Water-based components

Abstract

To provide means for easily solubilizing an oil-based component in an aqueous composition, creating a transparent appearance.SOLUTION: An aqueous composition contains a monovalent-tetravalent alcohol alkylene oxide-added polymer, alkyl glycoside, and oil-based component.SELECTED DRAWING: None

Description

Technical Field

[0001] The present invention relates to an aqueous composition.

Background Art

[0002] Aqueous cosmetics such as lotions are widely used to penetrate the skin and impart a moisturizing feeling. It is common to blend lipophilic components in aqueous cosmetics, and usually the lipophilic components are solubilized in an aqueous medium. Such aqueous cosmetics are more preferably transparent because they can administer lipophilic components and hydrophilic components simultaneously and have excellent aesthetics (Patent Document 1, etc.).

Prior Art Documents

Patent Documents

Patent Document 1

Summary of the Invention

Problems to be Solved by the Invention

[0004] Generally, various oily components are blended in cosmetics, and some of them are difficult to solubilize in aqueous cosmetics. In particular, essential oils, oily fragrances, silicone oils, etc. are said to be more difficult to solubilize than many mineral oils and ester oils. In view of such a situation, an object of the present invention is to provide an aqueous composition in which an oily component is easily and transparently solubilized.

Means for Solving the Problems

[0005] As a result of intensive studies to solve the above problems, the present inventors have found that the above problems can be solved by combining a predetermined nonionic surfactant and an alkyl glycoside, and have completed the present invention.

[0006] That is, the present invention is as follows. [1] An aqueous composition containing a mono-tetravalent alcohol alkylene oxide addition polymer and / or polyoxyalkylene glycol copolymer, an alkyl glycoside, and an oily component. [2] The composition according to [1], wherein the monovalent to tetravalent alcohol alkylene oxide addition polymer is glycerin polyoxyalkylene glycol ether. [3] The composition according to [2], wherein the glycerin polyoxyalkylene glycol ether is an ether of glycerin and polyoxyethylene and polyoxypropylene with an addition number of 20 to 25. [4] The composition according to [1], wherein the polyoxyalkylene glycol copolymer is a copolymer of polyoxyethylene with 5 to 15 additions and polyoxypropylene with 20 to 35 additions. [5] The composition according to any one of [1] to [4], wherein the content of the 1-4 valent alcohol alkylene oxide addition polymer and / or polyoxyalkylene glycol copolymer is 0.1 to 5% by mass with respect to the whole composition. [6] The composition according to any one of [1] to [5], wherein the alkyl glycoside is an alkyl glycoside represented by the following general formula (1).

[0007] [ka] (In the formula, N represents an integer between 2 and 7, R independently represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and n represents an integer between 1 and 4.)

[0008] [7] The composition according to any one of [1] to [6], wherein the content of the alkyl glycoside is 0.01 to 10% by mass relative to the whole composition. [8] The composition according to any one of [1] to [7], wherein the mass ratio of the content of the monovalent to tetravalent alcohol alkylene oxide addition polymer and / or polyoxyalkylene glycol copolymer to the content of the alkyl glycoside is 50:1 to 1:50. [9] The composition according to any one of [1] to [8], wherein the content of the oily component is 0.001 to 5% by mass relative to the whole composition. [Effects of the Invention]

[0009] The present invention provides an aqueous composition in which oily components are transparently solubilized and incorporated. Furthermore, in certain embodiments, the composition becomes more compatible with sebum and penetrates deep into the pores, thus providing an aqueous composition that easily delivers a sense of penetration, moisturizing effects, and the effects of active ingredients. [Modes for carrying out the invention]

[0010] The aqueous composition of the present invention contains a monovalent to tetravalent alcohol alkylene oxide addition polymer and / or polyoxyalkylene glycol copolymer, an alkyl glycoside, and an oily component.

[0011] In the 1-4 valent alcohol alkylene oxide addition polymer contained in the aqueous composition of the present invention, the alkylene oxide is preferably an alkylene oxide having 2 to 4 carbon atoms, specifically polyoxyethylene (also written as POE or PEG), polyoxypropylene (also written as POP or PPG), and polyoxybutylene (also written as POB or PBG). Furthermore, the number of alkylene oxides added is not particularly limited, but each is preferably 2 to 100, more preferably 2 to 60, and even more preferably 6 to 50.

