Biaxially oriented polyester film and laminate

Abstract

Provided is a biaxially-oriented polyester film that can be suitably used for deep drawing molding by layering metal layers, that is excellent in terms of moldability and adhesion to a metal layer, that is excellent in terms of blocking resistance, and that hardly curls.　The biaxially-oriented polyester film, that is a layered film having at least an easily adhering layer and a base material layer in which polyester is the main component, that is layered in the order of easily adhering layer / base material layer / easily adhering layer, and that satisfies any of (1)-(4) below. (1) The difference in the reversible thermal capacity variations ΔCp between the vicinities of the glass transition temperatures of the easily adhering layers and the base material layer is 0.10-0.45, inclusive. (2) The heatseal strength between the two easily adhering layers of the film is 0.5 N / 15 mm or less. (3) Stress F10 at the time of 10% elongation in the MD direction and the TD direction is 90 MPa to 160 MPa, inclusive. (4) The molecular orientation ratio measured by using a molecular orientation meter is 1.0 to 1.3, inclusive.

Description

[Technical field]

[0001] The present invention relates to a molding polyester film used in the field of packaging medicines, industrial products, etc. [Background technology]

[0002] Polyethylene terephthalate (hereinafter sometimes abbreviated as PET) is used in a wide range of fields such as food packaging and industrial products due to its excellent transparency, dimensional stability, mechanical properties, electrical properties, chemical resistance, etc. However, since it is harder and more brittle than nylon films, for example, molding it into deep-draw molding applications can be difficult.

[0003] Polybutylene terephthalate (hereinafter sometimes abbreviated as PBT) has been used as an engineering plastic because of its excellent mechanical properties, impact resistance, gas barrier properties, and chemical resistance. PBT has been used as a useful material as an engineering plastic because of its good productivity due to its fast crystallization rate, but when used as a stretched film, for example, crystallization causes deterioration in stretchability and transparency.

[0004] Patent Document 1 discloses a polyester film that has a stress difference at 5% elongation and 15% elongation in four directions of 50 MPa or less and 70 MPa, respectively, and an elastic modulus in the range of 2.0 to 3.5 GPa, making it suitable for cold forming.

[0005] Generally, crystalline polyester films tend to have low moldability and low lamination strength due to their high crystallinity. Therefore, when laminated with a metal layer, for example, it is expected that the adhesion is insufficient. If the adhesion with the metal layer is low, the stress generated by drawing during molding is not dispersed, and deep drawing is not possible, so that it is highly likely that it is unsuitable for deep drawing molding applications.

[0006] Patent Document 2 discloses that a polyester film characterized in that the stress at 5% elongation F5 and the stress at 10% elongation F10 in the longitudinal and transverse directions of the film are 1.5≧F10 / F5≧1.0 and F10≧120 MPa can be suitably used for molding applications.

[0007] In order to solve the above-mentioned problem of low lamination strength of crystalline polyester, an easy-adhesion coating is applied to the polyester film to improve adhesion with the metal layer and improve moldability. However, when the film is rolled, there are concerns about blocking caused by the easy-adhesion coating and deterioration of transparency caused by the lubricant added to the easy-adhesion coating to provide slipperiness. In addition, since the easy-adhesion coating is applied only to one side of the polyester film, there are concerns about deterioration of handling such as processing due to curling of the film. [Prior art documents] [Patent documents]

[0008] [Patent Document 1] Patent No. 6177475 [Patent Document 2] Patent No. 5891792 DISCLOSURE OF THEINVENTION [Problem to be solved by the invention]

[0009] The present invention has been made against the background of the problems of the conventional techniques. That is, an object of the present invention is to provide a biaxially oriented polyester film which can be suitably used in applications in which a metal layer is laminated and deep-draw molded, has excellent adhesion to the metal layer, excellent moldability, excellent blocking resistance, and is less prone to curling. [Means for solving the problem]

[0010] The present invention comprises the following configurations. [1] A biaxially oriented polyester film having at least a base layer and an easy-adhesion layer, the easy-adhesion layer being laminated in this order: easy-adhesion layer / base layer / easy-adhesion layer, and satisfying any of the following (1) to (4). (1) The difference in reversible heat capacity difference ΔCp between the adhesive layer and the base layer near the glass transition temperature is 0.10 to 0.45 (2) The heat seal strength between the adhesive layers of two films is 0.5 N / 15 mm or less. (3) Stress F10 at 10% elongation in MD and TD is 90 MPa or more and 160 MPa or less (4) A molecular orientation ratio measured using a molecular orientation meter is 1.0 or more and 1.3 or less. [2] The biaxially oriented polyester film according to [1], wherein the base layer contains, as polyester, 60% by mass or more and 100% by mass or less of polyethylene terephthalate and 0% by mass or more and 40% by mass or less of polyester other than polyethylene terephthalate. [3] The biaxially oriented polyester film according to [1] or [2], wherein the easy-adhesion layer contains polyethylene terephthalate and copolymerized polyethylene terephthalate as polyesters, the content of ethylene glycol units in the diol component in the polyester is 75 to 95 mol%, and the content of the copolymer component is 5 to 25 mol%. [4] The biaxially oriented polyester film according to [3], wherein the content of ethylene glycol units in the diol component of the polyester in the adhesion layer is 75 to 95 mol %, and the content of diethylene glycol units and / or neopentyl glycol units is 5 to 25 mol %. [5] The biaxially oriented polyester film according to any one of [1] to [4], wherein the difference in thickness between the two easy-adhesion layers in the biaxially oriented polyester film is 1.0 μm or less. [6] A laminate comprising a metal layer laminated on at least one surface of the biaxially oriented polyester film according to any one of [1] to [5]. [7] The laminate according to [6], wherein the metal layer is an aluminum layer having a thickness of 80 μm or less. [8] A deep-draw packaging material using the laminate described in [7]. Effect of the Invention

[0011] The biaxially oriented polyester film of the present invention has a reversible heat capacity difference ΔCp between the easy-adhesion layer and the base material layer near the glass transition, a stress F10 at 10% elongation in the MD and TD directions, a heat seal strength between the easy-adhesion layers, and a molecular orientation ratio within a predetermined range, thereby providing a biaxially oriented polyester film that has excellent adhesion to a metal layer, formability, and blocking resistance, has little curl, and is excellent in deep draw formability. [Brief description of the drawings]

[0012] [Figure 1] FIG. 2 shows a logarithmic stretching pattern in the TD direction of a film. [Diagram 2] FIG. 2 shows an exponential stretching pattern in the TD direction of a film. [Diagram 3] FIG. 1 is a diagram showing a measurement example of reversible heat capacity difference ΔCp. [Figure 4] FIG. 2 is a plan view of a mold used for evaluating deep draw formability of a laminate. [Diagram 5] FIG. 2 is a cross-sectional view taken along the line AA' of a mold used for evaluating the deep drawability of a laminate. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0013] The present invention will be described in detail below.

