Packaging materials containing PLA films with moisture barrier layers produced by atomic layer deposition

Abstract

To provide a moisture barrier film for packaging, such as tobacco or cigarette packaging.SOLUTION: A film comprises polylactic acid ("PLA") that is both biodegradable and transparent. The film includes multiple layers of PLA with a base layer having a relatively high melting point compared to two outer layers which have a relatively low melting point. The outer layers provide heat sealing capabilities to the film. The film is coated with a metal oxide layer comprised of aluminum oxide, titanium oxide, and / or aluminum-titanium oxide using an atomic layer deposition ("ALD") coating method. The ALD coating to the PLA film results in a moisture vapor transmission rate of less than 4 g / m2 / day after the film has been subjected to creasing, which induces cracking of an ALD metal oxide layer.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS This application claims priority to U.S. Patent Application No. 15 / 208,352, filed July 12, 2016, the entire contents of which are incorporated herein by reference.

[0002] The present disclosure relates to moisture-proof packaging wrappers. [Background technology]

[0003] Cigarettes are traditionally sold in packages, each package often containing 20 cigarettes. A typical cigarette package is generally rectangular in shape. One type of common cigarette package uses a container in the form of a so-called "hard pack," "crushproof box," or "hinge-lid package." See, for example, U.S. Pat. No. 3,874,581 to Fox et al.; U.S. Pat. No. 3,944,066 to Niepmann et al.; U.S. Pat. No. 4,852,734 to Allen et al.; European Patent No. 0392737 to Moeller; and U.S. Patent Application Publication No. 2008 / 0230410 to Jones et al., each of which is incorporated herein by reference. Another type of common cigarette package uses a container in the form of a so-called "soft pack." See, for example, U.S. Patent No. 3,695,422 to Tripodi, U.S. Patent No. 4,717,017 to Sprinkel et al., and U.S. Patent No. 5,333,729 to Wolfe, each of which is incorporated herein by reference. Both types of cigarette packages are commonly packed in cartons, also generally rectangular in shape, with typically 10 packages per carton.

[0004] Additional examples of cigarette packages can be found in U.S. Pat. No. 8,522,515 to Carter et al.; U.S. Pat. No. 8,118,161 to Guerrera et al.; U.S. Pat. No. 7,823,731 to Wu; U.S. Pat. No. 7,228,961 to Koetter et al.; U.S. Pat. No. 7,048,115 to Stringfield; U.S. Pat. No. 7,014,039 to Henson et al.; U.S. Pat. No. 6,364,106 to Fagg et al.; U.S. Pat. No. 5,379,889 to Cobler et al.; U.S. Pat. No. 5,248,031 to Burrows et al.; U.S. Pat. No. 5,139,140 to Burrows et al.; and U.S. Pat. No. 4,807,745 to Langley et al., each of which is incorporated herein by reference.

[0005] Cigarette packages as described above are typically formed from folded and glued paper stock. The paper stock provides structural rigidity to the cigarette package. However, the paperboard itself does not provide the moisture retention properties necessary for proper storage of tobacco products. Therefore, most commercial cigarette packages are enclosed within a plastic film that prevents moisture loss from the inside of the pack to the outside. The plastic film is typically a petroleum-derived, transparent, biaxially oriented, heat-sealable polypropylene film with an inherent moisture barrier. The moisture vapor transmission rate through these polypropylene films is approximately 4 g / m when measured at 38°C and 90% relative humidity according to ASTM D1249. 2 / day. This moisture barrier keeps the tobacco inside the pack moist for several months, allowing the package to have a shelf life of several months. However, these films are not considered sustainable due to their petroleum-based origin. Furthermore, petroleum-derived plastic films are not at all biodegradable and contribute to landfill waste. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] U.S. Patent No. 3,874,581 [Patent Document 2] U.S. Patent No. 3,944,066 [Patent Document 3] U.S. Patent No. 4,852,734 [Patent Document 4] European Patent No. 0392737 [Patent Document 5] US Patent Application Publication No. 2008 / 0230410 [Patent Document 6] U.S. Patent No. 3,695,422 [Patent Document 7] U.S. Patent No. 4,717,017 [Patent Document 8] U.S. Patent No. 5,333,729 [Patent Document 9] U.S. Patent No. 8,522,515 [Patent Document 10] U.S. Patent No. 8,118,161 [Patent Document 11] U.S. Patent No. 7,823,731 [Patent Document 12] U.S. Patent No. 7,228,961 [Patent Document 13] U.S. Patent No. 7,048,115 [Patent Document 14] U.S. Patent No. 7,014,039 [Patent Document 15] U.S. Patent No. 6,364,106 [Patent Document 16] U.S. Patent No. 5,379,889 [Patent Document 17] U.S. Patent No. 5,248,031 [Patent Document 18] U.S. Patent No. 5,139,140 [Patent Document 19] U.S. Patent No. 4,807,745 Summary of the Invention [Problem to be solved by the invention]

