesotensis + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Isaria fumosorosea isolate B3 + SX, Isaria fumosorosea strain Isfm-CPF + SX, Isaria tenuipes + SX, Laccaria bicolor + SX, Laccaria laccata + SX, Lagenidium giganteum + SX, Lecanicillium lecanii KV01 + SX, Lecanicillium lecanii conidia of strain DAOM198499 + SX, Lecanicillium lecanii conidia of strain DAOM216596 + SX,Lecanicillium muscarium (formerly Verticillium lecanii) strain 1 / 1 + SX, Lecanicillium muscarium (formerly Verticillium lecanii) strain Ve6 + SX, Metarhizium anisopliae isolate D1 + SX, Metarhizium anisopliae isolate IBCB425 + SX, Metarhizium anisopliae strain CQMa421 + SX, Metarhizium anisopliae strain ESALQ E9 + SX, Metarhizium anisopliae strain ESF1 + SX, Metarhizium anisopliae strain F52 + SX, Metarhizium anisopliae strain FI-985 + SX, Metarhizium anisopliae strain FI-1045 + SX, Metarhizium anisopliae strain ICIPE30 + SX, Metarhizium anisopliae strain ICIPE62 + SX, Metarhizium anisopliae strain ICIPE69 + SX, Metarhizium anisopliae strain ICIPE78 + SX, Metarhizium anisopliae strain NCIM1311 + SX, Metarhizium anisopliae var. acridum strain EVCH077 + SX,Metarhizium anisopliae var. acridum isolate IMI 330189 + SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Metarhizium brunneum strain Cb15-III + SX, Metarhizium flavoviride strain F001 + SX, Metarhizium rileyi strain PHP1705 + SX, Metschnikowia fructicola strain NRRLY-27328 + SX, Metschnikowia fructicola strain NRRLY-30752 + SX, Microdochium dimerum strain L13 + SX, Microsphaeropsis ochracea + SX, Monacrosporium phymatopagum + SX, Mucor hiemalis + SX, Muscodor albus strain 620 + SX, Muscodor albus strain QST 20799 + SX, Muscodor albus strain SA13 + SX, Muscodor roseus strain A3-5 + SX,Myrothecium verrucaria strain AARC-0255 + SX, Nomuraea rileyi strain CG128 + SX, Nomuraea rileyi strain GU87401 + SX, Nomuraea rileyi strain SA86101 + SX, Nomuraea rileyi strain SR86151 + SX, Nomuraea rileyi strain VA9101 + SX, Ophiostoma piliferum strain D97 + SX, Pacispora spp. + SX, Paecilomyces fumosoroseus Apopka strain 97, Now, Isaria fumosorosea Apopka strain 97 + SX, Paecilomyces fumosoroseus strain FE9901, Now, Isaria fumosorosea strain FE9901 + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 + SX, Paecilomyces variotii strain Q-09 + SX, Pandora delphacis + SX, Paraglomus spp. + SX,Paraglomus brasilianum (formerly Glomus brasilianum) + SX, Penicillium bilaiae strain ATCC22348 + SX, Penicillium citrinum strain VFI-51 + SX, Penicillium vermiculatum + SX, Phlebiopsis gigantea strain FOC PG410.3 + SX, Phlebiopsis gigantea strain VRA1835 + SX, Phlebiopsis gigantea strain VRA1984 + SX, Phlebiopsis gigantea strain VRA1985 + SX, Phlebiopsis gigantea strain VRA1986 + SX, Phlebiopsis gigantea strain VRA1992 + SX, Phlebiopsis spp. + SX, Phoma macrostroma strain 94-44B + SX, Phytophthora palmivora + SX, Pichia anomala strain WRL-076 + SX, Pichia guilliermondii strain Z1 + SX, Pichia guilliermondii strain Z8 + SX, Pisolithus tinctorius + SX,Pochonia chlamydosporia isolate strain PC10 + SX, Pochonia chlamydosporia + SX, Pseudozyma flocculosa strain ATTC64874 + SX, Pseudozyma flocculosa strain PF-A22UL + SX, Puccinia thlaspeos strain woad + SX, Purpureocillium lilacinum strain 251 + SX, Purpureocillium lilacinum strain PL11 + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Racocetra spp. + SX, Rhizophagus spp. (formerly Glomus spp.) + SX, Rhizophagus clarus (formerly Glomus clarum) + SX, Rhizophagus intraradices (formerly Glomus intraradices) + SX, Rhizophagus intraradices strain RTI-801 + SX, Rhizophagus irregularis (formerly Glomus intraradices) + SX, Rhizophagus irregularis strain DAOM 197198 + SXScutellospora spp. + SX, Rhizopogon amylopogon + SX, Rhizopogon fulvigleba + SX, Rhizopogon luteolus + SX, Rhizopogon villosullus + SX, Saccharomyces cerevisiae strain LAS02 + SX, Saccharomyces cerevisiae strain DDSF623 + SX, Saccharomyces cerevisiae strain SP.1026 + SX, Scleroderma cepa + SX, Scleroderma citrinum + SX, Sclerotinia minor strain IMI34414 + SX, Sporothrix insectorum + SX, Suillus granulatus + SX, Suillus punctatapies + SX, Talaromyces flavus strain SAY-Y-94-01 + SX, Talaromyces flavus strain V117b + SX, Trichoderma afroharzianum + SX, Trichoderma album + SX, Trichoderma asperelloides strain JM41R + SX,Trichoderma asperellum strain CBMAI840 + SX, Trichoderma asperellum strain CBMAI1622 + SX, Trichoderma asperellum strain BV09 + SX, Trichoderma asperellum strain BV10 + SX, Trichoderma asperellum strain ICC012 + SX, Trichoderma asperellum strain kd + SX, Trichoderma asperellum strain M103 + SX, Trichoderma asperellum strain RNCIM F-1323 + SX, Trichoderma asperellum T11 + SX, Trichoderma asperellum T25 + SX, Trichoderma asperellum strain T34 + SX, Trichoderma asperellum strain SKT-1 + SX, Trichoderma asperellum strain TV1 + SX, Trichoderma atroviride strain 77B + SX, Trichoderma atroviride strain CNCM 1-1237 + SX, Trichoderma atroviride strain I-1237 + SX, Trichoderma atroviride strain IMI 206040 + SX, Trichoderma atroviride strain K4 + SX, Trichoderma atroviride strain LC52 + SX, Trichoderma atroviride strain LU132 + SX, Trichoderma atroviride strain SC1 + SX, Trichoderma atroviride strain SKT-1 + SX, Trichoderma atroviride strain T11 + SX, Trichoderma atroviride strain TV1 + SX, Trichoderma atroviride strain WW10TC4 + SX, Trichoderma gamsii strain ICC080 + SX, Trichoderma harmatum strain 382 + SX, Trichoderma harmatum strain TH382 + SX, Trichoderma harzianum strain 21 + SX,Trichoderma harzianum strain AP-001 + SX, Trichoderma harzianum strain BK-Th001 + SX, Trichoderma harzianum strain CBS101525 + SX, Trichoderma harzianum strain DB 104 + SX, Trichoderma harzianum strain DSM 14944 + SX, Trichoderma harzianum strain ESALQ-1303 + SX, Trichoderma harzianum strain ESALQ-1306 + SX, Trichoderma harzianum strain F11Bab + SX, Trichoderma harzianum strain Gomorteka + SX, Trichoderma harzianum strain IB19 / 17 + SX, Trichoderma harzianum strain IBLF006 + SX, Trichoderma harzianum strain IIHR-Th-2 + SX, Trichoderma harzianum strain ITEM908 + SX, Trichoderma harzianum strain K2 + SX, Trichoderma harzianum strain kd + SX,Trichoderma harzianum strain KRL-AG2 + SX, Trichoderma harzianum strain MO1 + SX, Trichoderma harzianum strain queule + SX, Trichoderma harzianum strain RR17Bc + SX, Trichoderma harzianum strain SF + SX, Trichoderma harzianum strain T5 + SX, Trichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T24 + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma harzianum strain TH315 + SX, Trichoderma harzianum rifai + SX, Trichoderma koningii + SX, Trichoderma lignorum strain TL-0601 + SX, Trichoderma lignorum + SX, Trichoderma longibrachiatum strain T-397 + SX,Trichoderma polysporum strain IMI206039 + SX, Trichoderma parceramosum + SX, Trichoderma reesei + SX, Trichoderma strain SKT-1 + SX, Trichoderma spp. + SX, Trichoderma saturnisporium strain PBP-TH-001 + SX, Trichoderma stromaticum + SX, Trichoderma virens strain chagual + SX, Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 (formaly Gliocladium virens GL-21) + SX, Trichoderma virens strain nire + SX, Trichoderma virens strain sherwood + SX, Trichoderma viride strain (NRRL B-50520) + SX, Trichoderma viride strain K5 + SX, Trichoderma viride strain T111 + SX, Tsukamurella paurometabola strain C-924 + SX, Tsukamurella paurometabola + SX,Typhula phacorrhiza strain 94671 + SX, Ulocladium oudemansii strain HRU3 + SX, Ulocladium oudemansii strain U3 + SX, Verticillium alboatrum strain WCS850 + SX, Verticillium chlamydosporium + SX, Verticillium dahliae + SX, Verticillium lecanii strain ID05-F0117 + SX, Verticillium lecanii strain NCIM1312 + SX, Verticillium lecanii strain SZWL7 + SX, Zoophtora radicans + SX.,
[0085] Subgroup (j-3): Combination of the present component of protozoa and the present compound: Nosema locustae + SX, Thelohania solenopsis + SX, Vairimorpha spp. strain Q-09 + SX.
[0086] Subgroup (j-4): Combination of the present component of virus and the present compound: Adoxophyes orana granulovirus strain BV-0001 + SX, Agrotis segetum nucleopolyhedrovirus + SX, Anagraoha falcifera nucleopolyhedrovirus + SX, Anticarsia gemmatalis multiple nucleocapsid nucleopolyhedrovirus + SX, Autographa californica multiple nucleopolyhedrovirus strain FV11 + SX, Autographa californica multiple nucleopolyhedrovirus strain R3 + SX, Bacteriophage of Clavibacter michiganesis + SX, Bacteriophage active against Clavibacter michiganensis subsp. michiganensis + SX, Bacteriophage active against Erwinia amylovora + SX, Bacteriophage active against Pseudomonas syringae pv. tomato + SX, Bacteriophage active against Xanthomonas campestris pv. vesicatoria + SX, Bacteriophage active against Xanthomonas citri subsp. citri + SX, Bacteriophage against Xylella fastidiosa + SX, Biston suppressaria nucleopolyhedrovirus + SX, Bombyx mori nucleopolyhedrovirus + SX,Chrysodeixis includens NPV isolate 460 + SX, Cryptophlebia leucotreta GV + SX, Cydia pomonella GV + SX, Cydia pomonella GV M + SX, Cydia pomonella GV strain CP4 + SX, Cydia pomonella GV strain R5 + SX, Cydia pomonella GV strain V15 + SX, Cydia pomonella GV strain V22 + SX, Douglas fir tussock moth NPV + SX, Dendrolimus punctatus cypovirus + SX, Ectropis obliqua picorna-like virus + SX, Helicoverpa armigera NPV + SX, Helicoverpa armigera NPV strain BV-0003 + SX, Helicoverpa zea NPV + SX, Indian meal moth GV + SX, Leucoma salicis NPV + SX, Lymantria dispar MNPV + SX, Mamestra brassicae NPV + SX,Mamestra configurata NPV + SX, Neodiprion abietis NPV + SX, Neodiprion lecontei NPV + SX, Neodiprion sertifer NPV + SX, Orgyia pseudotsugata NPV + SX, pepino mosaic virus strain CH2 isolate 1906 + SX, pepino mosaic virus strain CH2 isolate Abp1 + SX, pepino mosaic virus strain CH2 isolate Abp2 + SX, pepino mosaic virus isolate VC1 + SX, pepino mosaic virus isolate VX1 + SX, Phthorimaea operculella GV isolate DSMZ GV-0019 + SX, Pieris rapae GV + SX, Plodia interpunctella GV + SX, Plutella xylostella GV + SX, Spodoptera albula MNPV + SX, Spodoptera exempta MNPV + SX,Spodoptera exigua multiple nucleopolyhedrovirus BV-0004 strain (Spodoptera exigua MNPV strain BV-0004) + SX, Spodoptera frugiperda multiple nucleopolyhedrovirus (Spodoptera frugiperda MNPV) + SX, Spodoptera littoralis multiple nucleopolyhedrovirus DSMZ BV-0005 isolate (Spodoptera littoralis MNPV isolate DSMZ BV-0005) + SX, Spodoptera litura nucleopolyhedrovirus (Spodoptera litura NPV) + SX, Tobacco mild tobamovirus strain U2 (Tobacco mild tobamovirus strain U2) + SX, Zucchini Yellow Mosaik Virus weak strain (Zucchini Yellow Mosaik Virus weak strain) + SX.,
[0087] Subgroup (j-5): combination of the main component of the nematode and this compound: Abbreviata caucasica + SX, Acuaria spp. + SX, Agamermis decaudata + SX, Allantonema spp. + SX, Amphimermis spp. + SX, Deladenus siricidicola + SX, Bovienema spp. + SX, Cameronia spp. + SX, Chitwoodiella ovofilamenta + SX, Contortylenchus spp. + SX, Culicimermis spp. + SX, Diplotriaena spp. + SX, Empidomermis spp. + SX, Filipjevimermis leipsandra + SX, Gastromermis spp. + SX, Gongylonema spp.) + SX, Gynopoecilia pseudovipara + SX, Heterorhabditis bacteriophora + SX, Heterorhabditis baujardi + SX, Heterorhabditis downesi + SX, Heterorhabditis heliothidis + SX, Heterorhabditis indica + SX, Heterorhabditis marelatus + SX, Heterorhabditis megidis + SX, Heterorhabditis zealandica + SX, Hexamermis spp. + SX, Hydromermis spp. + SX, Isomermis spp. + SX, Limnomermis spp. + SX, Maupasina weissi + SX, Mermis nigrescens + SX, Mesomermis spp. + SX, Neomesomermis spp. + SX, Neoparasitylenchus rugulosi + SX, Octomyomermis spp. + SX, Parasitaphelenchus spp. + SX, Parasitorhabditis spp. + SX, Parasitylenchus spp.) + SX, Perutilimermis culicis + SX, Phasmarhabditis hermaphrodita isolate DDT M1 + SX, Physaloptera spp. + SX, Protrellatus spp. + SX, Pterygodermatites spp. + SX, Romanomermis spp. + SX, Seuratum cadarachense + SX, Sphaerulariopsis spp. + SX, Spirura guianensis + SX, Steinernema bibionis + SX, Steinernema carpocapsae + SX, Steinernema feltiae isolate DDT D2 + SX, Steinernema glaseri + SX, Steinernema indica + SX, Steinernema kraussei + SX, Steinernema riobrave + SX, Steinernema scapterisci + SX, Steinernema scarabaei + SX, Steinernema siamkayai + SX, Steinernema thailandse + SX, Steinernema spp.) + SX, Strelkovimermis peterseni + SX, Subulura spp. + SX, Sulphuretylenchus elongatus + SX, Tetrameres spp. + SX.
[0088] Subgroup (j-6): Combination of the main component of the natural product and this compound: (2S,3R,4R,5S)-2,5-bis(hydroxymethyl)pyrrolidine-3,4-diol + SX, 1,4-dimethylnaphthalene + SX, 2-methyl-1-butanol + SX, 2-phenylethyl propionate + SX, 9,21-didehydroyanodine + SX, alizarin 2-glucoside + SX, dihydroazadirachtin + SX, ethyl 3-[acetyl(butyl)amino]propanoate + SX, glycerol monocaprate + SX, glycerol monocaprylate + SX, glycerol monolaurate + SX, heptyl butyrate + SX, methyl anthranilate + SX, methyl nonyl ketone + SX, methyl salicylate + SX, N-(3-methyl-2-buten-1-yl)-9H-purin-6-amine + SX, N,N'-diformylurea + SX, octanal + SX, oxypurinol + SX, p-cymene + SX, p-menthane-3,8-diol + SX, phenazine-1-carboxylic acid + SX, propylene glycol monocaprylate + SX, propylene glycol monolaurate + SX, sorbitol octanoate + SX, sucrose octanoate + SX, terpinen-4-ol + SX, balsam fir oil (Abies balsamea oil) + SX, α-ionone + SX, β-citronellol + SX, gamma-terpinene + SX, ammonium bicarbonate + SX, anabasine + SX, anise oil + SX,Ascaridole + SX, Azadirachtin + SX, Bark of Celastrus angulatus + SX, Brassica juncea + SX, Brassinolide + SX, Bacillus thuringiensis Cry1Ab protein + SX, Bacillus thuringiensis Cry1Ac protein + SX, Bacillus thuringiensis Cry1Fa protein + SX, Bacillus thuringiensis Cry1A.105 protein + SX, Bacillus thuringiensis Cry2Ab protein + SX, Bacillus thuringiensis Vip3A protein + SX, Bacillus thuringiensis mCry3A protein + SX, Bacillus thuringiensis Cry3Ab protein + SX, Bacillus thuringiensis Cry3Bb protein + SX,Bacillus thuringiensis-derived Cry34Ab1 / Cry35Ab1 protein + SX, insecticidal protein Tma12 derived from the fern plant Tectaria macrodonta + SX, insecticidal protein IPD083 derived from the fern plant Adiantum spp. + SX, insecticidal protein IPD113 derived from Pteris cretica cv. albolineata or Pteris umbrosa + SX, calcium acetate + SX, calcium lactate + SX, calcium polysulfide + SX, Canola oil + SX, capsicin + SX, Capsicum oleoresin + SX, Castor oil + SX, Cedarwood oil + SX, cevadine + SX, chitin + SX, Chitosan + SX, chlorophyllin + SX, chlortetracycline + SX, cinerin I + SX, cinerin II + SX, cinnamaldehyde + SX, cis-jasmone + SX, citral + SX, citric acid + SX,Citronella oil + SX, Citrus bergamia fruit oil + SX, clarified hydrophobic extract of neem oil + SX, Clove oil + SX, Collagen protein hydrolysate + SX, colletochlorin B + SX, concanamycin A + SX, cottonseed oil + SX, cytokinin + SX, cow's milk + SX, deguelin + SX, diallyl sulfide + SX, d-limonene + SX, dried leaves of Dryopteris filix-mas + SX, Ea peptide 91398 + SX, eucalyptol + SX, extract of Acacia mearnsii + SX, extract of Achillea fragrantissima + SX, extract of Allium cepa + SX, extract of Allium sativum + SX, extract of Anethum graveolens + SX, extract of Annona squamosa + SX, extract of Arctium lappa + SX, extract of Artemisia absinthium + SX, extract of Artocarpus heterophyllus + SX,Extract of Azadirachta indica + SX, Extract of Calendula officinalis + SX, Extract of Camelia sinensis + SX, Extract of Capsicum annum + SX, Extract of Cassia nigricans + SX, Extract of Chenopodium ambrosioides + SX, Extract of Chenopodium quinoa + SX, Extract of Cinnamomum verum + SX, Extract of Clitoria ternatea + SX, Extract of the cotyledons of lupine plantlets ("BLAD") + SX, Extract of Daphne gnidium + SX, Extract of Equisetum arvense + SX, Extract of Equisetum giganteum + SX, Extract of Galenia africana + SX, Extract of green tea + SX, Extract of Liliaceae + SX, Extract of Macleaya + SX, Extract of Matricaria chamomilla + SX, Extract of Melaleuca alternifolia + SX, Extract of Millettia pinnata + SX,Extract of Opuntia lindheimeri + SX, extract of Origanum vulgare + SX, extract of Piper auritum + SX, extract of Pyrethrum, extract of Quercus falcata + SX, extract of Quillaja saponaria + SX, extract of Reynoutria sachalinensis + SX, extract of Rhamnus utilis + SX, extract of Rhus aromatica + SX, extract of Rheum officinale + SX, extract of Rhizophora mangle + SX, extract of Rosmarinus officinalis + SX, extract of Ruta chalepensis + SX, extract of Schoenocaulon spp. seed + SX, extract of Sweet lupin seed + SX, extract of Swinglea glutinosa + SX, extract of Symphytum officinale + SX, extract of Sweet lupinseed + SX, extract of Tagetes erecta + SX, extract of Tanacetum vulgare + SX, extract of Thymus vulgaris + SX,Nasturtium extract + SX, Nettle extract + SX, Mistletoe extract + SX, Yucca schidigera extract + SX, Fenugreek seed powder + SX, Fish oil + SX, Formic acid + SX, Geraniol + SX, Ginkgolide A + SX, Ginkgolide B + SX, Ginkgolide C + SX, Ginkgolide J + SX, Ginkgolide M + SX, Gougerotin + SX, GS-omega / kappa HXTX-Hv1a peptide + SX, Harpin protein + SX, Hydrogenated castor oil + SX, Hydroprene + SX, Star anise oil + SX, Ivermectin + SX, Jasmolin I + SX, Jasmolin II + SX, Jojoba oil + SX, Karanjin + SX, Kasugamycin + SX, Kinoprene + SX, Laminarine + SX, L-ascorbic acid + SX, Oak leaves and bark + SX, Lemongrass oil + SX, L-glutamic acid + SX, Linalool + SX,Linseed oil + SX, Lobularia maritima + SX, lysophosphatidylethanolamine + SX, maltodextrin + SX, matrine + SX, matrine N-oxide + SX, menthol + SX, methoprene + SX, Milbemycin A4 + SX, Mildiomycin + SX, Natamycin + SX, Nemadectin + SX, Nepeta cataria oil + SX, Nootkatone + SX, Oil of the seeds of Chenopodium anthelminticum + SX, Orange oil + SX, Pelargonium odoratissimum oil + SX, Pellitorine + SX, Piperine + SX, Piper nigrum seed oil + SX, Polyoxin B + SX, Polyoxorim + SX, Potassium phosphonate + SX, Potassium silicate + SX, Precocene II + SX, Putrescent whole egg solids + SX, Pyrethrin I + SX, Pyrethrin II + SX, Quillaja extract + SX, Rotenone + SX, Rapeseed oil + SX, Rhamnolipid + SX, Ryanodine + SX, Rosemary oil + SX, Sabadilla + SX, Salicylic acid + SX, Sanguinarine + SX, Saponins of Chenopodium quinoa + SX, Sesame oil + SX, Soy lecithin + SX,Soybean oil + SX, spinosad + SX, Squamocin + SX, streptomycin + SX, sunflower oil + SX, Tagetes oil + SX, terpene constituents of the extract of chenopodium ambrosioides near ambrosioides, Brand name: Terpenoid blend QRD 460 + SX, Thyme oil + SX, thymol + SX, trypsin modulating oostatic factor + SX, Veratrine + SX, veratridine + SX, wood extract of Quassia amara + SX, Xanthine + SX, yellow mustard powder + SX.,
