Transitional driving modes for impulse balancing when switching between global color and direct update modes for electrophoretic displays

Abstract

A method for driving a multi-pixel electrophoretic display designed to enable at least three colors, e.g., eight colors, at each pixel. The method uses a first drive scheme capable of producing transitions between all of the color states that can be displayed at each pixel, and a second drive scheme containing only transitions that end in white or black, which is very useful for drawing black lines on a white page, reading black text on a white page, or reading white text on a black page. Two intermediate transition modes are added to control the amount of impulse potential stored at each pixel during switching between drive modes.

Description

[Background technology]

[0001] (Related Applications) This application claims priority to U.S. Provisional Application No. 63 / 401,110, filed August 25, 2022. All patents and publications disclosed herein are incorporated by reference in their entirety.

[0002] (background) Electrophoretic displays (EPDs) change color by modifying the position of electrically charged colored particles relative to a light-transmitting viewing surface. Such electrophoretic displays are typically referred to as "electronic paper" or "e-paper" because the resulting display has high contrast and is sunlight-readable, much like ink on paper. Electrophoretic displays have enjoyed widespread adoption in electronic readers, such as the AMAZON KINDLE®, because they offer a book-like reading experience, use low power consumption, and allow users to carry a library of hundreds of books in a lightweight, handheld device.

[0003] For many years, electrophoretic displays included only two types of charged color particles: black and white (for clarity, "color," as used herein, includes black and white). White particles are often light-scattering and comprise, for example, titanium dioxide, while black particles are absorptive across the visible spectrum and may comprise absorbing metal oxides such as carbon black or copper chromite. In the simplest sense, a black-and-white electrophoretic display requires only a light-transmitting electrode at the viewing surface, a back electrode, and an electrophoretic medium containing oppositely charged white and black particles. When a voltage of one polarity is applied, the white particles migrate to the viewing surface, and when a voltage of the opposite polarity is applied, the black particles migrate to the viewing surface. If the back electrode contains controllable regions (pixels), either segmented electrodes or an active matrix of pixel electrodes controlled by transistors, a pattern can be made to appear electronically at the viewing surface. This pattern could be, for example, the text of a book.

[0004] More recently, a variety of color options have become commercially available for electrophoretic displays, including three-color displays (black, white, red, and black, white, yellow) and four-color displays (black, white, red, yellow). Similar to the operation of black-and-white electrophoretic displays, electrophoretic displays with three or four reflective particles operate similarly to simple black-and-white displays, as the desired color particles are driven relative to the viewing surface. While this driving scheme is much more complex than black-and-white only, ultimately, the optical function of the particles is the same.

[0005] Advanced Color Electronic Paper (ACeP®) also contains four particles, but the cyan, yellow, and magenta particles are subtractive rather than reflective, thereby allowing thousands of colors to be produced at each pixel. This color process is functionally equivalent to the printing method long used in offset and inkjet printers. A given color is produced by using the correct ratios of cyan, yellow, and magenta on a bright white paper background. In the case of ACeP, the relative positions of the cyan, yellow, magenta, and white particles with respect to the viewing surface will determine the color at each pixel. This type of electrophoretic display allows for thousands of colors at each pixel, but careful control of the position of each pigment (50 to 500 nanometers in size) within a working space approximately 10 to 20 microns thick is crucial. Obviously, variations in particle position will result in the wrong color being displayed at a given pixel. Therefore, precise voltage control is required for such systems. Further details of this system are available in the following U.S. patents: U.S. Patent Nos. 9,361,836, 9,921,451, 10,276,109, 10,353,266, 10,467,984, and 10,593,272, all of which are incorporated by reference in their entirety.

[0006] Colors produced with such color electrophoretic displays may be subject to various "accumulation of errors" phenomena. These errors may result from minute variations in drive voltage, residual voltages stored on the driven pixels, or temperature variations in the electrophoretic medium during successive transitions. As a result, the desired color state may vary from the displayed color state due to voltages stored on the pixel and / or disorders in the internal phase medium adjacent to that pixel. For example, a pixel that returns to a black state after 100 successive color transitions in one area of ​​the display may have an L* of 6 (L* has the usual CIE definition: L*=116(R / R0) 1 / 3 -16

[0007] (where R is the reflectance and R is the standard reflectance value), while another adjacent pixel that did not change during those 100 consecutive transitions starts out black and remains that way, having an L* of 4 after the same 100 transitions. A deviation of 2L* is obvious to the average observer and detracts from the overall experience of the display.

[0008] This accumulation of error phenomenon applies to color states as well as black and white states. Again, due to the mutual influence of electrophoretic particles, slight changes in the local voltage or electrophoretic medium environment can result in different colors being displayed on the display. Furthermore, for certain color states, especially yellow and green, the human eye is more sensitive to changes in saturation, and slight variations in the color state can be physically irritating. For example, skin tones that take on a greenish cast can be very disconcerting to the viewer. Therefore, general grayscale / color image flow requires very precise control of the applied impulses to give good results.

[0009] Further complicating matters, in some situations, it may be desirable for a single display to utilize multiple drive schemes. For example, a display capable of producing many colors at each pixel may typically operate in “global full” (“GC mode”), where each color pixel has the ability to transition from a first color to a second color during each image update. Naturally, as described, for example, in U.S. Pat. No. 10,657,869, such updates can take time (e.g., one second or more), especially when DC balance and remnant voltage management are required to achieve the highest quality colors. However, in other cases, such as drawing with a stylus or turning pages of text, very rapid updates are desired, and users would readily sacrifice color fidelity in exchange for a faster update experience. Such faster update schemes are typically known as “direct updates” (“DU mode”) and typically involve simply driving the electrophoretic medium to the black-and-white range. See, for example, U.S. Pat. No. 9,672,766. For more sophisticated products such as color e-readers / tablets, there may be multiple types of each mode depending on the content being displayed. Additional modes such as video (known as "A2 mode") may also be included, and the display controller may be programmed to automatically switch between modes depending on the content being displayed or user actions, such as touching with a stylus.

[0010] As discussed in U.S. Pat. No. 11,686,989, in multi-particle systems used to process black or white, driving between the white and black states can require very different impulse potentials (voltages accumulated over time). For example, ACeP®, which contains one negative white particle and three differently charged positive particles that together produce the black state, can require a much larger impulse potential to achieve a good black state than a good white state. That is, to achieve white, the negative white particles simply need to be placed between the viewer and the colored particles, whereas to achieve a good black state, all the positively charged particles must be driven to the viewing surface and mixed, and all the white particles must be driven behind the positive colored particles. In a typical "GC" mode, the white and black states are achieved using DC balancing so that shuttling for both the black and white states does not result in any impulse potentials for those color states. However, this comes at the expense of a longer waveform, i.e., typically about 1 second, e.g., 500 ms to 3 seconds, e.g., 700 ms to 1 second. For DU mode, the switching time between the black and white states should desirably be much shorter, e.g., less than 500 ms, e.g., less than 300 ms, e.g., about 250 ms. However, because of the difference in impulse potential between the black and white states, the impulse potential must be carefully managed to keep charge from building up on the pixels, which would later result in a faulty color state. This condition may be encountered in an electronic reader where a reader is viewing 20 pages of text and then viewing a full-color image.

[0011] The term "gray state" is used herein in its conventional sense in the imaging arts to refer to a state intermediate between two extreme optical states of a pixel, and does not necessarily imply a black-to-white transition between these two extreme states. For example, several of the E INK patents and published applications referenced below describe electrophoretic displays in which the extreme states are white and dark blue, so that an intermediate gray state would actually be light blue. In fact, as already noted, a change in optical state may not be a change in color at all. The term "black and white" may hereinafter be used herein to refer to the two extreme optical states of a display, and should be understood to include extreme optical states that are not typically strictly black and white, such as the white and dark blue color states discussed above.

[0012] The terms "bistable" and "bistable" are used herein in their conventional sense in the art to refer to a display comprising display elements having first and second display states that differ in at least one optical property, such that after any given element is driven with a finite-duration addressing pulse to assume either its first or second display state, that state will persist after the addressing pulse is terminated for at least several times, e.g., at least four times, the minimum duration of the addressing pulse required to change the state of the display element. U.S. Pat. No. 7,170,670 indicates that some grayscale-capable particle-based electrophoretic displays are stable not only in their extreme black and white states but also in their intermediate gray states, and the same is true for several other types of electro-optic displays. Displays of this type are properly referred to as "multistable" rather than "bistable," although for convenience the term "bistable" may be used herein to encompass both bistable and multistable displays.

[0013] The term "impulse", when used, refers to the driving of an electrophoretic display and refers to the integral of the applied voltage with respect to time during the period in which the display is driven.

[0014] Particles that absorb, scatter, or reflect light, either broadly or at selected wavelengths, are referred to herein as colored or pigment particles. A variety of materials other than pigments (in the strict sense of that term as meaning insoluble colored materials) that absorb or reflect light, such as dyes or photonic crystals, may also be used in the electrophoretic media and displays of the present invention.

[0015] Particle-based electrophoretic displays have been the subject of intense research and development for many years. In such displays, a plurality of charged particles (sometimes referred to as pigment particles) move through a fluid under the influence of an electric field. Electrophoretic displays can have attributes of good brightness and contrast, wide viewing angles, state bistability, and low power consumption when compared to liquid crystal displays. Nevertheless, problems with the long-term image quality of these displays have prevented their widespread use. For example, the particles that make up electrophoretic displays tend to settle, resulting in an inadequate usable lifespan for these displays.

[0016] As noted above, electrophoretic media require the presence of a fluid. In most prior art electrophoretic media, this fluid is liquid, but electrophoretic media can also be produced using gaseous fluids. See, for example, Kitamura, T., et al., Electrical toner movement for electronic paper-like display, IDW Japan, 2001, Paper HCS1-1, and Yamaguchi, Y., et al., Toner display using insulative particles charged triboelectrically, IDW Japan, 2001, Paper AMD4-4. See also U.S. Patent Nos. 7,321,459 and 7,236,291. Such gas-based electrophoretic media are believed to be susceptible to the same types of problems as liquid-based electrophoretic media due to particle settling when used in an orientation that allows such settling, such as in a sign where the medium is positioned in a vertical plane. In fact, particle settling is believed to be a more serious problem in gas-based electrophoretic media than in liquid-based electrophoretic media due to the lower viscosity of the gaseous suspending fluid compared to the viscosity of a liquid, which allows for faster settling of the electrophoretic particles.