[0012] Preferred addition polymers of 1-4 valent alcohol alkylene oxides include polyoxyalkylene alkyl ethers, such as PPG-2-Buteth-2 (representing "polyoxyethylene (2) polyoxypropylene (2) butyl ether"; the same applies hereinafter), PPG-40 butyl (representing "polyoxypropylene (40) butyl ether"; the same applies hereinafter), PPG-33-Buteth-45, PPG-30-Buteth-30, PPG-5-Buteth-5, PPG-7-Buteth-10, PPG-12-Buteth-12, PPG-15-Buteth-20, and PPG-75-PEG-300 hexylene glycol.

[0013] Furthermore, glycerin polyoxyalkylene glycol ethers are also preferred as 1-4 valent alcohol alkylene oxide addition polymers, such as PPG-8 glyceryl, PPG-16 glyceryl ether, PPG-24 glyceryl-24, PPG-50 glyceryl, glycereth-26, PPG-68-PEG-10 trimethylolpropane, P Examples include PG-14 diglyceryl, PEG-5-PPG-65 pentaerythrityl, and PPG-24 glycereth-24. Of these, ethers of polyoxyethylene with 20 to 25 addition groups and polyoxypropylene with 20 to 25 addition groups and glycerin are more preferred due to their good compatibility with sebum. Specifically, PPG-24 glycereth-24 is particularly preferred.

[0014] In the polyoxyalkylene glycol copolymer contained in the aqueous composition of the present invention, the alkylene oxide is preferably an alkylene oxide having 2 to 4 carbon atoms, and specifically, polyoxyethylene, polyoxypropylene, and polyoxybutylene are preferred. Furthermore, the number of alkylene oxides added is not particularly limited, but each is independently preferably 2 to 100, more preferably 2 to 60, and even more preferably 6 to 50. Specifically, examples include PEG / PPG-5 / 35 copolymer, PEG / PPG-12 / 35 copolymer, PEG / PPG-30 / 33 copolymer, and PEG / PPG-16 / 30 copolymer. Of these, copolymers of polyoxyethylene with 5 to 15 additions and polyoxypropylene with 20 to 35 additions are more preferred due to their good compatibility with sebum. Specifically, PEG / PPG-5 / 35 copolymer, PEG / PPG-12 / 35 copolymer, and PEG / PPG-16 / 30 copolymer are particularly preferred.

[0015] When using a 1- to 4-valent alcohol alkylene oxide addition polymer or a polyoxyalkylene glycol copolymer having good compatibility with sebum as described above, in addition to the solubilizing action of the oily component in the composition, when the composition is applied to the skin, it is compatible with sebum and feels familiar, and particularly the composition can easily penetrate into the pores with a lot of sebum. Therefore, a sense of penetration can be obtained during use, and the composition can spread to the inside of the pores and it is easier to obtain a moisturizing effect and the effect of the active ingredient, which can give satisfaction to the user and is preferable.

[0016] The content of the 1- to 4-valent alcohol alkylene oxide addition polymer and / or polyoxyalkylene glycol copolymer in the aqueous composition of the present invention is preferably 0.1 to 5% by mass, more preferably 0.3 to 4% by mass, and still more preferably 0.5 to 3% by mass in total with respect to the whole composition. By using within such a range, it becomes easier to stably solubilize the oily component.

[0017] The alkyl glycoside that the aqueous composition of the present invention essentially contains is a compound in which an aliphatic alcohol is bonded by a glycosidic bond to a sugar and has a hydrocarbon chain and a sugar residue. The hydrocarbon chain constituting the alkyl glycoside may be either linear or branched, and may be either saturated or unsaturated, but preferably linear or branched saturated hydrocarbons. Also, the number of carbon atoms of the hydrocarbon chain is not particularly limited, but for example, 8 to 35 is preferable, 10 to 22 is more preferable, 12 to 20 is still more preferable, and 12 to 16 is particularly preferable.

[0018] The sugar residue constituting the alkyl glycoside may be any of monosaccharides, oligosaccharides, or polysaccharides. As the degree of condensation of the sugar (i.e., the number of monosaccharides constituting the sugar residue), for example, 1 to 10 is preferable, 1 to 5 is more preferable, and 2 to 3 is even more preferable. Specific examples of the sugar residue include monosaccharides such as glucose, galactose, xylose, mannose, lyxose, arabinose, and fructose; oligosaccharides or polysaccharides such as maltose, xylobiose, isomaltose, cellobiose, lactose, gentiobiose, maltotriose, isomaltotriose, cellotriose, maltotetraose, maltopentaose, maltohexaose, maltoheptaose, isomaltotetraose, isomaltopentaose, isomaltohexaose, and isomaltoheptase. Among these However, preferably, they are monosaccharides, disaccharides, or trisaccharides. More preferably, glucose, galactose, maltose, and maltotriose are included

[0019] As the alkyl glycoside in the present invention, an alkyl glycoside represented by the following general formula (1) is more preferable.