[0089] Subgroup (j-7): Combinations of the essential components of the insect and this compound: Two-spotted ladybird (Adalia bipunctata) + SX, Amitus hesperidum + SX, Amitus spiniferus + SX, Anagrus atomus + SX, Anagrus epos + SX, Anagyrus fusciventris + SX, Anagyrus fusciventris + SX, Anagyrus pseudococci + SX, Anaphes flavipes + SX, Parasitic wasp (Anaphes iole) + SX, Anaphes nitens + SX, Anastatus tenuipes + SX, Anthocoris nemoralis + SX, Aphelinus abdominalis + SX, Aphelinus asychis + SX, Aphelinus mali + SX, Aphelinus semiflavus + SX, Aphidius colemani + SX, Aphidius ervi + SX, Aphidius gifuensis + SX, Aphidius matricariae + SX, Aphidius smithi + SX, Aphidoletes aphidimyza + SX, Aphytis holoxanthus + SX, Aphytis lepidosaphes + SX, Aphytis lignanensis + SX, Aphytis melinus + SX, Aphytis mytilaspidis + SX, Apion fuscirostre + SX, Apion ulicis + SX, Aprostocetus hagenowii + SX, Avetianella longoi + SX, Bangasternus orientalis + SX, Bathyplectes anurus + SX, Bathyplectes curculionis + SX, Bracon cushmani + SX,Bracon gelechiae + SX, Bracon hebetor + SX, Cales noacki + SX, Calosoma sycophanta + SX, Carcinops pumillio + SX, Catolaccus grandis + SX, Cephalonomia tarsalis + SX, Chilocorus baileyi + SX, Chilocorus bipustulatus + SX, Chilocorus circumdatus + SX, Chilocorus kuwanae + SX, Chilocorus nigritus + SX, Chilocorus stigma + SX, Chrysoperla carnea + SX, Chrysoperla rufilabris + SX, Clitostethus arcuatus + SX, Coccidoxenoides perminutus + SX, Coccophagus cowperi + SX, Coccophagus lycimnia + SX, Coenosia attenuata + SX, Coleomegilla maculata + SX, Comperia merceti + SX, Comperiella bifascita + SX, Copidosoma floridanum + SX, Copidosoma truncatellum + SX, Cotesia flavipes + SX, Cotesia glomerata + SX, Cotesia marginiventris + SX, Cotesia medicaginis + SX, Cotesia melanoscela + SX, Cotesia plutellae + SX, Cotesia ruficrus + SX, Cryptolaemus montrouzieri + SX, Cybocephalus nipponicus + SX,Dacnusa sibirica + SX, Dalotia coriaria + SX, Delphastus catalinae + SX, Delphastus pusillus + SX, Dendrolimus punctatus + SX, Deraeocoris brevis + SX, Diaeretiella rapae + SX, Dicyphus hesperus + SX, Diglyphus isaea + SX, Encarsia aurantii + SX, Encarsia formosa + SX, Encarsia inaron + SX, Encarsia opulenta + SX, Encarsia perplexa + SX, Ephedrus cerasicola + SX, Episyrphus balteatus + SX, Eretmocerus eremicus + SX, Eretmocerus mundus + SX, Feltiella acarisuga + SX, Franklinothrips megalops + SX, Franklinothrips orizabensis + SX, Franklinothrips vespiformis + SX, Geocoris punctipes + SX, Glyptapanteles liparidis + SX, Goniozus legneri + SX, Harmonia axyridis + SX, Hippodamia convergens + SX, Hyposoter exiguae + SX, Hyposoter fugitivus + SX, Lariophagus distinguendus + SX, Leptomastidea abnormis + SX, Leptomastix algirica + SX, Leptomastix dactylopii + SX,Horsefly (Leptomastix epona) + SX, Lydella thompsoni + SX, Lysiphlebus testaceipes + SX, Macrocentrus ancylivorus + SX, Macrocentrus iridescens + SX, Macrolophus pygmaeus + SX, Mallada signata + SX, Metaphycus bartletti + SX, Metaphycus californicus + SX, Metaphycus flavus + SX, Metaphycus funicularis + SX, Metaphycus helvolus + SX, Metaphycus luteolus + SX, Metaphycus stanleyi + SX, Meteorus autographae + SX, Meteorus laphygmae + SX, Meteorus pulchricornis + SX, Meteorus trachynotus + SX, Metoecus paradoxus + SX, Microctonus aethiopoides + SX, Minute Damsel Bug (Micromus angulatus) + SX, Micromus tasmaniae + SX, Micromus variegatus + SX, Microplitis brassicae + SX, Microplitis plutellae + SX, Microterys flavus + SX, Muscidifurax raptor + SX, Muscidifurax raptorellus + SX, Nabis kinbergii + SX, Necremnus artynes + SX, Neochrysocharis formosa + SX, Neodryinus typhlocybae + SX, Nesidiocoris tenuis + SX, Orius albidipennis + SX, Orius armatus + SX, Orius insidiosus + SX, Orius laevigatus + SX,Orius majusculus + SX, Orius niger + SX, Orius strigicollis + SX, Orygia pseudotsugata + SX, Pediobius foveolatus + SX, Pentalitomastix plethorica + SX, Pnigalio flavipes + SX, Podisus maculiventris + SX, Praon volucre + SX, Pseudaphycus maculipennis + SX, Psyllaephagus pilosus + SX, Rhapalosiphum padi + SX, Rhizophagus grandis + SX, Rhyzobius forestieri + SX, Rhyzobius lophantae + SX, Vedalia beetle (Rodolia cardinalis) + SX, Scolothrips sexmaculatus + SX, Serangium parcesetosum + SX, Spalangia cameroni + SX, Spalangia endius + SX, Stethorus punctillum + SX, Sympiesis stigmata + SX, Telenomus podisi + SX, Chinese mantis (Tenodera sinensis) + SX, Tetrastichus brevistigma + SX, Tetrastichus gallerucae + SX, Tetrastichus howardi + SX, Tetrastichus setifer + SX, Thripobius semiluteus + SX, Chinese long-tailed wasp (Torymus sinensis) + SX, Trichogramma achaeae + SX, Trichogramma brassicae + SX, Trichogramma evanescens + SX, Trichogramma minutum + SX, Trichogramma ostriniae + SX, Trichogramma platneri + SX,Trichogramma pretiosum + SX, Trichogramma semifumatum + SX, Trichogrammatoidea bactrae + SX, Trichopoda pennipes + SX, Trioxys complanatus + SX, Trioxys curvicaudus + SX, Trioxys pallidus + SX, Trioxys tenuicaudus + SX, Trissolcus basalis + SX, Vairimorpha necatrix + SX, Volucella inanis + SX, Voria ruralis + SX, Southern fleahopper (Xylocoris flavipes) + SX, Zelus renardii + SX.,
[0090] Subgroup (j-8): Combination of the main components of mites and this compound: Amblydromalus limonicus + SX, Amblyseius andersoni + SX, Amblyseius barkeri + SX, Amblyseius californicus + SX, Amblyseius cucumeris + SX, Amblyseius degenerans + SX, Amblyseius montdorensis + SX, Amblyseius swirskii + SX, Amblyseius womersleyi + SX, Anystis agilis + SX, Cheyletus eruditus + SX, Euseius gallicus + SX, Euseius stipulatus + SX, Euseius tularensis + SX, Gaeolaelaps gillespiei + SX, Galendromus annectens + SX, Galendromus helveolus + SX, Galendromus occidentalis + SX, Hypoaspis aculeifer + SX, Hypoaspis miles + SX, Macrocheles robustulus + SX, Mesoseiulus longipes + SX, Neoseiulus fallacis + SX, Phytoseiulus macropilis + SX, Phytoseiulus persimilis + SX, Thyreophagus entomophagus + SX, Typhlodromus pyri + SX。
[0091] Subgroup (j-9): Combination of the present component of mollusks and the present compound: Rumina decollata + SX。
[0092] The component selected from group (j) is usually prepared by methods known in the art. For example, in the case of (j-1) bacteria or (j-2) fungi / yeasts, it is prepared using media and fermentation methods known in the art. When this component is (j-1) bacteria or (j-2) fungi / yeasts, the preparation contains from 1×104 to 1×1013 CFU (colony forming units), preferably from 1×108 to 1×1012 CFU of this component per gram. When this component is (j-4) virus, the preparation contains from 1×104 to 1×1013 occlusion bodies (sometimes denoted as Obs), preferably from 1×108 to 1×1012 occlusion bodies (sometimes denoted as Obs) of this component per gram. When this component is (j-5) nematodes, the preparation contains from 1×104 to 1×1013 individuals, preferably from 1×108 to 1×1012 individuals of the component per gram.
[0093] This compound can be mixed or used in combination with chemical fertilizers (such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.).
[0094] The weight ratio of the application rate of this compound to the application rate of this component in composition A is not particularly limited, but can be appropriately adjusted to an optimal weight ratio depending on the type of plant to be protected, the types and occurrence frequencies of harmful arthropods, harmful nematodes, harmful mollusks, phytopathogenic microorganisms or weeds to be controlled, the formulation form, the application time, the application method, the application location, the weather conditions, etc. For example, in the agricultural field, when applying to plants (especially foliage, seeds, vegetative reproductive organs) or to the cultivation carrier (especially soil) for cultivating plants, the following weight ratios can be mentioned. Note that the weight of the component selected from group (j) means the weight of its preparation. For example, a weight ratio of 1:500 means that the application rate of the preparation of one or more components selected from group (j) is 500 parts by weight per 1 part by weight of this compound.
[0095] Weight ratio [(this compound):(this component)] = 1:10^15 to 10^15:1. Specifically, for example, approximately, 1:10^15, 1:10^14, 1:10^13, 1:10^12, 1:10^11, 1:10^10, 1:10^9, 1:10^8, 1:10^7, 1:10^6, 1:10^5, 1:10000, 1:9000, 1:8000, 1:7000, 1:6000, 1:5000, 1:4000, 1:3000, 1:2000, 1:1000, 1:900, 1:800, 1:700, 1:600, 1:500, 1:400, 1:350, 1:300, 1:250, 1:200, 1:150, 1:100, 1:90, 1:80, 1:70, 1:60, 1:50, 1:40, 1:30, 1:20, 1:19, 1:18, 1:17, 1:16, 1:15, 1:14, 1:13, 1:12, 1:11, 1:10, 1:9, 1:8, 1:7, 1:6, 1:5, 2:9, 1:4, 2:7, 3:10, 1:3, 3:8, 2:5, 3:7, 4:9, 1:2, 5:9, 4:7, 3:5, 5:8, 2:3, 7:10, 5:7, 3:4, 7:9, 4:5, 5:6, 6:7, 7:8, 8:9, 9:10, 1:1, 10:9, 9:8, 8:7, 7:6, 6:5, 5:4, 9:7, 4:3, 7:5, 10:7, 3:2, 8:5, 5:3, 7:4, 9:5, 2:1, 9:4, 7:3, 5:2, 8:3, 3:1, 10:3, 7:2, 4:1, 9:2, 5:1, 6:1, 7:1, 8:1, 9:1, 10:1, 11:1, 12:1, 13:1, 14:1, 15:1, 16:1, 17:1, 18:1, 19:1, 20:1, 30:1, 40:1, 50:1, 60:1, 70:1, 80:1, 90:1, 100:1, 150:1, 200:1, 250:1, 300:1, 400:1, 500:1, 600:1, 700:1, 800:1, 900:1, 1000:1, 2000:1, 3000:1, 4000:1, 5000:1, 6000:1, 7000:1, 8000:1, 9000:1, 10000:1, 10^5:1, 10^6:1, 10^7:1, 10^8:1, 10^9:1, 10^10:1, 10^11:1, 10^12:1, 10^13:1, 10^14:1, 10^15:1. Here, the caret symbol '^' is an operator representing exponentiation. For example, '10^5' means '105' (i.e., 10 to the power of 5).The "approximate" in the preceding paragraph includes a range of ratios that are 10% higher or lower by weight ratio with respect to the specified ratio. For example, if it is approximately 1:2, it includes the range of 1:1.8 to 1:2.2.
[0096] This compound or composition A is usually used as a composition (hereinafter referred to as composition B) further containing an inert carrier. Composition B is usually prepared by mixing this compound or composition A with a solid carrier, a liquid carrier, a surfactant, etc., and adding formulation adjuvants such as a binder, a dispersant, a stabilizer, a gas, etc. as necessary, and formulating it into an aqueous suspension formulation, an oily suspension formulation, an emulsion, an emulsion formulation, a microemulsion formulation, a microcapsule formulation, a wettable powder, a granular wettable powder, a powder, a granule, a tablet, an aerosol, a resin formulation, etc. for use. Not limited to these formulations, it can be formulated into the dosage forms described in the Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers - 271~276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2016, ISSN:0259-2517 for use. In addition, composition B can be, for example, a spray (aerosol, pump spray, ultrasonic vibration type formulation, electrostatic spray type formulation, etc.), a bait agent, an incendiary agent (such as a mosquito coil), a heating evaporation agent (electric mosquito mat, liquid mosquito repellent formulation, etc.), a blowing evaporation agent (fan type mosquito repellent formulation, etc.), a fumigant (self-combustible type fumigant, chemical reaction type fumigant, porous ceramic plate fumigant, etc.), a fumigation agent, a smoke agent, an ultra-low volume (ULV) agent, a mist agent, a foam agent, a paste-like formulation, a paint, a wood protection paint, a sealing material, a carbon dioxide gas formulation, a sheet formulation, a tape formulation, a paper formulation, a non-woven fabric formulation, an animal collar, an animal ear tag, a shampoo, a spot-on agent, a pour-on agent, a suppository, an injection, an oral treatment agent (capsule, tablet, chewable, feed, etc.), a sublimable tablet, a mosquito net, an attractant cord, a gardening support, a screen door, and may be processed and used. These formulations usually contain this compound in a weight ratio of 0.0001 to 99%, preferably 0.1 to 99%, more preferably 0.2 to 90%.
[0097] When formulating this compound or composition A into an aqueous suspension formulation, an oily suspension formulation, a wettable powder, or a granule wettable powder, the particle size of this compound or composition A is usually in the range of 0.1 to 20 μm, preferably 0.2 μm to 15 μm. Also, when formulating this compound or composition A into granules, the particle size of this compound or composition A is usually in the range of 0.1 to 200 μm, preferably 0.5 μm to 100 μm. The particle size of this compound or composition A means the particle size (volume median diameter) at which the cumulative frequency is 50% in the volume-based frequency distribution, and it can be determined by wet measurement using a laser diffraction particle size distribution measuring device. Examples of the laser diffraction particle size measuring device include the Mastersizer 3000 manufactured by Malvern. In the volume-based frequency distribution, the cumulative frequency can also be expressed based on any percentage other than the median (50%), and the preferred range can also be expressed as "the volume 40% diameter is 2.5 μm to the volume 60% diameter is 2.5 μm", etc. Also, it can be expressed by the weight median diameter in addition to the volume median diameter, and further, it can be expressed as any percentage.
[0098] Examples of the solid carrier include the following. Inorganic substances: minerals (natural silicates, marble, pumice, limestone, rare earth minerals, cryolite, activated clay, lime, activated carbon, talc, attapulgite, sodium montmorillonite, calcium montmorillonite, kaolinite, calcite, dolomite, diatomite, bentonite, zeolite, sepiolite, pyrophyllite, vermiculite, crystalline silica, amorphous silica, etc.), silicon dioxide, calcium sulfate, magnesium sulfate, barium sulfate, magnesium oxide, aluminum oxide, ammonium sulfate, ammonium phosphate, ammonium nitrate, calcium phosphate, sulfur, calcium carbonate, sodium bicarbonate, sodium carbonate, synthetic silicates, and ground products thereof; Organic substances: cereal powders (rice bran, rice flour, corn powder, wheat flour, etc.), saccharides (cellulose, starch, lactose, glucose, fructose, sucrose, etc.), plant-derived powders (nut shell pulverized products (pulverized products of coconut, walnut, peanut, etc. nut shells), tree-derived powders (bark powder, sawdust, etc.), other plant pulverized products (tobacco stems, soybeans, cottonseed hulls, etc.)), lignin, wax, shells, urea, polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinyl pyrrolidone-methacrylic acid copolymer, polyvinyl pyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenolic resins, melamine resins, epoxy resins. Also, the above solid carrier can also be used as an adsorption carrier.
[0099] Examples of the liquid carrier include water, aliphatic hydrocarbons (hexane, 1 - hexene, cyclohexane, octane, isooctane, 1 - heptene, d - limonene, pinene, hexadecane, etc.), aromatic hydrocarbons (alkylbenzenes (toluene, xylene, isopropylbenzene, p - diethylbenzene, etc.), derivatives of alkylbenzenes, alkylnaphthalenes, derivatives of alkylnaphthalenes, tetrahydronaphthalene, etc.), chlorinated hydrocarbons (monochloroethylene, dichloroethylene, trichloroethylene, tetrachloroethylene, dichloromethane, 1,1,1 - trichloroethane, 1,1,2 - trichloroethane, 1,2 - dichloropropane, etc.), ketones (cyclohexanone, acetone, 2 - heptanone, isophorone, mesityloxide, methyl isopentyl ketone, methyl ethyl ketone, methyl isobutyl ketone, acetophenone, diacetone alcohol, methylcyclohexanone, etc.), esters (fatty acid esters (ethyl acetate, butyl acetate, amyl acetate, isoamyl acetate, isobornyl acetate, hexyl acetate, heptyl acetate, octyl acetate, isopropyl myristate, methyl octanoate, methyl oleate, methyl laurate, dibutyl adipate, tributyl citrate, dibutyl phthalate, etc.), lactate esters (ethyl lactate, propyl lactate, etc.), carbonate esters (ethylene carbonate, propylene carbonate, butylene carbonate, diethyl carbonate, dibutyl carbonate, etc.), esterified polyols (glycerol acetate, glycol acetate, glycerol monoacetate, glycerol diacetate, glycerol triacetate, diethylene glycol abietate, dipropylene glycol dibenzoate, dipropylene glycol monomethyl ester, etc.), lactones (γ - butyrolactone, etc.), ethers (1,4 - dioxane, tetrahydrofuran, dipropylene glycol methyl ether, ethylene glycol methyl ether, propylene glycol methyl ether, etc.), amides (N - octyl - caprolactam, N - dodecyl - caprolactam, N,N - dimethylformamide, fatty acid dimethylamides (N,N - dimethylacetamide, N,N - dimethyldecanamide, N,N-dimethyloctanamide, etc.), alkylpyrrolidones (N-methylpyrrolidone, N-octyl-pyrrolidone, N-dodecyl-pyrrolidone, etc.), lactams (α-lactam, β-lactam, γ-lactam, δ-lactam, etc.), amines (octylamine, octylamine acetate, oleylamine, diethanolamine, laurylamine, etc.), alcohols (methanol, ethanol, butanol, propanol, isopropanol, butanol, amyl alcohol, hexanol, heptanol, octanol, 2-ethylhexanol, etc.), hexylene glycol, cyclohexanol, phenol, benzyl alcohol, methoxypropanol (1-methoxy-2-propanol), tetrahydrofurfuryl alcohol, furfuryl alcohol, polyethylene glycol, ethylene glycol, diethylene glycol, hexylene glycol, ethylene glycol methyl ether, diethylene glycol methyl ether, diethylene glycol butyl ether, triethylene glycol, propylene glycol methyl ether, dipropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol ether, dipropylene glycol monomethyl ether, glycerin, etc.), mineral oils (naphtha, petroleum ether, kerosene, diesel oil, paraffin, olefin, etc.), oils derived from animals and plants, vegetable oils (palm oil, rapeseed oil, castor oil, coconut oil, soybean oil and its derivatives, etc.), animal oils (sardine oil, saury oil, whale oil and its derivatives, etc.), dimethyl sulfoxide, silicone oil, acetonitrile, propanenitrile, acid anhydrides (acetic anhydride, etc.), triethyl phosphate, oleic acid, propionic acid, lactic acid, xylene sulfonic acid.
[0100] Examples of the gaseous carrier include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide gas.
[0101] Examples of the anionic surfactant include carboxylic acids, sulfonic acids, sulfuric acid esters, and phosphoric acid esters, and specific examples thereof are as follows. Carboxylic acids: fatty acid salts (octanoate, decanoate, laurate, myristate, palmitate, stearate, behenate, oleate, polyoxyethylene alkyl ether carboxylate (laureth-3-carboxylate, α-(carboxymethyl)-ω-(dodecyloxy)poly(oxyethylene) salt, etc.), N-acyl sarcosine salt (N-lauroyl sarcosine salt, etc.), N-acyl glutamate salt (N-lauroyl glutamate salt, etc.), polycarboxylate (polyacrylate, polyvinyl acetate, comb-shaped polymer of polyacid salt, and its derivatives, etc.), Sulfonic acids: alkyl sulfonic acid and its salts (dodecyl sulfonate, etc.), alpha olefin sulfonate (alkene (C14-18) hydroxy sulfonate, alkapolyene (C12-20) hydroxy sulfonate, alkene (C14-18) hydroxy sulfonate, alkene (C12-20) hydroxy sulfonate, tetradecene-1-sulfonate, α-olefin (C14-16) sulfonate, etc.), alkyl benzene sulfonate (decyl benzene sulfonate, dodecyl benzene sulfonate, tridecyl benzene sulfonate, diphenyl sulfonate, etc.), alkyl naphthalene sulfonate (naphthalene sulfonate, 6-methyl-2-naphthalene sulfonate, dibutyl naphthalene sulfonate, 2,2'-dinaphthylmethane-6,6'-disulfonate, diisopropylnaphthalenesulfonate, triisopropylnaphthalenesulfonate, 1-isopropyl-2-naphthalenesulfonate, etc.), sulfosuccinic acid, monoalkylsulfosuccinate, dialkylsulfosuccinate, (di(2-ethylhexyl)sulfosuccinate, etc.), N-methyl-N-acyltaurine salt (oleoylmethyltaurine salt, etc.), ligninsulfonate, alkylphenolsulfonate, naphthalenesulfonate-formaldehyde condensate, benzimidazolesulfonate and its derivatives, as sulfate esters, alkyl sulfates (hexyl sulfate, heptyl sulfate, octyl sulfate, lauryl sulfate, lauryl sulfate diethanol salt, hexadecyl sulfate, octadecyl sulfate, etc.), polyoxyethylene alkyl ether sulfate and its salts (laureth-3-sulfate, polyoxyethylene monotridecyl ether sulfate, α-sulfo-ω-hydroxyalkyl (C6-10) ether poly(oxyethylene) salt, etc.), polyoxyethylene alkyl phenyl ether sulfate (poly(oxyethylene) 2-decylphenyl ether sulfate, poly(oxyethylene) 3-decylphenyl ether sulfate, α-sulfo-ω-[2,4-bis(1,1,3,3-tetramethylbutyl)phenoxy]poly(oxyethylene) salt, etc.), polyoxypropylene alkyl ether sulfate, lignosulfite waste liquor, and derivatives thereof;, Phosphate esters: alkyl phosphates (propyl phosphate, hexadecyl phosphate, lauryl phosphate, dioctyl phosphate, etc.), polyoxyethylene alkyl ether phosphates (polyoxyethylene decyl phosphate ester, α-phosphono-ω-butoxy poly(oxyethylene), etc.), polyoxyethylene alkyl phenyl ether phosphates (α-(dinonylphenyl)-ω-hydroxy poly(oxyethylene) phosphate ester, α-(dodecylphenyl)-ω-hydroxy poly(oxyethylene) phosphate ester, α-(nonylphenyl)-ω-hydroxy poly(oxyethylene) phosphate ester, etc.), polyoxypropylene alkyl ether phosphates, and derivatives thereof.