[0017] Numerous patents and applications assigned to or in the name of the Massachusetts Institute of Technology (MIT) and E Ink Corporation describe various techniques used in encapsulated electrophoretic and other electro-optic media. Such encapsulated media comprise a multitude of small capsules, each of which comprises an internal phase containing electrophoretically movable particles in a fluid medium and a capsule wall surrounding the internal phase. Typically, the capsules are themselves held within a polymer binder to form a coherent layer positioned between two electrodes. Techniques described in these patents and applications include the following: (a) Electrophoretic particles, fluids, and fluid additives (see, e.g., U.S. Pat. Nos. 7,002,728 and 7,679,814) (b) Capsules, binders, and encapsulation processes (see, e.g., U.S. Patent Nos. 6,922,276 and 7,411,719) (c) Microcell structures, wall materials, and methods of forming the microcells (see, e.g., U.S. Patent Nos. 7,072,095 and 9,279,906) (d) Methods for filling and sealing microcells (see, e.g., U.S. Patent Nos. 7,144,942 and 7,715,088) (e) Films and subassemblies containing electro-optical materials (see, e.g., U.S. Patent Nos. 6,982,178 and 7,839,564) (f) Backplanes, adhesive layers, other auxiliary layers, and methods used in displays (see, e.g., U.S. Pat. Nos. 7,116,318 and 7,535,624) (g) Color formation and color control (e.g., U.S. Patent Nos. 6,017,584, 6,545,797, 6,664,944, 6,788,452, 6,864,875, 6,914,714, 6,972,893, 7,038,656, 7,038,670, 7,046,228, 7,052,571, 7,075,502***, 7,167,155, 7,385,751, 7,492,505, 7,667,68 No. 4, No. 7,684,108, No. 7,791,789, No. 7,800,813, No. 7,821,702, No. 7,839,564***, No. 7,910,175, No. 7,952,790, No. 7,956,841, No. 7,982, No. 941, No. 8,040,594, No. 8,054,526, No. 8,098,418, No. 8,159,636, No. 8,213,076, No. 8,363,299, No. 8,422,116, No. 8,441,714, No. 8,441,7 No. 16, No. 8,466,852, No. 8,503,063, No. 8,576,470, No. 8,576,475, No. 8,593,721, No. 8,605,354, No. 8,649,084, No. 8,670,174, No. 8,704,7 No. 56, No. 8,717,664, No. 8,786,935, No. 8,797,634, No. 8,810,899, No. 8,830,559, No. 8,873,129, No. 8,902,153, No. 8,902,491, No. 8,917,43 Nos. 9, 8,964,282, 9,013,783, 9,116,412, 9,146,439, 9,164,207, 9,170,467, 9,170,468, 9,182,646, 9,195,111, 9,199,441, 9,268,191, 9,285,649, 9,293,511, 9,341,916, 9,360,733, 9,361,836, 9,383,623, and 9,423,666, and U.S. Patent Application Publication Nos. 2008 / 0043318, 2008 / 0048970, 2009 / 0225398, 2010 / 0156780, 2011 / 0043543, 2012 / 0326957, 2013 / 0242378, 2013 / 0278995, 2014 / 0055840, 2014 / 0078576, 2014 / 0340430, 2014 / 0340736, and 2014 / 0362 213, No. 2015 / 0103394, No. 2015 / 0118390, No. 2015 / 0124345, No. 2015 / 0198858, No. 2015 / 0234250, No. 2015 / 0268531, No. 2015 / 0301246, No. 2016 / 0011484, No. 2016 / 0026062, No. 2016 / 0048054, No. 2016 / 0116816, No. 2016 / 0116818, and No. 2016 / 0140909). (h) Methods for driving displays (e.g., U.S. Patent Nos. 5,930,026, 6,445,489, 6,504,524, 6,512,354, 6,531,997, 6,753,999, 6,825,970, 6,900,851, 6,995,550, 7,012,600, 7,023,420, 7,034,783, 7,061,166, 7,061,662, 7,116,466, 7,119,772, 7,177,066, 7,193,625, 7,2 No. 02,847, No. 7,242,514, No. 7,259,744, No. 7,304,787, No. 7,312,794, No. 7,327 ,511, No. 7,408,699, No. 7,453,445, No. 7,492,339, No. 7,528,822, No. 7,545,3 No. 58, No. 7,583,251, No. 7,602,374, No. 7,612,760, No. 7,679,599, No. 7,679,813 No. 7,683,606, No. 7,688,297, No. 7,729,039, No. 7,733,311, No. 7,733,335, No. No. 7,787,169, No. 7,859,742, No. 7,952,557, No. 7,956,841, No. 7,982,479, No. 7, No. 999,787, No. 8,077,141, No. 8,125,501, No. 8,139,050, No. 8,174,490, No. 8,24 No. 3,013, No. 8,274,472, No. 8,289,250, No. 8,300,006, No. 8,305,341, No. 8,314, No. 784, No. 8,373,649, No. 8,384,658, No. 8,456,414, No. 8,462,102, No. 8,514,168 No. 8,537,105, No. 8,558,783, No. 8,558,785, No. 8,558,786, No. 8,558,855, No. 8,576,164, No. 8,576,259, No. 8,593,396, No. 8,605,032, No. 8,643,595, No. 8 ,665,206, No.8,681,191, No.8,730,153, No.8,810,525, No.8,928,562, No.8,9 No. 28,641, No. 8,976,444, No. 9,013,394, No. 9,019,197, No. 9,019,198, No. 9,019,Nos. 318, 9,082,352, 9,171,508, 9,218,773, 9,224,338, 9,224,342, 9,224,344, 9,230,492, 9,251,736, 9,262,973, 9,269,311, 9,299,294, 9,373,289, 9,390,066, 9,390,661, and 9,412,314, and U.S. Patent Application Publication Nos. 2003 / 0102858, 2004 / 0246562, 2005 / 0253777, 2007 / 0091418, 2007 / 0103427, 2007 / 0176912, 2008 / 0024429, 2008 / 0024482, 2008 / 0136774, 2008 / 0291129, 2008 / 0303780, 2009 / 0174651, 2009 / 0195568, and 2009 / 0322721 , No. 2010 / 0194733, No. 2010 / 0194789, No. 2010 / 0220121, No. 2010 / 0265561, No. 2010 / 0283804, No. 2011 / 0063314, No. 2011 / 0175875, No. 2011 / No. 0193840, No. 2011 / 0193841, No. 2011 / 0199671, No. 2011 / 0221740, No. 2012 / 0001957, No. 2012 / 0098740, No. 2013 / 0063333, No. 2013 / 0194250 , No. 2013 / 0249782, No. 2013 / 0321278, No. 2014 / 0009817, No. 2014 / 0085355, No. 2014 / 0204012, No. 2014 / 0218277, No. 2014 / 0240210, No. 2014 / No. 0240373, No. 2014 / 0253425, No. 2014 / 0292830, No. 2014 / 0293398, No. 2014 / 0333685, No. 2014 / 0340734, No. 2015 / 0070744, No. 2015 / 0097877 , 2015 / 0109283, 2015 / 0213749, 2015 / 0213765, 2015 / 0221257, 2015 / 0262255, 2015 / 0262551, 2016 / 0071465, 2016 / 0078820, 2016 / 0093253, 2016 / 0140910, and 2016 / 0180777) (these patents and applications may hereinafter be referred to as the MEDEOD (Method for Driving an Electro-Optic Display) Applications). (i) Display applications (see, e.g., U.S. Patent Nos. 7,312,784 and 8,009,348) (j) Non-electrophoretic displays, such as those described in U.S. Pat. No. 6,241,921, and U.S. Patent Application Publication Nos. 2015 / 0277160, and U.S. Patent Application Publication Nos. 2015 / 0005720 and 2016 / 0012710.

[0018] Many of the aforementioned patents and applications recognize that the walls surrounding discrete microcapsules in an encapsulated electrophoretic medium may be replaced by a continuous phase, thus producing so-called "polymer-dispersed electrophoretic displays," in which the electrophoretic medium consists of a plurality of discrete droplets of electrophoretic fluid and a continuous phase of polymer material, and that the discrete droplets of electrophoretic fluid in such polymer-dispersed electrophoretic displays may be considered capsules or microcapsules, even though no discrete capsule membrane is associated with each individual droplet. See, e.g., U.S. Pat. No. 6,866,760. Therefore, for purposes of this application, such polymer-dispersed electrophoretic media are considered a subspecies of encapsulated electrophoretic media.

[0019] A related type of electrophoretic display is the so-called "microcell electrophoretic display." In a microcell electrophoretic display, the charged particles and fluid are not encapsulated in microcapsules, but instead are retained within a plurality of cavities formed in a carrier medium, typically a polymer film. See, e.g., U.S. Patent Nos. 6,672,921 and 6,788,449.

[0020] Although electrophoretic media are often opaque (e.g., because in many electrophoretic media the particles substantially block the transmission of visible light through the display) and can operate in a reflective mode, many electrophoretic displays can be made to operate in a so-called "obscured mode," in which one display state is substantially opaque and one is light transmissive. See, e.g., U.S. Patent Nos. 5,872,552, 6,130,774, 6,144,361, 6,172,798, 6,271,823, 6,225,971, and 6,184,856. Dielectrophoretic displays, which are similar to electrophoretic displays but rely on variations in electric field strength, can operate in a similar mode. See U.S. Patent No. 4,418,346. Other types of electro-optic displays may also be capable of operating in a obscured mode. Electro-optic media operating in the shielding mode can be used in multilayer structures for full-color displays, where at least one layer adjacent to the viewing surface of the display operates in the shielding mode to expose or obscure a second layer more remote from the viewing surface.

[0021] Encapsulated electrophoretic displays typically do not suffer from the clustering and settling failure modes of conventional electrophoretic devices and offer additional advantages, such as the ability to print or coat the display on a wide variety of flexible and rigid substrates. (The use of the term "printing" is intended to include, but is not limited to, all forms of printing and coating, including pre-metered coatings such as patch die coating, slot or extrusion coating, slide or cascade coating, curtain coating, roll coatings such as knife-over-roll coating, forward and reverse roll coating, gravure coating, dip coating, spray coating, meniscus coating, spin coating, brush coating, air knife coating, silk screen printing processes, electrostatic printing processes, thermal printing processes, inkjet printing processes, electrophoretic deposition (see U.S. Pat. No. 7,339,715), and other similar techniques.) The resulting display can therefore be flexible. Furthermore, because the display medium can be printed (using a variety of methods), the display itself can be made inexpensively.

[0022] As noted above, the simplest prior art electrophoretic media essentially display only two colors. Such electrophoretic media use either a single type of electrophoretic particles having a first color in a colored fluid having a second, different color (where the first color is displayed when the particles are adjacent to the viewing surface of the display and the second color is displayed when the particles are spaced from the viewing surface), or first and second types of electrophoretic particles having different first and second colors in a non-colored fluid (where the first color is displayed when the first type of particles are adjacent to the viewing surface of the display and the second color is displayed when the second type of particles are adjacent to the viewing surface). Typically, the two colors are black and white. If a full-color display is desired, a color filter array may be deposited across the viewing surface of a monochrome (black-and-white) display. Displays with color filter arrays rely on area sharing and color blending to create color stimuli. The available display area is shared among three or four primary colors, such as red / green / blue (RGB) or red / green / blue / white (RGBW), and the filters can be arranged in a one-dimensional (striped) or two-dimensional (2x2) repeating pattern. Other alternative primary colors or more than three primary colors are also known in the art. The three (for RGB displays) or four (for RGBW displays) subpixels are chosen to be small enough that, at the intended viewing distance, they visually blend together into a single pixel with a uniform color stimulus ("color blending"). An inherent disadvantage of area sharing is that the colorants are always present, and the color can only be modulated by switching corresponding pixels of the underlying monochrome display to white or black (switching the corresponding primary colors on or off). For example, in an ideal RGBW display, the red, green, blue, and white primaries each occupy one-quarter of the display area (one subpixel out of four), and the white subpixel is as bright as the white of the underlying monochrome display, but each colored subpixel is no brighter than one-third of the white of the monochrome display.The brightness of the white color shown by the display as a whole cannot exceed half the brightness of the white subpixel (the white area of ​​the display is produced by displaying one white subpixel out of every four, plus each colored subpixel in its colored form equal to one-third of the white subpixel; thus, three colored subpixels combined contribute no more than one white subpixel). Color brightness and saturation are reduced by area sharing with color pixels switched to black. Area sharing is particularly problematic when mixing yellow, because it is brighter than any other color of equal brightness, and saturated yellow is nearly as bright as white. Switching a blue pixel (one-quarter of the display area) to black causes the yellow to darken significantly.

