Ethylene glycol copolymer polybutylene terephthalate composition and method for producing the same

The production of ethylene glycol copolymerized polybutylene terephthalate addresses variability in crystallization rates and moldability issues by utilizing residual ethylene glycol, resulting in improved molding efficiency and material properties.

JP2026104246APending Publication Date: 2026-06-25MITSUBISHI CHEM CORP

Patent Information

Authority / Receiving Office
JP · JP
Patent Type
Applications
Current Assignee / Owner
MITSUBISHI CHEM CORP
Filing Date
2024-12-13
Publication Date
2026-06-25

AI Technical Summary

Technical Problem

Existing PBT compositions face issues with variability in material properties, moldability, and productivity due to inconsistent crystallization rates during injection molding, which are exacerbated by the need for additional processing steps to remove residual ethylene glycol (EG) after cleaning, leading to increased costs and reduced efficiency.

Method used

A method for producing ethylene glycol copolymerized polybutylene terephthalate (EG copolymer PBT) with controlled terminal hydroxyl group concentration and EG copolymerization amount, utilizing residual EG in the production process to eliminate the need for EG removal steps, thereby enhancing molding cycle characteristics and material properties.

Benefits of technology

The EG copolymer PBT composition exhibits improved molding cycle characteristics, fit and hinge properties, and is easily converted to high molecular weight, reducing processing steps and costs while maintaining excellent material stability and productivity.

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Abstract

The present invention provides an EG copolymer PBT composition that exhibits excellent molding cycle characteristics, interlocking properties and hinge characteristics of the resulting molded articles, and is easily converted to high molecular weight by solid-phase polycondensation. [Solution] A method for producing an ethylene glycol copolymerized polybutylene terephthalate composition, comprising the step of reacting ethylene glycol with dimethyl terephthalate and / or terephthalic acid and 1,4-butanediol, and then reacting the resulting reaction product with ethylene glycol. A method for producing an ethylene glycol copolymerized polybutylene terephthalate composition, comprising the step of reacting dimethyl terephthalate and / or terephthalic acid and 1,4-butanediol, and then reacting the resulting reaction product with ethylene glycol, dimethyl terephthalate and / or terephthalic acid and 1,4-butanediol.
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