[0102] Examples of cationic surfactants include amine salts and quaternary ammonium salts, and specifically, the following can be mentioned. Amine salts: alkylamine salts (monomethylamine salt, dimethylamine salt, trimethylamine salt, etc.), fatty acid amide amine salts (stearamidopropyldimethylamine, behenamidopropyldimethylamine, etc.), polyamine salts (polyvinylamine, polyethyleneimine, etc.), and their derivatives; Quaternary ammonium salts: lauryltrimethylammonium salt, cetyltrimethylammonium salt, dodecyltrimethylammonium salt, stearyltrimethylammonium salt, benzalkonium chloride, benzethonium chloride, benzylbis(2-chloroethyl)ethylammonium bromide salt.
[0103] Examples of amphoteric surfactants include betaine, alkyl betaine, alkyldimethyl betaine, imidazoline, taurine, alkyl taurine, dodecyldimethylammonioacetate, 4-carboxy-N,N,N-trimethyl-1-butanaminium, 1-carboxy-N,N,N-2-tetramethyl-1-propanaminium, N-alkyl(or alkenyl)(C12-18) glycine and its salts, N-dodecylglycine and its salts, and their derivatives.
[0104] Examples of nonionic surfactants include alcohols, amides, amines, esters, ethers, ether esters, and carboxylic acids, and specifically, the following can be mentioned. Alcohols: aromatic alcohols (alkylphenols (allylphenol, octylphenol, nonylphenol, octylcresol, etc.), acylphenols, etc.), aliphatic alcohols (isotridecyl alcohol, oleyl alcohol, cetyl alcohol, etc.), polyhydric alcohols (polysaccharides, starch, starch derivatives, sucrose, alkyl polyglucoside, sorbitan, ethoxylated sorbitan, cellulose derivatives, gum arabic, etc.), synthetic polymers (polyvinyl alcohol, polyethylene glycol, etc.); Amides: alkanolamides (fatty acid alkanolamides (such as diethanol laurate), fatty acid glucamides (such as alkoxylated propylene oxide fatty acid glucamides), alkoxylated amides (such as polyoxyethylene oleic acid amide, polyoxyethylene stearic acid amide), synthetic polymers (such as polyvinylpyrrolidone), Amines: alkoxylated amines (such as polyoxyethylene oleylamine, α,α'-[(9-octadecenylimino)di-2,1-ethanediyl]bis(ω-hydroxy)polyoxyethylene); Esters: fatty acid esters (such as fatty acid esters of polyols, monoglycerides, phospholipids), esters derived from sugars (such as sucrose fatty acid esters (such as sucrose distearate), sorbitan fatty acid esters (such as sorbitan monooleate), glucose esters, cellulose esters), synthetic polymers (such as vinyl acetate copolymers, polymethacrylic acid, copolymers of methacrylic acid and methacrylic acid esters); Ethers: alcohol ethoxylates (such as aliphatic alcohol ethoxylates (such as tridecyl alcohol ethoxylate, isooctyl alcohol ethoxylate, lauryl alcohol ethoxylate, hexadecyl alcohol ethoxylate, stearyl alcohol ethoxylate)), alkylphenol ethoxylates (such as nonylphenol ethoxylate, tristyrylphenol ethoxylate, tributylphenol ethoxylate, octylphenol ethoxylate), arylalkylphenol ethoxylates, arylphenol ethoxylates (such as monobenzylbiphenol alcohol ethoxylate), alcohol propoxylates (such as aliphatic alcohol propoxylates, alkylphenol propoxylates, arylalkylphenol propoxylates), block polymers (such as block polymers of polyethylene oxide and polypropylene oxide, polyethylene oxide block polymers, polypropylene oxide block polymers, block polymers of alkanol, polyethylene oxide and polypropylene oxide); Ether esters: Polyoxyethylene fatty acid esters (such as polyoxyethylene castor oil ester, polyoxyethylene stearate, polyoxyethylene tallow fatty acid ester, etc.), polyoxyethylene sorbitan fatty acid esters (such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan trioleate, polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan stearate, etc.), polyoxyethylene fatty acid amine esters, polyoxyethylene rosin esters, polyoxypropylene fatty acid esters (such as polyoxypropylene castor oil ester, etc.), polyoxypropylene fatty acid amine esters; Carboxylic acids: Undecafluorocaproic acid.
[0105] Other pharmaceutical adjuvants include, for example, thickeners, cryoprotectants / humectants, antifoaming agents, antioxidants, pH adjusters, colorants, preservatives / bactericides, binders, fixing / spreading agents, lubricants / slipping agents, anti-caking agents, light stabilizers, fragrances, propellants, fertilizers, film agents, deodorants, plasticizers, desiccants / anti-humidity agents, fumigant auxiliaries, attractants, inclusion agents, and efficacy enhancers. Specifically, the following are examples. Thickeners: Polysaccharides (such as xanthan gum, cellulose esters, cellulose ethers, carboxymethyl cellulose and its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, carrageenan, etc.), clays (such as organic clays, organically modified clays, inorganic clays, inorganically modified clays, etc.), minerals (such as bentonite, attapulgite, silica, silicates, etc.), synthetic polymers (such as polycarboxylates, polyacrylic acid derivatives, polyvinylpyrrolidone, polyvinyl alcohol, etc.); Antifreeze agent and humectant: Alcohols (ethylene glycol, propylene glycol, dipropylene glycol, triethylene glycol, ethylene glycol methyl ether, propylene glycol methyl ether, dipropylene glycol methyl ether, ethylene glycol butyl ether, glycerin, polyethylene glycol, etc.), esters (dipropylene glycol dibenzoate, glycerol acetate, glycerol diacetate, glycerol triacetate, gamma-butyrolactone, etc.), ethers (1,4-dioxane, etc.), urea; Defoaming agent: Silicones (polysiloxane, diblock ethoxyl siloxane, triblock ethoxyl siloxane, etc.), alkyl sulfosuccinates, higher alcohols, higher alcohol derivatives, salts of fatty acids, fatty acid derivatives; Antioxidant: Phenols (2,6-di-t-butyl-p-cresol, 2,2'-methylenebis(4-methyl-6-t-butylphenol), etc.), amines (p,p'-dioctyldiphenylamine, N,N'-diphenyl-p-phenylenediamine, etc.), dibutylhydroxytoluene, butylhydroxyanisole, sodium erythorbate, sodium sulfite, potassium sulfite, potassium pyrosulfite, catechin, propyl gallate, sulfurs (didodecyl thiodipropionate, etc.), phosphates (trisnonylphenyl phosphite, etc.), vitamins (alpha tocopherol, L-ascorbic acid, sodium ascorbate, ascorbyl palmitate, etc.); pH adjuster: Sulfuric acid, nitric acid, hydrochloric acid, acetic acid, carbonic acid, oxalic acid, lactic acid, succinic acid, gluconic acid, citric acid, phosphoric acid, sorbic acid, and their salts, sodium hydrogen carbonate, sodium hydroxide, potassium hydroxide, calcium hydroxide, aluminum hydroxide, copper hydroxide, magnesium hydroxide; Colorants: Monoazo compounds (Pigment Red 48:1, Pigment Red 48:2, Pigment Red 53:1, Pigment Red 57:1, Pigment Red 112, Pigment Brown 25, C.l. Solvent Red 1, Pigment Yellow 1, Pigment Orange 5, Acid Red 14, Acid Yellow 23, etc.), Disazo compounds (Pigment Yellow 13, Pigment Orange 34, etc.), Phthalocyanine compounds (Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Green 7, Pigment Green 36, etc.), Anthraquinone-based compounds (Pigment Red 83, etc.), Dioxazine-based compounds (Pigment Blue 80, etc.), Xanthene-based compounds (Basic Violet 10 (Rhodamine B), Acid Red 51, Acid Red 52, etc.), Triarylmethane-based compounds (Acid Blue 9, etc.), Pigment Orange 43, Iron oxide, Titanium, Titanium oxide, Zinc oxide, Zinc sulfide, Ferric hexacyano acid salt, Chrome vermilion, Lead yellow, Calcium carbonate, Barite powder, Aluminum powder; Antiseptics and bactericides: Phenols (orthophenylphenol, thymol, 3,5-dimethyl-4-chlorophenol, etc.), isothiazolinone derivatives (methylisothiazolinone (2-methyl-4-isothiazolin-3-one), chloromethylisothiazolinone (5-chloro-2-methyl-4-isothiazolin-3-one), octylisothiazolinone (2-n-octyl-4-isothiazolin-3-one), dichlorooctylisothiazolinone (4,5-dichloro-2-octyl-4-isothiazolin-3-one), benzisothiazolinone (1,2-benzisothiazolin-3-one), etc.), bronopol derivatives (bronopol (2-bromo-2-nitropropane-1,3-diol), etc.), benzyl alcohol hemiformal, isopropylmethylphenol, parabens (methylparaben, ethylparaben, propylparaben, isopropylparaben, butylparaben, isobutylparaben, heptylparaben, benzylparaben), imidazoles (thiabendazole), benzalkonium chloride, glyceryl caprylate, glyceryl caprate, glycerin fatty acid ester, sodium dehydroacetate, hinokitiol, acids (citric acid, phosphoric acid, sorbic acid, salicylic acid, benzoic acid, and their salts, etc.); Binders: Polysaccharides (xanthan gum, cellulose ester, cellulose ether, carboxymethyl cellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clay, organically modified clay, inorganic clay, inorganically modified clay), minerals (bentonite), synthetic polymers (polycarboxylic acid or its salt, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salt), waxes (vegetable oils, animal fats, and their derivatives, paraffin, olefin, etc.); Fixing agent and spreading agent: The surfactants and liquid carriers described above (esters (alkyl fatty acid esters, sorbitan fatty acid esters, ethoxylated fatty acid esters, ethoxysorbitan fatty acids, etc.), alcohols (ethoxylated aliphatic alcohols, ethoxysorbitan aliphatic alcohols, etc.), waxes (vegetable oils, animal fats, and their derivatives, paraffin, olefins, etc.), vegetable oils (alkylated vegetable oils, etc.), mineral oils (mineral oils, etc.), silicone emulsions, synthetic polymers (styrene-butadiene copolymers, methyl methacrylate-butadiene copolymers, polyacrylic acid or its salts, polyvinyl acetate, polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene glycol, polypropylene glycol, etc.), natural polymers (xanthan gum, cellulose esters, cellulose ethers, carboxymethyl cellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, etc.); Lubricant: The alcohols, fatty acid esters, sucrose fatty acid esters, glycerin fatty acid esters, hydrocarbons, paraffin, ethylene wax, aliphatic amides, erucic acid amide, stearic acid amide, oleic acid amide, methylene bis stearic acid amide, ethylene bis stearic acid amide, metal soaps, lead stearate, zinc stearate, calcium stearate, magnesium stearate, mineral oil, vegetable oil, kerosene, diesel oil described in the liquid carriers and surfactants described above; Anti-caking agent: The solid carriers, liquid carriers, calcium phosphate, sodium phosphate, sodium carbonate, sodium silicate, calcium silicate, magnesium silicate, potassium aluminum silicate, silicon dioxide, talc, sodium aluminosilicate, calcium aluminosilicate, bentonite, stearic acid, dimethylpolysiloxane, powdered cellulose described above; Light stabilizers: titanium oxide, zinc oxide, activated carbon, carbon black, ethylhexyl methoxycinnamate, tert-butyl methoxydibenzoylmethane, hindered amines, ferulic acid, phenyl hydroxybenzoate, ethyl para-aminobenzoate, octyl salicylate, t-butylphenyl salicylate, 4-tert-octylphenyl salicylate, 2-ethylhexyl 2-cyano-3,3-diphenylacrylate (octocrylene), droxmetrizole trisiloxane, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine (octyltriazine, TEAT), 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol] (MBP), 2-ethylhexyl dimethylaminobenzoate (EDB), homomenthyl salicylate (HS), phenylbenzimidazole sulfonic acid (PBS), hydroxymethoxybenzophenone sulfonic acid (oxybenzone 4, OXB4), sodium hydroxymethoxybenzophenone sulfonate (oxybenzone 5, OXB5), sodium dihydroxydimethoxybenzophenone disulfonate (oxybenzone 9, OXB9), tetrahydroxybenzophenone, dihydroxybenzophenone, dihydroxydimethoxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-ethylhexyl dimethoxybenzylidene dioxoimidazolidine propionate, 2,4-dihydroxybenzophenone, bis(2-methoxy-4-hydroxy-5-benzoylphenyl)methane; Fragrances: hydrocarbons, α-limonene, β-caryophyllene, alcohols, cis-3-hexenol, linalool, farnesol, β-phenylethyl alcohol, aldehydes, 2,6-nonadienal, citral, α-hexylcinnamic aldehyde, ketones, β-ionone, L-carvone, cyclopentadecanone, esters, linalyl acetate, benzyl benzoate, lactones, γ-undecalactone, phenols, eugenol, oxides, rose oxide, acetals, phenylacetaldehyde dimethyl acetal, α-pinene, β-pinene; Propellants: liquefied petroleum gas, propane, normal butane, isobutane, normal pentane, isopentane and other aliphatic hydrocarbons with 3 to 5 carbon atoms, hydrofluoroolefins such as trans-1,3,3,3-tetrafluoroprop-1-ene, trans-2,3,3,3-tetrafluoroprop-1-ene, dimethyl ether, nitrogen gas, carbon dioxide gas, nitrous oxide gas, compressed air, and mixtures thereof; Fertilizers: nitrogenous fertilizer components (urea, ammonium nitrate, ammonium magnesium nitrate, ammonium chloride, ammonium sulfate, ammonium phosphate, sodium nitrate, calcium nitrate, potassium nitrate, calcium cyanamide, formaldehyde-treated urea (UF), acetaldehyde-treated urea (CDU), isobutylaldehyde-treated urea (IBDU), guanylurea (GU)), phosphatic fertilizer components (superphosphate of lime, triple superphosphate of lime, fused phosphate, humic acid phosphate, calcined phosphate, double calcined phosphate, magnesium superphosphate, ammonium polyphosphate, potassium metaphosphate, calcium metaphosphate, magnesium phosphate, ammonium sulfate phosphate, ammonium phosphate nitrate potassium, ammonium chloride phosphate, etc.), potassium fertilizer components (potassium chloride, potassium sulfate, potassium sodium sulfate, potassium magnesium sulfate, potassium bicarbonate, potassium phosphate, etc.), silicate fertilizer components (calcium silicate, etc.), magnesium fertilizer components (magnesium sulfate, magnesium chloride, etc.), calcium fertilizer components (quicklime, slaked lime, calcium carbonate, etc.), manganese fertilizer components (manganese sulfate, magnesium sulfate manganese, manganese ore, etc.), boron fertilizer components (boric acid, borate, etc.), iron-containing fertilizer components (steel slag, etc.), and other fertilizer components (copper, cobalt, zinc, etc.); Film agents: natural rubber, synthetic rubber, resins (styrene-butadiene copolymer, polyacrylonitrile, polyester, polyamide, polyurethane, polyurea, polyether, rosin, melamine, etc.), waxes (vegetable oils, animal oils, and their derivatives, paraffin, olefin, etc.), polysaccharides (xanthan gum, cellulose ester, cellulose ether, carboxymethyl cellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, starch xanthate, carrageenan, etc.), proteins (gelatin, etc.); Deodorants: organic clay, organically modified clay, unmodified clay, zinc silicate, silica gel; Plasticizers: Triethyl phosphate, citrate esters, phthalate esters, adipate esters, sebacate esters, phosphate esters; Desiccants and moisture-proof agents: Silica gel, calcium chloride, quicklime, aluminum oxide, zeolite, allophane; Smoke agent auxiliaries: Nitrocellulose, potassium chlorate, calcium oxide, melamine, potassium nitrate, azodicarbonamide; Attractants: Starch, cellulose, dextrin, acetic acids, alcohols, yeast extract; Inclusion agents: Cyclodextrins, α-cyclodextrin, β-cyclodextrin, γ-cyclodextrin; Potency enhancers: The liquid carriers and surfactants described above.
[0106] When formulating the present compound or composition A into an aqueous suspension formulation or an oily suspension formulation, usually, a cryoprotectant and / or a preservative are added. Preferred cryoprotectants include ethylene glycol, propylene glycol, and glycerin. Preferred preservatives include isothiazolinone derivatives (e.g., 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-n-octyl-4-isothiazolin-3-one), and Proxel (1,2-benzisothiazolin-3-one). Ethylene glycol (hereinafter referred to as EG), propylene glycol (hereinafter referred to as PG), glycerin (hereinafter referred to as GL), 2-methyl-4-isothiazolin-3-one (hereinafter referred to as MIT), 5-chloro-2-methyl-4-isothiazolin-3-one (hereinafter referred to as CMIT), 2-n-octyl-4-isothiazolin-3-one (hereinafter referred to as OIT), 4,5-dichloro-2-octyl-4-isothiazolin-3-one (hereinafter referred to as DCOIT), 1,2-benzisothiazolin-3-one (hereinafter referred to as BIT), and 2-bromo-2-nitropropane-1,3-diol (hereinafter referred to as BNPD), which are used as cryoprotectants and preservatives, are commercially available.
[0107] Examples of the combination of the present compound or composition A and the above-mentioned antifreeze or preservative are described below. SX + EG, SX + PG, SX + GL, SX + MIT, SX + CMIT, SX + OIT, SX + DCOIT, SX + BIT, SX + BNPD, Composition A + EG, Composition A + PG, Composition A + GL, Composition A + MIT, Composition A + CMIT, Composition A + OIT, Composition A + DCOIT, Composition A + BIT, Composition A + BNPD.
[0108] The weight ratio of the present compound or composition A to the above-mentioned antifreeze or preservative is in the range of 1:0.0001 to 1:100, for example, in the ranges of 1:0.0001 to 1:1, 1:0.005 to 1:0.01, 1:0.15 to 1:0.35, 1:0.125 to 1:0.25. Specific weight ratios include 1:0.0001, 1:0.0002, 1:0.0003, 1:0.0004, 1:0.0005, 1:0.0006, 1:0.0007, 1:0.0008, 1:0.0009, 1:0.001, 1:0.002, 1:0.003, 1:0.004, 1:0.005, 1:0.006, 1:0.007, 1:0.008, 1:0.009, 1:0.01, 1:0.02, 1:0.03, 1:0.04, 1:0.05, 1:0.06, 1:0.07, 1:0.08, 1:0.09, 1:0.1, 1:0.125, 1:0.15, 1:0.2, 1:0.25, 1:0.3, 1:0.4, 1:0.5, 1:0.6, 1:0.7, 1:0.8, 1:0.9, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:30, 1:40, 1:50, 1:60, 1:70, 1:80, 1:90, 1:100. The above weight ratios can also be expressed approximately. Approximately means plus or minus 10%, for example, "approximately 1:2" means 1:1.8 to 1:2.2.
[0109] Examples of the combination of the present compound or composition A and the above-mentioned antifreeze and preservative are described below. SX + EG + MIT, SX + EG + CMIT, SX + EG + OIT, SX + EG + DCOIT, SX + EG + BIT, SX + EG + BNPD, SX + PG + MIT, SX + PG + CMIT, SX + PG + OIT, SX + PG + DCOIT, SX + PG + BIT, SX + PG + BNPD, SX + GL + MIT, SX + GL + CMIT, SX + GL + OIT, SX + GL + DCOIT, SX + GL + BIT, SX + GL + BNPD, Composition A + EG + MIT, Composition A + EG + CMIT, Composition A + EG + OIT, Composition A + EG + DCOIT, Composition A + EG + BIT, Composition A + EG + BNPD, Composition A + PG + MIT, Composition A + PG + CMIT, Composition A + PG + OIT, Composition A + PG + DCOIT, Composition A + PG + BIT, Composition A + PG + BNPD, Composition A + GL + MIT, Composition A + GL + CMIT, Composition A + GL + OIT, Composition A + GL + DCOIT, Composition A + GL + BIT, Composition A + GL + BNPD. When combining this compound or Composition A with the above-mentioned antifreeze agent and preservative, the mixing ratios of this compound or Composition A with the antifreeze agent and this compound or Composition A with the preservative can be used within the same range as the ratios described above.
[0110] In the case of granules or fine granules, a colorant can also be added to make it easier to confirm the granules or fine granules during or after application. Also, when applying Composition B to plant seeds or vegetative reproductive organs, a colorant can also be added to make it easier to confirm that the application has been made.
[0111] Examples of the substrate of the resin preparation include polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenol resin, melamine resin, and epoxy resin. These substrates may contain plasticizers such as phthalates (dimethyl phthalate, dioctyl phthalate, etc.), adipic acid esters, and stearic acid, if necessary. The resin preparation can be processed into various forms by molding as necessary, such as plates, films, tapes, threads, nets, cloths, strings, blocks, and the like, and can be used in the form of animal collars, animal ear tags, clothing, protective hats, arm / leg covers, attractant strings, gardening poles, screen doors, mosquito nets, and the like. The composition B can also be post-treated after molding the resin. Examples of base materials for poison bait include grain flour, vegetable oil, sugar, crystalline cellulose, etc., and, if necessary, antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, preservatives such as dehydroacetic acid, agents to prevent children or pets from accidentally eating the poison, such as chili powder, and pest-attracting flavors such as cheese flavoring, onion flavoring, and peanut oil may be added.
[0112] The plant pathogenic microorganisms can be controlled by applying an effective amount of the present compound, composition A, or composition B directly to the plant pathogenic microorganisms or to the habitat of the plant pathogenic microorganisms. The habitat referred to here includes not only the place where the plant pathogenic microorganisms live, but also the place where the plant pathogenic microorganisms are expected to live. Specifically, the habitat includes plants, plant cultivation areas, plant cultivation carriers, indoor and outdoor buildings, building materials, food, daily necessities, wood, vehicles, animals, etc.