[0023] U.S. Patent Nos. 8,576,476 and 8,797,634 describe multicolor electrophoretic displays having a single backplane with independently addressable pixel electrodes and a common light-transmitting front electrode. Multiple electrophoretic layers are disposed between the backplane and the front electrode. The displays described in these applications are capable of rendering any of the primary colors (red, green, blue, cyan, magenta, yellow, white, and black) at any pixel location. However, there are disadvantages to using multiple electrophoretic layers positioned between a single set of addressing electrodes. The electric field experienced by particles in a particular layer is lower than would be the case for a single electrophoretic layer addressed with the same voltage. In addition, optical losses (e.g., caused by light scattering or unwanted light absorption) in the electrophoretic layers closest to the viewing surface can affect the appearance of the image formed in the underlying electrophoretic layers.

[0024] A second form of electrophoretic medium capable of rendering any color at any pixel location is described in U.S. Pat. No. 9,921,451. In the '451 patent, the electrophoretic medium includes four particles: white, cyan, magenta, and yellow; two of the particles are positively charged and two are negatively charged. However, the display of the '451 patent also suffers from color mixing with the white state. Because one of the particles has the same charge as the white particles, when a white state is desired, a certain number of identically charged particles migrate along with the white toward the viewing surface. While complex waveforms could potentially be used to overcome this unwanted color hue, such waveforms would significantly increase the display's update time and, in some cases, result in unacceptable "flashing" between images.

[0025] As discussed above with respect to U.S. Patent No. 11,686,989, one solution is to use an electrophoretic medium comprising four particles: white, cyan, magenta, and yellow; three of the particles are positively charged, and the negatively charged particles are white. While charging all non-white particles oppositely to the white particles helps reduce color contamination in the white state, this combination results in an unbalanced waveform when transitioning from a color state to either the white or black state. In particular, the black state typically requires a sustained, highly positive drive to ensure that all positively charged particles are transferred to the viewing surface. [Prior art documents] [Patent documents]

[0026] [Patent Document 1] U.S. Patent No. 9,361,836 [Patent Document 2] U.S. Patent No. 9,921,451 [Non-patent literature]

[0027] [Non-Patent Document 1] Kitamura, T., et al., Electrical toner movement for electronic paper-like display, IDW Japan, 2001, Paper HCS1-1 [Non-patent document 2] Yamaguchi, Y., et al., Toner display using insulative particles charged triboelectrically, IDW Japan, 2001, Paper AMD4-4 Summary of the Invention [Means for solving the problem]

[0028] (summary) A first aspect of the present invention is a method of driving an electrophoretic display having a plurality of pixels, each pixel capable of displaying at least three optical states including white, black, and a color that is neither white nor black. The method includes driving the electrophoretic display using a first drive mode that allows transitions between all of the optical states; driving the electrophoretic display using a second drive mode that includes transitions only between a black optical state and a white optical state, wherein in the second drive mode, the impulse potential experienced by a pixel going from a white state to a black state is equal to and opposite to the impulse potential experienced by a pixel going from a black state to a white state; driving the electrophoretic display using a first transition mode that allows transitions from a color state of the first drive mode to a white or black state of the second drive mode, wherein the first transition mode compensates for excess impulse potential that would be delivered to the pixel in the second drive mode; and driving the electrophoretic display using a second transition mode that allows transitions from the white or black state of the second drive mode to a color state of the first drive mode, wherein the second transition mode compensates for excess impulse potential delivered to the pixel in the second drive mode. In one embodiment, in the first drive mode, the impulse potential experienced by a pixel transitioning from a white state to a black state is not equal to the impulse potential experienced by a pixel transitioning from a black state to a white state, and vice versa. In one embodiment, the first transition mode and the second transition mode do not have identical impulse potential compensation between the color state of the first drive mode and the white state of the second drive mode, and between the color state of the first drive mode and the black state of the second drive mode. In one embodiment, the first transition mode and the second transition mode do not have identical waveforms between the color state of the first drive mode and the white state of the second drive mode, and between the color state of the first drive mode and the black state of the second drive mode. In one embodiment, in the second drive state, the waveform causing the transition from the white state to the black state includes at least five frames of maximum positive voltage.In one embodiment, the waveform causing a transition from the black state to the white state in the second drive state includes at least five frames of maximum negative voltage. In one embodiment, the first drive mode is DC balanced. In one embodiment, the first and second transition modes are not DC balanced. In one embodiment, each pixel is capable of displaying at least eight optical states, and the first transition mode allows transitions from each of six non-black and non-white optical states to the white or black state of the second drive mode. In one embodiment, the eight optical states are black, white, red, magenta, yellow, green, cyan, and blue.

[0029] In another aspect, a display controller is configured to perform any of the above methods.

[0030] In another aspect, an electrophoretic display is configured to implement any of the above methods. In one embodiment, the electrophoretic display includes an electrophoretic medium comprising at least three types of particles having different electrophoretic mobilities. In one embodiment, at least two of the three types of particles have the same electric charge but different charge magnitudes. In one embodiment, one of the particle types is negatively charged and white in color. In one embodiment, the display includes three positively charged particle types, with the positively charged particles of each type being partially light-absorbing and different in color from the other types of positively charged particles. In one embodiment, the electrophoretic medium is confined within a plurality of capsules or a plurality of microcells. [Brief explanation of the drawings]

[0031] [Figure 1] FIG. 1 is a schematic cross-sectional view showing the positions of various colored particles in an electrophoretic medium of the present invention when displaying black, white, the three subtractive primary colors, and the three additive primary colors.

[0032] [Figure 2A]2A is a general illustration of an electrophoretic display having four types of particles in a non-polar fluid, with a full range of colors available at each pixel electrode. In some embodiments, one type of negatively charged particles is white, one type of positively charged particles is yellow, one type of positively charged particles is magenta, and one type of positively charged particles is cyan; however, it should be understood that the invention is not limited to the exemplary color set or combinations of charge polarities and magnitudes.

[0033] [Figure 2B] FIG. 2B illustrates a transition between a first optical state, having all of the particles at the viewing surface with a first charge polarity, and a second optical state, having particles at the viewing surface with a second (opposite) polarity.

[0034] [Figure 2C] FIG. 2C illustrates a transition between a first optical state, having all of the particles at the viewing surface of a first charge polarity, and a third optical state, having particles with a second (opposite) polarity located at the viewing surface behind intermediate charged particles of the first polarity.

[0035] [Figure 2D] FIG. 2D illustrates a transition between a first optical state, having all of the particles at the viewing surface of a first charge polarity, and a fourth optical state, having particles with a second (opposite) polarity located at the viewing surface behind the less charged particles of the first polarity.

[0036] [Figure 2E] FIG. 2E illustrates a transition between a first optical state, having all particles of a first charge polarity at the viewing surface, and a fifth optical state, having particles with a second (opposite) polarity located at the viewing surface behind a combination of low and medium charged particles of the first polarity.

[0037] [Figure 3]FIG. 3 illustrates an exemplary equivalent circuit of a single pixel of an electrophoretic display.

[0038] [Figure 4] FIG. 4 shows the layers of an exemplary electrophoretic color display.

[0039] [Figure 5] 5 shows an exemplary push-pull drive scheme for addressing an electrophoretic medium containing three subtractive particles and a scattering (white) particle. Such addressing pulses are typically accompanied by a DC balanced clearing pulse, allowing each color state to be switched to every other color state.

[0040] [Figure 6] 6 illustrates a drive mode workflow that may be performed by a display controller using the methods of the present invention. In particular, the display drive mode changes based on the color content of the image to be displayed and / or the need to have fast page turns and / or the need for stylus updates. In some embodiments, the controller switches between modes automatically. In other embodiments, switching modes requires user input.

[0041] [Figure 7] FIG. 7 is a generalized schematic diagram of the present invention showing the DUin and DUout transition modes that compensate for impulse potentials when moving between globally complete ("GC") and DU modes and vice versa.

[0042] [Figure 8] 8 illustrates waveforms that can be used to provide fast transitions between white and black optical states in direct update ("DU") mode. Other waveforms can also be used, provided they introduce an offset impulse potential when going between black and white states.

[0043] [Figure 9A] FIG. 9A shows a series of waveforms as voltage frames for several transitions in the DUin mode (a mode of the present invention), which allows for impulse potential-compensated transitions between the GC mode and the DU mode. It is noteworthy that "duK" and "duW" correspond to the black and white optical states in the DU mode, respectively. K, W, GC2, and GC3 correspond to the black, white, and generalized second and third colors in the GC mode, respectively. Typically, K is the first color and W is the last color in the GC mode.

[0044] [Figure 9B] FIG. 9B shows the actual visual transitions with each frame in DUin mode, ie, corresponding to the waveforms shown in FIG. 9A.

[0045] [Figure 10A] FIG. 10A shows a series of waveforms as voltage frames for several transitions in DUout mode, which allow impulse potential compensated transitions between DU and GC modes.

[0046] [Figure 10B] FIG. 10B shows the actual visual transitions with each frame in DUout mode, ie, corresponding to the waveforms shown in FIG. 10A.

[0047] [Figure 11] 11 is an illustrative example of how impulse potentials are compensated when moving between GC and DU modes. It is notable that impulse compensation from GC to DU (i.e., DUIn) is different from impulse compensation from DU to GC (i.e., DUout). DETAILED DESCRIPTION OF THE INVENTION

[0048] (Detailed explanation) The present invention provides a method for driving a multi-pixel electrophoretic display designed to enable at least three colors, e.g., eight colors, at each pixel. The method uses a first drive scheme capable of producing transitions between all of the colors that can be displayed at each pixel, and a second drive scheme containing only transitions that end in white or black, which is very useful for drawing black lines on a white page, reading black text on a white page, or reading white text on a black page. The second drive scheme is intended to enable fast response of the display to user input, such as a user "writing" with a stylus on a display incorporating a touchscreen, electromagnetic resonance (EMR), or another form of stylus or touch interaction. The present invention further provides a transition drive scheme for switching between the first and second drive schemes.

[0049] The present invention includes an improved four-particle electrophoretic medium, which includes a first particle of a first polarity and three other particles of the opposite polarity but with different charge magnitudes. Typically, such a system includes a negative white particle and positively charged particles of the subtractive primary colors yellow, magenta, and cyan. In addition, some particles can be engineered so that their electrophoretic mobility is nonlinear with the strength of the applied electric field. Thus, one or more particles will experience a decrease in electrophoretic mobility upon application of a high electric field of the correct polarity (e.g., 20 V or greater). Such a four-particle system is shown diagrammatically in FIG. 1 and can provide white, yellow, red, magenta, blue, cyan, green, and black at every pixel.

