Oil-based solid cleansing cosmetic

A specific formulation of solid oil, nonionic surfactants, and charcoal powder with controlled ratios and water prevents agglomeration and sedimentation, ensuring uniformity and effective makeup removal in oil-based solid cleansing cosmetics.

JP7864429B2Active Publication Date: 2026-05-25MANDOM CORP
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Patent Information

Authority / Receiving Office
JP · JP
Patent Type
Patents
Current Assignee / Owner
MANDOM CORP
Filing Date
2022-07-12
Publication Date
2026-05-25

AI Technical Summary

Technical Problem

Oil-based solid cleansing cosmetics face issues with agglomeration and sedimentation of charcoal powder due to its properties, leading to uneven composition when incorporated before solidification.

Method used

A composition containing solid oil, specific nonionic surfactants with HLB values of 2 to 6 and 8 to 15, charcoal powder with a median diameter of 1 to 35 μm, and water, in predetermined ratios, ensures uniform dispersibility of charcoal powder without aggregation or sedimentation.

Benefits of technology

The cosmetic maintains excellent dispersibility of charcoal powder, providing effective makeup removal and rinsing without residue, while remaining solid at room temperature.

✦ Generated by Eureka AI based on patent content.

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Abstract

To provide oil-based solid cleansing cosmetics that contain charcoal powder but prevent the aggregation and sedimentation of the charcoal powder and ensure sufficient dispersion of the charcoal powder.SOLUTION: Oil-based solid cleansing cosmetics contain the following component A of 4.0-20 mass%, the following component B of 50-90 mass%, the following component C of 0.01-5.0 mass%, the following component D of 8-22 mass%, the following component E of 0.01-5.0 mass%, and the following component F of 0.5-6.0 mass%. Component A: a solid oil with a melting point of 50-120°C, component B: a liquid oil, component C: a nonionic surfactant with an HLB value of 2-6, component D: a nonionic surfactant with an HLB value of 8-15, component E: charcoal powder with a volume-based median size of 1-35 μm and component F: water.SELECTED DRAWING: None
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Description

Technical Field

[0001] The present invention relates to an oil-based solid cleansing cosmetic.

Background Art

[0002] In recent years, oil-based solid cleansing cosmetics for removing makeup cosmetics have been proposed. Since the oil-based solid cleansing cosmetic is solid at normal temperature, there is no dripping during use, and since it is an oil-based cleansing cosmetic mainly composed of solid oil, liquid oil, and nonionic surfactant, it has the characteristic of excellent makeup removal performance.

[0003] Patent Document 1 discloses that a solid oil-based cleansing cosmetic having good compatibility with makeup cosmetics, excellent dirt removal, and excellent refreshing feeling after washing can be obtained by containing a hydrocarbon oil having a melting point of 60 to 1 - 20 °C, an ester oil, and a predetermined amount of a nonionic surfactant. However, it does not disclose blending powder components such as carbon powder.

[0004] [[ID= twenty]]In addition, Patent Document 2 discloses that by containing powder and fumed silica in a specific ratio together with a solid oil component, a liquid oil, and a nonionic surfactant having a specific HLB value, an oil-based solid cleansing cosmetic having no dripping, high cleansing power and massage effect, excellent ease of rinsing and refreshing feeling after rinsing, and excellent quality stability can be obtained. However, it does not disclose a technique for uniformly blending carbon powder.

Prior Art Documents

Patent Documents

[0005]

Patent Document 1

Patent Document 2

Summary of the Invention

[0006] Oil-based solid cleansing cosmetics are prepared by melting and solidifying the aforementioned main component and other components. Therefore, when components that have properties of agglomeration and sedimentation, such as charcoal powder, are incorporated, agglomeration and sedimentation tend to occur before solidification, resulting in a problem of an uneven composition.