[0020] [Chemical formula]

[0021] In the general formula (1), N represents an integer of 2 to 7. R independently represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, preferably represents a methyl group. n represents an integer of 1 to 4, preferably represents 2 or 3, and more preferably represents 2. That is, the alkyl glycoside represented by the general formula (1) has a structure in which the hydroxyl group at the 1-position of the terminal sugar of the oligosaccharide is bonded (condensed) to an aliphatic alcohol. In addition, such an aliphatic alcohol is preferably an aliphatic alcohol having 12 to 20 carbon atoms, more preferably 12 to 16 carbon atoms, still more preferably 15 carbon atoms, and may have a branch.

[0022] In alkyl glycosides represented by general formula (1), the sugar residue is the hydrophilic part. Examples of sugar residues include maltose, maltotriose, maltotetraose, maltopentaose, maltohexaose, and maltheptaose, with maltose and maltotriose being more preferred.

[0023] In general formula (1), the fatty chain is the hydrophobic portion of the alkyl glycoside according to the present invention. The fatty acid chain portion may or may not have branched chains, but preferably has branched chains. That is, in general formula (1), R independently represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, preferably an alkyl group having 1 to 3 carbon atoms, and more preferably a methyl group.

[0024] As the alkyl glycoside according to the present invention, compounds represented by the following general formula (2) are more preferred.

[0025] [ka]

[0026] In general formula (2), N represents an integer from 2 to 7. n represents an integer from 1 to 4, and is more preferred Alternatively, n is 2 or 3, and more preferably 2. Examples of compounds included in general formula (2) include, but are not limited to, Mal2Far (a glycoside of maltose and hexahydrofarnesol), Mal3Far (a glycoside of maltotriose and hexahydrofarnesol), and Mal3Phyt (a glycoside of maltotriose and hexahydrophytol).

[0027] The alkyl glycosides according to the present invention can be obtained by various well-known methods, such as glycosylation using bromide sugar, glycosylation using fluoride sugar, glycosylation using trichloroacetimidate, and glycosylation using acetylated sugar. More specifically, examples of synthesis steps include those described in Japanese Patent No. 3882067, Japanese Patent No. 4817435, Japanese Patent No. 5207420, Japanese Unexamined Patent Publication No. 2013-129660, and Japanese Unexamined Patent Publication No. 2012-17318.

[0028] The alkyl glycoside content in the aqueous composition of the present invention is preferably 0.01 to 10% by mass, more preferably 0.03 to 5% by mass, and even more preferably 0.05 to 2% by mass, relative to the total composition. Using it within this range makes it easier to stably solubilize oily components.

[0029] The mass ratio of the content of the monovalent to tetravalent alcohol alkylene oxide addition polymer and / or polyoxyalkylene glycol copolymer to the content of the alkyl glycoside in the aqueous composition of the present invention is preferably 50:1 to 1:50, more preferably 20:1 to 1:20, and even more preferably 10:1 to 1:10. Using it within this range makes it easier to stably solubilize oily components.

[0030] The oily components essential to the aqueous composition of the present invention refer to so-called oils or oil-soluble components, and more specifically, to components that undergo phase separation from water after being suspended in water at 25-65°C and allowed to stand for 1 hour. Preferred oily components include essential oils, oily fragrances, and silicone oils.

[0031] Essential oils are mixtures of water-insoluble to sparingly soluble organic compounds found in plants, generally containing volatile organic compounds and possessing aromatic properties depending on the raw materials. The essential oils used in this invention can be those manufactured by conventional methods or those that are commercially available. The part from which the essential oil is extracted in this invention is not particularly limited and may include flowers, branches, leaves, roots, fruits, buds, etc., but the whole plant can also be used. Furthermore, the method for extracting essential oils in the present invention is not particularly limited and includes steam distillation, solvent extraction, pressing, adsorption / absorption, leaching, and methods for recovering liquid exuded by damaging plants, but steam distillation is preferred.