[0050] As shown in Figure 1, each of the eight primary colors (red, green, blue, cyan, magenta, yellow, black, and white) corresponds to a different arrangement of four particles, so that the viewer sees only those colored particles (i.e., light-scattering particles) on the viewing side of the white particles. To achieve a wide range of colors, additional voltage levels must be used for finer control of the particles. In the described formulation, the first (typically negative) particle is reflective (typically white), while the other three particles, i.e., the oppositely charged (typically positive) particles, comprise three substantially non-light-scattering ("SNLS") particles. The use of SNLS particles allows for color mixing, providing more color results than can be achieved with the same number of scattering particles. These thresholds must be sufficiently separated to avoid crosstalk, which necessitates the use of high addressing voltages for some colors. The disclosed four-particle electrophoretic media can update faster, require "less flash" transitions, and produce a color spectrum that is more pleasing to the viewer (and therefore more commercially useful). In addition, the disclosed formulations provide faster updates between black and white pixels (e.g., less than 500 ms, e.g., less than 300 ms, e.g., less than 200 ms, e.g., less than 100 ms), thereby enabling fast page turns for black on white text.

[0051] In FIG. 1 , the viewing surface of the display is assumed to be at the top (as shown), i.e., the user views the display from this direction and light is incident from this direction. As already mentioned, in a preferred embodiment, only one of the four particles used in the electrophoretic medium of the present invention substantially scatters light, and in FIG. 1 , this particle is assumed to be a white pigment. The light-scattering white particles form a white reflector against which any particles above the white particles are viewed (as shown in FIG. 1 ). Light that enters the viewing surface of the display and passes through these particles is reflected from the white particles, passes back through these particles, and emerges from the display. Thus, particles above the white particles may absorb various colors, and the color that appears to the user results from the combination of the particles above the white particles. Any particles located below the white particles (behind them from the user's perspective) are masked by the white particles and do not affect the displayed color. Because the second, third, and fourth particles are substantially non-light scattering, their order or arrangement relative to one another is not important, but for the reasons already stated, their order or arrangement relative to the white (light scattering) particles is important.

[0052] More specifically, when cyan, magenta, and yellow particles are present below a white particle (situation [A] in FIG. 1), no particles are present above the white particle, and the pixel simply displays white. When a single particle is present above the white particle, the color of that single particle is displayed as yellow, magenta, and cyan, respectively, in situations [B], [D], and [F] in FIG. 1. When two particles are present above a white particle, the displayed color is a combination of those two particles. That is, in situation [C] in FIG. 1, magenta and yellow particles display red, in situation [E], cyan and magenta particles display blue, and in situation [G], yellow and cyan particles display green. Finally, when all three colored particles are present above the white particle (situation [H] in FIG. 1), all incident light is absorbed by the subtractive primary colored particles, and the pixel displays black.

[0053] It is possible that one subtractive primary color could be rendered by light-scattering particles, so that the display would have two types of light-scattering particles, one of which would be white and the other of which would be colored. However, in this case, the position of the light-scattering colored particles relative to the other colored particles that cover the white particles would be important. For example, when rendering black (when all three colored particles are present over the white particles), the scattering colored particles cannot be present over the non-scattering colored particles (otherwise they would be partially or completely hidden behind the scattering particles, and the color rendered would be that of the scattering colored particles, not black).

[0054] FIG. 1 shows an ideal situation in which there is no color contamination (i.e., the light-scattering white particles completely mask any particles present behind them). In practice, masking by the white particles may be non-perfect, so that there may be slight absorption of light by particles that would ideally be completely masked. Such contamination typically reduces both the lightness and saturation of the color being rendered. In the electrophoretic media of the present invention, such color contamination should be minimized to the point that the colors produced are comparable to industry standards for color rendering. A particularly preferred standard is SNAP (a standard for newspaper advertising production), which specifies L*, A*, and b* values ​​for each of the eight primary colors referenced above (hereinafter, "primary colors" will be used to refer to the eight colors, i.e., black, white, the subtractive primary colors, and the additive primary colors, as shown in FIG. 1).

[0055] 2A-2E show schematic cross-sectional representations of four particle types used in the present invention. Utilizing an improved electrophoretic medium, the display layer includes a first (viewing) surface 13 on the viewing side and a second surface 14 opposite the first surface 13. The electrophoretic medium is disposed between the two surfaces. Each space between two vertical dotted lines represents a pixel. Within each pixel, the electrophoretic medium can be addressed such that the viewing surface 13 of each pixel can achieve the color states shown in FIG. 1 without the need for additional layers or color filter arrays.

[0056] As is standard for electrophoretic displays, the first surface 13 is light-transmitting and includes a common electrode 11, constructed, for example, from a sheet of PET with indium tin oxide (ITO) disposed thereon. On the second surface (14) is an electrode layer 12, including a plurality of pixel electrodes 15. Such pixel electrodes are described in U.S. Pat. No. 7,046,228, the contents of which are incorporated herein by reference in their entirety. Note that while active matrix driving in conjunction with a thin film transistor (TFT) backplane is described with respect to the pixel electrode layer, the scope of the present invention also encompasses addressing of other types of electrodes, so long as the electrodes perform the desired function. For example, the top and bottom electrodes can be continuous. Additionally, pixel electrode backplanes other than those described in the '228 patent are also suitable, including active matrix backplanes, which are capable of providing higher driving voltages than those typically found with amorphous silicon thin film transistor backplanes.

[0057] Newly developed active matrix backplanes may include thin-film transistors incorporating metal oxide materials such as tungsten oxide, tin oxide, indium oxide, zinc oxide, or more complex metal oxides such as indium gallium zirconium oxide. In these applications, a channel-forming region is formed for each transistor using such metal oxide materials, enabling faster switching of higher voltages. Such metal oxide transistors also allow for less leakage in the "off" state of the thin-film transistor (TFT), which can be achieved, for example, with amorphous silicon TFTs. In a typical scanning TFT backplane with n rows, the transistors would be in the "off" state for approximately the fraction (n-1) / n of the time required to refresh all rows of the display. Any leakage of charge from the storage capacitor associated with each pixel would result in degradation of the electro-optical performance of the display. TFTs typically include a gate electrode, a gate insulating film (typically SiO2), a metal source electrode, a metal drain electrode, and a metal oxide semiconductor film covering the gate insulating film, which at least partially polymerizes the gate, source, and drain electrodes. Such backplanes are available from manufacturers such as Sharp / Foxconn, LG, and BOE. Such backplanes can provide drive voltages of ±30V (or more). In some embodiments, a mid-voltage driver is included, whereby the resulting drive waveform can include five levels, or seven levels, or nine levels, or more.

[0058] One preferred metal oxide material for such applications is indium gallium zinc oxide (IGZO). IGZO TFTs have electron mobility 20 to 50 times greater than that of amorphous silicon. Using IGZO TFTs in an active matrix backplane allows for the potential of providing voltages greater than 30 V via a suitable display driver. Furthermore, a source driver capable of providing at least five, and preferably seven, levels provides different driving paradigms for a four-particle electrophoretic display system. In one embodiment, there will be two positive voltages, two negative voltages, and zero volts. In another embodiment, there will be three positive voltages, three negative voltages, and zero volts. In one embodiment, there will be four positive voltages, four negative voltages, and zero volts. These levels can be selected within the range of approximately -27 V to +27 V, without the limitations imposed by top-plane switching as described above.

[0059] The electrophoretic medium of the present invention includes four types of electrophoretic particles in a nonpolar fluid 17, as shown in Figures 2A-2E. The first particles (W-*; open circles) are negatively charged and can be surface-treated so that their electrophoretic mobility depends on the strength of the driving electric field (discussed in more detail below). In such cases, the electrophoretic mobility of the particles actually decreases in the presence of a stronger electric field, which is somewhat counterintuitive. The second particles (M++*; dark circles) are positively charged and can also be surface-treated (or intentionally untreated) so that their electrophoretic mobility either depends on the strength of the driving electric field or, upon reversal of the electric field direction, the rate of expansion of the second particle population after being driven to one side of the cavity containing the particles is slower than the rates of expansion of the third and fourth particle populations. The third particle (Y+; checkered circle) has a positive charge magnitude but a smaller charge magnitude than the second particle. Additionally, the third particle may be surface-treated, but not in a way that makes the third particle's electrophoretic mobility dependent on the strength of the driving electric field. That is, the third particle has a surface treatment, but such surface treatment does not result in a decrease in electrophoretic mobility with increasing electric field. The fourth particle (C+++; gray circle) has the highest positive charge magnitude and the same type of surface treatment as the third particle. As shown in FIG. 2A, the particles are nominally white, magenta, yellow, and cyan to produce the colors shown in FIG. 1. However, the present invention is not limited to this specific color set, nor is it limited to one reflective particle and three absorbing particles. For example, the system may include one black absorbing particle and three reflective particles in red, yellow, and blue with reflectance spectra that are suitably matched to produce a process white state when all three reflective particles are mixed and visible on the surface.

[0060] In a preferred embodiment, the first particles (negative) are white and scattering; the second particles (positive, medium charge magnitude) are magenta and absorbing; the third particles (positive, low charge magnitude) are yellow and absorbing; and the fourth particles (positive, high charge magnitude) are cyan and absorbing. Table 1 below shows the diffuse reflectance of exemplary yellow, magenta, cyan, and white particles useful in the electrophoretic media of the present invention, along with the ratios of their absorption and scattering coefficients by Kubelka-Munk analysis of these materials as dispersed in a poly(isobutylene) matrix. [Table 1]

[0061] The electrophoretic medium of the present invention can be in any of the forms discussed above. Thus, the electrophoretic medium may be unencapsulated, encapsulated in separate capsules surrounded by capsule walls, encapsulated in sealed microcells, or in the form of a polymeric dispersion medium. Pigments are described in detail elsewhere, such as in U.S. Pat. Nos. 9,697,778 and 9,921,451. Briefly, white particles W1 are silanol-functionalized light-scattering pigments (titanium dioxide) to which a polymeric material containing lauryl methacrylate (LMA) monomer is attached, as described in U.S. Pat. No. 7,002,728. White particles W2 are polymer-coated titania produced substantially as described in Example 1 of U.S. Pat. No. 5,852,196, with a polymeric coating containing lauryl methacrylate and 2,2,2-trifluoroethyl methacrylate in a ratio of approximately 99:1. Yellow particles Y1 are CI Pigment Yellow 180, used without coating and dispersed by attrition in the presence of Solsperse 19000, as generally described in U.S. Pat. No. 9,697,778. Yellow particles Y2 are CI Pigment Yellow 155, used without coating and dispersed by attrition in the presence of Solsperse 19000, as generally described in U.S. Pat. No. 9,697,778. Yellow particles Y3 are CI Pigment Yellow 139, used without coating and dispersed by attrition in the presence of Solsperse 19000, as generally described in U.S. Pat. No. 9,697,778. Yellow particles Y4 are CI Pigment Yellow 139, coated by dispersion polymerization and incorporating trifluoroethyl methacrylate, methyl methacrylate, and dimethylsiloxane-containing monomers, as described in Example 4 of U.S. Pat. No. 9,921,451. Magenta particles M1 are a positively charged magenta material (dimethylquinacridone, CI Pigment Red 122) coated with vinylbenzyl chloride and LMA as described in Example 5 of U.S. Pat. No. 9,697,778 and U.S. Pat. No. 9,921,451.