[0014] [Base material layer] The base layer of the biaxially oriented polyester film of the present invention is mainly composed of PET resin, and the PET content is 60% by mass or more, preferably 70% by mass, and more preferably 80% by mass. By making the PET content 60% by mass or more, the stress F10 at 10% elongation in the longitudinal direction and the transverse direction of the biaxially oriented polyester film can be increased, leading to improved deep drawing formability. In addition, the transparency is good, and when printed, the printing is clear and can be used suitably. In addition, since the relatively inexpensive PET resin is the main component, the cost is low.

[0015] The base layer of the biaxially oriented polyester film of the present invention may contain polyesters other than PET for the purpose of adjusting the mechanical properties and stretchability. Examples of polyesters other than PET include polyesters such as polybutylene terephthalate (PBT), polyethylene naphthalate (PEN), polybutylene naphthalate (PBN), and polypropylene terephthalate (PPT). PET or a copolymer polyester with the above polyester may also be used, and isoflavone may also be used. Examples of the polyester include polyesters copolymerized with dicarboxylic acids such as phthalic acid, orthophthalic acid, naphthalenedicarboxylic acid, biphenyldicarboxylic acid, cyclohexanedicarboxylic acid, adipic acid, azelaic acid, and sebacic acid, and polyesters copolymerized with diol components such as ethylene glycol, 1,3-propylene glycol, 1,2-propylene glycol, neopentyl glycol, 1,5-pentanediol, 1,6-hexanediol, diethylene glycol, cyclohexanediol, polyethylene glycol, polytetramethylene glycol, and polycarbonate diol.

[0016] Among them, PBT has excellent mechanical properties, and adding a small amount of it improves stretchability. It also reduces the upper yield stress in the stress-strain curve of the resulting biaxially oriented polyester film. The lower the upper yield stress, the more local stretching can be suppressed during drawing, and as a result, deeper drawing is possible. It is also preferred because it has good compatibility with PET resin and excellent transparency.

[0017] The polyester other than PET may not be contained, but by containing 10% by mass or more, the stretchability during film production can be improved. In addition, the moldability of the film can be improved. The upper limit of the content of the polyester other than PET is 40% by mass or less, preferably 30% by mass or less, and more preferably 20% by mass or less.

[0018] The lower limit of the intrinsic viscosity of the PET is preferably 0.45 dl / g, more preferably 0.50 dl / g, and most preferably 0.55 dl / g. By setting it to 0.45 dl / g or more, the intrinsic viscosity of the obtained biaxially oriented polyester film can be maintained high, and the stress F10 at 10% elongation in the longitudinal direction and the transverse direction can be easily increased. The upper limit of the intrinsic viscosity is preferably 0.80 dl / g, more preferably 0.75 dl / g, and most preferably 0.70 dl / g. By setting it to 0.80 dl / g or less, it is possible to suppress the stress during film stretching from becoming too high, and to obtain good film formability. The intrinsic viscosity of the polyester other than the PET is preferably an intrinsic viscosity at which the melt viscosity of the PET and the polyester other than the PET in the extruder is approximately the same.

[0019] [Easy adhesive layer] The adhesive layer of the biaxially oriented polyester film of the present invention is mainly composed of PET resin. By using PET as the main component, the adhesiveness with the base layer is increased, and the decrease in laminate strength due to interlayer peeling between the adhesive layer and the base layer can be suppressed.

[0020] In order to enhance the adhesion to the metal layer, it is preferable to add a copolymerized polyester to the adhesive layer of the biaxially oriented polyester film of the present invention. Copolymerized polyethylene terephthalate is particularly preferable. Examples of copolymerized polyesters include polyester resins copolymerized with dicarboxylic acids such as isophthalic acid, orthophthalic acid, naphthalenedicarboxylic acid, biphenyldicarboxylic acid, cyclohexanedicarboxylic acid, adipic acid, azelaic acid, and sebacic acid as dicarboxylic acid components, and / or polyesters copolymerized with diol components such as diethylene glycol, ethylene glycol, 1,3-propylene glycol, 1,2-propylene glycol, neopentyl glycol, 1,5-pentanediol, 1,6-hexanediol, cyclohexanediol, polyethylene glycol, polytetramethylene glycol, and polycarbonate diol as diol components. In the present invention, it is preferable to use copolymerized polyethylene terephthalate in which diethylene glycol and / or neopentyl glycol are copolymerized as diol components in addition to polyethylene terephthalate.

[0021] The lower limit of the content of the copolymerization component of the copolymerized polyester in the easy-adhesion layer is preferably 5 mol%, more preferably 8 mol%, and most preferably 11 mol%, based on the dicarboxylic acid unit or diol unit. By making it 5 mol% or more, the laminate strength of the obtained biaxially oriented polyester film can be increased, and the adhesion with the metal layer can be made sufficient. The upper limit of the content of the copolymerization component is preferably 25 mol%, more preferably 22 mol%, and most preferably 19 mol%, based on the dicarboxylic acid unit or diol unit. By making it 25 mol% or less, the reversible heat capacity difference ΔCp of the easy-adhesion layer becomes large, so that blocking can be suppressed when the film is rolled. In addition, by making it 25 mol% or less, the stress F10 at 10% elongation in the longitudinal direction and the transverse direction can be suppressed from decreasing.

[0022] [Additives] The biaxially oriented polyester film of the present invention may contain, in addition to the polyester resin composition, conventionally known additives such as lubricants, stabilizers, colorants, antioxidants, antistatic agents, and ultraviolet absorbers.

[0023] When the entire biaxially oriented polyester film of the present invention is taken as 100% by mass, the content of the polyester resin composition is preferably 99.5% by mass or more, more preferably 99.6% by mass, and most preferably 99.7% by mass.

[0024] The lubricant can adjust the dynamic friction coefficient of the film, and examples of the lubricant include inorganic lubricants such as silica, calcium carbonate, alumina, and organic lubricants. Silica and calcium carbonate are preferred, and from the viewpoint of achieving both transparency and lubricity, porous silica is the most preferred.

[0025] The lower limit of the lubricant content in the biaxially oriented polyester film of the present invention is preferably 100 ppm by mass, more preferably 300 ppm by mass, and most preferably 500 ppm by mass. By making it 100 ppm by mass or more, the slipperiness of the film can be improved, and the seal strength between the easy-adhesion layers can be suppressed, and blocking when rolled can be suppressed. The upper limit of the lubricant content in the biaxially oriented polyester film of the present invention is preferably 10000 ppm by mass, more preferably 6000 ppm by mass, and most preferably 2000 ppm by mass. By setting it to 10000 ppm by mass or less, the transparency of the film can be made good.

