Fragrance composition

Abstract

A fragrance composition is provided. The fragrance composition comprises one or more fragrance ingredients, at least one solubilizing agent, and an acceptable carrier, and the composition is substantially free of ethanol. The composition is a fragrance, perfume, eau de toilette, eau de cologne, eau de parfum, fragrance mist, or air freshener. The composition can be personalized and can also provide a sensory experience.

Description

【Technical Field】 【0001】 The present disclosure generally relates to fragrance compositions. More specifically, the present disclosure relates to aqueous fragrance compositions. 【Background Art】 【0002】 Fragrances have been used for thousands of years. The industrial production of essential oils and the synthesis of odorants have improved the availability and scope of application of fragrances. Fragrances generally focus on the creation of new fragrances composed of more than 100 individual components, as well as the fixation of base notes to increase the adhesion and attachment of the fragrance to the user's skin. Other focuses of fragrances are the skin feel brought by the fragrance upon application to the skin and the transparency index of the fragrance solution. 【0003】 Typically, fragrance components are water-insoluble, and thus traditional fragrances use ethanol, other organic solvents, or carrier oils to dissolve the fragrance components. Ethanol is the most used component in the fragrance industry due to many advantages such as rapid evaporation in the atmosphere, cooling of the skin, and providing a very desirable cooling sensation to human skin. On the other hand, due to the nature of ethanol as a volatile organic compound (VOC) and its negative impact on skin integrity, the fragrance industry has been consistently working to partially or completely replace ethanol in fragrances as regulations on VOCs become stricter. More importantly, informed consumers are demanding fragrance products containing less ethanol. 【0004】 The fragrance industry has achieved some success by replacing ethanol in fragrances with other organic solvents. However, the advantages of ethanol cannot be easily realized with other organic solvents. One major drawback of other organic solvents is that their low vapor pressure results in an oily feeling on the skin that impairs fragrance bloom. Another drawback is that other organic solvents can cause staining on the application surface. As described above, there is a need for improved fragrance compositions that are substantially free of ethanol. [Overview of the Initiative] 【0005】 A water-based fragrance composition is provided. The fragrance composition comprises at least one fragrance component, at least one solubilizer, and an acceptable carrier, and is substantially free of ethanol. The at least one solubilizer is selected from the group consisting of PPG-26-buteth-26, PEG-40 hydrogenated castor oil, tridecth-9, PPG-20 methyl glucose ether, dipropylene glycol, hydrophilic polymers, and mixtures thereof, and the at least one fragrance component is selected from the group consisting of fragrance oils, esters, terpenes, aldehydes, ethers, lactones, amines, and mixtures thereof. The at least one fragrance oil is present in an amount of about 0.01% to about 25% by weight of the total weight of the composition. The at least one solubilizer is present in an amount of about 0.01% to about 75% by weight of the total weight of the composition, and the ratio of solubilizer to fragrance component is about 10:1 to about 1:10. The fragrance composition further comprises one or more preservatives or boosters. 【0006】 The fragrance composition has a viscosity of less than approximately 100 cps. The fragrance composition is stable at room temperature for at least 8 weeks. 【0007】 Fragrance components have a cLog P value of less than approximately 5. 【0008】 Fragrance compositions are in forms selected from the group consisting of fragrances, perfumes, eau de toilette, eau de cologne, eau de parfum, fragrance mist, and air freshener. Compositions may be sprays or continuous sprays. Compositions can be paired with one or more fragrance accords to obtain personalized fragrance compositions tailored to the needs of individual users. Compositions may further contain particles that provide a sensory experience. [Modes for carrying out the invention] 【0009】 The dimensions and values ​​disclosed herein should not be understood as strictly limited to the exact numerical values ​​listed. Instead, unless otherwise specified, each such dimension is intended to mean both the listed value and the functionally equivalent range surrounding that value. Unless otherwise expressly indicated in the Examples and Comparative Examples, all numbers herein indicating the quantities or ratios of materials or reaction conditions, or the physical properties of materials and / or uses, should be understood as being modified by the word “approximately.” All quantities are given by weight of the final composition unless otherwise specified. 