[0007] It would therefore be desirable to provide a sustainably sourced transparent film that is biodegradable and also provides the necessary moisture barrier properties. [Means for solving the problem]

[0008] These and other needs are met by an embodiment of the present disclosure, which provides a moisture-proof coated film. The film includes a first layer including a first material having a first melting point. The film further includes a second layer including a second material having a second melting point, the second melting point being lower than the first melting point. A first surface of the second layer is bonded to the first surface of the first layer. The film includes a moisture-proof coating applied to the second surface of the second layer, the moisture-proof coating including a metal oxide.

[0009] In a second aspect, a method for producing a film having a moisture-resistant coating is provided. The method includes forming a first layer including a first material having a first melting point. The method further includes forming a second layer including a second material having a second melting point, the second melting point being lower than the first melting point. The first surface of the second layer is bonded to the first surface of the first layer. The method further includes coating the second surface of the second layer with a moisture-resistant coating including a metal oxide. The second surface of the second layer is opposite the first surface of the second layer.

[0010] In a third aspect, a package is provided. The package includes a body and a top formed of a paper material. The package includes a central compartment formed by the top and the body. The package further includes a packaging material formed of a film. The film includes a first layer including a first material having a first melting point and a second layer including a second material having a second melting point. The second melting point is lower than the first melting point. The first surface of the second layer is bonded to the first surface of the first layer. The film further includes a moisture-resistant coating applied to the second surface of the second layer, the moisture-resistant coating including a metal oxide.

[0011] Further features and advantages of the present disclosure are described in more detail in the description that follows.

[0012] Having described the present disclosure in general terms, reference will now be made to the accompanying drawings, which are not necessarily drawn to scale. [Brief explanation of the drawings]

[0013] [Figure 1] 1 is a cross-sectional view of a moisture barrier film according to an exemplary embodiment. [Figure 2] 2 is a flow diagram of a method for manufacturing the moisture barrier film of FIG. 1 according to an exemplary embodiment. [Figure 3] 1 is a perspective view of a cigarette pack formed in accordance with an exemplary embodiment; [Figure 4] 4 is another perspective view of the cigarette pack of FIG. 3. [Figure 5] 4 is a view of the cigarette pack of FIG. 3 wrapped in the film of FIG. 1. FIG. [Figure 6] 2 is a flow diagram of a method for manufacturing a cigarette pack wrapped in the film of FIG. 1 according to an exemplary embodiment. DETAILED DESCRIPTION OF THE INVENTION

[0014] The present disclosure will now be described more fully hereinafter with reference to the accompanying drawings, in which some, but not all, aspects of the disclosure are shown. Indeed, this disclosure may be embodied in many different forms and should not be construed as limited to the aspects set forth herein. Rather, these aspects are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the disclosure to those skilled in the art, and will satisfy applicable legal requirements. Like numerals refer to like elements throughout. As used in this specification and claims, the singular forms "a," "an," and "the" include plural referents unless the context clearly dictates otherwise.