[0026] [Manufacturing method of biaxially oriented polyester film] The method for obtaining the biaxially oriented polyester film of the present invention is not particularly limited, but the T-die method is preferred from the viewpoint of obtaining a stress F10 at 10% elongation in the longitudinal and transverse directions. In the inflation method, the stretch ratio is difficult to increase due to the manufacturing method, and it may be difficult to increase F10.

[0027] The upper limit of the cooling roll temperature is preferably 40°C, and more preferably 20°C or less. If the temperature is 40°C or less, the crystallinity of the molten polyester resin composition is not too high when it is cooled and solidified, making it easier to stretch, and also suppressing the decrease in transparency due to crystallization. The lower limit of the cooling roll temperature is preferably 0°C. If the temperature is 0°C or more, the crystallization suppression effect when the molten polyester resin composition is cooled and solidified can be fully exhibited. In addition, when the temperature of the cooling roll is in the above range, it is preferable to reduce the humidity of the environment around the cooling roll to prevent condensation.

[0028] The thickness of the unstretched sheet is preferably in the range of 15 to 2500 μm, more preferably 600 μm or less, and most preferably 400 μm or less.

[0029] The stretching method may be either simultaneous biaxial stretching or sequential biaxial stretching, with sequential biaxial stretching being preferred from the viewpoint of controlling the molecular orientation in the width direction, which will be described later.

[0030] The lower limit of the stretching temperature in the longitudinal direction (hereinafter also referred to as MD direction) is preferably 90°C, more preferably 95°C, and particularly preferably 100°C. At 90°C or higher, breakage can be further suppressed. The upper limit of the stretching temperature in the MD direction is preferably 140°C, more preferably 135°C, and particularly preferably 130°C. At 140°C or lower, the stress at 10% elongation in the MD direction F10 can be increased, resulting in good deep draw formability.

[0031] The lower limit of the stretching ratio in the MD direction is preferably 3.5 times, more preferably 3.6 times, and particularly preferably 3.7 times. If it is 3.5 times or more, the stress F10 at 10% elongation in the MD direction can be increased, and the deep drawability is good. In addition, since the seal strength can be suppressed, the blocking resistance is good. The upper limit of the stretching ratio in the MD direction is preferably 4.5 times, more preferably 4.4 times, and particularly preferably 4.3 times. If it is 4.5 times or less, the effect of improving the stress F10 at 10% elongation in the MD direction can be sufficiently obtained.

[0032] The lower limit of the stretching temperature in the width direction (hereinafter also referred to as TD direction) is preferably 100°C, more preferably 105°C, and particularly preferably 110°C. If it is 100°C or higher, breakage can be made less likely to occur. The upper limit of the stretching temperature in the TD direction is preferably 140°C, more preferably 135°C, and particularly preferably 130°C. If it is 140°C or lower, the stress F10 at 10% elongation in the TD direction can be increased, and the deep drawability is improved.

[0033] The lower limit of the stretching ratio in the TD direction is preferably 3.5 times, more preferably 3.6 times, and particularly preferably 3.7 times. When it is 3.5 times or more, the stress F10 at 10% elongation in the TD direction can be increased, and the deep drawability is good. In addition, since the seal strength can be suppressed, the blocking resistance is good. The upper limit of the stretching ratio in the TD direction is preferably 4.5 times, more preferably 4.4 times, and particularly preferably 4.3 times. When it is 4.5 times or less, the effect of improving the stress F10 at 10% elongation in the TD direction can be sufficiently obtained.

[0034] As described below, the biaxially oriented polyester film of the present invention preferably has a molecular orientation ratio measured using a molecular orientation meter of 1.0 to 1.3. By having the molecular orientation ratio in a predetermined range, good deep drawability can be obtained for various shapes of drawing. Specifically, it is preferable that the stretch ratio in the MD direction: MD ratio and the stretch ratio in the TD direction: TD ratio satisfy the following. 0.9≦TD magnification / MD magnification≦1.2 By being in this range, the molecular orientation ratio falls within the range described in the claims, and good deep drawability can be obtained for drawing of various shapes.

[0035] In order to set the molecular orientation ratio within a predetermined range, in addition to the method of setting the stretching ratio within a predetermined range as described above, there is also a method of setting the TD stretching pattern to a logarithmic or exponential pattern. Specifically, as shown in FIG. 1 (logarithmic pattern), a normal TD stretching pattern is linear, whereas the logarithmic pattern is a TD stretching pattern in which the stretching is large in the first half of the stretching and is gentle in the second half of the stretching. By using such a TD stretching pattern, most of the stretching can be completed in the first half where the stretching stress of the film is low, making it possible to suppress the orientation in the TD direction. On the other hand, as shown in FIG. 2 (exponential pattern), the exponential pattern is a TD stretching pattern in which the stretching is gentle in the first half of the stretching and is large in the second half of the stretching. By using such a TD stretching pattern, most of the stretching can be completed in the second half where the stretching stress of the film is high, making it possible to strengthen the orientation in the TD direction. It is sufficient to select an appropriate TD stretching pattern so that the molecular orientation ratio of the obtained biaxially oriented polyester film is within the specified range.

[0036] The lower limit of the heat setting temperature is preferably 170°C, more preferably 175°C, and particularly preferably 180°C. If the temperature is 170°C or higher, the heat shrinkage rate can be further reduced. The upper limit of the heat setting temperature is preferably 210°C, more preferably 205°C, and particularly preferably 200°C. If the temperature is 210°C or lower, the decrease in the stress F10 at 10% elongation in the longitudinal direction and width direction due to relaxation of molecular orientation can be suppressed, and the deep drawability can be improved. In addition, the easy-adhesion layer melts due to heat treatment at high temperatures, increasing the seal strength and suppressing the deterioration of blocking resistance.

[0037] The lower limit of the relaxation rate in the heat-relaxing step is preferably 0.5%, more preferably 1.0%, and particularly preferably 2.0%. If it is 0.5% or more, the thermal shrinkage rate in the TD direction can be kept low. The upper limit of the relaxation rate is preferably 10%, more preferably 8%, and particularly preferably 6%. If it is 10% or less, the occurrence of slackness can be prevented, and flatness can be improved.

[0038] [Structure and properties of biaxially oriented polyester film] The lower limit of the thickness of the biaxially oriented polyester film of the present invention is preferably 5 μm, more preferably 10 μm, and particularly preferably 15 μm. By making it 5 μm or more, the strength of the film can be maintained and the deep drawing formability is good. The upper limit of the thickness is preferably 50 μm, more preferably 40 μm, and particularly preferably 30 μm. By making it 50 μm or less, cold forming is possible.