[0113] In the present invention, plants include whole plants and specific parts of plants, such as foliage, flowers, spikes, fruits, trunks, branches, crowns, seeds, vegetative reproductive organs and seedlings.
[0114] The vegetative reproductive organs refer to those parts among the roots, stems, leaves, etc. of plants that have the ability to grow when separated from the main body and placed in the soil. Examples of vegetative reproductive organs include tuberous root, creeping root, bulb, corm (or solid bulb), tuber, rhizome, stolon, rhizophore, cane cuttings, propagule, and vine cutting. Note that stolons are sometimes called runners, propagules are also called bulbils, and are divided into broad buds and bulbil. Vine cutting means the shoots (collective term for leaves and stems) of sweet potatoes and yams, etc. Bulbs, corms, tubers, rhizomes, cane cuttings, rhizophores, or tuberous roots are collectively called bulbs. The cultivation of potatoes begins by planting tubers in the soil, and the tubers used are generally called seed tubers.
[0115] Seedlings include seedlings and saplings.
[0116] Cultivation sites of plants include, for example, agricultural lands such as fields, paddy fields, orchards, and non-agricultural lands such as lawns and forests.
[0117] The cultivation carrier of plants is a support for plants, and any material on which plants can grow can be used. Examples include soil, nursery mats, and water. Specific materials for soil and nursery mats include, for example, sand, pumice, vermiculite, diatomaceous earth, gel substances, polymer substances, rock wool, glass wool, wood chips, and bark.
[0118] Examples of buildings include houses, commercial facilities, stations, airports, hospitals, factories, offices, schools, accommodation facilities, waste treatment facilities, livestock houses, and warehouses. Examples of the indoor areas of buildings include closets, cupboards, chests of drawers, sideboards, toilets, bathrooms, storerooms, living rooms, bedrooms, and dining rooms.
[0119] Examples of the outdoor environment include, for example, the ground, exterior walls, fences, ditches, spaces, water meters, water storage tanks, wells, puddles, rain barrels, rain gutters, septic tanks, old tires, reservoirs, rivers, waterways, forests, and lakes.
[0120] Examples of building materials include, for example, wood, concrete, bricks, plastics, glass, wallpaper, insulation materials, packing materials, pipes, electric cables, paints, and sealing materials.
[0121] Examples of food include, for example, agricultural products (grains, fruits, spices, and products processed from these), livestock and fishery products (meat, fish, eggs, milk, and products processed from these). Also, examples of daily necessities include plant-derived products (cotton, paper, tobacco, and products processed from these), animal-derived products (leather, hair, wool, feathers, silk, and products processed from these), electrical appliances, and other products (furniture, stationery, toys, tableware).
[0122] Examples of wood include, for example, wood processed for construction (high-density wood, laminated wood, plywood, fiberboard, hardboard, MDF, insulation board, particle board, insulation hardboard, OSB, LSL, glued laminated timber, cross-laminated timber, flooring, composite flooring, etc.).
[0123] Examples of vehicles include, for example, bicycles, cars (private cars, buses, taxis, freight carriers, etc.), trains, airplanes, and ships.
[0124] Examples of animal bodies include, for example, livestock (cows, horses, pigs, sheep, goats, chickens, etc.) and small animals (dogs, cats, rats, mice, etc.).
[0125] When Composition B is used for controlling plant diseases in the agricultural field, its application rate can vary widely depending on the type of plant to be applied, the type and occurrence frequency of the plant disease to be controlled, the formulation form, the application time, the application method, the application location, the weather conditions, etc. Usually, the application rate of this compound or one kind of this component is 1 to 10,000 g per hectare, preferably 5 to 5,000 g, more preferably 50 to 2,000 g (specifically, for example, 100 g, 200 g, 300 g, 500 g). When Composition B is formulated into an emulsion, wettable powder, flowable agent, etc., usually, it is diluted with water so that the concentration of this compound or one kind of this component is 0.01 to 10,000 ppm, preferably 0.1 to 5,000 ppm, more preferably 1 to 1,000 ppm (specifically, for example, 10 ppm, 100 ppm, 500 ppm) and then applied. When Composition B is formulated into a granule, powder, etc., usually, it is applied as it is.
[0126] These formulations and the water-diluted solutions of the formulations may be directly sprayed on the plant diseases or the plants to be protected from plant diseases, or may be treated on the cultivation carrier to control the plant diseases occurring on the cultivation carrier.
[0127] Also, Composition B, which is a resin formulation processed into a sheet or string shape, can be treated by methods such as winding it around the plant, stretching it near the plant, or laying it on the cultivation carrier.
[0128] When Composition B is applied to a plant or a plant cultivation area, it is applied once or multiple times. The plant or the plant cultivation area may have plant diseases already occurring, or may be before the occurrence.
[0129] Examples of the treatment method of Composition B include foliar treatment, soil treatment, root treatment, shower treatment, mist spraying treatment, fumigation treatment, water surface treatment, hydroponic solution treatment, and seed treatment.
[0130] Examples of foliar treatment include methods of treating Composition B on the surface of leaves, stems, trunks, fruits, flowers, or ears. Examples of root treatment include, for example, a method of immersing the roots in a chemical solution containing Composition B, and a method of attaching a solid preparation containing Composition B to the roots of plants. Examples of soil treatment include, for example, soil spraying, soil mixing, and chemical solution irrigation of the soil. Also, examples of the location for soil treatment include, for example, planting holes, furrows, areas near planting holes, areas near furrows, the entire cultivation area in its entirety, the plant rhizosphere, between plants, under the tree trunk, on the main stem ridge, soil covering, seedling boxes, seedling trays, seedling beds, etc. Examples of the treatment time include, for example, before sowing, at sowing, after sowing, during the seedling raising period, before planting, at planting, and during the growth period after planting, etc. Also, in the above soil treatment, Composition B may be treated on the plant simultaneously, or a paste fertilizer, liquid fertilizer, solid fertilizer, etc. containing Composition B may be applied to the soil. Also, it may be mixed with the irrigation liquid, for example, injection into irrigation facilities (irrigation tubes, irrigation pipes, sprinklers, etc.), mixing into the inter-row flooded liquid, mixing into the hydroponic solution, etc. Also, the irrigation liquid and the active ingredient may be mixed in advance, and for example, it can be treated using the above irrigation methods or other appropriate irrigation methods such as spraying and flooding. Examples of shower treatment include, for example, a method of showering a diluted solution of Composition B on the harvested fruits. Examples of mist spraying treatment include, for example, a method of atomizing a diluted solution of Composition B and scattering it in the air so that it adheres to the stems, leaves, and fruits of plants. Examples of fumigation treatment include, for example, a method of heating a solid preparation containing Composition B to make it smoky and floating it in the air so that it adheres to the stems, leaves, and fruits of plants. Examples of water surface treatment include, for example, a method of spraying a chemical solution containing Composition B or a solid preparation containing Composition B on a paddy field in a flooded state. Examples of hydroponic solution treatment include, for example, a method of mixing or incorporating a chemical solution containing Composition B or a solid preparation containing Composition B into the hydroponic solution (hydroponic solution mixing treatment, hydroponic solution incorporation treatment, etc.).
[0131] Seed treatment Seed treatment means treating the seeds or vegetative reproductive organs with Composition B. Examples of the seed treatment method of Composition B include, for example, a spraying treatment in which a suspension of Composition B is atomized and sprayed onto the seed surface or the surface of the vegetative reproductive organ, a coating treatment in which Composition B is applied to the seeds or vegetative reproductive organs, a dipping treatment in which the seeds are immersed in the chemical solution of Composition B for a certain period of time, and a method of coating the seeds or vegetative reproductive organs with a carrier containing Composition B (film coating treatment, pellet coating treatment, etc.). Among the above-mentioned vegetative reproductive organs, seed tubers are particularly mentioned. When treating the seeds or vegetative reproductive organs with Composition A, Composition A can be treated as one formulation on the seeds or vegetative reproductive organs, or Composition A can be treated on the seeds or vegetative reproductive organs in multiple times as different multiple formulations. Examples of the method of treating Composition A in multiple times as different multiple formulations include, for example, treating with a formulation containing only this compound as the active ingredient, air-drying the seeds or vegetative reproductive organs, and then treating with a formulation containing this component; and treating with a formulation containing this compound and this component as the active ingredient, air-drying the seeds or vegetative reproductive organs, and then treating with a formulation containing this component other than the treated this component. After the seed treatment, the active ingredient may completely or partially cover the seeds or vegetative reproductive organs, may be scattered on their surfaces, and / or may be present inside them. When treating, it is preferably to use a composition containing this component having at least one bactericidal activity selected particularly from group (b) and group (j) among Composition B. At this time, this compound may be treated on commercially available seeds or vegetative reproductive organs treated with this component having at least one bactericidal activity selected from group (b) and group (j). When treating Composition B on the seeds or vegetative reproductive organs, manganese, copper, zinc, etc. may also be treated simultaneously. When treating Composition B on seeds, the application amount of Composition B is usually 0.001 to 100 g, preferably 0.02 to 50 g per 1 kg of seeds or vegetative reproductive organs, and the application amount per active ingredient contained in Composition B is usually 0.001 to 100 g, preferably 0.01 to 50 g, more preferably 0.1 to 10 g per 1 kg of seeds or vegetative reproductive organs. Specifically, for example, the following treatment amounts are included. 0.05 g of the active ingredient per 1 kg of seeds or vegetative reproductive organs; 0.5 g of the active ingredient per 1 kg of seeds or vegetative reproductive organs; 5 g of the active ingredient per 1 kg of seeds or vegetative reproductive organs. The seeds or vegetative reproductive organs holding the present compound or Composition A in the present invention mean those in a state where the present compound or Composition A is adhered to the surface of the seeds or vegetative reproductive organs. The above-mentioned seeds or vegetative reproductive organs holding the present compound or Composition A may have materials other than the present compound or Composition A adhered thereto before and after the present compound or Composition A is adhered to the seeds or vegetative reproductive organs. In addition, when Composition A is adhered to the surface of the seeds or vegetative reproductive organs as a layer, the layer may consist of one layer or a plurality of layers. When consisting of a plurality of layers, each layer is a layer containing one or more active ingredients, or consists of a layer containing one or more active ingredients and a layer not containing an active ingredient. The seeds or vegetative reproductive organs holding the present compound or Composition A can be obtained, for example, by applying a composition B containing the present compound or Composition A to the seeds or vegetative reproductive organs by the above-mentioned seed treatment method.
[0132] As seed treatment formulations, generally, DS, ES, FS, LS, WS, CF, GF, SS, etc. are known, but CS, EG, EW, GW, ME, OD, OF, SC, SE, SG, SL, SP, ST, WG, WP, WT, ZC, ZE, ZW, etc. can also be used. These formulations contain one of the present compounds or the present component in a weight ratio of 0.01 to 70%, preferably 0.1 to 50%. When treating these formulations on seeds or vegetative reproductive organs, they may be used as they are, or diluted with water before use. When treating the seeds or vegetative reproductive organs with the formulation diluted with water, it can be arbitrarily diluted according to the content of the active ingredient in the formulation and the amount of the active ingredient to be retained on the seeds or vegetative reproductive organs. Generally, it is often diluted 2 to 1000 times before use. When treating seeds, the seeds before sowing or the seeds after germination may be treated. When seed-treating the present compound or composition A, adjuvants such as colorants and binders may be mixed during formulation, or may be further mixed when seed-treating the formulated composition B. The colorant facilitates confirmation of whether the composition B can be applied to each individual seed or vegetative reproductive organ. A binder can also be added to improve the adhesion of the active ingredient to the seed or vegetative reproductive organ. Examples of specific colorants and binders are shown below. Colorants: For example, monoazo compounds (Pigment Red 48:1, Pigment Red 48:2, Pigment Red 53:1, Pigment Red 57:1, Pigment Red 112, Pigment Brown 25, C.l. Solvent Red 1, Pigment Yellow 1, Pigment Orange 5, Acid Red 14, Acid Yellow 23, etc.), disazo compounds (Pigment Yellow 13, Pigment Orange 34, etc.), phthalocyanines (Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Green 7, Pigment Green 36, etc.), anthraquinone-based compounds (Pigment Red 83, etc.), dioxazine-based compounds (Pigment Blue 80, etc.), xanthene-based compounds (Basic Violet 10 (Rhodamine B), Acid Red 51, Acid Red 52, etc.), triarylmethane-based compounds (Acid Blue 9, etc.), Pigment Orange 43, iron oxide, titanium, titanium oxide, zinc oxide, zinc sulfide, hexacyanoferrate salts, chrome vermilion, lead yellow, calcium carbonate, barite powder, aluminum powder; Binder: Polysaccharides (xanthan gum, cellulose ester, cellulose ether, carboxymethyl cellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clay, organically modified clay, inorganic clay, inorganically modified clay, etc.), minerals (bentonite, etc.), synthetic polymers (polycarboxylic acid or its salt, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salt, styrene-butadiene copolymer, methyl methacrylate-butadiene copolymer, polyacrylic acid or its salt, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, polypropylene glycol, etc.), waxes (vegetable oils, animal fats, and their derivatives, paraffin, olefin, etc.). When treating the seed or vegetative reproductive organ with Composition B, an adjuvant may be mixed with Composition B as needed. The seeds or vegetative reproductive organs treated with Composition B are sown or planted in the field by a normal method.
[0133] This compound and this component may be applied to plants or the soil in which the plants are cultivated, or the place where plant diseases occur, separately at the same time, or alternatively, this compound and this component may be applied to plants or the cultivation carrier, or the place where plant diseases occur, separately at different times. Specifically, for example, either one of this compound or this component may be applied to the cultivation carrier (e.g., soil, etc.) before or after planting the seeds or vegetative reproductive organs treated with the other one.
[0134] Composition B can be applied to plants in which one or more components selected from this component have been previously seed-treated and the cultivation carrier of the plants. Examples of the application methods include foliar treatment, soil treatment, root treatment, shower treatment, mist spraying treatment, fumigation treatment, water surface treatment, and hydroponic solution treatment.
[0135] Examples of the seed treatment agent previously treated on soybeans include the following. STANDAK-TOP 500FS (Fipronil / Pyraclostrobin / Thiophanate-m), DERMACOR 625FS (Chlorantraniliprole), CRUISER 350FS (Thiamethoxam), CROPSTAR 600FS (Imidacloprid / Thiodicarb), FORTENZA 600FS (Cyantraniliprole), S-UNSPEC-INS-WHEAT, NEMAT 300WP (Verticillium), FIPRONIL-ALTA 250FS (Fipronil), MAXIM-ADVANCED 195FS (Fludioxonil / Metalaxyl-M / Thiabendazole), SHELTER 250SC (Fipronil), MAXIM-XL 035FS (Fludioxonil / Metalaxyl-M), DEROSAL Plus(Carbendazim / Thirum), Vitavax - THIRAM(Carboxin / Thiram).
[0136] Examples of seed treatment agents pre-treated on corn seeds include, for example, the following. PONCHO-VOTIVO 601EC (Bacillus-firmus / Clothianidin), ACCELERON-IC-609 600EC (Clothianidin), CRUISER 600FS (Thiamethoxam), ACCELERON-D-342 480FS (Prothioconazole), PONCHO 600FS (Clothianidin), MAXIM-QUATTRO 382.5FS (Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole), AVICTA-COMPLETE-CORN-250 280FS, Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), AVICTA-COMPLETE-CORN-500 423FS, (Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), LUMIVIA 625FS (Chlorantraniliprole), ACCELERON-D-281 480FS (Fluoxastrobin), ACCELERON-DC-309 312FS (Metalaxyl).
[0137] Examples of the seed potato treatment agents pre-treated on potatoes include, for example, the following. Maxim 4FS (fludioxonil), Maxim MZ (fludioxonil + Mancozeb), Cruiser MAXX Vibrance Potato (fludioxonil + difenoconazole + Sedaxane + Thiamethoxam), Emesto Silver (penflufen + prothioconazole), MonCoatMZ (flutolanil + Mancozeb), Moncut (flutolanil), Elatus (azoxystrobin + benzovindiflupyr), Quadris (azoxystrobin), Serenade ASO (Bacillus subtillis), DoubleNickel LC (Bacillus amyloliquefaciens), Attackin (streptomycin, thiophanate M), Frontside (fluazinam), Basidac (mepronil), Moncut (flutolanil), Rovral (ipro-dione), Moncut (flutolanil), Benlate (benomyl).
[0138] When applying Composition B, spraying equipment can be used. Examples of the equipment used for application include, for example, hand sprayers, power sprayers, puncture sprayers, manned aircraft (such as manned helicopters), unmanned aircraft (such as radio-controlled helicopters, drones), tractors, planters, etc. Also, it may be applied by hand without using spraying equipment.
[0139] When using a sprayer to apply Composition B, the spraying pressure is not particularly limited, but is usually 30 - 120 PSI, preferably 40 - 80 PSI. Here, the spraying pressure is the setting before introduction to the nozzle.
[0140] When using a sprayer to apply Composition B, the spray nozzle is not particularly limited, and examples include flat spray nozzles, conical nozzles, rotary nozzles, hollow cone nozzles, deflector nozzles, linear nozzles, etc.
[0141] When Composition B is applied in the form of a solution, the pH and hardness of the solution are not particularly limited, but the pH is generally in the range of 5 to 9, and the hardness is generally in the range of 0 to 500. The time period for applying Composition B is not particularly limited, but generally, the range from 5 am to 9 pm is common. Also, the photosynthetic photon flux density at the grass canopy level at the location where Composition B is applied is generally 10 to 2500 micromoles / m2 / second. The weather conditions when applying Composition B are not particularly limited, but the air temperature is generally 0 to 30°C, preferably 10 to 20°C, the soil temperature is generally 0 to 30°C, preferably 10 to 20°C, the relative humidity is 50 to 90%, preferably 40 to 80%, and the wind speed is 0 to 2 MPH.
[0142] When spraying Composition B, it is usually carried out by spraying a spraying liquid obtained by mixing Composition B with water. When preparing the spraying liquid, it can be directly diluted in the water of the spraying liquid volume, or after mixing Composition B with a small amount of water and making it uniform, water is added to prepare a specified liquid volume. Although the spraying liquid volume is not particularly limited, it is generally in the range of 5 to 5000 L / ha, preferably 20 to 1000 L / ha, more preferably 140 to 300 L / ha. Specific spraying liquid volumes can include 10 L / ha, 30 L / ha, 50 L / ha, 70 L / ha, 90 L / ha, 100 L / ha, 120 L / ha, 150 L / ha, 180 L / ha, 200 L / ha, 250 L / ha, 300 L / ha, 400 L / ha, 500 L / ha, 700 L / ha, 900 L / ha, 2000 L / ha, 4000 L / ha.
[0143] When spraying Composition B using a manned aircraft or an unmanned aircraft, although the spraying height is not particularly limited, it is generally 0.5 to 30 m, preferably 1 to 10 m.
[0144] When carrying out foliage treatment, soil treatment, root treatment, shower treatment, fumigation treatment, water surface treatment, seed treatment, and hydroponic solution treatment of Composition B, Composition B and an adjuvant may be mixed. They may be premixed (premix) before formulation or mixed immediately before use (tank mix). The type of adjuvant is not particularly limited, and examples include COC (Crop oil concentrate) derived from mineral oil, MSO (methylated seed oil) derived from vegetable oil, alcohol-based solvents, nonionic surfactants, anionic surfactants, cationic surfactants, silicone-based, nitrogen fertilizers, etc., and mixtures thereof. Specifically, AgriDex (registered trademark), Induce (registered trademark), Gramin S (registered trademark), Genamin T 200BM (registered trademark), Silwet L77 (registered trademark), Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol Gold (registered trademark), BreakThru (registered trademark), SundanceII (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), BANOLE (registered trademark), Ochima (registered trademark), Agris (registered trademark), AMS (Ammonium Sulfate), UAN (Urea Ammonium Nitrate), AdGreen (registered trademark), Mees (trademark), Rumba (registered trademark), Strides (registered trademark), Partner, Orix (registered trademark), Penetrator, etc. Furthermore, a drift reducer such as Intact (registered trademark) may be mixed. The weight ratio of Composition B to the above adjuvant or drift reducer is not particularly limited, and for example, a range of 1:100 to 100:1 can be mentioned.
[0145] Composition B can be mixed or used in combination with fertilizers. When mixing, it may be premixed during formulation (premix) or mixed immediately before application (tank mix). Fertilizers include substances containing various elements such as nitrogen (N), phosphorus (P), potassium (K), silicon, magnesium, calcium, manganese, boron, iron, copper, zinc, sulfur, molybdenum, cobalt, etc. Substances containing nitrogen, phosphorus, and potassium include, for example, urea, ammonium nitrate (ammonium nitrate), ammonium chloride (ammonium chloride), ammonium sulfate (ammonium sulfate), sodium nitrate, magnesium nitrate, nitric acid, anhydrous ammonia, urea ammonium nitrate, calcium nitrate, calcium cyanamide, phosphoric acid, superphosphate of lime, triple superphosphate of lime, potassium sulfate, potassium chloride, potassium silicate, potassium hydroxide, potassium nitrate, potassium phosphate, MAP (monoammonium phosphate), DAP (diammonium phosphate). The form of the fertilizer can be any of granular, powdered, lumpy, liquid, etc., and fertilizers in various forms can be used. The places of application include, for example, the soil surface, in the soil, and on plants. The equipment used for application includes, for example, hand sprayers, power sprayers, puncture sprayers, manned aircraft (such as manned helicopters), unmanned aircraft (such as radio-controlled helicopters, drones), tractors, planters, broadcasters, seeders, etc. Also, it may be applied by hand without using spraying equipment. As a specific application method, for example, at the time of sowing or planting of plants, or during the period before or after sowing or planting (e.g., sowing ±0, 1, 2, 3, 4, 5 days), a method of treating the composition B and the fertilizer together near the seeds, vegetative reproductive organs, or seedlings can be mentioned (sometimes also called in-furrow application). The fertilizer applied at the time of sowing or planting of plants, or during the period before or after sowing or planting, may be a solid fertilizer and / or a liquid fertilizer. For example, fertilizers having an N:P:K ratio are included (sometimes called starter fertilizer, pop-up fertilizer, etc.). The composition B and the fertilizer may be mixed immediately before application and used, or may be applied separately and simultaneously. The application location is not particularly limited as long as it is near the seeds, vegetative reproductive organs, or seedlings, but it may be the planting furrow of the seeds, vegetative reproductive organs, or seedlings, or a location several inches away from the planting furrow of the seeds, vegetative reproductive organs, or seedlings. For example, 2 inches horizontally and 2 inches vertically from the planting furrow of the seeds, vegetative reproductive organs, or seedlings can be mentioned (sometimes called 2-by2 band). Examples of crops include corn, soybean, sugarcane, potato, wheat, barley, rye, oat, and rice. The ratio of the weight of one active ingredient contained in the composition B to the total NPK weight contained in the fertilizer is not particularly limited, but for example, a range of 1:1 to 1:10000 can be mentioned.