[0062] The magenta particles M2 are CI Pigment Red 122, which are coated by dispersion polymerization and incorporate methyl methacrylate and dimethylsiloxane-containing monomers as described in Example 6 of U.S. Patent No. 9,921,451. The cyan particles C1 are copper phthalocyanine materials (CI Pigment Blue 15:3), which are coated by dispersion polymerization and incorporate methyl methacrylate and dimethylsiloxane-containing monomers as described in Example 7 of U.S. Patent No. 9,921,451. In some embodiments, the color gamut has been found to be improved by using Inkjet Yellow 4GC (Clariant) as the core yellow pigment with the incorporation of a methyl methacrylate surface polymer. The zeta potential of this yellow pigment can be adjusted with the addition of 2,2,2-trifluoroethyl methacrylate (TFEM) monomer and monomethacrylate-terminated poly(dimethylsiloxane).

[0063] Additives and surface treatments of electrophoretic media for promoting differential electrophoretic mobility, as well as proposed mechanisms for interactions between the surface treatment and surrounding charge control agents and / or free polymers, are discussed in detail in U.S. Pat. No. 9,697,778, which is incorporated by reference in its entirety. In such electrophoretic media, one way to control interactions between various types of particles is by controlling the type, amount, and thickness of the polymer coating on the particles. For example, to control particle properties so that particle-particle interactions are less between, for example, second type particles and third and fourth type particles than between third type particles and fourth type particles, the second type particles can carry a polymer surface treatment, while the third and fourth type particles can either not carry a polymer surface treatment or can carry a polymer surface treatment with a lower mass coverage per unit area of ​​particle surface than the second type particles. More generally, the Hammerker constant (which is a measure of the strength of the van der Waals interaction between two particles; the pair potential is proportional to the Hammerker constant and inversely proportional to the sixth power of the distance between the two particles) and / or the spacing between the particles needs to be adjusted by judicious selection of the polymer coating on the third type of particles.

[0064] As discussed in U.S. Pat. No. 9,921,451, different types of polymers may include different types of polymer surface treatments. For example, Coulombic interactions may be weakened when the closest distance of approach of oppositely charged particles is maximized by a steric barrier (typically a polymer grafted or adsorbed to the surface of one or both particles). The polymer shell may be a covalently bonded polymer created by grafting or chemisorption, as is well known in the art, or it may be physisorbed onto the particle surface. For example, the polymer may be a block copolymer comprising insoluble and soluble compartments. Alternatively, the polymer shell may be dynamic in that it is a loose network of free polymer from the electrophoretic medium that is complexed with the pigment particle in the presence of an electric field and a sufficient amount and type of charge control agent (CCA—discussed later). Thus, depending on the strength and polarity of the electric field, the particle may have more associated polymer, which may cause the particle to interact differently with the container (e.g., microcapsule or microcell) and other particles. [The extent of the polymer shell is conveniently assessed by thermogravimetric analysis (TGA), a technique in which the temperature of a dried sample of the particle is raised and the mass loss due to thermal decomposition is measured as a function of temperature. Using TGA, the proportion of the particle's mass that is polymer can be measured, which can be converted to a volume fraction using the known densities of the core pigment and the polymer attached thereto.] Conditions can be found under which the polymer coating is lost but the core pigment remains (these conditions depend on the precise core pigment particle used). Various polymer combinations can be made to work as described below with respect to Figures 2A-2E. For example, in some embodiments, a particle (typically the first and / or second particle) can have a covalently attached polymer shell that significantly interacts with the container (e.g., microcell or microcapsule). At the same time, other particles of the same charge either do not have a polymer coating or are complexed with free polymer in solution such that they have fewer interactions with the container.In other embodiments, the particles (typically the first and / or second particles) do not have a surface coating, which would make it easier for the particles to form a charge double layer and undergo reduced electrophoretic mobility in the presence of strong fields.

[0065] The fluid 17, in which the four types of particles are dispersed, is clear and colorless. The fluid contains charged electrophoretic particles, which move through the fluid under the influence of an electric field. A preferred suspending fluid has a low dielectric constant (about 2) and a high volume resistivity (about 10 15 They have a low viscosity (less than 5 mPas), low toxicity and environmental impact, low water solubility (less than 10 ppm (parts per million) if traditional hydrous methods of encapsulation are to be used, however note that this requirement may not be relaxed for non-encapsulated or secure microcell displays), a high boiling point (greater than about 90° C.), and a low refractive index (less than 1.5). The last requirement arises from the use of high refractive index scattering (typically white) pigments, whose scattering efficiency depends on the refractive index mismatch between the particle and the fluid.

[0066] Organic solvents such as saturated linear or branched hydrocarbons, silicone oils, halogenated organic solvents, and low molecular weight halogen-containing polymers are some useful fluids. The fluid may consist of a single component or may be a hybrid of more than one component to tailor its chemical and physical properties. Reactants or solvents for the microencapsulation process, such as oil-soluble monomers, may be contained in the fluid (if used).

[0067] The fluid preferably has a low viscosity and a dielectric constant in the range of about 2 to about 30, preferably about 2 to about 15, for high particle mobility. Examples of suitable dielectric fluids include hydrocarbons such as Isopar®, decahydronaphthalene (DECALIN), 5-ethylidene-2-norbornene, fatty oils, paraffin oil, silicone fluids, aromatic hydrocarbons such as toluene, xylene, phenylxylylethane, dodecylbenzene or alkylnaphthalenes, halogenated solvents such as perfluorodecalin, perfluorotoluene, perfluoroxylene, dichlorobenzotrifluoride, 3,4,5-trichlorobenzotrifluoride, chloropentafluorobenzene, dichlorononane or pentachlorobenzene, perfluorinated solvents such as FC-43, FC-70, or FC-5060 from 3M Company, St. Paul, MN, low molecular weight halogen-containing polymers such as poly(perfluoropropylene oxide) from TCI America, Portland, Oregon, and Halocarbon from Halocarbon Product Corp., River Edge, NJ. and perfluoropolyalkyl ethers such as Galden from Ausimont or Krytox Oils and Greases K-Fluid Series from DuPont, Delaware, polydimethylsiloxane-based silicone oils from Dow-corning (DC-200).

[0068] Electrophoretic media typically contain one or more charge control agents (CCAs) and may also contain charge guide agents. CCAs and charge guide agents typically comprise low-molecular-weight surfactants, polymeric agents, or hybrids of one or more components, and serve to stabilize or otherwise modify the sign and / or magnitude of the charge on the electrophoretic particles. CCAs are typically molecules containing ionic or other polar groups, hereinafter referred to as head groups. At least one of the positive or negative ionic head groups is preferably attached to a nonpolar chain (typically a hydrocarbon chain), hereinafter referred to as a tail group. CCAs form reverse micelles within the internal phase, and it is believed that it is the small population of charged reverse micelles that leads to conductivity in the ultra-nonpolar fluids typically used as electrophoretic fluids.

[0069] The addition of CCA results in the production of reverse micelles, which contain a highly polar core, which can vary in size from 1 nm to tens of nanometers (and can have spherical, cylindrical, or other geometric shapes), surrounded by the nonpolar tail groups of the CCA molecules. Three phases can typically be distinguished in electrophoretic media: solid particles with surfaces, highly polar phases (reverse micelles) distributed in the form of tiny droplets, and a continuous phase containing fluid. Both charged particles and charged reverse micelles can move through the fluid in response to the application of an electric field; thus, two parallel paths exist for electrical conduction through the fluid (which itself typically has a negligible conductivity, approaching zero).

[0070] The polar core of the CCA is thought to affect the charge on the surface by adsorption onto the surface. In electrophoretic displays, such adsorption occurs on the surface of electrophoretic particles or the inner walls of microcapsules (or other solid phases, such as the walls of microcells) to form structures similar to reverse micelles; these structures are hereafter referred to as hemimicelles. When one ion of an ion pair is more firmly attached to the surface than the other (e.g., by covalent bonding), ion exchange between the hemimicelle and the unbound reverse micelle can lead to charge separation, in which the more firmly bound ion remains associated with the particle and the less firmly bound ion becomes incorporated into the core of the free reverse micelle.

[0071] It is also possible that the ionic material forming the head group of the CCA can induce ion pairing on the particle (or other) surface. Thus, the CCA can perform two basic functions: charge generation on the surface and charge separation from the surface. Charge generation can result from acid-base or ion exchange reactions between some moieties present in the CCA molecule or otherwise incorporated into the reverse micelle core or fluid and the particle surface. Therefore, useful CCA materials are those that can participate in such reactions or any other charge reactions known in the art.

[0072] Non-limiting classes of charge control agents useful in the media of the present invention include organic sulfates or sulfonates, metal soaps, block or comb copolymers, organic amides, organic zwitterions, and organic phosphates and phosphonates. Useful organic sulfates and sulfonates include, but are not limited to, sodium bis(2-ethylhexyl) sulfosuccinate, calcium dodecylbenzene sulfonate, calcium petroleum sulfonate, neutral or basic barium dinonylnaphthalene sulfonate, neutral or basic calcium dinonylnaphthalene sulfonate, dodecylbenzene sulfonic acid sodium salt, and ammonium lauryl sulfate. Useful metal soaps include, but are not limited to, basic or neutral barium petronate, calcium petronate, cobalt, calcium, copper, manganese, magnesium, nickel, zinc, aluminum, and iron salts of carboxylic acids such as naphthenic acid, octanoic acid, oleic acid, palmitic acid, stearic acid, myristic acid, and the like. Useful block or comb copolymers include, but are not limited to, (A) an AB diblock copolymer of a polymer of 2-(N,N-dimethylamino)ethyl methacrylate quaternized with methyl p-toluenesulfonate and (B) poly(2-ethylhexyl methacrylate), and a comb graft copolymer having a molecular weight of about 1,800 with an oil-soluble tail of poly(12-hydroxystearic acid) pendant on an oil-soluble anchor group of poly(methyl methacrylate-methacrylic acid). Useful organic amides / amines include, but are not limited to, polyisobutylene succinimides such as OLOA371 or 1200 (available from Chevron Oronite Company LLC, Houston, Tex.), or SOLSPERSE 17000 or 19000 (available from Lubrizol, Wickliffe, Ohio; Solsperse is a registered trademark), and N-vinylpyrrolidone polymers. Useful organic zwitterions include, but are not limited to, lecithin. Useful organic phosphates and phosphonates include, but are not limited to, sodium salts of phosphorylated mono- and di-glycerides with saturated and unsaturated acid substituents.Useful tail groups for CCAs include polymers of olefins, such as poly(isobutylene), with molecular weights ranging from 200 to 10,000. The head group may be a sulfonic, phosphoric, or carboxylic acid, or an amide, or alternatively, an amino group, such as a primary, secondary, tertiary, or quaternary ammonium group. One class of CCAs useful in the disclosed four-particle electrophoretic media is disclosed in U.S. Patent Publication No. 2017 / 0097556, which is incorporated herein by reference in its entirety. Such CCAs typically contain a quaternary amine head group and an unsaturated polymer tail, i.e., at least one C-C double bond. The polymer tail is typically a fatty acid tail. A variety of CCA molecular weights can be used. In some embodiments, the molecular weight of the CCA is 12,000 g / mole or greater, for example, 14,000 g / mole to 22,000 g / mole.