[0039] The lower limit of the thickness of the base layer in the biaxially oriented polyester film of the present invention is preferably 60% of the total thickness of the biaxially oriented polyester film, more preferably 70%, and particularly preferably 80%. By making it 60% or more, the stress F10 at 10% elongation in the longitudinal direction and the width direction can be increased, and the deep drawability is good. The upper limit of the thickness of the base layer is preferably 96% of the total thickness of the biaxially oriented polyester film, more preferably 90%, and particularly preferably 86%. By making it 96% or less, the effect of improving the adhesion to the metal layer by the easy-adhesion layer can be obtained, and the deep drawability is good.

[0040] The lower limit of the thickness of the easy-adhesion layer in the biaxially oriented polyester film of the present invention is preferably 4% of the total thickness of the biaxially oriented polyester film, more preferably 8%, and particularly preferably 12%. By making it 4% or more, the effect of improving adhesion to the metal layer can be obtained, and the deep drawability is good. The upper limit of the thickness of the easy-adhesion layer is preferably 40% of the total thickness of the biaxially oriented polyester film, more preferably 30%, and particularly preferably 20%. By making it 40% or less, the stress F10 at 10% elongation in the longitudinal direction and the width direction can be increased, and the deep drawability is good. The thickness of the easy-adhesion layer referred to here refers to the total thickness of the easy-adhesion layer on both sides of the easy-adhesion layer / base material layer / easy-adhesion layer.

[0041] The upper limit of the thickness difference between the easy-adhesion layers is preferably 1.0 μm, more preferably 0.8 μm or less, and particularly preferably 0.6 μm. By setting the thickness to 1.0 μm or less, curling of the film can be suppressed, and handling properties such as processing can be improved.

[0042] The upper limit of the reversible heat capacity difference ΔCp in the vicinity of the glass transition temperature in the base layer of the biaxially oriented polyester film of the present invention is preferably 0.05, more preferably 0.03, and particularly preferably 0.01. By setting it to 0.05 or less, the base layer becomes sufficiently rigid, and the stress F10 at 10% elongation in the longitudinal direction and the transverse direction can be increased.

[0043] The lower limit of the reversible heat capacity difference ΔCp near the glass transition temperature of the easy-adhesion layer of the biaxially oriented polyester film of the present invention is preferably 0.10, more preferably 0.15, and particularly preferably 0.20. By making it 0.10 or more, it is possible to obtain an effect of improving adhesion to the metal layer, and the deep drawing formability is good. The upper limit of the reversible heat capacity difference ΔCp near the glass transition temperature of the easy-adhesion layer of the biaxially oriented polyester film of the present invention is preferably 0.45, more preferably 0.40, and particularly preferably 0.35. By making it 0.45 or less, blocking can be suppressed when it is made into a film roll.

[0044] The lower limit of the difference between the reversible heat capacity difference ΔCp of the substrate layer and the easy-adhesion layer of the biaxially oriented polyester film of the present invention near the glass transition temperature is preferably 0.10, more preferably 0.15, and particularly preferably 0.20. By making it 0.10 or more, it is possible to obtain an effect of improving adhesion to the metal layer, and not only can the deep drawing formability be improved, but the substrate layer becomes sufficiently rigid, and the stress F10 at 10% elongation in the longitudinal direction and the width direction can be increased. The upper limit of the difference between the reversible heat capacity difference ΔCp of the substrate layer and the easy-adhesion layer of the biaxially oriented polyester film of the present invention near the glass transition temperature is preferably 0.45, more preferably 0.40, and particularly preferably 0.35. By making it 0.35 or less, blocking can be suppressed when the film is rolled.

[0045] The reversible heat capacity difference ΔCp near the glass transition temperature corresponds to the mobile amorphous amount when the reversible heat capacity curve is measured by a temperature-modulated differential scanning calorimeter. When the reversible heat capacity curve of a film sample is measured by a temperature-modulated differential scanning calorimeter, the baseline shifts at a temperature corresponding to the glass transition temperature. The difference between the values ​​before and after the shift is called the reversible heat capacity difference ΔCp, which corresponds to the mobile amorphous amount in which molecular chains can move near the glass transition temperature in the amorphous region of the biaxially oriented polyester film. The difference between the reversible heat capacity difference ΔCp near the glass transition temperature of the substrate layer and the easy-adhesion layer of the biaxially oriented polyester film of the present invention indicates the difference in the mobile amorphous amount between the substrate layer and the easy-adhesion layer.

[0046] The upper limit of the molecular orientation ratio of the biaxially oriented polyester film of the present invention is preferably 1.30, more preferably 1.25, and particularly preferably 1.20. By making it 1.30 or less, the deep drawability is good for drawing into various shapes. The molecular orientation ratio refers to the ratio (maximum value / minimum value) of the maximum and minimum microwave intensity measured by a molecular orientation meter. The lower limit of the molecular orientation ratio is preferably 0.90, more preferably 0.95, and particularly preferably 1.00. By making it 0.90 or more, the deep drawability is good for drawing into various shapes.

[0047] The lower limit of the stress F10 at 10% elongation in the MD direction of the biaxially oriented polyester film of the present invention is preferably 90 MPa, more preferably 95 MPa, and particularly preferably 100 MPa. By making it 90 MPa or more, stress dispersion during drawing is possible, and deep drawing formability is improved. The upper limit of the stress F10 at 10% elongation in the MD direction is preferably 160 MPa, more preferably 155 MPa, and particularly preferably 150 MPa. By making it 160 MPa or less, problems such as breakage during film formation can be suppressed.

[0048] The lower limit of the stress F10 at 10% elongation in the TD direction of the biaxially oriented polyester film of the present invention is preferably 90 MPa, more preferably 95 MPa, and particularly preferably 100 MPa. By making it 90 MPa or more, stress dispersion during drawing is possible, and deep drawing formability is improved. The upper limit of the stress F10 at 10% elongation in the TD direction is preferably 160 MPa, more preferably 155 MPa, and particularly preferably 150 MPa. By making it 160 MPa or less, problems such as breakage during film formation can be suppressed.

[0049] The upper limit of the haze of the biaxially oriented polyester film of the present invention is preferably 5.0%, more preferably 4.5%, and particularly preferably 4.0%. By keeping it at 5.0% or less, the print looks beautiful, which is preferable.

[0050] The lower limit of the dynamic friction coefficient of the biaxially oriented polyester film of the present invention is preferably 0.2, more preferably 0.25, and particularly preferably 0.30. By making it 0.20 or more, the transparency can be increased and the appearance can be improved. The upper limit of the dynamic friction coefficient is preferably 0.55, more preferably 0.50, and particularly preferably 0.45. By making it 0.55 or less, the film can slide well and blocking can be suppressed.