【0010】 As used herein, the term “aqueous fragrance composition” refers to a fragrance composition containing more than approximately 40% water relative to the total weight of the composition. 【0011】 As used herein, the terms “fragrance composition” or “fragrance composition” refer to ordinary fragrance products, but also to other fragrances such as colognes, eau de toilettes, aftershaves, facial tonics, and tonics. 【0012】 The term "fragrance oil" refers to substances known to modify the scent of a product or to provide a scent to a person, including but not limited to essential oils, synthetic fragrances, or mixtures thereof. Essential oils may be odorous substances obtained from plants or spices by physical means, preferably by distillation. 【0013】 As used herein, the terms “spray” or “spray system” refer to a fluid composition that can be released or distributed from an aerosol, sprayer, or the like. 【0014】 As used herein, the term "Log P" value (of a compound) refers to the logarithm of its partition coefficient (P), defined as a specific ratio (cLog P(octanol / water)) of the solute concentrations between two solvents (in the case of a non-ionized solute, between n-octanol and water) (in the two phases of a liquid phase), calculated as Log P(partition coefficient) = Log([organic] / [aqueous]), and indicates the concentration of the solute in the organic and aqueous partitions. cLog P is the calculated Log P value. The higher the cLog P value of a compound, the more hydrophobic the compound is. 【0015】 As used herein, the term “substantially ethanol-free” refers to a composition containing less than approximately 0.001% ethyl alcohol by weight of the composition. According to the FDA, cosmetics that do not contain ethyl alcohol (also known as ethanol or grain alcohol) may be referred to and labeled as “alcohol-free.” Furthermore, in the fragrance industry, the term “alcohol” generally refers to ethyl alcohol, and therefore, in the fragrance industry, the term “substantially alcohol-free” refers to a composition containing less than approximately 0.001% ethyl alcohol by weight of the composition. However, since alcohol can also mean a wide variety of chemical substances in the general chemical community with different names and various effects on human skin, to avoid potential misunderstandings, the term “substantially ethanol-free” is used in this disclosure instead of “substantially alcohol-free.” 【0016】 As used herein, the term "room temperature" refers to a temperature between approximately 20°C and approximately 40°C. 【0017】 The fragrance compositions disclosed herein may comprise at least one fragrance component, at least one solubilizer, and water. 【0018】 The fragrance composition does not need to contain substantially no ethanol. Preferably, the fragrance composition may contain less than about 0.001% ethyl alcohol relative to the total weight of the fragrance composition. 【0019】 In conventional fragrance development, a large amount of water in a composition can reduce the clarity of the fragrance composition, resulting in a cloudy or milky appearance. The fragrance industry is well aware that the higher the water content, the more difficult it is to obtain a stable fragrance composition. The fragrance compositions disclosed herein may contain more than about 40% water relative to the total weight of the composition. In some compositions, the water content may be more than about 50% by weight relative to the total weight of the fragrance composition, while in others it may be more than 60%, 70%, 75%, or 80% by weight. In some special cases, the fragrance composition contains more than 85% by weight relative to the total weight of the fragrance composition. Advantageously, the fragrance compositions are translucent or transparent. 【0020】 The fragrance composition is stable and storable over a wide range of temperatures and conditions. The fragrance composition provides complete olfactory recovery of the fragrance oils, which is associated with long-term olfactory stability. When stored at 40°C, the fragrance composition may remain stable and clear for at least 8 weeks without any precipitation or turbidity. 【0021】 The fragrance composition contains a large amount of water, is substantially free of ethanol, and is in the form of a translucent or transparent composition over a wide range of temperatures and conditions. When applied to the skin, the fragrance composition provides an unexpectedly smooth, silky, non-sticky skin feel with an improved sensation. 