[0015] Various embodiments described herein relate to moisture-barrier films for packaging, such as cigarette or cigarette packages. The film comprises polylactic acid ("PLA"), which is biodegradable and transparent. In some configurations, the film is corn-derived. The film comprises multiple layers of PLA, with a base layer having a relatively high melting point compared to two outer layers having relatively low melting points. The outer layers provide the film with heat-sealing capabilities. In some configurations, an atomic layer deposition ("ALD") coating method is used to coat the film with a metal oxide layer comprised of aluminum oxide, titanium oxide, and / or aluminum titanium oxide, having a coating thickness of 2-10 nm. The ALD coating on the PLA film is performed at a coating thickness of 4 g / m² after the film is creased to induce cracking of the ALD metal oxide layer. 2 The film described provides a moisture vapor transmission rate of less than 1 / day. Therefore, the film described is suitable for use as a substitute for polypropylene film for packaging cigarette packs. The appearance of the PLA-packaged packs is similar to or even better than that of packs packaged with polypropylene film.

[0016] Moisture-proof film Referring to FIG. 1, a cross-sectional view of an exemplary film 100 is shown. The film 100 is a multilayer film consisting of a base layer 102, an outer layer 104, and an inner layer 106. The base layer 102 is disposed between the outer layer 104 and the inner layer 106. The base layer 102, the outer layer 104, and the inner layer 106 have a combined thickness of between 15 and 30 microns. In some configurations, the combined thickness of the base layer 102, the outer layer 104, and the inner layer 106 is 20 microns. In some configurations, the outer layer 104 and the inner layer 106 each have a thickness of between 1 and 2 microns. In some configurations, the base layer 102, the outer layer 104, and the inner layer 106 are formed and bonded together by a coextrusion process. After the extrusion process, the film 100 may be wrapped around a core.

[0017] The outer layer 104 and the inner layer 106 are made of a first material. The first material is a first polylactic acid ("PLA") material. The first PLA material is transparent and biodegradable. In some configurations, the first PLA material is corn-based. The first PLA material has a first melting temperature. In some configurations, the first melting temperature is less than 120 degrees Celsius. In further configurations, the first melting temperature is less than 100 degrees Celsius. The base layer 102 is made of a second material that is transparent and has a second melting temperature. The second melting temperature is higher than the first melting temperature, providing the film 100 with heat-sealing capabilities. In some configurations, the second material is a second polylactic acid material. The second PLA material may be corn-based. In other arrangements, the second material is bio-based polypropylene. In a further configuration, the second material is the first PLA material modified to have a melting temperature higher than the first melting temperature. In some configurations, the second melting temperature is between 130 and 220 degrees Celsius.

[0018] The film 100 includes a coating 108. The coating 108 provides a moisture barrier to the film 100. The coating 108 is applied to a free surface of the outer layer 104 such that the outer layer 104 is disposed between the coating 108 and the base layer 102. In some configurations, the coating 108 is also applied to a free surface of the inner layer 106 such that the inner layer 106 is disposed between the coating 108 and the base layer 102.

[0019] The coating 108 is a transparent or substantially transparent metal oxide coating. In some configurations, the coating 108 is aluminum titanium oxide (“ATO”). In other configurations, the coating 108 is aluminum oxide or titanium oxide. Coatings made of ATO are more flexible and crack resistant than coatings made from aluminum oxide or titanium oxide. In other configurations, the coating includes other metal oxides, such as silicon dioxide (SiO2), zinc oxide (ZnO), etc. The coating 108 is applied to the film through an atomic layer deposition (“ALD”) process. In some configurations, the ALD process is performed under vacuum. In other configurations, the ALD process is performed under atmospheric pressure. In some configurations, the ALD chamber has a temperature below 100 degrees Celsius. The ALD process may be a thermal ALD process or a plasma-enhanced ALD (“PEALD”) process. During the ALD process, a roll of film 100 without coating 108 is fed through an ALD coater, where the film 100 is exposed to metal precursors and oxidizing agents to deposit the desired ALD coating on the film 100. In some configurations, the ALD coating is applied to only one side of the film 100. In other configurations, the ALD coating is applied to both sides of the film 100 during a single pass or multiple passes of the film 100 through the ALD coater. Thus, a metal oxide is deposited on the film 100 (e.g., on the outer layer 104 and / or the inner layer 106) to form the coating 108. In some configurations, the coating 108 is formed to a thickness of 3 nanometers.