[0007] The object of the present invention is to provide an oily solid cleansing cosmetic composition that, despite containing charcoal powder, exhibits excellent dispersibility of charcoal powder without aggregation or sedimentation of the charcoal powder. [Means for solving the problem]

[0008] As a result of diligent research to solve the above problems, the inventors of the present invention have found that by creating an oily solid cleansing cosmetic composition containing solid oil, liquid oil, a nonionic surfactant with an HLB value of 2 to 6, a nonionic surfactant with an HLB value of 8 to 15, a predetermined charcoal powder, and water, an oily solid cleansing cosmetic composition with excellent uniformity can be obtained without the charcoal powder agglomerating or settling, thus completing the present invention.

[0009] In other words, the present invention relates to an oily solid cleansing cosmetic composition containing 4.0 to 20% by mass of component A, 50 to 90% by mass of component B, 0.01 to 5.0% by mass of component C, 8 to 22% by mass of component D, 0.01 to 5.0% by mass of component E, and 0.5 to 6.0% by mass of component F. Component A: Solid oil with a melting point of 50-120°C Ingredient B: Liquid oil Component C: Nonionic surfactant with an HLB value of 2-6 Component D: Nonionic surfactant with an HLB value of 8-15 Component E: Carbon powder with a median diameter of 1-35 μm by volume. Ingredient F: Water [Effects of the Invention]

[0010] The oil-based solid cleansing cosmetic of the present invention, despite containing charcoal powder, exhibits excellent dispersibility of charcoal powder without aggregation or sedimentation. [Modes for carrying out the invention]

[0011] The oil-based solid cleansing cosmetic composition of the present invention is characterized by containing predetermined amounts of a solid oil (component A) having a melting point of 50 to 120°C, a liquid oil (component B), a nonionic surfactant (component C) with an HLB value of 2 or more and less than 6, a nonionic surfactant (component D) with an HLB value of 8 to 15, charcoal powder (component E) with a volume-based median diameter of 1 to 35 μm, and water (component F).

[0012] In other words, the oil-based solid cleansing cosmetic composition of the present invention contains at least component A, component B, component C, component D, component E, and component F. Depending on the desired feel and other factors, the oil-based solid cleansing cosmetic composition of the present invention may further contain components other than the essential components A to F. Each of the components A to F and other components contained in the oil-based solid cleansing cosmetic composition of the present invention may be used individually or in combination of two or more.

[0013] The oil-based solid cleansing cosmetic of the present invention is solid at room temperature, so it does not drip during use, and because it is an oil-based cleansing cosmetic mainly composed of solid oil, liquid oil, and a nonionic surfactant, it has the characteristic of having excellent makeup removal performance. Furthermore, the oil-based solid cleansing cosmetic of the present invention contains a predetermined amount of charcoal powder, the amounts of components A and B are within a predetermined range, and predetermined amounts of components C and F are also included, so despite containing charcoal powder, the charcoal powder does not aggregate or settle, and the charcoal powder has the characteristic of having excellent dispersibility.

[0014] The essential components A to F of the oil-based solid cleansing cosmetic composition of the present invention are described below.

[0015] [Component A] Component A is solid at 25°C and is a solid oil with a melting point of 50 to 120°C. In this specification, "solid at 25°C" means a property without fluidity at 25°C. Also, the melting point of Component A can be measured by the second method of the melting point measurement method, which is a general test method for quasi-drugs raw material specifications.

[0016] From the viewpoints of moldability, which can be molded into a uniform solid shape during preparation, and stability over time, the melting point of Component A is 50°C or higher, preferably 55°C or higher, more preferably 60°C or higher. Also, from the viewpoints of finger pickability during use and the feel during application (usability), the melting point of Component A is 120°C or lower, preferably 115°C or lower, more preferably 110°C or lower.

[0017] Examples of Component A include wax esters such as animal and plant waxes, mineral waxes, and hydrocarbon waxes.

[0018] Examples of the above animal and plant waxes include carnauba wax, sunflower seed wax, candelilla wax, beeswax, shellac wax, rice wax, rice bran wax, shellac wax, and spermaceti wax.

[0019] Examples of the above mineral waxes include montan wax.

[0020] The above hydrocarbon wax may be a petroleum-derived wax or a synthetic wax. Examples of the above hydrocarbon waxes include, for example, ceresin, ozokerite, paraffin wax, microcrystalline wax, polyethylene wax, ethylene-propylene copolymer, and Fischer-Tropsch wax (synthetic wax).