【0022】 The fragrance components may include at least one fragrance oil. The fragrance oil may include essential oils, synthetic fragrances, or mixtures thereof. The fragrance oil may be present in an amount ranging from about 0.01% to about 40%, preferably about 0.1% to about 25%, and more preferably about 1% to about 10%, relative to the total weight of the fragrance composition. 【0023】 Fragrance oils may have a cLog P value of less than about 5, preferably less than about 3.1, and more preferably less than about 2.0. It is well understood in the fragrance industry that fragrance oils with a cLog P value greater than 5 are extremely hydrophobic and require additional solubilizers to aid in proper mixing into compositions. 【0024】 Fragrance ingredients may include fragrance oils, esters, terpenes, aldehydes, ethers, lactones, amines, and mixtures thereof. Musk oil, civet, castorium, ambergris, vegetable fragrances, sandalwood oil, neroli oil, bergamot oil, lemon oil, lavender oil, sage oil, rosemary oil, peppermint oil, eucalyptus oil, menthol, camphor, verbena oil, citronella oil, coconut oil, sage oil, clove oil, chamomile oil, costus oil, labdanum oil, bloom extract, carrot seed extract, jasmine extract, mimosa extract, narcissus extract, frankincense extract, rose extract, and Cetophenone and its derivatives, dimethylaniline derivatives, naphthalene derivatives, allyl caprate, α-amyl cinnamaldehyde, anethole, anisaldehyde, benzyl acetate, benzyl alcohol, benzyl propionate, bomeol, cinnamyl acetate, cinnamyl alcohol, citral, citronellal, cuminaldehyde, cyclamenaldehyde, decanol, ethyl butyrate, ethyl caprate, ethyl syl Nnamete, ethyl vanillin, eugenol, geraniol, exenol, α-hexyl cinnamaldehyde, hydroxycitronellal, indole, isoamyl acetate, isoamyl isovalerate, isoeugenol, linalool, linalyl acetate, p-methylacetophenone, methyl anthranilate, methyl dihydrojasmonate, methyl eugenol, methyl-β-naphthol ketone, methylphenylcarbinyl Fragrance oils that may be used include, but are not limited to, ammonium acetate, musk ketol, muskoxylol, 2,5,6-nonadienal, γ-nonalactone, phenylacetaldehyde dimethyl acetal, β-phenylethyl alcohol, 3,3,5-trimethylcyclohexanol, γ-undecalactone, undecenal, vanillin, metofluthrin, limonene, γ-terpinene, chalon, helional, or mixtures thereof. 【0025】 Fragrance additives or fragrance oils also include musk oil, civet, castorium, ambergris, vegetable fragrances, sandalwood oil, neroli oil, bergamot oil, lemon oil, lavender oil, sage oil, rosemary oil, peppermint oil, eucalyptus oil, menthol, camphor, verbena oil, citronella oil, coconut oil, sage oil, clove oil, chamomile oil, costus oil, labdanum oil, bloom extract, carrot seed extract, jasmine extract, mimosa extract, narcissus extract, frankincense extract, rose extract, acetophenone and its derivatives, dimethylaniline Cinnamal derivatives, naphthalene derivatives, allyl caprate, α-amyl cinnamaldehyde, anethole, anisaldehyde, benzyl acetate, benzyl alcohol, benzyl propionate, vomeol, cinnamyl acetate, cinnamyl alcohol, citral, citronellal, cuminaldehyde, cyclamenaldehyde, decanol, ethyl butyrate, ethyl caprate, ethyl cinnamate, ethyl vanillin, eugenol, geraniol, exenol, α-hexyl cinnamaldehyde, hydroxycitronellal (hydroxy It may contain citrolnellal, indole, isoamyl acetate, isoamyl isovalerate, isoeugenol, linalool, linalyl acetate, p-methylacetophenone, methyl anthranilate, methyl dihydrojasmonate, methyl eugenol, methyl-β-naphthol ketone, methylphenylcarbyl acetate, musk ketol, muskoxyl, 2,5,6-nonadienal, γ-nonalactone, phenylacetaldehyde dimethyl acetal, β-phenylethyl alcohol, 3,3,5-trimethylcyclohexanol, γ-undecalactone, undecenal, vanillin, metofluthrin, or mixtures thereof, bergamot oil, jasmine extract, lavender oil, limonene, γ-terpinene, chalon, helional, or mixtures thereof, limonene, γ-terpinene, chalon, helional, or mixtures thereof. Aromatic additives may also include bergamot oil, jasmine extract, lavender oil, bergamot oil, jasmine extract, lavender oil, or mixtures thereof. 【0026】 The fragrance composition can have a viscosity of less than about 100 cps, preferably less than about 50 cps, more preferably less than 15 cps. 【0027】 The measured viscosity indicates the transparency of the composition. 【0028】 The ratio of the total amount of solubilizer to the total amount of fragrance oil present can be from about 10:1 to about 1:10, including all ranges and sub-ranges within that range. At such ratios, the composition exhibits stability and transparency at temperatures in the range of about 3°C to about 55°C and ambient conditions. 