[0020] As mentioned above, coating 108 provides a moisture barrier to film 100. After the film is coated with coating 108, film 100 has a moisture content of 4 g / m after film 100 is creased (e.g., as is done when using the film to wrap a package). 2 / day. Creases induce cracking of the coating 108. In some configurations, the film 100 has a moisture vapor transmission rate of less than 2 g / m 2 / day.

[0021] As will be described in more detail below, film 100 can be used to encase a packaged product, sealing the contents of the package from the environment. The resulting packaged product, once packaged in the film, is both moisture-proof and heat-sealable.

[0022] Moisture-proof film manufacturing method In various embodiments, the invention described herein relates to a method for manufacturing the film 100. Referring to Figure 2, a flow diagram of a method 200 for manufacturing a moisture barrier film 100 according to an exemplary embodiment is shown.

[0023] The method 200 begins when the base layer 102 of the film is formed. In some configurations, the base layer 102 is formed by extruding a second material to form the base layer 102 film. The base layer 102 is formed to have a thickness between 13 and 26 microns. In some configurations, the base layer 102 is formed to have a thickness between 16 and 18 microns. As noted above, in some configurations, the second material is a PLA material. The PLA material may be corn-based. In other arrangements, the second material is a bio-based polypropylene.

[0024] At 204, the outer layer 104 is formed. In some configurations, the outer layer 104 is formed by extruding a first material onto one side of the base layer 102. The outer layer 104 is formed to have a thickness of between 1 and 2 microns. As mentioned above, the first material is a PLA material, such as a corn-based PLA material.

[0025] At 206, an inner layer is formed. In some configurations, the inner layer 106 is formed by extruding a first material onto the side of the base layer 102 opposite the outer layer 104. The inner layer 106 is formed to have a thickness of between 1 and 2 microns. As mentioned above, the first material is a PLA material, such as a corn-based PLA material.

[0026] In some configurations, the base layer 102, outer layer 104, and inner layer 206 are formed in a single manufacturing process, such as a co-extrusion manufacturing process.

[0027] At 208, the partially completed film comprising the base layer 102, the outer layer 104, and the inner layer 106 is wound around a core to form a roll of partially completed film. In some configurations, the partially completed film is wound around a core as it exits the extruder. Winding the partially completed film around a core to form a roll of partially completed film allows for easy storage and transportation of the partially completed film.

[0028] At 210, the coating 108 is applied. The partially completed film is fed from a roll into an ALD coater. As the partially completed film is fed through the ALD coater, the coating 108 is deposited on the outer surface of the outer layer 104. The ALD coater may utilize a PEALD process. In some configurations, the ALD chamber of the ALD coater has a temperature of less than 100 degrees Celsius during the ALD coating process. In some configurations, the coating 108 is between 2 and 10 nanometers thick. In further configurations, the coating 108 is 3 nanometers thick. In some configurations, the coating 108 is ATO. In other configurations, the coating 108 is aluminum oxide or titanium oxide. In further configurations, the coating 108 includes other metal oxides, such as silicon dioxide (SiO2), zinc oxide (ZnO), etc. In some embodiments, the ALD coater also applies the coating 108 to the outer surface of the inner layer 106. In such embodiments, the coating 108 may be applied to both sides in a single pass of the film 100 through the ALD coater, or in multiple passes of the film 100 through the ALD coater. The total thickness of the finished film 100 is between 15 and 30 microns thick. In some configurations, the total thickness of the film is 20 microns thick.