[0021] From the viewpoint of obtaining a uniform oily solid cleansing cosmetic that is less likely to oxidize during heating, hydrocarbon wax is preferred as Component A, and microcrystalline wax and Fischer-Tropsch wax (synthetic wax) are more preferred.

[0022] The content of component A in the oil-based solid cleansing cosmetic of the present invention is 4.0 to 20% by mass, preferably 4.2 to 18% by mass, and more preferably 4.4 to 16% by mass. When the above content is 4.0% by mass or more, the moldability is excellent, and the effect of suppressing the aggregation and sedimentation of carbon powder is excellent. Further, when the above content is 20% by mass or less, the usability is excellent, and the disintegration during transportation or the like caused by excessive hardening can be suppressed. The content of the above component A is the total content of all component A in the oil-based solid cleansing cosmetic of the present invention.

[0023] [Component B] Component B is a liquid oil and includes an oil component having a fluid property at 25°C, a semi-solid oil component having a melting point of less than 50°C, and a volatile oil component having a boiling point of less than 260°C. By using component B, it becomes easy to pick up with fingers during use, and an oil-based solid cleansing cosmetic excellent in elongation and makeup compatibility during application can be obtained.

[0024] Examples of component B include ester oil, animal and vegetable oil, hydrocarbon oil, silicone oil, higher fatty acid, higher alcohol, and the like.

[0025] The above ester oils include isocetyl isostearate, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octanoate, pentaerythryl tetraoctanoate, glyceride tri-2-heptylundecanoate, diisobutyl adipate, 2-hexyldecyl sebacate, glycerin trioctanoate, glycerin triisopalmitate, and diiso malate. Stearyl, isopropyl myristate, 2-octyldodecyl oleate, hexyldecyl dimethyloctanoate, 2-hexyldecyl myristate, myristyl myristate, octyldodecyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, butyl stearate, isocetyl stearate, decyl oleate, dodecyl oleate, oleyl oleate, myristyl lactate, cetyl lactate , 12-Hydroxystearate Cholesteryl, Castor Oil Fatty Acid Methyl Ester, 2-Ethylhexyl Succinate, 2-Hexyldecyl Adipate, Di-2-Heptylundecyl Adipate, Diisopropyl Sebatate, Di-2-Ethylhexyl Sebatate, Neopentyl Glycol Dicaprate, Neopentyl Glycol Dioctanoate, Glycerin Tri-2-Ethylhexanoate, Glycerin Trimyristate, Glyceride Tri-2-Heptylundecanoate, Trimethylol Triisostearate Examples include lupropane, glyceryl tri-2-ethylhexanoate, glyceryl trioctanoate, glyceryl triisopalmitate, triglycerin, isopropyl myristate, isopropyl palmitate, hexyl laurate, oleyl oleate, decyl oleate, octyldodecyl myristate, hexyldecyl dimethyloctanoate, diethyl phthalate, dibutyl phthalate, dioctyl succinate, fluorine-modified ester oil, trioctanoin, and tripropylene glycol dipivalate.

[0026] Examples of the above-mentioned animal and vegetable oils include linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, avocado oil, sasanqua oil, castor oil, safflower oil, apricot kernel oil, cinnamon oil, jojoba oil, grape oil, sunflower oil, almond oil, rapeseed oil, sesame oil, wheat germ oil, rice germ oil, rice bran oil, cottonseed oil, soybean oil, peanut oil, tea seed oil, evening primrose oil, egg yolk oil, beef tallow, and liver oil.

[0027] Examples of the above-mentioned hydrocarbon oils include α-olefin oligomers, light isoparaffins, light liquid isoparaffins, liquid isoparaffins, liquid paraffins, synthetic squalane, vegetable squalane, polybutene, hydrogenated polyisobutene, and petrolatum.

[0028] Examples of the above-mentioned silicone oils include linear silicones such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane; cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane; amino-modified silicone oils; polyether-modified silicone oils; carboxy-modified silicone oils; alkyl-modified silicone oils; ammonium salt-modified silicone oils; and fluorine-modified silicone oils.