【0029】 The total amount of solubilizer can be from about 0.001 wt% to about 75 wt%, preferably from about 0.01 wt% to about 50 wt%, more preferably from about 0.1 wt% to about 20 wt%, most preferably from about 1 wt% to about 10 wt%, particularly preferably from about 2 wt% to about 5 wt% based on the total weight of the composition. 【0030】 The fragrance composition can contain two or more solubilizers. 【0031】 The solubilizer can be selected from the group consisting of PPG-26-buteth-26, PEG-40 hydrogenated castor oil, trideceth-9, glyceryl-26, heptyl glucoside, capryl / capric glucoside, PPG-5-laureth-5, polysorbate 20, PEG-40 castor oil, PPG-1-PEG-9 lauryl glycol ether, coceth-7, PPG-1-PEG-9 lauryl glycol ether, PEG-80 castor oil, PEG-25 hydrogenated castor oil, PEG-4, PEG-20, and mixtures thereof. Preferably, the solubilizer can be selected from the group consisting of PPG-26-buteth-26, PEG-40 hydrogenated castor oil, trideceth-9, and mixtures thereof. 【0032】 Most preferably, the solubilizer comprises PPG-26-buteth-26, PEG-40 hydrogenated castor oil, and trideceth-9. The ratio of the amount of PPG-26-buteth-26 to the amount of PEG-40 hydrogenated castor oil may be in the range of about 10:1 to about 1:30, preferably about 5:1 to about 1:20, more preferably about 2:1 to about 1:10, and most preferably about 1:1 to about 1:5. The ratio of the amount of PPG-26-buteth-26 to the amount of trideceth-9 may be in the range of about 30:1 to about 1:20, preferably about 20:1 to about 1:15, more preferably about 10:1 to about 1:10, and most preferably about 5:1 to about 1:5. 【0033】 Fragrance compositions may be formulated as fragrances, perfumes, eau de toilettes, eau de colognes, eau de parfums, fragrance mists, or air fresheners. In some compositions, the fragrance blend may be formulated as a body lotion, body cream, deodorant spray, deodorant stick, shower gel, body scrub, shampoo, bubble bath, or soap. 【0034】 The fragrance composition may further contain a fragrance adjuster and a silicone oil suitable for use as a cosmetic. 【0035】 Fragrance modifiers include 3-((2-ethylhexyl)oxy)-propane-1,2-diol, dibenzylidenesorbitol, distearyl ether; ethylene glycol monomethyl ether, tri-o-(cis-3-hexenyl)-glactopyranose, (E)-1-(2,2,6-trimethylcyclohexyl)octa-1-en-3-one; 1-amino-3-((2-ethylhexyl)oxy)-propane-2-ol, 1-(1-methyl-2-propoxyethoxy)-2-propanol; 1-(1-menthoxy)propane N-2-ol, 1,2,4,4-pentamethyl-6-acetyl-7-formyl-1,2,3,4-tetrahydronaphthalene, 1,1,4,4-tetramethyl-6-acetyl-7-formyl-1,2,3,4-tetrahydronaphthalene, 2-(2-butoxyethoxy)ethanol, 2-(2-butoxyethoxy)ethyl(6-propylpiperonyl)ether, 2-(hexadecyloxy)ethanol, 2-(1-menthoxy) Ethane-1-ol, 2,4,6-tris[bis(methoxymethyl)amino]-1,3,5-triazineformaldehyde)methylated; 2-diphenylmethoxy-N,N-dimethylethylamine hydrochloride, 2-methyl-3-(1-mentheptyl)propane-1,2-diol, 3-((2-propylheptyl)oxy)-propane-1,2-diol; 3-(1-mentheptyl)propane-1,2-diol, 3-(1-mentheptyl) C) Propan-1-ol; 3-methoxybutanol; 4-(1-menthoxy), O2-14, ethoxylated; allantoin ascorbic acid, beheneth-5; benzyl hemiformal, bis-methoxy PEG-13, bis-o-(3,6-dioxadecanyl)-glucopyranose, bis-o-(3,6-dioxadecanyl)-glucopyranose, bis-o-(3,6-dioxadecanyl)-xylopyranose, bis-o-(3,6-Dioxadecanyl)-Galactopyranose, Butoxyethanol, C10-16 Pareth-1, C12-14 Sec-Pareth-3, C14-15 Pareth-7, Caprylyl Glyceryl Ether, Cetearyl Ethylhexanoate, Ceteth-10, Ceteth-12, Ceteth-2, Ceteth-3, Ceteth-4, Ceteth-5, Cetreth-10, Cetreth-10, Coceth-10 or Polyoxyethylene (10) Dodecyl Ether, Decaethylene Glycol Monododecyl Ether Laurin Ether, Deceth-4, Deceth-4 Phosphate, Deceth-6, Dermofeel G, Dicetyl Ether, Diethylene Glycol, Diethoxynonadiene, Diethylene Glycol Ethyl Ether, Diglycerin, Dihydro-7a-Ethyl Oxazolo[3,4-c]Oxazole dioxabicyclo[3.3.0]octane, diisoamyl adipate, diisobutyl adipate, dimethoxydiglycol ether, dimethyloxazolidine, di-o-(cis-3-hexenyl)-glactopyranose, di-o-(linalyl)-glucopyranose, dioxolane, dipentaerythrityl, hexacaprylate / hexacaprate, dipropylene glycol dimethyl ether, dipropylene glycol monomethyl ether, disodium lauroamphodipropionate, distearyl ether, DL-pan Tenol, ethoxyethanol alcohol, diethyl ether, ethyl hydroxymethyl oleyl oxazoline; ethylhexylglycerin, glycerol ethoxylate; glycerol formal, glycerol propoxylate, hexaethylene glycol monododecyl ether, hexaethylene glycol monohexadecyl ether, hexaethylene monododecyl ether, sodium disaccharide hyaluronate, hydroquinone β-D-glucoside, hydroxymethyl dioxoazabicyclooctane, isoceteth-10 Isocetes-12, Isocetes-15, Isocetes-20, Isocetes-25, Isocetes-30, Isocetes-5, Isocetes-7, Isosteareth-5, Laureth-1, Laureth-10, Laureth-2, Laureth-3, Laureth-4, Laureth-5, Laureth-7, Laureth-8, Menthong Glycerin Acetal, Menthoxypropanediol, Methoxydiglycol Ether, Methylhexyl