[0029] At 212, the finished film 100 is wound around a core to form a roll of finished film 100. After exiting the ALD coater, the film 100 is wound around a core to form a roll of finished film 100. The roll of finished film 100 may be stored for later processing or use. Winding the finished film 100 around a core to form a roll of finished film 100 allows for easy storage and transportation of the finished film 100.

[0030] Packaged in moisture-proof film In various embodiments, the invention described herein relates to a package wrapped in a moisture barrier film 100. For example, the package may be a cigarette pack, such as those described in U.S. Pat. No. 4,852,734 to Allen et al.; U.S. Pat. No. 8,522,515 to Carter et al.; U.S. Pat. No. 8,118,161 to Guerrera et al.; U.S. Pat. No. 7,823,731 to Wu; U.S. Pat. No. 7,228,961 to Koetter et al.; U.S. Pat. No. 7,048,115 to Stringfield; U.S. Pat. No. 7,014,039 to Henson et al.; U.S. Pat. No. 6,364,106 to Fagg et al.; U.S. Pat. No. 5,379,889 to Cobler et al.; U.S. Pat. No. 5,248,031 to Burrows et al.; U.S. Pat. No. 5,139,140 to Burrows et al.; and U.S. Pat. No. 4,807,745 to Langley et al.

[0031] FIG. 3 shows a perspective view of a cigarette pack 300. The cigarette pack 300 includes a top cover 302 and a body 304. The top cover 302 and body 304 are made of at least partially moisture-permeable paper material. As shown in FIG. 4, the top cover 302 can be rotated away from the body 304 along a hinge 402 formed from a fold in the paper material. When the top cover 302 is rotated away from the body 304, a central compartment 404 is revealed. The central compartment 404 is sized and shaped to store cigarettes in any of the manners described in the above-incorporated patent documents. When the top cover 302 is closed (e.g., as shown in FIG. 3), the central compartment 404 is partially sealed from the ambient environment. However, moisture can still pass through the paper material (e.g., into or out of the central compartment 404).

[0032] Thus, after contents (e.g., cigarettes) are loaded into the central compartment 404, the top cover 302 is closed and the pack 300 is packaged in the film 100. As shown in FIG. 5 , the pack 300 is packaged in the film 100. The film 100 is folded and creased to form overlapping flaps 502 and 504. The flaps 502 and 504 are heat sealed. Upon exposure to heat, the outer layer 104 and the inner layer 106 become flexible and partially melt, causing the flaps 502 and 504 to adhere to one another and form a seal between the flaps 502 and 504. After the flaps 502 and 504 are sealed, the film 100 provides a moisture barrier to the pack 300, maintaining the contents in the central compartment at an appropriate humidity level until the film 100 is removed from the pack 300.

[0033] Manufacturing method for cigarette packs wrapped in moisture-proof film In various embodiments, the invention described herein relates to a method of manufacturing a cigarette pack (e.g., cigarette pack 300 as shown in FIG. 5) wrapped in film 100. Referring to FIG. 6, a flow diagram of a method 600 of manufacturing a cigarette pack wrapped in film 100 is shown, according to an exemplary embodiment. Method 600 may be performed by a cigarette pack manufacturing machine.

[0034] The method 500 begins at 602 when the cigarette pack 300 is formed. The cigarette pack 300 is formed by folding a package blank along creases and securing the cigarette pack with an adhesive. At 604, contents are inserted into the cigarette pack 300. The contents may be, for example, cigarettes loaded into the central compartment 404. After the contents are loaded into the cigarette pack 300 at 604, the cigarette pack 300 is closed at 606. The top cover 302 of the cigarette pack 300 is closed. At 608, the cigarette pack 300 is wrapped in a film 100, and the film 100 is sealed at 610. The film 100 is sealed by applying heat to the flaps 502 and 504.