[0146] The composition B can be applied by spot treatment. Spot treatment is a concept opposite to uniformly treating the composition B, and means a treatment of selectively spraying the composition B at a location where a plant disease has occurred or where there is a risk of occurrence of a plant disease. "Treating at a location" means treating a plant or soil where a plant disease has occurred or is likely to occur, but preferably when treating a plant. When treating a plant, it also includes treating only the individuals in a plant population where a plant disease has occurred or is likely to occur, and treating only the parts in an individual plant where a plant disease has occurred or is likely to occur. Even when Composition B is somewhat sprayed on a place where no plant disease has occurred due to scattering, evaporation, etc., or a place where there is no risk of plant disease occurring, it is included in spot treatment unless it is a uniform surface treatment. Also, in a continuous cultivation area, it is not considered spot treatment only when all places where plant disease has occurred or places where there is a risk of plant disease occurring are selectively treated. That is, even when a part of the cultivation area is subjected to surface treatment, or when a part of the place where plant disease has occurred or a place where there is a risk of plant disease occurring is not treated with Composition B, if there is a place that has been spot-treated in a continuous cultivation area, it is included in spot treatment.
[0147] As a method of spot treatment, specific examples are given below. In a plant cultivation area, while a sprayer walks, or while a sprayer rides on a device that travels on the ground or an aircraft, spot treatment may be carried out by visually spraying Composition B using a handheld nozzle or a robot arm nozzle. Furthermore, a place where plant disease has occurred or is likely to occur may be mapped in advance, and spot treatment may be carried out by spraying Composition B based on the map information. In spraying based on map information, in addition to the above method, during the running or flying of the sprayer, the nozzles on the boom or the robot arm nozzles may be automatically or manually opened and closed based on the position information of the sprayer (obtained by GPS, etc.) and the map information, etc., to carry out spot treatment. The map information may be created based on image information taken by a manned or unmanned flying object, etc., or may be created visually by an observer walking on the ground, an observer riding on a device traveling on the ground, or an observer riding on an aircraft. Furthermore, a running or flying sprayer may be equipped with a function to detect a place where plant disease has occurred or is likely to occur, and spot treatment may be carried out using the boom or robot arm, etc., while performing real-time mapping.
[0148] The locations where plant diseases occur can be recognized not only by visual recognition by sprayers or observers, but also by image analysis using visible light, or may be recognized by image analysis using specific wavelengths in hyperspectral images. The image analysis may be in the form of visually observing the screen to recognize the occurrence of plant diseases, or image recognition using artificial intelligence can also be used (for example, Optimum Co., Ltd. press release on December 26, 2017). These images may be taken by manned or unmanned flying objects, etc., or may be taken by a photographer walking on the ground, a photographer riding on a device traveling on the ground, or a photographer riding on an aircraft. The locations where there is a risk of plant diseases occurring may be estimated based on the fact that the plant diseases have occurred patchily during the past cultivation period of the crop, or may be estimated from the distribution of plant diseases in the soil. The distribution of plant diseases in the soil may be investigated by soil sampling or may be estimated by remote sensing. Also, the fact that plant diseases are latent in plants may be sensed and estimated by image analysis. Such technology is known as a form of emerging agriculture called precision agriculture, smart agriculture, or digital agriculture, and the non-uniform spraying pattern generated by the spot treatment may also be called VRA (Variable Rate Application) in the terminology of this emerging agriculture.
[0149] As a method for spot-treating Composition B, there are a method of spraying it on the soil at the location where plant diseases have occurred or at the location where plant diseases may occur (soil treatment), and a method of spraying Composition B on the plants where plant diseases have occurred or on the plants where plant diseases may occur (foliar treatment). Spraying is usually carried out using a spraying solution prepared by mixing Composition B with water. Although the amount of the spraying solution is not particularly limited, usually, within the section to be spot-treated, it is 50 - 1000 L / ha, preferably 100 - 500 L / ha, more preferably 140 - 300 L / ha. The ratio of the area to be spot-treated in the plant cultivation area (the ratio of the area where Composition B is sprayed to the entire area of a continuous cultivation area) is usually 1 - 99%, preferably 10 - 80%. Specifically, 20%, 30%, 40%, 50%, 60%, and 70% etc. can be mentioned. The treatment amount of Composition B during spot treatment, as the treatment amount of one active ingredient within the section to be spot-treated, is 5 - 2000 g per hectare, preferably 50 - 1500 g per hectare, more preferably 200 - 1000 g per hectare, and even more preferably 400 - 700 g per hectare. In addition, when carrying out spot treatment, an adjuvant or a drift reducing agent may be mixed. The types of the adjuvant or the drift reducing agent are not particularly limited, but for example, those mentioned above can be cited. The pH and hardness of the spraying solution are not particularly limited, but the pH is usually in the range of 5 - 9, and the hardness is usually in the range of 0 - 500. The time period for carrying out spot treatment is not particularly limited, but it is usually in the range from 5 am to 9 pm, and the photosynthetic photon flux density at the grass canopy level at the location where spot treatment is carried out is usually 10 - 2500 micromoles / m2 / second. On the other hand, spot treatment can also be carried out at night using the map information and the position information. The spraying pressure during spot treatment is not particularly limited, but it is usually 30 - 120 PSI, preferably 40 - 80 PSI. Here, the spraying pressure is the setting before introduction to the nozzle. The weather conditions for spot treatment are not particularly limited. However, the air temperature is usually 0 to 30°C, preferably 10 to 20°C, the ground temperature is usually 0 to 30°C, preferably 10 to 20°C, the relative humidity is 50 to 90%, preferably 40 to 80%, and the wind speed is 0 to 2 MPH.
[0150] The treatment methods for Composition B are more specifically hole treatment (hole spraying, hole treatment with soil mixing), base treatment (base spraying, base treatment with soil mixing, base irrigation, base treatment in the latter half of the seedling raising period), furrow treatment (furrow spraying, furrow treatment with soil mixing), ridging treatment (ridging spraying, ridging treatment with soil mixing, ridging spraying during the growth period), ridging treatment at sowing (ridging spraying at sowing, ridging treatment with soil mixing at sowing), overall treatment (overall soil spraying, overall soil mixing), side ridging treatment, water surface treatment (water surface application, water surface application after flooding), other soil spraying treatments (spraying of granules on leaves during the growth period, spraying under the tree crown or around the main trunk, spraying on the soil surface, soil surface mixing, sowing hole spraying, spraying on the surface of the ridge part, inter-plant spraying), other irrigation treatments (soil irrigation, irrigation during the seedling raising period, chemical solution injection treatment, ground-level irrigation, chemical solution drip irrigation, chemigation), seedling box treatment (seedling box spraying, seedling box irrigation, flooding of the seedling box with chemical solution), seedling tray treatment (seedling tray spraying, seedling tray irrigation, flooding of the seedling tray with chemical solution), seedbed treatment (seedbed spraying, seedbed irrigation, spraying on the seedbed for water seedlings, seedling dipping), bed soil mixing treatment (bed soil mixing, bed soil mixing before sowing, spraying before covering soil at sowing, spraying after covering soil at sowing, covering soil mixing), and other treatments (mixing with soil for hill covering, hoeing in, mixing with topsoil, mixing with soil in the rainwater runoff area, treatment of planting position, spraying of granules on the inflorescence, mixing with paste fertilizer, mixing with hydroponic solution, mixing hydroponic solution into the soil), etc.
[0151] The application of this compound or composition A may also reduce the mycotoxin content in the harvested materials and the foods and feeds prepared therefrom. The mechanism of the mycotoxin reduction effect is not limited, but is exerted, for example, by direct or indirect actions on mycotoxin-producing fungi. Examples of direct actions include bactericidal effects on mycotoxin-producing fungi and inhibitory effects on mycotoxin biosynthesis. Examples of indirect actions include effects on the microbiota (microbiome) such as the abundance ratio of mycotoxin-producing fungi to non-producing fungi, and reduction of fungal infections by suppressing damage by harmful arthropods. Also, mycotoxins include, but are not particularly limited to, the following. Deoxynivalenol (DON), nivalenol, fusarenone X, 15-Ac-DON, 3-Ac-DON, T2- and HT2-toxins, neosolaniol, fumonisins, zearalenone, moniliformin, fusarins, diacetoxyscirpenol (DAS), beauvericin, enniatins, fusaroproliferin, fusarenol, ochratoxin, patulin, sterigmatocystin, martrin, citrinin, rugulosin, rubratoxin, citreoviridin, cyclochlorotine, luteoskyrin, lolitrem B, slaframine, sporidesmin, ergot alkaloids (e.g., lysergic acid, ergotamine, ergometrine), aflatoxins, and cyclopiazonic acid. These mycotoxins can be produced, for example, by the following fungi. Species of the genus Fusarium, such as F. acuminatum, F. asiaticum, F. avenaceum, F. crookwellense, F. culmorum, F. graminearum (Gibberella zeae), F. equiseti, F. fujikoroi, F. moniliforme, F. musarum, F. oxysporum, F. proliferatum, F. poae, F. pseudograminearum, F. sam-bucinum, F. scirpi, F. semitectum, F. solani, F. sporotrichoides, F. langsethiae, F. subglutinans, F. tricinctum, F. verticillioides, etc.; species of the genus Aspergillus, such as A. flavus, A. parasiticus, A. nomius, A. ochraceus, A. carbonarius, A. clavatus, A. terreus, A. versicolor; species of the genus Penicillium, such as P. verrucosum, P. viridicatum, P. citrinum, P. expansum, P. claviforme, P. roqueforti, species of the genus Claviceps, such as C. purpurea, C. fusiformis, C.fusiformis), C. paspali, C. africana, etc.; species of the genus Stachybotrys; species of the genus Slafractonia, such as S. leguminicola, etc.; species of the genus Neotyphodium, such as N. lolii, etc.; species of the genus Pithomyces, such as P. chartarum.
[0152] By applying the present compound or composition A, depending on the plant species or variety, their growth location and growth conditions (soil, climate, growth period, nutrients), it is possible to improve the seedling establishment rate of plants, improve plant growth, improve tolerance to abiotic stress (for example, improve tolerance or tolerance to high or low temperatures, drought, waterlogging, over-wetting, or salts contained in water or soil, improve tolerance to osmotic stress, improve tolerance to drought stress, improve tolerance to ozone exposure, improve tolerance to ultraviolet stress, improve tolerance to wind stress, and improve tolerance to sunlight stress), improve flowering ability, improve ease of harvesting, promote maturation, increase yield, increase the number, size or weight of seeds or fruits, improve leaf greenness, maintain leaf greenness for a long period, increase the number of healthy leaves, suppress the progress of aging, reduce plant lodging, promote earlier flowering, increase the number of flowerings or fruit settings, increase the fruiting rate, improve the quality of the harvested product and / or increase nutritional value (for example, increase the sugar content in fruits, improve gluten strength, optimize protein content, optimize oil content, improve nutritional value), improve the storage stability of the harvested product and / or improve processability, etc. More specifically, as for the improvement of plant growth, it includes promoting stem elongation, promoting stem thickening, promoting an increase in the number of leaves or total leaf area, increasing the number of healthy leaves, and promoting stem branching (for example, promoting an increase in the number of stem branches), promoting lateral root formation (for example, increasing the number of lateral roots, etc.), increasing the auxin production sites in the roots (main roots or lateral roots), promoting root elongation, improving root spreading, and promoting root thickening. Also, it may be possible to improve tolerance to nutritional stress caused by a deficiency of any of the 17 essential nutrients (essential elements) for plant growth.
[0153] When using composition B for pest control in non-agricultural fields, its application rate can be widely varied depending on the type and occurrence frequency of the pests to be controlled, formulation form, application time, application method, application location, weather conditions, etc. As specific application methods, for example, when applying to a building, it includes treatment of the building's walls, floors, underfloors, ceilings, roofs, attics, doors, windows, screen doors, etc., treatment of the indoor space of the building, and installation of bait agents and resin formulations. When applying outdoors, examples include treatment of the ground, outer walls, fences, ditches, soil injection under floors or on the ground, etc., treatment of spaces, and treatment of granular or resin formulations in water. When applying to building materials, examples of methods include kneading and coating on building materials. When applying to food and daily necessities, examples include treatment of emulsions, wettable powders, flowables, oils, etc. on the walls, floors, and ceilings of the places where the food and daily necessities are stored, treatment of fumigants, vaporizers, aerosol sprays, etc. in spaces, installation of poisonous baits, resin formulations, etc., kneading, coating, treatment with powders, emulsions, etc. of the daily necessities. When applying to wood, examples include coating, spraying, dipping, impregnation, injection, mixing during wood processing, and mixing with adhesives. When applying to vehicles, examples include treatment of the interior space and walls of the vehicle, and installation of poisonous baits and resin formulations. When applying to animals, methods of oral administration by mixing into capsule agents, chewables, syrups, tablets, powders, and feed / drinking water, etc., methods of administration by suppositories and injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), methods of spraying, coating, and dripping liquid agents such as spot-on agents, pour-on agents, shampoo agents, lotion agents, paste agents, etc., or methods of processing resin formulations into collars, ear tags, bracelets, and clothing, etc. and wearing them.
[0154] When Composition B is used for pest control in non-agricultural fields, the application rate for surface treatment is the amount of one active ingredient per 1 m2 of the treated area, usually 0.01 to 1000 mg, preferably 10 to 500 mg, more preferably 20 to 400 mg (specifically, for example, 25 mg, 50 mg, 400 mg). The application rate for space treatment is the amount of one active ingredient per 1 m3 of the treated space, usually 0.01 to 500 mg. The application rate for treatment in water is the amount of one active ingredient per 1 L of water volume, usually 0.001 to 1000 mg, more preferably 0.01 to 100 mg. The application rate for treatment on animals is usually the amount of one active ingredient per 1 kg of the animal's body weight, usually in the range of 0.01 to 1000 mg. When Composition B is formulated into an emulsion, wettable powder, flowable agent, etc., it is usually diluted with water so that the concentration of one active ingredient becomes 0.1 to 10000 ppm and then applied. When it is formulated into an oil agent, etc., it is applied as it is or usually diluted with kerosene, light oil, etc. so that the concentration of one active ingredient becomes 0.1 to 10000 ppm and then applied. Granules, powders, aerosol agents, fumigants, fumigation agents, bait agents, resin preparations, etc. are applied as they are. Also, incense sticks are ignited and applied. Electric mosquito mats, liquid mosquito control preparations, fan-type mosquito control preparations, ultrasonic vibration-type preparations, electrostatic spray-type preparations, etc. are usually applied using a power source or battery.
[0155] Examples of plants for which Composition B can be used include the following. Crops; maize (dent, flint, soft, pop, waxy, sweet, field corn), rice (long grain, short grain, medium grain, japonica, tropical japonica, indica, javanica, paddy rice, upland rice, floating rice, direct seeding, transplantation, glutinous rice), wheat (bread wheat (hard, soft, medium, red wheat, white wheat), durum wheat, spelt wheat, club wheat, each winter wheat type, spring wheat type), barley (two-row barley (= beer barley), six-row barley, naked barley, glutinous barley, each winter barley type, spring barley type), rye (winter rye type, spring rye type), triticale (winter triticale type, spring triticale type), oats (winter oats type, spring oats type), sorghum, cotton (upland cotton, pima cotton), soybean (fully mature seed harvesting variety, edamame variety, green forage variety, each indeterminate growth type, determinate growth type, semi-determinate growth type), peanut, adzuki bean, lima bean, azuki bean, mung bean, kidney bean, urad bean, scarlet runner bean, winged bean, moth bean, tepary bean, broad bean, pea, chickpea, lentil, lupin, kidney bean, alfalfa, potato (tetraploid, diploid, true seed variety), buckwheat, sugar beet (for sugar production, for feed, root vegetable, leaf vegetable, for fuel), rapeseed (winter rapeseed type, spring rapeseed type), canola (winter canola type, spring canola type), sunflower (for oil extraction, for food, for ornamental purposes), sugarcane, tobacco, tea tree, mulberry, etc. Vegetables; Solanaceae vegetables (eggplant, tomato, pepper, chili pepper, bell pepper, etc.), Cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon, squash, etc.), Brassicaceae vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, mustard spinach, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, shungiku, artichoke, lettuce, etc.), Alliaceae vegetables (leek, onion, garlic, asparagus, etc.), Apiaceae vegetables (carrot, parsley, celery, American lovage, etc.), Amaranthaceae vegetables (spinach, common amaranth, etc.), Lamiaceae vegetables (perilla, mint, basil, lavender, etc.), strawberry, sweet potato, yam, taro, etc. Fruit trees; pome fruits (apple, pear, Japanese pear, Chinese pear, quince, medlar, etc.), stone fruits (peach, plum, nectarine, Japanese apricot, apricot, cherry, prune, etc.), citrus fruits (mandarin orange, orange, lemon, lime, grapefruit, etc.), nuts (chestnut, walnut, hazelnut, almond, pistachio, cashew nut, macadamia nut, etc.), berry fruits (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster mushroom, fig, olive, loquat, banana, coffee, date palm, coconut palm, etc. Ornamental plants; flowering trees and shrubs, street trees (Paulownia, Catalpa, Japanese Judas tree, eucalyptus, ginkgo, lilac, maple, oak, poplar, magnolia, wisteria, plane tree, zelkova, elm, beech, spruce, fir, pine, Japanese red pine, dawn redwood), flowers, foliage plants, lawns.
[0156] The above-mentioned plants are not limited as long as they are commonly cultivated varieties.