Ether Ether, Methylhydroxymethyloleyloxazoline, Methylmorpholin Oxideamine Oxide, Methylal Ether, Mo No-o-(cis-3-hexenyl)-galactopyranose, mono-o-(linalyl)-glucopyranose; morpholine, myles-3, myles-4, myles-5, octyl ether dioctyl ether, octylphenoxy poly(ethyleneoxy)ethanol, branched oleth-10, oleth-2, oleth-3, oleth-4, oleth-5, oleth-8, panthenol ethyl ether, PEG-10, PEG-12, PEG-15 oleamine, PEG-3 methyl ether, PEG-5 hydrogenated beef tallowamine, PEG-6, PEG-9, pentakis-o-(3,6-Dioxadecanyl)-Glucopyranose, Pentax-o-(3,6-Dioxadodecanyl)-Glucopyranose, Pentax-o-(3,6-Dioxaoctanyl)-Galactopyranose, Penta-o-(Cis-3-Hexenyl)-Galactopyranose, Penta-o-(Linalyl)-Glucopyranose, Pluronic F-127, Poloxamine 1307, Poly(ethylene glycol) Methyl Ether, Poly(ethylene glycol-ran-propylene glycol) Monobutyl Ether, Poly(oxy-1,2-Ethanediyl), α-Decyl-ω-Hydroxy-Ethoxylate, Polypropylene Glycol) Monobutyl Ether, Polyethylene Glycol 1100 Mono(Hexadecyl / Octadecyl), Polyethylene Glycol Hexadecyl Ether, Polyglycerin #310, Polyglycerin-4 Ether, Polyglyceryl-10 Dioleate; Polyglyceryl-10 Myristale, Polyglyceryl-10 Oleate, Polyglyceryl-10 Stearate, Polyglyceryl-10 Tetraoleate, Polyglyceryl-10 trioleate, polyglyceryl-2 oleyl ether, polyglyceryl-6 isostearate, polyglyceryl-6 laurate, polyimide-1, polymethoxy bicyclic oxazolidine, polyoxy(ethylene glycol), polyoxyethylene(20) oleoyl ether; polyquaternium-10, polyvinyl stearyl ether, PPG-10 cetyl ether, PPG-11 stearyl ether, PPG-11 stearyl ether Kj, PPG-2 methyl ether, PPG-23- Steareth-34, PPG-4-Ceteth-10, PPG-5-Ceteth-20, Pramoxin HCl, Propyl (4-[2-(Diethylamino)-2-Oxoethoxy]-3-Methoxyphenyl) Acetate, Propylene Glycol, Propylene Glycol Caprylate, Propylene Glycol n-Butyl Ether, Propylene Glycol Propyl Ether, Sodium Hyaluronate, Sodium Octoxynol-2 Ethane Sulfonate, Stearamidopropyl Morpholine, Stearamidopropyl Morpholine Lactate, Steareth-10 Steareth-10 allyl ether, Steareth-10 allyl ether / acrylate copolymer, Steareth-2, Steareth-3, Steareth-4, Steareth-5, Steareth-6, Steareth-7, stearoxypropyl dimethylamine, sucrose dilaurate, sucrose distearate, sucrose laurate, sucrose myristate, sucrose palmitate, sucrose stearate, sucrose stristearate, Tarose-7, TEA-lauryl ether, tetra(ethylene glycol), tetrakiss-o-(3,6-Dioxadodecanyl)-Glucopyranose, Tetrakis-o-(3,6-Dioxaheptanyl)-Xylopyranoose, Tetrakis-o-(3,6-Dioxaoctanyl)-Galactopyranoose, Tetra-o-(cis-3-hexenyl)-Galactopyranoose (glactopyranose), Tetra-o-(Linalyl)-Glucopyranose, Tri(propylene glycol) n-butyl ether, Trideceth-3, Tridecyl ether, Triethylene glycol, Triglycerol diisostearate, Trimethylphenyl This can be selected from linalohydroxyethyl ether, tri-o-(linalyl)-glucopyranose, tripropylene glycol, tris-o-(3,6-dioxadecanyl)-glucopyranose, tris-o-(3,6-dioxadodecanyl)-glucopyranose, tris-o-(3,6-dioxaheptanyl)-xylopyranoose, tris-o-(3,6-dioxaoctanyl)-galactopyranoose, PPG-20, methyl glucose ether, dipropylene glycol, hydrophilic polymers, or mixtures thereof. 【0036】 Examples of silicone oils include bis-PEG-12 dimethicone, PEG-8 dimethicone, PEG-12 dimethicone, PEG-8 dimethicone, PEG-33 (and) PEG-8 dimethicone, PEG-14, PEG / PPG-18 / 18 dimethicone, PEG-9 dimethicone, PEG-12 dimethicone, PEG-9 polydimethylsiloxyethyl dimethicone, PEG-10 dimethicone, PEG-3 dimethicone, PEG-17 dimethicone, bis-PEG-8 dimethicone, bis-PEG-10 dimethicone, bis-PEG-8 PEG-8 dimethicone, dimethicone PEG-8 succinate, PEG / PPG-20 / 15 dimethicone (and) PPG-20 (and) dimethicone, and bis-PEG / PPG-16 / 16 Examples include, but are not limited to, PEG / PPG-16 / 16 dimethicone, PEG / PPG-19 / 19 dimethicone, PEG / PPG-14 / 4 dimethicone, PEG / PPG-22 / 23 dimethicone, cetyl PEG / PPG-10 / 1 dimethicone, bis-PEG / PPG-20 / 20 dimethicone, PEG / PPG-20 / 20, and phenylisopropylcaprylyl dimethicone. 【0037】 The fragrance composition may contain hydroxyacetophenone, potassium sorbate, and caprylyl glycol in a ratio ranging from approximately 0.01:0.01:0.01 to approximately 1:1:1. 【0038】 In some compositions, additives may be included, including particles that provide the user with a tactile sensory experience. Such particles may provide the user's skin with a soft, cold, or warm sensory experience, or a modifier. Additives may further provide visual effects, such as flashes from light-reflecting luminous particles. Light-reflecting luminous particles may be selected from one or more of titanium dioxide, mica, other iron oxides (e.g., yellow, reddish-brown, black), tin oxide, or mixtures thereof. 