[0051] The lower limit of the heat shrinkage rate in the MD direction of the biaxially oriented polyester film of the present invention is preferably 1.0%, more preferably 1.5%, and particularly preferably 2.0%. By making it 1.0% or more, the stress F10 at 10% elongation in the longitudinal direction can be increased, resulting in good deep drawability. The upper limit of the heat shrinkage rate is preferably 6.0%, more preferably 5.5%, and particularly preferably 5.0%. By making it 6.0% or less, processing troubles due to film shrinkage in processes such as printing can be reduced.

[0052] The lower limit of the heat shrinkage rate in the TD direction of the biaxially oriented polyester film of the present invention is preferably -1.0%, more preferably -0.5%, and particularly preferably 0%. By making it -1.0% or more, the stress F10 at 10% elongation in the width direction can be increased, resulting in good deep drawability. The upper limit of the heat shrinkage rate in the TD direction is preferably 5.0%, more preferably 4.5%, and particularly preferably 4.0%. By making it 5.0% or less, processing troubles due to film shrinkage in processes such as printing can be reduced.

[0053] The upper limit of the heat seal strength when the biaxially oriented polyester film of the present invention is sealed at 120° C. is 0.5 N / 15 mm, more preferably 0.4 N / 15 mm, and particularly preferably 0.3 N / 15 mm. By setting it to 0.5 N / 15 mm or less, blocking can be suppressed when the film is wound up as a roll while still hot, for example, immediately after heat is applied in printing or processing.

[0054] A printed layer may be laminated on the biaxially oriented polyester film of the present invention. As the printing ink for forming the printed layer, water-based and solvent-based resin-containing printing inks can be preferably used. Here, examples of the resin used in the printing ink include acrylic resins, urethane resins, polyester resins, vinyl chloride resins, vinyl acetate copolymer resins, and mixtures thereof. The printing ink may contain known additives such as antistatic agents, light blocking agents, ultraviolet absorbing agents, plasticizers, lubricants, fillers, colorants, stabilizers, lubricants, defoamers, crosslinking agents, antiblocking agents, and antioxidants.

[0055] The printing method for providing the printed layer is not particularly limited, and known printing methods such as offset printing, gravure printing, screen printing, etc. can be used. For drying the solvent after printing, known drying methods such as hot air drying, hot roll drying, infrared drying, etc. can be used.

[0056] The biaxially oriented polyester film of the present invention may be laminated with a layer of another material. As a method for laminating the layer, a method of laminating the layer after the biaxially oriented polyester film is produced, or a method of laminating the layer during the film production can be adopted.

[0057] The biaxially oriented polyester film of the present invention can be used as a packaging material by forming a heat-sealable resin layer called a sealant (also called a sealant layer) on at least one of the surfaces of the easy-adhesion layer. The sealant layer is usually formed by extrusion lamination or dry lamination. The thermoplastic copolymer forming the heat-sealable resin layer may be any one that can fully exhibit the sealant adhesiveness, and may be polyethylene resins such as HDPE, LDPE, and LLDPE, polypropylene resins, ethylene-vinyl acetate copolymers, ethylene-α-olefin random copolymers, ionomer resins, etc.

[0058] The sealant layer may be a single layer film or a multilayer film, and may be selected according to the required function. For example, in order to provide moisture resistance, a multilayer film containing a resin such as an ethylene-cyclic olefin copolymer or polymethylpentene may be used. The sealant layer may also contain various additives such as a flame retardant, a slip agent, an antiblocking agent, an antioxidant, a light stabilizer, and a tackifier. The thickness of the sealant layer is preferably 10 to 100 μm, more preferably 20 to 60 μm.

[0059] One of the preferred embodiments of the present invention is a laminate in which a metal layer is laminated on at least one surface of an easy-adhesion layer of a biaxially oriented polyester film. The metal layer may be laminated so as to be in direct contact with the biaxially oriented polyester film of the present invention, or may be laminated via another layer such as an adhesive layer. When the sealant layer is provided on the film, it is preferable that the metal layer is laminated on the opposite surface to the sealant layer. A sealant layer may be further provided on the metal layer.

[0060] The metal layer may be a metal foil and / or an inorganic thin film layer.

[0061] When a metal foil is used as the metal layer, various metal elements such as aluminum, iron, copper, nickel, etc. can be used, and aluminum foil is particularly preferred. The thickness of the metal layer is not particularly limited, but is preferably 15 μm to 80 μm, particularly preferably 20 μm to 60 μm, from the viewpoint of deep drawing formability.

[0062] When an inorganic thin film layer is used as the metal layer, the material forming the inorganic thin film layer is not particularly limited as long as it can be made into a thin film, but from the viewpoint of gas barrier properties, inorganic oxides such as aluminum, silicon oxide (silica), aluminum oxide (alumina), and a mixture of silicon oxide and aluminum oxide are preferred. In particular, a composite oxide of silicon oxide and aluminum oxide is preferred from the viewpoint of achieving both flexibility and denseness of the thin film layer. The thickness of the inorganic thin film layer is usually 1 to 100 nm, preferably 5 to 50 nm. If the thickness of the inorganic thin film layer is 1 nm or less, more satisfactory gas barrier properties are easily obtained. On the other hand, if it is 100 nm or less, it is advantageous in terms of bending resistance and production costs.

[0063] The method for forming the inorganic thin film layer is not particularly limited, and for example, a known deposition method such as a physical deposition method (PVD method) such as a vacuum deposition method, a sputtering method, or an ion plating method, or a chemical deposition method (CVD method) may be appropriately adopted. When the inorganic thin film layer is provided, it is preferable to provide a protective layer on the inorganic thin film layer. The gas barrier layer made of a metal oxide is not a completely dense film, and minute defective parts are scattered therein. By forming a protective layer by applying a specific resin composition for a protective layer described later on the metal oxide layer, the resin in the protective compatible resin composition penetrates into the defective parts of the metal oxide layer, and as a result, the effect of stabilizing the gas barrier property is obtained. In addition, by using a material having gas barrier properties for the protective layer itself, the gas barrier performance of the laminated film is also greatly improved. Examples of the protective layer include urethane-based, polyester-based, acrylic-based, titanium-based, isocyanate-based, imine-based, polybutadiene-based, and other resins to which epoxy-based, isocyanate-based, melamine-based, and other curing agents are added.