[0157] Examples of corn varieties include the following. P30F53, P30F53RR, P30F53YHV, DKB390, DKB390IPRO3, DKC62 - 08, DKC35 - 88RIB RR2 BT, P7958AM RR2 LL BT, NK1120 - 3122 RR+GLU+ECB+CRW, P9608AM LL RR2 CRW ECB, Golden Bantam
[0158] Examples of wheat varieties include the following. PAKITO; KWS Zyatt; Skyfall; Crusoe; RGT Illustrious; KWS Extrase; KWS Extase; KWS Siskin; LG Detroit; KWS Lili; KWS Firefly; KWS Barrel; Elicit; KWS Basset; Zulu; LGSkyscraper; RGT Saki; LG Spotlight; KWS Jackal; Elation; Bennington; LG Sundance; LG Motown; Leeds; Viscount; Revelation; SY Insitor; KWS Kinetic; Gleam; RGT Gravity; KWS Kerrin; Shabras; Graham; KWS Crispin; Theodore; Dunston; Costello
[0159] Examples of wheat varieties include, for example, the following. Electrum; Craft; SY Venture; KWS Hawking; LG Mountain; KWS Gimlet; Jordan; LG Flynn; KWS Orwell; Valerie; Surge; KWS Creswell; KWS Tower; KWS Glacier; California; KWS Cassia; Belmont; SY Kingsbarn; SY Baracooda; Bazooka; Belfry; KWS Astaire; Funky; Libra; SY Splendor; Firefoxx; Cosmopolitan; SY Tungsten; LG Diablo; Laureate; RGT Planet; RGT Asteroid; Iconic; KWS Sassy; Sienna; Propino; Fairing; Concerto; Fairway; Prospect
[0160] Examples of soybean varieties include, for example, the following. 5G8015 RR IPRO; ANTA 82 PR; AS 3797 IPRO; BMX POTENCIA RR; BRS 8170IPRO; BRS 8280 RR; DM 6583 IPRO; M 5947 IPRO; M 6410 IPRO; M 8644 IPRO; M8372 IPRO; M9114PR; MONSOY 5947 IPRO; MONSOY 7730 IPRO; MSOY 8372 IPRO; NA 5909 RG; NS 5445 IPRO; NS 5909 PR; NS 5969 IPRO; NS 6700 IPRO; ST 797; TMG 1180 RR; TMG 1188 RR NS 4823 RR; NS 5445 IPRO; NA 5909 RR; NS 6209 RR; NS 6601 IPRO; NS 6823 RR; NS 6906 IPRO; NS 7000 IPRO; NS 7200 RR; NS 7227 RR; NS 7300 IPRO; NS 7474 IPRO; NS 7505 IPRO; NS 7709 IPRO; NS 8270 IPRO; NS 8393 IPRO RR; NS 5106 IPRO; NS 5727 IPRO; NS 5959 IPRO; NS 6390; NS 6700 IPRO; NS 6828; NS 6909 IPRO - Centro; NS 7000 IPRO -SUL; NS 7202 IPRO; NS 7237 IPRO; NA 7337 RR; NS 7490 RR; NS 7667 IPRO; NS 7901; NS 8338 IPRO; NS 8490 IPRO; NS 5160 IPRO; NA 5909- RG IPRO; NS 6006 IPRO; NS 6535 IPRO; NS 6767 RR; NS 6906 IPRO - Centro; NS 6909 IPRO - Sul; NS 7070 IPRO; NS 7209 IPRO; NS 7300 IPRO - Centro; NS 7338 IPRO; NS 7497 RR; NS 7670 RR ; NS 8094 RR; NS 8383 RR; Syn 15600 IPRO;Syn 16861 IPRO; Syn 1059 RR; Syn 1163 RR; Syn 1258 RR; Syn 1281 RR; Syn 1683 IPRO; Syn 1785 IPRO; Syn 1687 IPRO; Syn 13610 IPRO; Syn 15640 IPRO; Syn 15630 IPRO; Syn 1562 IPRO; Syn 1561 IPRO; Syn 1366 IPRO; CZ 15B64 IPRO; CZ15B70 IPRO; CZ 15B92 IPRO; CZ 26B05 IPRO; CZ 26B10 IPRO; CZ 26B77 IPRO; CZ 7022 IPRO; CZ 26B42 IPRO; CZ 26B36 IPRO; CZ 26B42 IPRO; CZ 26B77 IPRO; TEC 7022 IPRO; CZ 37B22 IPRO; CZ 37B43 IPRO; CZ 47B90 IPRO; CZ 58B28 IPRO; CZ 48B32 IPRO; CZ 58B61 IPRO; W 791 RR; W 842 RR; CZ 58B61 IPRO; BS 1511 IPRO; BS 1543 IPRO; ST 575 IPRO; BS 1580 IPRO; ST 592 IPRO; BS 2590 IPRO; BS 2606 IPRO- SUL; ST 644 IPRO; BSIRGA 1642 IPRO; TEC 6702 IPRO; BS 1691 IPRO; TEC 7849 IPRO; TECIRGA 6070 RR; BS 1519 LL; BS 2606 IPRO -CERRADO; TEC 6702 IPRO -CERRADO; TEC 7849 IPRO-CERRADO; ST 721 IPRO; TEC 7578 IPRO; ST 777 IPRO; ST 797 IPRO; ST 804 IPRO; ST 830 IPRO; ST 845 IPRO; W 787 IPRO; W 799 RR; ST 815 RR; ST 820 RR; ST 860 RR; ST 920 RR; W 870; BRASMAX COMPACTA IPRO; BRASMAX FIBRA IPRO BRASMAX ZEUS IPRO; BRASMAX DELTA IPRO; BRASMAX RAIO IPRO; BRASMAX ICONE IPRO; BRASMAX LANCA IPRO; BRASMAX GARRA IPRO; BRASMAX PONTA IPRO BRASMAX VALENTE RR; BRASMAX POTENCIA RR; BRASMAX TORNADO RR; BRASMAX ALVO RR; BRASMAX ATIVA RR; BRASMAX VELOZ RR; BRASMAX VELOZ RR; BRASMAX VORAZ IPRO; BRASMAX EXTREMA IPRO; BRASMAX UNICA IPRO; BRASMAX DOMINIO IPRO; BRASMAX FOCO IPRO; BRASMAX EXTREMA IPRO; BRASMAX EXTRA IPRO; BRASMAX CERTA IPRO; BRASMAX POWER IPRO; BRASMAX ULTRA IPRO; BRASMAX FLX IPRO; BRASMAX BONUS; BRASMAX PONTA IPRO; BRASMAX OPUS IPRO; BRASMAX DESAFIO RR; M5705IPRO; MS5838IPRO; M5892IPRO; M8644IPRO; M5917IPRO; M5947IPRO; M6210IPRO; M7739IPRO; M8349IPRO; M8372IPRO; M6410IPRO; M7110IPRO; M7198IPRO; M8210IPRO; M8808IPRO; 95R51; 95Y52; 97R22IPRO; 99R03; P98Y70; 95R90IPRO; 95Y72; 98Y21IPRO; 99R09; 95R95IPRO; 96Y90; 98Y30; P98C81; BG4290; BG4786; CD2720 IPRO; CD2728 IPRO; CD2820 IPRO; CD2851 IPRO; CD2857 RR; DS5916 IPRO; 5D6215 IPRO; 5D634 RR; 5G8015 IPRO; DS6017 IPRO; DS7417 IRPO; B5860 IPRO; BG4781 IPRO; DS6217 IPRO; TMG2375 IPRO; TMG2379 IPRO; TMG7058 IPRO; TMG2165 IPRO; TMG2165 IPRO; TMG4377 IPRO; TMG1180 RR;TMG7063IPRO; TMG7062 IPRO; TMG7067 IPRO; TMG4182; TMG4182; TMG7262 RR; TMG2185 IPRO; TMG7061 IPRO; TMG2381 IPRO; TMG2383 IPRO; TMG1288 RR; TMG2181 IPRO; TMG1188 RR; TMG2378 IPRO; TMG2173 IPRO; TMG4185; TMG 7363 RR: TMG7260 IPRO; TMG133 RR; TMG132 RR; ANTA82; TMG1182 RR; TMG2182 IPRO; TMG7161 RR; TMG2183 IPRO; TMG2286 IPRO; K8620 IPRO; RK5519 RR; M6210 IPRO; RK6719 IPRO; RK6316 IPRO; RK7518 IPRO; RK8115 IPRO; RK8317 IPRO; RK5813 RR; RK6813 RR; BRS 1001IPRO; BRS 1074IPRO; BRS 6970IPRO; BRS 7570IPRO; BRS 9383IPRO; BRS 1003IPRO; BRS 706IPRO; BRS 7170IPRO; BRS 7780IPRO; BRS 1007IPRO; BRS 713IPRO; BRS 7270IPRO; BRS 7180IPRO; BRS1010IPRO; BRS 729IPRO; BRS 7470IPRO; BRS 9180IPRO; BRS 279RR; BRS 360RR; BRS 413RR; BRS 8890RR; BRSGO 8151RR; BRSMG 850GRR; BRS 378RR; BRSMG 760SRR; BRS 9090RR; BRS 740SRR; BRS FAVORITA RR; BRS 333RR; BRS 388RR; BRS 7950RR; BRS 9280RR; BRSMG 750SRR; BRS Sambaiba RR; BRS 359RR; BRS 399RR; BRS 8160RR; BRS 7460RR; BRSMG 811CRR; BRS VALIOSA RR; BRS 232; BRS 283; BRS 257;BRS 284; BRS 317 ; BRS 361; BRSMG 800A; BRSGO 8360; BRSGO LUZIANIA; BRS Petala; BRSMG 790A; BRSMG 7525; MG / BR 46 (Conquista); BRS 8381; BRS 217 (Flora); BRS 252 (Serena); BRSMG 810C; BRSMG 68 (Vencedora); BRSGO 7960; BRS 8480; BRSGO Chapadoes; BRS Raimunda; BRS313 (TIETA); BRS Corisco; BRS Barreiras; BRS 314 (Gabriela); BRS Tracaja; BRS Perola
[0161] The above-mentioned plant varieties are not particularly limited as long as they are commonly cultivated varieties.
[0162] The above-mentioned plants may be plants that can be produced by natural cross-breeding, plants that can be generated by mutation, F1 hybrid plants, or transgenic plants (also referred to as genetically modified plants). These plants generally have characteristics such as resistance to herbicides, accumulation of toxic substances against pests (also referred to as pest resistance), suppression of susceptibility to diseases (also referred to as disease resistance), increase in yield potential, improvement in resistance to biotic and abiotic stress factors, modification of the quality of the product (for example, increase or decrease in the content of specific components, change in composition, improvement in preservability or processability), modification of the harvesting time (for example, extremely early maturing, early maturing, medium maturing, late maturing, extremely late maturing), etc.
[0163] An F1 hybrid plant is a first-generation hybrid obtained by crossing two different strains of varieties, and generally has the characteristic of hybrid vigor with traits superior to those of either parent. A transgenic plant is a plant to which characteristics that cannot be easily obtained by cross-breeding, mutagenesis, or natural recombination in the natural environment are imparted by introducing foreign genes from other organisms such as microorganisms.
[0164] Examples of techniques for creating the above-described plants include conventional breeding techniques; genetic recombination techniques; genomic breeding techniques; new breeding techniques; and genome editing techniques. Conventional breeding techniques are techniques for obtaining plants having desirable properties through mutation or crossing. Genetic recombination techniques are techniques for conferring new properties on an organism by extracting a target gene (DNA) from a certain organism (e.g., a microorganism) and introducing it into the genome of another target organism, or techniques such as antisense technology or RNA interference technology for conferring new or improved characteristics by silencing other genes present in a plant. Genomic breeding techniques are techniques for improving the efficiency of breeding using genomic information, and include DNA marker (also called genomic marker or gene marker) breeding techniques and genomic selection. For example, DNA marker breeding is a method of selecting progeny having a target useful trait gene from a large number of cross progeny using a DNA marker, which is a DNA sequence serving as a landmark for the location of a specific useful trait gene on the genome. By analyzing cross progeny using DNA markers at the seedling stage, it is possible to effectively shorten the time required for breeding. Genomic selection is a technique that creates a prediction formula from previously obtained phenotypic and genomic information and predicts traits without evaluating the phenotype from the prediction formula and genomic information, and is a technology that can contribute to improving breeding efficiency. New breeding techniques are a general term for variety improvement (breeding) techniques that combine molecular biological techniques. For example, there are techniques such as cisgenesis / intragenesis, oligonucleotide-directed mutagenesis, RNA-dependent DNA methylation, genome editing, grafting onto GM rootstocks or scions, reverse breeding, agroinfiltration, and seed production technology (Seed Production Technology, SPT). Genome editing technology is a technology that converts genetic information in a sequence-specific manner and enables deletion of base sequences, substitution of amino acid sequences, introduction of foreign genes, etc. As tools, for example, zinc-finger nucleases (ZFNs), TALENs, CRISPR / Cas9, CRISPR / Cpf1, and meganucleases that can perform sequence-specific DNA cleavage can be mentioned. In addition, there are sequence-specific genome modification techniques such as CAS9 nickase and Target-AID created by modifying the above-mentioned tools.
[0165] Examples of the above-mentioned plants include, for example, plants listed in the registered database of genetically modified crops (GM APPROVAL DATABASE) on the electronic information site of the INTERNATINAL SERVICE for the ACQUISITION of AGRI-BIOTECH APPLICATIONS (ISAAA) (http: / / www.isaaa.org / ). More specifically, for example, herbicide-tolerant plants, pest-resistant plants, disease-resistant plants, plants with modified product quality (e.g., increased or decreased content of components, changes in composition, improved shelf life or processability), plants with modified fertility traits, abiotic stress-tolerant plants, or plants with modified traits related to growth and yield.
[0166] Examples of herbicide-tolerant plants are given below. Mechanisms of tolerance to herbicides include, for example, reducing the affinity between the herbicide and its target; rapid metabolism (decomposition, modification, etc.) of the herbicide by the expression of an enzyme that inactivates the herbicide; inhibiting the uptake of the herbicide into the plant body; and inhibiting the translocation of the herbicide in the plant body.
[0167] Plants imparted with herbicide tolerance by genetic recombination technology include, for example, protoporphyrinogen oxidase (hereinafter abbreviated as PPO) herbicides such as flumioxazin; 4-hydroxyphenylpyruvate dioxygenase (hereinafter abbreviated as HPPD) inhibitors such as isoxaflutole and mesotrione; acetolactate synthase (hereinafter abbreviated as ALS) inhibitors such as imidazolinone herbicides like imazetapyr and sulfonylurea herbicides like thifensulfuron-methyl; 5-enolpyruvylshikimate-3-phosphate synthase (hereinafter abbreviated as EPSPS) inhibitors such as glyphosate; glutamine synthetase inhibitors such as glufosinate; auxin-type herbicides such as 2,4-D and dicamba; and plants imparted with tolerance to oxynil herbicides such as bromoxynil. Preferred herbicide-tolerant transgenic plants are cereals such as wheat, barley, rye, and oats, canola, sorghum, soybean, maize, cotton, rice, rapeseed, sugar beet, sugarcane, grape, lentil, sunflower, alfalfa, pome fruits, stone fruits, coffee, tea, strawberry, miscanthus, tomato, potato, cucumber, lettuce and other vegetables, more preferably cereals such as wheat, barley, rye, and oats, soybean, maize, rice, grape, tomato, potato, and pome fruits. Specific herbicide-tolerant plants are shown below. Glyphosate-tolerant plants: Obtained by introducing one or more of the following genes: a glyphosate-tolerant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4, a glyphosate N-acetyltransferase gene (gat4601 or gat4621) modified from a glyphosate N-acetyltransferase gene derived from Bacillus licheniformis, a glyphosate oxidase gene (goxv247) derived from Ochrobacterum anthropi strain LBAA, or an EPSPS gene with a glyphosate tolerance mutation derived from Zea mays (mepsps or 2mepsps). Major plants include, for example, Medicago sativa, Brassica napus, Gossypium hirsutum L., Agrostis stolonifera, Zea mays L., Brassica rapa, Solanum tuberosum L., Glycine max L., Beta vulgaris, and Triticum aestivum. Some glyphosate-tolerant plants are commercially available. For example, genetically modified plants with CP4 epsps are sold under trademark names including "Roundup Ready®", genetically modified plants with gat4601 or gat4621 are sold under trademark names such as "Optimum GAT™", "Optimum® Gly canola", etc., and genetically modified plants with mepsps or 2mepsps are sold under the trademark name "GlyTol™".More specific glyphosate-tolerant plants include, for example, maize such as "Roundup Ready(Trademark) Maize", "Roundup Ready(Trademark) 2 Maize", "Agrisure(Trademark) GT", "Agrisure(Trademark) GT / CB / LL", "Agrisure(Trademark) GT / RW", "Agrisure(Trademark) 3000GT", "YieldGard(Trademark) VT(Trademark) Rootworm(Trademark) RR2", and "YieldGard(Trademark) VT Triple"; soybean such as "Roundup Ready(Trademark) Soybean" and "Optimum GAT(Trademark)"; cotton such as "Roundup Ready(Trademark) Cotton", "Roundup Ready(Trademark) Flex Cotton", and "GlyTol(Trademark)"; canola such as "Roundup Ready(Trademark) Canola" and "Optimum(Registered Trademark) Gly canola"; alfalfa such as "Roundup Ready(Trademark) Alfalfa"; rice such as "Roundup Ready(Trademark) Rice"; sugar beet such as "Roundup Ready(Trademark) sugarbeet" and "InVigor(Trademark) sugarbeet"; and wheat (Triticum aestivum) sold under the trademark name "Roundup Ready(Trademark) wheat". Glyphosate herbicide-tolerant plants: Obtained by introducing one or more of the following genes: the gene (bar) for phosphinothricin N-acetyltransferase (hereinafter abbreviated as PAT) derived from Streptomyces hygroscopicus, the PAT gene (pat) derived from Streptomyces viridochromogenes, or the synthetic PAT gene (pat syn) derived from Streptomyces viridochromogenes strain Tu494. Main plants include, for example, Argentine canola (Brassica napus), chicory (Cichorium intybus), cotton (Gossypium hirsutum L.), corn (Zea mays L.), Polish canola (Brassica rapa), rice (Oryza sativa L.), soybean (Glycine max L.), and sugar beet (Beta vulgaris). Some glyphosate-tolerant plants are commercially available. For example, genetically modified plants into which bar or pat has been introduced are sold under the trade names "LibertyLink (trademark)", "InVigor (trademark)", or "WideStrike (trademark)". More specific glyphosate-tolerant plants are, for example, corn sold under the trade names "Roundup Ready (trademark) 2", "Liberty Link (trademark)", "Herculex (trademark) I", "Herculex RW", "Herculex XTRA (trademark)", "Agrisure (trademark) GT / CB / LL", "Agrisure (trademark) CB / LL / RW", and "Bt10"; cotton sold under the trade name "FiberMax (trademark) Liberty Link (trademark)"; rice sold under the trade name "Liberty Link (trademark) Rice"; canola sold under the trade name "inVigor (trademark) Canola"; soybean sold under the trade name "Liberty Link (trademark) Soybean"; and sugar beet sold under the trade name "Liberty Link (trademark) sugarbeet". Oxynil herbicide (e.g., bromoxynil)-tolerant plants: Obtained by introducing the nitrilase gene (bxn) derived from Klebsiella pneumoniae subsp. Ozaenae. Main plants include, for example, Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), and tobacco (Nicotiana tabacum L.). Some oxynil herbicide-tolerant plants are commercially available. For example, they are sold under trademark names including "Navigator (trademark)" or "BXN (trademark)". More specific oxynil herbicide-tolerant plants include, for example, cotton sold under the trademark name "BXN (trademark) Cotton"; Argentine canola sold under the trademark name "Navigator (trademark) Cotton". ALS herbicide-tolerant plants: Carnation (Dianthus caryophyllus) into which the ALS gene (surB) conferring ALS herbicide tolerance derived from tobacco (Nicotiana tabacum) has been introduced is sold under trademark names such as, for example, "Moondust (trademark)", "Moonshadow (trademark)", "Moonshade (trademark)", "Moonlite (trademark)", "Moonaqua (trademark)", "Moonvista (trademark)", "Moonique (trademark)", "Moonpearl (trademark)", "Moonberry (trademark)" or "Moonvelvet (trademark)". Flax (Linum usitatissumum L.) into which the ALS gene (als) conferring ALS herbicide tolerance derived from Arabidopsis thaliana has been introduced is sold under the trademark name such as, for example, "CDC Triffid Flax". Maize (Zea mays L.) having resistance to sulfonylurea and imidazolinone herbicides into which the ALS gene (zm-hra) conferring ALS herbicide tolerance derived from maize has been introduced is sold under the trademark name such as, for example, "Optimum GAT (trademark)". Soybean having resistance to imidazolinone herbicides into which the ALS gene (csr1-2) conferring ALS herbicide tolerance derived from Arabidopsis thaliana has been introduced is sold under the trademark name such as, for example, "Cultivance". Soybean (Glycine max) into which the ALS gene (gm-hra) conferring ALS herbicide tolerance derived from soybean has been introduced is sold under the trademark names such as, for example, "Treus (trademark)", "Plenish (trademark)" and "Optimum GAT (trademark)". There is also cotton into which the ALS gene (S4-HrA) conferring ALS herbicide tolerance derived from tobacco (Nicotiana tabacum cv. Xanthi) has been introduced. HPPD herbicide-tolerant plants: Obtained by introducing the HPPD gene (avhppd-03) derived from Avena sativa. For example, soybeans into which the PAT gene (pat) derived from Streptomyces viridochromogenes is introduced simultaneously with the above gene are sold under the trademark name "Herbicide-tolerant Soybean line" as soybeans tolerant to mesotrione and glufosinate. 2,4-D tolerant plants or ACCase herbicide-tolerant plants: Maize tolerant to 2,4-D or ACCase herbicides into which the aryloxyalkanoate dioxygenase gene (aad-1) derived from Sphingobium herbicidovorans is introduced are sold, for example, under the trademark name "Enlist(™) Maize". Soybeans and cotton tolerant to 2,4-D or ACCase herbicides into which the aryloxyalkanoate dioxygenase gene (aad-12) derived from Delftia acidovorans is introduced are known and are sold, for example, under the trademark name "Enlist(™) Soybean". Dicamba herbicide-tolerant plants: Obtained by introducing the dicamba monooxygenase gene (dmo) derived from Stenotrophomonas maltophilia strain DI-6. Soybeans and cotton into which the above gene is introduced are known. Soybeans (Glycine max L.) into which the glyphosate-tolerant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4 is introduced simultaneously with the above gene are sold, for example, under the trademark name "Genuity(®) Roundup Ready(™) 2 Xtend(™)". Additional plants with modified herbicide resistance are widely known, for example, alfalfa, apple, barley, eucalyptus, flax, grape, chickpea, rapeseed, pea, potato, rice, sugar beet, sunflower, tobacco, tomato, shibakusa and wheat that are resistant to glyphosate (see, for example, US5188642, US4940835, US5633435, US5804425, US5627061); legumes, cotton, soybean, pea, potato, sunflower, tomato, tobacco, corn, sorghum and sugarcane that are resistant to dicamba (see, for example, WO2008 / 051633, US7105724 and US5670454); soybean, sugar beet, potato, tomato and tobacco that are resistant to glufosinate (see, for example, US6376754, US5646024, US5561236); cotton, peppers, apple, tomato, sunflower, tobacco, potato, corn, cucumber, wheat, soybean, sorghum and minor cereals that are resistant to 2,4-D (see, for example, US6153401, US6100446, WO2005 / 107437, US5608147 and US5670454); canola, corn, millet, barley, cotton, mustard, lettuce, lentil, melon, oats, durum wheat, turnip, potato, rice, rye, sorghum, soybean, sugar beet, sunflower, tobacco, tomato and wheat that are resistant to ALS-inhibiting herbicides (for example, sulfonylurea herbicides or imidazolinone herbicides) (see, for example, US5013659, WO2006 / 060634, US4761373, US5304732, US6211438, US6211439 and US6222100), in particular rice that is resistant to imidazolinone herbicides, rice having specific mutations in the acetohydroxyacid synthase gene (for example, S653N, S654K, A122T, S653(At)N, S654(At)K, A122(At)T) (see, for example, US2003 / 0217381, WO2005 / 020673); HPPD-inhibiting herbicides (for example, isoxazole herbicides such as isoxaflutole;Barley, sugarcane, rice, corn, tobacco, soybean, cotton, rapeseed, sugar beet, wheat and potato that are resistant to diketonitrile, a degradation product of isoxaflutole, or to triketone herbicides such as sulcotrione and mesotrione, or pyrazole herbicides such as pyrazolate (see, for example, WO2004 / 055191, WO1996 / 38567, WO1997 / 049816 and US6791014); and wheat, soybean, cotton, sugar beet, rapeseed, rice, corn, sorghum, sugarcane and sugar beet that are resistant to PPO-inhibiting herbicides (see, for example, US2002 / 0073443, US2008 / 0052798, Pest Management Science, 61, 2005, 277-285).;
[0168] Examples of plants with herbicide tolerance conferred by conventional variety improvement techniques or genomic breeding techniques include rice "Clearfield® Rice", wheat "Clearfield® Wheat", sunflower "Clearfield® Sunflower", lentils "Clearfield® lentils", and canola "Clearfield® canola" (products of BASF), which are tolerant to imidazolinone ALS-inhibiting herbicides such as imazethapyr and imazamox; soybean "STS soybean", which is tolerant to sulfonylurea ALS-inhibiting herbicides such as thifensulfuron-methyl; corn "SR corn" (also known as "Poast Protected® corn"), which is tolerant to acetyl-CoA carboxylase inhibitors such as trione oxime herbicides and aryloxyphenoxypropionate herbicides; sunflower "ExpressSun®", which is tolerant to sulfonylurea herbicides such as tribenuron; rice "Provisia™ Rice", which is tolerant to acetyl-CoA carboxylase inhibitors such as quizalofop; canola "Triazine Tolerant Canola", which is tolerant to photosystem II inhibitors; and sorghum "Igrowth™", which is tolerant to imidazolinone herbicides.
[0169] Examples of plants with herbicide tolerance conferred by genome editing technologies include canola "SU Canola (registered trademark)" with sulfonylurea herbicide tolerance using the Rapid Trait Development System (RTDS (registered trademark)). RTDS (registered trademark) corresponds to oligonucleotide-directed mutagenesis of genome editing technologies and is a technology that can introduce mutations without cleaving DNA in plants via Gene Repair Oligonucleotide (GRON), that is, a chimeric oligonucleotide of DNA and RNA. Other examples include maize with reduced herbicide tolerance and phytic acid content by deleting the endogenous gene IPK1 using zinc finger nuclease (see, for example, Nature 459, 437-441 in 2009); rice conferred with herbicide tolerance using CRISPR-Cas9 (see, for example, Rice, 7, 5 in 2014).
[0170] Examples of plants with herbicide tolerance conferred by new breeding technologies include, for example, soybeans in which the properties of the GM rootstock are conferred on the scion using variety improvement technology using grafting. Specifically, examples include soybeans in which glyphosate tolerance was conferred on non-transgenic soybean scions using Roundup Ready (registered trademark) soybeans with glyphosate tolerance as the rootstock (see Weed Technology 2013, 27, 412).
[0171] Examples of plants with pest resistance are given below.