【0039】 In some compositions, the visual effect may result from the inclusion of particles and / or dyes in the composition. Such particles may include one or more of the following: ferric ammonium ferrocyanide (blue), manganese violet, ultramarine blue, chromium oxide (green), 30 talc, lecithin-modified talc, zeolite, kaolin, lecithin-modified kaolin, titanium dioxide (white), and mixtures thereof. In some compositions, the visual effect may include particles containing one or more pearlescent materials, e.g., mica, bismuth oxychloride, and treated mica, e.g., titanized mica and lecithin-modified mica, and mica coated with titanium dioxide of varying thicknesses, as well as thin-film optics that impart a bright luster and a wide range of interference colors and pleochroic effects. The visual effect may further include one or more particles containing small light-emitting diodes, LEDs, or light-emitting materials, which impart to the fragrance the ability to emit light continuously or intermittently. Fragrance compositions can be used in the form of fragrances and products, such as sunscreen gels, after-sun products, lotions, body gels, post- and pre-shave lotions, colonies, moisturizing eau de toilette, styling water, and / or facial tonics. The manufacture of such products is carried out by methods known to those skilled in the art. 【0040】 The following examples illustrate the compositions and methods of fragrance compositions described herein. Exemplary preservative systems and preservative booster systems include, but are not limited to, gluconolactone / sodium benzoate / calcium gluconate, phenoxyethanol / chlorooxylenol, benzyl alcohol / benzoic acid / sorbic acid, benzyl alcohol / pentylene glycol / benzoic acid / sorbic acid, phenoxyethanol / decylene glycol / phenoxyethanol / caprylyl glycol / potassium sorbate / water / hexylene glycol; 1,2-hexanediol, propanediol / phenylpropanol / caprylyl glycol; phenoxyethanol / caprylyl glycol / sorbic acid; phenoxyethanol / chlorphenesin / glycerin / sorbic acid; caprylyl glycol / phenoxyethanol / hexylene glycol; hydroxyacetophenone; phenoxyethanol / benzyl alcohol / potassium sorbate / tocopherol or combinations thereof. 【0041】 use Various methods of treatment, application, adjustment, or improvement may utilize the aforementioned composition. The composition may be applied to any skin surface of the body. Skin surfaces of greatest concern tend to be those not covered by clothing, such as the facial skin, the skin of the hands and arms, the skin of the feet and legs, and the skin of the neck and chest (e.g., the décolleté). The composition may be applied at least once a day, twice a day, or more frequently during the treatment period. If applied twice a day, the first and second applications should be spaced at least 1 to approximately 12 hours apart. 【0042】 The composition may be applied in conjunction with other products or formulations. The form of the composition or acceptable carrier should be selected to facilitate topical application. While specific embodiments of the present invention are intended for topical application, it will be understood that the compositions of the present invention may be applied more generally or broadly to one or more skin surfaces. Similarly, the composition may be applied as a continuous spray, as a lotion, or as a spray. Formulations may be paired with multiple fragrance notes and may be individualized and / or layered to benefit the needs of individual customers. Such pairings may be achieved by adding additional fragrance notes or fragrance accords to meet individual needs, resulting in a personalized fragrance composition unique to the consumer. 【0043】 Non-limiting examples of fragrance compositions include, but are not limited to, fragrances, household fragrances, sunscreens and sunscreens, mousses, bath and shower gels, lip balms, skin conditioners, cold creams, moisturizers, soaps, body scrubs, body washes, facial cleansers, body sprays, exfoliants, astringents, scuffing lotions, hair removal shaving products, pre-shave and after-shave products, deodorants and antiperspirants, cleansing agents, skin gels, rinses, whitening agents, and self-tanning compositions. Non-limiting examples of hair care compositions include, but are not limited to, shampoos, conditioners, treatments, styling products, hair sprays, perm styling products, tonics, cream rinses, hair dyes, hair coloring agents, hair bleaching agents, hair shines, hair serums, anti-frizzles, volumizers, split end repair agents, anti-dandruff formulations, and mascaras. Other non-exclusive examples of cosmetic compositions include, but are not limited to, cosmetics such as lipstick, lip gloss, foundation, blush, eyeliner, lip liner, lip gloss, face and body powder, nail polish, and eyeshadow. 