[0064] The laminate obtained by laminating a metal layer on the biaxially oriented polyester film of the present invention is preferably one having a large breaking elongation because the deep drawing moldability is good. The lower limit of the tensile breaking elongation in the laminate obtained by laminating the biaxially oriented polyester film / adhesive / metal layer / adhesive / sealant layer in this order is preferably 30%, more preferably 32%, and particularly preferably 34%. By making it 30% or more, the laminate can be sufficiently elongated, and the deep drawing moldability is good. The upper limit of the tensile breaking elongation of the laminate is preferably 50%, more preferably 48%, and particularly preferably 46%. By making it 50% or less, the mechanical strength of the laminate can be made high, and problems such as pinholes during deep drawing can be prevented.

[0065] The laminate of the present invention is suitably used in applications where deep-draw molding is performed using a mold to form recesses, and deep-draw molded laminates are used for various packaging materials. EXAMPLES

[0066] Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited to the following examples.

[0067] [Film thickness] The measurement was performed using a dial gauge in accordance with JIS K7130-1999 Method A.

[0068] [Reversible heat capacity near the glass transition temperature ΔCp] The surfaces of the substrate layer and the adhesive layer of the biaxially oriented polyester film were scraped off with a razor blade to prepare samples for measurement. The substrate layer was sampled from the substrate layer surface exposed after the adhesive layer surface was sufficiently scraped off. Using a temperature modulated differential scanning calorimeter DSC "DSC250" (manufactured by TA Instruments), a sample was weighed at 5.0±0.2 mg in a hermetic aluminum pan, and measured in MDSC (registered trademark) heat-only mode at an average heating rate of 2.0°C / min and a modulation period of 60 seconds to obtain a reversible heat capacity curve. In the obtained heat capacity curve, an inflection point was obtained using the attached analysis software (TA Analysis, manufactured by TA Instruments), and the reversible heat capacity difference was calculated by the following formula for the heat capacity difference before and after the inflection point (abbreviated as glass transition temperature: Tg). Here, the inflection point refers to the point where the value when the reversible heat capacity curve is differentiated twice is 0 when the reversible heat capacity curve is an ideal curve without unevenness. Reversible heat capacity difference ΔCp = (heat capacity on the higher side than Tg) - (heat capacity on the lower side than Tg) An example of the measurement of the reversible heat capacity difference is shown in FIG. 3. Here, an extension line of the baseline of the heat capacity curve on the higher temperature side than Tg is drawn in the heat capacity curve. The baseline of the heat capacity curve in the range of Tg+5°C to Tg+15°C is linearly fitted by the least squares method to be the extension line 3 of the baseline of the heat capacity curve on the higher temperature side than Tg. Then, the intersection with the tangent line 2 at the inflection point (Tg) is obtained, and the value of the Y axis (reversible heat capacity) at this intersection is read and taken as the heat capacity on the high temperature side. Next, an extension line of the baseline of the heat capacity curve on the lower temperature side than Tg is drawn. Here, the baseline of the heat capacity curve in the range of Tg-15°C to Tg-5°C is linearly fitted by the least squares method to be the extension line 4 of the baseline of the heat capacity curve on the lower temperature side than Tg. Then, the intersection point with tangent 2 at inflection point 1 (Tg) was determined, and the value on the Y-axis (reversible heat capacity) at this intersection point was read and regarded as the heat capacity on the low temperature side. The difference between the heat capacity values ​​on the high temperature side and the low temperature side was regarded as the heat capacity difference ΔCp. It was also confirmed that the baseline shift in the reversible heat capacity measurement was not disturbed and the measurement was performed normally.

[0069] [Molecular orientation ratio of film] The molecular orientation ratio of the biaxially oriented polyester film (the ratio of the maximum and minimum values ​​of the transmitted microwave intensity measured by the molecular orientation meter) (maximum value / minimum value) was determined using a molecular orientation meter MOA-6004 manufactured by Oji Measurement Co., Ltd.

[0070] [Film stress at 10% elongation F10] A sample with a width of 15 mm and a length of 180 mm was cut out from the biaxially oriented polyester film. The cut out sample was aged for 12 hours in an atmosphere of 23°C and 65% RH, and then measured under the conditions of 23°C, 65% RH, chuck distance of 100 mm, and tensile speed of 360 mm / min. The measurement was repeated five times, and the average value of the stress when the film was elongated by 10% (stress at 10% elongation) was used. The measurement device used was an Autograph (registered trademark) AG-1 manufactured by Shimadzu Corporation.

[0071] [Film Haze] In accordance with JIS K7361-1, the biaxially oriented polyester film was cut into a square shape with each side being 10 cm long, and the haze was measured using a haze meter NDH2000 manufactured by Nippon Denshoku Co., Ltd. Measurements were performed at three locations, and the average value was taken as the actual haze measurement value.

[0072] [Dynamic friction coefficient of film] In accordance with JIS K-7125, a tensile tester (A&D Tensilon RTG-1210) was used to determine the dynamic friction coefficient when the front and back surfaces of a biaxially oriented polyester film were joined together in an environment of 23°C and 65% RH. The weight of the thread (weight) on which the upper film was wrapped was 1.5 kg, and the size of the base area of ​​the thread was 39.7 mm 2 The pulling speed in measuring the friction coefficient was 200 mm / min.

[0073] [Film heat shrinkage rate] The thermal shrinkage rate was measured using a dimensional change test method in accordance with JIS-C-2318, except that the test temperature was 150°C and the heating time was 15 minutes.

[0074] [Heat seal strength of film] Heat seal strength was measured in accordance with JIS Z1707. The specific procedure is as follows: The easy-adhesion layer surfaces of the samples were bonded together using a heat sealer. The heat seal conditions were upper bar temperature 120°C, lower bar 30°C, pressure 0.2MPa, and time 2 seconds. The bonded samples were cut out to have a seal width of 15mm. Peel strength was measured using a tensile tester "AGS-KNX" (manufactured by Shimadzu Corporation) at a tensile speed of 200mm / min. Peel strength is expressed as strength per 15mm (unit: N / 15mm).

[0075] [Observation of film seal layer thickness] A sample for observation was cut out from the unstretched sheet before stretching. The sample for observation was reinforced with a UV-curable resin (epoxy acrylate resin) and then hardened by UV irradiation. A cross section was cut out using a microtome "RX-860" (manufactured by Yamato Kogyo Co., Ltd.) so that the thickness cross section of the sample could be observed. Next, the cross section of the sample that had been cut out was observed using an industrial microscope "ECLIPSE LV150N" (manufactured by Nikon Corporation). From the microscope image, the thickness ratio of the base layer and the easy-adhesion layer of the unstretched sheet was calculated, and this thickness ratio was multiplied by the thickness of the film after biaxial stretching to calculate the thickness of each layer of the biaxially oriented polyester film.