[0032] Oily fragrances are fragrances that are oil-soluble and can be used regardless of whether they are synthetic or natural. Furthermore, those manufactured by conventional methods or commercially available products can also be used.

[0033] As essential oils and oily fragrances, but not limited to, examples include acetylcedrene, amyl cinnamaldehyde, allyl amyl glycolate, β-ionone, iso-esuper, isobutylquinoline, iris oil, ylone, indole, ylang-ylang oil, undecanal, undecenal, γ-undecalactone, estragol, eugenol, oakmoss, opoponax resinoid, orange oil, eugenol, aurantiol, galacsolid, carvacrol, L-carbone, camphor, canone, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile, isobornyl acetate, geranyl acetate, dimethylbenzylcarbinyl acetate, styraryl acetate, cedyl acetate, terepinel acetate, pt-butylcyclohexyl acetate, vetiveryl acetate, benzyl acetate, linalyl acetate, saturates Isopentyl lycylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanol, methyl dihydrojasmonate, dihydromyrcenol, jasmine absolute, jasmine lactone, cis-jasmone, citral, citronenol, citronellal, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, styrax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascone, damascenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, tripral, nerol, nonanal, 2,6-nonadienol, nonalactone, patchouli alcohol, vanilla abscess Examples include rose absolute, vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitgrain oil, hexyl cinnamaldehyde, cis-3-hexenol, Peruvian balsam, vetiver oil, vetiverol, peppermint oil, pepper oil, heliotropin, bergamot oil, benzyl benzoate, borneol, myrrhizinoid, musk ketone, methyl nonylacetaldehyde, γ-methylionone, menthol, L-menthol, L-menthone, eucalyptus oil, β-ionone, lime oil, lavender oil, D-limonene, linalool, liral, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, etc.

[0034] Examples of silicone oils include dimethylpolysiloxane (dimethicone), cyclopentasiloxane, decamethylcyclopentasiloxane, caprylyl methicone, (dimethicone / vinyl dimethicone) crosspolymer, and (dimethicone / phenylvinyl dimethicone) crosspolymer. - are some examples.

[0035] In addition, other oily components besides essential oils, oily fragrances, and silicone oils include other oils, specifically polar oils, natural oils, and hydrocarbon oils.

[0036] As polar oils, synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearylate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexylate, trimethylolpropane triisostearate, pentaneerythritol tetra-2-ethylhexylate, and tri -2-Glyceryl ethylhexanoate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, glyceride tri-2-heptyl undecanoate, methyl castor oil fatty acid ester, oleic acid oil, cetostearyl alcohol, acetoglyceride, 2-heptyl undecyl palmitate, diisobutyl adipate, N-lauroyl- Examples include L-glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebatate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebatate, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, amyl acetate, triethyl citrate, octyl methoxycinnamate, and the like.

[0037] Natural oils include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, peach oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, hen oil, soybean oil, and peanut oil. Examples include tea seed oil, kaya oil, rice bran oil, cinnamon oil, Japanese tung oil, jojoba oil, wheat germ oil, sunflower oil, triglycerin, glyceryl trioctanoate, and glyceryl triisopalmitate.

[0038] Examples of hydrocarbon oils include isododecane, isohexadecane, squalane, hydrogenated poly(C6-12) olefin, and hydrogenated polyisobutene.

[0039] The aqueous composition of the present invention may use one or more oily components in combination.

[0040] The oily component content in the aqueous composition of the present invention is preferably 0.001 to 5% by mass, more preferably 0.01 to 1% by mass, and even more preferably 0.1 to 0.5% by mass, as a total amount of the oily component alone or in combination, relative to the entire composition. From the viewpoint of solubilization stability, 5% by mass or less is preferred, and from the viewpoint of the effect on the composition, 0.001% by mass or more is preferred.

[0041] The aqueous composition of the present invention can be produced by conventional methods. That is, the mixing order is not particularly limited, and it can be obtained by mixing and solubilizing the constituent components in any order and method.

[0042] The aqueous composition of the present invention typically uses water as its main medium. Specifically, it contains water in an amount of preferably 50% by mass or more, more preferably 55% by mass or more, and even more preferably 60% by mass or more of the total composition. The aqueous composition of the present invention is in a so-called solubilized form, where the constituent components are soluble in water, and is therefore usually transparent. However, if it contains hydrophobic powders or the like, these may settle upon standing, resulting in a transparent medium portion. In this specification, transparency can be determined by visually confirming the absence of sediment or turbidity, or quantitatively by a visible light transmittance (wavelength 600 nm, optical path length 1 cm) measured with a spectrophotometer at 25°C, which is in the range of 70 to 100, with the control distilled water set to 100.