[0073] The charge adjuvant used in the media of the present invention can bias the charge on the electrophoretic particle surface, as described in more detail below. Such charge adjuvant may be a Bronsted or Lewis acid, or a base. Exemplary charge adjuvant agents are disclosed in U.S. Patent Nos. 9,765,015, 10,233,339, and 10,782,586, all of which are incorporated by reference in their entireties. Exemplary charge adjuvant agents may include polyhydroxy compounds containing at least two hydroxyl groups, including, but not limited to, ethylene glycol, 2,4,7,9-tetramethyldecyne-4,7-diol, poly(propylene glycol), pentaethylene glycol, tripropylene glycol, triethylene glycol, glycerol, pentaerythritol, glycerol tris(12-hydroxystearate), propyleneglycerol monohydroxystearate, and ethylene glycol monohydroxystearate. Examples of aminoalcohol compounds containing at least one alcohol function and one amine function in the same molecule include, but are not limited to, triisopropanolamine, triethanolamine, ethanolamine, 3-amino-1-propanol, o-aminophenol, 5-amino-1-pentanol, and tetrakis(2-hydroxyethyl)ethylenediamine. In some embodiments, the charge adjuvant is present in the electrophoretic display medium in an amount of from about 1 to about 500 milligrams per gram of particle mass ("mg / g"), more preferably from about 50 to about 200 mg / g.

[0074] Particle dispersion stabilizers may be added to prevent particle aggregation or attachment to capsules or other walls or surfaces. For typical high-resistivity liquids used as fluids in electrophoretic displays, non-water-containing surfactants may be used. These include, but are not limited to, glycol ethers, acetylene glycols, alkanolamides, sorbitol derivatives, alkylamines, quaternary amines, imidazolines, dialkyl oxides, and sulfosuccinates.

[0075] As explained in U.S. Patent No. 7,170,670, the bistability of electrophoretic media can be improved by including in the fluid a polymer with an average molecular weight greater than about 20,000, which is essentially non-absorbent on the electrophoretic particles; poly(isobutylene) is a preferred polymer for this purpose. Also, as explained, for example, in U.S. Patent No. 6,693,620, particles with immobilized charges on their surfaces establish an electrical double layer of opposite charge in the surrounding fluid. The ionic head groups of the CCA may ion-pair with charged groups on the electrophoretic particle surface, forming a layer of immobilized or partially immobilized charged species. Outside this layer, there is a diffusion layer comprising charged (reverse) micelles comprising CCA molecules in the fluid. In conventional DC electrophoresis, an applied electric field exerts a force on the fixed surface charge and an opposing force on the mobile countercharge, causing sliding within the diffusion layer and causing the particles to move relative to the fluid. The potential at the sliding plane is known as the zeta potential.

[0076] As a result, some particle types within an electrophoretic medium have different electrophoretic mobilities across the medium, depending on the strength of the electric field. For example, when a first (low-strength, i.e., about ±10 V or less) electric field is applied to the electrophoretic medium, the first type of particles move in one direction relative to the electric field; however, when a second (high-strength, i.e., about ±20 V or more) electric field with the same polarity as the first electric field is applied, the first type of particles begin to move in the opposite direction relative to the electric field. This behavior is theorized to result from conduction in a highly nonpolar fluid mediated by charged reverse micelles or countercharged electrophoretic particles. Thus, any electrochemically generated protons (or other ions) are likely transported through the nonpolar fluid within the micelle core or adsorbed onto the electrophoretic particles. For example, as illustrated in Figure 5B of U.S. Patent No. 9,697,778, a positively charged reverse micelle approaches a negative electrophoretic particle traveling in the opposite direction, and the reverse micelle can incorporate into an electrical double layer around the negatively charged particle (the electrical double layer includes both a diffuse layer of charge with enhanced counterion concentration and a hemimicelle surface adsorption coating on the particle; in the latter case, the reverse micelle charge would be associated with the particle within the sliding envelope, defining the particle's zeta potential, as mentioned above). Through this mechanism, an electrochemical current of positively charged ions flows through the electrophoretic fluid, and the negatively charged particle can become biased toward a more positive charge. As a result, for example, the electrophoretic mobility of a first, negative type of particle is a function of the magnitude of the electrochemical current and the residence time of the positive charge near the particle surface, which is a function of the strength of the electric field.

[0077] Furthermore, as described in U.S. Patent No. 9,697,778, positively charged particles can also be prepared to exhibit different electrophoretic mobilities depending on the applied electric field. In some embodiments, a secondary (or co-)CCA can be added to the electrophoretic medium to adjust the zeta potential of various particles. The selection of the co-CCA allows for the modification of the zeta potential of one particle while leaving the zeta potential of other particles essentially unchanged, allowing for careful control of both the electrophoretic velocity of various particles and the interactions between particles during switching.

[0078] In some embodiments, a portion of the charge control agent intended for the final formulation is added during the synthesis of electrophoretic particles to engineer the desired zeta potential and affect the reduction in electrophoretic mobility due to a strong electric field. For example, it has been observed that adding a quaternary amine charge control agent during polymer grafting results in a certain amount of CCA being complexed to the particles. (This can be confirmed by removing the particles from the electrophoretic fluid to remove all adsorbed species, followed by stripping the surface species from the pigment with THF. When the THF extraction is evaluated by 1H NMR, it is clear that a significant amount of CCA has been adsorbed to the pigment particles or complexed with the surface polymer.) Experiments suggest that high CCA loading between the surface polymers of the particles promotes the formation of a charge double layer around the particles in the presence of a strong electric field. For example, magenta particles having more than 200 mg of charge control agent (CCA) per gram of finished magenta particles have excellent retention properties in the presence of high positive electric fields (see, e.g., FIG. 2C and the discussion above). In some embodiments, the CCA comprises a quaternary amine head group and a fatty acid tail. In some embodiments, the fatty acid tail is unsaturated. When some of the particles in the electrophoretic medium contain high CCA loadings, it is important that particles for which consistent electrophoretic mobility is desired do not have much CCA loading, e.g., less than 50 mg of charge control agent (CCA) per gram of finished particles, e.g., less than 10 mg of charge control agent (CCA) per gram of finished particles.

[0079] In another embodiment, an electrophoretic medium containing four types of particles benefits from the addition of a small amount of an acidic entity, such as the aluminum salt of di-t-butyl salicylic acid (Bontron E-88, available from Orient Corporation, Kenilworth, NJ), in the presence of Isopar E's Solsperse 17000. The addition of an acidic material shifts the zeta potential of many (but not all) particles to more positive values. In one embodiment, about 1% of the acidic material and 99% of Solsperse 17000 (based on the total weight of the two materials) shifts the zeta potential of the third type of particles (Y+) from -5 mV to about +20 mV. Whether the zeta potential of a particular particle is altered by a Lewis acidic material such as an aluminum salt will depend on the details of the particle's surface chemistry.

[0080] Table 2 shows exemplary relative zeta potentials for three types of colored particles and only one white particle in a preferred embodiment. [Table 2]

[0081] In one embodiment, the negative (white) particles have a zeta potential of -30 mV, and the remaining three particles are all positive relative to the white particles. Thus, a display comprising positive cyan, magenta, and yellow particles can switch between a black state (where all colored particles are in front of the white particles relative to the viewing surface) and a white state, with the white particles closest to the viewer and blocking the viewer's perception of the remaining three particles. In contrast, when the white particles have a zeta potential of 0 V, the negatively charged yellow particles are the most negative of all particles, and therefore a display comprising these particles will switch between a yellow color state and a blue color state. This would also occur if the white particles were positively charged. However, the positively charged yellow particles will be more positive than the white particles unless their zeta potential exceeds +20 mV.

[0082] This behavior of the electrophoretic medium of the present invention is consistent with the mobility of the white particles (expressed in Table 2 as zeta potential), which depends on the applied electric field. Thus, in the example illustrated in Table 2, when addressed with a low voltage, the white particles may behave as if their zeta potential were -30 mV, but when addressed with a higher voltage, they may behave as if their zeta potential were more positive, perhaps as high as +20 mV (corresponding to the zeta potential of the yellow particles). Thus, when addressed with a low voltage, the display will switch between black and white states, but when addressed with a higher voltage, it will switch between blue and yellow color states.

[0083] The motion of various particles in the presence of high (e.g., "±H," e.g., ±20 V, e.g., ±25 V) and low (e.g., "±L," e.g., ±5 V, e.g., ±10 V) electric fields is shown in Figures 2B-2E. For illustrative purposes, each box bounded by a dashed line represents a pixel bounded by a top light-transmitting electrode 21 and a bottom electrode 22, which may be an active matrix pixel electrode; however, it may also be a light-transmitting electrode or a segmented electrode, etc. Starting from a first state in which all of the positive particles are present at the viewing surface (nominally black), the electrophoretic medium can be driven into four different optical states, as shown in Figures 2B-2E. In a preferred embodiment, this results in a white optical state (Figure 2B), a magenta optical state (Figure 2C), a yellow optical state (Figure 2D), and a red optical state (Figure 2E). It is clear that the remaining four optical states of FIG. 1 can be achieved by reversing the sequence of the initial states and the driving electric fields, as shown in the abbreviated representation of FIG.

[0084] When addressed with a low voltage, as in FIG. 2B, the particles behave according to their relative zeta potentials, with relative velocities illustrated by the arrows for when a negative voltage is applied to the backplane. Thus, in this example, the cyan particles move faster than the yellow particles, which move faster than the magenta particles. The first (positive) pulse does not change the particle positions because the particles are already constrained by the enclosure walls. The second (negative) pulse swaps the positions of the colored and white particles, so the display switches between black and white states, with the transition color reflecting the relative mobility of the colored particles. Reversing the starting position and the polarity of the pulse allows a white-to-black transition. Thus, this embodiment provides a black-to-white update that requires lower voltages (and consumes less power) compared to other black and white formulations achieved with multiple colors, either via process black or process white.

[0085] In Figure 2C, the first (positive) pulse is a high positive voltage sufficient to reduce the mobility of the magenta particles (i.e., the particles with the intermediate mobility of the three positively charged colored particles). Due to their reduced mobility, the magenta particles essentially remain frozen in place, and a subsequent pulse in the opposite direction at a lower voltage moves the cyan, white, and yellow particles more than the magenta particles, thereby producing magenta at the viewing surface with the negative white particles behind the magenta particles. Importantly, if the starting position and polarity of the pulses are reversed (equivalent to viewing the display from the opposite side of the viewing surface, i.e., through electrode 22), this pulse sequence will produce green (i.e., a mixture of yellow and cyan particles).

[0086] In Figure 2D, the first pulse is a low voltage that does not significantly reduce the mobility of either the magenta or white particles. However, the second pulse is a high negative voltage that reduces the mobility of the white particles. This allows for more effective competition between the three positive particles, so that the slowest type of particle (yellow in this example) remains visible in front of the white particles, whose mobility was reduced using the previous negative pulse. In particular, the yellow particles do not reach the top surface of the cavity containing the particles. Importantly, if the starting position and polarity of the pulses are reversed (equivalent to viewing the display from the opposite side of the viewing surface, i.e., through electrode 22), this pulse sequence will produce a blue color (i.e., a mixture of magenta and cyan particles).