[0172] Examples of plants imparted with resistance to Lepidoptera pests by genetic recombination technology include, for example, maize (Zea mays L.), soybean (Glycine max L.), cotton (Gossypium hirsutum L.), rice (Oryza sativa L.), poplar (Populus sp.), tomato (Lycopersicon esculentum), eggplant (Solanum melongena), and sugarcane (Saccharum sp.) into which a gene encoding a delta-endotoxin, an insecticidal protein derived from the soil bacterium Bacillus thuringiensis (hereinafter abbreviated as Bt bacterium), has been introduced. Examples of delta-endotoxins that impart resistance to Lepidoptera pests include Cry1A, Cry1Ab, modified Cry1Ab (Cry1Ab with some parts deleted), Cry1Ac, Cry1Ab-Ac (a hybrid protein in which Cry1Ab and Cry1Ac are fused), Cry1C, Cry1F, Cry1Fa2 (modified cry1F), moCry1F (modified Cry1F), Cry1A.105 (a hybrid protein in which Cry1Ab, Cry1Ac, and Cry1F are fused), Cry2Ab2, Cry2Ae, Cry9C, Vip3A, and Vip3Aa20. Examples of plants imparted with resistance to Coleoptera pests by genetic recombination technology include, for example, maize and potato into which a gene encoding a delta-endotoxin, an insecticidal protein derived from the Bt bacterium, a soil bacterium, has been introduced. Examples of delta-endotoxins that impart resistance to Coleoptera pests include Cry3A, mCry3A (modified Cry3A), Cry3Bb1, Cry34Ab1, Cry35Ab1, Cry6A, Cry6Aa, and mCry6Aa (modified Cry6Aa). Examples of plants imparted with resistance to Diptera pests by genetic recombination technology include, for example, maize (Zea mays L.) into which a synthetic gene encoding a hybrid protein eCry3.1Ab, which is a fusion of Cry3A and Cry1Ab derived from the soil bacterium Bt, has been introduced, and cotton (Gossypium hirsutum L.) into which a gene encoding a trypsin inhibitor CpTI derived from cowpea (Vigna unguiculata) has been introduced. Furthermore, there are poplars into which a gene encoding a protease inhibitor protein A (API) derived from arrowhead (Sagittaria sagittifolia) has been introduced, which exhibit resistance to a wide range of pests. Insecticidal proteins that confer pest resistance to plants also include hybrid proteins, proteins with partial deletions, and modified proteins of the above insecticidal proteins. Hybrid proteins are produced by combining different domains of multiple insecticidal proteins using genetic recombination technology, and Cry1Ab-Ac and Cry1A.105 are known, for example. Known proteins with partial deletions include Cry1Ab with a partial deletion of the amino acid sequence. Known modified proteins include proteins in which one or more amino acids of the native delta-endotoxin have been substituted, such as Cry1Fa2, moCry1F, and mCry3A. Modified proteins also include cases where a protease recognition sequence that does not naturally exist has been inserted into the toxin. For example, Cry3A055 in which a cathepsin G-recognition sequence has been inserted into the Cry3A toxin (see WO2003 / 018810) can be mentioned. Cotton (event MON88702) into which a modified BT protein Cry51Aa2 (Cry51Aa2.834_16) has been introduced by genetic recombination technology has been developed by Monsanto and exhibits resistance to species of the genus Lygus such as Lygus lineolaris, Hemiptera such as aphids, and Thysanoptera such as species of the genus Frankliniella. In addition, as insecticidal proteins that confer pest resistance to plants by genetic recombination technology, for example, insecticidal proteins derived from Bacillus cereus or Bacillus popilliae; plant insecticidal proteins Vip1, Vip2, Vip3 (subclasses Vip3Aa to Vip3Aj, Vip3Ba, Vip3B, and Vip3Ca are known, specifically, for example, Vip3Aa20 and Vip3Aa61 are known) and Vip4; insecticidal proteins derived from nematode-symbiotic (colony-forming in nematodes) bacteria such as Photorhabdus spp. like Photorhabdus luminescens or Xenorhabdus spp. like Xenorhabdus nematophilus; insecticidal protein Tma12 (insecticidal protein Tma12 derived from Tactaria macrodonata) from the fern plant Tectaria macrodonta; insecticidal protein IPD083 (insecticidal protein IPD083 derived from Adiantum spp.) from the fern plant Adiantum spp.; insecticidal protein IPD113 (insecticidal protein IPD113 derived from Pteris cretica cv. albolineata or Pteris umbrosa) from the fern plant Pteris cretica cv. albolineata or Pteris umbrosatoxins produced by animals containing insect-specific neurotoxins such as alpha-latrotoxin or Pteris umbrosa; toxins produced by animals containing insect-specific neurotoxins such as scorpion toxin, spider toxin, bee toxin, etc.; toxins produced by filamentous fungi such as Streptomycetes toxin; plant lectins such as pea lectin, barley lectin, snowdrop lectin; agglutinin; protease inhibitors such as trypsin inhibitor, serine protease inhibitor, patatin, cystatin, papain inhibitor; ribosome-inactivating proteins (RIP) such as ricin, corn-RIP, abrin, luffin, saporin, bryodin; steroid-metabolizing enzymes such as 3-hydroxy steroid oxidase, ecdysteroid-UDP-glucosyltransferase, cholesterol oxidase; ecdyson inhibitor; HMG-CoA-reductase; ion channel inhibitors such as sodium channel inhibitor, calcium channel inhibitor; juvenile hormone esterase; diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase; and glucanase.
[0173] In addition, plants imparted with pest resistance by introducing one or more insecticidal protein genes are already known, and some plants are commercially available. Examples of cotton with pest resistance include "Bollgard™ cotton", "BXN™ Plus Bollgard™ Cotton", "BXN™ Plus Bollgard™ Cotton", "JK 1", "Roundup Ready™ Bollgard™ Cotton", and "Ingard™", which express the insecticidal protein Cry1Ac derived from Bacillus thuringiensis (Bt); "Herculex™ I" and "Herculex™ CB", which express the modified insecticidal protein Cry1F (Cry1Fa2) derived from Bt; "VIPCOT™ Cotton", which expresses the insecticidal protein Vip3A derived from Bt; "Bollgard II™ cotton", "Roundup Ready™ Bollgard II™ Cotton", "Roundup Ready™ Flex™ Bollgard II™ Cotton", and "Fivermax™ Liberty Link™ Bollgard II™", which express the insecticidal proteins Cry1Ac and Cry2Ab derived from Bt; "Bollgard III®" and "Bollgard® III x Roundup Ready™ Flex™", which express the insecticidal proteins Cry1Ac, Cry2Ab, and Vip3A derived from Bt; "VIPCOT™ Roundup Ready Flex™ Cotton", which expresses the insecticidal proteins Vip3A and Cry1Ab derived from Bt; "VIPCOT® Cotton", which expresses the insecticidal proteins Vip3A and Cry1Ac derived from Bt; "WideStrike™ Cotton", "WideStrike™ Roundup Ready™ Cotton", and "Widestrike™ Roundup Ready Flex™ Cotton", which express the insecticidal proteins Cry1Ac and Cry1F derived from Bt; "TwinLink™ Cotton" and "Glytol™ x Twinlink™", which express the insecticidal proteins Cry1Ab and Cry2Ae derived from Bt;"Widestrike® 3" and "Widestrike™ x Roundup Ready Flex™ x VIPCOT™ Cotton" that express insecticidal proteins Cry1Ac, Cry1F, and Vip3A derived from Bt bacteria; "Glytol™ x Twinlink™ x VIPCOT™ Cotton" that express insecticidal proteins Cry1Ab, Cry2Ae, and Vip3A derived from Bt bacteria, and these are commercially available.; Examples of corn with pest resistance include "YieldGard® Rootworm RW", "YieldGard™ RW + RR", "YieldGard™ VT™ Rootworm™ RR2", and "MaxGard™", which express the insecticidal protein Cry3Bb1 derived from Bacillus thuringiensis (Bt); "YieldGard® VT Triple" and "YieldGard™ Plus with RR", which express the insecticidal proteins Cry3Bb1 and Cry1Ab derived from Bt; "Bt Xtra™ Maize", which expresses the insecticidal protein Cry1Ac derived from Bt; "YieldGard Plus®", which expresses the insecticidal proteins Cry1Ab and Cry3Bb1 derived from Bt; "Bt10", "Liberty Link™ Yieldgard™ Maize", "Agrisure™ GT / CB / LL", and "YieldGard™ CB + RR", which express the insecticidal protein Cry1Ab derived from Bt; the insecticidal protein Cry1A. derived from Bt."YieldGard® VT Pro®" and "Genuity® VT Double Pro®" that express 105 and Cry2Ab2; "Agrisure® RW" and "Agrisure® GT / RW" that express the insecticidal protein mCry3A derived from Bt bacteria; "Starlink® Maize" that expresses the insecticidal protein Cry9C derived from Bt bacteria; "YieldGard®", "MaizeGard®", "NaturGard KnockOut®", "Maximizer®", "Roundup Ready® YieldGard® maize", "Agrisure® CB / LL" and "Mavera® YieldGard® Maize" that express the insecticidal protein Cry1Ab derived from Bt bacteria; "Agrisure® 3122" that expresses the insecticidal proteins Cry1Ab, Cry1F, modified Cry3A, Cyr34Ab1 and Cyr35Ab1 derived from Bt bacteria; "Agrisure® Viptera" that expresses the insecticidal protein Vip3Aa20 derived from Bt bacteria; "Agrisure® Viptera® 2100" and "Agrisure® Viptera® 3110" that express the insecticidal proteins Vip3Aa20 and Cry1Ab derived from Bt bacteria; "Agrisure® Viptera® 3100", "Agrisure® Viptera® 3111)" and "Agrisure® Viptera® 4" that express the insecticidal proteins Vip3Aa20, Cry1Ab and modified Cry3A derived from Bt bacteria; "Agrisure® Viptera® 3220" that expresses the insecticidal proteins Vip3Aa20, Cry1Ab and modified Cry1F derived from Bt bacteria; "Agrisure® Duracade®" that expresses the insecticidal protein eCry3.1Ab (a chimeric protein of Cry3A-Cry1Ab) derived from Bt bacteria; the insecticidal protein eCry3.1Ab (chimeric protein of Cry3A-Cry1Ab), modified Cry3A, Cry1Ab and modified Cry1F-expressing "Agrisure® Duracade™ 5122"; Bt insecticidal protein eCry3.1Ab (chimeric protein of Cry3A-Cry1Ab), modified Cry3A, modified Cry1Ab and Vip3A variant-expressing "Agrisure® Duracade™ 5222"; Bt insecticidal proteins Cyr34Ab1 and Cyr35Ab1-expressing "Herculex™ RW"; Bt insecticidal proteins Cyr34Ab1, Cyr35Ab1 and Cry1F-expressing "Herculex XTRA™"; Bt insecticidal proteins Cry1A.105, Cry2Ab2 and Cry3Bb1-expressing "Genuity® VT Triple Pro™"; Bt insecticidal proteins Cry1F, Cry2Ab, Cyr34Ab1, Cyr35Ab1, Cry3Bb1 and Cry1A.105-expressing "Genuity® SmartStax™"; Bt insecticidal proteins modified Cry1F, Cry2Ab and Cry1A.105-expressing "Power Core™"; Bt insecticidal proteins modified Cry1F, Cyr34Ab1 and Cyr35Ab1-expressing "Herculex XTRA™ RR"; Bt insecticidal proteins modified Cry1F, Cyr34Ab1, Cyr35Ab1, Cry1Ab and modified Cry3A-expressing "Optimum® Intrasect Xtreme"; Bt insecticidal proteins modified Cry1F, Cyr34Ab1, Cyr35Ab1 and Cry1Ab-expressing "Optimum® Intrasect XTRA"; Bt insecticidal proteins modified Cry1F and modified Cyr3A-expressing "Optimum® TRIsect" are mentioned, and these are commercially available. Examples of other plants imparted with pest resistance include the potato varieties "Atlantic NewLeaf™ potato", "NewLeaf™ Russet Burbank potato", "Lugovskoi plus", "Elizaveta plus", "Hi-Lite NewLeaf™ Y potato, Superior NewLeaf™ potato" and "Shepody NewLeaf™ Y potato", which express the insecticidal protein Cry3A derived from Bacillus thuringiensis (Bt); the rice varieties "hanyou 63" and "Huahui-1", which express the insecticidal proteins Cry1Ab and Cry1Ac derived from Bt; the soybean variety "Intacta™ Roundup Ready™ 2 Pro", which expresses the insecticidal protein Cry1Ac derived from Bt; and the eggplant varieties "BARI Bt Begun-1, -2, -3 and -4", which express the insecticidal protein Cry1Ac derived from Bt. These are commercially available. Also, corn varieties with resistance to corn rootworms, such as "YieldGard corn rootworm", "YieldGard VT", "Herculex RW", "Herculex Rootworm", and "Agrisure CRW"; corn varieties with resistance to corn borers, such as "YieldGard corn borer", "YieldGard plus", "YieldGard VT Pro", "Agrisure CB / LL", "Agrisure 3000GT", "Hercules I", "Hercules II", "KnockOut", "NatureGard", and "StarLink"; corn varieties with resistance to western bean cutworms, corn borers, black cutworms, and fall armyworms, such as "Herculex I", "Herculex Xtra", "NewLeaf", "NewLeaf Y", and "NewLeaf Plus"; corn varieties with resistance to corn borers and corn rootworms, such as "YieldGard Plus"; cotton varieties with resistance to pink bollworms, such as "Bollgard I" and "Bollgard II"; cotton varieties with resistance to pink bollworms, cotton bollworms, fall armyworms, beet armyworms, cabbage loopers, soybean loopers, and pink bollworms, such as "Bollgard II", "WideStrike™", and "VipCot"; potato varieties with resistance to Colorado potato beetles, such as "NewLeaf", "NewLeaf Y", and "NewLeaf Plus"; eggplant varieties with resistance to eggplant fruit and shoot borers and cotton bollworms, such as "Bt brinjal", "Dumaguete Long Purple", and "Mara" (see, for example, US5128130) are known. Additional plants with pest resistance are generally known. For example, there are stem borer-resistant rice (see, for example, Molecular Breeding, Vol. 18 (2006), No. 1), Lepidoptera-resistant lettuce (see, for example, US5349124), and rice with resistance to Lepidoptera (such as the yellow stem borer, the rice leaf folder, the rice armyworm, the rice caseworm, and the rice ear caterpillar) (see, for example, WO2001 / 021821). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above publications.
[0174] As a plant imparted with pest resistance by RNA interference technology, corn with resistance to coleopteran pests (corn rootworms) is commercially available under the trade names "SmartStax (registered trademark) Pro" or "Vorceed Enlist (registered trademark)".
[0175] As plants imparted with pest resistance by conventional breeding techniques or genomic breeding techniques, for example, soybeans with resistance to the soybean aphid (Aphis glycines) having the "Rag1 (Resistance to Aphis glycines 1)" gene or the "Rag2 (Resistance to Aphis glycines 2)" gene, which are aphid resistance genes (see J. Econ. Entomol., 2015, 108, 326); soybeans with resistance to the soybean cyst nematode (Heterodera glycines) (see Phytopathology, 2016, 106, 1444); cotton with resistance to the root-knot nematode (Meloidogyne incognita) (see J. Nematol., 2009, 41, 140); rice "Kanto BPH1" with resistance to the brown planthopper; and soybeans "Fukuminori" with resistance to the fall armyworm can be mentioned.
[0176] These plants imparting pest resistance are imparted with resistance to any harmful insects (especially Lepidoptera insects, Coleoptera insects, Diptera insects, beetle insects), harmful spiders and harmful nematodes. The plants imparting pest resistance are preferably selected from wheat (e.g., common wheat, barley, rye, oats), corn, canola, sorghum, soybean, rice, rapeseed, sugar beet, sugarcane, grape, lentil, sunflower, alfalfa, pome fruits, stone fruits, peanuts, coffee, tea, strawberries, turfgrass, vegetables (e.g., tomato, potato, cucurbitaceae plants and lettuce), more preferably selected from soybean, corn, tomatoes, rice and wheat (e.g., common wheat, barley, rye and oats), and most preferably selected from soybean, rice, corn and wheat (e.g., common wheat, barley, rye and oats).
[0177] Examples of plants imparting disease resistance are given below.
[0178] Plants imparted with disease resistance by genetic recombination technology are, for example, plants that express so-called "pathogenesis-related proteins" (PRPs, see, for example, EP0392225) or so-called "antifungal proteins" (AFPs, see, for example, US6864068). Various antifungal proteins having activity against plant pathogenic fungi have been isolated from specific plant species and have become common knowledge. Examples of such anti-pathogenic substances and plants capable of synthesizing such anti-pathogenic substances are known, for example, from EP0392225, WO1993 / 05153, WO1995 / 33818, and EP0353191. Plants resistant to fungicidal pathogens, viral pathogens, and bacterial pathogens are produced by introducing disease resistance genes. A number of resistance genes have been identified, isolated, and used to improve disease resistance. Examples of such resistance genes include the N gene introduced into a tobacco line sensitive to tobacco mosaic virus (TMV) to produce a TMV-resistant tobacco plant (see, for example, US 5571706), the Prf gene introduced into plants to obtain enhanced pathogen resistance (see, for example, WO1998 / 02545), and the Rps2 gene derived from Arabidopsis thaliana used to create resistance to bacterial pathogens such as Pseudomonas syringae (see, for example, WO1995 / 028423). Plants showing a systemic acquired resistance response were obtained by introducing a nucleic acid molecule encoding the TIR domain of the N gene (see, for example, US 6630618).Additional examples of well-known resistance genes include the Xa21 gene introduced into numerous rice varieties (see, for example, US5952485, US5977434, WO1999 / 009151, WO1996 / 022375), the Rcg1 gene for resistance to Colletotrichum (see, for example, US2006 / 225152), the prp1 gene (see, for example, US5859332, WO2008 / 017706), the ppv-cp gene that confers resistance to plum pox virus (see, for example, US PP15,154Ps), the P1 gene (see, for example, US5968828), genes such as Blb1, Blb2, Blb3, RB2, and Rpi-vnt1 for introducing resistance to Phytophthora infestans in potatoes (see, for example, US7148397), the LRPKml gene (see, for example, WO1999 / 064600), the P1 gene for resistance to potato virus Y (see, for example, US5968828), the HA5-1 gene (see, for example, US5877403 and US6046384), the PIP gene for introducing broad resistance to viruses such as potato virus X (PVX), potato virus Y (PVY), and potato leafroll virus (PLRV) (see, for example, EP0707069), and genes such as the NI16 gene, ScaM4 gene, and ScaM5 gene of Arabidopsis for obtaining fungal resistance (see, for example, US6706952 and EP1018553). In addition, beans resistant to Bean golden mosaic virus (hereinafter referred to as BGMV) are plants in which resistance is conferred by RNA interference technology. By introducing a double-stranded RNA gene (sense and antisense ac1 gene) of the replication protein, the synthesis of the BGMV replication protein is inhibited, thereby showing resistance to BGMV. Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above publications. Examples of anti-pathogenic substances that can be expressed by such plants include, for example, ion channel blockers (sodium channel blockers, calcium channel blockers, etc.); viral KP1, KP4, and KP6 toxins; stilbene synthase; bibenzyl synthase; chitinase; glucanase; so-called "pathogenesis-related proteins" (PRPs; see, for example, EP0392225); anti-pathogenic substances produced by microorganisms (e.g., peptide antibiotics, heterocyclic antibiotics (see, for example, WO1995 / 033818), and protein factors or polypeptide factors involved in plant pathogen defense (so-called "plant disease resistance genes" described in WO2003 / 000906)). Anti-pathogenic substances produced by plants can protect plants from various pathogenic microorganisms such as fungi, viruses, and bacteria. Useful plants that have been attracting increasing interest in connection with the present invention are cereals (e.g., wheat, barley, rye, and oats), soybeans, corn, rice, rapeseed, pome fruits, stone fruits, peanuts, coffee, tea, strawberries, turf; vine plants and vegetables (e.g., tomatoes, potatoes), cucurbitaceae plants, papayas, melons, lentils, and lettuce, more preferably selected from soybeans, tomatoes, rice, and cereals (e.g., wheat, barley, rye, and oats), and most preferably selected from soybeans, rice, and cereals (e.g., wheat, barley, rye, and oats). Examples of plants having resistance to fungal pathogens include, for example, soybeans having resistance to soybean rust (Phakopsora pachyrhizi and Phakopsora meibomiae) (see, for example, WO2008 / 017706); solanaceous plants such as cotton, tomatoes, and potatoes having resistance to Phytophthora infestans (see, for example, US5859332, US7148397, EP1334979); corn having resistance to Colletotrichum such as Colletotrichum graminicola (see, for example, US2006 / 225152); apples having resistance to Venturia inaequalis (see, for example, WO1999 / 064600); plants having resistance to Fusarium species (e.g., fusarium graminearum, fusarium sporotrichioides, fusarium lateritium, fusarium pseudograminearum, fusarium sambucinum, fusarium culmorum, fusarium poae, fusarium acuminatum, fusarium equiseti) such as rice, wheat, barley, rye, corn, oats, potatoes, melons, soybeans, and sorghum (see, for example, US6646184, EP1477557); and plants such as corn, soybeans, wheat (especially wheat, barley, rye, and oats), rice, tobacco, sorghum, sugarcane, and potatoes having broad-spectrum fungicide resistance (see, for example, US5859332, US5689046, US6706952, EP1018553, and US6020129). Examples of plants having resistance to bacterial pathogens include, for example, rice having resistance to Xylella fastidiosa (see, for example, US6232528); plants such as rice, cotton, soybean, potato, sorghum, corn, wheat, barley, sugarcane, tomato and pepper having resistance to bacterial stem rot pathogens (see, for example, WO2006 / 42145, US5952485, US5977434, WO1999 / 09151, WO1996 / 22375); tomato having resistance to Pseudomonas syringae (see, for example, Can. J. Plant Path., 1983, 5:251-255). Examples of plants resistant to viral pathogens include, for example, stone fruits (e.g., plum, almond, apricot, cherry, peach, nectarine) resistant to plum pox virus (see, e.g., US PP15154Ps, EP0626449); potatoes resistant to potato virus Y (see, e.g., US5968828); plants such as potatoes, tomatoes, cucumbers, and legumes resistant to tomato spotted wilt virus (see, e.g., EP0626449, US5973135); corn resistant to maize streak virus (see, e.g., US6040496); papaya resistant to papaya ring spot virus (see, e.g., S5877403, US6046384); cucurbitaceae plants (e.g., cucumber, melon, watermelon, and pumpkin) and solanaceae plants (e.g., potato, tobacco, tomato, eggplant, pepper, paprika, pepper, and chili pepper) resistant to cucumber mosaic virus (see, e.g., US6849780); cucurbitaceae plants (e.g., cucumber, melon, watermelon, and pumpkin) resistant to watermelon mosaic virus 2 and zucchini yellow mosaic virus (see, e.g., US6015942); potatoes resistant to potato leafroll virus (see, e.g., US5576202); potatoes with broad resistance to viruses such as potato virus X, potato virus Y, and potato leafroll virus (see, e.g., EP0707069);Examples include common beans resistant to Bean golden mosaic virus (see, for example, Mol Plant Microbe Interact. 2007 Jun;20(6):717-26.).; There are plants that are resistant to antibiotics (e.g., kanamycin, neomycin, and ampicillin). The naturally occurring bacterial nptII gene expresses an enzyme that blocks the action of the antibiotics kanamycin and neomycin. The ampR (also known as blaTEM1), an ampicillin resistance gene, is derived from the bacterium Salmonella paratyphi and is used as a marker gene in the transformation of microorganisms and plants. ampR is involved in the synthesis of beta-lactamase, an enzyme that neutralizes penicillin group antibiotics including ampicillin. Plants having resistance to antibiotics include, for example, potato, tomato, flax, canola, rapeseed, Brassica seeds, and corn (e.g., see Plant Cell Reports, 20, 2001, 610-615; Trends in Plant Science, 11, 2006, 317-319; Plant Molecular Biology, 37, 1998, 287-296; Mol Gen Genet., 257, 1998, 606-13; Plant Cell Reports, 6, 1987, 333-336; Federal Register (USA), Vol. 60, No. 113, 1995, p. 31139; Federal Register (USA), Vol. 67, No. 226, 2002, 70392; Federal Register (USA), Vol. 63, No. 88, 1998, 25194; Federal Register (USA), Vol. 60, No. 141, 1995, 37870; Canadian Food Inspection Agency, FD / OFB-095-264-A, October 1999, FD / OFB-099-127-A, October 1999). Preferably, the above plants are selected from soybean, tomatoes, and cereals (e.g., wheat, barley, rye, and oats), and most preferably from soybean and cereals (e.g., wheat, barley, rye, and oats). Examples of plants that have been rendered resistant to plant viral diseases that are available include, for example, papayas “Rainbow,” “SunUp,” and “Huanong No. 1” that have been rendered resistant to Papaya ringspot virus; potatoes “Innate® Hibernate,” “Innate® Glaciate,” and “Innate® Acclimate” that exhibit resistance to phytophthora infestans; and potato “Newleaf™” that exhibits resistance to potato virus Y and / or potato leafroll virus (PLRV).