[0029] Examples of the above-mentioned higher fatty acids include oleic acid, tall oil fatty acids, and isostearic acid.

[0030] Examples of the above-mentioned higher alcohols include lauryl alcohol, oleyl alcohol, isostearyl alcohol, octyldodecanol, and jojoba alcohol.

[0031] The content of component B in the oil-based solid cleansing cosmetic of the present invention is 50 to 90% by mass, preferably 60 to 88% by mass, and more preferably 70 to 86% by mass. When the above content is 50% by mass or more, it is excellent in terms of how easily it comes off with fingers during use and how easily it spreads and blends during application. When the above content is 90% by mass or less, it is excellent in terms of moldability. The above content of component B is the total content of all component B in the oil-based solid cleansing cosmetic of the present invention.

[0032] [Component C] Component C is a nonionic surfactant with an HLB value of 2 to 6. Nonionic surfactants with an HLB value of 6 or less are nonionic surfactants with low hydrophilicity and high lipophilicity. When such nonionic surfactants are incorporated into oil-based solid cleansing cosmetics, even when trying to wash them off with water or lukewarm water after cleansing, they are difficult to rinse off due to their low affinity for water, and it takes time for the slippery feeling of the cleansing cosmetic to disappear. For this reason, the incorporation of nonionic surfactants with low HLB values ​​into oil-based solid cleansing cosmetics is generally avoided. However, by using a specific amount of component C and water in combination with charcoal powder, the above problems can be avoided, and the aggregation and sedimentation of the charcoal powder can be suppressed.

[0033] The HLB value of component C is 2 to 6, preferably 2 to 5, and more preferably 2 to 4. By having the above HLB value within this range, aggregation and sedimentation of the charcoal powder can be effectively suppressed.

[0034] Component C is not particularly limited as long as it is a nonionic surfactant with an HLB value of 2 to 6, but examples include polyglyceryl-2 triisostearate, PEG-20 hydrogenated castor oil triisostearate, PEG-5 glyceryl triisostearate, glyceryl monostearate, diglyceryl monostearate, decaglyceryl pentastearate, sorbitan sesquistearate, and sorbitan monooleate. Among these, polyglyceryl-2 triisostearate is preferred because it can suppress the aggregation and sedimentation of charcoal powder without impairing the user experience, such as the feeling of residue after rinsing.

[0035] The content of component C in the oil-based solid cleansing cosmetic of the present invention is 0.01 to 5.0% by mass, preferably 0.01 to 4.0% by mass. When the above content is 0.01% by mass or more, aggregation and sedimentation of charcoal powder can be suppressed. Furthermore, when the above content is 5.0% by mass or less, aggregation and sedimentation of charcoal powder can be suppressed without impairing the feeling of residue when rinsing. The above content of component C is the total content of all component C in the oil-based solid cleansing cosmetic of the present invention.

[0036] [Component D] Component D is a nonionic surfactant with an HLB value of 8-15. By using component D, it is possible to create an oil-based solid cleansing cosmetic that blends well with makeup during use and leaves little residue after rinsing. The HLB value in this specification can be calculated using the Griffin method.

[0037] The HLB value of component D is 8 to 15, preferably 8 to 14, and more preferably 8 to 13. Having the above HLB value within this range results in excellent makeup blendability and washability during use.

[0038] Component D is not particularly limited as long as it is a nonionic surfactant with an HLB value of 8 to 15, but examples include polyglycerin fatty acid esters, sorbitan fatty acid esters, monoglycerin fatty acid esters and their alkylene oxide adducts, polyoxyalkylene alkyl ethers, polyoxyalkylene fatty acid esters, polyoxyalkylene alkylphenols, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene alkylphenyl formaldehyde condensates, polyoxyethylene sterols and their derivatives, polyoxyethylene lanolin and its derivatives, polyoxyethylene beeswax derivatives, sugar esters, polyoxyethylene hydrogenated castor oil, and polyoxyethylene castor oil.