[0087] Finally, Figure 2E shows that when both pulses are at a high voltage, the mobility of the magenta particles will be reduced by the first, high positive pulse, and the competition between cyan and yellow will be intensified by the reduction in white mobility caused by the second, high negative pulse. This produces red. Importantly, if the starting position and polarity of the pulses are reversed (equivalent to viewing the display from the opposite side of the viewing surface, i.e., through electrode 22), this pulse sequence will produce cyan.

[0088] To obtain a high-resolution display, each pixel of the display must be addressable without interference from neighboring pixels. One way to achieve this goal is to provide an array of nonlinear elements, such as transistors or diodes, with at least one nonlinear element associated with each pixel to produce an "active matrix" display. The addressing or pixel electrode that addresses a pixel is connected to an appropriate voltage source through the associated nonlinear element. Typically, when the nonlinear element is a transistor, the pixel electrode is connected to the drain of the transistor; although this arrangement will be assumed in the following description, it is essentially arbitrary; the pixel electrode may also be connected to the source of the transistor. Conventionally, in high-resolution arrays, the pixels are arranged in a two-dimensional array of rows and columns, such that any particular pixel is uniquely defined by the intersection of one defined row and one defined column. The sources of all transistors in each column are connected to a single column electrode, while the gates of all transistors in each row are connected to a single row electrode. Again, the assignment of sources to rows and gates to columns is conventional, but essentially arbitrary and can be reversed as desired. The row electrodes are connected to row drivers, which essentially ensure that at any given moment, only one row is selected; i.e., a select voltage is applied to the selected row electrode to ensure that all transistors in the selected row are conductive, while a non-select voltage is applied to all other rows to ensure that all transistors in those non-selected rows remain non-conductive. The column electrodes are connected to column drivers, which place selected voltages on the various column electrodes to drive the pixels in the selected row to their desired optical states (these voltages are conventionally relative to a common front electrode provided opposite the non-linear array of electro-optic medium and extending across the entire display). After a preselected interval known as the "line address time," the selected row is deselected, the next row is selected, and the voltages on the column drivers are changed so that the next line of the display is written.This process is repeated so that the entire display is written in a row-by-row fashion.

[0089] Conventionally, each pixel electrode has a capacitor electrode associated with it, such that the pixel electrode and the capacitor electrode form a capacitor. See, for example, International Patent Application No. WO 01 / 07961. In some embodiments, an N-type semiconductor (e.g., amorphous silicon) may be used to form the transistor, and the "select" and "unselect" voltages applied to the gate electrode can be positive and negative, respectively.

[0090] FIG. 3 of the accompanying drawings depicts an exemplary equivalent circuit of a single pixel of an electrophoretic display. As shown, the circuit includes a capacitor 10 formed between the pixel electrode and a capacitor electrode. An electrophoretic medium 20 is represented as a parallel capacitor and resistor. In some cases, direct or indirect coupling capacitance 30 (commonly referred to as "parasitic capacitance") between the gate electrode of a transistor associated with the pixel and the pixel electrode can introduce undesirable noise into the display. Typically, the parasitic capacitance 30 is much smaller than that of the storage capacitor 10, and when a pixel row of the display is selected or deselected, the parasitic capacitance 30 can introduce a slight negative offset voltage, also known as a "kickback voltage," on the pixel electrode, which is typically less than 2 volts. In some embodiments, to compensate for the undesirable "kickback voltage," V com is the kickback voltage (V KB ), all voltages supplied to the display are offset by the same amount so that no net DC imbalance can be experienced. com may be supplied to the top plane electrode and capacitor electrode associated with each pixel.

[0091] However, V comProblems can arise when V is set to a voltage that is not compensated for kickback voltage. This can occur when it is desired to apply a higher voltage to the display than is available from the backplane alone. For example, the maximum voltage applied to the display may be higher than V, while the backplane may be supplied with a choice of, for example, nominal +V, 0, or -V. com It is well known in the art that if V is supplied with -V, it may be doubled. The maximum voltage experienced in this case is +2V (i.e., at the backplane relative to the topplane), while the minimum voltage is zero. If a negative voltage is required, V com The potential must be raised to at least zero. The waveforms used to address displays with positive and negative voltages using top-plane switching must therefore be raised to above one V com Each voltage setting must have a specific frame allocated to it.

[0092] A set of waveforms for driving a color electrophoretic display having four particles is described in U.S. Pat. No. 9,921,451, which is incorporated herein by reference. In U.S. Pat. No. 9,921,451, seven different voltages are applied to the pixel electrodes: three positive, three negative, and zero. However, in some embodiments, the maximum voltages used in these waveforms are higher than can be handled by amorphous silicon thin-film transistors. In such cases, suitable high voltages can be obtained by using top-plane switching. (As explained above) V com But V KB However, when top-plane switching is used, V com Using as many separate power supplies as there are settings is costly and inconvenient. Additionally, top-plane switching is known to increase kickback, thereby degrading color state stability.

[0093] Display devices may be constructed using the electrophoretic fluid of the present invention in several ways known in the prior art. The electrophoretic fluid may be encapsulated in microcapsules or incorporated into a microcell structure, which is then sealed with a polymer layer. The microcapsule or microcell layer may be coated or embossed onto a plastic substrate or film carrying a transparent coating of conductive material. The assembly may be laminated to a backplane carrying pixel electrodes using a conductive adhesive. Alternatively, the electrophoretic fluid may be dispensed directly onto a thin, continuous cell grid arranged on a backplane, containing the active matrix of pixel electrodes. The filled grid may then be top-sealed with an integrated protective sheet / light-transmitting electrode.

[0094] FIG. 4 shows a schematic cross-sectional drawing (not to scale) of a display structure 200 suitable for use with the present invention. In display 200, the electrophoretic fluid is shown confined in microcells, although equivalent structures incorporating microcapsules can also be used. A substrate 202, which can be glass or plastic, carries pixel electrodes 204, which are either individually addressed sections or associated with thin-film transistors in an active matrix array (the combination of substrate 202 and electrodes 204 is conventionally referred to as the display backplane). Layer 206 is an optional dielectric layer according to the present invention that is applied to the backplane (methods of depositing suitable dielectric layers are described in U.S. patent application Ser. No. 16 / 862,750, which is incorporated by reference). The display front plane comprises a transparent substrate 222 carrying a transparent conductive coating 220. The overlying electrode layer 220 is optional dielectric layer 218. Layer (or layers) 216 is a polymer layer that may comprise a primer layer for adhesion of the microcell to the transparent electrode layer 220, with some residual polymer forming the bottom of the microcell. The walls of the microcell 212 are used to contain the electrophoretic fluid 214. The microcell is sealed together with layer 210, and the entire frontplane structure is adhered to the backplane using a conductive adhesive layer 208. Processes for forming microcells are described in the prior art, for example, in U.S. Pat. No. 6,930,818. In some cases, the microcell is less than 20 μm deep, e.g., less than 15 μm deep, e.g., less than 12 μm deep, e.g., about 10 μm deep, e.g., about 8 μm deep.

[0095] Most commercial electrophoretic displays use amorphous silicon-based thin film transistors (TFTs) in the construction of their active matrix backplanes (202 / 204) due to the wider availability of processing equipment and the cost of various starting materials. Unfortunately, amorphous silicon thin film transistors become unstable when supplied with gate voltages that would allow switching voltages greater than approximately ±15V. Nevertheless, as explained below, ACeP performance is improved when high positive and negative voltage magnitudes are allowed to exceed ±15V. Therefore, as explained in the previous disclosure, improved performance is achieved by additionally varying the bias of the top light-transmitting electrode relative to the bias on the backplane pixel electrodes, also known as top-plane switching. Thus, if a voltage of +30V (relative to the backplane) is required, the top plane can be switched to −15V, while the appropriate backplane pixels are switched to +15V. Methods for driving four-particle electrophoresis systems using top-plane switching are described in more detail, for example, in US Pat. No. 9,921,451.

[0096] These waveforms indicate that each pixel on the display is high , +V low , 0, -V low , and -V high and illustrated as 30V, 15V, 0, -15V, and -30V. In practice, it may be preferable to use more addressing voltages. high , 0, and -V high ) is available, the voltage V high pulses of 1 / n, but with a duty cycle of 1 / n, to a lower voltage (e.g., V high / n, where n is a positive integer >1), it may be possible to achieve the same result as addressing in

[0097] FIG. 5 shows typical waveforms (in simplified form) used to drive the four-particle color electrophoretic display system described above. Such waveforms have a "push-pull" structure, i.e., they consist of a dipole with two pulses of opposite polarity. The magnitude and length of these pulses determine the color obtained. At a minimum, five such voltage levels should be present. FIG. 5 shows high and low positive and negative voltages as well as zero volts. Typically, "low" (L) refers to a range of about 5 to 15 volts, while "high" (H) refers to a range of about 15 to 30 volts. Generally, the higher the magnitude of the "high" voltage, the better the color gamut achieved by the display. In some embodiments, an additional "medium" (M) level is used, which is typically about 15 volts; however, the value for M will depend somewhat on the particle composition and the environment of the electrophoretic medium. In many of the waveforms shown below, +V high / -V high = ±24V, +V med / -V med = ±17V, and +V low / -V low =±10V, which is achieved using a power management integrated circuit (PMIC) and a drive backplane incorporating metal oxide transistors such as IGZO, i.e., as discussed above. Suitable controllers are commercially available for incorporation into the displays of the present invention, such as the UltraChip UC8152c or UC8159c, or the Solomon Systech SPD1656.

[0098] While Figure 5 shows the simplest dipoles required to produce color, it will be understood that practical waveforms may be multiple repetitions of these patterns, or other patterns that are aperiodic, and may use more than five voltage levels. Typically, such waveforms are shown as frames, i.e., a series of impulses corresponding to the amount of time between new cycles of gate opening for the TFTs of an active matrix array. Thus, for example, Figures 9A-10B include frame numbers, and it will be understood that each frame represents approximately 20 ms. However, the size of each frame may vary, for example, due to larger arrays or faster transistors.

[0099] Of course, achieving a desired color using the drive pulses of FIG. 5 depends on starting the process from a known state, which is unlikely to be the final color displayed on the pixel. Therefore, a series of reset pulses precedes the drive pulse, which increases the amount of time required to update the pixel from a first color to a second color. Reset pulses are described in more detail in U.S. Pat. No. 10,593,272, which is incorporated by reference. The lengths of these pulses (refresh and address) and any rest periods (i.e., periods of zero voltage between them) may be selected so that the entire waveform (the integral of voltage with respect to time over the entire waveform) is DC-balanced (i.e., the integral of voltage over time is substantially zero). DC balance can be achieved by adjusting the lengths of the pulses and rest periods in the reset phase so that the net impulse delivered in the reset phase is equal in magnitude and opposite in sign to the net impulse delivered in the address phase, during which the display switches to a particular desired color. However, as shown in Figures 2B-2E, the starting states for the eight primary colors are either black or white states, which can be achieved with sustained low-voltage drive pulses. The simplicity of achieving this starting state also reduces the update time between states, which is more satisfying to the user, and also reduces the amount of power consumed (thus increasing battery life).