[0043] The aqueous composition of the present invention is preferably in the form of a topical skin preparation, and more specifically, in the form of a cosmetic, quasi-drug, or pharmaceutical.

[0044] The aqueous composition of the present invention may optionally contain other components, as long as they do not impair the effects of the present invention. Such optional ingredients can be anything commonly used in topical skin preparations such as cosmetics, and examples include alcohols, ethers, powders, humectants, surfactants other than 1-4 valent alcohol alkylene oxide addition polymers and alkyl glycosides, metal ion chelating agents, pearlescent agents, amino acids, organic amines, polymer emulsions, pH adjusters, vitamins, antioxidants, preservatives, water-soluble polymers, and various active ingredients.

[0045] Examples of alcohols include dihydric alcohols such as ethylene glycol, 1,3-butylene glycol, trimethylene glycol, 1,2-butylene glycol, propylene glycol, dipropylene glycol, propanediol, 1,2-pentanediol, 3-methyl-1,3-butanediol, tetramethylene glycol, 2,3-butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, and octylene glycol; trihydric alcohols such as trimethylolpropane; tetrahydric alcohols such as pentaerythritol; pentahydric alcohols such as xylitol; polyhydric alcohol polymers such as triglycerin, tetraglycerin, and polyglycerin; sugar alcohols such as starch-degrading sugar-reducing alcohols; and polyglycerin. Alcohol alkyl ethers such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol mono-2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, and ethylene glycol isopropyl ether; Alcohol alkyl ethers such as diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, dipropylene glycol ethyl ether, and dipropylene glycol butyl ether; Glycerin monoalkyl ethers such as xyl alcohol, ceracyl alcohol, and batyl alcohol; Alcohol polymers such as diethylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, and polyethylene glycol; Examples include glycolid; tetrahydrofurfuryl alcohol; POE-tetrahydrofurfuryl alcohol; POP-butyl ether; POP·POE-butyl ether; tripolyoxypropylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphate; POP·POE-pentaneerythritol ether, etc.

[0046] Ethers include those that fall under the category of alcohols mentioned above, Examples include ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol methyl ethyl ether, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol diazibate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, and propylene glycol monophenyl ether acetate.

[0047] The shape of the powder is not particularly limited, and can be spherical, needle-shaped, plate-shaped, etc. Examples include inorganic powders (e.g., talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, red mica, biotite, vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, tungstate metal salts, magnesium, silica, alumina, zeolite, barium sulfate, calcined calcium sulfate (calcined gypsum), calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, boron nitride, etc.); organic powders (e.g., polyamide resin powder (nylon powder), polyethylene powder, poly(meth)acrylate powder, polystyrene powder, styrene-acrylic acid copolymer resin powder, silicone resin powder, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, etc.); metal soaps (e.g., Zinc lysitate, calcium palmitate, aluminum stearate; inorganic white pigment (For example, titanium dioxide, zinc oxide, etc.); inorganic red pigments (for example, iron oxide (red iron oxide), iron titanate, etc.); inorganic brown pigments (for example, γ-iron oxide, etc.); inorganic yellow pigments (for example, yellow iron oxide, yellow ochre, etc.); inorganic black pigments (for example, black iron oxide, lower titanium oxide, etc.); inorganic purple pigments (for example, mango violet, cobalt violet, etc.); inorganic green pigments ( For example, chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (for example, ultramarine, Prussian blue, etc.); pearl pigments (for example, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, etc.); metal powder pigments (for example, aluminum powder, copper powder, etc.); organic pigments such as zirconium, barium, or aluminum lake (for example, Red No. 201, Red No. 2 Examples include organic pigments such as No. 02, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, and Blue 404; Red 3, Red 104, Red 106, Red 227, Red 230, Red 401, Red 505, Orange 205, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Green 3, and Blue 1; and natural pigments (e.g., chlorophyll, β-carotene, etc.).

[0048] Examples of moisturizing agents include chondroitin sulfate, hyaluronic acid, mucoitin sulfate, carotenoid acid, atelocollagen, cholesteryl-12-hydroxystearate, sodium lactate, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO)PO adduct, Rosa rugosa extract, Achillea millefolium extract, and Melilotus extract.