【0044】 Furthermore, the compositions may be applied topically through the use of patches or other delivery devices. In some embodiments, for example, the compositions described herein may take the form of skin lotions, clear lotions, emulsions, creams, gels, foams, ointments, pastes, emulsions, sprays, conditioners, tonics, cosmetics, lipsticks, foundations, nail polishes, aftershave lotions, etc., which are intended to be left on the skin or other keratinous tissue for some aesthetic, preventative, therapeutic, or other benefit (i.e., “leave-on” compositions or skincare compositions). After applying the composition to keratinous tissue (e.g., skin), the composition is preferably left on for a period of at least about 2 minutes, 5 minutes, 15 minutes, more preferably at least about 30 minutes, even more preferably at least about 1 hour, and even more preferably at least several hours, for example, up to about 12 hours. The fragrance composition can be applied to any non-sensitive outer part of the human body. The composition can be applied using the palm and / or fingers or a device or instrument (e.g., cotton balls, swabs, pads, applicator pens, spray applicators, etc.). 【0045】 Examples Example 1: Fragrance composition The compositions of the examples (compositions 1 to 7) were prepared as follows. 1. Phase D was heated to a temperature above 45°C until it melted. 2. Phase B was premixed and added to phase D, and then cooled to room temperature to obtain phase BD. 3. Next, the premixed phase C and phase BD were combined to obtain phase BDC. 4. Phase BDC was slowly added to the pre-mixed phase A while mixing at 500 rpm until the solution went from turbid to clear. 【0046】 The methods described herein may be modified to reduce the particle size of the emulsion by adjusting the mixing rate and mixing ratio. The fragrance oil was measured to have a cLog P value of 2.57, and no significant levels of acid and base were present. The exemplary compositions provided herein are embodiments of stable, clear fragrance compositions that are substantially free of ethanol. 【0047】 [Table 1] * It is sold by IFF under the product name "Happy Different MOD 126". 【0048】 All formulations 1-7 passed the microcontent and standard challenges after 8 weeks. All formulations remained clear and stable. Surprisingly, the preparations were found to be silky smooth after application. Representative skin texture attributes from expert panelists are listed in Table 2 below on a 0-10 rating scale (for smoothness, higher numbers indicate a better experience; for oiliness, higher numbers indicate a worse experience; for stickiness, higher numbers indicate a worse experience). 【0049】 [Table 2] 【0050】 Therefore, formulation 1 provided the best overall experience in terms of smoothness, oiliness, and stickiness, while formulations 4 and 5 also provided a satisfactory experience, but not as good as the experience provided by formulation 1. 【0051】 Example 2: Stability of Formulation 1 The compositions of Formulation 1 were stored for 8 weeks at 4°C, 25°C, and 40°C, respectively. The compositions were observed to remain clear and transparent without any precipitation or turbidity. Their viscosity and pH were also measured, as shown in the table below. 【0052】 [Table 3] 【0053】 All documents referenced herein, including any cross-references or related patents or applications, are incorporated herein by reference in their entirety unless expressly excluded or otherwise limited. No reference to any document constitutes prior art to any invention disclosed or claimed herein, nor does it constitute teaching, suggestion, or disclosure of any such invention, either alone or in any combination with any other referenced document. Furthermore, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in any document incorporated by reference, the meaning or definition given to that term in this document shall apply. 【0054】 While specific embodiments of the present invention have been illustrated and described, it will be apparent to those skilled in the art that various other changes and modifications can be made without departing from the scope of the invention. Accordingly, the appended claims are intended to cover all such changes and modifications that fall within the scope of the invention. Examples of embodiments of the present invention include the following. [Embodiment 1] A fragrance composition, At least one fragrance ingredient, At least one solubilizing agent, The fragrance composition comprises more than 40% by weight of water relative to its total weight, The fragrance composition is substantially free of ethanol. [Embodiment 2] The fragrance composition according to Embodiment 1, wherein the at least one solubilizer is selected from the group consisting of PPG-26-buteth-26, PEG-40 hydrogenated castor oil, trideceth-9, and mixtures thereof. [Embodiment 