[0039] Ingredient D preferably contains a polyglycerin fatty acid ester, as it provides excellent makeup blendability during use and leaves the skin feeling supple after rinsing. Examples of polyglycerin fatty acid esters include polyglyceryl-6 dicaprate, polyglyceryl-10 dioleate, polyglyceryl-6 caprylate, and polyglyceryl-2 caprate.

[0040] The content of component D in the oil-based solid cleansing cosmetic of the present invention is 8 to 22% by mass, preferably 9 to 21% by mass, and more preferably 10 to 20% by mass. When the above content is 8% by mass or more, it blends well with makeup during use. When the above content is 22% by mass or less, it rinses off well.

[0041] Furthermore, when polyglycerin fatty acid ester is included as component D, the content of polyglycerin fatty acid ester in the oily solid cleansing cosmetic composition of the present invention is preferably 0.1 to 6.0% by mass, and more preferably 0.5 to 4.0% by mass. When the above content is 0.1% by mass or more, a moist and supple after-skin feeling is obtained after rinsing. When the above content is 6.0% by mass or less, the rinseability is even better.

[0042] [Component E] Component E is charcoal powder having a predetermined volume-based median diameter (hereinafter also simply referred to as median diameter). By using component E, the charcoal powder adsorbs makeup and sebum, resulting in an oil-based solid cleansing cosmetic with superior cleansing power. In the preparation process of oil-based solid cleansing cosmetics, there is a problem that the charcoal powder aggregates and settles, resulting in an uneven composition. However, by using it in combination with a predetermined amount of component C and water, aggregation and settling can be suppressed, and an oil-based solid cleansing cosmetic with excellent dispersibility of charcoal powder can be obtained.

[0043] Component E is not particularly limited, but is a porous carbon material and may contain hydrogen, oxygen, inorganic components, etc., in addition to carbon. Preferably, it is activated carbon with fine pores, produced by reacting a carbon material with gas or chemicals at high temperatures.

[0044] The raw materials for component E are not particularly limited, and those commonly used as raw materials for charcoal powder can be used. Specifically, examples include coconut shells, bamboo, wood, sawdust, coal, phenolic resin, rayon, acrylonitrile, coal pitch, petroleum pitch, etc. Among these, coconut shells, bamboo, and wood are preferred.

[0045] The median diameter of component E is 1 μm or more, preferably 3 μm or more, from the viewpoint of cleansing power. Furthermore, the median diameter of component E is 35 μm or less, preferably 32 μm or less, from the viewpoint of suppressing aggregation and sedimentation and the feeling of residue after rinsing.

[0046] In this specification, the volume-based median diameter of the charcoal powder can be measured by laser analysis / scattering particle size distribution measurement, and can be the value measured by, for example, a "Particle Size Distribution Meter LA-950V2" (manufactured by Horiba, Ltd.).

[0047] The content of component E in the oil-based solid cleansing cosmetic of the present invention is 0.01 to 5.0% by mass, preferably 0.02 to 4.0% by mass, and more preferably 0.03 to 3.5% by mass. When the above content is 0.01% by mass or more, the effects of incorporating charcoal powder can be obtained. Furthermore, when the above content is 5.0% by mass or less, excellent rinseability is achieved, and aggregation and sedimentation of component E can be suppressed. The above content of component E is the total content of all components E in the oil-based solid cleansing cosmetic of the present invention.

[0048] [Component F] Component F is water, and is not particularly limited, but purified water is preferred. Oily solid cleansing cosmetics generally do not contain water because they mainly consist of solid oil, liquid oil, and nonionic surfactants, and there is a risk of separation and precipitation. However, by using it in combination with predetermined amounts of components C and E, it is possible to suppress the aggregation and sedimentation of component E and to produce an oily solid cleansing cosmetic with excellent dispersibility of charcoal powder.

[0049] The content of component F in the oil-based solid cleansing cosmetic of the present invention is 0.5 to 6.0% by mass, preferably 0.6 to 5.5% by mass, and more preferably 0.8 to 4.0% by mass. When the above content is 0.5% by mass or more, aggregation and sedimentation of component E can be suppressed. Furthermore, when the above content is 6.0% by mass or less, excellent makeup blending is achieved during use. The above content of component F is the total content of all component F in the oil-based solid cleansing cosmetic of the present invention.