[0049] Other surfactants besides 1-4 valent alcohol alkylene oxide addition polymers, polyoxyalkylene glycol copolymers, and alkyl glycosides include anionic surfactants, cationic surfactants, amphoteric surfactants, and nonionic surfactants other than 1-4 valent alcohol alkylene oxide addition polymers and polyoxyalkylene glycol copolymers (other nonionic surfactants).

[0050] Examples of anionic surfactants include fatty acid soaps (e.g., sodium laurate, sodium palmitate, etc.); higher alkyl sulfate salts (e.g., sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfate salts (e.g., POE lauryl sulfate triethanolamine, POE lauryl sulfate sodium, etc.); N-acyl sarcosinate (e.g., sodium lauroyl sarcosinate, etc.); higher fatty acid amide sulfonates (e.g., sodium N-myristoyl-N-methyl taurate, sodium coconut oil fatty acid methyl taulide, sodium lauryl methyl taulide, etc.); phosphate salts (e.g., sodium POE oleyl ether phosphate, POE stearyl ether phosphate, etc.); sulfosuccinates (e.g., sodium di-2-ethylhexyl sulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, lauryl polypropylene glycol sulfosuccinate) Examples include sodium citrate, alkylbenzene sulfonates (e.g., linear dodecylbenzenesulfonate sodium, linear dodecylbenzenesulfonate triethanolamine, linear dodecylbenzenesulfonate, etc.), higher fatty acid ester sulfates (e.g., hydrogenated coconut oil fatty acid glycerin sulfate sodium, etc.), N-acyl glutamates (e.g., N-lauroyl glutamate monosodium, N-stearoyl glutamate disodium, N-myristoyl-L-glutamate monosodium, etc.), sulfated oils (e.g., belladonna oil, etc.), POE alkyl ether carboxylic acids, POE alkyl allyl ether carboxylic acid salts, α-olefin sulfonates, higher fatty acid ester sulfonates, secondary alcohol sulfates, higher fatty acid alkylolamide sulfates, lauroyl monoethanolamide succinate sodium, N-palmitoyl aspartate ditriethanolamine, sodium caseinate, etc.

[0051] Examples of cationic surfactants include alkyltrimethylammonium salts (e.g., stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (e.g., cetylpyridinium chloride, etc.); distearyldimethylammonium chloride dialkyldimethylammonium salt; poly(N,N'-dimethyl-) chloride 3,5-Methylenepiperidinium; alkylquaternary ammonium salt; alkyldimethylbe Examples include diammonium salts; alkylisoquinolinium salts; dialkylmolionium salts; POE alkylamines; alkylamine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride, etc.

[0052] Examples of amphoteric surfactants include imidazoline-based amphoteric surfactants (e.g., 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, etc.); and betaine-based surfactants (e.g., 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkyl betaine, amide betaine, sulfobetaine, etc.).

[0053] Other nonionic surfactants include polyether-modified silicones (e.g., polyethylene glycol-10 dimethicone, polyethylene glycol-12 dimethicone, etc.); polyglycerin-modified silicones (e.g., polyglyceryl-3 disiloxane dimethicone, polyglyceryl-3 polydimethylsiloxyethyl dimethicone, etc.); sorbitan fatty acid esters (e.g., sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, penta- Examples of non-hydrophilic nonionic surfactants include: diglycerol sorbitan 2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate, etc.; glycerin fatty acids (e.g., monocottonseed oil fatty acid glycerin, monoerucate glycerin, sesquioleate glycerin, monostearate glycerin, α,α'-oleate pyroglutamate glycerin, monostearate glycerin malic acid, etc.); propylene glycol fatty acid esters (e.g., propylene glycol monostearate, etc.); POE castor oil and hydrogenated castor oil derivatives (POE castor oil, POE hydrogenated castor oil, etc.); and glycerin alkyl ethers.Furthermore, polyglycerin fatty acid esters (e.g., polyglyceryl monooleate, polyglyceryl monostearate, etc.); POE sorbitan fatty acid esters (e.g., POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan tetraoleate, etc.); POE sorbitan fatty acid esters (e.g., POE sorbitan monolaurate, POE sorbitan monooleate, POE sorbitan pentaoleate, POE sorbitan monostearate, etc.); POE glycerin fatty acid esters (e.g., POE glycerin monostearate, POE glycerin monoisosulfate, etc.) POE monooleates such as thearates and POE glycerin triisostearate); POE fatty acid esters (e.g., POE distearate, POE monodioleate, ethylene glycol distearate, etc.); POE alkyl ethers (e.g., POE lauryl ether, POE oleyl ether, POE stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE cholestanol ether, etc.); POE alkylphenyl ethers (e.g., POE nonylphenyl ether, etc.); Pluronic® type (e.g., Pluronic, etc.); Tetra POE-TetraPOP ethylenediamine. Other examples include condensates (e.g., tetronic); POE castor oil hydrogenated castor oil derivatives (e.g., POE castor oil, POE hydrogenated castor oil, POE hydrogenated castor oil monoisostearate, POE hydrogenated castor oil triisostearate, POE hydrogenated castor oil monopyroglutamic acid monoisostearate diester, POE hydrogenated castor oil maleic acid, etc.); POE beeswax / lanolin derivatives (e.g., POE sorbitol beeswax, etc.); alkanolamides (e.g., coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE propylene glycol fatty acid esters; POE alkylamines; POE fatty acid amides; sucrose fatty acid esters; other alkyl glycosides; alkylethoxydimethylamine oxide; and hydrophilic nonionic surfactants such as trioleyl phosphate.