[0179] As plants with disease resistance conferred by conventional variety improvement techniques or genomic breeding techniques, rice with resistance to blast; rice with resistance to sheath blight; wheat with resistance to leaf rust; wheat with resistance to stripe rust; wheat with resistance to stem rust; wheat with resistance to powdery mildew; wheat with resistance to leaf blotch; wheat with resistance to glume blotch; wheat with resistance to tan spot; barley with resistance to powdery mildew; barley with resistance to dwarf leaf rust; barley with resistance to net blotch; barley with resistance to scald; barley with resistance to Ramularia disease; corn with resistance to Anthracnose; corn with resistance to gray leaf spot; corn with resistance to Goss's wilt; corn with resistance to Fusarium stalk rot; soybean with resistance to Asian soybean rust; soybean with resistance to phytophthora stem and root rot; soybean with resistance to sudden death syndrome; pepper with resistance to Phytophthora rot; lettuce with resistance to powdery mildew; tomato with resistance to bacterial wilt; tomato with resistance to Gemini virus;Lettuce imparted with resistance to downy mildew; Brassicaceae plants such as rapeseed, cabbage, Brussels sprouts, cauliflower, kale (Borekale), broccoli, etc. imparted with resistance to clubroot; Brassicaceae plants such as rapeseed, cabbage, Brussels sprouts, cauliflower, kale (Borekale), broccoli, etc. imparted with resistance to black leg; Melons imparted with resistance to Fusarium wilt of melons caused by Fusarium oxysporum f.sp. melonis (see, for example, WO2009 / 000736).;
[0180] As plants imparted with disease resistance by genome editing technology, by using TALEN and CRISPR-Cas9 to delete the powdery mildew resistance gene (MILDEW RESISTACE LOCUS O, hereinafter abbreviated as MLO), bread wheat showing resistance to powdery mildew (see, for example, Nat. Biotech., 32, 947-951, 2014); by using CRISPR-Cas9 to delete the SlMLO1 gene, which is one of the MLOs, slmlo1 tomato showing resistance to powdery mildew (see, for example, Scientific Reports 7, Article number: 482, 2017); by using TALEN to edit the OsSWEET14 gene in rice, rice showing resistance to Xanthomonas oryzae pv. Oryzae that causes bacterial leaf blight (see Nat. Biotechnol. 30, 390-392, 2012); by using CRISPR-Cas9 to modify the OsERF922 gene in rice, rice showing resistance to Magnaporthe oryzae that causes blast (see PLoS ONE 11:e0154027. doi: 10.1371 / journal.pone.0154027, 2016); by using CRISPR-Cas9 to disrupt the recessive eIF4E (eukaryotic translation initiation factor 4E) gene, cucumber showing resistance to cucumber vein yellow ingvirus (CVYV), zucchini yellow mosaic virus (ZYMV), papaya ringspot virus-typeW (PRSV-W) (Mol. Plant Pathol.(see Mol Plant Pathol 17(1)127 - 139, 2016); soybean plants that show resistance to phytophthora stem and root rot caused by Phytophthora sojae by disrupting the RXLR effector gene (Avr4 / 6) using CRISPR - Cas9 (see Mol Plant Pathol 17(7)1140 - 1153, 2016).
[0181] Examples of plants with disease resistance conferred by new breeding techniques include apple plants resistant to apple scab caused by Venturia inaequalis by introducing the Rvi6 (formerly called HcrVf2) gene using cisgenesis (see, for example, Plant Biotech.J., 12, 2 - 9, 2014); examples of imparting the properties of a GM rootstock, a variety improvement technique using grafting, to a scion include sweet cherries that have transferred the property of resistance to Prunus necrotic ringspot virus from a transgenic rootstock to a non - transgenic scion (see Plant Biotech. J., 12, 1319 - 1328, 2014).
[0182] Examples of plants with modified product quality are given below. Modifying the quality of the product means increasing or decreasing the synthesis of the modified component or the amount of component synthesis compared to the corresponding wild - type plant. Examples of plants with modified product quality include modified plants with increased or decreased contents of vitamins, amino acids, proteins, starch, various oils, and modified plants with decreased nicotine content.
[0183] Plants whose product quality has been modified by genetic recombination technology include, for example, alfalfa in which the lignin content has been reduced by RNA interference by introducing a gene that produces double-stranded RNA of the S-adenosyl-L-methionine:trans-caffeoyl-CoA 3-O-methyltransferase (ccomt) gene derived from alfalfa involved in lignin production; canola "Laurical (trademark) Canola" in which the content of triacylglycerol containing lauric acid has increased by introducing the 12:0 ACP thioesterase gene derived from Umbellularia californica involved in fatty acid synthesis; soybeans "Plenish (trademark)" and "Treus (trademark)" in which the expression of the ω-6 desaturase partial gene (gm-fad2-1) derived from soybeans, which is a fatty acid desaturase, has been suppressed and the oleic acid content has increased; soybeans "Vistive Gold (trademark)" in which the saturated fatty acid content has decreased by introducing a gene that produces double-stranded RNA of the acyl-acyl carrier protein thioesterase gene (fatb1-A) derived from soybeans and a gene that produces double-stranded RNA of the δ-12 desaturase gene (fad2-1A) derived from soybeans; genetically modified soybeans in which stearidonic acid, one of the ω3 fatty acids, is produced by introducing the δ-6 desaturase gene (Pj.D6D) derived from sugar beet and the δ-12 desaturase gene (Nc.Fad3) derived from Neurospora crassa; corn "Enogen (registered trademark)" in which the production of bioethanol has been enhanced by introducing the thermostable α-amylase gene (amy797E) of Thermococcales sp. related to starch degradation; corn "Mavera (trademark) Maize" and "Mavera (trademark) YieldGard (trademark) Maize" in which lysine production has increased by introducing the dihydrodipicolinate synthase gene (cordapA) derived from Corynebacterium glutamicum related to the production of the amino acid lysine;By introducing the antisense gene gbss of the starch synthase enzyme (granule-bound starch synthase enzyme, GBSS) derived from potato, the amylose content in starch granules is reduced and the amylopectin content is increased in potatoes such as "Amflora (trademark)", "Starch Potato"; By introducing the genes pPhL and pR1 that generate double-stranded RNA of the transcription factor genes PhL and R1 that promote starch degradation from potato, starch degradation is suppressed, and by introducing the gene asn1 that generates double-stranded RNA of the gene Asn1 involved in asparagine production, asparagine synthesis is suppressed (the aim is to suppress the accumulation of asparagine and reducing sugars involved in the production of acrylamide, a carcinogenic substance by heating) and potatoes such as "Innate (registered trademark) Cultivate", "Innate (registered trademark) Generate", "Innate (registered trademark) Accelerate", "Innate (registered trademark) Invigorate", "Innate (registered trademark) Glaciate", "Innate (registered trademark) Acclimate" and "Innate (registered trademark) Hibernate" in which black spot formation is suppressed by introducing the gene ppo5 that generates double-stranded RNA of the polyphenol oxidase gene Ppo5 derived from potato; Tobacco in which the nicotine content is reduced by introducing the antisense gene (NtQPT1) of the quinolinate phosphoribosyltransferase gene QpTase derived from tobacco (Nicotiana tabacum); Golden rice, which is rice capable of harvesting vitamin A-containing rice by producing β-carotene in the endosperm tissue by introducing the phytoene synthase gene (psy) derived from daffodil (Narcissus pseudonarcissus) and the carotene desaturase gene (crt1) derived from the soil bacterium (Erwinia uredovora) that synthesizes carotenoids and expressing them specifically in the endosperm. In addition, for example, potatoes and corns with modified amylopectin contents (see, for example, US6784338, US2007 / 0261136, WO1997 / 04471);Plants of canola, corn, cotton, grape, cattail, catalpa, rice, soybean, rapeseed, wheat, sunflower, bitter gourd, safflower, and Vernonia genus (e.g., see US7294759, US7157621, US5850026, US6441278, US5723761, US6380462, US6365802, US6974898, WO2001 / 079499, US2006 / 0075515, and US7294759) with modified oil content; sunflower with increased fatty acid content (e.g., see US6084164); soybean with reduced allergen content (e.g., see US6864362); tobacco with reduced nicotine content (e.g., see US2006 / 0185684, WO2005 / 000352, and WO2007 / 064636); canola and soybean with increased lysine content (e.g., see Bio / Technology 13, 1995, 577 - 582); corn and soybean with modified composition of methionine, leucine, isoleucine, and / or valine (e.g., see US6946589, US6905877); soybean with increased sulfur amino acid content (e.g., see EP0929685, WO1997 / 041239); corn with increased methionine content by leaf - specifically expressing 3'-Phosphoadenosine - 5'-phosphosulfate reductase derived from Escherichia coli (see PNAS, 2017, 114(43), 11386); tomato with increased content of free amino acids (e.g., asparagine, aspartic acid, serine, threonine, alanine, histidine, and glutamic acid) (e.g., see US6727411); corn with increased amino acid content (e.g., see WO05 / 077117); potato, corn, and rice with modified starch content (e.g., see WO1997 / 044471 and US7317146); tomato, corn, grape, alfalfa, apple, legumes, and pea with modified flavonoid content (e.g., see WO00 / 04175);Maize, rice, sorghum, cotton, and soybean with modified phenolic compound content (see, for example, US2008 / 0235829); tomato and canola with increased vitamin A content (see, for example, US6797498, US7348167); tomato, canola, soybean, wheat, sunflower, rice, maize, barley, and rye with increased vitamin E content (see, for example, US7348167, WO2004 / 058934); alfalfa, apple, legume, maize, grape, tomato, and pea with modified flavonoid content (see, for example, WO00 / 04175). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above publications. Preferably, the plant is selected from soybean, canola, tomatoes, rice, and cereals (e.g., wheat, barley, rye, and oats), and most preferably from soybean, canola, rice, wheat, and barley.;
[0184] As plants with modified product quality by conventional breeding techniques or genomic breeding techniques, rapeseed "Nexera® Canola" that produces unsaturated omega-9 fatty acids; soybean "Yumeminori" with reduced allergen content; rice for the purpose of improving good taste, for example, rice "Yumepirika" with reduced amylose content, etc. are commercially available. In addition, citrus fruits with modified fruit characteristics (e.g., fruit weight, aroma intensity, juiciness, and sugar content) by genomic selection are known (see Scientific Reports 7, 4721 in 2017).
[0185] Examples of plants with modified nutrient utilization include plants with enhanced nitrogen or phosphorus assimilation or metabolism. Plants with enhanced nitrogen assimilation ability and nitrogen utilization ability by genetic recombination technology include, for example, canola, corn, wheat, sunflower, rice, tobacco, soybean, cotton, alfalfa, tomato, wheat, potato, sugar beet, sugarcane and rapeseed (see, for example, WO1995 / 009911, WO1997 / 030163, US6084153, US5955651 and US6864405). Examples of plants with improved phosphorus uptake by genetic recombination technology include, for example, alfalfa, barley, canola, corn, cotton, tomato, rapeseed, rice, soybean, sugar beet, sugarcane, sunflower, wheat and potato (see, for example, US7417181, US2005 / 0137386). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above publications. Preferably, the plant is selected from soybean, tomato and cereals (e.g., wheat, barley, rye and oats), and most preferably from soybean, rice, corn and wheat.
[0186] Plants with modified fertility traits by genetic recombination technology include plants with male sterility and fertility restoration traits conferred on them. For example, maize and chicory with male sterility traits conferred by expressing the ribonuclease gene (barnase) derived from Bacillus amyloliquefaciens in the tapetum cells of anthers; maize with male sterility traits conferred by introducing the DNA adenine methylase gene (dam) derived from Escherichia coli; maize with fertility traits controlled by introducing the alpha - amylase gene (zm - aa1) derived from maize that confers male sterility traits and the ms45 protein gene (ms45) derived from maize that confers fertility restoration traits; canola with fertility restoration function conferred by expressing the ribonuclease inhibitor protein gene (barstar) derived from Bacillus in the tapetum cells of anthers; canola with fertility traits controlled by expressing the ribonuclease gene (barnase) derived from Bacillus that confers male sterility traits and the ribonuclease inhibitor protein gene (barstar) derived from Bacillus that confers fertility restoration traits. Other plants with fertility traits conferred by genetic recombination technology include tomat...
Claims
1. Formula (I) 【Chemistry 1】 [During the ceremony, Ring A6 represents a 6-membered non-aromatic nitrogen-containing heterocycle or a 6-membered aromatic nitrogen-containing heterocycle (provided that in ring A6, the atom bonded to D is a carbon atom or a nitrogen atom, and at least one of the atoms constituting ring A6 adjacent to the atom bonded to D is a nitrogen atom); D represents CR1R2, C=O, C=S, or C=N-OR7; n represents 0, 1, 2, or 3; m represents 0, 1, 2, 3, or 4; q represents 0, 1, 2, 3, 4, or 5; R1 and R2 are the same or different and represent a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group A, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group B}, a phenyl group, a 5-6 membered aromatic heterocyclic group {the phenyl group and the 5-6 membered aromatic heterocyclic group may be substituted with one or more substituents selected from group C}, OR8, SR9, S(O)R10, S(O)2R11, NRR13, C(O)R14, C(R15)=NOR16, a cyano group, a nitro group, a halogen atom, or a hydrogen atom; R1 and R2 may, together with the carbon atom to which they are bonded, form a C3-C8 alicyclic hydrocarbon or a 3- to 8-membered non-aromatic heterocycle {the C3-C8 alicyclic hydrocarbon and the 3- to 8-membered non-aromatic heterocycle may be substituted with one or more substituents selected from group B}; R3 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group A, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group may be substituted by one or more substituents selected from group B}, a phenyl group, a 5-6 membered aromatic heterocyclic group {the phenyl group and the 5-6 membered aromatic heterocyclic group may be substituted by one or more substituents selected from group C}, OR17, SR18, S(O)R19, S(O)2R20, NRR22, C(O)R23, C(R24)=NOR25, a cyano group, a nitro group, or a halogen atom; R4 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group A, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group B}, a phenyl group optionally substituted with one or more substituents selected from group C, OR26, NR27R28, C(O)R29, C(R30)=NOR31, a cyano group, a nitro group, or a halogen atom; R6 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group A, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group B}, a phenyl group, a 5-6 membered aromatic heterocyclic group {the phenyl group and the 5-6 membered aromatic heterocyclic group may be substituted with one or more substituents selected from group C}, OR32, SR33, S(O)R34, S(O)2R35, NR36R37, C(O)R38, C(R39)=NOR40, a cyano group, a nitro group, or a halogen atom; R8, R12, R13, R17, R21, R22, R26, R27, R28, R32, R36, and R37 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted by one or more substituents selected from group A, a C1-C6 alkylsulfonyl group, a (C1-C6 alkyl)carbonyl group, a (C1-C6 alkoxy)carbonyl group, a (C1-C6 alkylamino)carbonyl group, a (C2-C8 dialkylamino)carbonyl group {the C1-C6 alkylsulfonyl group, the (C1-C6 alkyl)carbonyl group, the (C1-C6 alkoxy) a carbonyl group, the (C1-C6 alkylamino)carbonyl group, and the (C2-C8 dialkylamino)carbonyl group are optionally substituted with one or more halogen atoms}, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group, and the 3-8 membered non-aromatic heterocyclic group are optionally substituted with one or more substituents selected from group B}, a phenyl group, a 5-6 membered aromatic heterocyclic group {the phenyl group and the 5-6 membered aromatic heterocyclic group are optionally substituted with one or more substituents selected from group C}, or a hydrogen atom, R7, R9, R16, R18, R25, R31, R33, and R40 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group A, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group B}, a phenyl group, a 5-6 membered aromatic heterocyclic group {the phenyl group and the 5-6 membered aromatic heterocyclic group may be substituted with one or more substituents selected from group C}, or a hydrogen atom; R10, R11, R19, R20, R34, and R35 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group A, a C1-C6 alkylamino group, a C2-C8 dialkylamino group {the C1-C6 alkylamino group and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group B}, a phenyl group, or a 5-6 membered aromatic heterocyclic group {the phenyl group and the 5-6 membered aromatic heterocyclic group may be substituted with one or more substituents selected from group C}; R14, R23, R29, and R38 are the same or different and represent a C1-C6 chain hydrocarbon group, a C1-C6 alkoxy group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group {the C1-C6 chain hydrocarbon group, the C1-C6 alkoxy group, the C1-C6 alkylamino group, and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, or a hydroxy group; R15, R24, R30, and R39 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group A, or a hydrogen atom; When q is 2, 3, 4, or 5, two adjacent R6 and R6, together with the carbon atom to which they are bonded, may form a C5-C6 alicyclic hydrocarbon, a 5-6 membered non-aromatic heterocycle (the C5-C6 alicyclic hydrocarbon and the 5-6 membered non-aromatic heterocycle may be substituted with one or more substituents selected from group B), a benzene ring, or a 5-6 membered aromatic heterocycle (the benzene ring and the 5-6 membered aromatic heterocycle may be substituted with one or more substituents selected from group C). Group A: the group consisting of a C1-C6 alkoxy group, a C1-C6 alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group {the C1-C6 alkoxy group, the C1-C6 alkylsulfanyl group, the C1-C6 alkylsulfinyl group and the C1-C6 alkylsulfonyl group may be substituted with one or more halogen atoms}, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from Group B}, a phenyl group, a 5-6 membered aromatic heterocyclic group {the phenyl group and the 5-6 membered aromatic heterocyclic group may be substituted with one or more substituents selected from Group C}, a halogen atom, a cyano group, a nitro group, a hydroxy group, and a sulfanyl group. Group B: a group consisting of an oxo group, a thioxo group, a C1-C6 chain hydrocarbon group, a C1-C6 alkoxy group, a C1-C6 alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group {the C1-C6 chain hydrocarbon group, the C1-C6 alkoxy group, the C1-C6 alkylsulfanyl group, the C1-C6 alkylsulfinyl group and the C1-C6 alkylsulfonyl group are optionally substituted with one or more halogen atoms}, a hydroxy group, a sulfanyl group, a halogen atom, and a cyano group. Group C: a C1-C6 chain hydrocarbon group, a C1-C6 alkoxy group, a C1-C6 alkylsulfanyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group, a (C1-C6 alkyl)carbonyl group, a (C1-C6 alkoxy)carbonyl group, a (C1-C6 alkylamino)carbonyl group, a (C2-C8 dialkylamino)carbonyl group, a (C1-C6 alkyl)carbonylamino group, a (C1-C6 alkoxy)carbonylamino group {the C1-C6 chain hydrocarbon group, the C1-C6 alkoxy group, the C1-C6 alkylsulfanyl group, the C1-C6 alkylsulfinyl group, the C1-C6 alkylsulfonyl group, the C1-C6 alkylamino group, the C2-C8 dialkylamino group, the (C1-C6 alkyl)carbonyl group, the (C1-C6 alkoxy)carbonyl group, the (C1-C6 alkylamino)carbonyl group, the (C2-C8 dialkylamino)carbonyl group, the (C1-C6 alkyl)carbonylamino group and the (C1-C6 alkoxy)carbonylamino group are optionally substituted with one or more halogen atoms}, the group consisting of a C3-C8 alicyclic hydrocarbon group optionally substituted with one or more substituents selected from group B, an amino group, a nitro group, a cyano group, a hydroxy group, a sulfanyl group, and a halogen atom.] or an N-oxide thereof, or a salt thereof to a plant or a cultivation carrier for a plant.
2. The method for controlling plant diseases according to claim 1, wherein the cultivation carrier for plants is soil.
3. A composition comprising the compound represented by formula (I) according to claim 1 or an N-oxide thereof, or a salt thereof, and one or more components selected from the group consisting of group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i) and group (j): Group (a): A group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients; Group (b): bactericidal active ingredient; Group (c): plant growth regulating ingredients; Group (d): phytotoxicity-safening components; Group (e): synergists; Group (f): repellent components; Group (g): molluscicidal ingredients; Group (h): insect pheromones; Group (i): herbicidal active ingredients; Group (j): biological control materials.
4. A method for controlling plant diseases, comprising the step of applying an effective amount of the composition according to claim 3 to a plant or a cultivation carrier for a plant.
5. The method for controlling plant diseases according to claim 4, wherein the cultivation carrier for plants is soil.
6. A seed or vegetative reproductive organ carrying an effective amount of a compound of formula (I) or an N-oxide thereof or a salt thereof as defined in claim 1, or a composition as defined in claim 3.
Citation Information
Patent Citations
Method for the preparation of 3,4,6-trisubstituted 3-alkylthio-1,2,4-triazin-5-one derivatives
EP0144668A1