[0035] Many modifications and other embodiments of the disclosures set forth herein will come to mind to one skilled in the art to which these disclosures pertain having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. It is to be understood, therefore, that the disclosure is not limited to the particular embodiments disclosed, and that equivalents, modifications, and other embodiments are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.

Claims

1. a body formed of a paper material; an upper portion formed from the paper material; a central section formed by the top and the body; Packaging materials made from biodegradable films A package comprising: a base layer including a first material that is a bio-based polypropylene and has a first melting point; an outer layer comprising a second material that is polylactic acid and has a second melting point lower than the first melting point, the first surface of the outer layer being bonded to the first surface of the base layer; a moisture-proof coating applied to a second surface of the outer layer, the moisture-proof coating comprising a metal oxide; and A package comprising:

2. 2. The package of claim 1, wherein the film further comprises an inner layer comprising the second material, a first surface of the inner layer bonded to a second surface of the base layer, the second surface of the base layer being opposite the first surface of the base layer.

3. The package of claim 2 , wherein the film further comprises the moisture barrier coating applied to the second surface of the inner layer.

4. 10. The package of claim 1, wherein the polylactic acid is corn-based.

5. The package of claim 1 , wherein the moisture-resistant coating is transparent.

6. 10. The package of claim 1, wherein the moisture barrier coating is at least one of aluminum oxide, titanium oxide, titanium aluminum oxide, silicon dioxide, or zinc oxide.

7. 10. The package of claim 1, wherein the film has a moisture vapor transmission rate of less than 4 grams per square meter per day.

8. 8. The package of claim 7, wherein the film has a moisture vapor transmission rate of less than 2 grams per square meter per day.

9. 10. The package of claim 1, wherein the film is 15 to 30 microns thick.

10. 1. A method for producing a biodegradable film having a moisture-proof coating, comprising: forming a base layer including a first material that is bio-based polypropylene and has a first melting point; forming an outer layer comprising a second material that is polylactic acid and has a second melting point lower than the first melting point, the first surface of the outer layer being bonded to the first surface of the base layer; coating the second surface of the outer layer with a moisture-resistant coating comprising a metal oxide; wherein the second side of the outer layer is opposite the first side of the outer layer.

11. The method of claim 10 , further comprising forming an inner layer comprising the second material, a first surface of the inner layer being bonded to a second surface of the base layer.

12. The method of claim 11 , further comprising coating a second surface of the inner layer with the moisture barrier coating.

13. 11. The method of claim 10, wherein the polylactic acid is corn-based.

14. The method of claim 10, wherein the moisture resistant coating is transparent.

15. 11. The method of claim 10, wherein the moisture resistant coating is at least one of aluminum oxide, titanium oxide, aluminum titanium oxide, silicon dioxide, or zinc oxide.

16. 11. The method of claim 10, wherein the film has a moisture vapor transmission rate of less than 4 grams per square meter per day.

17. 17. The method of claim 16, wherein the film has a moisture vapor transmission rate of less than 2 grams per square meter per day.

18. The method of claim 10, wherein the film is 15 to 30 microns thick.

19. A laminate comprising: a base layer including a first material that is a bio-based polypropylene and has a first melting point; an outer layer comprising a second material that is polylactic acid and has a second melting point lower than the first melting point, the first surface of the outer layer being bonded to the first surface of the base layer; a moisture-proof coating applied to a second surface of the outer layer, the moisture-proof coating comprising a metal oxide; and A biodegradable film comprising:

20. 20. The film of claim 19, further comprising an inner layer comprising the second material, wherein a first surface of the inner layer is bonded to a second surface of the base layer, the second surface of the base layer being opposite the first surface of the base layer.

21. 20. The film of claim 19, wherein the polylactic acid is corn-based.

22. 20. The film of claim 19, wherein the moisture barrier coating is at least one of aluminum oxide, titanium oxide, aluminum titanium oxide, silicon dioxide, or zinc oxide.

Images