[0054] However, it is preferable that the aqueous cosmetic composition of the present invention substantially does not contain other surfactants other than monovalent to tetravalent alcohol alkylene oxide addition polymers, polyoxyalkylene glycol copolymers, and alkyl glycosides. Here, "substantially absent" means that the content of other surfactants is preferably 3% by mass or less, more preferably 1% by mass or less, and even more preferably 0.5% by mass or less of the total cosmetic composition.

[0055] Examples of metal ion chelating agents include 1-hydroxyethane-1,1-diphosphonic acid, tetrasodium 1-hydroxyethane-1,1-diphosphonic acid, disodium edetate, trisodium edetate, tetrasodium edetate, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetate, and trisodium ethylenediaminehydroxyethyl triacetate.

[0056] Examples of pearlescent agents include glycol distearate and titanium mica.

[0057] Examples of amino acids include neutral amino acids (e.g., threonine, cysteine, etc.) and basic amino acids (e.g., hydroxylysine, etc.). Examples of amino acid derivatives include sodium acyl sarcosinate (sodium lauroyl sarcosinate), and acyl sarcosinate. Examples include glutamate, acyl β-alanine sodium, glutathione, and pyrrolidone carboxylic acid.

[0058] Examples of organic amines include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol.

[0059] Examples of polymer emulsions include acrylic resin emulsion, ethyl polyacrylate emulsion, acrylic resin liquid, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, and natural rubber latex.

[0060] Examples of pH adjusting agents include buffering agents such as lactate-sodium lactate, citrate-sodium citrate, and succinate-sodium succinate.

[0061] Examples of vitamins include vitamins A, B1, B2, B6, C, E and their derivatives. Examples include pantothenic acid and its derivatives, biotin, and the like.

[0062] Examples of antioxidants include tocopherols, dibutylhydroxytoluene (BHT), butylhydroxyanisole, pyrosulfites, gallic acid esters, phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphorate, phytic acid, and ethylenediaminetetraacetic acid.

[0063] Examples of preservatives include parabens and phenoxyethanol.

[0064] Examples of water-soluble polymers include plant-derived polymers (e.g., carrageenan, starch (co (Corn, potato, wheat), glycyrrhizic acid); microbial polymers (for example) For example, dextran, pullulan, etc.; natural water-soluble polymers such as animal-derived polymers (e.g., collagen, casein, albumin, gelatin, etc.), Starch-based polymers (e.g., carboxymethyl starch, methylhydroxypropyl starch, etc.); Cellulose-based polymers (hydroxypropylmethylcellulose, hydroxypropyl Chill cellulose, hydroxypropyl cellulose, methylcellulose, ethylcellulose, hydroxypropyl methylcellulose stearoxyl ether, sodium cellulose sulfate, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder, etc.); Examples of water-soluble polymers used in the synthesis of vinyl polymers (e.g., polyvinyl alcohol, polyvinyl methyl ether, polyvinylpyrrolidone, carboxyvinyl polymer, etc.); polyoxyethylene polymers (e.g., polyethylene glycol 20,000, 40,000, 60,000, etc.); acrylic polymers (e.g., sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimines; and cationic polymers.