[0050] [Other ingredients] In addition to components A to F, the oil-based solid cleansing cosmetic composition of the present invention may contain other components as optional components, provided that they do not impair the effects of the present invention.

[0051] Other ingredients include surfactants other than components C and D, powders other than component E, dyes, oily gelling agents, oil-soluble resins, polyhydric alcohols, lower alcohols, whitening agents, activators, blood circulation promoters, anti-seborrheic agents, anti-inflammatory agents, cooling agents (also known as chilling agents), antibacterial agents, antiperspirant agents, UV absorbers, UV scattering agents, moisturizers, fragrances, antioxidants, preservatives, defoaming agents, and various extracts.

[0052] [Oil-based solid cleansing cosmetic] The oil-based solid cleansing cosmetic of the present invention is solid at 25°C. The term "solid" means that it does not have fluidity, and includes paste and gel forms. Furthermore, the shape of the oil-based solid cleansing cosmetic of the present invention is not particularly limited and may include stick, rod, plate, or molded form in containers such as jars.

[0053] The method for producing the oil-based solid cleansing cosmetic of the present invention is not particularly limited, and known methods for producing oil-based solid cleansing cosmetics can be employed. Examples of methods for producing the oil-based solid cleansing cosmetic of the present invention include mixing each component while heating to obtain a mixture, and then cooling and solidifying the obtained mixture. Examples of methods for mixing each component include using stirring devices such as disperser mixers and paddle mixers. However, the present invention is not limited to the above-described production method. Furthermore, it is preferable that the oil-based solid cleansing cosmetic of the present invention be filled into containers that can be easily removed, such as wide-mouth jar containers and tube containers.

[0054] The areas to which the oily solid cleansing cosmetic composition of the present invention is applied are not particularly limited, and include, for example, the face (forehead, around the eyes, corners of the eyes, cheeks, around the mouth, etc.) and the body (arms, elbows, back of the hands, fingertips, feet, knees, heels, neck, armpits, back, etc.). Among these, the face is particularly preferred. [Examples]

[0055] The present invention will be described in more detail below based on examples, but the present invention is not limited to these examples. The amounts listed in the table are the amounts of each component (i.e., the amount of the active ingredient in each raw material), and are expressed in "mass%" unless otherwise specified. Also, a "-" in the amounts in the table indicates that the component is not included.

[0056] Examples and Comparative Examples [Preparation of each sample] Oily solid cleansing cosmetics for the examples and comparative examples were prepared by conventional methods according to the compositions listed in Tables 1 and 2, and subjected to the evaluation tests described below. The evaluation results are shown in Tables 1 and 2.

[0057] The details of the main ingredients listed in the table are as follows: <Ingredient A> Synthetic wax: Product name "CireWax 80", manufactured by Cirebelle Fine Chemicals, melting point: 61-67°C Microcrystalline wax: Product name "MULTIWAX W-835", manufactured by Sonneborn Inc., melting point: 73.9~79.4℃ <Component B> Cetyl ethylhexanoate: Product name "NIKKOL-CIO", manufactured by Nikko Chemicals Co., Ltd. Ethylhexyl palmitate: Product name "NIKKOL TGI-20", manufactured by Nikko Chemicals Co., Ltd. <Component C> Polyglyceryl-2 triisostearate: Product name "Cossmall 43V", manufactured by Nisshin Oillio Group Ltd., HLB: 2.5 <Component D> PEG-20 Glyceryl Triisostearate: Product name "NIKKOL TGI-20", manufactured by Nikko Chemicals Co., Ltd., HLB: 8 PEG-8 glyceryl isostearate: Product name "Brownon RGL-8MISE", manufactured by Aoki Oil & Fat Industry Co., Ltd., HLB: 11.5 Polyglyceryl-6 dicaprate: Product name "Sunsoft Q-102H-C", manufactured by Taiyo Kagaku Co., Ltd., HLB: 10.2 <Component E> Charcoal powder 1: Product name "Medicinal Charcoal", manufactured by Horie Seiyaku Co., Ltd., median diameter: 31.1 μm Charcoal powder 2: Product name "Fine Binchotan Charcoal Powder", manufactured by Kiriya Chemical Co., Ltd., median diameter: 1.2 μm Charcoal powder 3: Product name "Binchotan Su" (Binchotan powder), manufactured by Kiriya Chemical Co., Ltd., median diameter: 5.7 μm Charcoal powder 4: Product name "Bamboo Charcoal Powder MM", manufactured by Latest Co., Ltd., median diameter: 11.4 μm <Other ingredients> Charcoal powder 5: Product name "Kuraraycol PGW-20MD", manufactured by Kuraray Chemical Co., Ltd., median diameter: 36.9 μm