[0100] Additionally, the preceding discussion of waveforms, and specifically the DC balance discussion, ignores the issue of kickback voltage. In practice, as described above, all backplane voltages are subject to a kickback voltage V KB The voltage supplied by the power supply is offset by an amount equal to V. Thus, if the power supply being used provides three voltages, +V, 0, and -V, the backplane will actually receive a voltage equal to V+V. KB , V KB , and -V +V KB will receive (V KB (Note that V is typically a negative number for amorphous silicon TFTs.) However, the same power supply will supply +V, 0, and -V to the front electrode without any kickback voltage offset. So, for example, when the front electrode is supplied with -V, the display will only supply a maximum voltage of 2V +V KB and minimum voltage V KB Using a separate power supply would be costly and inconvenient. KB Instead of supplying V to the front electrode, the waveform changes so that the front electrode is supplied with a positive voltage, a negative voltage, and V KB may be divided into sections.

[0101] An exemplary workflow of the controller is shown in Figure 6. The above workflow represents a conventional workflow for a two-particle system as described in U.S. Patent No. 9,672,766, in which the black / white and white / black transitions in GC mode are nearly symmetrical. Therefore, it is very easy to switch between GC mode and DU mode as required depending on the use case (e.g., menu, scrolling, stylus writing, etc.). There is almost no buildup of impulse potential, and therefore, there is no need for intermediate transition modes in a two-particle system.

[0102] However, in some multi-particle systems, such as ACeP®, the electrophoretic medium suffers from large blooming-based afterimages when symmetric white / black and black / white transitions are used in GC mode. Therefore, the GC waveform is asymmetric when conventional transition rules are used, resulting in impulse potential buildup when the device is switched to DU (direct update) mode. However, using the present invention, i.e., as illustrated in the lower workflow of Figure 6, when switching between GC mode and DU mode for a multi-particle system, transition modes (DU_IN; DU_OUT) are used to compensate for unbalanced impulse potentials when moving between black and white states in GC mode. In one embodiment, DU (direct update) mode sets the black and white states to very high impulse potentials (approximately 400 V*frame), thereby achieving a good black state and balanced impulse potentials when the display operates in DU mode. Essentially, the present invention keeps the black state impulse potential consistent between DU and GC modes, while driving the white state in DU mode with the same and opposite impulse potential as the black state, allowing the white state to remain optically matched, but not impulse potential matched, when transitioning between GC and DU modes.

[0103] A generalized visualization of the DUin and DUout modes is shown in FIG. 7. In FIG. 7, a series of GC states are shown transitioning to DU mode via a set of DUin waveforms, each compensating for the impulse difference. Furthermore, when leaving DU mode, the display transitions back to GC mode via a DUout waveform, i.e., in DUout mode. The diagram in FIG. 7 is general purpose and equally well suited for GC modes including 8, 16, 32, 64, or more color states. In most cases, the DU mode will include only a white state and a black state; however, with the right selection of colored particles, alternative DU modes, for example, using green and white as DU states, can also be achieved.

[0104] An exemplary waveform suitable for DU mode in a four-particle ACEP® system, including a negative white particle and three (differently charged) positive particles of cyan, yellow, and magenta, is shown in FIG. 8. While the waveforms are not symmetrical (or opposite), the accumulated impulse (voltage*frame) is approximately 400V*frame for both the white-to-black transition (top right waveform) and the black-to-white transition (bottom left waveform). Thus, as the pixel transitions between white and black in DU mode, there will be little accumulated impulse potential. In some embodiments, duK and duW are distinct controller states, i.e., transitions that A) maintain reciprocal balance and b) match optical performance with the corresponding GC optical state. Furthermore, due to the high voltage drive for most of the DU waveforms, it is possible to achieve black-to-white or white-to-black pixel updates within approximately 250 ms. While this is still slightly slower than the best black and white (only) electrophoretic displays, this update time is sufficient for page turning and stylus input.

[0105] As discussed above, the need for transition modes (DU_IN; DU_OUT) exists to allow the display to move between GC mode and DU mode without excessive impulse potentials that can manifest as afterimages and shorten the life of the backplane electronics. The structure imposed on these transitions is such that when using DUin, the transition to duK is direct, i.e., no flash effect, and is a single pulse, while optical state matching between duK and K is enforced. In contrast, conventional DU mode keeps K→K as an empty transition. In the DUin scheme, duK→duK is empty, but K→duK is filled in with a direct transition, as shown in FIG. 9A. FIG. 9A shows a set of potential transition waveforms for DU_IN, with voltage on the y-axis and frame number on the x-axis. It is noteworthy that many of the transitions are actually empty, i.e., no pulse is delivered. Generally, DUin, intended to be applied when transitioning between text-mode states (K, GT2, GT3, W) and DU states (duK, duW), applies a net impulse to the transition equal to the duK impulse potential to become duK. This is because the impulse potential of K in GC mode is zero due to the associated clearing pulse. The impulse potential of the W state in GC is also zero. All transitions between white states are selected to maintain a zero net impulse potential. Finally, the transition from gray tones to DU black and white preserves the original text-mode net impulse potential. To get a sense of the actual optical transitions experienced, the waveform in Figure 9A was run on a simulator of a four-particle ACEP® system containing a negative white particle and three (differently charged) positive particles in cyan, yellow, and magenta. The resulting transitions are seen in Figure 9B. For empty transitions, there is no color change. However, for some transitions, such as GC2 to duK and GC2 to duW, the display will "flash" a bright color (e.g., red, blue) for a few frames. However, because the DUin transition is about 365 ms, the color transition is not very noticeable.10A and 10B show various waveform embodiments that can be used to transition from DU to GC, i.e., in DU_OUT mode. Again, some of the transitions, such as duK to GC2, will transition through light colors, but the transitions are fast and therefore not noticeable.

[0106] Round-trip impulse balance from GC mode to DU mode and back is preserved by tailoring the DU_out transition to have a specific net impulse potential. In particular, transitions between DU states (duK, duW) and GC mode states (K, GC2, GC3, W) have a net impulse potential equal to negative duK IP, as shown in FIG. 10A. Transitions from duW to W / K have a net impulse of 0. In general, all transitions from DU states to GC states using DU_out will appear to be switching to white before they transition to a text mode state, as can be seen in FIG. 10B. A full transition from DU to GC using DU_OUT is typically approximately 576 ms.

[0107] An example of impulse potential calculation is shown in FIG. 11. In FIG. 11, four display pixels are represented as squares in the upper box, and the matrix for impulse potential balance is shown in the lower box (i.e., the lower box is not a pixel). The starting and final states are GC mode, with two black pixels on top and two white pixels on the bottom. As shown in the leftmost square, the four pixels end the last GC update with an impulse potential of zero. In DU mode, represented by the two lower matrices in the middle, an impulse of +1 results from the duW to duK transition, while an impulse of -1 results from the duK to duW transition. It should be understood that +1 and -1 are arbitrary units. Using the waveforms of FIG. 8, +1 would correspond to approximately 400V*frame. The important point is that in DU mode, the transitions are of the same impulse potential and opposite sign.

[0108] However, to accommodate the DU mode calculations, the transition from K, the black state in GC mode, to duK in DU mode must also incur a +1 impulse potential. This is shown in the bottom-left matrix. This is not intuitive. In most prior art, the transition between black states from GC to DU does not have any additional impulse added to the pixel. The transition from W to duK also requires a +1 impulse potential, which is not surprising since the pixel's color state must change. Nevertheless, this amount of impulse would not normally be required to drive from white to black, but would be necessary for the increased impulse potential used to switch between states in DU mode. As can be seen from the three boxes in the center of the pixel, as the pixel moves between black and white in DU mode, the impulse potential cycles until it is time to switch back to GC mode. At this point, any remaining impulse potential needs to be eliminated to eliminate afterglow in GC mode. Thus, the DUout matrix indicates that an impulse potential of -1 is required to move from duK to either black or white.

[0109] From the foregoing, it will be seen that the transitional driving mode method of the present invention can provide improved refresh rates for color electrophoretic displays, thereby enabling device designers to create more interactive applications and thus increase the usefulness of devices containing such displays. It will be apparent to those skilled in the art that numerous changes and modifications can be made in the specific embodiments of the invention described above without departing from the scope of the invention. Accordingly, the entirety of the foregoing description should be interpreted in an illustrative sense, and not in a limiting sense.

Claims

1. 1. A method of driving an electrophoretic display having a plurality of pixels, each pixel capable of displaying at least three optical states including white, black, and a color neither white nor black, the method comprising: driving the electrophoretic display using a first driving mode that allows transitions between all of the optical states; driving the electrophoretic display using a second drive mode involving only transitions between black and white optical states, wherein in the second drive mode an impulse potential experienced by a pixel going from the white state to the black state is equal and opposite to an impulse potential experienced by a pixel going from the black state to the white state; driving the electrophoretic display using a first transition mode that enables a transition from the color state in the first drive mode to the white state or the black state in the second drive mode, the first transition mode compensating for excess impulse potential that would be delivered to the pixel in the second drive mode; driving the electrophoretic display using a second transition mode that enables a transition from the white state or the black state of the second drive mode to the color state of the first drive mode, the second transition mode compensating for an excessive impulse potential delivered to the pixel in the second drive mode; A method comprising:

2. 2. The method of claim 1, wherein in the first driving mode, the impulse potential experienced by a pixel going from the white state to the black state is not equal to the impulse potential experienced by a pixel going from the black state to the white state, and vice versa.

3. 2. The method of claim 1, wherein the first transition mode and the second transition mode do not have identical impulse potential compensation between the color state of the first drive mode and the white state of the second drive mode and between the color state of the first drive mode and the black state of the second drive mode.

4. 2. The method of claim 1 , wherein the first transition mode and the second transition mode do not have identical waveforms between the color state of the first drive mode and the white state of the second drive mode and between the color state of the first drive mode and the black state of the second drive mode.

5. 2. The method of claim 1, wherein in the second drive state, a waveform causing a transition from the white state to the black state includes at least five frames of maximum positive voltage.

6. 2. The method of claim 1, wherein in the second drive state, a waveform causing a transition from the black state to the white state includes at least five frames of maximum negative voltage.

7. The method of claim 1 , wherein the first drive mode is DC balanced.

8. The method of claim 1 , wherein the first and second transition modes are not DC balanced.

9. 2. The method of claim 1, wherein each pixel is capable of displaying at least eight optical states, and wherein the first transition mode enables a transition from each of the six non-black and non-white optical states to the white state or the black state of the second drive mode.

10. The method of claim 9 , wherein the eight optical states are black, white, red, magenta, yellow, green, cyan, and blue.

11. A display controller configured to perform the method of claim 1.

12. 10. An electrophoretic display configured to implement the method of claim 1.

13. 13. The display of claim 12, wherein the electrophoretic display comprises an electrophoretic medium comprising at least three types of particles having different electrophoretic mobilities.

14. 14. The display of claim 13, wherein at least two of the three types of particles have the same electric charge but different charge magnitudes.

15. 14. The display of claim 13, wherein one of the particle types is negatively charged and white in color.

16. 16. The display of claim 15, further comprising three types of positively charged particles, each type of positively charged particle being partially light absorbing and different in color from the other types of positively charged particles.

17. 13. The display of claim 12, wherein the electrophoretic medium is confined within a plurality of capsules or a plurality of microcells.

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