[0065] Various active ingredients include, for example, anti-inflammatory agents (e.g., glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); whitening agents (e.g., placenta extract, saxifrage extract, arbutin, etc.); various extracts (e.g., Phellodendron amurense, Coptis japonica, Lithospermum erythrorhizon, Paeonia lactiflora, Swertia japonica, Birch, Sage, Loquat, Carrot, Aloe vera, Malva sylvestris, Iris ensata, Grape, Coix lacryma-jobi, Luffa gourd, Lily, Saffron, Cnidium officinale, Zingiber officinale, St. John's wort, Ononis sprouts, Garlic, Chili pepper, Citrus unshiu peel, Angelica acutiloba, Seaweed, etc.); and activators (e.g., royal jelly). Examples include photosensitizers, cholesterol derivatives, etc.; blood circulation promoters (e.g., nonyl valenylamide, benzyl nicotinate, β-butoxyethyl nicotinate, capsaicin, gingerol, cantharis tincture, ichthamol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cepharanthine, γ-oryzanol, etc.); anti-seborrheic agents (e.g., sulfur, thianthol, etc.); and anti-inflammatory agents (e.g., tranexamic acid, thiotaurine, hypotaurine, etc.). [Examples]

[0066] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to the following examples unless it exceeds the essence of the invention.

[0067] <Example Test> Aqueous compositions were prepared by mixing the formulation components listed in Table 1. For each aqueous composition obtained, the solubility of the composition was evaluated by a skilled evaluator. The results are shown in Table 1.

[0068] [Table 1]

[0069] <Transparency> Transparency immediately after manufacturing was evaluated according to the following criteria. ◎: Transparent ○: It is almost transparent. △: Slight turbidity or separation is observed. ×: Turbidity or separation is observed.

[0070] <Original> The presence or absence of sediment after 24 hours at 0°C following manufacturing was evaluated according to the following criteria. ○: Does not accept Ori ×: Acknowledge the culprit

[0071] <Skin compatibility> When the composition was applied to the cheek, experienced evaluators conducted a sensory evaluation of how well the composition blended into the skin and spread deep within (penetration) based on the following criteria. ◎: Excellent penetration. ○: Good absorption. △: Does not penetrate well ×: Does not penetrate well

[0072] <Example of a sample exam> The compatibility of various surfactants shown in Table 2 with sebum components was investigated using the following procedure. Surfactants and oleic acid (corresponding to sebum components) were mixed at 25°C in the amounts shown in Table 2, and compatibility was visually confirmed and evaluated according to the following criteria. Furthermore, the solubilization state was observed when small amounts of water were added dropwise to the compatible mixture and mixed by stirring, and the maximum solubilization amount (g) was measured. The results are shown in Table 2. ○: The surfactant and oleic acid are compatible and further soluble due to water retention. △: The surfactant and oleic acid are compatible, but there is no water-retaining property. ×: Surfactants and oleic acid are incompatible.

[0073] [Table 2] [Industrial applicability]

[0074] The present invention provides an aqueous composition in which oily components are transparently solubilized and incorporated. Furthermore, in certain embodiments, the composition becomes more compatible with sebum and penetrates deep into the pores, resulting in a more easily absorbed feel. Such a composition is suitable for topical skin preparations such as cosmetics, and is highly industrially useful as it meets the needs of consumers seeking excellent functionality and a pleasant appearance.

Claims

1. An aqueous composition containing 0.1 to 5% by mass of a monovalent to tetravalent alcohol alkylene oxide addition polymer and / or polyoxyalkylene glycol copolymer, 0.01 to 10% by mass of an alkyl glycoside represented by the following general formula (1), and 0.001 to 5% by mass of an oily component. 【Chemistry 1】 (In the formula, N represents an integer from 2 to 7, R independently represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and n represents an integer from 1 to 4.)

2. The composition according to claim 1, wherein the monovalent to tetravalent alcohol alkylene oxide addition polymer is glycerin polyoxyalkylene glycol ether.

3. The composition according to claim 2, wherein the glycerin polyoxyalkylene glycol ether is an ether of glycerin with polyoxyethylene and polyoxypropylene having 20 to 25 additions.

4. The composition according to claim 1, wherein the polyoxyalkylene glycol copolymer is a copolymer of polyoxyethylene with 5 to 15 additions and polyoxypropylene with 20 to 35 additions.

5. The mass ratio of the content of the monovalent to tetravalent alcohol alkylene oxide addition polymer and / or polyoxyalkylene glycol copolymer to the content of the alkyl glycoside is 5 The composition according to any one of claims 1 to 4, wherein the ratio is 0:1 to 1:50.

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