[0076] [Evaluation of film curl] A sample of 10 cm square was cut out from the biaxially oriented polyester film. The height of the sample floating above the table when the sample was placed on a flat table was measured. The same measurement was performed on both sides of the sample, and the largest value was recorded as the measurement value for that sample. The evaluation results were evaluated based on the following criteria. Float height is less than 5mm: A Float height is 5mm or more: C

[0077] [Laminated body production] A urethane-based two-component curing adhesive (Mitsui Chemicals' "Takelac (registered trademark) A525S" and "Takenate (registered trademark) A50" were mixed in a ratio of 13.5:1.0 (mass ratio)) and 40 μm thick "Aluminum Haku CE 8079" manufactured by Toyo Aluminum Co., Ltd. were laminated to the surface of the easy-adhesion layer of the biaxially oriented polyester film by dry lamination. Subsequently, a urethane-based two-component curing adhesive and a 70 μm thick non-oriented polypropylene film (Toyobo's "P1147") were similarly laminated to the aluminum layer side of the above laminate by dry lamination. This laminate was aged at 40 ° C for 4 days to obtain a laminated laminate. The lamination directions of the biaxially oriented polyester film and the non-oriented polypropylene film were all aligned in the longitudinal direction and the width direction. The thickness of the adhesive layer formed with the urethane-based two-component curing adhesive after drying was about 4 μm in each case.

[0078] [Laminated Tensile Elongation at Break] A sample of 15 mm in width and 180 mm in length was cut out from the laminate. The cut out sample was aged for 12 hours in an atmosphere of 23°C and 65% RH, and then measured under conditions of 23°C, 65% RH, 100 mm chuck distance, and 360 mm / min tensile speed. The measurement was repeated five times, and the average value of the elongation at which the aluminum layer broke was taken as the tensile breaking elongation of the laminate. An Autograph (registered trademark) AG-1 manufactured by Shimadzu Corporation was used as the measuring device.

[0079] [Evaluation of deep-draw formability of laminates] A sample measuring 10 cm in the longitudinal direction and 10 cm in the transverse direction was cut out from the aforementioned laminate. This sample was set in the mold shown in Figure 4, and pressed from above to perform drawing. Figure 5 is a cross-sectional view of the mold. Specifically, the laminate was placed on a mold measuring 54 mm in length, 54 mm in width, 12 mm in depth, and with four corners rounded by R = 3 mm, and the laminate was held down with a film holder. In this state, the sample was pressed with a punch of a shape corresponding to the die. The drawing speed was 6 mm / s. Evaluation was performed with N=10, and the maximum drawing depth when no film tears or pinholes occurred with N=10 was taken as the deep drawing molding value of the sample. A deep drawing molding value of 3.5 mm or more was evaluated as being practical.

[0080] [Example 1] The three-layer structure is easy-to-adhere layer B / base layer A / easy-to-adhere layer B. Extruder 1 produces base layer A. PET resin (terephthalic acid / / ethylene glycol = 100 / / 100 (mol%) inherent viscosity 0.62 dl / g, silica particle blend) and PBT resin (terephthalic acid / / butanediol = 100 / / 100 (mol%) inherent viscosity 1.28 dl / g) were fed. Next, PET resin (terephthalic acid / / ethylene glycol = 100 / / 100 (mol%) inherent viscosity 0.62 dl / g, silica particle blend) and copolymerized PET resin (terephthalic acid / / ethylene glycol / diethylene glycol = 100 / / 60 / 40 (mol%) inherent viscosity 0.62 dl / g) were fed into extruder 2, which becomes the easy-adhesion layer B, in a ratio such that the diethylene glycol component in the B layer is 17 mol%. After the resins were melted at 280°C in each extruder, layers A and B were merged in a merging device, cast from a T-die at 280°C, and adhered to a cooling roll at 10°C by electrostatic adhesion to obtain an unstretched sheet having a three-layer structure. The content of silica particles in each layer was 0.1% by mass as a silica concentration when the entire resin composition in each layer was taken as 100% by mass.

[0081] The unstretched sheet was then stretched 4.0 times in the MD direction at a temperature of 115°C, and then stretched 4.1 times in the TD direction at 110°C through a tenter with a linear stretching pattern, followed by heat setting at 190°C for 3 seconds and relaxation at 5% for 1 second to obtain a biaxially oriented polyester film with a thickness of 25 μm. The resin composition of the biaxially oriented polyester film and the film-forming conditions are shown in Table 1. The physical properties and evaluation results of the obtained film are also shown in Table 1.

[0082] [Example 2] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film production in the same manner as in Example 1, except that the tenter stretching pattern was changed to a logarithmic pattern. The physical properties and evaluation results of the obtained film are shown in Table 1.

[0083] [Example 3] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film production in the same manner as in Example 1, except that the tenter stretching pattern was changed to an exponential pattern. The physical properties and evaluation results of the obtained film are shown in Table 1.

[0084] [Example 4] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film formation in the same manner as in Example 1, except that the film formation conditions were changed to those shown in Table 1. The physical properties and evaluation results of the obtained film are shown in Table 1.

[0085] [Examples 5 and 6] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film production in the same manner as in Example 1, except that the weight ratio of the raw materials fed into the extruder 2 was changed so that the diethylene glycol component in the adhesive layer B was as shown in Table 1. The physical properties and evaluation results of the obtained film are shown in Table 1.

[0086] [Example 7] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film production in the same manner as in Example 1, except that the thicknesses of the base layer A and the adhesive layer B were changed as shown in Table 1. The physical properties and evaluation results of the obtained film are shown in Table 1.

[0087] [Example 8] A new extruder 3 was installed to form the easy-adhesion layer B, and PET resin (intrinsic viscosity 0.62 dl / g consisting of terephthalic acid / ethylene glycol = 100 / / 100 (mol%), silica particle blended) and copolymerized PET resin (intrinsic viscosity 0.62 dl / g consisting of terephthalic acid / ethylene glycol / diethylene glycol = 100 / / 60 / 40 (mol%)) were added at a ratio such that the diethylene glycol component in the B layer was 17 mol%. After melting the resin at 280 ° C. in each extruder, the A layer and the B layer were merged in a merging device, cast from a T-die at 280 ° C., and adhered to a cooling roll at 10 ° C. by electrostatic adhesion method to obtain a three-layered unstretched sheet. The extruder discharge amount was adjusted so that the thickness of the cooling roll contact surface and the non-contact surface of the easy-adhesion layer B layer were as shown in Table 1, and a biaxially oriented polyester film having a thickness of 25 μm was obtained by film formation in the same manner as in Example 1. The physical properties and evaluation results of the obtained film are shown in Table 1.