3] The fragrance composition according to Embodiment 1, wherein the at least one fragrance component is a fragrance oil. [Embodiment 4] The fragrance composition according to Embodiment 3, wherein the fragrance oil is present in an amount of about 0.01% to about 25% by weight relative to the total weight of the composition. [Embodiment 5] The fragrance composition according to Embodiment 4, wherein the cLog P value of the fragrance oil is less than 5. [Embodiment 6] The fragrance composition according to Embodiment 1, wherein the at least one solubilizer is present in an amount of about 0.01% to about 75% by weight relative to the total weight of the fragrance composition. [Embodiment 7] The fragrance composition according to Embodiment 1, wherein the solubilizer and the fragrance component are present in a ratio of about 10:1 to about 1:10. [Embodiment 8] The fragrance composition according to Embodiment 1, wherein the fragrance composition has a viscosity of less than about 100 cps. [Embodiment 9] The fragrance composition according to Embodiment 1, wherein the fragrance composition is a fragrance, perfume, eau de toilette, eau de cologne, eau de parfum, fragrance mist, or air freshener. [Embodiment 10] The composition according to Embodiment 9, wherein the composition is in the form of a spray. [Embodiment 11] The composition according to embodiment 10, wherein the composition is a continuous spray. [Embodiment 12] The composition according to Embodiment 1, wherein the composition is paired with one or more fragrance accords to obtain an individualized fragrance. [Embodiment 13] The composition according to Embodiment 1, comprising particles that provide a sensory experience.

Claims

[Claim 1] A fragrance composition, At least one fragrance ingredient, A solubilizer comprising at least one type of solubilizer, including PPG-26-buteth-26, PEG-40 hydrogenated castor oil, and trideceth-9, The fragrance composition comprises more than 40% by weight of water relative to its total weight, The fragrance composition comprises less than 0.001% ethyl alcohol relative to the total weight of the fragrance composition. [Claim 2] The fragrance composition according to claim 1, wherein PPG-26-buteth-26 and PEG-40 hydrogenated castor oil are present in a weight ratio of 10:1 to 1:

30. [Claim 3] The fragrance composition according to claim 1, wherein the at least one fragrance component includes a fragrance oil. [Claim 4] The fragrance composition according to claim 3, wherein the fragrance oil is present in an amount of 0.01% to 25% by weight relative to the total weight of the composition. [Claim 5] The fragrance composition according to claim 4, wherein the cLog P value of the fragrance oil is less than 5. [Claim 6] The fragrance composition according to claim 1, wherein the at least one solubilizer is present in an amount of 0.001% to 75% by weight relative to the total weight of the fragrance composition. [Claim 7] The fragrance composition according to claim 1, wherein the solubilizer and the fragrance component are present in a weight ratio of 10:1 to 1:

10. [Claim 8] The fragrance composition according to claim 1, wherein the fragrance composition has a viscosity of less than 100 cps. [Claim 9] The fragrance composition according to claim 1, wherein the fragrance composition is a fragrance, perfume, eau de toilette, eau de cologne, eau de parfum, fragrance mist, or air freshener. [Claim 10] The fragrance composition according to claim 9, wherein the fragrance composition is administered by spray. [Claim 11] The fragrance composition according to claim 1, further comprising at least one fragrance modifier. [Claim 12] The fragrance composition according to claim 1, wherein the fragrance component is selected from the group consisting of fragrance oils, esters, terpenes, aldehydes, ethers, lactones, amines, and mixtures thereof. [Claim 13] The fragrance composition according to claim 1, wherein the fragrance composition comprises particles that provide a tactile sensory experience. [Claim 14] The fragrance composition according to claim 1, wherein the fragrance composition is translucent or transparent at temperatures and ambient conditions in the range of 3°C to 55°C. [Claim 15] The fragrance composition according to claim 3, wherein at least one fragrance oil is selected from the group consisting of essential oils, synthetic fragrances, and mixtures thereof. [Claim 16] The fragrance composition according to claim 1, wherein PPG-26-buteth-26 and trideceth-9 are present in a weight ratio of 30:1 to 1:

20. [Claim 17] The fragrance composition according to claim 1, further comprising at least one silicone oil.

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