[0058] [Formulation Evaluation] The appearance of each oil-based solid cleansing cosmetic composition in the examples and comparative examples after preparation was visually observed and evaluated according to the following evaluation criteria.

[0059] <Uniformity> A (Excellent): The powder is uniformly dispersed, and no sedimentation or color gradation can be observed. B (Good): The powder is evenly distributed throughout the cosmetic product, but a slight gradient can be observed compared to A. C (Practical): The powder is evenly distributed throughout the cosmetic product, but a gradient is visible. There are no practical problems. D (Defective): Powder sedimentation can be observed in more than one-third of the layer from the bottom.

[0060] [User experience evaluation] Approximately 0.05g of commercially available liquid foundation was applied to the inner side of the forearm and spread evenly in a circle with a radius of approximately 2cm. Next, approximately 0.5g of each oil-based solid cleansing cosmetic obtained in the examples and comparative examples was applied to the makeup stains on the application area, and after being thoroughly blended, the makeup was cleansed for 30 seconds using small circular motions with the fingertips, and then the makeup stains were rinsed off with warm water. Makeup blending, rinseability, and after-skin feel were evaluated according to the evaluation criteria below. The evaluation was determined by a panel of three expert evaluators.

[0061] <Makeup blends well> A (Excellent): It blended well with the makeup and removed makeup stains thoroughly. B (Good): While inferior to A in terms of makeup blending, it effectively removed makeup stains. C (Practical): While inferior to B in terms of makeup blending, it effectively removed makeup stains. D (Poor): Makeup doesn't blend well and makeup stains aren't completely removed.

[0062] <Rinse-off properties> A (Excellent): The time it takes for the slippery feeling of the cleansing cosmetic to disappear is sufficiently short, resulting in practically good rinsing properties. It is a flowing type. B (Good): The time it takes for the slippery feeling of the cleansing cosmetic to disappear is between A and C, indicating good rinsing properties for practical use. C (Practical): It takes a little time for the slippery feeling of the cleansing cosmetic to disappear, but it is practical to rinse off. D (Poor): It takes more than one minute for the slippery feeling of the cleansing cosmetic to disappear, making it unsuitable for practical use due to its poor rinsing properties.

[0063] <After-skin feel> A (Excellent): Leaves a pleasant, supple feeling on the skin after use. B (Good): After use, the skin feels plump and moisturized, somewhere between A and C. C (Practical): The skin feels slightly moisturized after use. D (Poor): I don't feel any moisturizing effect on my skin after use.

[0064] [Table 1]

[0065] [Table 2]

[0066] Furthermore, the following are examples of formulations for oil-based solid cleansing cosmetics that can be used in the present invention.

[0067] [Table 3]

Claims

[Claim 1] An oil-based solid cleansing cosmetic containing 4.0 to 20% by mass of component A, 70 to 86% by mass of component B, 0.01 to 3.0% by mass of component C, 8 to 22% by mass of component D, 0.01 to 5.0% by mass of component E, and 0.5 to 6.0% by mass of component F. Component A: Solid oil with a melting point of 50-120°C Ingredient B: Liquid oil Component C: Nonionic surfactant with an HLB value of 2-6 Component D: Nonionic surfactant containing polyglycerin fatty acid ester with an HLB value of 8 to 15 (provided that the content of the polyglycerin fatty acid ester in the oily solid cleansing cosmetic is 0.1 to 6.0% by mass) Component E: Carbon powder with a median diameter of 1 to 35 μm by volume. Ingredient F: Water