[0088] [Example 9] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film formation in the same manner as in Example 1, except that PET resin (terephthalic acid / ethylene glycol = 100 / / 100 (mol%), inherent viscosity 0.62 dl / g, silica particle blend) and copolymerized PET resin (terephthalic acid / ethylene glycol / neopentyl glycol = 100 / / 60 / 40 (mol%), inherent viscosity 0.62 dl / g) were used for feeding into extruder 2 to form easy-adhesion layer B. The physical properties and evaluation results of the obtained film are shown in Table 1.

[0089] [Examples 10 and 11] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film formation in the same manner as in Example 1, except that the film formation conditions were changed to those shown in Table 1. The physical properties and evaluation results of the obtained film are shown in Table 1.

[0090] [Examples 12 and 13] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film production in the same manner as in Example 1, except that the resin composition in the base layer A was changed to the ratio shown in Table 1. The physical properties and evaluation results of the obtained film are shown in Table 1.

[0091] [Table 1A]

[0092] [Table 1B]

[0093] [Table 1C]

[0094] [Comparative Example 1] A biaxially oriented polyester film having a thickness of 25 μm was produced in the same manner as in Example 1, except that the weight ratio of the raw materials fed to the extruder 2 was changed so that the diethylene glycol component in the adhesive layer B was as shown in Table 2. The obtained film had a small reversible heat capacity difference ΔCp near the glass transition and insufficient adhesion, so that the rupture elongation of the laminate was low and the deep drawability was insufficient.

[0095] [Comparative Example 2] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film production in the same manner as in Example 1, except that the weight ratio of the raw materials fed to the extruder 2 was changed so that the diethylene glycol component in the adhesive layer B was as shown in Table 2. The obtained film had a small stress F10 at 10% elongation and a low breaking elongation of the laminate, and therefore not only was the deep drawability insufficient, but the sealing strength between the adhesive layers was large, and the blocking resistance was insufficient.

[0096] [Comparative Example 3] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film formation in the same manner as in Example 1, except that a single-layer structure was used consisting of only the base layer A. The obtained film had no easy-adhesion layer and no reversible heat capacity difference ΔCp near the glass transition, so that the adhesion was insufficient, the breaking elongation of the laminate was low, and the deep drawability was insufficient.

[0097] [Comparative Example 4] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film production in the same manner as in Example 1, except that the thicknesses of the base layer A and the easy-adhesion layer B were changed to those shown in Table 2. The obtained film had a small stress F10 at 10% elongation and a low breaking elongation of the laminate, and therefore the deep drawability was insufficient.

[0098] [Comparative Example 5] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film formation in the same manner as in Example 1, except that the film formation conditions were changed to those shown in Table 2. The obtained film had a large orientation ratio, and therefore was insufficient in deep drawability.

[0099] [Comparative Example 6] A biaxially oriented polyester film having a thickness of 25 μm was obtained by film formation in the same manner as in Example 1, except that the film formation conditions were changed to those shown in Table 2. The obtained film had a small stress F10 at 10% elongation and a low breaking elongation of the laminate, and therefore the deep drawability was insufficient.

[0100] [Comparative Example 7] A biaxially oriented polyester film having a thickness of 25 μm was produced in the same manner as in Example 1, except that the resin composition in the base layer A was changed to the ratio shown in Table 2. The obtained film had a small stress F10 at 10% elongation and a low breaking elongation of the laminate, and therefore the deep drawability was insufficient.

[0101] [Comparative Example 8] A new extruder 3 was installed to form the easy-adhesion layer B, and PET resin (intrinsic viscosity 0.62 dl / g consisting of terephthalic acid / ethylene glycol = 100 / / 100 (mol%), silica particle blended) and copolymerized PET resin (intrinsic viscosity 0.62 dl / g consisting of terephthalic acid / ethylene glycol / diethylene glycol = 100 / / 60 / 40 (mol%)) were added at a ratio such that the diethylene glycol component in the B layer was 17 mol%. After melting the resin at 280 ° C. in each extruder, the A layer and the B layer were merged in a merging device, cast from a T-die at 280 ° C., and adhered to a cooling roll at 10 ° C. by electrostatic adhesion method to obtain a three-layered unstretched sheet. The extruder discharge amount was adjusted so that the thickness of the cooling roll contact surface and the non-contact surface of the easy-adhesion layer B layer was as shown in Table 2, and a biaxially oriented polyester film having a thickness of 25 μm was obtained by film formation in the same manner as in Example 1. The obtained film had insufficient curling properties.

[0102] [Table 2A]

[0103] [Table 2B] [Explanation of symbols]

[0104] 1 Inflection point (Tg) 2 Tangent at the inflection point (Tg) 3. Extension of the baseline of the heat capacity curve above Tg 4. Extension of the baseline of the heat capacity curve below Tg 5. Reversible heat capacity difference ΔCp near the glass transition temperature 6. Punch 7 Film holder 8 Film Laminate 9. Mold

Claims

1. A laminated film having at least a base layer and an easy-adhesion layer mainly composed of polyester, the easy-adhesion layer being laminated in this order: easy-adhesion layer / base layer / easy-adhesion layer; The base layer contains, as polyester, 60% by mass or more and 100% by mass or less of polyethylene terephthalate and 0% by mass or more and 40% by mass or less of polyester other than polyethylene terephthalate, The easy-adhesion layer contains polyethylene terephthalate and copolymerized polyethylene terephthalate as polyesters, and the content of ethylene glycol units in a diol component in the polyester is 75 to 95 mol % and the content of a copolymer component is 5 to 25 mol %, The thickness difference between the two easy-adhesion layers is 1.0 μm or less, A biaxially oriented polyester film that satisfies any one of the following (1) to (4): (1) The difference in reversible heat capacity difference ΔCp between the adhesive layer and the substrate layer near the glass transition temperature is 0.10 or more and 0.45 or less. (2) The heat seal strength between the adhesive layers of two films is 0.5 N / 15 mm or less. (3) Stress F10 at 10% elongation in the MD and TD directions is 90 MPa or more and 160 MPa or less (4) A molecular orientation ratio measured using a molecular orientation meter is 1.0 to 1.

3.

2. The biaxially oriented polyester film according to claim 1, wherein the content of ethylene glycol units in the diol component of the polyester in the easy-adhesion layer is 75 to 95 mol%, and the content of diethylene glycol units and / or neopentyl glycol units is 5 to 25 mol%.

3. 3. A laminate comprising the biaxially oriented polyester film according to claim 1 or 2, and a metal layer laminated on at least one surface of the biaxially oriented polyester film.

4. 4. The laminate according to claim 3, wherein the metal layer is an aluminum layer having a thickness of 80 μm or less.

5. A deep-draw packaging material using the laminate according to claim 4.

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